JP6788762B2 - Foamable oil-in-water emulsified oil / fat composition - Google Patents

Foamable oil-in-water emulsified oil / fat composition Download PDF

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JP6788762B2
JP6788762B2 JP2020511071A JP2020511071A JP6788762B2 JP 6788762 B2 JP6788762 B2 JP 6788762B2 JP 2020511071 A JP2020511071 A JP 2020511071A JP 2020511071 A JP2020511071 A JP 2020511071A JP 6788762 B2 JP6788762 B2 JP 6788762B2
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涼輔 宮本
涼輔 宮本
敏秀 磯部
敏秀 磯部
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L9/00Puddings; Cream substitutes; Preparation or treatment thereof
    • A23L9/20Cream substitutes

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Description

本発明は、起泡性水中油型乳化油脂組成物、及び、該組成物がホイップされたホイップドクリームに関する。 The present invention relates to a foamable oil-in-water emulsified oil / fat composition and a whipped cream to which the composition is whipped.

ホイップドクリームは、起泡性水中油型乳化油脂組成物を起泡させて製造される。該起泡性水中油型乳化油脂組成物には良好な乳化安定性(原液安定性)と起泡性が求められ、かつ、得られるホイップドクリームにはシャープな口溶けと良好なコクが求められる。さらに、ホイップドクリームには保存中、経時的に水が遊離してくる場合があるが、そのような水の遊離が少ないこと、すなわち離水耐性が求められる。 The whipped cream is produced by foaming a foaming oil-in-water emulsified oil / fat composition. The foamable oil-in-water emulsified oil / fat composition is required to have good emulsion stability (undiluted solution stability) and foaming property, and the obtained whipped cream is required to have sharp melting in the mouth and good richness. .. Further, the whipped cream may release water over time during storage, and such water release is small, that is, water separation resistance is required.

一方、近年の健康志向により、ホイップドクリーム中のトランス脂肪酸や飽和脂肪酸含量の低減が求められている。トランス脂肪酸や飽和脂肪酸の含量を低減した起泡性水中油型乳化油脂組成物を製造するためには、その原料油脂として各種エステル交換油を用いる手法が知られている。しかし、エステル交換油を配合すると、コストが増大することに加えて、ホイップドクリームのコクが不足する傾向があった。 On the other hand, due to recent health consciousness, reduction of trans fatty acid and saturated fatty acid contents in whipped cream is required. In order to produce a foamable oil-in-water emulsified oil / fat composition having a reduced content of trans fatty acids and saturated fatty acids, a method of using various transesterified oils as the raw material oil / fat is known. However, when a transesterified oil is added, the cost tends to increase and the richness of the whipped cream tends to be insufficient.

また、起泡性水中油型乳化油脂組成物の乳化状態を安定させる目的で、該組成物にタンパク質溶融塩を配合することが行なわれているが、これを配合すると、食した時に苦みが感じられ、また、健康上の懸念も生じる。 Further, for the purpose of stabilizing the emulsified state of the foamable oil-in-water emulsified oil / fat composition, a protein molten salt is blended in the composition, but when this is blended, bitterness is felt when eating. And also raises health concerns.

特許文献1では、エステル交換油、タンパク質溶融塩及びトランス脂肪酸を実質的に含まず、かつ、飽和脂肪酸の含有量も低減しているにも関わらず、所定量のパーム油中融点部(PMF)とパーム油分別液状部を併用して起泡性水中油型乳化油脂組成物を構成することで、原液安定性が良好になり、コクと口溶けが良好なホイップドクリームが得られることが開示されている。 In Patent Document 1, although the transesterification oil, the molten protein salt and the trans fatty acid are substantially not contained and the content of the saturated fatty acid is also reduced, a predetermined amount of the melting point in palm oil (PMF) It is disclosed that by constructing a foamable oil-in-water emulsified oil / fat composition in combination with a transesterified liquid portion of palm oil, the stability of the undiluted solution is improved and a whipped cream having good richness and good melting in the mouth can be obtained. ing.

特開2016−202132号公報Japanese Unexamined Patent Publication No. 2016-20132

本発明者らが検討したところ、特許文献1に開示された起泡性水中油型乳化油脂組成物では、得られるホイップドクリームに乳化剤特有の異味が感じられ風味の点で問題があり、また、起泡性や離水耐性も十分ではないという問題があった。 As a result of examination by the present inventors, in the foamable oil-in-water emulsified oil / fat composition disclosed in Patent Document 1, the obtained whipped cream has a strange taste peculiar to an emulsifier, and there is a problem in terms of flavor. There was a problem that the foaming property and water separation resistance were not sufficient.

本発明は、上記現状に鑑み、タンパク質溶融塩及びエステル交換油を実質的に含有せず、トランス脂肪酸と飽和脂肪酸の含有量がそれぞれ少ない起泡性水中油型乳化油脂組成物であるにも関わらず、パーム油中融点部を多く配合しても、起泡性と原液安定性の双方が良好であり、かつ、ホイップされたホイップドクリームが良好な離水耐性、口溶け、及びコクを有し、乳化剤特有の異味が抑制された起泡性水中油型乳化油脂組成物、並びに、該組成物がホイップされたホイップドクリームを提供することである。 In view of the above situation, the present invention is a foamable oil-in-water emulsified oil / fat composition which does not substantially contain molten protein salt and ester exchange oil and has a low content of trans fatty acid and saturated fatty acid, respectively. However, even if a large amount of the melting point in palm oil is blended, both foaming property and stock solution stability are good, and the whipped cream has good water separation resistance, melting in the mouth, and richness. It is an object of the present invention to provide a foaming oil-in-water emulsified oil / fat composition in which an unpleasant taste peculiar to an emulsifier is suppressed, and a whipped cream in which the composition is whipped.

本発明者らは上記課題を解決するために鋭意研究を重ねた結果、タンパク質溶融塩及びエステル交換油を実質的に含有しなくても、油脂、カゼインタンパク質、ラウリン系油脂、パーム油中融点部、パームオレイン、及びハイエルシン菜種極度硬化油を特定量含み、カリウムとナトリウムの合計含有量が特定の範囲にあり、前記油脂の構成脂肪酸にトランス脂肪酸を実質的に含まず、特定量の飽和脂肪酸を含み、また、特定の不飽和脂肪酸の結合した特定の乳化剤を特定量含む起泡性水中油型乳化油脂組成物は、起泡性と原液安定性の双方が良好であり、かつ、当該起泡性水中油型乳化油脂組成物をホイップすることで好ましい離水耐性を有し、口溶けとコクが良好で、乳化剤特有の異味が抑制されたホイップドクリームが得られることを見出し、本発明を完成するに至った。 As a result of intensive studies to solve the above problems, the present inventors have conducted diligent studies, and as a result, fats and oils, casein proteins, laurin-based fats and oils, and melting points in palm oil, even if they do not substantially contain molten protein salts and ester-exchanged oils. , Palm olein, and hyelsin rapeseed extremely hardened oil, the total content of potassium and sodium is in a specific range, and the constituent fatty acids of the fats and oils are substantially free of trans fatty acids and contain a specific amount of saturated fatty acids. The foamable oil-in-water emulsified oil / fat composition containing a specific amount of a specific emulsifier to which a specific unsaturated fatty acid is bound has good foaming property and undiluted solution stability, and the foaming property is said to be good. The present invention is completed by finding that whipping an oil-in-water emulsified oil / fat composition gives a whipped cream having preferable water separation resistance, good melting in the mouth and richness, and suppressing an off-taste peculiar to an emulsifier. It came to.

即ち、本発明の第一は、起泡性水中油型乳化油脂組成物全体中、タンパク質溶融塩含有量が0.02重量%未満であり、油脂を25〜50重量%含有し、カゼインタンパク質を0.5〜1.3重量%含有し、カリウムとナトリウムとの合計含有量が0.028〜0.15重量%であり、かつ、C16〜C22の不飽和脂肪酸の結合した脂肪酸エステルである少なくとも1種の乳化剤の合計含有量が0.01〜0.055重量%であり、前記油脂全体中、エステル交換油含有量が1重量%未満であり、ラウリン系油脂を3.7〜25重量%、パーム油中融点部を25〜80重量%、パームオレインを15〜65重量%、及び、ハイエルシン菜種極度硬化油を0.3〜1.8重量%含有し、前記油脂の構成脂肪酸全体中、トランス脂肪酸含有量が1重量%未満で、かつ飽和脂肪酸含有量が47〜65重量%である、起泡性水中油型乳化油脂組成物に関する。好ましくは、起泡性水中油型乳化油脂組成物全体中、カリウムとナトリウムとの合計含有量がカルシウムの含有量に対して1.5〜2.9である。また、好ましくは、前記パーム油中融点部と前記パームオレインとの合計含有量が前記油脂全体中73.2〜96重量%である。That is, the first of the present invention is that the content of the molten protein salt is less than 0.02% by weight, the fat and oil is contained in 25 to 50% by weight, and the casein protein is contained in the whole foamable oil-in-water emulsified fat and oil composition. A fatty acid ester containing 0.5 to 1.3% by weight, having a total content of potassium and sodium of 0.028 to 0.15% by weight, and having a C 16 to C 22 unsaturated fatty acid bound thereto. The total content of at least one emulsifier is 0.01 to 0.055% by weight, the ester exchange oil content is less than 1% by weight in the whole fat and oil, and the laurin-based fat and oil is 3.7 to 25% by weight. It contains 25 to 80% by weight of the melting point in palm oil, 15 to 65% by weight of palm olein, and 0.3 to 1.8% by weight of highly hydrogenated hyelsin rapeseed, and all of the constituent fatty acids of the fat and oil. Among them, the present invention relates to a foamable oil-in-water emulsified oil / fat composition having a trans fatty acid content of less than 1% by weight and a saturated fatty acid content of 47 to 65% by weight. Preferably, the total content of potassium and sodium in the entire foamable oil-in-water emulsified fat composition is 1.5 to 2.9 with respect to the calcium content. Further, preferably, the total content of the melting point in the palm oil and the palm olein is 73.2 to 96% by weight in the whole oil and fat.

本発明の第二は、前記起泡性水中油型乳化油脂組成物がホイップされたホイップドクリームに関する The second aspect of the present invention relates to a whipped cream in which the foaming oil-in-water emulsified oil / fat composition is whipped.

本発明に従えば、タンパク質溶融塩及びエステル交換油を実質的に含有せず、トランス脂肪酸と飽和脂肪酸の含有量がそれぞれ少ない起泡性水中油型乳化油脂組成物であるにも関わらず、パーム油中融点部を多く配合しても、起泡性と原液安定性の双方が良好であり、かつ、ホイップされたホイップドクリームが良好な離水耐性、口溶け、及びコクを有し、乳化剤特有の異味が抑制された起泡性水中油型乳化油脂組成物、並びに、該組成物がホイップされたホイップドクリームを提供することができる。 According to the present invention, the palm is a foamable oil-in-water emulsified oil / fat composition that does not substantially contain molten protein salt and ester exchange oil and has a low content of trans fatty acid and saturated fatty acid. Even if a large amount of melting point in oil is blended, both foaming property and stock solution stability are good, and the whipped cream has good water separation resistance, melting in the mouth, and richness, which is peculiar to emulsifiers. It is possible to provide a foamable oil-in-water emulsified oil / fat composition in which the off-taste is suppressed, and a whipped cream in which the composition is whipped.

以下、本発明につき、さらに詳細に説明する。
本発明の起泡性水中油型乳化油脂組成物は、油脂と必要に応じて油脂以外の油溶性原料とを含む油相、及び、水と必要に応じて水溶性原料とを含む水相を含む、水中油型の乳化物である。当該起泡性水中油型乳化油脂組成物は、起泡性を示すものであり、これをホイップし、起泡させることにより、本発明のホイップドクリームを得ることができる。なお、油脂とは、1分子のグリセリンに対し3分子の脂肪酸がエステル結合してなるトリグリセリドのことをいう。トリグリセリドを構成している前記脂肪酸を、構成脂肪酸という。
Hereinafter, the present invention will be described in more detail.
The foamable oil-in-water emulsified oil / fat composition of the present invention comprises an oil phase containing an oil and fat and, if necessary, an oil-soluble raw material other than the oil and fat, and an aqueous phase containing water and, if necessary, a water-soluble raw material. It is an oil-in-water emulsion containing. The foamable oil-in-water emulsified oil / fat composition exhibits foaming property, and the whipped cream of the present invention can be obtained by whipping and foaming the composition. The fat and oil refers to a triglyceride in which three molecules of fatty acid are ester-bonded to one molecule of glycerin. The fatty acids that make up triglycerides are called constituent fatty acids.

本発明の起泡性水中油型乳化油脂組成物は、タンパク質溶融塩やエステル交換油を実質的に含有せず、油脂、カゼインタンパク質、ラウリン系油脂、パーム油中融点部、パームオレイン、及び、ハイエルシン菜種極度硬化油を特定量含み、カリウムとナトリウムの合計含有量が特定の範囲にあり、前記油脂の構成脂肪酸にトランス脂肪酸を実質的に含まず、特定量の飽和脂肪酸を含み、また、特定の不飽和脂肪酸の結合した特定の乳化剤を特定量含むことが特徴である。 The foamable oil-in-water emulsified oil / fat composition of the present invention does not substantially contain molten protein salts or ester-exchanged oils, and contains fats and oils, casein proteins, laurin-based fats and oils, melting point in palm oil, palm olein, and Hyelsin rapeseed contains a specific amount of extremely hydrogenated oil, the total content of potassium and sodium is in a specific range, and the constituent fatty acids of the fats and oils do not substantially contain trans fatty acids, but contain a specific amount of saturated fatty acids, and are also specified. It is characterized by containing a specific amount of a specific emulsifier to which the unsaturated fatty acid of the above is bound.

前記タンパク質溶融塩とは、通常ホイップドクリームの原液(起泡性水中油型乳化油脂組成物)の乳化安定剤として用いられる溶融塩のことであり、具体的には、リン酸ナトリウム、ポリリン酸ナトリウム、トリポリリン酸ナトリウム、メタリン酸ナトリウム、ヘキサメタリン酸ナトリウム等のリン酸塩や、クエン酸三ナトリウム、クエン酸一カリウム、クエン酸三カリウム等のクエン酸塩が挙げられる。更に、炭酸や、コハク酸、乳酸、酢酸等の有機酸のアルカリ金属塩も挙げられる。このようなタンパク質溶融塩は、摂取しすぎると健康を損なう場合があるため、本発明の起泡性水中油型乳化油脂組成物中のタンパク質溶融塩含有量は少ないほど好ましく、具体的には、タンパク質溶融塩は、起泡性水中油型乳化油脂組成物の全体中0.02重量%未満の範囲で含まれるか、又は全く含まれないことが好ましく、全く含まれないことがより好ましい。 The protein molten salt is a molten salt usually used as an emulsification stabilizer for a stock solution of whipped cream (foamable oil-in-water emulsified oil / fat composition), and specifically, sodium phosphate and polyphosphoric acid. Phosphates such as sodium, sodium tripolyphosphate, sodium metaphosphate, sodium hexametaphosphate, and citrates such as trisodium citrate, monopotassium citrate, and tripotassium citrate can be mentioned. Further, alkali metal salts of carbonic acid and organic acids such as succinic acid, lactic acid and acetic acid can be mentioned. Since such a molten protein salt may impair health if it is ingested too much, it is preferable that the content of the molten protein salt in the foamable oil-in-water emulsified oil / fat composition of the present invention is small. The molten protein salt is preferably contained in the range of less than 0.02% by weight, or more preferably not contained at all, in the total amount of the foamable oil-in-water emulsified oil / fat composition.

本発明の起泡性水中油型乳化油脂組成物は、油脂を、前記組成物全体中、合計で25〜50重量%含有することが好ましく、32〜45重量%含有することがより好ましい。油脂の含有量が25重量%より少ないと起泡性が悪化する場合があり、50重量%より多いと原液安定性が悪化し、ボテと呼ばれる現象が起こる場合がある。 The foamable oil-in-water emulsified oil / fat composition of the present invention preferably contains 25 to 50% by weight, more preferably 32 to 45% by weight, of the oil / fat in the entire composition. If the content of fats and oils is less than 25% by weight, the foaming property may be deteriorated, and if it is more than 50% by weight, the stability of the undiluted solution may be deteriorated and a phenomenon called botting may occur.

起泡性や、得られるホイップドクリームのコクの観点から、エステル交換油の含有量は少ないほど好ましい。ここで、エステル交換油とは、食用油脂をエステル交換反応して得られる油脂を指す。前記食用油脂としては菜種油、コーン油、綿実油、パーム油、パーム核油、ヤシ油、大豆油、ひまわり油、サフラワー油、オリーブ油等の植物性油脂や、乳脂肪、牛脂、豚脂、魚油等の動物性油脂が例示でき、これらを硬化、分別、エステル交換等の加工処理を行ったものも用いることができる。前記エステル交換油の製法については特に限定なく、常法を用いて製造することができる。例えば、ナトリウムメチラートまたはナトリウムエチラートを原料油脂に対して0.01〜1.0重量%添加してランダムエステル交換反応を起こす化学法や、リパーゼなどの酵素を用いてエステル交換を行なう酵素法などを適用できる。 From the viewpoint of foaming property and the richness of the obtained whipped cream, the smaller the content of the transesterified oil is, the more preferable. Here, the transesterified oil refers to an oil or fat obtained by transesterifying an edible oil or fat. Examples of the edible oils and fats include vegetable oils and fats such as rapeseed oil, corn oil, cottonseed oil, palm oil, palm kernel oil, coconut oil, soybean oil, sunflower oil, saflower oil and olive oil, milk fat, beef tallow, lard, fish oil and the like. Examples of animal fats and oils from the above can be used, and those obtained by processing such as hardening, sorting, and ester exchange can also be used. The method for producing the transesterified oil is not particularly limited, and it can be produced using a conventional method. For example, a chemical method in which 0.01 to 1.0% by weight of sodium methylate or sodium ethylate is added to a raw material fat or oil to cause a random transesterification reaction, or an enzyme method in which transesterification is carried out using an enzyme such as lipase. Etc. can be applied.

具体的には、エステル交換油は、本発明の起泡性水中油型乳化油脂組成物に含まれる油脂全体中1重量%未満の範囲で含まれるか、又は全く含まれないことが好ましく、全く含まれないことがより好ましい。エステル交換油の含有量が1重量%以上であると、コストがアップしたり、起泡性が低下したり、ホイップドクリームのコクが不足する場合がある。 Specifically, the transesterified oil is preferably contained in the range of less than 1% by weight or not contained in the total amount of the oil and fat contained in the foamable oil-in-water emulsified oil and fat composition of the present invention, and is not contained at all. It is more preferable that it is not contained. If the content of the transesterification oil is 1% by weight or more, the cost may increase, the foaming property may decrease, or the richness of the whipped cream may be insufficient.

本発明の起泡性水中油型乳化油脂組成物に含まれる油脂は、少なくとも、ラウリン系油脂、パーム油中融点部、パームオレイン、及び、ハイエルシン菜種極度硬化油を含有する。 The fats and oils contained in the foamable oil-in-water emulsified fats and oils composition of the present invention contain at least lauric-based fats and oils, a melting point in palm oil, palm olein, and hyelsin rapeseed extremely hydrogenated oil.

ラウリン系油脂とは、構成脂肪酸としてラウリン酸を多く含む油脂をいい、具体的には構成脂肪酸中のラウリン酸含有量が概ね35重量%以上の油脂であればよく、例えば、パーム核油、ヤシ油、及びこれらの分別油や硬化油等が挙げられる。ラウリン系油脂は特に油脂の結晶性やホイップドクリームの口溶けの観点から配合される油脂成分である。ラウリン系油脂の含有量は、前記油脂全体中3.7〜25重量%であることが好ましく、5〜20重量%がより好ましい。ラウリン系油脂の含有量が3.7重量%より少ないと、原液安定性が悪化し、また、ホイップドクリームの口溶けが悪化する場合があり、25重量%より多いとコストがアップし過ぎる場合がある。 Lauric acid-based fats and oils are fats and oils containing a large amount of lauric acid as constituent fatty acids. Specifically, fats and oils having a lauric acid content of approximately 35% by weight or more in the constituent fatty acids may be used, for example, palm kernel oil and coconut oil. Examples thereof include oils and their fractionated oils and hydrogenated oils. Lauric-based fats and oils are fats and oils components that are blended especially from the viewpoint of the crystallinity of fats and oils and the melting of whipped cream in the mouth. The content of the lauric-based fat and oil is preferably 3.7 to 25% by weight, more preferably 5 to 20% by weight, based on the total amount of the fat and oil. If the content of lauric oil is less than 3.7% by weight, the stability of the undiluted solution may deteriorate and the melting of whipped cream in the mouth may worsen, and if it is more than 25% by weight, the cost may increase too much. is there.

パーム油中融点部とは、パーム油を、食用油脂に一般的に適用される分別方法、例えば多段階分別や溶剤分別に供して得られ、且つエステル交換されていない中融点部である。より具体的には、分別時の温度において固体の成分であって、上昇融点が25〜32℃程度を示す成分をいう。しかし本発明の効果を奏する限り、中融点部の上昇融点はこの範囲に限定されない。 The melting point in palm oil is a melting point in palm oil obtained by subjecting palm oil to a fractionation method generally applied to edible oils and fats, for example, multi-step fractionation or solvent fractionation, and not transesterified. More specifically, it refers to a component that is a solid at the temperature at the time of fractionation and has an elevated melting point of about 25 to 32 ° C. However, as long as the effect of the present invention is exhibited, the rising melting point of the middle melting point portion is not limited to this range.

パーム油中融点部の含有量は、前記油脂全体中25〜80重量%であることが好ましく、50〜75重量%がより好ましい。パーム油中融点部の含有量が25重量%より少ないと離水耐性が悪化したり、起泡性やホイップドクリームの口溶けが悪化する場合があり、80重量%より多いと口溶けが悪化する場合がある。 The content of the melting point in palm oil is preferably 25 to 80% by weight, more preferably 50 to 75% by weight, based on the total amount of the fat and oil. If the content of the melting point in palm oil is less than 25% by weight, the water separation resistance may deteriorate, the foaming property and the melting of whipped cream in the mouth may deteriorate, and if it is more than 80% by weight, the melting in the mouth may deteriorate. is there.

パームオレインとは、パームの果肉から採取した油脂を分別して得られる液状部であって、ヨウ素価が55以上のものをいう。パームオレインは主にホイップドクリームの口溶けを向上させるために配合される。特に本発明の起泡性水中油型乳化油脂組成物ではラウリン系油脂の含有量を低減しているが、単にラウリン系油脂を減らすとホイップドクリームの口溶けが悪化しやすい。しかし本発明ではパームオレインを配合することで、ホイップドクリームの口溶けを改善することができる。 Palm olein is a liquid portion obtained by separating fats and oils collected from the pulp of palm, and has an iodine value of 55 or more. Palm olein is mainly formulated to improve the melting of whipped cream in the mouth. In particular, in the foamable oil-in-water emulsified oil / fat composition of the present invention, the content of lauric-based oil / fat is reduced, but simply reducing the amount of lauric-based oil / fat tends to worsen the melting of the whipped cream in the mouth. However, in the present invention, the melting of whipped cream in the mouth can be improved by blending palm olein.

パームオレインの含有量は、前記油脂全体中15〜65重量%であることが好ましく、16.5〜39重量%がより好ましく、20〜37重量%が更に好ましい。パームオレインの含有量が15重量%より少ないとホイップドクリームの口溶けが悪化する場合があり、65重量%より多いと離水耐性が悪化する場合がある。 The content of palm olein is preferably 15 to 65% by weight, more preferably 16.5 to 39% by weight, still more preferably 20 to 37% by weight in the whole fats and oils. If the content of palm olein is less than 15% by weight, the melting of the whipped cream in the mouth may be deteriorated, and if it is more than 65% by weight, the water separation resistance may be deteriorated.

また、前記パーム油中融点部と前記パームオレインとの合計含有量は、前記油脂全体中73.2〜96重量%であることが好ましく、80〜90重量%がより好ましい。該合計量が73.2重量%より少ないとコストがアップし過ぎる場合があり、96重量%より多いと原液安定性が悪化し、ボテと呼ばれる現象が起こる場合がある。 The total content of the melting point in palm oil and the palm olein is preferably 73.2 to 96% by weight, more preferably 80 to 90% by weight, based on the total amount of the fat and oil. If the total amount is less than 73.2% by weight, the cost may increase too much, and if it is more than 96% by weight, the stability of the undiluted solution deteriorates and a phenomenon called botting may occur.

ハイエルシン菜種極度硬化油とは、菜種の中でもエルシン酸(エルカ酸)含量が概ね40%以上の品種から搾油した油脂を極度硬化したものをいう。ハイエルシン菜種極度硬化油を配合することによって、ホイップドクリームの良好なコクを維持しながら、起泡性とホイップドクリームの離水耐性を改善することができる。 High-erucine rapeseed extremely hydrogenated oil refers to oil and fat squeezed from varieties having an erucic acid (erucic acid) content of approximately 40% or more among rapeseed. By blending Hyelsin rapeseed extremely hydrogenated oil, it is possible to improve the foaming property and the water separation resistance of the whipped cream while maintaining the good richness of the whipped cream.

ハイエルシン菜種極度硬化油の含有量は、前記油脂全体中0.3〜1.8重量%であることが好ましく、0.8〜1.5重量%がより好ましい。ハイエルシン菜種極度硬化油の含有量が0.3重量%より少ないと起泡性や離水耐性が悪化する場合があり、1.8重量%より多いと原液安定性が悪化する場合がある。このように微量のハイエルシン菜種極度硬化油を配合することで、乳化界面付近でハイエルシン菜種極度硬化油由来のトリグリセリドが結晶化して油滴同士が合一しやすくなり、ホイップ構造も強固になるため、起泡性と離水耐性を改善することができると推測される。 The content of the hyelsin rapeseed extremely hydrogenated oil is preferably 0.3 to 1.8% by weight, more preferably 0.8 to 1.5% by weight, based on the total amount of the oil and fat. If the content of the hyelsin rapeseed extremely hydrogenated oil is less than 0.3% by weight, the foaming property and water separation resistance may be deteriorated, and if it is more than 1.8% by weight, the stability of the undiluted solution may be deteriorated. By blending a small amount of Hyelsin rapeseed extremely hydrogenated oil in this way, the triglyceride derived from Hyelsin rapeseed extremely hydrogenated oil crystallizes near the emulsification interface, making it easier for the oil droplets to coalesce and strengthening the whip structure. It is presumed that foaming property and water separation resistance can be improved.

健康上の観点から、本発明の起泡性水中油型乳化油脂組成物に含まれる油脂の構成脂肪酸として、トランス脂肪酸を多量に含有しないことが好ましい。ここで、トランス脂肪酸とは、トランス型の二重結合を持つ不飽和脂肪酸のことをいう。具体的には、トランス脂肪酸は、前記油脂の構成脂肪酸全体中1重量%未満の範囲を占めるように構成脂肪酸として含まれるか、又は含まれないことが好ましく、全く含まれないことがより好ましい。なお、トランス脂肪酸の含有割合を少なくするには、本発明の起泡性水中油型乳化油脂組成物に配合する部分硬化油の量を低減すればよい。 From the viewpoint of health, it is preferable that the constituent fatty acids of the fats and oils contained in the foamable oil-in-water emulsified fat and oil composition of the present invention do not contain a large amount of trans fatty acids. Here, the trans fatty acid refers to an unsaturated fatty acid having a trans-type double bond. Specifically, the trans fatty acid is preferably contained or not contained as a constituent fatty acid so as to occupy a range of less than 1% by weight in the total constituent fatty acids of the fat and oil, and more preferably not contained at all. In order to reduce the content ratio of trans fatty acids, the amount of partially hydrogenated oil to be blended in the foamable oil-in-water emulsified oil / fat composition of the present invention may be reduced.

同じく健康上の観点から、前記油脂の構成脂肪酸として、飽和脂肪酸の含有量はできるだけ減らすことが好ましい。具体的には、飽和脂肪酸は、前記油脂の構成脂肪酸全体中47〜65重量%であることが好ましく、50〜60重量%がより好ましい。飽和脂肪酸の含有量が47重量%より少ないと起泡性が悪化する場合があり、65重量%より多いと健康上好ましくない場合がある。 Similarly, from the viewpoint of health, it is preferable to reduce the content of saturated fatty acids as constituent fatty acids of the fats and oils as much as possible. Specifically, the saturated fatty acid is preferably 47 to 65% by weight, more preferably 50 to 60% by weight, based on the total constituent fatty acids of the fat and oil. If the content of saturated fatty acid is less than 47% by weight, the foaming property may be deteriorated, and if it is more than 65% by weight, it may be unfavorable for health.

本発明の起泡性水中油型乳化油脂組成物に含まれる油脂は、本発明の効果を阻害しない範囲において、上述したラウリン系油脂、パーム油中融点部、パームオレイン、及び、ハイエルシン菜種極度硬化油以外の他の食用油脂を含有するものであってもよい。そのような他の食用油脂としては、ホイップドクリームに用いられ得るものであれば特に限定はなく、例えば、菜種油、大豆油、サフラワー油、コーン油、米油、綿実油、パーム油中融点部およびパームオレインを除くパーム系油脂などの植物油脂や、乳脂肪、豚脂などの動物油脂、および、これらの油脂の分別油、硬化油、エステル交換油やそれらの混合油などが挙げられる。 The fats and oils contained in the foamable oil-in-water emulsified fat and oil composition of the present invention are extremely cured of the above-mentioned lauric-based fats and oils, melting point in palm oil, palm olein, and hyelsin rapeseed, as long as the effects of the present invention are not impaired. It may contain edible oils and fats other than oil. Such other edible oils and fats are not particularly limited as long as they can be used for whipped cream, and for example, rapeseed oil, soybean oil, safflower oil, corn oil, rice oil, cottonseed oil, and palm oil medium melting point. Examples thereof include vegetable oils and fats such as palm-based oils and fats other than palm olein, animal fats and oils such as milk fat and pork fat, and fractionated oils, hydrogenated oils, ester exchange oils and mixed oils thereof of these fats and oils.

本発明の起泡性水中油型乳化油脂組成物はカゼインタンパク質を含有する。カゼインタンパク質を含有することにより、原液安定性を改善することができ、また、ホイップドクリームのコクを改善し、乳化剤特有の異味を抑制することができる。カゼインタンパク質としては、例えば、カゼインナトリウムやカゼインカリウムに含まれるカゼインタンパク質の他、生乳、牛乳、全粉乳、脱脂粉乳、脱脂濃縮乳、バターミルク、チーズ等の乳製品に含まれるカゼインタンパク質等が挙げられる。前記カゼインタンパク質の含有量は、本発明の起泡性水中油型乳化油脂組成物全体中0.5〜1.3重量%であることが好ましく、0.8〜1.2重量%がより好ましい。カゼインタンパク質の含有量が0.5重量%より少ないと原液安定性が悪化し、ボテと呼ばれる現象が起こる場合があり、また、ホイップドクリームのコクが低下し、乳化剤特有の異味が感じられる場合がある。1.3重量%より多いと起泡性が悪化する場合がある。 The foamable oil-in-water emulsified oil / fat composition of the present invention contains casein protein. By containing the casein protein, the stability of the undiluted solution can be improved, the richness of the whipped cream can be improved, and the unpleasant taste peculiar to the emulsifier can be suppressed. Examples of casein protein include casein protein contained in sodium caseinate and potassium casein potassium, as well as casein protein contained in raw milk, milk, whole milk powder, nonfat dry milk, nonfat concentrated milk, buttermilk, cheese and other dairy products. Be done. The content of the casein protein is preferably 0.5 to 1.3% by weight, more preferably 0.8 to 1.2% by weight, based on the total amount of the foamable oil-in-water emulsified oil / fat composition of the present invention. .. If the content of casein protein is less than 0.5% by weight, the stability of the undiluted solution deteriorates and a phenomenon called "botte" may occur, and the richness of the whipped cream is reduced and the taste peculiar to the emulsifier is felt. There is. If it is more than 1.3% by weight, the foaming property may deteriorate.

本発明の起泡性水中油型乳化油脂組成物は、乳化剤を必須成分として含有するが、乳化剤として、少なくとも、C16〜C22の不飽和脂肪酸の結合した脂肪酸エステルを含有する。このような乳化剤としては、特に限定されないが、例えば、C16〜C22の不飽和脂肪酸の結合したポリグリセリン脂肪酸エステル、C16〜C22の不飽和脂肪酸の結合したジグリセリン脂肪酸エステル、C16〜C22の不飽和脂肪酸の結合したショ糖脂肪酸エステル、C16〜C22の不飽和脂肪酸の結合したソルビタン脂肪酸エステル等が挙げられる。これら乳化剤において、1分子中に結合している不飽和脂肪酸の数は特に限定されない。これらの乳化剤は1種類のみを使用してもよいし、2種以上を併用してもよい。このような特定の乳化剤を配合することにより、起泡性とホイップドクリームの離水耐性を向上させることができる。前記特定の乳化剤の合計含有量は、本発明の起泡性水中油型乳化油脂組成物全体中0.01〜0.055重量%であることが好ましく、0.02〜0.04重量%がより好ましい。前記特定の乳化剤の合計含有量が0.01重量%より少ないと起泡性や離水耐性が悪化する場合があり、0.055重量%より多いと原液安定性が低下し、ホイップドクリームの口溶け及びコクが低下し、乳化剤特有の異味が感じられる場合がある。The foamable oil-in-water emulsified oil / fat composition of the present invention contains an emulsifier as an essential component, and contains at least a fatty acid ester to which unsaturated fatty acids C 16 to C 22 are bound as an emulsifier. Examples of such emulsifiers include, but are not limited to, for example, polyglycerol fatty acid ester bonded to the unsaturated fatty acids of C 16 -C 22, diglycerol fatty acid ester bonded to the unsaturated fatty acids of C 16 ~C 22, C 16 sucrose fatty acid ester bonded to the unsaturated fatty -C 22, sorbitan fatty acid esters bound to unsaturated fatty acids of C 16 -C 22 and the like. In these emulsifiers, the number of unsaturated fatty acids bound in one molecule is not particularly limited. Only one type of these emulsifiers may be used, or two or more types may be used in combination. By blending such a specific emulsifier, the foaming property and the water separation resistance of the whipped cream can be improved. The total content of the specific emulsifier is preferably 0.01 to 0.055% by weight, preferably 0.02 to 0.04% by weight, based on the total content of the foamable oil-in-water emulsified oil / fat composition of the present invention. More preferred. If the total content of the specific emulsifier is less than 0.01% by weight, the foaming property and water separation resistance may be deteriorated, and if it is more than 0.055% by weight, the stability of the undiluted solution is lowered and the whipped cream melts in the mouth. In some cases, the richness is reduced and the unique taste of the emulsifier is felt.

さらに、本発明の起泡性水中油型乳化油脂組成物は、カリウム及びナトリウムのいずれか1つ又は双方を含有するものである。カリウムとナトリウムとの合計含有量は0.028〜0.15重量%であることが好ましく0.03〜0.14重量%がより好ましい。カリウムとナトリウムの合計含有量が0.028重量%より少ないと原液安定性が悪化することに加え、ホイップドクリームのコクが低下したり、乳化剤特有の異味が感じられる場合があり、0.15重量%より多いと塩味が強く出てしまう場合がある。 Further, the foamable oil-in-water emulsified oil / fat composition of the present invention contains either one or both of potassium and sodium. The total content of potassium and sodium is preferably 0.028 to 0.15% by weight, more preferably 0.03 to 0.14% by weight. If the total content of potassium and sodium is less than 0.028% by weight, the stability of the undiluted solution deteriorates, the richness of the whipped cream may decrease, and the taste peculiar to the emulsifier may be felt. If it is more than% by weight, the salty taste may be strong.

また、本発明の起泡性水中油型乳化油脂組成物は、カリウム及び/又はナトリウムに加えてカルシウムを含有することが好ましい。(カリウムとナトリウムの合計含有量)/カルシウムの含有量(重量比)は、1.5〜2.9であることが好ましく、2.0〜2.9がより好ましく、2.0〜2.5がさらに好ましい。1.5より小さいと原液安定性が悪化する場合があり、2.9より大きいと起泡性が悪化したり、塩味が強く出てしまう場合がある。 Further, the foamable oil-in-water emulsified oil / fat composition of the present invention preferably contains calcium in addition to potassium and / or sodium. (Total content of potassium and sodium) / calcium content (weight ratio) is preferably 1.5 to 2.9, more preferably 2.0 to 2.9, and 2.0 to 2. 5 is more preferable. If it is less than 1.5, the stability of the undiluted solution may be deteriorated, and if it is more than 2.9, the foaming property may be deteriorated or the salty taste may be strong.

本発明の起泡性水中油型乳化油脂組成物は、本発明の効果を損なわない範囲で、必要に応じて、前述した乳化剤以外の他の乳化剤、増粘剤、糖類、乳原料、呈味剤、着色料、香料、塩分、ビタミン類、ミネラル類、油溶性酸化防止剤、その他の食品成分を含有してもよい。 The foamable oil-in-water emulsified oil / fat composition of the present invention is, if necessary, an emulsifier other than the above-mentioned emulsifier, a thickener, a sugar, a dairy raw material, and a taste, as long as the effect of the present invention is not impaired. It may contain agents, colorants, flavors, salts, vitamins, minerals, oil-soluble antioxidants and other food ingredients.

前述した乳化剤以外の他の乳化剤としては、主要構成脂肪酸が飽和脂肪酸及び/又はC14以下の不飽和脂肪酸及び/又はC24以上の不飽和脂肪酸のグリセリン脂肪酸エステル、主要構成脂肪酸が飽和脂肪酸及び/又はC14以下の不飽和脂肪酸及び/又はC24以上の不飽和脂肪酸のポリグリセリン脂肪酸エステル、主要構成脂肪酸が飽和脂肪酸及び/又はC14以下の不飽和脂肪酸及び/又はC24以上の不飽和脂肪酸のショ糖脂肪酸エステル、主要構成脂肪酸が飽和脂肪酸及び/又はC14以下の不飽和脂肪酸及び/又はC24以上の不飽和脂肪酸のソルビタン脂肪酸エステル、主要構成脂肪酸が飽和脂肪酸及び/又はC14以下の不飽和脂肪酸及び/又はC24以上の不飽和脂肪酸のプロピレングリコール脂肪酸エステルなどの合成乳化剤、大豆レシチン、卵黄レシチン、及びこれらの分画レシチン、更には酵素分解したリゾレシチンといった改質レシチンなどのレシチン類や乳由来のリン脂質を含む天然由来の乳化剤などが挙げられ、これらの群より選ばれる少なくとも1種を用いることができる。Examples of emulsifiers other than the above-mentioned emulsifiers include lecithin fatty acid esters in which the main constituent fatty acids are saturated fatty acids and / or unsaturated fatty acids with C 14 or less and / or unsaturated fatty acids with C 24 or more, and the main constituent fatty acids are saturated fatty acids and /. Or polyglycerin fatty acid esters of unsaturated fatty acids of C 14 or less and / or unsaturated fatty acids of C 24 or more, saturated fatty acids whose main constituent fatty acids are saturated fatty acids and / or unsaturated fatty acids of C 14 or less and / or unsaturated fatty acids of C 24 or more. Lecithin fatty acid ester, major constituent fatty acids are saturated fatty acids and / or unsaturated fatty acids of C 14 or less and / or sorbitan fatty acid esters of unsaturated fatty acids of C 24 or more, major constituent fatty acids are saturated fatty acids and / or C 14 or less. synthesis emulsifiers such as propylene glycol fatty acid esters of unsaturated fatty acids and / or C 24 or higher unsaturated fatty acid, soybean lecithin, egg yolk lecithin, and lecithin such as these fractions lecithin, modified lecithin such as lysolecithin further decomposed enzyme And naturally derived emulsifiers containing milk-derived phospholipids and the like, and at least one selected from these groups can be used.

他の乳化剤のなかでも大豆レシチンは、ホイップドクリームに乳化剤特有の異味を付加することなく、起泡性を向上することができるので、本発明の起泡性水中油型乳化油脂組成物に配合することが好ましい。特に、C16〜C22の不飽和脂肪酸の結合した脂肪酸エステルである乳化剤の含有量が少ない時ほど、大豆レシチンを配合することがより好ましい。大豆レシチンの含有量は、起泡性水中油型乳化油脂組成物全体中0.1〜0.35重量%が好ましく、0.15〜0.25重量%がより好ましい。大豆レシチンの含有量が0.1重量%より少ないと起泡性が悪化する場合があり、0.35重量%より多いと原液安定性が悪化し、ボテと呼ばれる現象が起こる場合がある。Among other emulsifiers, soy lecithin can improve the foaming property without adding a special taste peculiar to the emulsifier to the whipped cream, and therefore is blended in the foaming oil-in-water emulsified oil / fat composition of the present invention. It is preferable to do so. In particular, it is more preferable to add soybean lecithin when the content of the emulsifier, which is a fatty acid ester to which unsaturated fatty acids of C 16 to C 22 are bound, is small. The content of soybean lecithin is preferably 0.1 to 0.35% by weight, more preferably 0.15 to 0.25% by weight, based on the whole foamable oil-in-water emulsified oil / fat composition. If the content of soybean lecithin is less than 0.1% by weight, the foaming property may be deteriorated, and if it is more than 0.35% by weight, the stability of the undiluted solution may be deteriorated and a phenomenon called bote may occur.

前記増粘剤としては、例えば、ジェランガム、グアガム、キサンタンガム、寒天、ペクチン、アルギン酸ナトリウム、カラギーナン、ローカストビーンガム、アラビアガム、カルボキシメチルセルロース、ヒドロキシメチルセルロース、結晶セルロース、微結晶セルロース、澱粉、デキストリン等を挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the thickener include gellan gum, guar gum, xanthan gum, agar, pectin, sodium alginate, carrageenan, locust bean gum, arabic gum, carboxymethyl cellulose, hydroxymethyl cellulose, crystalline cellulose, microcrystalline cellulose, starch, dextrin and the like. At least one selected from these groups can be used.

前記糖類としては、例えば、ブドウ糖、砂糖、果糖、異性化糖、澱粉糖化物、デキストリン、澱粉又は糖アルコール等を挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the sugar include glucose, sugar, fructose, isomerized sugar, starch saccharified product, dextrin, starch, sugar alcohol, and the like, and at least one selected from these groups can be used.

前記乳原料としては、カゼイン、ホエイパウダー、蛋白質濃縮ホエイパウダー、全脂粉乳、脱脂粉乳、バターミルクパウダー、乳糖、トータルミルクプロテイン、生乳、牛乳、全脂濃縮乳、脱脂乳、脱脂濃縮乳、バターミルク、ホエー、生クリーム、加糖練乳、無糖練乳、バター、チーズ等を用いてもよく、さらに、UF膜やイオン交換樹脂処理等により蛋白質を分離、分画したものや、カゼインナトリウムやカゼインカリウムのような乳蛋白質の塩類が挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the dairy raw material include casein, whey powder, protein-concentrated whey powder, full-fat milk powder, defatted milk powder, butter milk powder, lactose, total milk protein, raw milk, milk, full-fat concentrated milk, defatted milk, defatted concentrated milk, butter. Milk, whey, fresh cream, sweetened milk, sugar-free milk, butter, cheese, etc. may be used, and proteins are separated and fractionated by UF membrane or ion exchange resin treatment, casein sodium, casein potassium, etc. Examples of milk protein salts such as, and at least one selected from these groups can be used.

前記呈味剤としては、前記乳原料を酵素分解、加熱、分離、分画等をしたものが挙げられ、これらの群より少なくとも1種を使用することができる。 Examples of the taste agent include those obtained by enzymatically decomposing, heating, separating, fractionating, etc. the dairy raw material, and at least one of these groups can be used.

前記着色料としては、天然成分や人工成分に関わらず、食品用途として使用できるものが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the colorant include those that can be used for food purposes regardless of natural ingredients or artificial ingredients, and at least one selected from these groups can be used.

前記香料としては、天然成分や人工成分に関わらず、食品用途として使用できるものが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the flavor include those that can be used for food purposes regardless of natural ingredients or artificial ingredients, and at least one selected from these groups can be used.

前記塩分としては、塩化ナトリウムを主成分とする食品用途として使用できるものが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the salt include those that can be used for foods containing sodium chloride as a main component, and at least one selected from these groups can be used.

前記ビタミン類としては、ビタミンA、ビタミンB群、ビタミンC、ビタミンD、ビタミンE、ビタミンKを主成分とする食品用途として使用できるものが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the vitamins include those that can be used for foods containing vitamin A, B vitamins, vitamin C, vitamin D, vitamin E, and vitamin K as main components, and at least one selected from these groups is used. can do.

前記ミネラル類としては、亜鉛、カリウム、カルシウム、クロム、セレン、鉄、銅、ナトリウム、マグネシウム、マンガン、モリブデン、ヨウ素、リンが挙げられ、これらの成分を含む食品及び食品添加物に分類されるものを少なくとも1種を使用することができる。 Examples of the minerals include zinc, potassium, calcium, chromium, selenium, iron, copper, sodium, magnesium, manganese, molybdenum, iodine and phosphorus, which are classified into foods and food additives containing these components. At least one type can be used.

前記油溶性酸化防止剤としては、ビタミンE、ローズマリー抽出物等の抗酸化成分を主成分とする食品用途として使用できるものが挙げられ、これらの群より選ばれる少なくとも1種を使用することができる。 Examples of the oil-soluble antioxidant include those that can be used for foods containing antioxidant components such as vitamin E and rosemary extract as main components, and at least one selected from these groups may be used. it can.

本発明の起泡性水中油型乳化油脂組成物の製造例は、特に限定されないが、次に一例を示す。まず、50〜70℃に加温溶融した油脂に、必要に応じて油溶性乳化剤、油溶性香料等の油溶性原料を混合し、該混合物を50〜70℃に維持しながら撹拌し、油相を調製する。 The production example of the foamable oil-in-water emulsified oil / fat composition of the present invention is not particularly limited, but an example is shown below. First, an oil-soluble raw material such as an oil-soluble emulsifier and an oil-soluble fragrance is mixed with an oil or fat that has been heated and melted at 50 to 70 ° C., and the mixture is stirred while maintaining the temperature at 50 to 70 ° C. to obtain an oil phase. To prepare.

また、50〜70℃の温水に、C16〜C22の不飽和脂肪酸の結合した脂肪酸エステルである乳化剤と、必要に応じて蛋白質、香料、増粘剤、呈味剤、糖類、乳原料、着色料、塩分、ビタミン類、ミネラル類などの水溶性原料を混合し、50〜70℃に維持しながら撹拌し、水相を調製する。In addition, an emulsifier which is a fatty acid ester in which unsaturated fatty acids of C 16 to C 22 are bound to warm water at 50 to 70 ° C., and if necessary, proteins, flavors, thickeners, flavoring agents, sugars, dairy raw materials, Water-soluble raw materials such as colorants, salts, vitamins and minerals are mixed and stirred while maintaining at 50 to 70 ° C. to prepare an aqueous phase.

そして、水相を撹拌しながらそこへ油相を添加して、予備乳化する。その後、微細化、均質化、予備加熱、殺菌、1次冷却、均質化、2次冷却、3次冷却、エージングなど、起泡性水中油型乳化油脂組成物の製造時に常法として行われる各処理を行うことにより、本発明の起泡性水中油型乳化油脂組成物を得ることができる。 Then, while stirring the aqueous phase, the oil phase is added thereto to pre-emulsify. After that, micronization, homogenization, preheating, sterilization, primary cooling, homogenization, secondary cooling, tertiary cooling, aging, etc. are performed as usual in the production of foamable oil-in-water emulsified oil / fat compositions. By carrying out the treatment, the foamable oil-in-water emulsified oil / fat composition of the present invention can be obtained.

そして、得られた起泡性水中油型乳化油脂組成物を、オープン式ホイッパーや密閉式連続ホイップマシンを用いて、トッピング、ナッペ、サンド等の使用目的に沿った適度な硬さに到達するまでホイップすることで、本発明のホイップドクリームが得られる。 Then, the obtained foaming oil-in-water emulsified oil / fat composition is used with an open type whipper or a closed type continuous whipping machine until it reaches an appropriate hardness according to the purpose of use such as toppings, nappes, and sands. By whipping, the whipped cream of the present invention can be obtained.

本発明の起泡性水中油型乳化油脂組成物は、食用のものとすることができ、主に、ホイップしてホイップドクリームとすることで、トッピング用、ナッペ用、サンド用、フィリング用、センター用等のホイップドクリームとして使用することができる。 The foamable oil-in-water emulsified oil / fat composition of the present invention can be edible, and is mainly used for toppings, nappes, sands, and fillings by whipping to make whipped cream. It can be used as a whipped cream for centers and the like.

しかし、本発明の起泡性水中油型乳化油脂組成物は、ホイップドクリーム用途に限定されず、例えば、コーヒー用クリーム、加工食品(ホワイトソース、グラタンなど)用クリーム、アイスクリーム、ソフトクリーム用プレミックス;飲料;パン、菓子、ハム、ソーセージ、食肉、魚肉、その他加工食品等への練り込み用油脂;マヨネーズ、ドレッシング、チーズ様食品、フラワーペースト、フィリング、トッピング、サンド、スプレッド等の加工食品用途としても用いることができる。 However, the foamable oil-in-water emulsified oil / fat composition of the present invention is not limited to whipped cream applications, for example, for coffee creams, creams for processed foods (white sauce, gratin, etc.), ice creams, and soft creams. Premix; Beverages; Oils and fats for kneading into bread, confectionery, ham, sausage, meat, fish, and other processed foods; Mayonnaise, dressings, cheese-like foods, flower pastes, fillings, toppings, sands, spreads, and other processed foods It can also be used as an application.

以下に実施例を示し、本発明をより具体的に説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、実施例において「部」や「%」は重量基準である。 Examples will be shown below and the present invention will be described in more detail, but the present invention is not limited to these examples. In the examples, "part" and "%" are based on weight.

なお、各実施例及び比較例で使用した各材料は以下のものである。
1)カネカ社製「パーム核油」
2)カネカ社製「パーム中融点分別油」
3)カネカ社製「パームオレイン」
4)横関油脂工業社製「ハイエルシン菜種極度硬化油」
5)カネカ社製「パーム核硬化油」
6)カネカ社製「ヤシ油とハイエルシン菜種極度硬化油のエステル交換油」
7)カネカ社製「パーム極度硬化油」
8)ADM社製「Yelkin TS」
9)阪本薬品工業社製「MS−3S」(テトラグリセリンモノステアレート、HLB:8.4)
10)よつば葉乳業社製「脱脂粉乳」
11)FrieslandCampina DMV社製「カゼインカリウムSPRAY」
12)HILMAR社製「ラクトース HILMAR FINE GRAIND」
13)阪本薬品工業社製「MS−5S」(ヘキサグリセリンモノステアレート、HLB:11.6)
14)阪本薬品工業社製「MO−5S」(ヘキサグリセリンモノオレエート、HLB:11.6)
15)第一工業製薬社製「DKエステルF−70」(ショ糖ステアリン酸エステル、HLB:8)
16)阪本薬品工業社製「MO−7S」(デカグリセリンモノオレエート、HLB:12.9)
17)理研ビタミン株製「J−0381V」(デカグリセリンモノオレエート、HLB:14)
18)三菱ケミカルフーズ社製「O−1570」(ショ糖オレイン酸エステル、HLB:15)
19)理研ビタミン製「DO−100V」(ジグリセリンモノオレエート、HLB:7.4)
The materials used in each of the examples and comparative examples are as follows.
1) "Palm kernel oil" manufactured by Kaneka Corporation
2) "Melting point fractionated oil in palm" manufactured by Kaneka Corporation
3) "Palm Olein" manufactured by Kaneka Corporation
4) "High Elsin Rapeseed Extremely Hardened Oil" manufactured by Yokoseki Oil & Fat Industry Co., Ltd.
5) "Palm kernel hydrogenated oil" manufactured by Kaneka Corporation
6) Kaneka's "Transesterification oil for coconut oil and rapeseed rapeseed extremely hydrogenated oil"
7) Kaneka's "Palm Extremely Hardened Oil"
8) ADM "Yelkin TS"
9) "MS-3S" manufactured by Sakamoto Yakuhin Kogyo Co., Ltd. (Tetraglycerin monostearate, HLB: 8.4)
10) "Skim milk powder" manufactured by Yotsuba Leaf Dairy Co., Ltd.
11) "Casein Potassium SPRAY" manufactured by FrieslandCampina DMV
12) "Lactose HILMAR FINE GRAIND" manufactured by HILMAR
13) "MS-5S" manufactured by Sakamoto Yakuhin Kogyo Co., Ltd. (Hexaglycerin monostearate, HLB: 11.6)
14) "MO-5S" manufactured by Sakamoto Yakuhin Kogyo Co., Ltd. (Hexaglycerin monooleate, HLB: 11.6)
15) "DK Ester F-70" manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd. (sucrose stearic acid ester, HLB: 8)
16) "MO-7S" manufactured by Sakamoto Yakuhin Kogyo Co., Ltd. (Decaglycerin monooleate, HLB: 12.9)
17) RIKEN Vitamin Co., Ltd. "J-0381V" (decaglycerin monooleate, HLB: 14)
18) "O-1570" manufactured by Mitsubishi Chemical Foods Co., Ltd. (sucrose oleic acid ester, HLB: 15)
19) RIKEN Vitamin "DO-100V" (diglycerin monooleate, HLB: 7.4)

<油脂の構成脂肪酸組成の測定>
油脂の構成脂肪酸組成の測定は、FID恒温ガスクロマトグラフ法により行った。FID恒温ガスクロマトグラフ法とは、社団法人日本油化学協会編「基準油脂分析試験法」(発行年:1996年)の「2.4.2.1 脂肪酸組成」に記載された方法である。油脂の構成脂肪酸組成を測定することにより、構成脂肪酸中のトランス脂肪酸含有量、及び、飽和脂肪酸含有量をそれぞれ得た。
<Measurement of constituent fatty acid composition of fats and oils>
The composition of fatty acids in the fats and oils was measured by the FID constant temperature gas chromatograph method. The FID constant temperature gas chromatograph method is a method described in "2.4.2.1 Fatty Acid Composition" of "Standard Oil and Fat Analysis Test Method" (published year: 1996) edited by Japan Oil Chemists' Association. By measuring the constituent fatty acid composition of the fat and oil, the trans fatty acid content and the saturated fatty acid content in the constituent fatty acids were obtained, respectively.

<起泡性水中油型乳化油脂組成物の粘度測定(原液安定性)>
各実施例及び比較例で得られた起泡性水中油型乳化油脂組成物について、ホイップ直前に、B型粘度計(TOKIMEC INC.製)を用いて粘度を測定し、その測定値(単位:mPa・s)を粘度の評価値とした。なお、評価値が250mPa・s以下の範囲であれば、起泡性水中油型乳化油脂組成物の原液安定性は良好であるといえる。
<Viscosity measurement of foamable oil-in-water emulsified oil / fat composition (stock solution stability)>
Immediately before whipping, the viscosity of the foamable oil-in-water emulsified oil / fat composition obtained in each Example and Comparative Example was measured using a B-type viscometer (manufactured by TOKIMEC INC.), And the measured value (unit:: mPa · s) was used as the evaluation value of viscosity. When the evaluation value is in the range of 250 mPa · s or less, it can be said that the stock solution stability of the foamable oil-in-water emulsified oil / fat composition is good.

<ボテの評価(原液安定性)>
各実施例及び比較例で得られた起泡性水中油型乳化油脂組成物60gを100mLビーカーに入れ、15℃で1時間温調後、縦1cm×横3cm×厚さ0.1cmの攪拌ペラで120rpm、室温20℃の条件で攪拌し、流動性が無くなるまでに要する時間を測定し、その測定値をボテの評価値とした。なお、評価値が30分以上であれば、起泡性水中油型乳化油脂組成物の原液安定性は良好であるといえる。
<Evaluation of body (stock solution stability)>
60 g of the foamable oil-in-water emulsified oil / fat composition obtained in each Example and Comparative Example was placed in a 100 mL beaker, and after temperature adjustment at 15 ° C. for 1 hour, a stirring propeller of 1 cm in length × 3 cm in width × 0.1 cm in thickness. The mixture was stirred under the conditions of 120 rpm and room temperature of 20 ° C., and the time required for the fluid to disappear was measured, and the measured value was used as the evaluation value of the body. If the evaluation value is 30 minutes or more, it can be said that the stock solution stability of the foamable oil-in-water emulsified oil / fat composition is good.

<ホイップ時間(起泡性)>
5L卓上ミキサー(ホバート製)に、各実施例及び比較例で得られた起泡性水中油型乳化油脂組成物300g、及び、グラニュー糖24gを入れ、285rpmでホイップした。クリープメーター((株)山電製「RE2−33005S」)を用いて直径16mmの円柱状のプランジャーにて、速度5mm/sの速さで1cm貫入させた時の最大荷重が0.30Nになるまでに要するホイップ時間を測定し、その測定値をホイップ時間の評価値とした。なお、評価値が6分00秒〜7分30秒の範囲であれば、起泡性水中油型乳化油脂組成物の起泡性は良好であるといえる。また、ホイップ時間の評価値が6分00秒未満であっても、次に説明するオーバーランの評価値が140%以上であれば起泡性は良好であるといえる。
<Whipped time (foaming property)>
300 g of the foamable oil-in-water emulsified oil / fat composition and 24 g of granulated sugar obtained in each Example and Comparative Example were placed in a 5 L tabletop mixer (manufactured by Hobart) and whipped at 285 rpm. With a cylindrical plunger with a diameter of 16 mm using a creep meter (“RE2-3305S” manufactured by Yamaden Co., Ltd.), the maximum load when penetrating 1 cm at a speed of 5 mm / s is 0.30 N. The whipping time required to achieve this was measured, and the measured value was used as the evaluation value of the whipping time. When the evaluation value is in the range of 6 minutes 00 seconds to 7 minutes 30 seconds, it can be said that the foaming property of the foamable oil-in-water emulsified oil / fat composition is good. Further, even if the evaluation value of the whip time is less than 6:00 seconds, it can be said that the foaming property is good if the evaluation value of the overrun described below is 140% or more.

<オーバーランの評価(起泡性)>
上記ホイップにより最大荷重0.30Nになった状態のホイップドクリームを予め重量と容積を測定した容器に積め、この時のホイップドクリームの重量からオーバーランを算出し、その測定値をオーバーランの評価値とした。なお、評価値が140%以上であれば、起泡性水中油型乳化油脂組成物の起泡性は良好であるといえる。
<Evaluation of overrun (foaming property)>
The whipped cream with the maximum load of 0.30 N by the above whipping is loaded in a container whose weight and volume have been measured in advance, the overrun is calculated from the weight of the whipped cream at this time, and the measured value is the overrun. It was used as an evaluation value. If the evaluation value is 140% or more, it can be said that the foaming property of the foaming oil-in-water emulsified oil / fat composition is good.

オーバーランとは、ホイップドクリームに含まれる空気の割合を%で示したもので、次式により求めた。
オーバーラン(%)=[(一定容積の起泡性水中油型乳化油脂組成物の重量)−(前記起泡性水中油型乳化油脂組成物と同容積のホイップドクリームの重量)]÷(前記起泡性水中油型乳化油脂組成物と同容積のホイップドクリームの重量)×100
The overrun is the percentage of air contained in the whipped cream, and was calculated by the following formula.
Overrun (%) = [(Weight of foaming oil-in-water emulsified fat composition)-(Weight of whipped cream in the same volume as the foaming oil-in-water emulsified oil composition)] ÷ ( Weight of whipped cream having the same volume as the foaming oil-in-water emulsified oil / fat composition) × 100

<離水耐性の評価>
各実施例及び比較例で得られたホイップドクリーム50gをプラスチック製カップに絞り出し、15℃で24時間静置した後、絞ったホイップドクリームから発生する離水の状態を目視で評価した。その際の評価基準は、以下の通りである。
◎…全く離水しない。
○…クリーム表面に水分を確認できる。
△…クリームからの水分の遊離を確認できる。
×…離水した水分にクリームが浸る程、激しい離水が確認できる
<Evaluation of water separation resistance>
50 g of the whipped cream obtained in each Example and Comparative Example was squeezed into a plastic cup, allowed to stand at 15 ° C. for 24 hours, and then the state of water separation generated from the squeezed whipped cream was visually evaluated. The evaluation criteria at that time are as follows.
◎… No water separation.
○… Moisture can be confirmed on the cream surface.
Δ: The release of water from the cream can be confirmed.
×… The more the cream is soaked in the separated water, the more severe the water separation can be confirmed.

<口溶けの官能評価>
各実施例及び比較例で得られたホイップドクリームを、熟練した評価者4人に食べてもらい、官能評価を行い、口溶けの平均値を評価値とした。その際、従来品相当である比較例4を「3」として評価し、評価基準は、以下の通りである。
5:速やかに溶けていき、口溶けが非常に良い
4:口残りが無く、口溶けが良い
3:口残りはあるが、許容できるレベル
2:口残りがあって、口溶けがやや悪い
1:最後まで口残りがあって、口溶けが悪い
<Sensory evaluation of melting in the mouth>
The whipped cream obtained in each Example and Comparative Example was eaten by four skilled evaluators, and sensory evaluation was performed, and the average value of melting in the mouth was used as the evaluation value. At that time, Comparative Example 4, which is equivalent to the conventional product, is evaluated as "3", and the evaluation criteria are as follows.
5: Melts quickly and melts in the mouth very well 4: No mouth residue and good melting in the mouth 3: There is a residue in the mouth but acceptable level 2: There is a residue in the mouth and the mouth melts slightly bad 1: Until the end There is a residue in the mouth and it does not melt in the mouth

<コクの官能評価>
各実施例及び比較例で得られたホイップドクリームを、熟練した評価者4人に食べてもらい、官能評価を行い、コクの平均値を評価値とした。その際、従来品相当である比較例4を「3」として評価し、評価基準は、以下の通りである。
5:より豊かに感じられる
4:十分に感じられる
3:十分ではないが、感じられる
2:感じられるが、やや不足
1:全く感じない
<Sensory evaluation of richness>
The whipped cream obtained in each Example and Comparative Example was eaten by four skilled evaluators, and sensory evaluation was performed, and the average value of richness was used as the evaluation value. At that time, Comparative Example 4, which is equivalent to the conventional product, is evaluated as "3", and the evaluation criteria are as follows.
5: Feeling richer 4: Feeling enough 3: Not enough but feeling 2: Feeling but slightly lacking 1: Not feeling at all

<乳化剤の異味の評価>
各実施例及び比較例で得られたホイップドクリームを、熟練した評価者4人に食べてもらい、官能評価を行い、乳化剤に由来する異味の平均値を評価値とした。その際、従来品相当である比較例4を「2」として評価し、評価基準は、以下の通りである。
5:異味をほとんど感じず、非常に好ましい
4:異味はやや感じるものの、少なく好ましい
3:異味が感じられるが許容できるレベル
2:異味がやや強く感じられ、悪い
1:異味が強く、非常に悪い
<Evaluation of the taste of emulsifier>
The whipped creams obtained in each Example and Comparative Example were eaten by four skilled evaluators, and sensory evaluation was performed, and the average value of the off-flavor derived from the emulsifier was used as the evaluation value. At that time, Comparative Example 4, which is equivalent to the conventional product, is evaluated as "2", and the evaluation criteria are as follows.
5: Almost no offensive taste, very preferable 4: Offensive taste is slightly felt but less favorable 3: Offensive taste is felt but acceptable level 2: Offensive taste is felt slightly strong, bad 1: Offensive taste is strong and very bad

<総合評価>
5:原液安定性に関してはボテの評価値が30分以上、起泡性に関してはホイップ時間が6分00秒〜7分30秒の範囲であるか又は6分00秒未満の時はオーバーランが140%以上、離水耐性は◎又は○評価、及び、官能評価はいずれも3以上の評価で、3項目のうち2項目以上で4以上の評価。
4:原液安定性に関してはボテの評価値が30分以上、起泡性に関してはホイップ時間が6分00秒〜7分30秒の範囲であるか又は6分00秒未満の時はオーバーランが140%以上、離水耐性は◎又は○評価、及び、官能評価はいずれも3以上の評価。
3:原液安定性、起泡性、離水耐性、及び、官能評価のうちいずれか1つが、基準「4」において示した評価値を満足しない。
2:原液安定性、起泡性、離水耐性、及び、官能評価のうち2以上が、基準「4」において示した評価値を満足しない。
1:原液安定性、起泡性、離水耐性、及び、官能評価のうちいずれかが著しく劣る(原液安定性に関してはボテの評価値が10分未満、起泡性に関してはホイップ時間が10分00秒以上又はオーバーランが120%未満、離水耐性は×評価)、又は、官能評価で著しく劣る(2以下を含む、又は乳化剤の異味が2以下)
<Comprehensive evaluation>
5: With regard to undiluted solution stability, the evaluation value of the body is 30 minutes or more, and with respect to foaming property, overrun occurs when the whipping time is in the range of 6 minutes 00 seconds to 7 minutes 30 seconds or less than 6 minutes 00 seconds. 140% or more, water separation resistance is evaluated as ◎ or ○, and sensory evaluation is evaluated as 3 or more, and 2 or more of 3 items are evaluated as 4 or more.
4: Overrun occurs when the evaluation value of the body is 30 minutes or more for the stability of the undiluted solution, and the whipping time is in the range of 6 minutes 00 seconds to 7 minutes 30 seconds or less than 6 minutes 00 seconds for the foaming property. 140% or more, water separation resistance is evaluated as ◎ or ○, and sensory evaluation is evaluated as 3 or more.
3: Any one of undiluted solution stability, foaming property, water separation resistance, and sensory evaluation does not satisfy the evaluation value shown in the standard "4".
2: Two or more of the stock solution stability, foaming property, water separation resistance, and sensory evaluation do not satisfy the evaluation values shown in the standard "4".
1: One of the undiluted solution stability, foaming property, water separation resistance, and sensory evaluation is significantly inferior (the evaluation value of the body is less than 10 minutes for undiluted solution stability, and the whipping time is 10 minutes for foaming property. Seconds or more or overrun less than 120%, water separation resistance x evaluation), or significantly inferior in sensory evaluation (including 2 or less, or emulsifier taste 2 or less)

(実施例1)起泡性水中油型乳化油脂組成物及びホイップドクリーム
表1の配合に従い、パーム核油(上昇融点:27℃、トランス脂肪酸:0重量%、総飽和脂肪酸:79.9%)3.50重量部、パーム油中融点部(トランス脂肪酸:0.1重量%、総飽和脂肪酸:55.6重量%)19.26重量部、パームオレイン(トランス脂肪酸:0.2重量%、総飽和脂肪酸:45.9重量%)12.07重量部及びハイエルシン菜種極度硬化油(トランス脂肪酸:0重量%、総飽和脂肪酸:99.9重量%)0.35重量部を混合した油脂混合物に、大豆レシチン0.200重量部、ポリグリセリン飽和脂肪酸エステル(HLB:8.4)0.140重量部を添加し、65℃で溶解して油相部を作製した。このとき、油相部の油脂の構成脂肪酸全体中、トランス脂肪酸含有量は0.1重量%、飽和脂肪酸含有量は54.5重量%であった。
(Example 1) Foamable oil-in-water emulsified fat composition and whipped cream According to the formulation shown in Table 1, palm kernel oil (rising melting point: 27 ° C., trans fatty acid: 0% by weight, total saturated fatty acid: 79.9%). ) 3.50 parts by weight, melting point in palm oil (trans fatty acid: 0.1% by weight, total saturated fatty acid: 55.6% by weight) 19.26 parts by weight, palm olein (trans fatty acid: 0.2% by weight, Total saturated fatty acids: 45.9% by weight) 12.07 parts by weight and 0.35 parts by weight of hyerucin rapeseed extremely hardened oil (trans fatty acids: 0% by weight, total saturated fatty acids: 99.9% by weight) in a fat mixture. , 0.200 parts by weight of soybean lecithin and 0.140 parts by weight of polyglycerin saturated fatty acid ester (HLB: 8.4) were added and dissolved at 65 ° C. to prepare an oil phase part. At this time, the trans fatty acid content was 0.1% by weight and the saturated fatty acid content was 54.5% by weight in the total constituent fatty acids of the oil and fat in the oil phase portion.

一方、脱脂粉乳1.50重量部、カゼインカリウム0.55重量部、乳糖1.55重量部、ポリグリセリン飽和脂肪酸エステル(HLB:11.6)0.090重量部、ポリグリセリン不飽和脂肪酸エステル(HLB:11.6)0.025重量部を、表1の配合と最終的に同じになるように60℃以上の温水に溶解して水相部を作製した。 On the other hand, 1.50 parts by weight of defatted milk powder, 0.55 parts by weight of potassium caseinate, 1.55 parts by weight of lactose, 0.090 parts by weight of polyglycerin saturated fatty acid ester (HLB: 11.6), polyglycerin unsaturated fatty acid ester ( HLB: 11.6) 0.025 parts by weight was dissolved in warm water at 60 ° C. or higher so as to have the same final composition as in Table 1 to prepare an aqueous phase part.

前記の油相部と水相部とを混合して高速乳化機(PRIMIX株式会社製「ホモミクサーMARKII」)にて5分間予備乳化した後、卓上型高圧ホモジナイザーを用いて1段目:10.0MPa/2段目:3.0MPaの圧力で処理した後に、低温恒温槽で5℃まで冷却したものを容器に充填し、5℃の冷蔵庫で24時間保管し、起泡性水中油型乳化油脂組成物を得た。得られた起泡性水中油型乳化油脂組成物の粘度、ボテ、ホイップ時間、及びオーバーランを評価し、表1に記載した。 The oil phase portion and the aqueous phase portion are mixed and pre-emulsified with a high-speed emulsifier (“Homomixer MARKII” manufactured by PRIMIX Co., Ltd.) for 5 minutes, and then the first stage is 10.0 MPa using a desktop high-pressure homogenizer. / 2nd stage: After processing at a pressure of 3.0 MPa, the container is filled with a product cooled to 5 ° C in a low-temperature constant temperature bath and stored in a refrigerator at 5 ° C for 24 hours. I got something. The viscosity, bottom, whipping time, and overrun of the obtained foamable oil-in-water emulsified oil / fat composition were evaluated and shown in Table 1.

さらに、この起泡性水中油型乳化油脂組成物100重量部に対してグラニュー糖を1重量部加え、5Q卓上ミキサーにて中速(2速)で攪拌してホイップドクリームを得た。得られたホイップドクリームの離水耐性、口溶け、コク及び乳化剤の異味を評価し、表1に記載した。 Further, 1 part by weight of granulated sugar was added to 100 parts by weight of this foamable oil-in-water emulsified oil / fat composition, and the mixture was stirred at medium speed (2nd speed) with a 5Q tabletop mixer to obtain whipped cream. The water separation resistance, melting in the mouth, richness and the taste of the emulsifier of the obtained whipped cream were evaluated and shown in Table 1.

Figure 0006788762
Figure 0006788762

(実施例2)
表1の配合に従い、パーム油中融点部の配合量を18.96重量部、ハイエルシン菜種極度硬化油の配合量を0.47重量部に変更した以外は、実施例1と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Example 2)
Foaming was performed in the same manner as in Example 1 except that the blending amount of the melting point in palm oil was changed to 18.96 parts by weight and the blending amount of the highly hydrogenated hyelsin rapeseed oil was changed to 0.47 parts by weight according to the formulation shown in Table 1. An oil-in-water emulsified oil / fat composition and whipped cream were obtained.

(実施例3)
表1の配合に従い、パーム油中融点部の配合量を18.91重量部、ハイエルシン菜種極度硬化油の配合量を0.53重量部に変更した以外は、実施例1と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Example 3)
Foaming was performed in the same manner as in Example 1 except that the blending amount of the melting point in palm oil was changed to 18.91 parts by weight and the blending amount of the hyelsin rapeseed extremely hydrogenated oil was changed to 0.53 parts by weight according to the formulation shown in Table 1. An oil-in-water emulsified oil / fat composition and whipped cream were obtained.

(比較例1)
表1の配合に従い、パーム油中融点部の配合量を19.40重量部、パームオレインの配合量を12.10重量部に変更し、ハイエルシン菜種極度硬化油を配合しなかった以外は、実施例1と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Comparative Example 1)
According to the formulation in Table 1, the blending amount of the melting point in palm oil was changed to 19.40 parts by weight, the blending amount of palm olein was changed to 12.10 parts by weight, and the mixture was carried out except that the hyelsin rapeseed extremely hydrogenated oil was not blended. A foaming oil-in-water emulsified oil / fat composition and whipped cream were obtained in the same manner as in Example 1.

(比較例2)
表1の配合に従い、パーム油中融点部の配合量を18.49重量部に変更し、ハイエルシン菜種極度硬化油を配合せず、エステル交換油を0.94重量部配合した以外は、実施例1と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Comparative Example 2)
Examples except that the blending amount of the melting point in palm oil was changed to 18.49 parts by weight, the transesterified oil was not blended, and the transesterified oil was blended by 0.94 parts by weight according to the formulation shown in Table 1. In the same manner as in No. 1, a foamable oil-in-water emulsified oil / fat composition and a whipped cream were obtained.

(比較例3)
表1の配合に従い、パーム油中融点部の配合量を18.96重量部に変更し、ハイエルシン菜種極度硬化油を配合せず、パーム極度硬化油を0.47重量部配合した以外は、実施例1と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Comparative Example 3)
According to the formulation in Table 1, the blending amount of the melting point in palm oil was changed to 18.96 parts by weight, and 0.47 parts by weight of palm extremely hardened oil was not blended, except that Hyelsin rapeseed extremely hardened oil was blended. A foaming oil-in-water emulsified oil / fat composition and a whipped cream were obtained in the same manner as in Example 1.

(比較例4)
表1の配合に従い、パーム核油の配合量を1.75重量部、パーム油中融点部の配合量を19.19重量部、パームオレインの配合量を12.20重量部に変更し、ハイエルシン菜種極度硬化油を配合せず、パーム核硬化油を1.75重量部、パーム極度硬化油を0.20重量部配合し、水相において、ポリグリセリン飽和脂肪酸エステルの配合量を0.080重量部に変更し、ポリグリセリン不飽和脂肪酸エステルの配合量を0.060重量部に変更し、さらにショ糖飽和脂肪酸エステルを0.050重量部配合した以外は、実施例1と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Comparative Example 4)
According to the formulation in Table 1, the blending amount of palm kernel oil was changed to 1.75 parts by weight, the blending amount of the melting point in palm oil was changed to 19.19 parts by weight, and the blending amount of palm olein was changed to 12.20 parts by weight. Without blending rapeseed extremely hydrogenated oil, 1.75 parts by weight of palm nuclear hydrogenated oil and 0.20 parts by weight of palm extremely hydrogenated oil were blended, and the amount of polyglycerin saturated fatty acid ester blended was 0.080 weight in the aqueous phase. The foaming was performed in the same manner as in Example 1 except that the amount of the polyglycerin unsaturated fatty acid ester was changed to 0.060 parts by weight and the amount of the sucrose saturated fatty acid ester was added to 0.050 parts by weight. An oil-in-water emulsified oil composition and a whipped cream were obtained.

実施例2〜3及び比較例1〜4で得られた起泡性水中油型乳化油脂組成物について粘度、ボテ、ホイップ時間、及びオーバーランを評価し、また、ホイップドクリームについて、離水耐性、口溶け、コク及び乳化剤の異味を評価し、それらの結果を表1に記載した。 The viscosity, bottom, whipping time, and overrun of the foamable oil-in-water emulsified oil and fat compositions obtained in Examples 2 to 3 and Comparative Examples 1 to 4 were evaluated, and the whipped cream was subjected to water separation resistance. The taste of melt in the mouth, richness and emulsifier was evaluated, and the results are shown in Table 1.

表1で示した結果より以下のことが分かる。油脂にハイエルシン菜種極度硬化油を1.0〜1.5重量%配合した実施例1〜3では、原液安定性と起泡性がいずれも良好であり、また、ホイップドクリームの離水耐性、口溶け、コク、及び乳化剤特有の異味の点でも良好な結果が得られた。ハイエルシン菜種極度硬化油を配合しなかった比較例1と比較すると、実施例1〜3ではホイップ時間が大幅に短縮されており起泡性が向上し、さらにホイップドクリームの離水耐性も向上していることが分かる。 The following can be seen from the results shown in Table 1. In Examples 1 to 3 in which 1.0 to 1.5% by weight of highly hydrogenated oil of rapeseed high-elsifier was blended with the fat and oil, both the stock solution stability and the foaming property were good, and the whipped cream was resistant to water separation and melted in the mouth. Good results were also obtained in terms of the richness and the unique taste of the emulsifier. Compared with Comparative Example 1 in which Hyelsin rapeseed extremely hydrogenated oil was not blended, in Examples 1 to 3, the whipping time was significantly shortened, the foaming property was improved, and the water separation resistance of the whipped cream was also improved. You can see that there is.

比較例2では、ハイエルシン菜種極度硬化油の代わりに、これを原料とするエステル交換油を、ベヘン酸含有量として実施例2のハイエルシン菜種極度硬化油と同量配合したが、実施例1〜3のような起泡性の大幅な向上は見られなかった。またホイップドクリームのコクの評価が低下した。さらに、比較例3及び4では、ハイエルシン菜種極度硬化油の代わりにパーム極度硬化油またはパーム核硬化油を配合したが、実施例1〜3のような起泡性の向上は見られなかった。また比較例3及び4では離水耐性の点も好ましくなく、加えて比較例4では乳化剤の異味の評価も低下した。 In Comparative Example 2, instead of the hyelsin rapeseed extremely hardened oil, a transesterified oil made from this was blended in the same amount as the hyelsin rapeseed extremely hardened oil of Example 2 as the behenic acid content, but Examples 1 to 3 No significant improvement in foaming property was observed. In addition, the evaluation of the richness of whipped cream decreased. Further, in Comparative Examples 3 and 4, palm extremely hardened oil or palm nuclear hardened oil was blended in place of the hyelsin rapeseed extremely hardened oil, but the improvement in foaming property as in Examples 1 to 3 was not observed. Further, in Comparative Examples 3 and 4, the point of water separation resistance was also unfavorable, and in addition, in Comparative Example 4, the evaluation of the off-taste of the emulsifier was also lowered.

(実施例4)
表2の配合に従い、パーム核油の配合量を1.75重量部、パーム油中融点部の配合量を20.03重量部に変更した以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Example 4)
In the same manner as in Example 2, the foaming water was changed to 1.75 parts by weight of palm kernel oil and 20.03 parts by weight of the melting point in palm oil according to the formulation shown in Table 2. An oil-type emulsified oil / fat composition and whipped cream were obtained.

(比較例5)
表2の配合に従い、パーム核油を配合せず、パーム油中融点部の配合量を21.10重量部、パームオレインの配合量を13.43重量部に変更した以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Comparative Example 5)
According to the formulation shown in Table 2, the blending amount of the melting point in palm oil was changed to 21.10 parts by weight and the blending amount of palm olein was changed to 13.43 parts by weight without blending palm kernel oil. Similarly, a foamable oil-in-water emulsified oil / fat composition and whipped cream were obtained.

(比較例6)
表2の配合に従い、パーム核油の配合量を0.88重量部、パーム油中融点部の配合量を20.57重量部、パームオレインの配合量を13.09重量部に変更した以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Comparative Example 6)
According to the formulation in Table 2, the amount of palm kernel oil was changed to 0.88 parts by weight, the amount of melting point in palm oil was changed to 20.57 parts by weight, and the amount of palm olein was changed to 13.09 parts by weight. , A foamable oil-in-water emulsified oil / fat composition and whipped cream were obtained in the same manner as in Example 2.

実施例4及び比較例5〜6で得られた起泡性水中油型乳化油脂組成物について粘度、ボテ、ホイップ時間、及びオーバーランを評価し、また、ホイップドクリームについて、離水耐性、口溶け、コク及び乳化剤の異味を評価し、それらの結果を、実施例2の結果と共に、表2に記載した。 The foaming oil-in-water emulsified oil and fat compositions obtained in Examples 4 and Comparative Examples 5 to 6 were evaluated for viscosity, body, whipping time, and overrun, and the whipped cream was subjected to water separation resistance, melting in the mouth, and so on. The richness and the taste of the emulsifier were evaluated, and the results are shown in Table 2 together with the results of Example 2.

Figure 0006788762
Figure 0006788762

表2の結果より以下のことが分かる。ハイエルシン菜種極度硬化油が配合され、ラウリン系油脂の含有量を油脂全体中5重量%まで低減した実施例4では、良好な起泡性を示し、その他の評価も良好であった。一方、ハイエルシン菜種極度硬化油が配合されているが、ラウリン系油脂が配合されていなかったり配合されていてもその含有量が2.5重量%と少ない比較例5及び6では、原液安定性、起泡性、及び、口溶けの点で評価が低下した。 The following can be seen from the results in Table 2. In Example 4 in which the hyelsin rapeseed extremely hydrogenated oil was blended and the content of the lauric-based fat and oil was reduced to 5% by weight in the whole fat and oil, good foaming property was exhibited and other evaluations were also good. On the other hand, in Comparative Examples 5 and 6, which contained an extremely hardened oil of rapeseed high-elsin, but the content of which was as small as 2.5% by weight even if the lauric-based oil was not or was contained, the stability of the undiluted solution was improved. The evaluation was lowered in terms of foaming property and melting in the mouth.

(実施例5)
表3の配合に従い、ポリグリセリン不飽和脂肪酸エステルの配合量を0.020重量部に変更した以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Example 5)
A foamable oil-in-water emulsified fat composition and whipped cream were obtained in the same manner as in Example 2 except that the blending amount of the polyglycerin unsaturated fatty acid ester was changed to 0.020 parts by weight according to the blending in Table 3. It was.

(実施例6)
表3の配合に従い、ポリグリセリン不飽和脂肪酸エステルの配合量を0.050重量部に変更した以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Example 6)
A foamable oil-in-water emulsified fat composition and whipped cream were obtained in the same manner as in Example 2 except that the blending amount of the polyglycerin unsaturated fatty acid ester was changed to 0.050 parts by weight according to the blending in Table 3. It was.

(比較例7)
表3の配合に従い、ポリグリセリン不飽和脂肪酸エステルを配合しなかった以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Comparative Example 7)
A foamable oil-in-water emulsified oil / fat composition and whipped cream were obtained in the same manner as in Example 2 except that the polyglycerin unsaturated fatty acid ester was not added according to the formulation shown in Table 3.

(比較例8)
表3の配合に従い、ポリグリセリン不飽和脂肪酸エステルの配合量を0.060重量部に変更した以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Comparative Example 8)
A foamable oil-in-water emulsified oil / fat composition and whipped cream were obtained in the same manner as in Example 2 except that the amount of the polyglycerin unsaturated fatty acid ester was changed to 0.060 parts by weight according to the formulation shown in Table 3. It was.

実施例5〜6及び比較例7〜8で得られた起泡性水中油型乳化油脂組成物について粘度、ボテ、ホイップ時間、及びオーバーランを評価し、また、ホイップドクリームについて、離水耐性、口溶け、コク及び乳化剤の異味を評価し、それらの結果を、実施例2及び比較例4の結果と共に、表3に記載した。 Viscosity, body, whipping time, and overrun were evaluated for the foamable oil-in-water emulsified oil and fat compositions obtained in Examples 5 to 6 and Comparative Examples 7 to 8, and the whipped cream was evaluated for water separation resistance. The taste of melt in the mouth, richness and emulsifier was evaluated, and the results are shown in Table 3 together with the results of Example 2 and Comparative Example 4.

Figure 0006788762
Figure 0006788762

表3の結果より以下のことが分かる。ハイエルシン菜種極度硬化油が配合されており、ポリグリセリン不飽和脂肪酸エステルの配合量が起泡性水中油型乳化油脂組成物全体中0.020〜0.050重量%である実施例2、5、及び6では、良好な起泡性を示し、その他の評価も良好であった。一方、ポリグリセリン不飽和脂肪酸エステルを配合しなかった比較例7では、起泡性と離水耐性の評価が低下した。また、ポリグリセリン不飽和脂肪酸エステルの配合量が0.060重量%と多い比較例8では、原液安定性が低下すると共に、ホイップドクリームの官能評価がいずれも好ましくないものであった。また、比較例同士の対比ではあるが、ハイエルシン菜種極度硬化油を配合していない比較例4に対して、ハイエルシン菜種極度硬化油を配合した比較例8では、起泡性と離水耐性が改善されたことを確認できる。 The following can be seen from the results in Table 3. Examples 2, 5 and 3, wherein the hyelsin rapeseed extremely hydrogenated oil is blended, and the blending amount of the polyglycerin unsaturated fatty acid ester is 0.020 to 0.050% by weight in the whole foamable oil-in-water emulsified oil / fat composition. In 1 and 6, good foaming property was shown, and other evaluations were also good. On the other hand, in Comparative Example 7 in which the polyglycerin unsaturated fatty acid ester was not blended, the evaluation of foaming property and water separation resistance was lowered. Further, in Comparative Example 8 in which the blending amount of the polyglycerin unsaturated fatty acid ester was as large as 0.060% by weight, the stability of the undiluted solution was lowered and the sensory evaluation of the whipped cream was not preferable. Further, although it is a comparison between the comparative examples, the foaming property and the water separation resistance are improved in the comparative example 8 in which the hyelsin rapeseed extremely hardened oil is blended, as opposed to the comparative example 4 in which the hyelsin rapeseed extremely hardened oil is not blended. You can confirm that.

(実施例7)
表4の配合に従い、ポリグリセリン不飽和脂肪酸エステルの種類を、HLB11.6のヘキサグリセリンモノオレエートから、HLB12.9のデカグリセリンモノオレエートに変更した以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Example 7)
The same as in Example 2 except that the type of polyglycerin unsaturated fatty acid ester was changed from hexaglycerin monooleate of HLB11.6 to decaglycerin monooleate of HLB12.9 according to the formulation shown in Table 4. A foamy oil-in-water emulsified oil / fat composition and a whipped cream were obtained.

(実施例8)
表4の配合に従い、ポリグリセリン不飽和脂肪酸エステルの種類を、HLB11.6のヘキサグリセリンモノオレエートから、HLB14のデカグリセリンモノオレエートに変更した以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Example 8)
Foaming property as in Example 2 except that the type of polyglycerin unsaturated fatty acid ester was changed from hexaglycerin monooleate of HLB11.6 to decaglycerin monooleate of HLB14 according to the formulation shown in Table 4. An oil-in-water emulsified oil / fat composition and a whipped cream were obtained.

(実施例9)
表4の配合に従い、ポリグリセリン不飽和脂肪酸エステルを、ジグリセリン不飽和脂肪酸エステル(ジグリセリンモノオレエート、HLB:7.4)に変更した以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Example 9)
Foaming water as in Example 2, except that the polyglycerin unsaturated fatty acid ester was changed to a diglycerin unsaturated fatty acid ester (diglycerin monooleate, HLB: 7.4) according to the formulation shown in Table 4. An oil-type emulsified fat composition and a whipped cream were obtained.

(実施例10)
表4の配合に従い、ポリグリセリン不飽和脂肪酸エステルを、ショ糖不飽和脂肪酸エステル(ショ糖オレイン酸エステル、HLB:15)に変更した以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Example 10)
Foamable oil-in-water type as in Example 2 except that the polyglycerin unsaturated fatty acid ester was changed to a sucrose unsaturated fatty acid ester (sucrose oleic acid ester, HLB: 15) according to the formulation shown in Table 4. Esterized oil and fat compositions and whipped cream were obtained.

実施例7〜10で得られた起泡性水中油型乳化油脂組成物について粘度、ボテ、ホイップ時間、及びオーバーランを評価し、また、ホイップドクリームについて、離水耐性、口溶け、コク及び乳化剤の異味を評価し、それらの結果を、実施例2の結果と共に、表4に記載した。 The foaming oil-in-water emulsified oil and fat compositions obtained in Examples 7 to 10 were evaluated for viscosity, body, whipping time, and overrun, and the whipped cream had water separation resistance, melting in the mouth, richness, and emulsifier. The off-taste was evaluated and the results are shown in Table 4 along with the results of Example 2.

Figure 0006788762
Figure 0006788762

表4の結果より以下のことが分かる。ポリグリセリン不飽和脂肪酸エステルの種類を変更した実施例7及び8、並びに、ポリグリセリン不飽和脂肪酸エステルに代えて、不飽和脂肪酸の結合した別の種類の乳化剤を使用した実施例9及び10のいずれにおいても、良好な原液安定性、起泡性、離水耐性を示し、かつ、乳化剤の異味を含む官能評価の点においても良好な結果を得ることができた。 The following can be seen from the results in Table 4. Any of Examples 7 and 8 in which the type of polyglycerin unsaturated fatty acid ester is changed, and Examples 9 and 10 in which another type of emulsifier to which an unsaturated fatty acid is bound is used instead of the polyglycerin unsaturated fatty acid ester. In addition, good stock solution stability, foaming property, and water separation resistance were exhibited, and good results were also obtained in terms of sensory evaluation including the off-taste of the emulsifier.

(実施例11)
表5の配合に従い、カゼインカリウムの配合量を0.22重量部に変更した以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Example 11)
A foamable oil-in-water emulsified oil / fat composition and whipped cream were obtained in the same manner as in Example 2 except that the amount of casein potassium was changed to 0.22 parts by weight according to the formulation shown in Table 5.

(実施例12)
表5の配合に従い、カゼインカリウムの配合量を0.34重量部に変更した以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Example 12)
A foamable oil-in-water emulsified oil / fat composition and whipped cream were obtained in the same manner as in Example 2 except that the amount of casein potassium was changed to 0.34 parts by weight according to the formulation shown in Table 5.

(実施例13)
表5の配合に従い、カゼインカリウムの配合量を0.78重量部に変更した以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Example 13)
A foamable oil-in-water emulsified oil / fat composition and whipped cream were obtained in the same manner as in Example 2 except that the amount of casein potassium was changed to 0.78 parts by weight according to the formulation shown in Table 5.

(比較例9)
表5の配合に従い、カゼインカリウムを配合しなかった以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Comparative Example 9)
According to the formulation shown in Table 5, a foamable oil-in-water emulsified fat composition and whipped cream were obtained in the same manner as in Example 2 except that potassium casein was not added.

実施例11〜13及び比較例9で得られた起泡性水中油型乳化油脂組成物について粘度、ボテ、ホイップ時間、及びオーバーランを評価し、また、ホイップドクリームについて、離水耐性、口溶け、コク及び乳化剤の異味を評価し、それらの結果を、実施例2の結果と共に、表5に記載した。 The foaming oil-in-water emulsified oil and fat compositions obtained in Examples 11 to 13 and Comparative Example 9 were evaluated for viscosity, body, whipping time, and overrun, and the whipped cream was subjected to water separation resistance, melting in the mouth, and so on. The richness and the taste of the emulsifier were evaluated, and the results are shown in Table 5 together with the results of Example 2.

Figure 0006788762
Figure 0006788762

表5の結果より以下のことが分かる。カゼインタンパク質の含有量が起泡性水中油型乳化油脂組成物全体中0.624重量%以上である実施例2、及び11〜13では、良好な原液安定性を示し、その他の評価も良好であった。一方、カゼインタンパク質の含有量が0.427重量%と少ない比較例9は、原液安定性が大幅に低下し、また、ホイップドクリームのコクや乳化剤の異味の点でも好ましくないものであった。さらに、カリウムとナトリウムとの合計含有量がカルシウムの含有量に対して1.5以上であると原液安定性が良好となり、該含有量比が2.0以上であると原液安定性がさらに良好になることも分かる。 The following can be seen from the results in Table 5. In Examples 2 and 11 to 13 in which the content of casein protein was 0.624% by weight or more in the entire foamable oil-in-water emulsified oil / fat composition, good stock solution stability was exhibited, and other evaluations were also good. there were. On the other hand, Comparative Example 9 in which the content of casein protein was as low as 0.427% by weight was not preferable in terms of the stability of the undiluted solution was significantly lowered and the richness of the whipped cream and the taste of the emulsifier were different. Further, when the total content of potassium and sodium is 1.5 or more with respect to the calcium content, the stock solution stability is good, and when the content ratio is 2.0 or more, the stock solution stability is further good. You can also see that

なお、カゼインタンパク質はカゼインカリウムに89.5重量%、脱脂粉乳に28.5重量%含有されており、各実施例で示したカゼインタンパク質の含有量は、カゼインカリウムに由来するカゼインタンパク質と、脱脂粉乳に由来するカゼインタンパク質の合計量である。 The casein protein is contained in 89.5% by weight of casein potassium and 28.5% by weight in defatted milk powder, and the content of casein protein shown in each example is the casein protein derived from casein potassium and defatted. The total amount of casein protein derived from powdered milk.

(実施例14)
表6の配合に従い、パーム油中融点部の配合量を9.48重量部、パームオレインの配合量を21.55重量部に変更した以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Example 14)
Foamable oil in water as in Example 2, except that the blending amount of the melting point in palm oil was changed to 9.48 parts by weight and the blending amount of palm olein was changed to 21.55 parts by weight according to the formulation shown in Table 6. A molded emulsified oil composition and whipped cream were obtained.

(実施例15)
表6の配合に従い、パーム油中融点部の配合量を25.00重量部、パームオレインの配合量を6.04重量部に変更した以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Example 15)
Foaming oil in water as in Example 2, except that the blending amount of the melting point in palm oil was changed to 25.00 parts by weight and the blending amount of palm olein was changed to 6.04 parts by weight according to the formulation shown in Table 6. A molded emulsified oil composition and whipped cream were obtained.

(比較例10)
表6の配合に従い、パーム油中融点分別油を配合せず、パームオレインの配合量を31.03重量部に変更した以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Comparative Example 10)
Foamable oil-in-water emulsified fat composition as in Example 2, except that the melting point fractionated oil in palm oil was not blended and the blending amount of palm olein was changed to 31.03 parts by weight according to the formulation shown in Table 6. Goods and whipped cream were obtained.

(比較例11)
表6の配合に従い、パーム油中融点分別油の配合量を31.03重量部、パームオレインを配合しなかった以外は、実施例2と同様に、起泡性水中油型乳化油脂組成物及びホイップドクリームを得た。
(Comparative Example 11)
According to the formulation shown in Table 6, the foamable oil-in-water emulsified oil / fat composition and the foaming oil-in-water emulsified oil / fat composition and the oil-in-water emulsion composition were the same as in Example 2 except that the amount of the melting point fractionated oil in palm oil was 31.03 parts by weight and palm olein was not added. Obtained whipped cream.

実施例14〜15及び比較例10〜11で得られた起泡性水中油型乳化油脂組成物について粘度、ボテ、ホイップ時間、及びオーバーランを評価し、また、ホイップドクリームについて、離水耐性、口溶け、コク及び乳化剤の異味を評価し、それらの結果を、実施例2の結果と共に、表6に記載した。 Viscosity, body, whipping time, and overrun were evaluated for the foamable oil-in-water emulsified oil and fat compositions obtained in Examples 14 to 15 and Comparative Examples 10 to 11, and the whipped cream was evaluated for water separation resistance. The taste of melt in the mouth, richness and emulsifier was evaluated, and the results are shown in Table 6 together with the results of Example 2.

Figure 0006788762
Figure 0006788762

表6の結果より以下のことが分かる。パーム油中融点分別油とパームオレインがそれぞれ配合された実施例2、及び14〜15では、パーム中融点分別油とパームオレインの配合比率が変わっても良好な結果を示した。一方、パーム油中融点分別油が配合されていない比較例10では、起泡性がやや不十分で、ホイップドクリームの離水耐性および口溶けの点で好ましくない結果が得られた。また、パームオレインが配合されていない比較例11では、口溶けの点で好ましくない結果が得られた。
The following can be seen from the results in Table 6. In Examples 2 and 14 to 15, in which the melting point fractionated oil in palm oil and palm olein were blended, good results were shown even if the blending ratio of the melting point fractionated oil in palm oil and palm olein was changed. On the other hand, in Comparative Example 10 in which the melting point fractionated oil in palm oil was not blended, the foaming property was slightly insufficient, and unfavorable results were obtained in terms of water separation resistance and melting in the mouth of the whipped cream. Further, in Comparative Example 11 in which palm olein was not blended, an unfavorable result was obtained in terms of melting in the mouth.

Claims (4)

起泡性水中油型乳化油脂組成物全体中、タンパク質溶融塩含有量が0.02重量%未満であり、油脂を25〜50重量%含有し、カゼインタンパク質を0.5〜1.3重量%含有し、カリウムとナトリウムとの合計含有量が0.028〜0.15重量%であり、かつ、C16〜C22の不飽和脂肪酸の結合した脂肪酸エステルである少なくとも1種の乳化剤の合計含有量が0.01〜0.055重量%であり、
前記油脂全体中、エステル交換油含有量が1重量%未満であり、ラウリン系油脂を3.7〜25重量%、パーム油中融点部を25〜80重量%、パームオレインを15〜65重量%、及び、ハイエルシン菜種極度硬化油を0.3〜1.8重量%含有し、
前記油脂の構成脂肪酸全体中、トランス脂肪酸含有量が1重量%未満で、かつ飽和脂肪酸含有量が47〜65重量%である、起泡性水中油型乳化油脂組成物。
The content of molten protein salt is less than 0.02% by weight, 25 to 50% by weight of fat and oil, and 0.5 to 1.3% by weight of casein protein in the whole foamable oil-in-water emulsified fat and oil composition. The total content of at least one emulsifier which is a fatty acid ester in which the total content of potassium and sodium is 0.028 to 0.15% by weight and the unsaturated fatty acid of C 16 to C 22 is bound. The amount is 0.01 to 0.055% by weight,
The transesterification oil content is less than 1% by weight in the whole oil and fat, 3.7 to 25% by weight of laurin-based oil and fat, 25 to 80% by weight of the melting point in palm oil, and 15 to 65% by weight of palm olein. , And, containing 0.3 to 1.8% by weight of extremely hardened oil of high-elsin rapeseed,
A foamable oil-in-water emulsified fat / oil composition having a trans fatty acid content of less than 1% by weight and a saturated fatty acid content of 47 to 65% by weight in the total constituent fatty acids of the fats and oils.
起泡性水中油型乳化油脂組成物全体中、カリウムとナトリウムとの合計含有量がカルシウムの含有量に対して1.5〜2.9である、請求項1に記載の起泡性水中油型乳化油脂組成物。 The foamable oil-in-water oil according to claim 1, wherein the total content of potassium and sodium in the whole foaming oil-type emulsified oil / fat composition is 1.5 to 2.9 with respect to the content of calcium. Molded emulsified oil composition. 前記パーム油中融点部と前記パームオレインとの合計含有量が前記油脂全体中73.2〜96重量%である、請求項1又は2に記載の起泡性水中油型乳化油脂組成物。 The foamable oil-in-water emulsified oil / fat composition according to claim 1 or 2, wherein the total content of the melting point in palm oil and the palm olein is 73.2 to 96% by weight in the whole oil / fat. 請求項1〜3の何れか1項に記載の起泡性水中油型乳化油脂組成物がホイップされたホイップドクリーム。 A whipped cream to which the foamable oil-in-water emulsified oil / fat composition according to any one of claims 1 to 3 is whipped.
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