JP4440653B2 - 水素および一酸化炭素の混合物を分離するための方法および装置 - Google Patents

水素および一酸化炭素の混合物を分離するための方法および装置 Download PDF

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JP4440653B2
JP4440653B2 JP2003583931A JP2003583931A JP4440653B2 JP 4440653 B2 JP4440653 B2 JP 4440653B2 JP 2003583931 A JP2003583931 A JP 2003583931A JP 2003583931 A JP2003583931 A JP 2003583931A JP 4440653 B2 JP4440653 B2 JP 4440653B2
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hydrogen
gas
synthesis gas
cryogenic separation
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デュモン、エリック
エルナンデズ、アントワーヌ
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レール・リキード−ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0233Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
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    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/506Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification at low temperatures
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    • C01B3/50Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/52Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with liquids; Regeneration of used liquids
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    • C01B3/50Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
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    • C01B32/40Carbon monoxide
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    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
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    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
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    • F25J3/0261Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of carbon monoxide
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    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0271Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of H2/CO mixtures, i.e. of synthesis gas
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415Purification by absorption in liquids
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    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
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    • C01B2203/0465Composition of the impurity
    • C01B2203/0475Composition of the impurity the impurity being carbon dioxide
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    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/048Composition of the impurity the impurity being an organic compound
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    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/74Refluxing the column with at least a part of the partially condensed overhead gas
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    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/90Details relating to column internals, e.g. structured packing, gas or liquid distribution
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    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/30Processes or apparatus using other separation and/or other processing means using a washing, e.g. "scrubbing" or bubble column for purification purposes
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    • F25J2270/00Refrigeration techniques used
    • F25J2270/02Internal refrigeration with liquid vaporising loop
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    • F25J2270/00Refrigeration techniques used
    • F25J2270/24Quasi-closed internal or closed external carbon monoxide refrigeration cycle
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S62/00Refrigeration
    • Y10S62/931Recovery of hydrogen

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Industrial Gases (AREA)
  • Separation Of Gases By Adsorption (AREA)
JP2003583931A 2002-04-15 2003-04-14 水素および一酸化炭素の混合物を分離するための方法および装置 Expired - Fee Related JP4440653B2 (ja)

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Application Number Priority Date Filing Date Title
FR0204681A FR2838424B1 (fr) 2002-04-15 2002-04-15 Procede et installation de separation d'un melange d'hydrogene et de monoxyde de carbone
PCT/FR2003/001174 WO2003086965A1 (fr) 2002-04-15 2003-04-14 Procede et installation de separation d'un melange d'hydrogene et de monoxyde de carbone

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JP2005522396A JP2005522396A (ja) 2005-07-28
JP2005522396A5 JP2005522396A5 (https=) 2009-08-20
JP4440653B2 true JP4440653B2 (ja) 2010-03-24

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US (1) US7380413B2 (https=)
EP (1) EP1503953B1 (https=)
JP (1) JP4440653B2 (https=)
CN (1) CN100339301C (https=)
AT (1) ATE362459T1 (https=)
AU (1) AU2003249147A1 (https=)
DE (1) DE60313863T2 (https=)
FR (1) FR2838424B1 (https=)
WO (1) WO2003086965A1 (https=)

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FR2861165B1 (fr) * 2003-10-20 2005-12-16 Air Liquide Procede et appareil pour la production de monoxyde de carbone et/ou d'hydrogene et/ou d'un melange d'hydrogene et de monoxyde de carbone par distillation cryogenique
FR2881417B1 (fr) * 2005-02-01 2007-04-27 Air Liquide Procede de production de gaz de synthese a faible emission de dioxyde de carbone
DE102005009393A1 (de) * 2005-03-01 2006-09-14 Linde Ag Verfahren zur Adsorberregenerierung
EP1890961B1 (fr) * 2005-06-06 2017-02-22 L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Procede pour la production simultanee d'hydrogene et de monoxyde de carbone
CN100358797C (zh) * 2006-07-12 2008-01-02 宋三奎 合成氨脱碳闪蒸气回收方法及回收装置
US20080181837A1 (en) * 2007-01-29 2008-07-31 Grover Bhadra S Hydrogen, Carbon Monoxide, and N2 Recovery From Low BTU Gases
EP2331898B1 (fr) * 2008-08-04 2017-12-27 L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Procédé de génération et de séparation d'un mélange d'hydrogène et de monoxyde de carbone par distillation cryogénique
CN101874962B (zh) * 2010-04-28 2012-08-22 上海戊正工程技术有限公司 一种分离羰基合成原料气的工艺及配套系统
FR2969136A1 (fr) * 2010-12-15 2012-06-22 Air Liquide Procede pour une production de monoxyde de carbone avec alimentation de boite froide stabilisee
FR2969134A1 (fr) * 2010-12-21 2012-06-22 Air Liquide Procede de traitement d'un gaz de synthese obtenu par gazeification, avec recyclage de gaz de flash extraits de la boite froide et de l'unite d'extraction des gaz acides
US8808425B2 (en) * 2011-08-30 2014-08-19 Air Products And Chemicals, Inc. Process and apparatus for producing hydrogen and carbon monoxide
WO2014082702A1 (de) 2012-11-29 2014-06-05 Linde Aktiengesellschaft Verfahren zum betrieb einer dampfreformierungsanlage
CN104512863A (zh) * 2013-09-30 2015-04-15 中国石油化工股份有限公司 一种净化粗氢气体的方法
DE102014003392A1 (de) 2014-03-06 2015-09-10 Linde Aktiengesellschaft Verfahren zum Betrieb einer Dampfreformierungsanlage
FR3054216B1 (fr) 2016-07-25 2021-07-09 Air Liquide Procede de separation d’un gaz de synthese
FR3057056B1 (fr) * 2016-10-03 2020-01-10 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Procede et appareil de recuperation d’argon dans une unite de separation d’un gaz de purge de synthese d’ammoniac
US11485637B2 (en) * 2020-08-10 2022-11-01 Praxair Technology, Inc. Process for purifying a synthesis gas

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EP1503953A1 (fr) 2005-02-09
EP1503953B1 (fr) 2007-05-16
FR2838424B1 (fr) 2004-05-28
US7380413B2 (en) 2008-06-03
ATE362459T1 (de) 2007-06-15
US20050232854A1 (en) 2005-10-20
DE60313863D1 (de) 2007-06-28
CN100339301C (zh) 2007-09-26
CN1646421A (zh) 2005-07-27
DE60313863T2 (de) 2008-01-17
WO2003086965A1 (fr) 2003-10-23
JP2005522396A (ja) 2005-07-28
AU2003249147A1 (en) 2003-10-27
FR2838424A1 (fr) 2003-10-17

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