JP4398860B2 - Uv処理膜 - Google Patents
Uv処理膜 Download PDFInfo
- Publication number
- JP4398860B2 JP4398860B2 JP2004521579A JP2004521579A JP4398860B2 JP 4398860 B2 JP4398860 B2 JP 4398860B2 JP 2004521579 A JP2004521579 A JP 2004521579A JP 2004521579 A JP2004521579 A JP 2004521579A JP 4398860 B2 JP4398860 B2 JP 4398860B2
- Authority
- JP
- Japan
- Prior art keywords
- membrane
- film
- halopolymer
- microporous
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000012528 membrane Substances 0.000 claims description 286
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 105
- 230000005855 radiation Effects 0.000 claims description 62
- 239000007788 liquid Substances 0.000 claims description 53
- 239000012530 fluid Substances 0.000 claims description 50
- 239000011148 porous material Substances 0.000 claims description 37
- 238000009736 wetting Methods 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 29
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 28
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 28
- 239000000284 extract Substances 0.000 claims description 27
- 230000001427 coherent effect Effects 0.000 claims description 24
- 238000004519 manufacturing process Methods 0.000 claims description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- 238000011282 treatment Methods 0.000 claims description 13
- 238000012545 processing Methods 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 229920002313 fluoropolymer Polymers 0.000 claims description 10
- 239000004811 fluoropolymer Substances 0.000 claims description 10
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 7
- 239000011737 fluorine Substances 0.000 claims description 7
- 229910052731 fluorine Inorganic materials 0.000 claims description 7
- -1 polytetrafluoroethylene Polymers 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 125000001475 halogen functional group Chemical group 0.000 claims 3
- 239000011344 liquid material Substances 0.000 claims 1
- 238000003672 processing method Methods 0.000 claims 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 106
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 52
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 35
- 235000010265 sodium sulphite Nutrition 0.000 description 26
- 239000000243 solution Substances 0.000 description 20
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 238000001914 filtration Methods 0.000 description 11
- 239000007789 gas Substances 0.000 description 11
- 238000007654 immersion Methods 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 8
- 229910052753 mercury Inorganic materials 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 230000035699 permeability Effects 0.000 description 8
- 239000011521 glass Substances 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 230000005457 Black-body radiation Effects 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 206010073306 Exposure to radiation Diseases 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000005067 remediation Methods 0.000 description 6
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 5
- 230000002209 hydrophobic effect Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000011144 upstream manufacturing Methods 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 230000004927 fusion Effects 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 239000004809 Teflon Substances 0.000 description 3
- 229920006362 Teflon® Polymers 0.000 description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000006911 nucleation Effects 0.000 description 3
- 238000010899 nucleation Methods 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- 235000011152 sodium sulphate Nutrition 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 239000011874 heated mixture Substances 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000012982 microporous membrane Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 2
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 2
- 229920002620 polyvinyl fluoride Polymers 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000010561 standard procedure Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- OBMBUODDCOAJQP-UHFFFAOYSA-N 2-chloro-4-phenylquinoline Chemical compound C=12C=CC=CC2=NC(Cl)=CC=1C1=CC=CC=C1 OBMBUODDCOAJQP-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000004630 atomic force microscopy Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- UFHBHNRBFWFTSP-UHFFFAOYSA-L disodium hydrogen peroxide sulfite Chemical compound [Na+].[Na+].OO.[O-]S([O-])=O UFHBHNRBFWFTSP-UHFFFAOYSA-L 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000005660 hydrophilic surface Effects 0.000 description 1
- 239000004434 industrial solvent Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000005374 membrane filtration Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000012465 retentate Substances 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- JZHIWRJMRVFHOR-UHFFFAOYSA-N tert-butylazanium;sulfate Chemical compound CC(C)(C)N.CC(C)(C)N.OS(O)(=O)=O JZHIWRJMRVFHOR-UHFFFAOYSA-N 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 238000004627 transmission electron microscopy Methods 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/009—After-treatment of organic or inorganic membranes with wave-energy, particle-radiation or plasma
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0088—Physical treatment with compounds, e.g. swelling, coating or impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0097—Storing or preservation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/30—Polyalkenyl halides
- B01D71/32—Polyalkenyl halides containing fluorine atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/30—Polyalkenyl halides
- B01D71/32—Polyalkenyl halides containing fluorine atoms
- B01D71/36—Polytetrafluoroethene
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US39486502P | 2002-07-11 | 2002-07-11 | |
| PCT/US2003/021438 WO2004007060A2 (en) | 2002-07-11 | 2003-07-09 | Uv treated membranes |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005532164A JP2005532164A (ja) | 2005-10-27 |
| JP2005532164A5 JP2005532164A5 (enExample) | 2006-08-17 |
| JP4398860B2 true JP4398860B2 (ja) | 2010-01-13 |
Family
ID=30115782
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004521579A Expired - Lifetime JP4398860B2 (ja) | 2002-07-11 | 2003-07-09 | Uv処理膜 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US7611629B2 (enExample) |
| EP (1) | EP1531925B1 (enExample) |
| JP (1) | JP4398860B2 (enExample) |
| KR (1) | KR100998521B1 (enExample) |
| AU (1) | AU2003253840A1 (enExample) |
| WO (1) | WO2004007060A2 (enExample) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004007060A2 (en) | 2002-07-11 | 2004-01-22 | Pall Corporation | Uv treated membranes |
| JP4761041B2 (ja) * | 2005-02-23 | 2011-08-31 | ソニー株式会社 | シリコン膜の形成方法 |
| US7393388B2 (en) | 2005-05-13 | 2008-07-01 | United Technologies Corporation | Spiral wound fuel stabilization unit for fuel de-oxygenation |
| US7435283B2 (en) | 2005-05-18 | 2008-10-14 | United Technologies Corporation | Modular fuel stabilization system |
| US7465336B2 (en) | 2005-06-09 | 2008-12-16 | United Technologies Corporation | Fuel deoxygenation system with non-planar plate members |
| US7377112B2 (en) | 2005-06-22 | 2008-05-27 | United Technologies Corporation | Fuel deoxygenation for improved combustion performance |
| US7615104B2 (en) | 2005-11-03 | 2009-11-10 | United Technologies Corporation | Fuel deoxygenation system with multi-layer oxygen permeable membrane |
| US7569099B2 (en) | 2006-01-18 | 2009-08-04 | United Technologies Corporation | Fuel deoxygenation system with non-metallic fuel plate assembly |
| US7824470B2 (en) | 2006-01-18 | 2010-11-02 | United Technologies Corporation | Method for enhancing mass transport in fuel deoxygenation systems |
| US7582137B2 (en) | 2006-01-18 | 2009-09-01 | United Technologies Corporation | Fuel deoxygenator with non-planar fuel channel and oxygen permeable membrane |
| EP2001666B1 (en) * | 2006-04-03 | 2017-08-23 | Entegris, Inc. | Atmospheric pressure microwave plasma treated porous membranes |
| WO2009110342A1 (ja) * | 2008-03-04 | 2009-09-11 | 東京エレクトロン株式会社 | 多孔質部材 |
| US9592476B2 (en) | 2014-05-30 | 2017-03-14 | Pall Corporation | Membrane comprising self-assembled block copolymer and process for producing the same by hybrid casting (IIb) |
| US9616395B2 (en) | 2014-05-30 | 2017-04-11 | Pall Corportaion | Membrane comprising self-assembled block copolymer and process for producing the same by spray coating (Ic) |
| US9593217B2 (en) | 2014-05-30 | 2017-03-14 | Pall Corporation | Self-assembled structure and membrane comprising block copolymer and process for producing the same by spin coating (Va) |
| US9765171B2 (en) | 2014-05-30 | 2017-09-19 | Pall Corporation | Self-assembling polymers—V |
| US9592477B2 (en) | 2014-05-30 | 2017-03-14 | Pall Corporation | Membrane comprising self-assembled block copolymer and process for producing the same by hybrid casting (Ib) |
| US9162189B1 (en) | 2014-05-30 | 2015-10-20 | Pall Corporation | Membrane comprising self-assembled block copolymer and process for producing the same by spin coating (Ia) |
| US9169361B1 (en) | 2014-05-30 | 2015-10-27 | Pall Corporation | Self-assembling polymers—VI |
| US9163122B1 (en) | 2014-05-30 | 2015-10-20 | Pall Corporation | Self-assembling polymers—II |
| US9469733B2 (en) | 2014-05-30 | 2016-10-18 | Pall Corporation | Self-assembled structure and membrane comprising block copolymer and process for producing the same by spin coating (IVa) |
| US9193835B1 (en) | 2014-05-30 | 2015-11-24 | Pall Corporation | Self-assembling polymers—IV |
| US9441078B2 (en) | 2014-05-30 | 2016-09-13 | Pall Corporation | Self-assembling polymers—I |
| US9604181B2 (en) | 2014-05-30 | 2017-03-28 | Pall Corporation | Membrane comprising self-assembled block copolymer and process for producing the same by spray coating (IIc) |
| US9593218B2 (en) | 2014-05-30 | 2017-03-14 | Pall Corporation | Self-assembled structure and membrane comprising block copolymer and process for producing the same by spin coating (IIIa) |
| US9598543B2 (en) | 2014-05-30 | 2017-03-21 | Pall Corporation | Self-assembled structure and membrane comprising block copolymer and process for producing the same by spin coating (VIa) |
| US9593219B2 (en) | 2014-05-30 | 2017-03-14 | Pall Corporation | Membrane comprising self-assembled block copolymer and process for producing the same by spin coating (IIa) |
| US9328206B2 (en) | 2014-05-30 | 2016-05-03 | Pall Corporation | Self-assembling polymers—III |
| US9303133B2 (en) | 2014-06-30 | 2016-04-05 | Pall Corporation | Hydrophilic membranes and method of preparation thereof (IV) |
| US9962662B2 (en) | 2014-06-30 | 2018-05-08 | Pall Corporation | Fluorinated polymer and use thereof in the preparation of hydrophilic membranes (vi) |
| US9260569B2 (en) | 2014-06-30 | 2016-02-16 | Pall Corporation | Hydrophilic block copolymers and method of preparation thereof (III) |
| US9718924B2 (en) | 2014-06-30 | 2017-08-01 | Pall Corporation | Hydrophilic block copolymers and membranes prepared therefrom (II) |
| US9254466B2 (en) | 2014-06-30 | 2016-02-09 | Pall Corporation | Crosslinked cellulosic membranes |
| US9309367B2 (en) | 2014-06-30 | 2016-04-12 | Pall Corporation | Membranes comprising cellulosic material and hydrophilic block copolymer (V) |
| US9394407B2 (en) | 2014-06-30 | 2016-07-19 | Pall Corporation | Hydrophilic block copolymers and membranes prepared therefrom (I) |
| US20170028358A1 (en) * | 2015-07-31 | 2017-02-02 | Pall Corporation | Hydrophilizing ptfe membranes |
| US20170028359A1 (en) * | 2015-07-31 | 2017-02-02 | Pall Corporation | Coated ptfe membrane |
| WO2017210293A1 (en) | 2016-06-01 | 2017-12-07 | Entegris, Inc. | Fluid circuit with integrated electrostatic discharge mitigation |
| SG11202010624WA (en) | 2018-05-07 | 2020-11-27 | Entegris Inc | Fluid circuit with integrated electrostatic discharge mitigation |
| CN113164883B (zh) * | 2018-11-28 | 2023-05-02 | 3M创新有限公司 | 膜的紫外线处理和所得膜 |
| EP3973216A4 (en) | 2019-05-23 | 2023-01-04 | Entegris, Inc. | ELECTROSTATIC DISCHARGE MITIGATION TUBE |
| JP7286585B2 (ja) * | 2020-04-22 | 2023-06-05 | 三菱重工機械システム株式会社 | 殺菌システムおよび殺菌方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3935096A (en) * | 1974-01-02 | 1976-01-27 | Hooker Chemicals & Plastics Corporation | Production of aqueous metal hydroxide solutions of low metal halide concentration |
| US3978341A (en) | 1974-04-10 | 1976-08-31 | E. I. Du Pont De Nemours And Company | Short wavelength ultraviolet irradiation treatment of polymeric surfaces |
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-
2003
- 2003-07-09 WO PCT/US2003/021438 patent/WO2004007060A2/en not_active Ceased
- 2003-07-09 JP JP2004521579A patent/JP4398860B2/ja not_active Expired - Lifetime
- 2003-07-09 KR KR1020057000562A patent/KR100998521B1/ko not_active Expired - Lifetime
- 2003-07-09 US US10/520,080 patent/US7611629B2/en not_active Expired - Lifetime
- 2003-07-09 AU AU2003253840A patent/AU2003253840A1/en not_active Abandoned
- 2003-07-09 EP EP03764401.0A patent/EP1531925B1/en not_active Expired - Lifetime
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2009
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2005532164A (ja) | 2005-10-27 |
| WO2004007060A2 (en) | 2004-01-22 |
| US20100018925A1 (en) | 2010-01-28 |
| US7833419B2 (en) | 2010-11-16 |
| AU2003253840A1 (en) | 2004-02-02 |
| KR20050025349A (ko) | 2005-03-14 |
| KR100998521B1 (ko) | 2010-12-07 |
| WO2004007060A3 (en) | 2004-11-04 |
| US7611629B2 (en) | 2009-11-03 |
| EP1531925A2 (en) | 2005-05-25 |
| US20050247629A1 (en) | 2005-11-10 |
| EP1531925B1 (en) | 2013-10-23 |
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