JP4768943B2 - 改良された色を有するオリゴマー状有機リン組成物の形成方法 - Google Patents
改良された色を有するオリゴマー状有機リン組成物の形成方法 Download PDFInfo
- Publication number
- JP4768943B2 JP4768943B2 JP2001523412A JP2001523412A JP4768943B2 JP 4768943 B2 JP4768943 B2 JP 4768943B2 JP 2001523412 A JP2001523412 A JP 2001523412A JP 2001523412 A JP2001523412 A JP 2001523412A JP 4768943 B2 JP4768943 B2 JP 4768943B2
- Authority
- JP
- Japan
- Prior art keywords
- phosphite
- reaction
- aryl group
- ethylene oxide
- organophosphorus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 12
- 238000000034 method Methods 0.000 title claims description 22
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims abstract description 20
- 125000003118 aryl group Chemical group 0.000 claims abstract description 13
- 150000002903 organophosphorus compounds Chemical class 0.000 claims abstract description 12
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims description 28
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 21
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 21
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- 229910019142 PO4 Inorganic materials 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000005600 alkyl phosphonate group Chemical group 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000001177 diphosphate Substances 0.000 claims 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims 1
- 235000011180 diphosphates Nutrition 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 abstract description 11
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 abstract description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 10
- 239000012467 final product Substances 0.000 abstract description 3
- -1 triphenyl phosphite Chemical compound 0.000 abstract description 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 abstract 2
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 10
- 238000007792 addition Methods 0.000 description 9
- 238000010992 reflux Methods 0.000 description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 8
- 229910052698 phosphorus Inorganic materials 0.000 description 8
- 239000011574 phosphorus Substances 0.000 description 8
- 241001550224 Apha Species 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 6
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- 235000011089 carbon dioxide Nutrition 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- VONWDASPFIQPDY-UHFFFAOYSA-N dimethyl methylphosphonate Chemical compound COP(C)(=O)OC VONWDASPFIQPDY-UHFFFAOYSA-N 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 125000005113 hydroxyalkoxy group Chemical group 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- MGMXGCZJYUCMGY-UHFFFAOYSA-N tris(4-nonylphenyl) phosphite Chemical group C1=CC(CCCCCCCCC)=CC=C1OP(OC=1C=CC(CCCCCCCCC)=CC=1)OC1=CC=C(CCCCCCCCC)C=C1 MGMXGCZJYUCMGY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2639—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing elements other than oxygen, nitrogen or sulfur
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/025—Purification; Separation; Stabilisation; Desodorisation of organo-phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/091—Esters of phosphoric acids with hydroxyalkyl compounds with further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
- C07F9/093—Polyol derivatives esterified at least twice by phosphoric acid groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4075—Esters with hydroxyalkyl compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Fireproofing Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/393,870 US6107507A (en) | 1999-09-10 | 1999-09-10 | Formation of oligomeric organophosphorus compositions with improved color |
US09/393,870 | 1999-09-10 | ||
PCT/EP2000/006352 WO2001019835A1 (fr) | 1999-09-10 | 2000-07-04 | Formation de compositions organophosphorees oligomeriques presentant une meilleure couleur |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2003509433A JP2003509433A (ja) | 2003-03-11 |
JP4768943B2 true JP4768943B2 (ja) | 2011-09-07 |
Family
ID=23556581
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2001523412A Expired - Lifetime JP4768943B2 (ja) | 1999-09-10 | 2000-07-04 | 改良された色を有するオリゴマー状有機リン組成物の形成方法 |
Country Status (9)
Country | Link |
---|---|
US (1) | US6107507A (fr) |
EP (1) | EP1210352B1 (fr) |
JP (1) | JP4768943B2 (fr) |
AT (1) | ATE250617T1 (fr) |
CA (1) | CA2384267A1 (fr) |
DE (1) | DE60005539T2 (fr) |
ES (1) | ES2206269T3 (fr) |
HK (1) | HK1049008B (fr) |
WO (1) | WO2001019835A1 (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050009939A1 (en) * | 2003-02-21 | 2005-01-13 | Woodbridge Foam Corporation | Isocyanate-based foam having improved anti-yellowing properties and process for production thereof |
US8557946B1 (en) | 2011-02-28 | 2013-10-15 | Wm. T. Burnett Ip, Llc | Oxidation discoloration resistant polyurethane foam |
CN103204876B (zh) * | 2012-01-12 | 2016-05-11 | 广东德美精细化工股份有限公司 | 一种低聚有机膦酸酯的制备方法 |
CN103146023A (zh) * | 2013-02-06 | 2013-06-12 | 北京东方美龙化工科技有限公司 | 一种高效阻燃剂脂肪族低聚磷/膦酸酯及其制备方法 |
CN110669194B (zh) * | 2019-09-04 | 2021-10-15 | 山西晋煤集团技术研究院有限责任公司 | 一种无卤高阻燃煤矿加固煤岩体用高分子材料及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5412325A (en) * | 1977-06-29 | 1979-01-30 | M & T Chemicals Inc | Phosphur compound and combustion inhibiting composition containing same |
JPS54133799A (en) * | 1978-04-03 | 1979-10-17 | Stauffer Chemical Co | Oligomer phosphoric acid ester flameproofing agent and method of producing same |
JPH07258371A (ja) * | 1993-12-16 | 1995-10-09 | Hoechst Ag | ヒドロキシアルコキシ基を持つ燐酸エステルオリゴマー、その製造方法およびその用途 |
JPH09188687A (ja) * | 1995-11-03 | 1997-07-22 | Hoechst Ag | 燐酸エステルオリゴマーの混合物の製造方法、並びにそれをウレタンフォームのための防炎加工剤として使用する方法 |
JPH09291093A (ja) * | 1996-04-25 | 1997-11-11 | Daihachi Chem Ind Co Ltd | 高温着色性が改善された芳香族ホスフェート組成物 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB812390A (en) * | 1955-06-06 | 1959-04-22 | Union Carbide Corp | Polymeric phosphate esters and their production |
US2909559A (en) * | 1958-02-03 | 1959-10-20 | Union Carbide Corp | Polymeric phosphate esters and their production |
US3099676A (en) * | 1961-11-03 | 1963-07-30 | Union Carbide Corp | Hydroxyalkyl polyphosphates |
AU4369272A (en) * | 1971-06-25 | 1974-01-03 | Berk Limited | Flame retardant composition |
US3931364A (en) * | 1974-12-23 | 1976-01-06 | Stauffer Chemical Company | Color improvement of phosphate esters |
US4140856A (en) * | 1978-02-22 | 1979-02-20 | Phillips Petroleum Company | Color stabilization of intumescent flame retardant |
US4382042A (en) * | 1978-04-03 | 1983-05-03 | Stauffer Chemical Company | Method of preparing oligomeric phosphate esters |
US4199534A (en) * | 1978-04-20 | 1980-04-22 | Stauffer Chemical Company | Poly (oxyorganophosphate/phosphonate) and process for preparing |
US5608100A (en) * | 1993-12-16 | 1997-03-04 | Hoechst Aktiengesellschaft | Oligomeric phosphoric acid esters which carry hydroxyalkoxy groups, their preparation and their use |
-
1999
- 1999-09-10 US US09/393,870 patent/US6107507A/en not_active Expired - Fee Related
-
2000
- 2000-07-04 WO PCT/EP2000/006352 patent/WO2001019835A1/fr active IP Right Grant
- 2000-07-04 DE DE60005539T patent/DE60005539T2/de not_active Expired - Lifetime
- 2000-07-04 ES ES00944002T patent/ES2206269T3/es not_active Expired - Lifetime
- 2000-07-04 CA CA002384267A patent/CA2384267A1/fr not_active Abandoned
- 2000-07-04 EP EP00944002A patent/EP1210352B1/fr not_active Expired - Lifetime
- 2000-07-04 JP JP2001523412A patent/JP4768943B2/ja not_active Expired - Lifetime
- 2000-07-04 AT AT00944002T patent/ATE250617T1/de not_active IP Right Cessation
-
2002
- 2002-12-05 HK HK02108877.9A patent/HK1049008B/zh not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5412325A (en) * | 1977-06-29 | 1979-01-30 | M & T Chemicals Inc | Phosphur compound and combustion inhibiting composition containing same |
JPS54133799A (en) * | 1978-04-03 | 1979-10-17 | Stauffer Chemical Co | Oligomer phosphoric acid ester flameproofing agent and method of producing same |
JPH07258371A (ja) * | 1993-12-16 | 1995-10-09 | Hoechst Ag | ヒドロキシアルコキシ基を持つ燐酸エステルオリゴマー、その製造方法およびその用途 |
JPH09188687A (ja) * | 1995-11-03 | 1997-07-22 | Hoechst Ag | 燐酸エステルオリゴマーの混合物の製造方法、並びにそれをウレタンフォームのための防炎加工剤として使用する方法 |
JPH09291093A (ja) * | 1996-04-25 | 1997-11-11 | Daihachi Chem Ind Co Ltd | 高温着色性が改善された芳香族ホスフェート組成物 |
Also Published As
Publication number | Publication date |
---|---|
CA2384267A1 (fr) | 2001-03-22 |
JP2003509433A (ja) | 2003-03-11 |
DE60005539D1 (de) | 2003-10-30 |
DE60005539T2 (de) | 2004-06-03 |
ES2206269T3 (es) | 2004-05-16 |
WO2001019835A1 (fr) | 2001-03-22 |
ATE250617T1 (de) | 2003-10-15 |
EP1210352B1 (fr) | 2003-09-24 |
HK1049008A1 (en) | 2003-04-25 |
EP1210352A1 (fr) | 2002-06-05 |
US6107507A (en) | 2000-08-22 |
HK1049008B (zh) | 2004-02-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4382042A (en) | Method of preparing oligomeric phosphate esters | |
CN105503946B (zh) | 羟甲基膦酸酯、聚氨酯泡沫形成组合物、聚氨酯泡沫以及由其制成的制品的制造方法 | |
Troev | Polyphosphoesters: chemistry and application | |
US4254018A (en) | Linear polyesters containing phosphonate heat stabilizers | |
US4697030A (en) | Phosphate-containing and phosphonate-containing phosphate esters | |
US4458035A (en) | Polyurethane foam having a flame retardant oligomeric phosphate ester | |
JP4768943B2 (ja) | 改良された色を有するオリゴマー状有機リン組成物の形成方法 | |
US3264247A (en) | Pentyl isobutyrate phosphite plastizer-stabilizer | |
US3152164A (en) | Novel cyclic phosphite esters and process involving transesterification of a phosphite diester with a glycol | |
US4886895A (en) | Phosphate-containing and phosphonate-containing phosphate esters | |
JP2010535163A (ja) | アルコキシル化リン酸トリエステルの製造方法 | |
US3422453A (en) | Di-o-biphenylyl diphenyl bisphenol a bis phosphate and process | |
JP3483152B2 (ja) | 有機りん化合物及びその製造方法 | |
US4142904A (en) | Flame retardant polycarboxy alkyl and aryl phosphonates | |
EP0735039B1 (fr) | Un procédé de préparation de phosphates de tribromonéopentyle et de chloroalkyle | |
US5117033A (en) | Phosphate-containing and phosphonate-containing phosphate esters | |
CN114524843A (zh) | 一种端羟基反应型阻燃剂及其制备方法 | |
CA1127176A (fr) | Procede d'obtention d'esters de phosphate oligomeriques, retardateurs de flammes | |
US4820854A (en) | Phosphate-containing and phosphonate-containing phosphate esters | |
US3830890A (en) | Method of making esters of 1,4-diphosphonyl butene | |
JPH06157567A (ja) | ペンタエリトリットに基づくリンヘテロ環を形成する方法 | |
US3890411A (en) | Process for forming phosphorus containing polymers | |
JPH10500656A (ja) | ビス(ペンタエリトリトールホスフェートアルコール)アルキルホスホネート | |
US3372209A (en) | Diphosphorus ester hydrocarbon diols | |
CN107074893A (zh) | 用于合成杂环氧化氢膦的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A711 Effective date: 20060224 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070629 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20091214 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20091221 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20100319 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20100329 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20100420 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20100427 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20100520 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20100527 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20101027 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110126 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20110613 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20110617 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 4768943 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140624 Year of fee payment: 3 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
EXPY | Cancellation because of completion of term |