JP4614963B2

JP4614963B2 - スルホン化脂肪族−芳香族コポリエステル、およびそれから生成された造形品

スルホン化脂肪族−芳香族コポリエステル、およびそれから生成された造形品 Download PDF

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Publication number: JP4614963B2
Authority: JP; Japan
Prior art keywords: film; aromatic; aliphatic; acid; sulfonated aliphatic
Prior art date: 2003-06-11
Legal status : Expired - Fee Related

Application number

JP2006533799A

Other languages

English (en)

Japanese (ja)

Other versions

JP2007502909A (ja

JP2007502909A5 (enExample

Inventor

アレンヘイズリチャード

Current Assignee

EIDP Inc

Original Assignee

EI Du Pont de Nemours and Co

Priority date

2003-06-11

Filing date

2004-06-10

Publication date

2011-01-19

2004-06-10 Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co

2007-02-15 Publication of JP2007502909A publication Critical patent/JP2007502909A/ja

2007-07-19 Publication of JP2007502909A5 publication Critical patent/JP2007502909A5/ja

2011-01-19 Application granted granted Critical

2011-01-19 Publication of JP4614963B2 publication Critical patent/JP4614963B2/ja

2024-06-10 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

229920001634 Copolyester Polymers 0.000 title claims description 202
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 170
239000000758 substrate Substances 0.000 claims description 162
239000000203 mixture Substances 0.000 claims description 124
239000000463 material Substances 0.000 claims description 116
239000000945 filler Substances 0.000 claims description 91
238000000576 coating method Methods 0.000 claims description 88
239000002245 particle Substances 0.000 claims description 87
239000011248 coating agent Substances 0.000 claims description 74
239000000835 fiber Substances 0.000 claims description 71
229920000728 polyester Polymers 0.000 claims description 66
239000004927 clay Substances 0.000 claims description 65
239000011087 paperboard Substances 0.000 claims description 62
235000013305 food Nutrition 0.000 claims description 55
239000006260 foam Substances 0.000 claims description 54
-1 chalk Substances 0.000 claims description 50
239000000123 paper Substances 0.000 claims description 46
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 42
229920002472 Starch Polymers 0.000 claims description 41
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 41
235000019698 starch Nutrition 0.000 claims description 39
239000002253 acid Substances 0.000 claims description 38
239000008107 starch Substances 0.000 claims description 35
125000003118 aryl group Chemical group 0.000 claims description 28
239000011521 glass Substances 0.000 claims description 28
125000001931 aliphatic group Chemical group 0.000 claims description 24
ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical group OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 claims description 24
229920002678 cellulose Polymers 0.000 claims description 23
239000001913 cellulose Substances 0.000 claims description 21
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 19
239000006085 branching agent Substances 0.000 claims description 19
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 17
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 16
229920000881 Modified starch Polymers 0.000 claims description 16
235000019426 modified starch Nutrition 0.000 claims description 16
XTDYIOOONNVFMA-UHFFFAOYSA-N dimethyl pentanedioate Chemical compound COC(=O)CCCC(=O)OC XTDYIOOONNVFMA-UHFFFAOYSA-N 0.000 claims description 15
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 14
239000004368 Modified starch Substances 0.000 claims description 12
TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 12
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 12
150000002148 esters Chemical class 0.000 claims description 12
238000011049 filling Methods 0.000 claims description 12
CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 claims description 12
239000011256 inorganic filler Substances 0.000 claims description 11
229910003475 inorganic filler Inorganic materials 0.000 claims description 11
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 10
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 10
150000002334 glycols Chemical class 0.000 claims description 10
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 10
239000012766 organic filler Substances 0.000 claims description 10
239000002023 wood Substances 0.000 claims description 9
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
229920008262 Thermoplastic starch Polymers 0.000 claims description 8
229910000019 calcium carbonate Inorganic materials 0.000 claims description 8
WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 claims description 8
235000013312 flour Nutrition 0.000 claims description 8
239000000377 silicon dioxide Substances 0.000 claims description 8
239000004408 titanium dioxide Substances 0.000 claims description 8
229920002261 Corn starch Polymers 0.000 claims description 7
229920003232 aliphatic polyester Polymers 0.000 claims description 7
239000000440 bentonite Substances 0.000 claims description 7
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SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 7
239000008120 corn starch Substances 0.000 claims description 7
VNGOYPQMJFJDLV-UHFFFAOYSA-N dimethyl benzene-1,3-dicarboxylate Chemical compound COC(=O)C1=CC=CC(C(=O)OC)=C1 VNGOYPQMJFJDLV-UHFFFAOYSA-N 0.000 claims description 7
KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims description 7
229910000271 hectorite Inorganic materials 0.000 claims description 7
239000000454 talc Substances 0.000 claims description 7
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239000005995 Aluminium silicate Substances 0.000 claims description 6
235000012211 aluminium silicate Nutrition 0.000 claims description 6
239000011324 bead Substances 0.000 claims description 6
QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 claims description 6
239000000919 ceramic Substances 0.000 claims description 6
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
229940100486 rice starch Drugs 0.000 claims description 6
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239000004628 starch-based polymer Substances 0.000 claims description 6
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims description 6
SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 claims description 6
UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 claims description 5
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239000001361 adipic acid Substances 0.000 claims description 5
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238000010030 laminating Methods 0.000 claims description 5
RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 claims description 5
229920006280 packaging film Polymers 0.000 claims description 5
239000012785 packaging film Substances 0.000 claims description 5
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RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 4
MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 claims description 4
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 4
150000007513 acids Chemical class 0.000 claims description 4
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 4
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 4
GYUVMLBYMPKZAZ-UHFFFAOYSA-N dimethyl naphthalene-2,6-dicarboxylate Chemical compound C1=C(C(=O)OC)C=CC2=CC(C(=O)OC)=CC=C21 GYUVMLBYMPKZAZ-UHFFFAOYSA-N 0.000 claims description 4
ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 claims description 4
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229920000098 polyolefin Polymers 0.000 claims description 4
125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 3
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239000007983 Tris buffer Substances 0.000 claims description 3
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 3
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GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 claims description 2
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QPKOBORKPHRBPS-UHFFFAOYSA-N bis(2-hydroxyethyl) terephthalate Chemical compound OCCOC(=O)C1=CC=C(C(=O)OCCO)C=C1 QPKOBORKPHRBPS-UHFFFAOYSA-N 0.000 description 13
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CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
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CESXSDZNZGSWSP-UHFFFAOYSA-L manganese(2+);diacetate;tetrahydrate Chemical compound O.O.O.O.[Mn+2].CC([O-])=O.CC([O-])=O CESXSDZNZGSWSP-UHFFFAOYSA-L 0.000 description 9
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DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
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125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 7
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WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 5
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