JP4396334B2 - Foamable oil-in-water emulsion - Google Patents

Foamable oil-in-water emulsion Download PDF

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JP4396334B2
JP4396334B2 JP2004068902A JP2004068902A JP4396334B2 JP 4396334 B2 JP4396334 B2 JP 4396334B2 JP 2004068902 A JP2004068902 A JP 2004068902A JP 2004068902 A JP2004068902 A JP 2004068902A JP 4396334 B2 JP4396334 B2 JP 4396334B2
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oil
water emulsion
rutin
tocopherol
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裕之 市山
博志 日高
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Fuji Oil Co Ltd
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本発明は、風味劣化防止剤を含有させた起泡性水中油型乳化物(ホイップクリーム)に関する。更に詳しくは風味劣化防止剤としてトコフェロール及びルチンを水中油型乳化物に含有させた、蛍光灯等の光照射による異味、異臭の品質の劣化が少ない起泡性水中油型乳化物に関する。   The present invention relates to a foamable oil-in-water emulsion (whipped cream) containing a flavor deterioration preventing agent. More particularly, the present invention relates to a foamable oil-in-water emulsion in which tocopherol and rutin are contained in an oil-in-water emulsion as a flavor deterioration preventing agent, and the quality of off-flavors and off-flavors due to irradiation with light such as a fluorescent lamp is small.

近年、デパート地下の洋菓子店、コンビニエンスストア、スーパーマーケット等では、蛍光灯によって強い光を長時間照射しながら種々の食品をショーケースに陳列して販売することが多くなった。ケーキ等のデコレーションやサンド等に用いられる起泡性水中油型乳化物もこれらの食品の中の一つにあげられる。しかしこのとき、照射される光から与えられるエネルギーによって、陳列されている食品中の成分が変化し、異味、異臭が生じる光劣化の問題が顕在化するようになった。食品の風味を著しく損ねて商品価値を下落させるために、光劣化防止対策は品質保持の上で大きな問題となっている。この光劣化を防止するために、特許文献1では、ミリセチン類とクエルセチン類を特定の配合比でもって併用したり、特許文献2では、プロポリスを使用したり、特許文献3では、クロロゲン酸、カフェー酸、フェルラ酸から選ばれる少なくとも1種を使用するなど、さまざまな風味劣化防止剤が光劣化の抑制作用を有する物質として食品中に添加されてきたが、添加しすぎるとそのもの自体の風味が出てしまうなど使用量が限定され、こと起泡性水中油型乳化物においてはそれだけでは十分な効果を得ることが出来なかった。   In recent years, in pastry stores, convenience stores, supermarkets, etc. in department stores, various foods are often displayed and sold in a showcase while irradiating with strong light with a fluorescent lamp for a long time. Foamable oil-in-water emulsions used for decorations such as cakes and sands are one of these foods. However, at this time, the ingredients in the displayed food change depending on the energy given from the irradiated light, and the problem of photodegradation in which an unpleasant taste and a strange odor become apparent. In order to reduce the product value by significantly deteriorating the flavor of food, measures for preventing light degradation have become a major problem in maintaining quality. In order to prevent this photodegradation, in Patent Document 1, myricetins and quercetin are used in combination at a specific mixing ratio, in Patent Document 2, propolis is used, and in Patent Document 3, chlorogenic acid and caffeine are used. Various flavor deterioration inhibitors, such as the use of at least one selected from acids and ferulic acids, have been added to foods as substances that have the effect of inhibiting photodegradation. The amount of use was limited, and in particular, a foamable oil-in-water emulsion could not provide a sufficient effect.

特開2003−33164号公報JP 2003-33164 A 特開平11−341971号公報Japanese Patent Laid-Open No. 11-341971 特開平10−183164号公報Japanese Patent Laid-Open No. 10-183164

本発明の目的は、ケーキ等のデコレーションやサンド等に用いられる起泡性水中油型乳化物において、蛍光灯等の光照射下に晒されても異味、異臭の品質の劣化が少なく、風味に優れた起泡性水中油型乳化物を提供する事にある。   The object of the present invention is to provide a foamable oil-in-water emulsion for use in decorations such as cakes and sand, and the like, even when exposed to light irradiation such as fluorescent lamps, there is little deterioration in the quality of off-flavors and off-flavors, The object is to provide an excellent foamable oil-in-water emulsion.

本発明者らは上記課題に対して、鋭意研究を行った結果、風味劣化防止剤として特定のトコフェロール及びルチンを特定の量と特定の配合比で含有させることにより、蛍光灯等の光照射下に晒されても異味、異臭の品質の劣化が抑えられることを見出し本発明を完成するに至った。
即ち本発明の第1は、油相と水相からなる水中油型乳化物であって、風味劣化防止剤としてトコフェロール及びルチンを含む起泡性水中油型乳化物であり、トコフェロール及びルチンの含む量が、水中油型乳化物全体に対してトコフェロールが0.04〜0.5重量%であり、且つルチンが0.003〜0.2重量%であって、トコフェロール及びルチンの含む量の割合が、トコフェロール100に対してルチンが3〜50の範囲内であり、油脂分が10〜50重量%、無脂乳固形分が1〜14重量%である、起泡性水中油型乳化物である。第2は、油脂、風味劣化防止剤としてトコフェロール及びルチン、無脂乳固形分及び水を原料とする、油相と水相とを混合後、予備乳化、殺菌又は滅菌処理し均質化処理されたものである、第1記載の起泡性水中油型乳化物である。第3は、レシチン及び/又は乳化剤として乳化剤中の構成脂肪酸に不飽和脂肪酸を含まない乳化剤を1種又は2種以上含むものである、第1又は第2記載の起泡性水中油型乳化物である。
As a result of diligent research on the above problems, the present inventors have included specific tocopherol and rutin as a flavor deterioration inhibitor in a specific amount and a specific mixing ratio, so that they can be irradiated under light irradiation such as a fluorescent lamp. As a result, it was found that deterioration in quality of off-flavors and off-flavors can be suppressed even when exposed to water.
That is, the first of the present invention is an oil-in-water emulsion comprising an oil phase and an aqueous phase, and is a foamable oil-in-water emulsion containing tocopherol and rutin as a flavor deterioration preventing agent, and contains tocopherol and rutin. The amount of tocopherol is 0.04 to 0.5% by weight and the amount of rutin is 0.003 to 0.2% by weight with respect to the whole oil-in-water emulsion, and the ratio of the amount of tocopherol and rutin is included. Is a foamable oil-in-water emulsion in which rutin is in the range of 3-50 with respect to tocopherol 100, the fat content is 10-50 wt%, and the nonfat milk solid content is 1-14 wt%. is there. Second, tocopherol and rutin as non-fat milk solids and water as raw materials were mixed with the oil phase and water phase, and then pre-emulsified, sterilized or sterilized and homogenized. it is those, a foamable oil-in-water emulsion of the first described. 3rd is a foamable oil-in-water emulsion of 1st or 2nd which contains 1 type, or 2 or more types of emulsifier which does not contain unsaturated fatty acid in the constituent fatty acid in an emulsifier as a lecithin and / or an emulsifier. .

ケーキ等のデコレーションやサンド等に用いられる起泡性水中油型乳化物において、蛍光灯等の光照射下に晒されても異味、異臭の品質の劣化が少なく、風味に優れた起泡性水中油型乳化物を提供する事が可能になった。   In foaming oil-in-water emulsions used for decorations such as cakes and sand, foaming water with excellent flavor and little deterioration in taste and odor quality even when exposed to light irradiation such as fluorescent lamps It has become possible to provide oil-type emulsions.

本発明の起泡性水中油型乳化物は、油脂、無脂乳固形分、水及び乳化剤を含む水中油型乳化物であって、流動状態の乳化物であり、”ホイップ用クリーム”と呼ばれたりもする。これを泡立器具、または専用のミキサーを用いて空気を抱き込ませるように攪拌したとき、俗に”ホイップドクリーム”または”ホイップクリーム”と称される、起泡状態を呈するものとなる。   The foamable oil-in-water emulsion of the present invention is an oil-in-water emulsion containing fats and oils, non-fat milk solids, water and an emulsifier, and is a fluid emulsion, and is called “whipping cream” There are also. When this is stirred using a foaming device or a dedicated mixer so that air is entrapped, a foamed state commonly referred to as “whipped cream” or “whipped cream” is exhibited.

本発明の起泡性水中油型乳化物は、油相と水相からなる水中油型乳化物であって、風味劣化防止剤としてトコフェロール及びルチンを含む必要がある。
本発明のトコフェロールとしては、それ自体既知のものであり、市販品として入手可能である。これらは天然の植物から抽出した精製品でも未精製品中に含まれたものでもよく、合成品でも良い。また、δ−トコフェロール等の単品でもα、β、γ、δ−トコフェロール等の混合物でも良いが、好ましくは低α、高δのものが好ましい。また、油脂、デキストリン等により希釈された製剤で使用しても良い。市販品としては理研ビタミン株式会社製の(商品名:理研オイルスーパー80、トコフェロール64%含有)などが例示できる。
本発明の水中油型乳化物に用いるトコフェロールの使用量については0.04〜0.5重量%、好ましくは0.05〜0.45重量%、最も好ましくは0.07〜0.4重量%の範囲で使用するのが望ましい。
トコフェロールの使用量が下限未満の場合は、期待される効果は得られにくく、上限を超える場合には起泡性水中油型乳化物の風味、色調が悪くなる。
The foamable oil-in-water emulsion of the present invention is an oil-in-water emulsion composed of an oil phase and an aqueous phase, and needs to contain tocopherol and rutin as flavor deterioration inhibitors.
The tocopherol of the present invention is known per se and is available as a commercial product. These may be refined products extracted from natural plants, those contained in immature products, or synthetic products. Further, a single product such as δ-tocopherol or a mixture of α, β, γ, δ-tocopherol and the like may be used, but those having low α and high δ are preferable. Moreover, you may use by the formulation diluted with fats and oils, dextrin, etc. Examples of commercially available products include those manufactured by Riken Vitamin Co., Ltd. (trade name: Riken Oil Super 80, containing 64% tocopherol).
The amount of tocopherol used in the oil-in-water emulsion of the present invention is 0.04 to 0.5% by weight, preferably 0.05 to 0.45% by weight, most preferably 0.07 to 0.4% by weight. It is desirable to use within the range.
When the amount of tocopherol used is less than the lower limit, the expected effect is difficult to obtain, and when the amount exceeds the upper limit, the flavor and color tone of the foamable oil-in-water emulsion deteriorates.

本発明のルチンとしては、それ自体既知の物であり、市販品として入手可能である。ルチンは元来、水にはほとんど溶けないため、その利用が遅れていた。本発明では酵素処理されたことにより、水溶性を格段に高められたものが適しており、東洋精糖株式会社製の(商品名:αGルチンPS、ルチン82%含有)が例示できる。
本発明の水中油型乳化物に用いるルチンの使用量については、0.003〜0.2重量%、好ましくは0.004〜0.15重量%、最も好ましくは0.005〜0.10重量%の範囲で使用するのが好ましい。ルチンの使用量が下限未満の場合は、期待される効果は得られにくく、上限を超える場合には起泡性水中油型乳化物の風味が悪くなる。
本発明の水中油型乳化物に、上記の範囲内においてトコフェロール及びルチンを使用するのであるが、トコフェロールの使用量が相対的にルチンの使用量より多いのが好ましく、トコフェロール及びルチンの含む量の割合が、トコフェロール100に対してルチンが3〜50の範囲内であるのが効果と風味を両立させる点で好ましい。
The rutin of the present invention is known per se and is available as a commercial product. Rutin was originally insoluble in water, so its use was delayed. In the present invention, those that have been markedly improved in water solubility by being treated with an enzyme are suitable, and examples include (trade name: αG rutin PS, containing 82% rutin) manufactured by Toyo Seika Co., Ltd.
The amount of rutin used in the oil-in-water emulsion of the present invention is 0.003 to 0.2% by weight, preferably 0.004 to 0.15% by weight, most preferably 0.005 to 0.10%. It is preferable to use in the range of%. When the amount of rutin used is less than the lower limit, the expected effect is difficult to obtain, and when it exceeds the upper limit, the flavor of the foamable oil-in-water emulsion becomes poor.
Tocopherol and rutin are used in the oil-in-water emulsion of the present invention within the above-mentioned range, but the amount of tocopherol used is preferably relatively larger than the amount of rutin used, and the amount of tocopherol and rutin is contained. It is preferable that the ratio is within the range of 3 to 50 for rutin with respect to tocopherol 100 in terms of achieving both effect and flavor.

本発明の油脂としては、動植物性油脂及びそれらの硬化油脂の単独又は2種以上の混合物或いはこれらのものに種々の化学処理又は物理処理を施したものが例示できる。かかる油脂としては、大豆油、綿実油、コーン油、サフラワー油、オリーブ油、パーム油、菜種油、米ぬか油、ゴマ油、カポック油、ヤシ油、パーム核油、乳脂、ラード、魚油、鯨油等の各種の動植物油脂及びそれらの硬化油、分別油、エステル交換油等の加工油脂(融点15〜40℃程度のもの)が例示できる。
油分は10〜50重量%、好ましくは13〜48重量%、更に15〜48重量%が好ましい。油脂分が上限を超える場合は起泡性水中油型乳化物がボテ(可塑化状態)易くなり、下限未満では起泡性、保形性が悪化する傾向になる。
Examples of the fats and oils of the present invention include animal and vegetable fats and oils and their hardened fats and oils, or a mixture of two or more thereof, or those obtained by subjecting these to various chemical treatments or physical treatments. Such fats and oils include soybean oil, cottonseed oil, corn oil, safflower oil, olive oil, palm oil, rapeseed oil, rice bran oil, sesame oil, kapok oil, coconut oil, palm kernel oil, milk fat, lard, fish oil, whale oil, etc. Examples include animal and vegetable oils and fats, processed oils and fats such as hydrogenated oils, fractionated oils, and transesterified oils (melting points of about 15 to 40 ° C.).
The oil content is 10 to 50% by weight, preferably 13 to 48% by weight, and more preferably 15 to 48% by weight. When the oil and fat content exceeds the upper limit, the foamable oil-in-water emulsion tends to be stabbed (plasticized state), and when it is less than the lower limit, the foamability and shape retention tend to deteriorate.

本発明の無脂乳固形分としては、牛乳の全固形分から乳脂肪分を差引いた成分をいい、生乳、牛乳、脱脂乳、生クリーム、濃縮乳、無糖練乳、加糖練乳、全脂粉乳、脱脂粉乳、バターミルクパウダー、ホエー蛋白、カゼイン、カゼインナトリウム等の乳由来の原料が例示でき、無脂乳固形分が1〜14重量%が好ましく、さらに好ましくは2〜12重量%、最も好ましくは4〜10重量%である。無脂乳固形分が1重量%より低い場合は、水中油型乳化物の乳化安定性が悪くなり、乳味感も少なくなって風味が悪くなる。14重量%を超える場合は、水中油型乳化物の粘度が高くなり、コストも高くなり、量に見合った効果が得難くなる。   The non-fat milk solid content of the present invention refers to a component obtained by subtracting the milk fat content from the total solid content of milk, raw milk, cow milk, skim milk, fresh cream, concentrated milk, sugar-free condensed milk, sweetened condensed milk, whole milk powder, Non-fat dry milk, buttermilk powder, whey protein, casein, sodium casein and other raw materials can be exemplified, and the non-fat milk solid content is preferably 1 to 14% by weight, more preferably 2 to 12% by weight, most preferably 4 to 10% by weight. When the non-fat milk solid content is lower than 1% by weight, the emulsification stability of the oil-in-water emulsion is deteriorated, the milky feeling is reduced, and the flavor is deteriorated. When it exceeds 14% by weight, the viscosity of the oil-in-water emulsion is increased, the cost is increased, and it is difficult to obtain an effect commensurate with the amount.

本発明の乳化剤としては、起泡性水中油型乳化物を調製する際に通常使用する乳化剤を適宜選択使用することが出来る。例えば、レシチン、モノグリセライド、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ショ糖脂肪酸エステル等の合成乳化剤が例示でき、これらの乳化剤の中から1種又は2種以上を選択して適宜使用することができる。これらの乳化剤のうち、光照射下に晒されても異味、異臭の品質の劣化が少ないという点で、乳化剤中の構成脂肪酸に不飽和脂肪酸を含まない乳化剤を使用するのが好ましい。   As the emulsifier of the present invention, an emulsifier usually used in preparing a foamable oil-in-water emulsion can be appropriately selected and used. Examples include synthetic emulsifiers such as lecithin, monoglyceride, sorbitan fatty acid ester, propylene glycol fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sucrose fatty acid ester, and one or two of these emulsifiers. The above can be selected and used appropriately. Among these emulsifiers, it is preferable to use an emulsifier that does not contain an unsaturated fatty acid as a constituent fatty acid in the emulsifier in that the quality of taste and odor is less deteriorated even when exposed to light.

本発明の起泡性水中油型乳化物に使用する上記風味劣化防止剤は、トコフェロール、ルチンを有効成分として含有する事により所望の効果が得られるが、必要に応じて公知の抗酸化剤(L−アスコルビン酸等)、香味劣化防止剤(茶抽出物、クロロゲン酸、リンゴポリフェノール、ヒマワリ抽出物、ヤマモモ抽出物等)、金属封鎖剤(グルコン酸、コウジ酸、フィチン酸、ポリリン酸、キチン、キトサン等)等を使用することもできる。これらの中では茶抽出物が風味安定性で含有させることが好ましい。   The flavor deterioration preventing agent used in the foamable oil-in-water emulsion of the present invention can obtain a desired effect by containing tocopherol and rutin as active ingredients, but if necessary, a known antioxidant ( L-ascorbic acid, etc.), flavor deterioration inhibitors (tea extract, chlorogenic acid, apple polyphenol, sunflower extract, bayberry extract, etc.), metal sequestering agents (gluconic acid, kojic acid, phytic acid, polyphosphoric acid, chitin, Chitosan etc.) can also be used. In these, it is preferable to contain a tea extract by flavor stability.

本発明の起泡性水中油型乳化物に使用する上記風味劣化防止剤の添加時期は、特に限定されないが、起泡性水中油型乳化物が光劣化を受ける前に予め添加しておくことが必要であって、起泡性水中油型乳化物を調製する際に添加してもよいし、起泡性水中油型乳化物を調製した後、ホイップする際に添加してもよい。好ましくは、起泡性水中油型乳化物を調製する際に各種原料とともに配合することが望ましい。   The timing of adding the flavor deterioration inhibitor used in the foamable oil-in-water emulsion of the present invention is not particularly limited, but should be added before the foamable oil-in-water emulsion undergoes photodegradation. May be added when preparing the foamable oil-in-water emulsion, or may be added when whipping after preparing the foamable oil-in-water emulsion. Preferably, it is desirable to blend with various raw materials when preparing a foamable oil-in-water emulsion.

本発明の起泡性水中油型乳化物は、オーバーランが40〜400%、好ましくは60〜300%、更に好ましくは60〜200%、最も好ましくは60〜150%であることが好ましい。オーバーランが高すぎる場合には食感が軽すぎたり、風味の乏しいものになる傾向がある。オーバーランが低すぎる場合には食感が重たくなりすぎ、良好な風味、口溶け感が得難くなる。   The foamable oil-in-water emulsion of the present invention preferably has an overrun of 40 to 400%, preferably 60 to 300%, more preferably 60 to 200%, and most preferably 60 to 150%. If the overrun is too high, the texture tends to be too light or the flavor tends to be poor. When the overrun is too low, the texture becomes too heavy, and it becomes difficult to obtain a good flavor and a feeling of melting in the mouth.

本発明の起泡性水中油型乳化物については、各種塩類を使用することが出来る。塩類としては、ヘキサメタリン酸塩、第2リン酸塩、クエン酸ナトリウム、ポリリン酸塩、重曹等を単独又は2種以上混合使用することが好ましい。その他所望により糖類、安定剤、香料、着色料、保存料等を使用することが出来る。   Various salts can be used for the foamable oil-in-water emulsion of the present invention. As the salts, it is preferable to use hexametaphosphate, diphosphate, sodium citrate, polyphosphate, sodium bicarbonate or the like alone or in combination. In addition, saccharides, stabilizers, fragrances, coloring agents, preservatives and the like can be used as desired.

本発明の起泡性水中油型乳化物の製造法としては、油脂、風味劣化防止剤としてトコフェロール及びルチン、無脂乳固形分、乳化剤及び水を原料とする、油相と水相とを混合後、予備乳化、殺菌又は滅菌処理し均質化処理することにより得ることができる。起泡性水中油型乳化物の保存性の点で滅菌処理することが好ましい。具体的には、各種原料を60〜70℃で20分間予備乳化した後(乳化装置はホモミキサー)、必要により0〜250Kg/cm2の条件下にて均質化(乳化装置は均質機)する。次いで超高温瞬間殺菌処理(UHT)した後、再度、0〜300Kg/cm2の条件化にて均質化し、冷却後、約24時間エージングする。 As the method for producing the foamable oil-in-water emulsion of the present invention, the oil phase is mixed with the oil phase and the water phase, using tocopherol and rutin as the flavor deterioration inhibitor, non-fat milk solids, emulsifier and water as raw materials. Thereafter, it can be obtained by preliminary emulsification, sterilization or sterilization and homogenization. It is preferable to sterilize the foamable oil-in-water emulsion from the viewpoint of storage stability. Specifically, after preliminarily emulsifying various raw materials at 60 to 70 ° C. for 20 minutes (the emulsifying device is a homomixer), the material is homogenized under the condition of 0 to 250 kg / cm 2 as necessary (the emulsifying device is a homogenizer). . Next, after ultra-high temperature instant sterilization (UHT), it is homogenized again under the condition of 0 to 300 kg / cm 2 , and after cooling, it is aged for about 24 hours.

超高温瞬間(UHT)殺菌には、間接加熱方式と直接加熱方式の2種類があり、間接加熱処理する装置としてはAPVプレート式UHT処理装置(APV株式会社製)、CP-UHT滅菌装置(クリマティー・パッケージ株式会社製)、ストルク・チューブラー型滅菌装置(ストルク株式会社製)、コンサーム掻取式UHT滅菌装置(テトラパック・アルファラベル株式会社製)等が例示できるが、特にこれらにこだわるものではない。また、直接加熱式滅菌装置としては、超高温滅菌装置(岩井機械工業(株)製)、ユーペリゼーション滅菌装置(テトラパック・アルファラバル株式会社製)、VTIS滅菌装置(テトラパック・アルファラバル株式会社製)、ラギアーUHT滅菌装置(ラギアー株式会社製)、パラリゼーター(パッシュ・アンド・シルケーボーグ株式会社製)等のUHT滅菌装置が例示でき、これらの何れの装置を使用してもよい。   There are two types of ultra-high temperature instant (UHT) sterilization: indirect heating method and direct heating method. As an indirect heat treatment device, APV plate type UHT treatment device (manufactured by APV Co., Ltd.), CP-UHT sterilization device (clima) Tea package Co., Ltd.), Torque / tubular sterilizer (Stork Co., Ltd.), Concer scraping type UHT sterilizer (Tetra Pak Alpha Label Co., Ltd.), etc. is not. Direct heating sterilizers include ultra-high temperature sterilizers (Iwai Kikai Kogyo Co., Ltd.), operation sterilizers (Tetra Pak Alfa Laval Co., Ltd.), and VTIS sterilizers (Tetra Pak Alfa Laval shares). UHT sterilizers such as Ragia UHT sterilizer (manufactured by company), Ragiazer (manufactured by Ragia Co., Ltd.), Paralyzer (manufactured by Pash & Silkeborg Co., Ltd.), and any of these apparatuses may be used.

以下に本発明の実施例を示し本発明をより詳細に説明するが、本発明の精神は以下の実施例に限定されるものではない。なお、例中、%及び部は、いずれも重量基準を意味する。
特に、添加剤の添加順序或いは油相を水相へ又は水相を油相へ加える等の乳化順序が以下の例示によって限定されるものではないことは言うまでもない。また、結果については以下の方法で評価した。
EXAMPLES The present invention will be described in more detail with reference to the following examples, but the spirit of the present invention is not limited to the following examples. In the examples, “%” and “part” mean weight basis.
In particular, it goes without saying that the order of addition of the additives or the emulsification order of adding the oil phase to the water phase or the water phase to the oil phase is not limited by the following examples. The results were evaluated by the following method.

水中油型乳化物を起泡させた場合の評価方法
(1)ホイップタイム:水中油型乳化物1kgをホバードミキサー(HOBART CORPORATION製 MODEL N−5)3速(300rpm)にてホイップし、最適起泡状態に達するまでの時間。
(2)オーバーラン:[(一定容積の水中油型乳化物重量)ー(一定容積の起泡後の起泡物重量)]÷(一定容積の起泡後の起泡物重量)×100
(3)保形性:造花した起泡物を15℃で24時間保存した場合の美しさを調べる。優れている順に、「良好」、「可」、「不可」の三段階にて評価をつける。
(4)風味:専門パネラー20名により官能評価を行う。ホイップ直後の風味評価と光照射後の風味評価の2種類を行った。光照射試験は、蛍光灯照射(照度4000Lx)、温度5℃にて3、6、12時間保存後評価した。風味評価は、優れている順に「5」、「4」、「3」、「2」、「1」の五段階にて評価を行い、平均化した評価を結果とした。
Evaluation method when foaming oil-in-water emulsion (1) Whip time: 1 kg of oil-in-water emulsion is whipped at 3rd speed (300 rpm) by Hovard mixer (MODEL N-5 manufactured by HOBART CORPORATION). Time to reach foaming condition.
(2) Overrun: [(weight of oil-in-water emulsion of a certain volume) − (weight of foam after a certain volume of foaming)] ÷ (weight of foam after a certain volume of foaming) × 100
(3) Shape retention: The beauty when the artificial foam is stored at 15 ° C. for 24 hours is examined. In order of superiority, give a rating in three stages: “Good”, “Yes”, and “No”.
(4) Flavor: Sensory evaluation is performed by 20 professional panelists. Two kinds of flavor evaluation immediately after whipping and flavor evaluation after light irradiation were performed. The light irradiation test was evaluated after storage at fluorescent lamp irradiation (illuminance 4000 Lx) at a temperature of 5 ° C. for 3, 6 and 12 hours. The flavor evaluation was evaluated in five stages of “5”, “4”, “3”, “2”, “1” in order of superiority, and the averaged evaluation was the result.

実施例1
市販の生クリーム(よつ葉乳業株式会社製、油脂分47%、無乳固形分5%)にトコフェロール(商品名:理研オイルスーパー80、理研ビタミン株式会社製、;トコフェロール64%含有)0.1部、ルチン(商品名:αGルチンPS、東洋精糖株式会社製、ルチン82%含有)0.01部を溶解し、65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、20Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。この水中油型乳化物1Kgに80gのグラニュー糖を加えて、上記のホイップ方法に従って評価した。結果を表1に纏めた。
Example 1
Tocopherol (trade name: Riken Oil Super 80, manufactured by Riken Vitamin Co., Ltd .; containing 64% tocopherol) in a fresh cream (made by Yotsuba Dairy Co., Ltd., oil content: 47%, milk-free solid content: 5%) , Rutin (trade name: αG rutin PS, manufactured by Toyo Seiki Co., Ltd., containing 82% rutin), dissolved in 0.01 part, stirred with a homomixer for 30 minutes at 65 ° C. and pre-emulsified, and then ultra-high temperature sterilizer (Iwai) The product was sterilized by a direct heating method at 145 ° C. for 4 seconds at 145 ° C., and then homogenized at a homogenization pressure of 20 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. 80 g of granulated sugar was added to 1 kg of this oil-in-water emulsion and evaluated according to the above whipping method. The results are summarized in Table 1.

実施例2
硬化菜種油(融点35℃)20.0部、硬化パーム核油(融点34℃)20.0部にレシチン0.3部、トコフェロール(商品名:理研オイルスーパー80、理研ビタミン株式会社製、;トコフェロール64%含有)0.1部を添加混合溶解し油相とする。これとは別に水54.29部に脱脂粉乳5.0部、ショ糖脂肪酸エステル(HLB5)0.2部、メタリン酸ナトリウム0.1部、ルチン(商品名:αGルチンPS、東洋精糖株式会社製、ルチン82%含有)0.01部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。実施例1と同様にして、上記のホイップ方法に従って評価した。結果を表1に纏めた。
Example 2
Hardened rapeseed oil (melting point 35 ° C) 20.0 parts, hardened palm kernel oil (melting point 34 ° C) 20.0 parts, lecithin 0.3 parts, tocopherol (trade name: Riken Oil Super 80, manufactured by Riken Vitamin Co., Ltd .; Tocopherol (Containing 64%) 0.1 part is added, mixed and dissolved to obtain an oil phase. Separately, 54.29 parts of water, 5.0 parts of skim milk powder, 0.2 parts of sucrose fatty acid ester (HLB5), 0.1 parts of sodium metaphosphate, rutin (trade name: αG rutin PS, Toyo Seika Co., Ltd.) Manufactured, containing 82% rutin) 0.01 parts is dissolved to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. In the same manner as in Example 1, the evaluation was performed according to the above whipping method. The results are summarized in Table 1.

実施例3
パーム中融点部(融点34℃)25.0部、硬化パーム核油(融点34℃)5.0部にトコフェーロール(商品名:理研オイルスーパー80、理研ビタミン株式会社製、;トコフェロール64%含有)0.1部を添加混合溶解し油相とする。これとは別に水64.59部に脱脂粉乳5.0部、モノミリスチン酸ペンタグリセリン0.2部、メタリン酸ナトリウム0.1部、ルチン(商品名:αGルチンPS、東洋精糖株式会社製、;ルチン82%含有)0.01部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。実施例1と同様にして、上記のホイップ方法に従って評価した。結果を表1に纏めた。
Example 3
Tocopherol (trade name: Riken Oil Super 80, manufactured by Riken Vitamin Co., Ltd .; Tocopherol 64%) 25.0 parts of the middle melting point of palm (melting point 34 ° C), 5.0 parts of hardened palm kernel oil (melting point 34 ° C) Contain) 0.1 part is added, mixed and dissolved to obtain an oil phase. Separately, 64.59 parts of water, 5.0 parts of skim milk powder, 0.2 parts of pentaglyceryl monomyristate, 0.1 part of sodium metaphosphate, rutin (trade name: αG rutin PS, manufactured by Toyo Seika Co., Ltd., ; Containing 82% rutin) 0.01 parts are dissolved to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. In the same manner as in Example 1, the evaluation was performed according to the above whipping method. The results are summarized in Table 1.

実施例4
硬化菜種油(融点35℃)18.0部にレシチン0.2部、トコフェロール(商品名:理研オイルスーパー80、理研ビタミン株式会社製、;トコフェロール64%含有)0.1部を添加混合溶解し油相とする。これとは別に市販の生クリーム(よつ葉乳業株式会社製、油脂分47%、無乳固形分5%)27.0部、水18.99部に脱脂粉乳5.0部、ショ糖脂肪酸エステル0.1部、メタリン酸ナトリウム0.1部、ルチン(商品名:αGルチンPS、東洋精糖株式会社製、ルチン82%含有)0.01部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、30Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。実施例1と同様にして、上記のホイップ方法に従って評価した。結果を表1に纏めた。
Example 4
Cured rapeseed oil (melting point 35 ° C.) 18.0 parts, lecithin 0.2 part, tocopherol (trade name: Riken Oil Super 80, manufactured by Riken Vitamin Co., Ltd .; containing 64% tocopherol) mixed and dissolved to dissolve oil Let it be a phase. Separately, 27.0 parts of commercially available fresh cream (made by Yotsuba Milk Industry Co., Ltd., oil / fat content 47%, milk-free solid content 5%), water 18.99 parts, skim milk powder 5.0 parts, sucrose fatty acid ester 0 .1 part, 0.1 part of sodium metaphosphate and 0.01 part of rutin (trade name: αG rutin PS, manufactured by Toyo Seika Co., Ltd., containing 82% rutin) are dissolved to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 30 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. In the same manner as in Example 1, the evaluation was performed according to the above whipping method. The results are summarized in Table 1.

実施例5
硬化菜種油(融点35℃)15.0部、硬化パーム核油(融点34℃)12.0部にレシチン0.2部、トコフェロール(商品名:理研オイルスーパー80、理研ビタミン株式会社製、;トコフェロール64%含有)0.1部を添加混合溶解し油相とする。これとは別に市販の生クリーム(よつ葉乳業株式会社製、油脂分47%、無乳固形分5%)18.0部、水49.39部に脱脂粉乳5.0部、ショ糖脂肪酸エステル0.2部、メタリン酸ナトリウム0.1部、ルチン(商品名:αGルチンPS、東洋精糖株式会社製、ルチン82%含有)0.01部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、30Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。実施例1と同様にして、上記のホイップ方法に従って評価した。結果を表1に纏めた。
Example 5
Hardened rapeseed oil (melting point 35 ° C) 15.0 parts, hardened palm kernel oil (melting point 34 ° C) 12.0 parts, lecithin 0.2 parts, tocopherol (trade name: Riken Oil Super 80, manufactured by Riken Vitamin Co., Ltd .; Tocopherol (Containing 64%) 0.1 part is added, mixed and dissolved to obtain an oil phase. Apart from this, 18.0 parts of commercially available fresh cream (manufactured by Yotsuba Milk Industry Co., Ltd., oil and fat content 47%, milk-free solid content 5%), water 49.39 parts, skim milk powder 5.0 parts, sucrose fatty acid ester 0 .2 parts, 0.1 part of sodium metaphosphate, and 0.01 part of rutin (trade name: αG rutin PS, manufactured by Toyo Seika Co., Ltd., containing 82% rutin) are dissolved to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 30 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. In the same manner as in Example 1, the evaluation was performed according to the above whipping method. The results are summarized in Table 1.

実施例6
植物性油脂ベースの水中油型乳化物を表1の配合に従い、以下の方法で調製した。硬化菜種油(融点35℃)42.5部にレシチン0.2部、トコフェロール(商品名:理研オイルスーパー80、理研ビタミン株式会社製、;トコフェロール64%含有)0.24部を添加混合溶解し油相とする。これとは別に水51.84部に脱脂粉乳5.0部、ショ糖脂肪酸エステル0.2部、メタリン酸ナトリウム0.1部、ルチン(商品名:αGルチンPS、東洋精糖株式会社製、ルチン82%含有)0.02部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、30Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、植物性油脂ベースの水中油型乳化物を得た。この乳化物40部と市販の生クリーム(よつ葉乳業株式会社製、油脂分47%、無乳固形分5%)60部を5℃にて混合し、実施例1と同様な方法でホイップし評価した。結果を表1に纏めた。
Example 6
A vegetable oil-based oil-in-water emulsion was prepared according to the formulation shown in Table 1 by the following method. Add 40.2 parts hardened rapeseed oil (melting point 35 ° C.) to 0.24 parts lecithin and 0.24 parts tocopherol (trade name: Riken Oil Super 80, manufactured by Riken Vitamin Co., Ltd .; 64% tocopherol). Let it be a phase. Separately, 51.84 parts of water, 5.0 parts of skim milk powder, 0.2 part of sucrose fatty acid ester, 0.1 part of sodium metaphosphate, rutin (trade name: αG rutin PS, manufactured by Toyo Seika Co., Ltd., rutin) 82% content) 0.02 part is dissolved to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 30 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion based on vegetable oil. 40 parts of this emulsified product and 60 parts of a commercially available fresh cream (made by Yotsuba Milk Industry Co., Ltd., oil and fat content 47%, milk-free solid content 5%) are mixed at 5 ° C., and whipped and evaluated in the same manner as in Example 1. did. The results are summarized in Table 1.

Figure 0004396334
Figure 0004396334

実施例7〜実施例12
表2に示した配合により、実施例4と同様な方法で水中油型乳化物を得た。実施例1と同様な方法でこれらの乳化物を評価した結果を表2に纏めた。
Example 7 to Example 12
With the formulation shown in Table 2, an oil-in-water emulsion was obtained in the same manner as in Example 4. The results of evaluating these emulsions in the same manner as in Example 1 are summarized in Table 2.

Figure 0004396334
Figure 0004396334

比較例1
市販の生クリーム(よつ葉乳業株式会社製、油脂分47%、無脂乳固形分5%)を実施例1と同様な方法でホイップし評価した。結果を表3に纏めた。
Comparative Example 1
A commercially available fresh cream (manufactured by Yotsuba Milk Industry Co., Ltd., oil / fat content 47%, non-fat milk solid content 5%) was whipped and evaluated in the same manner as in Example 1. The results are summarized in Table 3.

比較例2
硬化菜種油(融点35℃)20.0部、硬化パーム核油(融点34℃)20.0部にレシチン0.3部を添加混合溶解し油相とする。これとは別に水54.4部に脱脂粉乳5.0部、ショ糖脂肪酸エステル0.2部、メタリン酸ナトリウム0.1部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。実施例1と同様にして、上記のホイップ方法に従って評価した。結果を表3に纏めた。
Comparative Example 2
Add 0.3 parts of lecithin to 20.0 parts of hardened rapeseed oil (melting point 35 ° C.) and 20.0 parts of hardened palm kernel oil (melting point 34 ° C.) to dissolve and make an oil phase. Separately, 5.0 parts of skim milk powder, 0.2 part of sucrose fatty acid ester and 0.1 part of sodium metaphosphate are dissolved in 54.4 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. In the same manner as in Example 1, the evaluation was performed according to the above whipping method. The results are summarized in Table 3.

比較例3
硬化菜種油(融点35℃)20.0部、硬化パーム核油(融点34℃)20.0部にレシチン0.3部、トコフェロール(商品名:理研オイルスーパー80、理研ビタミン株式会社製、;トコフェロール64%含有)0.3部を添加混合溶解し油相とする。これとは別に水54.1部に脱脂粉乳5.0部、ショ糖脂肪酸エステル0.2部、メタリン酸ナトリウム0.1部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。実施例1と同様にして、上記のホイップ方法に従って評価した。結果を表3に纏めた。
Comparative Example 3
Hardened rapeseed oil (melting point 35 ° C) 20.0 parts, hardened palm kernel oil (melting point 34 ° C) 20.0 parts, lecithin 0.3 parts, tocopherol (trade name: Riken Oil Super 80, manufactured by Riken Vitamin Co., Ltd .; Tocopherol 64 parts) 0.3 parts is added, mixed and dissolved to obtain an oil phase. Separately, 5.0 parts of skim milk powder, 0.2 part of sucrose fatty acid ester and 0.1 part of sodium metaphosphate are dissolved in 54.1 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. In the same manner as in Example 1, the evaluation was performed according to the above whipping method. The results are summarized in Table 3.

比較例4
硬化菜種油(融点35℃)20.0部、硬化パーム核油(融点34℃)20.0部にレシチン0.3部を添加混合溶解し油相とする。これとは別に水54.37部に脱脂粉乳5.0部、ショ糖脂肪酸エステル0.2部、メタリン酸ナトリウム0.1部、ルチン(商品名:αGルチンPS、東洋精糖株式会社製、ルチン82%含有)0.03部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。実施例1と同様にして、上記のホイップ方法に従って評価した。結果を表3に纏めた。
Comparative Example 4
Add 0.3 parts of lecithin to 20.0 parts of hardened rapeseed oil (melting point 35 ° C.) and 20.0 parts of hardened palm kernel oil (melting point 34 ° C.) to dissolve and make an oil phase. Separately, 54.37 parts of water, 5.0 parts of skim milk powder, 0.2 parts of sucrose fatty acid ester, 0.1 parts of sodium metaphosphate, rutin (trade name: αG rutin PS, manufactured by Toyo Seika Co., Ltd., rutin) 82% content) 0.03 part is dissolved to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. In the same manner as in Example 1, the evaluation was performed according to the above whipping method. The results are summarized in Table 3.

比較例5〜比較例7
表3に示した配合により、実施例2と同様な方法で水中油型乳化物を得た。実施例1と同様な方法でこれらの乳化物を評価した結果を表3に纏めた。
Comparative Example 5 to Comparative Example 7
With the formulation shown in Table 3, an oil-in-water emulsion was obtained in the same manner as in Example 2. The results of evaluating these emulsions in the same manner as in Example 1 are summarized in Table 3.

Figure 0004396334
Figure 0004396334

比較例8〜比較例10
表4に示した配合により、実施例2と同様な方法で水中油型乳化物を得た。実施例1と同様な方法でこれらの乳化物を評価した結果を表4に纏めた。
ローズマリー抽出物は三菱化学株式会社の抽出精製品(抽出物含有量40%)を、生コーヒー豆抽出物は富士化学工業株式会社製の商品名カフェノールP−100(抽出物含有量100%)を、茶抽出物は太陽化学株式会社製の商品名サンフェノンBG(抽出物含有量100%)をそれぞれ使用した。
Comparative Example 8 to Comparative Example 10
With the formulation shown in Table 4, an oil-in-water emulsion was obtained in the same manner as in Example 2. The results of evaluating these emulsions in the same manner as in Example 1 are summarized in Table 4.
Rosemary extract is extracted from Mitsubishi Chemical Co., Ltd. (extract content 40%), fresh coffee bean extract is brand name Kaphenol P-100 (100% extract content) manufactured by Fuji Chemical Industry Co., Ltd. The tea extract used was the trade name Sunphenon BG (extract content 100%) manufactured by Taiyo Kagaku Co., Ltd.

Figure 0004396334
Figure 0004396334

実施例13
市販の生クリーム(よつ葉乳業株式会社製、油脂分47%、無乳固形分5%)100部に対して、トコフェロール(商品名:理研オイルスーパー80、理研ビタミン株式会社製、;トコフェロール64%含有)0.1部、ルチン(商品名:αGルチンPS、東洋精糖株式会社製、ルチン82%含有)0.01部、グラニュー糖8部を添加して、実施例1と同様のホイップ方法で評価した。結果は、ホイップ時間は40秒、オーバーランは65%、保形性15℃は良好であり、ホイップ直後の風味、光照射後の風味は実施例1と同じであった。
Example 13
Tocopherol (trade name: Riken Oil Super 80, manufactured by Riken Vitamin Co., Ltd .; 64% tocopherol) per 100 parts of commercially available fresh cream (Yotsuba Milk Industry Co., Ltd., fat and oil content 47%, milk-free solid content 5%) ) 0.1 part, rutin (trade name: αG rutin PS, manufactured by Toyo Seika Co., Ltd., containing 82% rutin), 0.01 part, and 8 parts of granulated sugar were added and evaluated by the same whipping method as in Example 1. did. As a result, the whipping time was 40 seconds, the overrun was 65%, the shape retention was 15 ° C., and the flavor immediately after whipping and the flavor after light irradiation were the same as in Example 1.

本発明は、ケーキ等のデコレーションやサンド等に用いられる起泡性水中油型乳化物(ホイップクリーム)に関する。更に詳しくは蛍光灯等の光照射による異味、異臭の品質の劣化が少ない起泡性水中油型乳化物に関する。   The present invention relates to a foamable oil-in-water emulsion (whipped cream) used for decoration such as cake or sand. More specifically, the present invention relates to a foamable oil-in-water emulsion with little deterioration in quality of off-flavors and off-flavors caused by light irradiation from a fluorescent lamp or the like.

Claims (3)

油相と水相からなる水中油型乳化物であって、風味劣化防止剤としてトコフェロール及びルチンを含む起泡性水中油型乳化物であり、トコフェロール及びルチンの含む量が、水中油型乳化物全体に対してトコフェロールが0.04〜0.5重量%であり、且つルチンが0.003〜0.2重量%であって、トコフェロール及びルチンの含む量の割合が、トコフェロール100に対してルチンが3〜50の範囲内であり、油脂分が10〜50重量%、無脂乳固形分が1〜14重量%である、起泡性水中油型乳化物。 An oil-in-water emulsion comprising an oil phase and an aqueous phase, which is a foamable oil-in-water emulsion containing tocopherol and rutin as flavor deterioration inhibitors, and the amount of tocopherol and rutin contained in the oil-in-water emulsion Tocopherol is 0.04 to 0.5% by weight and rutin is 0.003 to 0.2% by weight with respect to the whole, and the ratio of the amount of tocopherol and rutin contained is rutin to tocopherol 100. Is a foamable oil-in-water emulsion in which the fat content is 10 to 50% by weight and the nonfat milk solid content is 1 to 14% by weight . 油脂、風味劣化防止剤としてトコフェロール及びルチン、無脂乳固形分及び水を原料とする、油相と水相とを混合後、予備乳化、殺菌又は滅菌処理し均質化処理されたものである、請求項1記載の起泡性水中油型乳化物。 Oils, tocopherols and rutins as flavor deterioration inhibitors, using non-fat milk solids and water as raw materials, after mixing the oil phase and water phase, pre-emulsified, sterilized or sterilized and homogenized. The foamable oil-in-water emulsion according to claim 1. レシチン及び/又は乳化剤として乳化剤中の構成脂肪酸に不飽和脂肪酸を含まない乳化剤を1種又は2種以上含むものである、請求項1又は請求項2記載の起泡性水中油型乳化物。 The foamable oil-in-water emulsion according to claim 1 or 2 , wherein the constituent fatty acid in the emulsifier includes at least one emulsifier that does not contain an unsaturated fatty acid as lecithin and / or an emulsifier .
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