JP4584716B2 - 水素貯蔵用複合水素化物 - Google Patents

水素貯蔵用複合水素化物 Download PDF

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JP4584716B2
JP4584716B2 JP2004550428A JP2004550428A JP4584716B2 JP 4584716 B2 JP4584716 B2 JP 4584716B2 JP 2004550428 A JP2004550428 A JP 2004550428A JP 2004550428 A JP2004550428 A JP 2004550428A JP 4584716 B2 JP4584716 B2 JP 4584716B2
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hydrogen
hydride
hydrogen storage
titanium
pressure
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JP2006504616A (ja
JP2006504616A5 (https=
Inventor
ジダン ラゲイー
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サバンナ リバー ヌークリア ソリューションズ リミテッド ライアビリティ カンパニー
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/0005—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes
    • C01B3/001—Reversible storage of hydrogen, e.g. by hydrogen getters or electrodes characterised by the uptaking media; Treatment thereof
    • C01B3/0018—Inorganic elements or compounds, e.g. oxides, nitrides, borohydrides or zeolites; Solutions thereof
    • C01B3/0031—Intermetallic compounds; Metal alloys
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
    • C01B6/06—Hydrides of aluminium, gallium, indium, thallium, germanium, tin, lead, arsenic, antimony, bismuth or polonium; Monoborane; Diborane; Addition complexes thereof
    • C01B6/10—Monoborane; Diborane; Addition complexes thereof
    • C01B6/13—Addition complexes of monoborane or diborane, e.g. with phosphine, arsine or hydrazine
    • C01B6/15—Metal borohydrides; Addition complexes thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
    • C01B6/24—Hydrides containing at least two metals; Addition complexes thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Fuel Cell (AREA)
  • Battery Electrode And Active Subsutance (AREA)
JP2004550428A 2002-11-01 2003-11-03 水素貯蔵用複合水素化物 Expired - Fee Related JP4584716B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US42317202P 2002-11-01 2002-11-01
PCT/US2003/034980 WO2004041717A1 (en) 2002-11-01 2003-11-03 Complex hydrides for hydrogen storage

Publications (3)

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JP2006504616A JP2006504616A (ja) 2006-02-09
JP2006504616A5 JP2006504616A5 (https=) 2010-01-28
JP4584716B2 true JP4584716B2 (ja) 2010-11-24

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US (1) US7094387B2 (https=)
EP (1) EP1558520B1 (https=)
JP (1) JP4584716B2 (https=)
AT (1) ATE496865T1 (https=)
AU (1) AU2003286873A1 (https=)
CA (1) CA2503025C (https=)
DE (1) DE60335896D1 (https=)
WO (1) WO2004041717A1 (https=)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10163697A1 (de) * 2001-12-21 2003-07-03 Studiengesellschaft Kohle Mbh Reversible Speicherung von Wasserstoff mit Hilfe von dotierten Alkalimetallaluminiumhydriden
EP1558520B1 (en) 2002-11-01 2011-01-26 Savannah River Nuclear Solutions, LLC Complex hydrides for hydrogen storage
US7384574B2 (en) * 2003-07-17 2008-06-10 Westinghouse Savannah River Co. Hydrogen storage material and process using graphite additive with metal-doped complex hydrides
US20070014683A1 (en) * 2003-09-30 2007-01-18 General Electric Company Hydrogen storage composition, and associated article and method
US7175826B2 (en) * 2003-12-29 2007-02-13 General Electric Company Compositions and methods for hydrogen storage and recovery
US20060194695A1 (en) * 2004-08-27 2006-08-31 Westinghouse Savannah River Co., Llc Destabilized and catalyzed borohydrided for reversible hydrogen storage
US20110180753A1 (en) * 2008-02-22 2011-07-28 Toyota Motor Engineering & Manufacturing North America, Inc. Destabilized and catalyzed borohydride for reversible hydrogen storage
US8124559B2 (en) * 2004-08-27 2012-02-28 Toyota Motor Engineering & Manufacturing North America, Inc. Destabilized and catalyzed borohydride for reversible hydrogen storage
JP4427643B2 (ja) * 2004-08-27 2010-03-10 国立大学法人室蘭工業大学 活性化アルミニウム微粒子の乾燥及び保存方法
US8105974B2 (en) * 2004-08-27 2012-01-31 Toyota Motor Engineering & Manufacturing North America, Inc. Destabilized and catalyzed borohydride for reversible hydrogen storage
US8124558B2 (en) * 2004-08-27 2012-02-28 Savannah River Nuclear Solutions, Llc Catalyzed borohydrides for hydrogen storage
EP1838887B1 (en) * 2004-12-07 2012-04-18 The University of Queensland Magnesium alloys for hydrogen storage
CA2529427C (en) * 2004-12-17 2011-03-15 University Of New Brunswick Synthesis, recharging and processing of hydrogen storage materials using supercritical fluids
US20070092395A1 (en) * 2005-10-03 2007-04-26 General Electric Company Hydrogen storage material and method for making
US8883371B2 (en) * 2007-10-16 2014-11-11 Motorola Mobility Llc Hydrogen storage materials and hydrogen fuel cells
CN101970342B (zh) 2008-02-12 2012-11-28 爱利卡技术有限公司 掺杂的储氢材料
US7754641B2 (en) * 2008-02-14 2010-07-13 General Electric Company Hydrogen storage material and related processes
US8153020B1 (en) 2008-03-19 2012-04-10 University Of South Florida Hydrogen-storing hydride complexes
KR100984718B1 (ko) * 2008-08-11 2010-10-01 한화케미칼 주식회사 수소 저장물질로써 아릴 또는 알킬을 포함하는 유기-전이 금속 하이드라이드의 보다 개선된 제조방법
US20100233076A1 (en) * 2008-09-18 2010-09-16 Ford Global Technologies, Llc Hydrogen Storage Materials
AU2011220329B2 (en) 2010-02-24 2016-11-24 Hydrexia Pty Ltd Hydrogen release system
RU2466929C1 (ru) * 2011-03-24 2012-11-20 Федеральное государственное унитарное предприятие "Российский Федеральный ядерный центр - Всероссийский научно-исследовательский институт экспериментальной физики" (ФГУП "РФЯЦ-ВНИИЭФ") Способ обработки гидрида титана
CN104169211B (zh) 2011-12-15 2018-04-27 南威尔士大学商业服务有限公司 金属氢化物及它们在氢储存应用中的用途
RU2507150C1 (ru) * 2012-07-03 2014-02-20 Федеральное государственное унитарное предприятие "Российский Федеральный ядерный центр-Всероссийский научно-исследовательский институт экспериментальной физики" (ФГУП "РФЯЦ-ВНИИЭФ") Способ получения порошкообразного гидрида титана
JP6872902B2 (ja) 2013-06-14 2021-05-19 ユーエスダブリュー コマーシャル サービシズ リミテッド マンガン水素化物の合成及び水素貯蔵特性
DK3154901T3 (da) 2014-06-13 2023-12-18 Usw Commercial Services Ltd Syntese-og hydrogenlagringsegenskaber for hidtil ukendte metalhydrider
EP3325190A4 (en) 2015-07-23 2019-08-14 Hydrexia Pty Ltd MG-BASED ALLOY FOR HYDROGEN STORAGE
US11192783B1 (en) * 2017-06-08 2021-12-07 National Technology & Engineering Solutions Of Sandia, Llc Ternary borides and borohydrides for hydrogen storage and method of synthesis
US11267702B1 (en) 2017-06-08 2022-03-08 National Technology & Engineering Solutions Of Sandia, Llc Solid state synthesis of metal borohydrides
US11002255B2 (en) 2019-08-20 2021-05-11 Lowry Inheritors Trust Carbon negative clean fuel production system
US11976235B2 (en) 2020-10-27 2024-05-07 Battelle Savannah River Alliance, Llc High temperature thermochemical energy storage materials
CN114735643B (zh) * 2022-05-07 2023-10-27 瀚锐氢能科技集团有限公司 一种有机液态储氢材料及其性能调控方法和应用

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3720752A (en) * 1967-04-11 1973-03-13 Houten R Van Massive metal hydride structures and methods for their preparation
DE1909732A1 (de) * 1968-06-21 1970-02-19 Grosse Aristid Victor Verfahren und Vorrichtung zur Herstellung und Lagerung von Wasserstoff
US4360569A (en) * 1980-03-12 1982-11-23 The United States Of America As Represented By The United States Department Of Energy Porous metal hydride composite and preparation and uses thereof
US4790985A (en) * 1986-10-16 1988-12-13 Ethyl Corporation Synthesis of sodium aluminum hydride
US4948423A (en) * 1989-07-21 1990-08-14 Energy Conversion Devices, Inc. Alloy preparation of hydrogen storage materials
US5411928A (en) * 1993-05-24 1995-05-02 The United States Of America As Represented By The United States Department Of Energy Composition for absorbing hydrogen
DE4343321A1 (de) * 1993-12-18 1995-06-22 Varta Batterie Elektrischer Akkumulator
US5460745A (en) * 1994-02-07 1995-10-24 The United States Of America As Represented By The United States Department Of Energy Hydride compositions
DE69608182T2 (de) * 1995-07-18 2000-10-05 Matsushita Electric Industrial Co., Ltd. Wasserstoffspeichernde Legierung und Elektrode daraus
DE19526434A1 (de) * 1995-07-19 1997-01-23 Studiengesellschaft Kohle Mbh Verfahren zur reversilben Speicherung von Wasserstoff
JP3843459B2 (ja) * 1996-09-26 2006-11-08 トヨタ自動車株式会社 チタン系水素吸蔵合金粉末の製造方法
US6074453A (en) * 1996-10-30 2000-06-13 Iowa State University Research Foundation, Inc. Ultrafine hydrogen storage powders
DE69801860T2 (de) * 1997-01-27 2002-04-11 Shin-Etsu Chemical Co., Ltd. Verfahren zur Herstellung von Wasserstoffspeicherlegierungspulver und elektrode, die dieses Pulver enthält
SE9702189D0 (sv) * 1997-06-06 1997-06-06 Hoeganaes Ab Powder composition and process for the preparation thereof
CA2218271A1 (en) * 1997-10-10 1999-04-10 Mcgill University Method of fabrication of complex alkali mental hydrides
CA2220503A1 (en) * 1997-11-07 1999-05-07 Leszek Zaluski Hydrogen storage composition
DE19758384C2 (de) * 1997-12-23 2002-08-01 Geesthacht Gkss Forschung Verfahren zur Herstellung nanokristalliner Metallhydride
JP3528599B2 (ja) * 1998-05-21 2004-05-17 トヨタ自動車株式会社 水素吸蔵合金
CN1318033A (zh) * 1998-08-06 2001-10-17 夏威夷大学 新的储氢材料以及通过干式均化的制备方法
US6471935B2 (en) * 1998-08-06 2002-10-29 University Of Hawaii Hydrogen storage materials and method of making by dry homogenation
CA2345955A1 (en) * 1998-10-07 2000-04-13 Mcgill University Lithium-based hydrogen storage compositions
AU9425598A (en) * 1998-10-07 2000-04-26 Mcgill University Reversible hydrogen storage composition
US6268077B1 (en) * 1999-03-01 2001-07-31 Motorola, Inc. Portable fuel cell power supply
US6305442B1 (en) * 1999-11-06 2001-10-23 Energy Conversion Devices, Inc. Hydrogen-based ecosystem
DE10012794A1 (de) 2000-03-16 2001-09-20 Studiengesellschaft Kohle Mbh Verfahren zur reversiblen Speicherung von Wasserstoff auf der Basis von Alkalimetallen und Aluminium
US6680042B1 (en) * 2000-11-07 2004-01-20 Hydro-Quebec Method of rapidly carrying out a hydrogenation of a hydrogen storage material
US6596055B2 (en) * 2000-11-22 2003-07-22 Air Products And Chemicals, Inc. Hydrogen storage using carbon-metal hybrid compositions
TWI260344B (en) * 2001-01-12 2006-08-21 Safe Hydrogen Llc A method of operating a hydrogen-fueled device
US6773692B2 (en) * 2001-08-02 2004-08-10 Iowa State University Research Foundation, Inc. Method of production of pure hydrogen near room temperature from aluminum-based hydride materials
US6680043B2 (en) * 2001-11-29 2004-01-20 General Motors Corporation Process for enhancing the kinetics of hydrogenation/dehydrogenation of MAIH4 and MBH4 metal hydrides for reversible hydrogen storage
US6793909B2 (en) * 2002-01-29 2004-09-21 Sandia National Laboratories Direct synthesis of catalyzed hydride compounds
US20030165423A1 (en) * 2002-01-29 2003-09-04 Gross Karl J. Direct synthesis of hydride compounds using a titanium aluminate dopant
US7011768B2 (en) * 2002-07-10 2006-03-14 Fuelsell Technologies, Inc. Methods for hydrogen storage using doped alanate compositions
EP1558520B1 (en) 2002-11-01 2011-01-26 Savannah River Nuclear Solutions, LLC Complex hydrides for hydrogen storage

Also Published As

Publication number Publication date
AU2003286873A1 (en) 2004-06-07
DE60335896D1 (https=) 2011-03-10
JP2006504616A (ja) 2006-02-09
WO2004041717A1 (en) 2004-05-21
EP1558520A1 (en) 2005-08-03
US7094387B2 (en) 2006-08-22
EP1558520A4 (en) 2009-03-18
US20040105805A1 (en) 2004-06-03
EP1558520B1 (en) 2011-01-26
CA2503025C (en) 2011-01-04
CA2503025A1 (en) 2004-05-21
ATE496865T1 (de) 2011-02-15

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