JP5052047B2 - Polyester bottle with tack label - Google Patents

Description

  The present invention relates to a tack label adhered to the surface of a polyester bottle or the like via an adhesive layer, a polyester bottle with a tack label to which the tack label is adhered, and more specifically, when a polyester bottle is recycled. The present invention relates to a tack label capable of easily performing a label peeling operation and a polyester bottle with a tack label.

  Polyester bottles (so-called PET bottles and the like) are widely used as containers for drinking water, soft drinks, juice, tea, tea, sake, shochu, and the like. In recent years, the demand for recycling of this polyester bottle has been remarkably increased from the viewpoint of environmental protection. A label for displaying a product name or contents may be attached to a polyester bottle. When recycling a polyester bottle, this label is used in a recycling process (hot water treatment) in a recycling facility. Etc.) must be peeled off and removed. Further, in order to efficiently perform the regeneration process, it is desired to peel off the label at each home before discarding the bottle. For this reason, the label is excellent in sticking property to the bottle and sticking operability, and it is stuck to the bottle with good adhesion until the bottle contents are consumed, and does not easily peel off. The contradictory properties of being easily peelable after consumption are required. In addition, when a content is filled after a label is attached to an empty bottle, the inside of the bottle is often washed with water or a weak alkaline cleaning solution before filling the content. In this washing process, the label is not peeled off and needs to be kept in a stuck state.

  No. 6-3423 is a tack label in which an adhesive layer is provided on the back side of a label base material as a tack label for a container that can simplify the label peeling operation when the container is recycled, For a container in which the adhesive layer is partially provided so that an entry path for the label peeling liquid is formed between the label substrate and the container surface when the label substrate is attached to the container surface. A tack label is disclosed. Further, in JP-A-8-30201, as a container label that can be easily peeled off even by showering at a low temperature for a short time, an adhesive portion made of an adhesive layer is partially provided on the back side of the label substrate. In addition, a container label is disclosed in which a label base material is provided with a plurality of label peeling liquid intrusion holes that communicate with the adhesive portion. Furthermore, in Japanese Utility Model Publication No. 7-31261, the pressure-sensitive adhesive layer formed on the entire back surface of the substrate is masked in a mesh form with a non-sticky masking agent, and the exposed state of the pressure-sensitive adhesive layer is infinitely fine. A pressure-sensitive adhesive label having a uniform halftone dot shape and having a part of the pressure-sensitive adhesive layer on one edge side of the label completely covered with the masking agent is disclosed.

  However, when these labels are applied to the polyester bottle, in the cleaning step before filling the contents, the label is affixed by the cleaning liquid entering the label peeling liquid intrusion path or the mesh-like masking portion. There is a risk that the force will be reduced and peel off. Further, in the distribution process, there arises a problem that foreign matters such as dust are likely to be mixed into the ingress path of the label peeling liquid and the mesh-like masking portion.

No. 6-3423 JP-A-8-30201 No. 7-31261

Therefore, the object of the present invention is excellent in sticking to a bottle and sticking operability, and after label sticking, it is difficult to peel off from the bottle until the bottle contents are consumed, and after the bottle contents are consumed. It is an object of the present invention to provide a tack label that can be easily peeled and removed, and a polyester bottle with the tack label.
Another object of the present invention is to provide a tack label that is difficult to be peeled off by water at room temperature after sticking and can be easily peeled off and removed by hot water, and a polyester bottle with the tack label.

Still another object of the present invention is to provide a tack label and a polyester bottle with a tack label that can be peeled and removed in a regeneration treatment step in a regeneration treatment facility and can be easily removed by hand.
Another object of the present invention is to provide a tack label and a polyester bottle with a tack label, in which foreign matter is unlikely to enter between the label and the bottle.
Still another object of the present invention is to provide a tack label and a polyester bottle with a tack label that can easily separate the label and the bottle after the label peeling operation.

  As a result of intensive studies to achieve the above object, the present inventors have found that when a specific part of the surface of the adhesive layer made of a specific adhesive provided on the label base material is coated with a non-adhesive masking agent, After the label is attached to the bottle, the label is difficult to peel off until the contents of the bottle are consumed, and the label is used in a recycling treatment facility such as hot water treatment to recycle (collect, recycle, or reuse) the bottle. It can be peeled and removed in the regeneration process, and can be easily peeled and removed by hand, and if an adhesive layer formed with a specific adhesive is provided on the label substrate, it is immersed in water at room temperature after label sticking. However, it was not easily peeled off, but when immersed in hot water, it was found that it could be easily peeled off and removed, and the present invention was completed.

That is, the present invention is a polyester bottle with a tack label in which the tack label is adhered to the body surface of a polyester biaxially stretched blow bottle, and the tack label is provided with a printing layer on at least one surface. An adhesive layer made of a hot water soluble adhesive is provided on the back side of the label base material, and the label base material is an internal paper forming synthetic paper or a stretched polypropylene film made of a polyolefin resin having a specific gravity of less than 1. In addition, the label base material is not provided with a plurality of label peeling liquid intrusion holes leading to an adhesive portion made of an adhesive layer, and the hot water soluble adhesive is a pressure sensitive adhesive. And an acrylic water-soluble pressure-sensitive adhesive. As a base polymer of the acrylic water-soluble pressure-sensitive adhesive, an acrylic acid alkyl ester is used as a main monomer component, A copolymer mainly composed of a comonomer component selected from methyl sulfonate, methyl methacrylate, and vinyl acetate and a carboxyl group-containing monomer or a hydroxyl group-containing monomer is used, and the adhesive layer includes the tack label. When a polyester bottle with a tuck label attached to a polyester biaxially stretched blow bottle through the adhesive layer is immersed in water at 40 ° C, it does not peel for more than 30 minutes and is immersed in hot water at 92 ° C In such a case, hot water dissolves the adhesive and lowers the adhesive force, and within 30 minutes due to the displacement effect between the tack label and the bottle surface caused by the heat shrinkage force when the blow bottle undergoes heat shrinkage deformation. A polyester bottle with a tuck label is provided, which is formed of an adhesive that can be peeled off.

A non-adhesive masking layer may be provided on at least one edge of the surface of the adhesive layer of the tack label .

  In this specification, a printing layer is provided on the front surface side of the label base material, and an adhesive layer made of a hot water-soluble adhesive on the back surface side and a non-tacky masking layer that partially covers the adhesive layer; The label substrate is formed of a material having a specific gravity of less than 1, and the masking layer is separated from the central portion of the surface of the adhesive layer and the central portion. A tack label provided on the edge so that the adhesive layer is exposed in an annular shape may be abbreviated as “tack label A” in some cases.

  Moreover, it is a tack label in which an adhesive layer made of a hot water soluble adhesive is provided on the back side of a label base material provided with a printing layer on at least one surface, and the label base material has a specific gravity of less than 1 In addition to being formed of a material, the adhesive layer does not peel for 30 minutes or more when the adhesive obtained by adhering the tack label to the adherend through the adhesive layer is immersed in water at 40 ° C. In addition, when immersed in hot water of 75 ° C. or higher, a tack label formed of an adhesive that can be peeled off within 30 minutes may be abbreviated as “tack label B”.

  According to the tack label A and the polyester bottle with the tack label according to the present invention, the non-tacky masking layer is circular at a specific portion of the surface of the adhesive layer made of the hot water soluble adhesive. Since the specific gravity of the label base material is less than 1, it is excellent in label sticking property and sticking operability to the bottle, and the contents of the bottle are consumed after sticking the label. The label is difficult to peel off from the bottle until the bottle is consumed, and the label can be easily peeled off after the bottle contents are consumed. Further, not only can the label be peeled and removed in the recycling process in the recycling processing facility, but it can also be easily peeled off by hand, and foreign matter is hardly mixed between the label and the bottle.

  Moreover, according to the tack label B and the polyester bottle with the tack label of the present invention, the pressure-sensitive adhesive layer is formed of a specific adhesive, and the specific gravity of the label base material is less than 1, so that the label is stuck. After that, it is difficult to peel off with water at room temperature, and the inside of the bottle can be washed with water. After fulfilling a predetermined role, it can be easily peeled off and removed by a hot water treatment process in a regeneration treatment facility.

  Hereinafter, the present invention will be described in detail with reference to the drawings as necessary. 1 is a front view showing an example of a tack label of the present invention, FIG. 2 is a rear view thereof, and FIG. 3 is a sectional view taken along line III-III. FIG. 4 is a perspective view showing an example of a polyester bottle with a tack label according to the present invention.

  In this tack label 1, a printing layer 3 for displaying a product name, contents, and the like and a coating layer 4 covering the printing layer 3 are provided in this order on the surface side of a substantially rectangular label base material 2. On the back side of the label substrate 2, an adhesive layer 5 for adhering to the surface of the adherend and a non-adhesive masking layer 6 that partially covers the adhesive layer 5 are provided in sequence. The label substrate 2 is formed of a material having a specific gravity of less than 1. The adhesive layer 5 is made of a hot water-soluble adhesive and is formed over the entire back surface of the label substrate 2. Further, the non-adhesive masking layer 6 is formed on the surface of the adhesive layer 5 at the central part 6a excluding the peripheral part and one end edge part 6b (for example, a corner part) separated from the central part 6a. The agent layer 5 is exposed in a ring shape (frame shape) over the entire circumference of the tack label 1.

  When this tack label 1 is stuck on the surface of a polyester blow (molded) bottle 7 as shown in FIG. 4, the adhesive layer 5 is exposed in an annular shape over the entire circumference of the label. The label can be applied smoothly and easily by the application machine, and can be applied beautifully and reliably without causing inadvertent peeling. In addition, even after the tack label 1 is attached to the bottle 7 and before the contents are filled, the inside of the bottle 7 can be washed with room temperature (for example, 15 ° C.) water or weak alkaline cleaning liquid, and the label peeling liquid can enter. A cleaning liquid such as water does not easily enter the entire label unlike a conventional label in which a path, a mesh-like masking portion or the like is formed, and a decrease in the adhesive strength of the label in the above process can be prevented. Furthermore, it is possible to prevent foreign matters such as dust from entering between the bottle 7 and the tack label 1 in the distribution process after label sticking.

  On the other hand, in the tack label 1, one end edge 6 b (that is, the end edge of the tack label 1) of the surface of the pressure-sensitive adhesive layer 5 is covered with the non-adhesive masking layer 6. When affixed to 7, a non-adhesive part (knob part) for peeling is secured between the tack label 1 and the surface of the bottle 7. Moreover, since the center part 6a is also coat | covered with the non-adhesive masking layer among the surfaces of the adhesive bond layer 5, the adhesion area with the bottle 7 is very small. For example, the exposed area of the adhesive layer 5 can be reduced to, for example, 10 to 60% (preferably about 15 to 40%) with respect to the total surface area of the adhesive layer 5 when no masking layer is provided. Therefore, when the tack label 1 is peeled after the contents of the bottle 7 are consumed, it is easily peeled off by inserting a nail or the like into the non-adhesive portion and pinching the edge portion of the tack label 1. Can do. For example, it can be peeled off with a force of about 1/5, for example, as compared with a tack label in which the adhesive layer is entirely exposed. Even if the exposed area of the adhesive layer 5 is small, as described above, the adhesive layer 5 is exposed in an annular shape throughout the entire circumference of the label, so that inadvertent peeling does not occur.

  Moreover, since the adhesive bond layer 5 is comprised with the hot water soluble adhesive, if the bottle with a tack label which stuck the tack label 1 is immersed in hot water, adhesive force will fall large and will peel. At this time, since the adhesion area with the bottle 7 is extremely small as described above, the tack label 1 can be easily peeled off. Moreover, since the adhesive dissolves in hot water, the peeled tack label 1 is difficult to reattach to the bottle 7. Furthermore, since the bottle 7 is a blow-molded product made of polyester, it is deformed by heat shrinkage when immersed in hot water. The heat shrinkage force at this time causes a positional shift action between the tack label 1 and the bottle surface, and contributes to promotion of peeling of the tack label 1. For this reason, in the polyester bottle regeneration treatment step, for example, hot water treatment is performed on the polyester biaxial stretch blow (molded) bottle to which the tack label 1 is attached, so that the hot water dissolves the adhesive, and the adhesive strength is increased. In addition, the bottle is contracted and deformed in two vertical and horizontal axes, and the tack label 1 is easily separated from the bottle surface due to displacement. Further, since the adhesive is dissolved in hot water, the tack label 1 does not reattach to the bottle surface.

  Further, since the specific gravity of polyester is 1 or more (about 1.3 to 1.4), the bottle 7 (or a pulverized product thereof) sinks in water, whereas the label base 2 is formed of a material having a specific gravity of less than 1. It has the property of floating in water. For this reason, in the recycling process of the polyester bottle, for example, after the used bottle is washed, crushed, stirred and washed, the peeled tack label 1 (crushed product) and the bottle 7 (crushed product) are floated and submerged in water. Separation is very easy using (specific gravity difference).

  Thus, since the tack label 1 stuck to the bottle 7 can be efficiently peeled and removed in a regeneration process such as hot water treatment in a regeneration treatment facility and can be easily removed by hand, the polyester bottle can be recycled. It becomes extremely easy.

  Further, in the above example, since the coating layer 4 is formed on the surface of the printing layer 3, the printing layer 3 is protected, and the surface of the label is glossy by appropriately selecting a resin or the like constituting the coating layer 4. Can be granted.

  The specific gravity of the material constituting the label substrate 2 may be less than 1, and is usually about 0.3 to 0.99, preferably about 0.75 to 0.97. The label substrate 2 may be any of water-resistant synthetic paper, plastic film, laminates thereof, and the like, printability, affinity with an adhesive, separation from a bottle after label peeling, etc. Can be selected as appropriate. Synthetic paper includes internal paper synthetic paper [trade name: YUPO (Oji Oil Chemical Co., Ltd.)], surface coating synthetic paper [trade name: Peach Coat (Nisshinbo Co., Ltd.) Etc.], spunbond synthetic paper [trade name: TYVEK (manufactured by DuPont), etc.] and the like. Examples of the plastic film include polyolefin films such as polypropylene film and polyethylene film, and foamed plastic films such as foamed polystyrene film, foamed polyester film, and foamed polyolefin film. The plastic film may be a stretched film or an unstretched film. Among these, as a label base material, because it is excellent in printability, rigidity, cost, labeling suitability and the like, an internal paper-made synthetic paper or a stretched polypropylene film of a polyolefin-based resin such as “YUPO” is preferable.

  Although the thickness of the label base material 2 can be selected within a range that does not impair the handleability, workability, and the like when the tack label 1 is used, it is generally about 20 to 200 μm.

  In order to improve the printability, the surface of the label substrate 2 on the printing layer 3 side may be subjected to conventional surface treatment such as corona discharge treatment, plasma treatment, flame treatment, and acid treatment.

  The printing layer 3 is a layer that displays characters such as product names and handling precautions, images, and the like, and can be formed by a conventional printing method such as screen printing, letterpress printing, or gravure printing.

  The material constituting the coating layer 4 is not particularly limited as long as it is a material that can protect the printing layer 3, and examples thereof include polyolefin resins such as polyethylene and polypropylene; polystyrene, styrene copolymers containing styrene as a comonomer, and the like. Polystyrene-based resins; polyvinyl chloride; polyvinylidene chloride; resins such as polyester can be used, and the coating layer 4 can be formed by coating or film lamination of these resins. Of the above resins, a polyolefin-based resin is often used. For example, the coating layer 4 can be formed by laminating a stretched polypropylene film on the surface of the printing layer 3. The specific gravity of the material constituting the coating layer 4 is less than 1 (for example, about 0.85 to 0.99, particularly about 0.87 to 0.97) for the same reason as in the case of the label substrate 2. Is preferred.

The thickness of the coating layer 4 can be appropriately selected within a range that does not impair the handleability when the tack label 1 is formed, and is, for example, about 10 to 50 μm.
The coating layer 4 can be formed by, for example, conventional laminating or coating such as adhesive lamination, dry lamination, extrusion lamination, or the like. In the present invention, the coating layer 4 is not necessarily provided.

  The hot water-soluble adhesive constituting the adhesive layer 5 is not particularly limited as long as it is an adhesive that dissolves in hot water (for example, hot water of about 60 to 100 ° C.), but water at room temperature (for example, 15 ° C.). It is preferable that it is difficult to dissolve. A particularly preferable adhesive layer is 30 minutes or more (preferably 2 minutes) when an adhesive obtained by adhering a tack label to an adherend (for example, a polyester bottle) through the adhesive layer is immersed in water at 40 ° C. It is formed of an adhesive that can be peeled off within 30 minutes when it is immersed in hot water of 75 ° C. or higher (for example, about 75 to 95 ° C.). When a tack label having such an adhesive layer is used, the label cannot be easily peeled off even if it is immersed in water after being attached to an adherend such as a polyester bottle. However, the inside of the bottle and the like can be washed with normal water such as tap water for filling the contents, etc., and can be easily peeled off and removed with hot water after reaching a predetermined purpose.

As the hot water soluble adhesive, for example, a pressure sensitive adhesive such as an acrylic pressure-sensitive adhesive can be used. Preferred hot water-soluble adhesives are adhesives that are highly soluble in hot water and difficult to re-adhere, for example, base polymers with alkyl acrylate esters such as ethyl acrylate, butyl acrylate, 2-ethylhexyl acrylate (for example, , acrylic acid C _2-10 alkyl esters) or, butyl methacrylate, alkyl esters such as 2-ethylhexyl methacrylate (e.g., methacrylic acid C _4-12 alkyl ester) as a main monomer component, methyl acrylate, methacrylic Copolymers mainly composed of comonomer components such as methyl acid and vinyl acetate, and carboxyl group-containing monomers such as acrylic acid, methacrylic acid, and maleic acid, and hydroxyl group-containing monomers such as 2-hydroxyethyl (meth) acrylate To improve hydrophilicity And acrylic water-soluble pressure-sensitive adhesives such as those added with nonionic surfactants such as polyoxyethylene nonylphenyl ether and polyoxyethylene octylphenyl ether.
The thickness of the adhesive layer 5 is, for example, about 3 to 100 μm, preferably about 10 to 40 μm.

  The adhesive layer 5 is formed by applying an adhesive composition (emulsion, solution, etc.) containing a hot water-soluble adhesive onto the label substrate 2 using a conventional coating means such as a roll coater, bar coater, knife coater, spray or the like. It can be formed by processing.

  The masking agent constituting the non-tacky masking layer 6 may be any masking agent as long as it can form a non-tacky coating layer on the adhesive layer 5. For example, varnish, paint, printing ink, acrylic resin (polyethylene Methyl methacrylate, etc.), vinyl acetate, vinyl chloride, polystyrene, vinyl chloride-vinyl acetate copolymer, ethylene-vinyl acetate copolymer, silicone resin, synthetic resin such as polyvinyl alcohol, and the like can be used. In particular, it is preferable to form the non-adhesive masking layer 6 by applying ultraviolet curable printing ink by a printing method.

  The thickness of the non-adhesive masking layer 6 can be appropriately selected within a range that does not impair the operability when sticking the tack label 1 to the bottle 7, the sticking stability of the tack label 1, etc., but usually 2 to 30 μm, Preferably it is about 3-15 micrometers.

  The non-adhesive masking layer 6 is formed in the center of the surface of the adhesive layer 5 with a peripheral edge remaining in an annular shape, and at one edge of the surface of the adhesive layer 5 when the bottle surface is peeled off. As long as it is formed so as to be able to secure a peeling gap between them, the planar shape may be any of a square shape, a triangular shape, a circular shape, an elliptical shape, and the like.

Moreover, the total surface area of the non-adhesive masking layer 6 is 40 to 90% with respect to the total surface area of the adhesive bond layer 5 (or label base material 2), for example, Preferably it is about 60 to 85%. If the surface area of the non-adhesive masking layer 6 is too small, the label peelability at the time of peeling from the bottle tends to decrease. There is a risk of inadvertent peeling.
The non-adhesive masking layer 6 can be formed by a conventional method (for example, the paste surface printing method described in the specification of Japanese Patent No. 1504306).

  In the tack label B of the present invention, a non-adhesive masking layer does not necessarily have to be provided. However, in order to make it easier to pinch when peeling by hand, at least one edge of the surface of the adhesive layer is non-adhesive. It is preferable to provide a masking layer. In particular, as described above, the non-adhesive masking layer is annularly formed on the center portion of the surface of the adhesive layer and at one end edge separated from the center portion. It is desirable to be provided so as to be exposed.

A release sheet (separator) (not shown) is usually attached to the surface of the tack label 1 on the adhesive layer 5 side. When the tack label 1 is attached to the bottle 7, The sheet is peeled off for use.
In addition, in this invention, the shape and size of the label base material 2 are not specifically limited, It can select suitably according to the shape, size, etc. of the polyester blow bottles which are adherends.

  In the polyester bottle with a tack label of the present invention, a conventional polyester resin such as polyethylene terephthalate resin is used as a material constituting the blow molded bottle 7 body. The bottle 7 can be manufactured by a conventional blow molding method (for example, biaxial stretch blow molding). The tack label 1 can be attached to the polyester bottle 7 using a conventional label sticking machine.

  EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, this invention is not limited at all by an Example.

Example One side of a synthetic paper (trade name: YUPO (manufactured by Oji Oil Chemical Co., Ltd.), 170 mm × 140 mm, thickness 80 μm) of a specific gravity 0.84 made of an olefin resin as the label substrate 2 Furthermore, as a hot water soluble adhesive, an acrylic emulsion-type pressure-sensitive adhesive made of an alkyl acrylate copolymer mainly composed of butyl acrylate and 2-ethylhexyl acrylate was applied to a thickness of 25 μm. An adhesive layer 5 was formed, and a separator was laminated on the adhesive layer 5 to produce a label base paper. A printed layer 3 is formed on the surface of the label base 2 of the label base paper, and a stretched polypropylene film (specific gravity 0.92, thickness 20 μm) is formed on the upper surface of the printed layer 3 through an adhesive layer (not shown) as a coating layer 4. After laminating and peeling the separator from the adhesive layer 5, UV curing is applied to the central portion 6a and the one end edge portion 6b separated from the central portion of the surface of the adhesive layer (the back side as a label). A non-adhesive masking agent made of mold printing ink was applied with a thickness of 5 μm so that the adhesive layer 5 was exposed in an annular shape with a width of about 10 mm around the label, and the coated surface was irradiated with ultraviolet rays to cure the ink. Thereafter, separators were again laminated to form a tack label 1. The exposure rate of the adhesive layer 5 was 22%.

When this tack label 1 was peeled off from the separator and affixed to a round polyester biaxial stretch blow molded bottle having a capacity of 4 liters using an existing labeler, it could be adhered beautifully and reliably without wrinkles or floats. The bottle was stored for 8 days at room temperature before testing. The results are shown below.
(1) When the polyester bottle with a tack label was immersed in hot water of 92 ° C. for 30 minutes, the tack label was completely peeled off. Further, the peeled tack label floated on water and could be easily separated from the bottle.
(2) The tack label of the polyester bottle with the tack label was easily peeled off when the edge 6b was pinched with a finger and peeled off, because only the periphery was adhered. Further, the peel strength of the bonded portion (according to “180 degree peeling method” defined in JIS Z 0237) was measured and found to be 9.5 N / 15 mm.
(3) The above-mentioned polyester bottle with a tack label was immersed in water at 40 ° C. and allowed to stand for 30 minutes, but there was no change in appearance and the tack label was not peeled off.

It is a front view which shows an example of the tack label of this invention. It is a rear view of the tack label of FIG. It is the III-III sectional view taken on the line of FIG. It is a perspective view which shows an example of the polyester bottles with a tack label of this invention.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Tack label 2 Label base material 3 Printing layer 4 Coating layer 5 Adhesive layer 6 Non-adhesive masking layer 7 Polyester blow bottle

Claims (2)

The tack label is a polyester bottle with a tack label, which is stuck to the body surface of a polyester biaxially stretched blow bottle, and the tack label is a label base material provided with a printing layer on at least one surface. An adhesive layer made of a hot water soluble adhesive is provided on the back side, and the label base material is formed of an internal paper forming synthetic paper or a stretched polypropylene film made of a polyolefin resin having a specific gravity of less than 1, The label base material is not provided with a plurality of label peeling liquid intrusion holes that lead to an adhesive portion made of an adhesive layer. The hot water-soluble adhesive is a pressure-sensitive adhesive and is an acrylic water-soluble adhesive. As the base polymer of the acrylic water-soluble adhesive, alkyl acrylate ester is the main monomer component, methyl acrylate, A copolymer mainly composed of a comonomer component selected from methyl sulfonate and vinyl acetate, and a carboxyl group-containing monomer or a hydroxyl group-containing monomer is used, and the adhesive layer is made of polyester 2 When a polyester bottle with a tuck label attached to an axial stretch blow bottle through the adhesive layer is immersed in water at 40 ° C, it does not peel for 30 minutes or more and is immersed in hot water at 92 ° C. The hot water dissolves the adhesive and lowers the adhesive force, and can be peeled off within 30 minutes due to the displacement effect between the tack label and the bottle surface generated by the heat shrinkage force when the blow bottle undergoes heat shrinkage deformation. A polyester bottle with a tack label, which is formed of an adhesive.   The polyester bottle with a tack label according to claim 1, wherein a non-adhesive masking layer is provided on at least one edge of the surface of the adhesive layer of the tack label.

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