JP4424878B2 - label - Google Patents

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JP4424878B2
JP4424878B2 JP2001292931A JP2001292931A JP4424878B2 JP 4424878 B2 JP4424878 B2 JP 4424878B2 JP 2001292931 A JP2001292931 A JP 2001292931A JP 2001292931 A JP2001292931 A JP 2001292931A JP 4424878 B2 JP4424878 B2 JP 4424878B2
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label
adhesive
sensitive adhesive
pressure
water
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JP2003098969A5 (en
JP2003098969A (en
Inventor
充 宮本
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Daio Paper Corp
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Daio Paper Corp
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Description

【0001】
【発明の属する技術分野】
本発明は、PETボトルやビン類等に使用されるラベルに関するものである。
【0002】
【従来の技術】
従来、粘着剤を用いてPETボトルや、ガラスビン等の被着体にラベルを貼着することが一般に行われているが、使用済みPETボトルや、ガラスビンのリサイクル等、昨今の資源リサイクルの流れにおいては、被着体からの粘着剤の除去が困難であり、リサイクルの妨げになることから粘着剤の使用が避けられてきた。
【0003】
近年、PETボトル等のリサイクル工程に、熱水や熱アルカリ水による洗浄工程を組み入れることで、被着体に付着した粘着剤を溶解・離解させ、粘着ラベルを剥がしたり除去することが容易になっている。
【0004】
更に、粘着ラベルの粘着剤塗布面の一部をマスキング加工し、粘着剤によるラベル貼合面積を少なくすることで、剥離が更に容易なラベルが使用されるようになってきている。
【0005】
しかし、熱水や熱アルカリ水洗浄等による被着体からの粘着剤除去工程においては、熱水や熱アルカリ水の洗浄液汚水中に溶存する粘着剤の量が短時間で高くなり、洗浄されたPETボトル等の被着体に粘着剤が再付着し、粘着剤による汚染が生じる問題が発生し、熱水や熱アルカリ水洗浄液の入れ替えを頻繁に行わなければならないという問題を有している。
【0006】
また、僅かの熱水や熱アルカリ水にてラベルを容易に剥離可能にするマスキング加工は、従来の商品名、品質等の商品情報の印字に加え、マスキング加工工程を別途設けることが必要であり、コストアップの問題を有している
【0007】
更に、マスキング加工を施したラベルを、ガラスビンのプレラベルとして使用した場合においては、中身充填工程前のラベル付ガラスビン洗浄時にラベルが剥がれ易いという問題も有している
【0008】
【発明が解決しようとする課題】
本発明は、PETボトルやガラスビン等への商品充填工程において、ビン洗浄工程でラベルが剥がれ落ちることがなく、更に、使用後の、熱水・熱アルカリ水による洗浄工程においては、容易に被着物から剥離できるラベルを提供することを目的とする。
【0009】
【課題を解決するための手段】
本発明においては、表面基材、粘着剤層及び剥離紙を順次積層してなるラベルにおいて、前記粘着剤層がアルカリ可溶性アクリル系のエマルジョン型粘着剤と、前記アルカリ可溶性アクリル系のエマルジョン型粘着剤に対し、架橋剤が1〜3重量部添加されたことを特徴とし、更に好適には、前記架橋剤が、エポキシ基含有のポリグリコールポリグリシジルエーテル及び/またはエチレングリコールジグリシジルエーテルを主成分として含むことを特徴とする。
【0010】
【発明の実施の形態】
本発明に用いられるアルカリ可溶性アクリル系エマルジョン粘着剤としては、熱アルカリ水に対し溶解性が高く、かつ熱水に対し、膨潤しやすいものが用いられる。本発明における好適な粘着剤としては、ベースポリマーとして、アクリル酸ブチル、アクリル酸2−エチルヘキシル等のアクリル酸エステル等を用い、モノマー成分としてアクリル酸メチル等のカルボキシ含有モノマー、更に粘着剤へのアルカリ溶液及び水に対する親水性をあげるため、アクリルアマイド等親水性モノマーを共重合させたアクリル系粘着剤が挙げられる。
【0011】
一方、本発明に好適に用いられる架橋剤は、エポキシ基含有のポリグリコールポリグリシジルエーテル、エチレングリコールジグリシジルエーテル等が好ましく、特に、水酸基を含むことで親水性をより向上させたポリグリコールポリグリシジルエーテルが好ましい。
【0012】
本発明における架橋剤の添加量は、前記粘着剤100重量部に対して1重量部から3重量部添加される。1重量部未満では、粘着剤のアルカリ溶液に対する溶解性は上がるが、膨潤し難く、架橋密度が低く、粘着力が強いため、再剥離の際に糊残りが発生したり、基材破断が発生するため、剥離性に乏しい。
【0013】
架橋剤の添加が3.0重量部を超えると、再剥離の際に糊が残ることなく、再剥離性は良好であるが、実使用時に、ラベルの浮き・剥がれが発生し不具合を生じる問題が発生する。また、ガラスビンのプレラベルとして使用した際には、中身充填前の洗浄工程にてラベルの剥がれる問題が発生する。
【0014】
本発明に使用されるラベルの表面基材は、PETボトルとラベルの比重差を利用することで剥離したラベルを容易に分離させる必要があり、比重1未満の基材、例えば、上質紙、クレープ紙、耐水紙等の紙類やポリプロピレンフィルム、ポリエチレンフィルム、発泡ポリエチレンフィルムが好適に用いられ、延伸フィルムまたは無延伸フィルムでも好適に用いることができる。
【0015】
本発明におけるラベルの表面基材の厚みは、ラベリング適性、作業性を考慮して20μmから150μm程度が好適に用いられる。20μm未満では、ラベリングの際にシワ等が発生する場合があり、また150μm以上では、PETボトル及びガラスビン等の被着物に貼付した際、経時で曲面反発を起こす問題を有している。
【0016】
本発明のラベルに用いられる剥離シートは、グラシン紙に代表されるように、従来公知の剥離紙が好適に用いられ、ラベリングマシンの光電管センサーに感知することのできる一般的な透過率を持ち、その剥離シートに水、溶剤型あるいは無溶剤型のシリコーン樹脂やフッ素樹脂等を乾燥重量で0.05〜3g/m2程度塗布し、剥離層を形成したものが好適に使用される。
【0017】
本発明のラベルに粘着剤を塗布する装置としては、従来公知の塗布装置が用いられ、例えばロールコーター、ナイフコーター、バーコーター、ダイコーター、コンマコーター、リップコーターが、適宜使用される。
【0018】
本発明のラベルに設けられる粘着剤の塗工量は、乾燥重量で10〜30g/m2の範囲で用途、被着物に応じ調節される。粘着剤の塗布量は、10g/m2未満では、得られる粘着性能が不十分であり、30g/m2を超えると、保管時及び貼りあわせ時に粘着剤がはみ出す問題が生じる恐れがある。
【0019】
本発明に好適に用いられる粘着剤には、本発明の本来の目的を損なわない範囲で必要に応じ、一般に公知の粘着付与剤樹脂、軟化剤、各種顔料、あるいは粘度調整剤などの助剤を添加して用いることができる。例えば、粘着付与樹脂としては、ロジンエステル樹脂、ポリテルペン樹脂、石油系樹脂などが使用できる。
【0020】
また、本発明においては、必要に応じて表面基材と粘着剤層の間にプライマー層を設けることができる。特に、表面基材の支持体としてフィルム等の投錨性の低い支持体を用いる場合は、プライマー層を設けることが好ましい。プライマー層としては、例えば、水酸化マグネシウム、炭酸マグネシウム、硫酸マグネシウム、酸化カルシウム、水酸化カルシウム、炭酸カルシウム、サチンホワイト等の顔料と澱粉、ポリビニールアルコール、カルボキシメチルセルロース、スチレンブタジエン共重合体などのバインダーを用いたものが挙げられる。
【0021】
【実施例】
以下、本発明を実施例及び比較例により具体的に説明するが、本発明はこれらにより限定されるものではない。尚、特に断らない場合、部及び%はそれぞれ重量部及び重量%を示す。
【0022】
粘着剤として、まず、アルカリ可溶性粘着剤(商品名:RP−265/東亜合成製)100重量部に対し、架橋剤としてポリグリコールポリグリシジルエーテル(商品名:デナコールEX−521/ナガセ化成工業製)を0部、0.5部、1.0部、2.0部、3.0部、4.0部、5.0部それぞれ添加して作成した。また、他の架橋剤として、エチレングリコールジグリシジルエーテル(商品名:デナコールEX−810/ナガセ化成工業製)を2.0部添加して作成した。
市販のグラシン紙に剥離剤(商品名:KS−847/信越化学工業製)を乾燥重量0.7g/m2となるように塗布し、乾燥させグラシン系剥離紙を作成し、そのグラシン系剥離紙に上記粘着剤を乾燥重量20g/m2となるように塗布し乾燥させた後、表面基材(商品名:ユポ/ユポコーポレーション製 80μm)を貼りあわせて粘着シートを作成した。
更に比較例として、水溶性粘着剤を使用した粘着シートを用意した。
【0023】
上記粘着シートを2.7リットル用PETボトルに貼り付け、10mm角に断裁後、70℃、80℃、90℃の水及び1.5%濃度のアルカリ溶液内に30分間浸漬させたところ、添加部数1重量部〜5重量部のものについて70℃以上で粘着剤の膨潤によるラベルの自然剥離が確認できた。
上記粘着シートを2.7リットル用PETボトルに貼り付け、40℃80%条件下に1週間放置後に手による再剥離性を確認したところ、添加部数1重量部〜5重量部のものについて粘着剤が残ることなく再剥離できた。
【0024】
上記粘着シートを50mm×100mmの大きさに断裁し、ガラスビンに貼り付けた後、中身充填時のビン洗浄を想定した工程1及び2にて、添加部数0重量部〜3重量部のものについてラベルに浮き剥がれがないことが確認できた。更に浮き剥がれ試験後に手による再剥離性を確認したところ、添加部数1重量部〜3重量部のものについて粘着剤が残ることなく再剥離できた。
ビン洗浄を想定した工程1は、まず15℃の水道水で1分洗浄した後、66℃の1.5%アルカリ水洗浄液に4分、63℃の2%アルカリ水洗浄液に2分浸漬し、35℃の水道水ですすぎを行った。
ビン洗浄を想定した工程2は、まず常温水で10秒洗浄した後、40℃の湯に5分、50℃の湯に5分、72℃の湯に5分、70℃の湯に5分、49℃の湯に5分、38℃の湯に5分、35℃の湯に5分浸漬した。
実施例及び比較例の評価結果を表1に示す。
【0025】
【表1】

Figure 0004424878
【0026】
<評価方法>
[剥がれ]
70℃、80℃、90℃の水及び1.5%アルカリ溶液内に30分間浸潰させた時のラベルの自然剥離性を目視にて観察した。
○:30分以内にラベルの自然剥離あり △:ラベルの一部自然剥離あり ×:ラベル剥がれなし
[膨潤]
70℃、80℃、90℃の水及び1.5%アルカリ溶液内に30分間浸潰させた時の粘着剤の膨潤を目視にて観察した。
○:粘着剤の膨潤あり ×:粘着剤の膨潤なし
[不溶解性]
70℃、80℃、90℃の水及び1.5%アルカリ溶液内に30分間浸潰させた時の粘着剤の溶解性を観察した。
○:溶解しない ×:溶解した
[手剥離性]
ラベルをPETボトルに貼り付け、40℃、80%条件下で1週間放置後の再剥離性を手で剥がすことにより確認した。
○:再剥離性良好 ×:再剥離しない・糊残りあり
[分離性]
洗浄液中でラベルが剥がれた後に被着体との分離性を観察した。
○:ラベルとビンの分離性良好 ×:ラベルがビンから分離しない
[耐水性]
ラベルを直径22mmのポリエステル製の棒に貼り、水に浸潰し、1時間後、3時間後、24時間後の浮き・剥がれを目視により確認した。
○:浮き・剥がれなし △:端部に浮きあり ×:剥がれあり
【0027】
【発明の効果】
アルカリ可溶型アクリル系エマルジョン粘着剤にポリグリコールポリグリシジルエーテルを1重量部から3重量部添加することにより70℃以上の水及び1.5%のアルカリ溶液で粘着剤を膨潤させ、洗浄液を粘着剤汚染させることなくラベルを自然剥離させることができ、かつ手による再剥離も可能となった。
また、ガラスビンに対しても洗ビン工程内でラベルが剥がれることなく、かつ使用後には、手で再剥離が可能となった。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a label used for PET bottles and bottles.
[0002]
[Prior art]
Conventionally, sticking a label to an adherend such as a PET bottle or a glass bottle using an adhesive is generally performed, but in the recent flow of resource recycling such as recycling of used PET bottles and glass bottles, etc. However, since it is difficult to remove the adhesive from the adherend and hinders recycling, the use of the adhesive has been avoided.
[0003]
In recent years, by incorporating a washing process with hot water or hot alkaline water into the recycling process of PET bottles, etc., it has become easier to dissolve and dissociate the adhesive attached to the adherend, and to peel off or remove the adhesive label. ing.
[0004]
Furthermore, a part of the pressure-sensitive adhesive application surface of the pressure-sensitive adhesive label is masked to reduce the label bonding area by the pressure-sensitive adhesive, so that labels that are more easily peeled off have been used.
[0005]
However, in the step of removing the adhesive from the adherend by washing with hot water or hot alkaline water, etc., the amount of the adhesive dissolved in the washing liquid sewage of hot water or hot alkaline water increased in a short time and was washed. There is a problem that the adhesive is reattached to the adherend such as a PET bottle, causing contamination by the adhesive, and the hot water or the hot alkaline water cleaning solution must be frequently replaced.
[0006]
In addition, the masking process that allows the label to be easily peeled off with a little hot water or hot alkaline water requires a separate masking process in addition to the conventional printing of product information such as product name and quality. , Have a problem of cost increase .
[0007]
Further, when a label subjected to masking is used as a pre-label for a glass bottle, there is also a problem that the label is easily peeled off when the labeled glass bottle is washed before the content filling step .
[0008]
[Problems to be solved by the invention]
The present invention does not peel off the label in the bottle washing process in the product filling process to PET bottles or glass bottles, and is easy to adhere in the washing process with hot water or hot alkaline water after use. It aims at providing the label which can be peeled from.
[0009]
[Means for Solving the Problems]
In the present invention, in a label formed by sequentially laminating a surface base material, an adhesive layer and a release paper, the adhesive layer is an alkali-soluble acrylic emulsion-type adhesive and the alkali-soluble acrylic emulsion-type adhesive In contrast, 1 to 3 parts by weight of a cross-linking agent is added, and more preferably, the cross-linking agent is mainly composed of an epoxy group-containing polyglycol polyglycidyl ether and / or ethylene glycol diglycidyl ether. It is characterized by including.
[0010]
DETAILED DESCRIPTION OF THE INVENTION
As the alkali-soluble acrylic emulsion pressure-sensitive adhesive used in the present invention, those having high solubility in hot alkaline water and easy swelling with hot water are used. As a suitable adhesive in the present invention, an acrylic ester such as butyl acrylate or 2-ethylhexyl acrylate is used as a base polymer, a carboxy-containing monomer such as methyl acrylate is used as a monomer component, and an alkali to the adhesive is used. In order to raise the hydrophilicity with respect to a solution and water, the acrylic adhesive which copolymerized hydrophilic monomers, such as an acrylic amide, is mentioned.
[0011]
On the other hand, the cross-linking agent suitably used in the present invention is preferably an epoxy group-containing polyglycol polyglycidyl ether, ethylene glycol diglycidyl ether or the like, and in particular, polyglycol polyglycidyl whose hydrophilicity is further improved by containing a hydroxyl group. Ether is preferred.
[0012]
The addition amount of the crosslinking agent in the present invention is 1 to 3 parts by weight with respect to 100 parts by weight of the pressure-sensitive adhesive. If it is less than 1 part by weight, the solubility of the pressure-sensitive adhesive in an alkaline solution increases, but it is difficult to swell, has a low crosslinking density, and has a strong adhesive force. Therefore, the peelability is poor.
[0013]
If the addition of the cross-linking agent exceeds 3.0 parts by weight, the re-peelability is good without leaving glue at the time of re-peeling, but the problem arises that the label floats and peels off during actual use. Will occur. Moreover, when it uses as a pre-label of a glass bottle, the problem that a label peels in the washing | cleaning process before filling contents arises.
[0014]
The surface substrate of the label used in the present invention needs to easily separate the peeled label by utilizing the specific gravity difference between the PET bottle and the label, and the substrate having a specific gravity of less than 1, for example, fine paper, crepe Paper such as paper and water-resistant paper, polypropylene film, polyethylene film, and foamed polyethylene film are preferably used, and a stretched film or an unstretched film can also be suitably used.
[0015]
The thickness of the surface substrate of the label in the present invention is preferably about 20 μm to 150 μm in consideration of labeling suitability and workability. If it is less than 20 μm, wrinkles and the like may occur during labeling, and if it is 150 μm or more, it has a problem of causing curved surface repulsion over time when it is attached to an adherend such as a PET bottle or a glass bottle.
[0016]
As the release sheet used for the label of the present invention, a conventionally known release paper is suitably used, as represented by glassine paper, and has a general transmittance that can be sensed by a photoelectric tube sensor of a labeling machine, The release sheet is preferably used in which a release layer is formed by applying about 0.05 to 3 g / m 2 of dry weight with water, solvent-type or solvent-free type silicone resin or fluororesin.
[0017]
As a device for applying the pressure-sensitive adhesive to the label of the present invention, a conventionally known coating device is used. For example, a roll coater, a knife coater, a bar coater, a die coater, a comma coater, and a lip coater are appropriately used.
[0018]
The coating amount of the pressure-sensitive adhesive provided on the label of the present invention is adjusted in the range of 10 to 30 g / m 2 in terms of dry weight depending on the application and the adherend. When the application amount of the pressure-sensitive adhesive is less than 10 g / m 2 , the obtained adhesive performance is insufficient, and when it exceeds 30 g / m 2 , there is a possibility that the pressure-sensitive adhesive protrudes during storage and bonding.
[0019]
In the pressure-sensitive adhesive suitably used in the present invention, auxiliary agents such as generally known tackifier resins, softeners, various pigments, or viscosity modifiers are added as necessary as long as the original purpose of the present invention is not impaired. It can be added and used. For example, as the tackifier resin, rosin ester resin, polyterpene resin, petroleum resin, or the like can be used.
[0020]
Moreover, in this invention, a primer layer can be provided between a surface base material and an adhesive layer as needed. In particular, when a support having a low anchoring property such as a film is used as the support for the surface substrate, it is preferable to provide a primer layer. Examples of the primer layer include pigments such as magnesium hydroxide, magnesium carbonate, magnesium sulfate, calcium oxide, calcium hydroxide, calcium carbonate, and satin white, and binders such as starch, polyvinyl alcohol, carboxymethyl cellulose, and styrene butadiene copolymer. The thing using is mentioned.
[0021]
【Example】
EXAMPLES Hereinafter, although an Example and a comparative example demonstrate this invention concretely, this invention is not limited by these. Unless otherwise specified, parts and% represent parts by weight and% by weight, respectively.
[0022]
As an adhesive, first, 100 parts by weight of an alkali-soluble adhesive (trade name: RP-265 / manufactured by Toa Gosei), polyglycol polyglycidyl ether (trade name: Denacol EX-521 / manufactured by Nagase Kasei Kogyo) as a crosslinking agent. 0 parts, 0.5 parts, 1.0 parts, 2.0 parts, 3.0 parts, 4.0 parts, and 5.0 parts, respectively. Further, as another cross-linking agent, 2.0 parts of ethylene glycol diglycidyl ether (trade name: Denacol EX-810 / manufactured by Nagase Kasei Kogyo Co., Ltd.) was added.
A release agent (trade name: KS-847 / manufactured by Shin-Etsu Chemical Co., Ltd.) is applied to a commercially available glassine paper so as to have a dry weight of 0.7 g / m 2 and dried to prepare a glassine-type release paper. The pressure-sensitive adhesive was applied to paper so as to have a dry weight of 20 g / m 2 and dried, and then a surface base material (trade name: YUPO / manufactured by YUPO Corporation, 80 μm) was bonded to prepare a pressure-sensitive adhesive sheet.
Further, as Comparative Example 5 , an adhesive sheet using a water-soluble adhesive was prepared.
[0023]
The adhesive sheet was affixed to a 2.7 liter PET bottle, cut to 10 mm square, and immersed in 70 ° C., 80 ° C., 90 ° C. water and 1.5% strength alkaline solution for 30 minutes. About the thing of 1 weight part-5 weight part, the natural peeling of the label by swelling of an adhesive has been confirmed above 70 degreeC.
The pressure-sensitive adhesive sheet was affixed to a 2.7-liter PET bottle, and when it was manually re-peeled after being left for 1 week at 40 ° C. and 80%, the pressure-sensitive adhesive was added for 1 to 5 parts by weight. It was possible to peel again without remaining.
[0024]
After the adhesive sheet is cut to a size of 50 mm × 100 mm and attached to a glass bottle, labels are added for those with 0 to 3 parts by weight added in steps 1 and 2 assuming bottle washing during filling of the contents. It was confirmed that there was no lifting off. Furthermore, when the re-peelability by hand was confirmed after the float-off test, it was possible to re-peel without adding any adhesive to those having 1 to 3 parts by weight added.
In Step 1, assuming bottle washing, first, the bottle is washed with tap water at 15 ° C. for 1 minute, and then immersed in 1.5% alkaline water washing solution at 66 ° C. for 2 minutes and 2% alkaline water washing solution at 63 ° C. for 2 minutes, Rinse with tap water at 35 ° C.
In step 2 assuming bottle cleaning, first wash at room temperature water for 10 seconds, then 5 minutes in 40 ° C hot water, 5 minutes in 50 ° C hot water, 5 minutes in 72 ° C hot water, 5 minutes in 70 ° C hot water. 5 minutes in hot water at 49 ° C, 5 minutes in hot water at 38 ° C, and 5 minutes in hot water at 35 ° C.
The evaluation results of Examples and Comparative Examples are shown in Table 1.
[0025]
[Table 1]
Figure 0004424878
[0026]
<Evaluation method>
[Peeling]
The natural peelability of the label was visually observed when immersed in water at 70 ° C., 80 ° C., 90 ° C. and 1.5% alkaline solution for 30 minutes.
○: There is a natural peeling of the label within 30 minutes Δ: There is a partial natural peeling of the label ×: No label peeling [swelling]
The swelling of the adhesive was visually observed when immersed in water at 70 ° C., 80 ° C., 90 ° C. and 1.5% alkaline solution for 30 minutes.
○: There swelling of adhesive ×: No swelling of the adhesive [insoluble]
The solubility of the pressure-sensitive adhesive was observed when it was immersed in water at 70 ° C., 80 ° C., 90 ° C. and 1.5% alkaline solution for 30 minutes.
○: not dissolved ×: dissolved [hand peelability]
The label was attached to a PET bottle, and the re-peelability after standing for 1 week under the conditions of 40 ° C. and 80% was confirmed by peeling off by hand.
○: Good re-peelability ×: No re-peeling / paste residue [Separability]
After the label was peeled off in the cleaning solution, the separation from the adherend was observed.
○: Good separation between label and bottle ×: Label does not separate from bottle [Water resistance]
The label was attached to a polyester rod having a diameter of 22 mm, soaked in water, and the lifting / peeling after 1 hour, 3 hours, and 24 hours was visually confirmed.
○: No lifting / peeling △: Lifting at the end ×: Peeling [0027]
【The invention's effect】
By adding 1 to 3 parts by weight of polyglycol polyglycidyl ether to an alkali-soluble acrylic emulsion adhesive, the adhesive is swollen with water at 70 ° C or higher and a 1.5% alkaline solution to adhere the cleaning solution. The label can be naturally peeled without being contaminated with the agent, and re-peeling by hand is also possible.
Further, the label was not peeled off from the glass bottle in the washing bottle process, and after use, it could be peeled off again by hand.

Claims (2)

表面基材、粘着剤層及び剥離紙を順次積層してなるラベルにおいて、前記粘着剤層がアルカリ可溶性アクリル系のエマルジョン型粘着剤と、前記アルカリ可溶性アクリル系のエマルジョン型粘着剤に対し、架橋剤が1〜3重量部添加されたことを特徴とするラベル。In a label formed by sequentially laminating a surface base material, a pressure-sensitive adhesive layer, and a release paper, the pressure-sensitive adhesive layer is an alkali-soluble acrylic emulsion-type pressure-sensitive adhesive, and the alkali-soluble acrylic emulsion-type pressure-sensitive adhesive is a crosslinking agent. 1 to 3 parts by weight of a label is added. 前記架橋剤が、エポキシ基含有のポリグリコールポリグリシジルエーテル及び/またはエチレングリコールジグリシジルエーテルを主成分として含むことを特徴とする、請求項1に記載のラベル。The label according to claim 1, wherein the cross-linking agent contains an epoxy group-containing polyglycol polyglycidyl ether and / or ethylene glycol diglycidyl ether as a main component.
JP2001292931A 2001-09-26 2001-09-26 label Expired - Lifetime JP4424878B2 (en)

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