JP4882749B2 - Oil-in-water emulsion - Google Patents

Oil-in-water emulsion Download PDF

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JP4882749B2
JP4882749B2 JP2006537642A JP2006537642A JP4882749B2 JP 4882749 B2 JP4882749 B2 JP 4882749B2 JP 2006537642 A JP2006537642 A JP 2006537642A JP 2006537642 A JP2006537642 A JP 2006537642A JP 4882749 B2 JP4882749 B2 JP 4882749B2
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oil
water emulsion
fatty acid
acid ester
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JPWO2006035543A1 (en
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祐子 清原
亮太郎 佐藤
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Fuji Oil Co Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/003Compositions other than spreads
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/005Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides
    • A23D7/0053Compositions other than spreads
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/01Other fatty acid esters, e.g. phosphatides
    • A23D7/011Compositions other than spreads
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L9/00Puddings; Cream substitutes; Preparation or treatment thereof
    • A23L9/20Cream substitutes
    • A23L9/22Cream substitutes containing non-milk fats but no proteins other than milk proteins
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P30/00Shaping or working of foodstuffs characterised by the process or apparatus
    • A23P30/40Foaming or whipping

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Grain Derivatives (AREA)
  • Edible Oils And Fats (AREA)

Description

本発明は、水中油型乳化物(クリームとも言う)に関し、詳しくはあっさりした風味の水中油型乳化物であって、通常のクリームとしての他、酸性の原材料即ち果実、果汁、ヨーグルト、各種の酸味料等をホイップ操作の段階で混合しても、クリームが増粘、固化することなく、ホイップしてもオーバーランが低下せず、ホイップ後のシマリモドリのない耐酸性の水中油型乳化物に関する。   The present invention relates to an oil-in-water emulsion (also referred to as a cream), and more particularly, a light-flavored oil-in-water emulsion, which is an ordinary raw material such as fruit, fruit juice, yogurt It relates to acid-resistant oil-in-water emulsions that do not have thickened and solidified creams, do not decrease overrun even when whipped, and have no scallops after whipping. .

水中油型乳化物(クリームとも言う)は、一般的には、水、油脂、無脂乳固形分、各種乳化剤等を原料にして、予備乳化、均質化、殺菌、再均質化、冷却、エージングにより製造される。
これらのクリームは通常は生クリームと同様に中性である為、クリーム製造においては安定的に調製が可能であるという利点があるが、風味の面ではクリームのpHを変化させないために、生クリーム様の風味の他、チョコレート等に限定されることから、風味が画一的になるという欠点があった。
このような状況下において、最近特に嗜好が多様化し、クリームにおいても、各種の果実、果汁、ヨーグルト、各種の酸味料により、酸味を有する原材料を配合した、清涼感の高い酸性のクリームや耐酸性を有するクリームが種々提案されている。
特許文献1では、油相と水相とを酸性物質の存在下に乳化してpHが3.5乃至5.0の酸性ホイッピングクリームを製造するにあたり、乳化剤としてレシチン及びショ糖脂肪酸エステルと、さらに構成脂肪酸が飽和酸及び不飽和酸からそれぞれ成る2種以上のポリグリセリン脂肪酸エステルとを併用することを特徴とする酸性ホイッピングクリームの製造法が提案され、特許文献2では、酵素により加水分解された乳清蛋白質を主成分として含む加水分解物を含有することを特徴とする水中油型乳化脂組成物が提案されている。
そして、特許文献3では、牛乳より分離した生クリームに、全タンパク質中に占めるβーラクトグロブリン含有割合の高いホエータンパク質処理物を部分加水分解して得られる精製ホエータンパク質加水分解物を配合し、均質化することを特徴とする生クリーム乳化物の製造法が提案され、特許文献4では、油脂とタンパク質とから成るホイップクリームにおいて、配合比が3.8から0.24までのカゼインタンパク質とホエータンパク質との混合物、乳化剤としてレシチン及び特定の平均グリセリン重合度とHLB値を有する二種類のポリグリセリン飽和脂肪酸エステルから成る混合物及び食物繊維および/または化工澱粉とをそれぞれ特定量必須成分として配合したホイップクリーム組成物及びかかるホイップクリームの製造方法が提案されている。また、特許文献5では、40〜80重量%の水相と、20〜60重量%の油相から成る水中油型乳化物であって、0.05〜10重量%の乳清蛋白質、0.2〜5重量%の脱脂乳固形を含み、リン酸塩およびクエン酸塩の総重量が0.01重量%未満であることを特徴とする水中油型乳化物が提案されている。
しかしながら、これらの提案では、本発明の課題とする、あっさりした風味の水中油型乳化物であって、通常のクリームとしての他、酸性の原材料即ち果実、果汁、ヨーグルト、各種の酸味量等をホイップ操作の段階で混合しても、クリームが増粘、固化することなく、ホイップしてもオーバーランが低下せず、ホイップ後のシマリモドリのない耐酸性の水中油型乳化物を得るには十分ではなかった。
Oil-in-water emulsions (also called creams) are generally pre-emulsified, homogenized, sterilized, re-homogenized, cooled, and aged using water, fats and oils, non-fat milk solids, and various emulsifiers as raw materials. Manufactured by.
Since these creams are usually neutral like fresh creams, there is an advantage that they can be stably prepared in cream production. However, since the pH of the cream is not changed in terms of flavor, In addition to the above-mentioned flavor, there is a drawback that the flavor becomes uniform because it is limited to chocolate and the like.
Under these circumstances, tastes have been diversified recently, and in creams, a variety of fruits, fruit juices, yogurt, and various acidulants are blended with sour ingredients that have a refreshing acidity and acid resistance. Various creams having the following have been proposed.
In Patent Document 1, in producing an acidic whipping cream having a pH of 3.5 to 5.0 by emulsifying an oil phase and an aqueous phase in the presence of an acidic substance, lecithin and a sucrose fatty acid ester as an emulsifier, A method for producing an acidic whipping cream characterized in that two or more kinds of polyglycerin fatty acid esters each having a constituent fatty acid consisting of a saturated acid and an unsaturated acid are used in combination is proposed, and in Patent Document 2, it is hydrolyzed by an enzyme. An oil-in-water emulsified fat composition comprising a hydrolyzate containing whey protein as a main component has been proposed.
And in patent document 3, it mix | blends the refined whey protein hydrolyzate obtained by partially hydrolyzing the whey protein processed material with a high content rate of (beta) -lactoglobulin occupying in all the protein in the fresh cream isolate | separated from milk, A method for producing a fresh cream emulsion characterized by homogenization has been proposed. In Patent Document 4, casein protein and whey having a blending ratio of 3.8 to 0.24 in a whipped cream comprising fat and protein are disclosed. Whip comprising a mixture with protein, lecithin as an emulsifier and a mixture of two kinds of polyglycerin saturated fatty acid esters having a specific average glycerin polymerization degree and HLB value, and dietary fiber and / or modified starch each as an essential component A cream composition and a method for producing such whipped cream are provided. It is. Moreover, in patent document 5, it is an oil-in-water-type emulsion which consists of a 40-80 weight% aqueous phase and a 20-60 weight% oil phase, Comprising: 0.05-10 weight% whey protein, Oil-in-water emulsions have been proposed, characterized in that they contain 2-5% by weight of skim milk solids and the total weight of phosphate and citrate is less than 0.01% by weight.
However, in these proposals, it is a light-flavored oil-in-water emulsion, which is a subject of the present invention, and as an ordinary cream, acidic raw materials, that is, fruit, fruit juice, yogurt, various acidity amounts, etc. Even if mixed at the stage of whipping operation, the cream does not thicken and solidify, and even if whipped, the overrun does not decrease, and it is enough to obtain an acid-resistant oil-in-water emulsion without scallop after whipping. It wasn't.

特開昭60−54635号公報JP-A-60-54635 特開平2−257838号公報JP-A-2-257838 特開平7−79699号公報Japanese Patent Laid-Open No. 7-79699 特開平8−154612号公報JP-A-8-154612 特開2000−262236号公報JP 2000-262236 A

本発明は、あっさりした風味の水中油型乳化物であって、通常のクリームとしての他、酸性の原材料即ち果実、果汁、ヨーグルト、各種の酸味量等をホイップ操作の段階で混合しても、クリームが増粘、固化することなく、ホイップしてもオーバーランが低下せず、ホイップ後のシマリモドリのない耐酸性の水中油型乳化物すなわち、中性、酸性両用の耐酸性クリームを提供することを目的とする。   The present invention is a light-flavored oil-in-water emulsion, and as an ordinary cream, acidic raw materials such as fruit, fruit juice, yogurt, various sour amounts, etc. may be mixed at the stage of whipping operation, To provide an acid-resistant oil-in-water emulsion that does not thicken or solidify, does not decrease overrun even when whipped, and does not have scallops after whipping, ie, neutral and acid-resistant cream With the goal.

本発明者らは、上記課題を解決するため、数多くの試行錯誤の結果、乳清蛋白と特定のポリグリセリン脂肪酸エステル及び特定のショ糖脂肪酸エステルの組み合わせにより、本発明を完成するに至った。
即ち、本発明の第1は、水、油脂、乳清蛋白、乳化剤を含む水中油型乳化物において、乳清蛋白質を0.03〜0.4重量%含み、カゼイン蛋白質を含まないで、乳化剤としてレシチンを添加しないで、主要な構成脂肪酸がオレイン酸であるポリグリセリン脂肪酸エステル及びHLB値が4〜15の範囲にあるショ糖脂肪酸エステルを含み、当該ポリグリセリン脂肪酸エステルがグリセリンの重合度が2〜10であり、エステル化度が1〜6であることを特徴とする水中油型乳化物である。第2は、水中油型乳化物が耐酸性を有する、第1記載の水中油型乳化物 である。第3は、水中油型乳化物が起泡性を有する、第1又は第2記載の水中油型乳化物である。
As a result of numerous trials and errors, the present inventors have completed the present invention by combining whey protein, a specific polyglycerin fatty acid ester, and a specific sucrose fatty acid ester.
That is, the first present invention, water, oil, whey protein, oil-in-water emulsion containing an emulsifier, a whey protein 0.03 to 0.4 wt% seen including, without including casein proteins, without the addition of lecithin as an emulsifier, the major constituent fatty acids is a polyglycerol fatty acid ester and HLB value is oleic acid viewing contains a sucrose fatty acid ester in the range of 4 to 15, the polymerization degree of the polyglycerol fatty acid ester is glycerin Is an oil-in-water emulsion characterized by having an esterification degree of 1-6 . The second is the oil- in- water emulsion according to the first, wherein the oil- in- water emulsion has acid resistance . The third is the oil- in- water emulsion according to the first or second, wherein the oil- in- water emulsion has foamability .

pHを変化させる様な酸性物質(たとえば果汁等)を添加しても、増粘及び固化(ボテ)、ならびにホイップ機能の低下等を生じず、酸性にする前の中性のクリームのようなクリーム本来のホイップ機能を有し、あっさりしていて多種類の風味付けが可能である中性、酸性両用の水中油型乳化物及びその製造法を提供することが可能になった。   Even if an acidic substance that changes pH (such as fruit juice) is added, it does not cause thickening and solidification (bottom) and a decrease in whipping function. It has become possible to provide a neutral and acidic oil-in-water emulsion that has an original whipping function and is light and can be flavored in a variety of flavors, and a method for producing the same.

本発明の水中油型乳化物は、水、油脂、乳清蛋白、乳化剤等を原料にして、乳清蛋白質を0.03〜0.4重量%含むとともに、乳化剤としてレシチンを添加しないで、主要な構成脂肪酸がオレイン酸であるポリグリセリン脂肪酸エステル及び主要な構成脂肪酸が飽和酸であり、HLB値が4〜15の範囲にあるショ糖脂肪酸エステルを含む水中油型乳化物である。   The oil-in-water emulsion of the present invention contains 0.03 to 0.4% by weight of whey protein using water, fats and oils, whey protein, emulsifier, etc. as raw materials, and without adding lecithin as an emulsifier. This is an oil-in-water emulsion containing a polyglycerin fatty acid ester whose main constituent fatty acid is oleic acid and a main constituent fatty acid is a saturated acid, and a sucrose fatty acid ester whose HLB value is in the range of 4-15.

本発明で使用される油脂原料として例えば、菜種油、大豆油、ひまわり種子油、綿実油、落花生油、米糠油、コーン油、サフラワー油、オリーブ油、カポック油、ゴマ油月見草油、パーム油、パーム核油、ヤシ油等の植物性油脂ならびに乳脂、牛脂、豚脂、魚油、鯨油等の動物性油脂が例示でき、上記油脂類の単独または混合油あるいはそれらの硬化分別油、ならびに酵素エステル交換、触媒によるランダムエステル交換等を施した加工油脂(融点15〜40℃程度のもの)が使用できる。油脂分としては15〜55重量%が好まく、更に20〜50重量%が好ましい。 油脂分が少ないと、水中油型乳化物の場合は、油脂分に由来する濃厚な口あたり、風味が得にくくなり、起泡性水中油型乳化物の場合は起泡性、保形性が悪化する傾向になる。油脂分が多すぎると、水中油型乳化物又は起泡性水中油型乳化物がボテ(可塑化状態)易くなる。   Examples of oils and fats used in the present invention include rapeseed oil, soybean oil, sunflower seed oil, cottonseed oil, peanut oil, rice bran oil, corn oil, safflower oil, olive oil, kapok oil, sesame oil evening primrose oil, palm oil, palm kernel oil Examples include vegetable oils such as coconut oil and animal fats such as milk fat, beef tallow, pork fat, fish oil, whale oil, and the like. Processed fats and oils subjected to random transesterification (melting point of about 15 to 40 ° C.) can be used. The oil content is preferably 15 to 55% by weight, more preferably 20 to 50% by weight. When the oil and fat content is low, in the case of an oil-in-water emulsion, it is difficult to obtain a rich mouthfeel derived from the oil and fat, and in the case of a foamable oil-in-water emulsion, foamability and shape retention are low. It tends to get worse. When there is too much oil and fat content, an oil-in-water type emulsion or a foamable oil-in-water type emulsion will become easy (plasticization state).

本発明の乳清蛋白は、生乳や脱脂乳からチーズや酸カゼイン、レンネットカゼインを製造する際のカードと分離する上清中(ホエー)に存在する蛋白の総称であり、通称名で乳清蛋白あるいはラクトアルブミンとも呼ぶ。本発明においては市販の乳清蛋白あるいはラクトアルブミンなどが使用でき、またそれらの濃縮物(WPC)や分離物(WPI)なども、使用できる。また、乳清蛋白の主成分であるβーラクトグロブリンやαーラクトアルブミンを含む脱脂乳のUF膜並びに電気透析物である乳蛋白濃縮物や乳蛋白分離物も使用可能である。本発明の乳清蛋白の含む量としては、水中油型乳化物全体に対して、乳清蛋白質として0.03〜0.4重量%の範囲で使用する必要があって、下限未満では効果を得難く、逆に上限を越えると酸味料を加えた乳化物が起泡しづらくなる傾向にある為、好ましくない。 乳清蛋白質を上記範囲内において使用する場合、乳清蛋白質1に対して、カゼイン蛋白質量が0.5以下が好ましく、更にカゼイン蛋白質を含まないのが好ましい。   The whey protein of the present invention is a generic term for proteins present in the supernatant (whey) separated from curd when producing cheese, acid casein, or rennet casein from raw milk or skim milk. Also called protein or lactalbumin. In the present invention, commercially available whey protein, lactalbumin, or the like can be used, and concentrates (WPC) or isolates (WPI) thereof can also be used. Moreover, a UF membrane of skim milk containing β-lactoglobulin and α-lactalbumin, which are the main components of whey protein, and a milk protein concentrate and a milk protein isolate, which are electrodialysates, can also be used. The amount of the whey protein of the present invention should be used in the range of 0.03 to 0.4% by weight as the whey protein based on the whole oil-in-water emulsion. On the other hand, if the upper limit is exceeded, the emulsion added with the sour agent tends to be difficult to foam, which is not preferable. When whey protein is used within the above range, the amount of casein protein is preferably 0.5 or less with respect to whey protein 1 and further preferably does not contain casein protein.

本発明の乳化剤としては、レシチンを添加しないで、主要な構成脂肪酸がオレイン酸であるポリグリセリン脂肪酸エステル及びHLB値が4〜15の範囲にあるショ糖脂肪酸エステルを含むことが必要である。更に、主要な構成脂肪酸がオレイン酸であるポリグリセリン脂肪酸エステルが、グリセリンの重合度が2〜10であり、エステル化度が1〜6であるのが好ましい。また、主要な構成脂肪酸がオレイン酸であるポリグリセリン脂肪酸エステルの量は水中油型乳化物全体に対して、0.02〜0.15重量%が好ましく、さらに0.04〜0.1重量%が好ましい。構成脂肪酸がオレイン酸であるポリグリセリン脂肪酸エステルの量が少ないと十分な保形性が得られ難くなり、多くなると耐酸性が弱くなり風味的にも好ましくない。
また、ショ糖脂肪酸エステルの量は、水中油型乳化物全体に対して、0.2〜1.5重量%が好ましく、さらに0.3〜1.3重量%が好ましい。ショ糖脂肪酸エステルの量が少ないと乳化安定性が悪くなり、多くなると風味的に好ましくない。
上記の乳化剤の他に、構成脂肪酸がオレイン酸でないポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、モノグリセライド、有機酸モノグリセライドなどのいわゆる合成乳化剤を併用しても良い。
As an emulsifier of the present invention, it is necessary to contain a polyglycerin fatty acid ester whose main constituent fatty acid is oleic acid and a sucrose fatty acid ester having an HLB value in the range of 4 to 15 without adding lecithin. Furthermore, it is preferable that the polyglycerol fatty acid ester whose main constituent fatty acid is oleic acid has a polymerization degree of glycerol of 2 to 10 and an esterification degree of 1 to 6. The amount of the polyglycerol fatty acid ester whose main constituent fatty acid is oleic acid is preferably 0.02 to 0.15% by weight, more preferably 0.04 to 0.1% by weight, based on the whole oil-in-water emulsion. Is preferred. When the amount of the polyglycerin fatty acid ester whose constituent fatty acid is oleic acid is small, sufficient shape retention is difficult to obtain, and when it is large, the acid resistance is weak and the flavor is not preferred.
The amount of sucrose fatty acid ester is preferably 0.2 to 1.5% by weight, more preferably 0.3 to 1.3% by weight, based on the whole oil-in-water emulsion. When the amount of the sucrose fatty acid ester is small, the emulsion stability is deteriorated, and when it is large, the flavor is not preferable.
In addition to the above-mentioned emulsifiers, so-called synthetic emulsifiers such as polyglycerin fatty acid esters whose constituent fatty acids are not oleic acid, sorbitan fatty acid esters, polyoxyethylene sorbitan fatty acid esters, propylene glycol fatty acid esters, monoglycerides, organic acid monoglycerides may be used in combination. .

本発明においては、糖類は、甘味を付与すると共に固形分の増加の働きをもつので適宜、使用してもかまわない。甘味を抑えたいときは甘味度が低いものを用いて固形分を上げることもできる。糖質の種類は限定されないが、ショ糖、麦芽糖、果糖、ブドウ糖、転化糖、混合液糖、水飴類、デキストリン類、糖アルコールの他、アスパルテーム、ステビアといった甘味付与だけを目的とした高甘味度甘味料も使用できる。   In the present invention, saccharides may be used as appropriate because they give sweetness and increase the solid content. When it is desired to suppress the sweetness, the solid content can be increased by using a low sweetness. The type of sugar is not limited, but it has high sweetness only for sweetening such as sucrose, maltose, fructose, glucose, invert sugar, mixed sugar, syrup, dextrin, sugar alcohol, aspartame, stevia Sweeteners can also be used.

本発明の水中油型乳化物については、各種塩類を使用するのが好ましく、ヘキサメタリン酸塩、第2リン酸塩、クエン酸ナトリウム、ポリリン酸塩、重曹等を単独又は2種以上混合使用することが望ましい。
その他所望により安定剤、香料、着色剤、保存料等を使用することができる。
For the oil-in-water emulsion of the present invention, it is preferable to use various salts, and hexametaphosphate, diphosphate, sodium citrate, polyphosphate, sodium bicarbonate, etc. may be used alone or in combination. Is desirable.
In addition, stabilizers, fragrances, colorants, preservatives and the like can be used as desired.

本発明の水中油型乳化物の製造法としては、一般的なクリーム類を製造する要領で行うことができる。具体的には油脂、乳清蛋白、乳化剤として構成脂肪酸がオレイン酸であるポリグリセリン脂肪酸エステル及び主要な構成脂肪酸が飽和酸であり、HLB値が4〜15の範囲にあるショ糖脂肪酸エステル及び水を主要原料とするこれらのものを混合し、予備乳化、殺菌又は滅菌処理し均質化処理することにより得ることができる。
水中油型乳化物の保存性の点で滅菌処理することが好ましい。
As a manufacturing method of the oil-in-water emulsion of this invention, it can carry out in the point which manufactures general cream. Specifically, fats and oils, whey protein, polyglycerin fatty acid ester whose constituent fatty acid is oleic acid as an emulsifier and sucrose fatty acid ester and water whose main constituent fatty acid is a saturated acid and whose HLB value is in the range of 4 to 15 Can be obtained by mixing these materials with the main raw material and pre-emulsifying, sterilizing or sterilizing and homogenizing.
It is preferable to sterilize from the viewpoint of storage stability of the oil-in-water emulsion.

滅菌処理には、間接加熱方式と直接加熱方式の2種類があり、間接加熱処理する装置としてはAPVプレート式UHT処理装置(APV株式会社製)、CP−UHT滅菌装置(クリマティー・パッケージ株式会社製)、ストルク・チューブラー型滅菌装置(ストルク株式会社製)、コンサーム掻取式UHT滅菌装置(テトラパック・アルファラベル株式会社製)等が例示できるが、特にこれらにこだわるものではない。また、直接加熱式滅菌装置としては、超高温滅菌装置(岩井機械工業(株)製)、ユーペリゼーション滅菌装置(テトラパック・アルファラバル株式会社製)、VTIS滅菌装置(テトラパック・アルファラバル株式会社製)、ラギアーUHT滅菌装置(ラギアー株式会社製)、パラリゼーター(パッシュ・アンド・シルケーボーグ株式会社製)等のUHT滅菌装置が例示でき、これらの何れの装置を使用してもよい。   There are two types of sterilization treatment: indirect heating method and direct heating method. APV plate type UHT treatment device (manufactured by APV Co., Ltd.), CP-UHT sterilization device (Climati Package Co., Ltd.) Manufactured), Stork tubular type sterilizer (manufactured by STORK Co., Ltd.), Concer scraping type UHT sterilizer (manufactured by Tetra Pak Alpha Label Co., Ltd.), etc., but not particularly limited to these. Direct heating sterilizers include ultra-high temperature sterilizers (Iwai Kikai Kogyo Co., Ltd.), operation sterilizers (Tetra Pak Alfa Laval Co., Ltd.), and VTIS sterilizers (Tetra Pak Alfa Laval Co., Ltd.). UHT sterilizers such as Ragia UHT sterilizer (manufactured by Ragia Co., Ltd.), Paralyzer (manufactured by Pash and Silkeborg Co., Ltd.), and any of these devices may be used.

以下に本発明の実施例を示し本発明をより詳細に説明するが、本発明の精神は以下の実施例に限定されるものではない。なお、例中、%及び部は、いずれも重量基準を意味する。
また、評価は以下の方法で実施した。
EXAMPLES The present invention will be described in more detail with reference to the following examples, but the spirit of the present invention is not limited to the following examples. In the examples, “%” and “part” mean weight basis.
Moreover, evaluation was implemented with the following method.

粘度:水中油型乳化物の粘度の測定は、B型粘度計(株式会社東京計器製)にて、2号ローター、30rpmの条件下で行った。
ホイップタイム:水中油型乳化物1kgをホバートミキサー(HOBART CORPORATION製 MODELN−5)3速(300rpm)にてホイップし、最適起泡状態に達するまでの時間
オーバーラン:[(一定容積の水中油型乳化物重量)−(一定容積の起泡後の起泡物重量)] ÷(一定容積の起泡後の起泡物重量)×100
レオメーター値:ホイップ後のクリームの硬さ(g/cm2)はレオメーター(不動工業製)にて直径8センチ、容量200mLカップにホイップ後のクリームを入れ、直径3センチの円盤状のプランジャーを用いて評価した。
耐酸性テスト:10%クエン酸溶液をホイップした後のクリームに対して2%添加し、へらにて均一に混ぜた後、上記のホイップ後の硬さを測定したのと同様な容器に入れ、同様なプランジャーを用いて硬さを測定した。上記のホイップ時間、オーバーラン、耐酸性テストを総合的に判断して、全体の評価を良い方から○、△、×で評価した。
Viscosity: The viscosity of the oil-in-water emulsion was measured with a B-type viscometer (manufactured by Tokyo Keiki Co., Ltd.) under the conditions of No. 2 rotor and 30 rpm.
Whip time: 1 kg of oil-in-water emulsion is hobbed at Hobart mixer (MODELN-5 manufactured by HOBART CORPORATION) at 3rd speed (300 rpm), and the time required to reach the optimum foaming state Overrun: [(Fixed volume oil-in-water type Emulsion weight)-(Foam weight after foaming a certain volume)] / (Foam weight after foaming a certain volume) × 100
Rheometer value: The hardness of the cream after whipping (g / cm 2 ) is a rheometer (made by Fudo Kogyo Co., Ltd.). The whipped cream is put into a 200 mL cup with a diameter of 3 cm. Evaluation was performed using a jar.
Acid resistance test: 10% citric acid solution was added 2% to the whipped cream, mixed evenly with a spatula, and placed in the same container as the one after measuring the hardness after whipping. Hardness was measured using a similar plunger. The above whipping time, overrun, and acid resistance test were comprehensively evaluated, and the overall evaluation was evaluated by ○, Δ, and × from the better one.

実施例1
硬化パーム核油20.0部に、テトラグリセリンモノオレート(阪本薬品工業株式会社製、商品名:グリスターMO−3S)0.04部を添加混合溶解し油相とする。
これとは別に水37.0部に、乳清蛋白(雪印乳業株式会社製、商品名:製菓原粉K、分類:ホエイパウダー、蛋白質:12.5重量%)2.0部、糖類(株式会社林原製、商品名:サンマルトシロ)40.0部、増粘剤(三栄源エフ・エフ・アイ株式会社製、商品名:サンエース)0.04部、ショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS570、HLB 5)0.6部、ヘキサメタリン酸ナトリウム0.3部、重曹0.02部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、144℃において4秒間の直接加熱方式による滅菌処理を行った後、40kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、水中油型乳化物を得た。この水中油型乳化物1kgを上記ホイップ方法にてホイップし、上記の方法に従いホイップ時間、オーバーラン、レオメーター値の測定を行い、同時に耐酸性条件でのテストも実施した。結果を表1に纏めた。
Example 1
To 20.0 parts of hardened palm kernel oil, 0.04 part of tetraglycerin monooleate (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd., trade name: Glyster MO-3S) is added and dissolved to obtain an oil phase.
Separately, 37.0 parts of water, 2.0 parts of whey protein (manufactured by Snow Brand Milk Products Co., Ltd., trade name: confectionery raw powder K, classification: whey powder, protein: 12.5% by weight), sugar (stock) Company Hayashibara, product name: San Martoshiro) 40.0 parts, thickener (manufactured by Saneigen FFI Co., Ltd., product name: Sanace) 0.04 parts, sucrose fatty acid ester (Mitsubishi Chemical Foods Co., Ltd.) , Trade name: Sugar ester S570, HLB 5) 0.6 part, 0.3 part of sodium hexametaphosphate and 0.02 part of sodium bicarbonate are dissolved to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by a direct heating method at 144 ° C. for 4 seconds using an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.). After the run, it was homogenized at a homogenization pressure of 40 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion. 1 kg of this oil-in-water emulsion was whipped by the above whipping method, and the whipping time, overrun and rheometer values were measured according to the above method, and at the same time a test under acid resistance conditions was also carried out. The results are summarized in Table 1.

実施例2〜実施例4
実施例2は、実施例1のテトラグリセリンモノオレート0.04部を0.06部に、ショ糖脂肪酸エステル0.6部を1.0部に増量し、総量が100部になる様、水の配合量にて調整した以外は、実施例1の水中油型乳化物と同様に調製し、同様な評価を行い結果を表1に纏めた。
実施例3は、実施例1の硬化パーム核油20.0部を40.0部に油脂分を高め、総量が100部になる様、水の配合量にて調整した以外は、実施例1の水中油型乳化物と同様に調製し、同様な評価を行い結果を表1に纏めた。
実施例4は、実施例1の硬化パーム核油20.0部を40.0部に油脂分を高め、糖類のサンマルトシロを削除し、総量が100部になる様、水の配合量にて調整した以外は、実施例1の水中油型乳化物と同様に調製し、同様な評価を行い結果を表1に纏めた。
Example 2 to Example 4
In Example 2, 0.04 part of tetraglycerin monooleate of Example 1 was increased to 0.06 part, 0.6 part of sucrose fatty acid ester was increased to 1.0 part, and water was added so that the total amount became 100 parts. The oil-in-water emulsion of Example 1 was prepared in the same manner as in Example 1 except that the amount was adjusted.
Example 3 is the same as Example 1 except that 20.0 parts of the hardened palm kernel oil of Example 1 was increased to 40.0 parts and the fat content was increased, and the total amount was adjusted to 100 parts by the amount of water. Were prepared in the same manner as the oil-in-water emulsion, and the same evaluation was performed. The results are summarized in Table 1.
In Example 4, 20.0 parts of the hardened palm kernel oil of Example 1 was increased to 40.0 parts, the fat and oil content was increased, and the saccharide, St. Martoshiro, was removed, and the total amount was adjusted to 100 parts by adjusting the amount of water. Except that, it was prepared in the same manner as the oil-in-water emulsion of Example 1, the same evaluation was performed, and the results are summarized in Table 1.

比較例1、比較例2
比較例1は、実施例1の乳清蛋白(雪印乳業株式会社製、商品名:製菓原粉K、分類:ホエイパウダー、蛋白質:12.5重量%)2.0部を0.01部にし、総量が100部になる様、水の配合量にて調整した以外は、実施例1の水中油型乳化物と同様に調製し、同様な評価を行い結果を表1に纏めた。
比較例2は、実施例1の乳清蛋白(雪印乳業株式会社製、商品名:製菓原粉K、分類:ホエイパウダー、蛋白質:12.5重量%)2.0部を4.0部にし、総量が100部になる様、水の配合量にて調整した以外は、実施例1の水中油型乳化物と同様に調製し、同様な評価を行い結果を表1に纏めた。
Comparative Example 1 and Comparative Example 2
In Comparative Example 1, 2.0 parts of whey protein of Example 1 (manufactured by Snow Brand Milk Products Co., Ltd., trade name: confectionery raw powder K, classification: whey powder, protein: 12.5% by weight) is 0.01 parts. The oil was prepared in the same manner as in the oil-in-water emulsion of Example 1 except that the total amount was adjusted to 100 parts, and the results were summarized in Table 1.
In Comparative Example 2, whey protein (manufactured by Snow Brand Milk Products Co., Ltd., trade name: confectionery raw powder K, classification: whey powder, protein: 12.5% by weight) of Example 1 was changed to 4.0 parts. The oil was prepared in the same manner as in the oil-in-water emulsion of Example 1 except that the total amount was adjusted to 100 parts, and the results were summarized in Table 1.

表1に実施例1〜実施例4、比較例1、比較例2の配合、評価を纏めた。

Figure 0004882749
Table 1 summarizes the formulation and evaluation of Examples 1 to 4, Comparative Example 1, and Comparative Example 2.
Figure 0004882749

比較例3
実施例1のテトラグリセリンモノオレート(阪本薬品工業株式会社製、商品名:グリスターMO−3S)0.04部をレシチン(辻製油株式会社製、商品名:SLPペースト)0.04部に代えた以外は、実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表2に纏めた。
Comparative Example 3
0.04 part of tetraglycerin monooleate (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd., trade name: Glyster MO-3S) in Example 1 was replaced with 0.04 part of lecithin (manufactured by Sakai Oil Co., Ltd., trade name: SLP paste). Except for the above, the same composition as in the oil-in-water emulsion of Example 1 was prepared in the same manner, the same evaluation was performed, and the results are summarized in Table 2.

比較例4〜比較例7
比較例4は、実施例1に乳化剤としてレシチン(辻製油株式会社製、商品名:SLPペースト)0.04部を添加した以外は、実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表2に纏めた。
比較例5は、実施例1のショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS570、HLB 5)0.6部を除き、総量が100部になる様、水の配合量にて調整した以外は、実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表2に纏めた。
比較例6は、実施例1のテトラグリセリンモノオレート(阪本薬品工業株式会社製、商品名:グリスターMO−3S)0.04部を除き、総量が100部になる様、水の配合量にて調整した以外は、実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表2に纏めた。
比較例7は、実施例1のテトラグリセリンモノオレート(阪本薬品工業株式会社製、商品名:グリスターMO−3S)0.04部をテトラグリセリンモノステアレート(阪本薬品工業株式会社製、商品名:グリスターMS−3S)0.04部に代えた以外は、実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表2に纏めた。
Comparative Example 4 to Comparative Example 7
Comparative Example 4 is the same as in Example 1 except that 0.04 part of lecithin (trade name: SLP paste, manufactured by Sakai Oil Co., Ltd.) is added as an emulsifier to Example 1. The same evaluation was performed and the results are summarized in Table 2.
Comparative Example 5 is a sucrose fatty acid ester of Example 1 (Mitsubishi Chemical Foods Co., Ltd., trade name: Sugar Ester S570, HLB 5), except for 0.6 part, so that the total amount is 100 parts. The same formulation as in the oil-in-water emulsion of Example 1 was prepared in the same manner as described in Example 1, and the same evaluation was performed. The results are summarized in Table 2.
In Comparative Example 6, except for 0.04 part of tetraglycerin monooleate (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd., trade name: Glyster MO-3S) of Example 1, the amount of water is such that the total amount becomes 100 parts. Except for the adjustment, the same formulation as in the oil-in-water emulsion of Example 1 was similarly prepared, the same evaluation was performed, and the results are summarized in Table 2.
In Comparative Example 7, 0.04 part of tetraglycerin monooleate (manufactured by Sakamoto Yakuhin Kogyo Co., Ltd., trade name: Glyster MO-3S) of Example 1 was added to tetraglycerin monostearate (Sakamoto Yakuhin Kogyo Co., Ltd., trade name: (Glister MS-3S) Except that the amount was changed to 0.04 part, the same formulation as in the oil-in-water emulsion of Example 1 was prepared in the same manner, the same evaluation was performed, and the results are summarized in Table 2.

実施例5
実施例1のテトラグリセリンモノオレート(阪本薬品工業株式会社製、商品名:グリスターMO−3S)0.04部をヘキサグリセリンモノオレート(阪本薬品工業株式会社製、商品名:グリスターMO−5S)0.04部に代えた以外は、実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表2に纏めた。
Example 5
0.04 part of tetraglycerin monooleate (trade name: Glyster MO-3S, manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.) of Example 1 was added to 0.04 part of hexaglycerin monooleate (trade name: Glyster MO-5S, manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.). 0.04 parts were prepared in the same manner as in the oil-in-water emulsion of Example 1 except that the amount was changed, and the same evaluation was performed. The results are summarized in Table 2.

表2に比較例3〜比較例7、実施例5の配合、評価を纏めた。

Figure 0004882749
Table 2 summarizes the composition and evaluation of Comparative Examples 3 to 7 and Example 5.
Figure 0004882749

比較例8〜比較例11
比較例8は、実施例1のテトラグリセリンモノオレート(阪本薬品工業株式会社製、商品名:グリスターMO−3S)0.04部をデカグリセリンモノオレート(阪本薬品工業株式会社製、商品名:グリスターMO−7S)0.04部に代えた以外は、実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表3に纏めた。
比較例9は、実施例1のショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS570、HLB 5)0.6部をショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS170、HLB 1)0.6部に代えた以外は、実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表3に纏めた。
比較例10は、実施例1のショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS570、HLB 5)0.6部をショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS270、HLB 2)0.6部に代えた以外は、実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表3に纏めた。
比較例11は、実施例1のショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS570、HLB 5)0.6部をショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS370、HLB 3)0.6部に代えた以外は、実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表3に纏めた。
Comparative Example 8 to Comparative Example 11
In Comparative Example 8, 0.04 part of tetraglycerin monooleate (produced by Sakamoto Yakuhin Kogyo Co., Ltd., trade name: Glyster MO-3S) of Example 1 was added to decaglycerin monooleate (Sakamoto Pharmaceutical Co., Ltd., trade name: Glister). (MO-7S) Except that the amount was changed to 0.04 parts, the same formulation as in the oil-in-water emulsion of Example 1 was prepared in the same manner, the same evaluation was performed, and the results are summarized in Table 3.
In Comparative Example 9, sucrose fatty acid ester of Example 1 (manufactured by Mitsubishi Chemical Foods Co., Ltd., trade name: Sugar Ester S570, HLB 5) 0.6 parts : Sugar ester S170, HLB 1) Except for replacing with 0.6 parts, the same composition as in the oil-in-water emulsion of Example 1 was prepared in the same manner, the same evaluation was performed, and the results are summarized in Table 3.
In Comparative Example 10, sucrose fatty acid ester of Example 1 (Mitsubishi Chemical Foods Co., Ltd., trade name: Sugar Ester S570, HLB 5) 0.6 part was replaced with sucrose fatty acid ester (Mitsubishi Chemical Foods Co., Ltd., trade name). : Sugar ester S270, HLB 2) Except that the amount was changed to 0.6 part, the same composition as in the oil-in-water emulsion of Example 1 was prepared in the same manner, the same evaluation was performed, and the results are summarized in Table 3.
In Comparative Example 11, sucrose fatty acid ester of Example 1 (Mitsubishi Chemical Foods Co., Ltd., trade name: Sugar Ester S570, HLB 5) 0.6 parts : Sugar ester S370, HLB 3) Except that the amount was changed to 0.6 part, the same composition as in the oil-in-water emulsion of Example 1 was prepared in the same manner, the same evaluation was performed, and the results are summarized in Table 3.

実施例6、実施例7
実施例6は、実施例1のショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS570、HLB 5)0.6部をショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS770、HLB 7)0.6部に代えた以外は、実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表3に纏めた。
実施例7は、実施例1のショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS570、HLB 5)0.6部をショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS970、HLB 9)0.6部に代えた以外は、実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表3に纏めた。
Example 6 and Example 7
In Example 6, 0.6 part of sucrose fatty acid ester of Example 1 (Mitsubishi Chemical Foods, trade name: Sugar Ester S570, HLB 5) was replaced with sucrose fatty acid ester (Mitsubishi Chemical Foods, trade name). : Sugar ester S770, HLB 7) Except that the amount was changed to 0.6 parts, the same composition as in the oil-in-water emulsion of Example 1 was prepared in the same manner, the same evaluation was performed, and the results are summarized in Table 3.
In Example 7, sucrose fatty acid ester (manufactured by Mitsubishi Chemical Foods Co., Ltd., trade name: Sugar Ester S570, HLB 5) 0.6 part of Example 1 was replaced with sucrose fatty acid ester (Mitsubishi Chemical Foods Co., Ltd., trade name). : Sugar ester S970, HLB 9) Except for replacing with 0.6 parts, the same formulation as in the oil-in-water emulsion of Example 1 was prepared in the same manner, the same evaluation was performed, and the results are summarized in Table 3.

表3に比較例8〜比較例11、実施例6、実施例7の配合、評価を纏めた。

Figure 0004882749
Table 3 summarizes the formulations and evaluations of Comparative Examples 8 to 11, Example 6, and Example 7.
Figure 0004882749

実施例8、実施例9、比較例12
実施例8は、実施例1のショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS570、HLB 5)0.6部をショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS1170、HLB 11)0.6部に代えた以外は、実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表4に纏めた。
実施例9は、実施例1のショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS570、HLB 5)0.6部をショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS1570、HLB 15)0.6部に代えた以外は、実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表4に纏めた。
比較例12は、実施例1のショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS570、HLB 5)0.6部をショ糖脂肪酸エステル(三菱化学フーズ株式会社製、商品名:シュガーエステルS1670、HLB 16)0.6部に代えた以外は、実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表4に纏めた。
Example 8, Example 9, Comparative Example 12
In Example 8, 0.6 part of sucrose fatty acid ester of Example 1 (Mitsubishi Chemical Foods, trade name: Sugar Ester S570, HLB 5) was replaced with sucrose fatty acid ester (Mitsubishi Chemical Foods, trade name). : Sugar ester S1170, HLB 11) Except that the amount was changed to 0.6 parts, the same composition as in the oil-in-water emulsion of Example 1 was prepared in the same manner, the same evaluation was performed, and the results are summarized in Table 4.
In Example 9, 0.6 part of sucrose fatty acid ester of Example 1 (Mitsubishi Chemical Foods, trade name: Sugar Ester S570, HLB 5) was replaced with sucrose fatty acid ester (Mitsubishi Chemical Foods, trade name). : Sugar ester S1570, HLB 15) Except for 0.6 parts, the same formulation as in the oil-in-water emulsion of Example 1 was prepared in the same manner, the same evaluation was performed, and the results are summarized in Table 4.
Comparative Example 12 is a sucrose fatty acid ester (manufactured by Mitsubishi Chemical Foods, Inc., trade name: Sugar Ester S570, HLB 5) 0.6 part of sucrose fatty acid ester (Mitsubishi Chemical Foods, Inc., trade name). : Sugar ester S1670, HLB 16) Except that the amount was changed to 0.6 part, the same composition as in the oil-in-water emulsion of Example 1 was prepared in the same manner, the same evaluation was performed, and the results are summarized in Table 4.

比較例13〜比較例15
比較例13は、実施例1の乳清蛋白(雪印乳業株式会社製、商品名:製菓原粉K、分類:ホエイパウダー、蛋白質:12.5重量%)2.0部を脱脂粉乳(よつ葉乳業株式会社製、商品名:脱脂粉乳)4.0部にし、総量が100部になる様、水の配合量にて調整し、それ以外は実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表4に纏めた。
比較例14は、実施例1の乳清蛋白(雪印乳業株式会社製、商品名:製菓原粉K、分類:ホエイパウダー、蛋白質:12.5重量%)2.0部を脱脂粉乳(よつ葉乳業株式会社製、商品名:脱脂粉乳)0.8部にし、総量が100部になる様、水の配合量にて調整し、それ以外は実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表4に纏めた。
比較例15は、実施例1の乳清蛋白(雪印乳業株式会社製、商品名:製菓原粉K、分類:ホエイパウダー、蛋白質:12.5重量%)2.0部をカゼインナトリウム(太陽化学株式会社製、商品名:サンラクトS12、蛋白質:85.8重量%)0.3部にし、総量が100部になる様、水の配合量にて調整し、それ以外は実施例1の水中油型乳化物と同様な配合で同様に調製し、同様な評価を行い結果を表4に纏めた。
Comparative Example 13 to Comparative Example 15
In Comparative Example 13, whey protein of Example 1 (manufactured by Snow Brand Milk Products Co., Ltd., trade name: confectionery raw powder K, classification: whey powder, protein: 12.5% by weight) 2.0 parts skim milk powder (Yotsuba Milk Industry) Co., Ltd., trade name: nonfat dry milk) 4.0 parts, adjusted with the amount of water so that the total amount is 100 parts, otherwise the same composition as the oil-in-water emulsion of Example 1 Preparations were made in the same manner, similar evaluations were performed, and the results are summarized in Table 4.
In Comparative Example 14, whey protein of Example 1 (manufactured by Snow Brand Milk Products Co., Ltd., trade name: confectionery raw powder K, classification: whey powder, protein: 12.5% by weight) 2.0 parts skim milk powder (Yotsuba Milk Industry) Co., Ltd., trade name: nonfat dry milk) adjusted to 0.8 parts and adjusted with the amount of water so that the total amount is 100 parts, otherwise the same composition as the oil-in-water emulsion of Example 1 Preparations were made in the same manner, similar evaluations were performed, and the results are summarized in Table 4.
In Comparative Example 15, whey protein of Example 1 (manufactured by Snow Brand Milk Products Co., Ltd., trade name: confectionery raw powder K, classification: whey powder, protein: 12.5% by weight) 2.0 parts of sodium caseinate (Taiyo Kagaku) (Product name: Sanlacto S12, protein: 85.8% by weight) 0.3 parts and adjusted with the amount of water so that the total amount becomes 100 parts, otherwise the oil-in-water of Example 1 The same formulation as in the type emulsion was prepared in the same manner, the same evaluation was performed, and the results are summarized in Table 4.

表4に実施例8、実施例9、比較例12〜比較例15の配合、評価を纏めた。

Figure 0004882749
Table 4 summarizes the formulations and evaluations of Example 8, Example 9, and Comparative Examples 12 to 15.
Figure 0004882749

本発明は、水中油型乳化物(クリームとも言う)に関し、詳しくはあっさりした風味の水中油型乳化物であって、通常のクリームとしての他、酸性の原材料即ち果実、果汁、ヨーグルト、各種の酸味量等をホイップ操作の段階で混合しても、クリームが増粘、固化することなく、ホイップしてもオーバーランが低下せず、ホイップ後のシマリモドリのない耐酸性の水中油型乳化物に関するものである。   The present invention relates to an oil-in-water emulsion (also referred to as a cream), and more particularly, a light-flavored oil-in-water emulsion, which is an ordinary raw material such as fruit, fruit juice, yogurt It relates to an acid-resistant oil-in-water emulsion that does not have a thickening or solidifying cream, does not decrease overrun even if it is whipped, and does not have scallops after whipping. Is.

Claims (3)

水、油脂、乳清蛋白、乳化剤を含む水中油型乳化物において、乳清蛋白質を0.03〜0.4重量%含み、カゼイン蛋白質を含まないで、乳化剤としてレシチンを添加しないで、主要な構成脂肪酸がオレイン酸であるポリグリセリン脂肪酸エステル及びHLB値が4〜15の範囲にあるショ糖脂肪酸エステルを含み、当該ポリグリセリン脂肪酸エステルがグリセリンの重合度が2〜10であり、エステル化度が1〜6であることを特徴とする水中油型乳化物。Water, fat, whey protein, oil-in-water emulsion containing an emulsifier, a whey protein 0.03 to 0.4 wt% seen including, without including casein protein, without the addition of lecithin as an emulsifier, the primary Do constituent fatty acid is oleic acid polyglycerin fatty acid ester and HLB values observed contains a sucrose fatty acid ester in the range of 4 to 15, the polyglycerol fatty acid ester is the degree of polymerization of glycerin is 2 to 10, esterified An oil-in-water emulsion having a degree of 1 to 6 . 水中油型乳化物が耐酸性を有する、請求項1記載の水中油型乳化物。The oil-in-water emulsion according to claim 1, wherein the oil-in-water emulsion has acid resistance. 水中油型乳化物が起泡性を有する、請求項1又は請求項2記載の水中油型乳化物。The oil-in-water emulsion according to claim 1 or 2, wherein the oil-in-water emulsion has foamability.
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