JP2016007153A - Oil-in-water type emulsified fat composition having foamability - Google Patents

Oil-in-water type emulsified fat composition having foamability Download PDF

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JP2016007153A
JP2016007153A JP2014128503A JP2014128503A JP2016007153A JP 2016007153 A JP2016007153 A JP 2016007153A JP 2014128503 A JP2014128503 A JP 2014128503A JP 2014128503 A JP2014128503 A JP 2014128503A JP 2016007153 A JP2016007153 A JP 2016007153A
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oil
fat composition
milk
weight
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崇至 柳田
Takashi Yanagida
崇至 柳田
山本 章博
Akihiro Yamamoto
章博 山本
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Kaneka Corp
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Abstract

PROBLEM TO BE SOLVED: To provide an oil-in-water type emulsified fat composition having foamability, which is not affected from aggregation and scorching of heat-denatured proteins caused by high temperature sterilization such as HTST sterilization and UHT sterilization, even with no use of molten salt or sugar alcohol, having a good flavor with excellent emulsion stability and whipping properties; and a whipped cream made by whipping the same.SOLUTION: An oil-in-water type emulsified fat composition having foamability, which contains substantially no sugar alcohol and no molten salt, 0.01 wt.% or less of sodium caseinate, 2 to 4 wt.% of milk protein, 0.3 to 0.9 wt.% of whey protein, and 0.1 to 1 wt.% of potassium caseinate relative to the whole oil-in-water type emulsified fat composition having foamability, is whipped.

Description

本発明は、起泡性水中油型乳化油脂組成物及びそれをホイップしてなるホイップドクリームに関する。   The present invention relates to a foamable oil-in-water emulsified oil and fat composition and a whipped cream obtained by whipping it.

水中油型乳化油脂組成物の製造においては、加熱による殺菌や滅菌処理、中でも高温短時間(HTST)殺菌や超高温瞬間(UHT)殺菌処理時に生じる蛋白質の熱変性による凝集や焦げ付きに起因する不溶物が付着し、連続製造が困難になるばかりではなく、製品中に凝集物や焦げが混入して、商品価値が損なわれてしまう。そこで、熱変性を防ぐ目的でリン酸塩等の各種溶融塩が添加されている。しかしながら、前記溶融塩を添加すると、好ましくない特有の異味が付与されてしまい食品本来の風味が損なわれること、また近年、健康志向が高まっていることから、消費者より前記溶融塩の使用量を低減することが求められている。   In the production of oil-in-water emulsified oils and fat compositions, insolubility due to heat sterilization and sterilization, especially aggregation and scorching due to heat denaturation of proteins that occur during high temperature short time (HTST) sterilization and ultra high temperature instant (UHT) sterilization. Not only does the product adhere to it, but continuous production becomes difficult, and agglomerates and scorch are mixed in the product, resulting in a loss of commercial value. Therefore, various molten salts such as phosphates are added for the purpose of preventing heat denaturation. However, when the molten salt is added, an unpleasant peculiar taste is imparted and the original flavor of the food is impaired, and in recent years, health-consciousness has been increasing. There is a need to reduce it.

これらの問題を解決する態様として、各種溶融塩を含まず、乳蛋白質含量が1.8重量%以下且つホエー蛋白質含量が0.3重量%以下で、カゼインナトリウムを0.15〜0.5重量%含む水中油型乳化油脂組成物が記載されている(特許文献1)。しかし、乳蛋白質含量と耐熱性の低いホエー蛋白質の含有量が少ないために蛋白質の熱変性による凝集や焦げ付きに起因する不溶物は発生しにくいものの、蛋白質含量が少ないため乳化安定性に劣り、且つ風味が弱いという問題がある。また、乳蛋白質含有水中油型乳化物を製造する際、合成乳化剤および蛋白溶融塩を使用しなくても水相中に糖アルコールを含有させ、且つUHT殺菌処理後に均質化処理を施すことによって、乳蛋白質の熱変性による不溶化が抑制され、凝集物やコゲが製品中に混入しない、乳蛋白質含有水中油型乳化物が記載されている(特許文献2)。しかし、凝集や焦げ付きの抑制効果は十分ではなく、更に、糖アルコールを多く含む為、摂取しすぎると緩下を誘発する問題や糖アルコールの種類によっては食品添加物表示が必要となる問題がある。   As an embodiment for solving these problems, various molten salts are not included, the milk protein content is 1.8 wt% or less, the whey protein content is 0.3 wt% or less, and sodium caseinate is 0.15 to 0.5 wt%. % Oil-in-water emulsified oil / fat composition is described (Patent Document 1). However, since the milk protein content and the low heat-resistant whey protein content are small, insoluble matter due to aggregation and scorching due to heat denaturation of the protein is difficult to occur, but because the protein content is small, the emulsion stability is poor, and There is a problem that the flavor is weak. Further, when producing a milk protein-containing oil-in-water emulsion, by containing a sugar alcohol in the aqueous phase without using a synthetic emulsifier and a protein molten salt, and performing a homogenization treatment after UHT sterilization treatment, A milk protein-containing oil-in-water emulsion in which insolubilization due to heat denaturation of milk protein is suppressed and aggregates and koge are not mixed in the product is described (Patent Document 2). However, the effect of suppressing aggregation and scorching is not sufficient, and furthermore, since it contains a lot of sugar alcohol, there is a problem of inducing laxation if it is consumed too much, and there is a problem that a food additive label is required depending on the type of sugar alcohol .

特開平10-215783号公報Japanese Patent Laid-Open No. 10-215783 特開平10-304821号公報Japanese Patent Laid-Open No. 10-304821

本発明の目的は、溶融塩や糖アルコールを使用しなくても、HTST殺菌やUHT殺菌などの高温殺菌処理時に生じる蛋白質の熱変性による凝集や焦げ付きの影響が無く、風味が良好で且つ乳化安定性とホイップ性に優れた起泡性水中油型乳化油脂組成物及びこれをホイップしてなるホイップドクリームを提供することである。   The object of the present invention is that there is no influence of aggregation and scorching due to heat denaturation of proteins generated during high-temperature sterilization treatment such as HTST sterilization and UHT sterilization without using molten salt or sugar alcohol, and the flavor is good and the emulsion is stable. It is providing the foamable oil-in-water type emulsified oil-fat composition excellent in the property and whipping property, and the whipped cream formed by whipping this.

本発明者らは上記課題を解決するために鋭意研究を重ねた結果、起泡性水中油型乳化油脂組成物全体中、糖アルコール、溶融塩の何れも実質的に含有せず、カゼインナトリウム含有量を特定量以下としても、乳蛋白質、ホエー蛋白質及びカゼインカリウムをそれぞれ特定量含有させることにより、HTST殺菌やUHT殺菌処理時に生じる蛋白質の熱変性による凝集や焦げの影響が無く、風味が良好で、且つ優れた乳化安定性とホイップ性をもつ起泡性水中油型乳化油脂組成物を得ることができることを見出し、本発明を完成するに至った。   As a result of intensive studies to solve the above problems, the present inventors have found that the entire foamable oil-in-water emulsified fat composition contains substantially no sugar alcohol or molten salt, and contains sodium caseinate. Even if the amount is less than a specific amount, the milk protein, whey protein and casein potassium are contained in specific amounts, so that there is no influence of aggregation and scorching due to heat denaturation of proteins generated during HTST sterilization and UHT sterilization treatment, and the flavor is good. And it discovered that the foamable oil-in-water type emulsified oil-fat composition which has the outstanding emulsification stability and whip property can be obtained, and came to complete this invention.

即ち、本発明の第一は、起泡性水中油型乳化油脂組成物全体中、糖アルコール及び溶融塩を実質的に含有せず、カゼインナトリウム含量が0.01重量%以下で、乳蛋白質を2〜4重量%且つホエー蛋白質を0.3〜0.9重量%含有し、さらにカゼインカリウムを0.1〜1重量%含有することを特徴とする起泡性水中油型乳化油脂組成物に関する。好ましい実施態様は、起泡性水中油型乳化油脂組成物全体中の油脂含量が15〜45重量%である上記記載の起泡性水中油型乳化油脂組成物に関する。本発明の第二は、上記記載の起泡性水中油型乳化油脂組成物をホイップしてなるホイップドクリームに関する。   That is, the first of the present invention is that the entire foamable oil-in-water emulsified fat composition is substantially free of sugar alcohol and molten salt, has a sodium caseinate content of 0.01% by weight or less, and contains milk protein. The present invention relates to a foamable oil-in-water emulsified oil and fat composition comprising 2 to 4% by weight, whey protein in an amount of 0.3 to 0.9% by weight, and further containing 0.1 to 1% by weight of casein potassium. . A preferred embodiment relates to the foamable oil-in-water emulsified oil / fat composition as described above, wherein the oil / fat content in the whole foamable oil-in-water emulsified oil / fat composition is 15 to 45% by weight. The second of the present invention relates to a whipped cream obtained by whipping the foamable oil-in-water emulsified fat composition described above.

本発明に従えば、溶融塩や糖アルコールを使用しなくても、HTST殺菌やUHT殺菌などの高温殺菌処理時に生じる蛋白質の熱変性による凝集や焦げ付きの影響が無く、風味が良好で且つ乳化安定性とホイップ性に優れた起泡性水中油型乳化油脂組成物及びこれをホイップしてなるホイップドクリームを提供することができる。   According to the present invention, there is no influence of aggregation or scorching due to heat denaturation of proteins generated during high-temperature sterilization treatment such as HTST sterilization or UHT sterilization without using molten salt or sugar alcohol, and the flavor is good and the emulsion is stable. A foamable oil-in-water emulsified oil / fat composition excellent in properties and whipping properties and a whipped cream obtained by whipping the composition can be provided.

以下、本発明につき、さらに詳細に説明する。本発明の起泡性水中油型乳化油脂組成物は、糖アルコール、溶融塩の何れも実質的に含有せず、カゼインナトリウム含有量を特定量以下とし、乳蛋白質、ホエー蛋白質及びカゼインカリウムをそれぞれ特定量含有することを特徴とする。そして前記起泡性水中油型乳化油脂組成物をホイップすることでホイップドクリームを得ることができる。   Hereinafter, the present invention will be described in more detail. The foamable oil-in-water emulsified oil / fat composition of the present invention substantially contains neither sugar alcohol nor molten salt, sodium casein content is a specific amount or less, milk protein, whey protein and casein potassium are each It is characterized by containing a specific amount. And whipped cream can be obtained by whipping the said foamable oil-in-water type emulsified fat composition.

本発明中の起泡性水中油型乳化油脂組成物において、糖アルコールは、消化管で吸収されにくいため、一度に多量に摂取するとお腹が一時的に緩くなることがあり、また種類によっては食品添加物表示が必要となるため、その含有量は少ないほど良く、起泡性水中油型乳化油脂組成物全体中に0.01重量%以下が好ましく、全く含有しないことがより好ましい。   In the foamable oil-in-water emulsified oil / fat composition of the present invention, sugar alcohol is difficult to be absorbed in the digestive tract, so if a large amount is ingested at one time, the stomach may become temporarily loose, and depending on the type, Since additive labeling is required, the lower the content, the better. The total amount of the foamable oil-in-water emulsified oil / fat composition is preferably 0.01% by weight or less, and more preferably not contained at all.

前記糖アルコールは食品に使用できるものであれば何でも良く、例えば、還元水飴、還元澱粉糖化物、還元乳糖、トレハロース、エリスリトール、ソルビトール等が挙げられる。   The sugar alcohol may be anything as long as it can be used in foods, and examples thereof include reduced starch syrup, reduced starch saccharified product, reduced lactose, trehalose, erythritol, and sorbitol.

本発明中の起泡性水中油型乳化油脂組成物において、溶融塩は、風味に悪影響を及ぼす場合や、健康上好ましくない場合があるため、その含有量は少ないほど良く、起泡性水中油型乳化油脂組成物全体中に0.01重量%以下が好ましく、全く含有しないことがより好ましい。   In the foamable oil-in-water emulsified oil / fat composition in the present invention, the molten salt may adversely affect the flavor or may be unfavorable for health. The total amount of the emulsified fat / oil composition is preferably 0.01% by weight or less, and more preferably not contained at all.

前記溶融塩は、具体的にはリン酸ナトリウム、ポリリン酸ナトリウム、トリポリリン酸ナトリウム、メタリン酸ナトリウム、ヘキサメタリン酸ナトリウム、クエン酸三ナトリウム、クエン酸一カリウム、クエン酸三カリウム等が挙げられる。更に、コハク酸、乳酸、炭酸、酢酸等の有機酸のアルカリ金属塩等が挙げられる。   Specific examples of the molten salt include sodium phosphate, sodium polyphosphate, sodium tripolyphosphate, sodium metaphosphate, sodium hexametaphosphate, trisodium citrate, monopotassium citrate, tripotassium citrate and the like. Furthermore, alkali metal salts of organic acids such as succinic acid, lactic acid, carbonic acid, and acetic acid are exemplified.

本発明の起泡性水中油型乳化油脂組成物で用いられる乳蛋白質は、乳製品に含まれている蛋白質のことを意味し、カゼイン蛋白質、ホエー蛋白質などが挙げられる。乳蛋白質を含む乳原料としては特に制限はなく、例えば、バターミルク、チーズ、クリームチーズ、濃縮ホエー、ホエー、生乳、牛乳、特別牛乳、生山羊乳、殺菌山羊乳、生めん羊乳、部分脱脂乳、脱脂乳、加工乳、乳飲料、濃縮乳、脱脂濃縮乳、無糖練乳、無糖脱脂練乳、加糖練乳、加糖脱脂練乳、発酵乳又はそれらの粉体や、ホエー蛋白質濃縮物(WPC)、トータルミルクプロテイン等が乳蛋白質の供給源として挙げられる。   The milk protein used in the foamable oil-in-water emulsified oil / fat composition of the present invention means a protein contained in a dairy product, and examples thereof include casein protein and whey protein. There are no particular restrictions on milk materials containing milk protein, such as buttermilk, cheese, cream cheese, concentrated whey, whey, raw milk, milk, special milk, raw goat milk, pasteurized goat milk, raw noodle milk, and partially skimmed milk. Skim milk, processed milk, milk beverage, concentrated milk, skim concentrated milk, sugar-free condensed milk, sugar-free skimmed condensed milk, sweetened condensed milk, sugar-free skimmed condensed milk, fermented milk or powder thereof, whey protein concentrate (WPC), A total milk protein etc. are mentioned as a milk protein supply source.

前記乳蛋白質の含有量は、起泡性水中油型乳化油脂組成物全体中2〜4重量%が好ましく、2〜3重量%がより好ましい。2重量%より少ないと乳化安定性が悪くなる場合がある。4重量%より多いと蛋白質の熱変性による凝集や焦げ付きが発生したり、起泡性水中油型乳化油脂組成物のホイップ時間が極端に長くなったり、得られたホイップドクリームのコシが弱くなったりする場合がある。   The content of the milk protein is preferably 2 to 4% by weight, more preferably 2 to 3% by weight in the whole foamable oil-in-water emulsified oil / fat composition. If it is less than 2% by weight, the emulsion stability may deteriorate. If it exceeds 4% by weight, aggregation and scorching due to heat denaturation of the protein occur, the whipping time of the foamable oil-in-water emulsified oil and fat composition becomes extremely long, and the resulting whipped cream becomes weak Sometimes.

本発明の起泡性水中油型乳化油脂組成物で用いられるホエー蛋白質は、乳蛋白質の中でも、牛乳からカゼイン蛋白質や脂肪を取り除いた液体であるホエーに含まれる蛋白質であり、具体的にはα−ラクトアルブミン、β−ラクトグロブリン、血清アルブミン、免疫グロブリン、ラクトフェリン、トラスフェリンなどが挙げられる。ホエー蛋白質の供給源としては、特に制限はなく、例えば、バターミルク、濃縮ホエー、ホエー、生乳、牛乳、特別牛乳、生山羊乳、殺菌山羊乳、生めん羊乳、部分脱脂乳、脱脂乳、加工乳、乳飲料、濃縮乳、脱脂濃縮乳、無糖練乳、無糖脱脂練乳、加糖練乳、加糖脱脂練乳、発酵乳等又はそれらの粉体や、WPC、トータルミルクプロテイン等が挙げられる。   The whey protein used in the foamable oil-in-water emulsified oil / fat composition of the present invention is a protein contained in whey, which is a liquid obtained by removing casein protein and fat from milk among milk proteins, specifically α -Lactalbumin, β-lactoglobulin, serum albumin, immunoglobulin, lactoferrin, trassferin and the like. The source of whey protein is not particularly limited. For example, buttermilk, concentrated whey, whey, raw milk, milk, special milk, raw goat milk, pasteurized goat milk, raw noodle milk, partially skimmed milk, skimmed milk, processed milk Examples include milk, milk drinks, concentrated milk, defatted concentrated milk, sugar-free condensed milk, sugar-free defatted condensed milk, sweetened condensed milk, sugar-free defatted condensed milk, fermented milk and the like, powders thereof, WPC, total milk protein, and the like.

前記ホエー蛋白質の含有量は、起泡性水中油型乳化油脂組成物全体中0.3〜0.9重量%が好ましく、0.3〜0.5重量%がより好ましい。0.3重量%より少ないと、牛乳や脱脂粉乳、バターミルクパウダー等の乳風味を付与する原料を十分に配合できなくなる場合がある。0.9重量%より多いとホエー蛋白質の熱変性による凝集や焦げ付きが発生したり、起泡性水中油型乳化油脂組成物のホイップ時間が極端に長くなったり、得られたホイップドクリームのコシが弱くなる場合がある。   The content of the whey protein is preferably 0.3 to 0.9% by weight, more preferably 0.3 to 0.5% by weight, based on the entire foamable oil-in-water emulsified oil / fat composition. If it is less than 0.3% by weight, raw materials imparting milk flavor such as milk, skim milk powder and buttermilk powder may not be sufficiently blended. If it is more than 0.9% by weight, the whey protein may be agglomerated or burnt due to thermal denaturation, the whipping time of the foamable oil-in-water emulsified oil / fat composition may be extremely long, or the resulting whipped cream may be May become weaker.

本発明の起泡性水中油型乳化油脂組成物で用いられるカゼインカリウムは、牛乳中の全蛋白質の約80%を占めるカゼイン蛋白質を、酢酸、乳酸、塩酸等の酸の添加により等電点沈澱させて牛乳中より凝固分離せしめ、これを再び、水に分散せしめた後に、水酸化カリウムを添加して中和反応を行うことで得られるものである。   Casein potassium used in the foamable oil-in-water emulsified oil and fat composition of the present invention comprises isoelectric point precipitation by adding casein protein, which accounts for about 80% of the total protein in milk, by adding an acid such as acetic acid, lactic acid or hydrochloric acid. It is obtained by coagulating and separating from milk and dispersing it again in water and then adding potassium hydroxide to carry out a neutralization reaction.

前記カゼインカリウムの含有量は、起泡性水中油型乳化油脂組成物全体中0.1〜1重量%であることが好ましく、0.2〜0.6重量%がより好ましく、0.2〜0.4重量%が更に好ましい。0.1重量%より少ないと乳化が不安定になる場合があり、1重量%より多いと起泡性水中油型乳化油脂組成物のホイップ時間が極端に長くなる場合や、得られるホイップドクリームのコシが弱くなる場合がある。   The content of the casein potassium is preferably 0.1 to 1% by weight, more preferably 0.2 to 0.6% by weight, and more preferably 0.2 to 0.6% by weight in the entire foamable oil-in-water emulsified oil / fat composition. 0.4% by weight is more preferred. When the amount is less than 0.1% by weight, the emulsification may become unstable. When the amount is more than 1% by weight, the whipped time of the foamable oil-in-water emulsified oil / fat composition may be extremely long, or the whipped cream obtained. The stiffness may be weak.

本発明中の起泡性水中油型乳化油脂組成物において、カゼインナトリウムは、風味に悪影響を及ぼす場合があることや、消費者にその添加を好まれない場合があるため、その含有量は少ないほど好ましく、起泡性水中油型乳化油脂組成物全体中に0.01重量%以下が好ましく、全く含有しないことがより好ましい。   In the foamable oil-in-water emulsified oil / fat composition in the present invention, casein sodium has a low content because it may adversely affect the flavor or the consumer may not like its addition. More preferably, it is preferably 0.01% by weight or less in the whole foamable oil-in-water emulsified oil and fat composition, and more preferably not contained at all.

前記カゼインナトリムは、酢酸、乳酸、塩酸等の酸の添加により等電点沈澱させて牛乳中よりカゼイン蛋白質を凝固分離せしめ、これを再び、水に分散せしめた後に、水酸化ナトリウムを添加して中和反応を行うことで得られるものである。   The casein sodium is isoelectrically precipitated by the addition of acids such as acetic acid, lactic acid, and hydrochloric acid to coagulate and separate the casein protein from the milk, and this is dispersed again in water, and then sodium hydroxide is added. It is obtained by performing a neutralization reaction.

本発明の起泡性水中油型乳化油脂組成物に用いられる油脂としては、通常、食品に用いられる油脂であれば特に制限はなく、具体的には、亜麻仁油、桐油、サフラワー油、かや油、胡桃油、芥子油、向日葵油、綿実油、菜種油、大豆油、辛子油、カポック油、米糠油、胡麻油、落花生油、オリーブ油、椿油、茶油、ひまし油、椰子油、パーム油、パーム核油、葡萄油、カカオ脂、シア脂、コクム脂、ボルネオ脂等の植物油脂や、乳脂肪、魚油、鯨油、牛脂、豚脂、鶏油、卵黄油、羊油等の動物油脂等が挙げられ、また、これらの油脂をエステル交換したものや、硬化、分別したものやその混合油等を挙げられる。   The oil used in the foamable oil-in-water emulsified oil / fat composition of the present invention is not particularly limited as long as it is usually used in foods. Specifically, flaxseed oil, tung oil, safflower oil, Oil, walnut oil, coconut oil, sunflower oil, cottonseed oil, rapeseed oil, soybean oil, peanut oil, kapok oil, rice bran oil, sesame oil, peanut oil, olive oil, coconut oil, tea oil, castor oil, coconut oil, palm oil, palm kernel Examples include vegetable oils such as oil, coconut oil, cacao butter, shea fat, coconut fat, and borneo fat, and animal fats such as milk fat, fish oil, whale oil, beef fat, pork fat, chicken oil, egg yolk oil, and sheep oil. Also, those obtained by transesterification of these oils and fats, those obtained by curing and fractionation, and mixed oils thereof can be mentioned.

前記油脂の含有量は、起泡性水中油型乳化油脂組成物全体中に15〜45重量%が好ましく、20〜40重量%がより好ましく、25〜35重量%が更に好ましい。15重量%より少ないと起泡性水中油型乳化油脂組成物のホイップ時間が極端に長くなったり、得られるホイップドクリームのコシが弱くなる場合がある。45重量%より多いと乳化安定性が悪くなる場合がある。   The content of the oil / fat is preferably 15 to 45% by weight, more preferably 20 to 40% by weight, and still more preferably 25 to 35% by weight in the entire foamable oil-in-water emulsified oil / fat composition. If it is less than 15% by weight, the whipping time of the foamable oil-in-water emulsified oil / fat composition may be extremely long, or the resulting whipped cream may be weak. If it exceeds 45% by weight, the emulsion stability may deteriorate.

本発明の起泡性水中油型乳化油脂組成物には、必要に応じてさらに、起泡性水中油型乳化油脂組成物に通常配合される成分を含有することができる。例えば、糖質、無脂乳固形分、乳化剤、増粘剤、着色料や香料、クエン酸、グルコン酸、コハク酸、乳酸、炭酸、酢酸などの有機酸等が挙げられる。   The foamable oil-in-water emulsified oil / fat composition of the present invention may further contain components usually blended in the foamable oil-in-water emulsified oil / fat composition as necessary. Examples thereof include saccharides, non-fat milk solids, emulsifiers, thickeners, colorants and fragrances, citric acid, gluconic acid, succinic acid, lactic acid, carbonic acid, and organic acids such as acetic acid.

前記記載の糖質としては、砂糖、果糖、ブドウ糖、水飴、はちみつ、異性化糖、転化糖、オリゴ糖(イソマルトオリゴ糖、還元キシロオリゴ糖、還元ゲンチオオリゴ糖、キシロオリゴ糖、ゲンチオオリゴ糖、ニゲロオリゴ糖、テアンデオリゴ糖、大豆オリゴ糖等)、砂糖結合水飴、澱粉、デキストリン等を挙げることができ、粉糖でも液糖でも構わない。また糖質の代わりにアスパルテーム、アセスルファムカリウム、スクラロース、アリテーム、ネオテーム、カンゾウ抽出物(グリチルリチン)、サッカリン、サッカリンナトリウム、ステビア抽出物、ステビア粉末等の甘味成分などを用いても良い。   The sugars described above include sugar, fructose, glucose, syrup, honey, isomerized sugar, invert sugar, oligosaccharide (isomaltooligosaccharide, reduced xylo-oligosaccharide, reduced gentio-oligosaccharide, xylo-oligosaccharide, gentio-oligosaccharide, nigerooligosaccharide, theande-oligosaccharide Sugar, soybean oligosaccharide, etc.), sugar-bound starch syrup, starch, dextrin and the like, and powdered sugar or liquid sugar may be used. Moreover, sweet ingredients such as aspartame, acesulfame potassium, sucralose, aritem, neotame, licorice extract (glycyrrhizin), saccharin, saccharin sodium, stevia extract, stevia powder, etc. may be used instead of carbohydrates.

前記記載の無脂乳固形分としては、灰分、乳糖等が挙げられる。   Examples of the non-fat milk solids described above include ash and lactose.

前記記載の乳化剤としては、ポリグリセリン脂肪酸エステル、グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、大豆レシチン、卵黄レシチン、及びこれらの分画レシチン、更には酵素分解したリゾレシチンといった改質レシチンなどのレシチン類等が挙げられる。   Examples of the emulsifier described above include polyglycerin fatty acid ester, glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, soybean lecithin, egg yolk lecithin, and fractionated lecithins thereof, as well as enzymatically decomposed lysolecithin. Examples include lecithins such as modified lecithin.

前記記載の増粘剤としては、ジェランガム、グアーガム、キサンタンガム、寒天、ペクチン、アルギン酸ナトリウム、カラギーナン、ローカストビーンガム、アラビアガム、カルボキシメチルセルロース、ヒドロキシメチルセルロース、結晶セルロース、微結晶セルロース等が挙げられる。   Examples of the thickener described above include gellan gum, guar gum, xanthan gum, agar, pectin, sodium alginate, carrageenan, locust bean gum, gum arabic, carboxymethylcellulose, hydroxymethylcellulose, crystalline cellulose, microcrystalline cellulose and the like.

前記記載の着色料や香料は食品用であれば特に制限はなく、必要に応じて適宜使用することができる。   The colorants and fragrances described above are not particularly limited as long as they are for food, and can be appropriately used as necessary.

本発明の起泡性水中油型乳化油脂組成物の製造例を以下に示すが、特に制限されるものではなく、公知の方法により製造することができる。例えば、油脂、乳化剤等の油系原料を混合して50〜80℃に加温溶解した油相部と、水溶性乳化剤や蛋白質などの水系原料を50〜70℃の温水に攪拌溶解した水相部とを予備乳化し、その後、均質化、殺菌、均質化、冷却などの通常行われる各処理を行うことにより、本発明の起泡性水中油型乳化油脂組成物を得ることができる。   Although the manufacture example of the foamable oil-in-water type emulsified oil-fat composition of this invention is shown below, it does not restrict | limit in particular, It can manufacture by a well-known method. For example, an oil phase part in which oil-based raw materials such as fats and oils and emulsifiers are mixed and dissolved by heating to 50 to 80 ° C., and an aqueous phase in which water-based raw materials such as water-soluble emulsifiers and proteins are stirred and dissolved in hot water at 50 to 70 ° C. The foamable oil-in-water emulsified oil / fat composition of the present invention can be obtained by pre-emulsifying the components and then performing usual treatments such as homogenization, sterilization, homogenization, and cooling.

前記均質化処理は、通常行われる方法であれば何でも良く、高圧ホモジナイザーの使用が一般的である。   The homogenization treatment may be any method that is normally performed, and a high-pressure homogenizer is generally used.

前記殺菌処理は、通常行われる方法であれば何でも良いが、蛋白質の熱変性による凝集や焦げ付きの発生しやすいHTST殺菌やUHT殺菌などの高温殺菌処理を実施した際に、本発明の効果をより顕著に得ることができる。   The sterilization treatment may be any method as long as it is performed normally. However, when the high-temperature sterilization treatment such as HTST sterilization or UHT sterilization, which is likely to cause aggregation or scorching due to heat denaturation of proteins, is performed, the effect of the present invention is further improved. Remarkably can be obtained.

前記冷却処理は、通常行われる方法であれば何でもよく、例えばプレート冷却、蒸発冷却、チューブ冷却などが挙げられる。   The cooling treatment may be any method that is normally performed, and examples thereof include plate cooling, evaporative cooling, and tube cooling.

そして、得られた起泡性水中油型乳化油脂組成物をオープン式ホイッパーや密閉式連続ホイップマシンを用いて、トッピングするのに適度な硬さに到達するまでホイップすることにより、ホイップドクリームを得ることができる。また、ホイップは、起泡性水中油型乳化油脂組成物単独でも、他の素材を混合しても良い。混合できる素材としては、通常使用されるものであれば何でもよく、例えば、砂糖、グラニュー糖、トレハロースなどの糖質の他に、牛乳、脱脂乳、脱脂濃縮乳、練乳、カスタードクリーム、生クリーム、チョコレート、フルーツソース、洋酒などが挙げられる。   And by whipping the obtained foamable oil-in-water emulsified oil and fat composition using an open-type whipper or a closed-type continuous whipping machine until reaching a suitable hardness for topping, a whipped cream is obtained. Can be obtained. The whip may be a foamable oil-in-water emulsified oil or fat composition alone or may be mixed with other materials. As a material that can be mixed, any material can be used as long as it is normally used.For example, in addition to sugars such as sugar, granulated sugar and trehalose, milk, skim milk, skim concentrated milk, condensed milk, custard cream, fresh cream, Chocolate, fruit sauce, Western liquor and so on.

以下に実施例を示し、本発明をより具体的に説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、実施例において「部」や「%」は重量基準である。   EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited to these examples. In the examples, “parts” and “%” are based on weight.

<加熱殺菌時のスケール発生に関する評価>
加熱殺菌時のスケール発生の有無は、実施例及び比較例で得られた起泡性水中油型乳化油脂組成物100Kgを100L/Hの流速でUHT殺菌処理(スチームインジェクション:140℃で4秒間ホールド)した際の殺菌前後の水運転時スチ−ムインジェクション部入り口圧力の上昇幅、及びUHT殺菌機のインジェクション部へのスケールの付着度合の目視観察により評価した。その際の評価基準は、以下の通りである。なお、前記スケールとは、加熱殺菌処理時に生じる蛋白質の熱変性による凝集や焦げ付きに起因する不溶物を指す。
◎:UHT殺菌による圧力の上昇幅が0.01MPa未満であり、インジェクション部へのスケールの付着がなく、生産には問題が全くない。
○:UHT殺菌による圧力の上昇幅が0.01MPa以上0.03MPa未満であり、インジェクション部へのスケールの付着がほとんどなく、生産には問題ない。
△:UHT殺菌による圧力の上昇幅が0.03MPa以上0.06MPa未満であり、インジェクション部へのスケールの付着が若干見られるが、安定生産に影響を与えるほどではない。
×:UHT殺菌による圧力の上昇幅が0.06MPa以上であり、インジェクション部へのスケールの付着が多く見られ、安定生産できない。
<Evaluation of scale generation during heat sterilization>
Presence or absence of scale generation during heat sterilization is determined by UHT sterilization treatment (steam injection: 140 ° C. for 4 seconds) at a flow rate of 100 L / H of the foamable oil-in-water emulsified oil / fat composition obtained in Examples and Comparative Examples. ) At the time of water operation before and after sterilization, the increase in the pressure at the inlet of the steam injection part and the degree of adhesion of the scale to the injection part of the UHT sterilizer were evaluated by visual observation. The evaluation criteria at that time are as follows. In addition, the said scale refers to the insoluble matter resulting from the aggregation and scorching by the heat denaturation of the protein produced at the time of a heat sterilization process.
(Double-circle): The raise of the pressure by UHT sterilization is less than 0.01 MPa, there is no adhesion of the scale to an injection part, and there is no problem in production.
○: The pressure increase due to UHT sterilization is 0.01 MPa or more and less than 0.03 MPa, there is almost no adhesion of scale to the injection part, and there is no problem in production.
(Triangle | delta): The increase width of the pressure by UHT disinfection is 0.03 Mpa or more and less than 0.06 Mpa, and some adhesion of the scale to an injection part is seen, but it is not so much that it affects stable production.
X: The increase in pressure due to UHT sterilization is 0.06 MPa or more, the scale is often attached to the injection part, and stable production cannot be achieved.

<乳化安定性の評価>
乳化安定性は、100ccビーカーに60gの水中油型乳化油脂組成物を入れ、15℃の恒温槽で1時間温調した後、それを直径4cmの撹拌ペラで120rpm、20℃の条件で攪拌し、流動性が無くなるまでに要する時間(分)を測定した。測定結果を元に、下記の評価基準に基づき、乳化安定性を評価した。
◎:60分以上で、極めて乳化安定性が良い。
○:30分以上60分未満で、乳化安定性が良い。
△:10分以上30分未満で、乳化安定性に問題はない。
×:10分未満で、乳化安定性が悪い。
<Evaluation of emulsion stability>
Emulsification stability was determined by placing 60 g of an oil-in-water emulsified oil and fat composition in a 100 cc beaker and controlling the temperature for 1 hour in a constant temperature bath at 15 ° C., and then stirring the mixture at 120 rpm and 20 ° C. with a 4 cm diameter stirring blade. The time (minutes) required until fluidity disappeared was measured. Based on the measurement results, the emulsion stability was evaluated based on the following evaluation criteria.
A: The emulsion stability is very good in 60 minutes or more.
○: 30 minutes or more and less than 60 minutes and good emulsion stability.
(Triangle | delta): It is 10 minutes or more and less than 30 minutes, and there is no problem in emulsification stability.
X: Less than 10 minutes, the emulsion stability is poor.

<ホイップ時間の測定>
ホイップ時間は、縦型ミキサー(「CS型20」、関東混合機工業株式会社製)にワイヤーホイッパーを取り付け、実施例及び比較例で得られた起泡性水中油型乳化油脂組成物4.0Kgとグラニュー糖320gを混合し、452rpmでホイップし、トッピングするのに適度な硬さに到達するまでの時間を評価値とした。ここで、トッピングするのに適度な硬さとは、ホイップ直後のサンプルを容器に入れ、クリープメーター(「RE2−33005S」、株式会社山電製)を用いてプランジャー(円柱状、直径16mm)を速度5mm/sの速さで1cm貫入した際、その最大荷重が0.20〜0.40N程度になる硬さを指す。
<Measurement of whip time>
The whip time was 4.0 kg of the foamable oil-in-water emulsified oil and fat composition obtained in the examples and comparative examples obtained by attaching a wire whipper to a vertical mixer (“CS type 20”, manufactured by Kanto Blender Kogyo Co., Ltd.). And 320 g of granulated sugar were mixed, whipped at 452 rpm, and the time taken to reach a suitable hardness for topping was taken as the evaluation value. Here, the hardness suitable for topping means that the sample immediately after whipping is put in a container, and a plunger (column shape, diameter 16 mm) is used with a creep meter ("RE2-30005S", manufactured by Yamaden Co., Ltd.). When 1 cm penetrates at a speed of 5 mm / s, the maximum load is about 0.20 to 0.40 N.

<オーバーランの測定>
オーバーランに関しては、縦型ミキサー(「CS型20」、関東混合機工業株式会社製)にワイヤーホイッパーを取り付け、実施例及び比較例で得られた起泡性水中油型乳化油脂組成物4.0Kgとグラニュー糖320gを混合し、452rpmで、トッピングするのに適度な硬さに到達するまでホイップし、次式に従ってオーバーランを求めた。
オーバーラン(%)=[(一定容積の起泡性水中油型乳化油脂組成物とグラニュー糖の混合液の質量)−(一定容積のホイップドクリームの質量)]÷(一定容積のホイップドクリームの質量)×100
<Measurement of overrun>
For overrun, a foam whirl-in-water emulsified oil / fat composition obtained in Examples and Comparative Examples is obtained by attaching a wire whipper to a vertical mixer (“CS type 20”, manufactured by Kanto Blender Kogyo Co., Ltd.). 0 Kg and granulated sugar 320 g were mixed, whipped at 452 rpm until reaching a suitable hardness for topping, and overrun was determined according to the following formula.
Overrun (%) = [(mass of a mixture of a certain volume of foamable oil-in-water emulsified oil and fat composition and granulated sugar) − (mass of a certain volume of whipped cream)] ÷ (constant volume of whipped cream Mass) x 100

<ホイップドクリームのコシの測定>
ホイップドクリームのコシに関しては、ホイップドクリームを35cm×25cmのステンレス製の平板に絞り、平板の片側を5cm持ち上げ、落とした時にどの程度形状を維持しているかを目視で確認し、下記の評価基準に基づき、ホイップドクリームのコシを評価した。
◎:ほとんど型崩れせず良好な状態を維持しており、極めてコシが良い。
○:わずかに型崩れをするが、良好な状態を維持しており、コシが良い。
△:少し型崩れをするが、概ね良好な状態を維持しており、コシに問題はない。
×:型崩れを起こし、形状を維持できておらず、コシが悪い。
<Measurement of stiffness of whipped cream>
Regarding the stiffness of the whipped cream, the whipped cream was squeezed to a 35 cm x 25 cm stainless steel plate, one side of the plate was lifted by 5 cm, and visually checked how much the shape was maintained when dropped, the following evaluation Based on the criteria, the firmness of the whipped cream was evaluated.
(Double-circle): The shape does not almost lose shape and is maintaining a favorable state, and it is extremely good.
○: Slightly out of shape, but maintains a good state and is firm.
Δ: Although the shape is slightly lost, it is generally maintained in a good state and there is no problem with stiffness.
X: The shape is lost, the shape is not maintained, and the stiffness is bad.

<ホイップドクリームの風味の評価>
実施例及び比較例で得られたホイップドクリームの異味の程度及び乳風味の強さに関し、熟練したパネラー10名による官能評価を以下の基準により実施し、それらの平均点を評価値とした。なお、ここで異味とは、起泡性水中油型乳化油脂組成物にとって好ましくない味を指す。その際の評価基準は下記の通りである。
(異味の程度)
5点:異味が全く感じられない。
4点:異味が僅かに感じられる。
3点:異味を感じる。
2点:異味を強く感じる。
1点:異味を極めて強く感じる。
(乳風味の強さ)
5点:乳風味を極めて強く感じる。
4点:乳風味を強く感じる。
3点:乳風味を感じる。
2点:乳風味を僅かに感じる。
1点:乳風味が感じられない。
<Evaluation of flavor of whipped cream>
The sensory evaluation by 10 skilled panelists was performed according to the following criteria regarding the degree of off-flavor and milk flavor strength of the whipped creams obtained in Examples and Comparative Examples, and the average score was used as the evaluation value. In addition, an unpleasant taste here refers to the taste unpreferable for a foamable oil-in-water type emulsified oil-fat composition. The evaluation criteria at that time are as follows.
(Degree of taste)
5 points: No nasty taste is felt.
4 points: A slightly different taste is felt.
3 points: I feel a strange taste.
2 points: A strong taste is felt.
1 point: I feel a very strong taste.
(Strength of milk flavor)
5 points: Milk flavor is very strong.
4 points: A strong milk flavor is felt.
3 points: Feels milk flavor.
2 points: A slight milk flavor is felt.
1 point: No milk flavor is felt.

(実施例1)
表1に示す配合に従い、硬化パーム核油(融点36℃)4.0重量部、パーム核油22.0重量部、硬化パームオレイン(融点31℃)4.0重量部及び菜種油2.0重量部にポリグリセリン脂肪酸エステル(HLB値12)0.10重量部、ショ糖脂肪酸エステル(HLB値1)ポリグリセリン脂肪酸エステル(HLB値3)0.02重量部、大豆レシチン0.17重量部を添加し、65℃で溶解して油相部とした。一方、脱脂粉乳(乳蛋白質35.6重量%、ホエー蛋白質7.1重量%)6.0重量部、カゼインカリウム(乳蛋白質89.5重量%)0.35重量部、乳糖0.6重量部、ポリグリセリン脂肪酸エステル(HLB値8)0.1重量部、ショ糖脂肪酸エステル(HLB値7)0.01重量部、デキストリン1.5重量部、セルロース0.35重量部を、表1の配合と最終的に同じになるようにスチームインジェクション(蒸気加熱工程)による水分増加量を考慮した量の60℃の温水に溶解して水相部を作製した。
Example 1
According to the formulation shown in Table 1, hardened palm kernel oil (melting point 36 ° C.) 4.0 parts by weight, palm kernel oil 22.0 parts by weight, hardened palm olein (melting point 31 ° C.) 4.0 parts by weight, and rapeseed oil 2.0 weights. 0.10 parts by weight of polyglycerol fatty acid ester (HLB value 12), 0.02 parts by weight of polyglycerol fatty acid ester (HLB value 3), and 0.17 parts by weight of soybean lecithin And it melt | dissolved at 65 degreeC and it was set as the oil phase part. On the other hand, skim milk powder (milk protein 35.6% by weight, whey protein 7.1% by weight) 6.0 parts by weight, casein potassium (milk protein 89.5% by weight) 0.35 parts by weight, lactose 0.6 parts by weight , 0.1 parts by weight of polyglycerol fatty acid ester (HLB value 8), 0.01 part by weight of sucrose fatty acid ester (HLB value 7), 1.5 parts by weight of dextrin, 0.35 parts by weight of cellulose, And an aqueous phase part was prepared by dissolving in 60 ° C. warm water in an amount taking into account the increased amount of water due to steam injection (steam heating process) so that the water phase was finally the same.

前記の油相部と水相部を20分間予備乳化後、高周速回転式乳化機(「クレアミックス」、エム・テクニック株式会社製)を用いて周速31.4m/sの回転速度で微細化した後、高圧ホモジナイザーを用いて1段目2MPa/2段目1MPaの圧力で処理した後に、プレート式加熱機を用いて90℃まで予備加熱した後、UHT殺菌機(スチームインジェクション)を用いて140℃で4秒間殺菌処理し、プレート式冷却機を用いて60℃まで冷却し、再び高圧ホモジナイザーを用いて1段目6MPa/2段目2MPaの圧力で処理し、その後、プレート式冷却機で5℃まで冷却したものを容器に充填し、起泡性水中油型乳化油脂組成物を得た。得られた水中油型乳化油脂組成物の、各乳蛋白質の含量、加熱殺菌時のスケール発生の程度及び乳化安定性の評価結果について表1にまとめた。得られた起泡性水中油型乳化油脂組成物は、スケールの発生がなく、乳化安定性は極めて良好であった。   After pre-emulsifying the oil phase part and the aqueous phase part for 20 minutes, using a high peripheral speed rotary emulsifier ("CLEAMIX", manufactured by M Technique Co., Ltd.) at a peripheral speed of 31.4 m / s. After miniaturization, after processing at a pressure of 1 MPa at the first stage / 2 MPa at the second stage using a high-pressure homogenizer, preheating to 90 ° C. using a plate type heater, and then using a UHT sterilizer (steam injection) Sterilized at 140 ° C. for 4 seconds, cooled to 60 ° C. using a plate type cooler, treated again with a high pressure homogenizer at a pressure of 6 MPa in the first stage / 2 MPa in the second stage, and then a plate type cooler The container cooled to 5 ° C. was filled in a container to obtain a foamable oil-in-water emulsified oil / fat composition. Table 1 summarizes the content of each milk protein, the degree of scale generation during heat sterilization, and the evaluation results of the emulsion stability of the obtained oil-in-water emulsified oil / fat composition. The obtained foamable oil-in-water emulsified oil / fat composition did not generate scale and had very good emulsification stability.

Figure 2016007153
Figure 2016007153

(実施例2〜7)
表1に示す配合に従い、各配合量を変更し、ホエー蛋白濃縮物を配合する場合には水相に添加し、水で全体量を調整した以外は、実施例1と同様の方法で起泡性水中油型乳化油脂組成物を得た。得られた水中油型乳化油脂組成物の、各乳蛋白質の含量、加熱殺菌時のスケール発生の程度及び乳化安定性の評価結果について表1にまとめた。
(Examples 2 to 7)
In accordance with the formulation shown in Table 1, each compounding amount was changed, and when adding a whey protein concentrate, it was added to the aqueous phase and foamed in the same manner as in Example 1 except that the total amount was adjusted with water. Oil-in-water emulsified oil and fat composition was obtained. Table 1 summarizes the content of each milk protein, the degree of scale generation during heat sterilization, and the evaluation results of the emulsion stability of the obtained oil-in-water emulsified oil / fat composition.

表1を見ると、得られた起泡性水中油型乳化油脂組成物(実施例1〜7)は、乳蛋白質含量が2〜4重量%、且つホエー蛋白質が0.3〜0.9重量%、且つカゼインカリウムが0.1〜1重量%、カゼインナトリウム0.01重量%以下の範囲では何れもスケールの発生が少なく安定生産が可能なレベルであり、乳化安定性にも優れていた。   Referring to Table 1, the obtained foamable oil-in-water emulsified oil / fat composition (Examples 1 to 7) had a milk protein content of 2 to 4% by weight and a whey protein of 0.3 to 0.9% by weight. %, Potassium casein in the range of 0.1 to 1% by weight, and sodium casein in an amount of 0.01% by weight or less, the scale generation was small and stable production was possible, and the emulsion stability was excellent.

(比較例1)
表1に示す配合に従い、カゼインカリウムを配合せず、水で全体量を調整した以外は、実施例1と同様の方法で起泡性水中油型乳化油脂組成物を得た。得られた水中油型乳化油脂組成物の、各乳蛋白質の含量、加熱殺菌時のスケール発生の程度及び乳化安定性の評価結果について表1にまとめた。表1の通り、スケールの発生はみられなかった一方で、乳化安定性が極めて悪かった。
(Comparative Example 1)
In accordance with the formulation shown in Table 1, a foamable oil-in-water emulsified oil and fat composition was obtained in the same manner as in Example 1 except that potassium casein was not added and the total amount was adjusted with water. Table 1 summarizes the content of each milk protein, the degree of scale generation during heat sterilization, and the evaluation results of the emulsion stability of the obtained oil-in-water emulsified oil / fat composition. As shown in Table 1, no scale was observed, but the emulsion stability was extremely poor.

(比較例2)
表1に示す配合に従い、脱脂粉乳及びカゼインカリウムの配合量を変更し、水で全体量を調整した以外は、実施例1と同様の方法で起泡性水中油型乳化油脂組成物を得た。得られた水中油型乳化油脂組成物の各乳蛋白質の含量、加熱殺菌時のスケール発生の程度及び乳化安定性の評価結果について表1にまとめた。表1の通り、スケールは発生せず、乳化安定性も良好であった。
(Comparative Example 2)
According to the formulation shown in Table 1, a foamable oil-in-water emulsified oil and fat composition was obtained in the same manner as in Example 1 except that the blended amounts of skim milk powder and potassium casein were changed and the total amount was adjusted with water. . Table 1 summarizes the content of each milk protein in the obtained oil-in-water emulsified oil and fat composition, the degree of scale generation during heat sterilization, and the evaluation results of the emulsion stability. As shown in Table 1, no scale was generated and the emulsion stability was good.

(比較例3)
表1に示す配合に従い、脱脂粉乳及びカゼインカリウムの配合量を変更し、水で全体量を調整した以外は、実施例1と同様の方法で起泡性水中油型乳化油脂組成物を得た。得られた水中油型乳化油脂組成物の各乳蛋白質の含量、加熱殺菌時のスケール発生の程度及び乳化安定性の評価結果について表1にまとめた。表1の通り、乳蛋白質含量が4.23重量%である比較例3の起泡性水中油型乳化油脂組成物は、インジェクション部へのスケールの付着が多く見られ、安定して生産するには問題があるものであった。
(Comparative Example 3)
According to the formulation shown in Table 1, a foamable oil-in-water emulsified oil and fat composition was obtained in the same manner as in Example 1 except that the blended amounts of skim milk powder and potassium casein were changed and the total amount was adjusted with water. . Table 1 summarizes the content of each milk protein in the obtained oil-in-water emulsified oil and fat composition, the degree of scale generation during heat sterilization, and the evaluation results of the emulsion stability. As shown in Table 1, the foamable oil-in-water emulsified oil / fat composition of Comparative Example 3 having a milk protein content of 4.23% by weight has a large amount of scale adhering to the injection part and can be stably produced. Was a problem.

(比較例4) 特開平10-215783号公報に準拠
表1に示す配合に従い、脱脂粉乳の配合量を変更し、カゼインカリウムをカゼインナトリウムに変えて、水で全体量を調整した以外は、実施例1と同様の方法で起泡性水中油型乳化油脂組成物を得た。得られた水中油型乳化油脂組成物の、各乳蛋白質の含量、加熱殺菌時のスケール発生の程度及び乳化安定性の評価結果について表1にまとめた。表1の通り、スケールの発生は殆んどなかったものの、乳化安定性が悪かった。
(Comparative example 4) Compliant with JP-A-10-215783 According to the formulation shown in Table 1, except for changing the blending amount of skim milk powder, changing the casein potassium to casein sodium, and adjusting the total amount with water. A foamable oil-in-water emulsified oil / fat composition was obtained in the same manner as in Example 1. Table 1 summarizes the content of each milk protein, the degree of scale generation during heat sterilization, and the evaluation results of the emulsion stability of the obtained oil-in-water emulsified oil / fat composition. As shown in Table 1, although there was almost no generation of scale, the emulsion stability was poor.

(実施例8〜14)
実施例1〜7で得られ、5℃に維持されていた起泡性水中油型乳化油脂組成物4.0Kgと、グラニュー糖320gとを混合し、カントーミキサー(「CS型20」、関東混合機工業株式会社製)を用いて452rpmでトッピングするのに適度な硬さに到達するまでホイップしホイップドクリームを得た。得られたホイップドクリームのホイップ時間、オーバーラン、ホイップドクリームのコシ、異味の程度、乳風味の強さを評価し、その結果を表1にまとめた。
(Examples 8 to 14)
4.0 kg of the foamable oil-in-water emulsified oil composition obtained in Examples 1 to 7 and maintained at 5 ° C. and 320 g of granulated sugar were mixed together, and a Can Tho mixer (“CS type 20”, Kanto mix) Was whipped until reaching a suitable hardness for topping at 452 rpm. The whipped cream thus obtained was evaluated for whipping time, overrun, stiffness of whipped cream, degree of off-taste, and strength of milk flavor, and the results are summarized in Table 1.

表1の通り、乳蛋白質含量が2〜4重量%、ホエー蛋白質が0.3〜0.9重量%、カゼインカリウムが0.1〜1重量%の範囲にある起泡性水中油型乳化油脂組成物(実施例1〜7)をホイップして得られたホイップドクリームは、何れもホイップ時間が長すぎず、オーバーランの値はホイップドクリームとして好ましい範囲内であり、ホイップドクリームのコシは好ましく、異味が全くない若しくは殆どなく、乳風味の強い、極めて好ましいホイップドクリームであった。   As shown in Table 1, a foamable oil-in-water emulsified fat having a milk protein content of 2 to 4% by weight, whey protein of 0.3 to 0.9% by weight, and casein potassium of 0.1 to 1% by weight. The whipped creams obtained by whipping the compositions (Examples 1 to 7) are not too long in whipping time, and the overrun value is within a preferable range as whipped cream. Was a highly preferred whipped cream with little or no off-taste and a strong milk flavor.

(比較例5)
比較例1で得られ、5℃に維持されていた起泡性水中油型乳化油脂組成物を用いて実施例8〜14と同様にしてホイップドクリームの作製を試みたが、乳化安定性が極めて悪く増粘したため、起泡性水中油型乳化油脂組成物が得られず、評価できなかった。
(Comparative Example 5)
Production of whipped cream was attempted in the same manner as in Examples 8 to 14 using the foamable oil-in-water emulsified oil composition obtained in Comparative Example 1 and maintained at 5 ° C. Since the viscosity increased extremely badly, a foamable oil-in-water emulsified fat composition could not be obtained and could not be evaluated.

(比較例6)
比較例2で得られ、5℃に維持されていた起泡性水中油型乳化油脂組成物を用いてそれぞれ実施例8〜14と同様にしてホイップドクリームを得、その結果を表1にまとめた。表1の通り、起泡性水中油型乳化油脂組成物(比較例2)をホイップして得られたホイップドクリームはホイップ時間、オーバーラン、コシの評価は良好であったものの、乳風味が弱く、満足できる風味ではなかった。
(Comparative Example 6)
Using the foamable oil-in-water emulsified oil composition obtained in Comparative Example 2 and maintained at 5 ° C., whipped cream was obtained in the same manner as in Examples 8 to 14, and the results are summarized in Table 1. It was. As shown in Table 1, the whipped cream obtained by whipping the foamable oil-in-water emulsified oil / fat composition (Comparative Example 2) had a good whipping time, overrun, and stiffness, but had a milk flavor. The flavor was weak and not satisfactory.

(比較例7)
比較例3で得られ、5℃に維持されていた起泡性水中油型乳化油脂組成物を用いてそれぞれ実施例8〜14と同様にしてホイップドクリームを得、その結果を表1にまとめた。表1の通り、起泡性水中油型乳化油脂組成物(比較例3)をホイップして得られたホイップドクリームは、風味及びオーバーランは比較的良好であったものの、ホイップ時間は長く、コシの評価も悪く、満足できる物性ではなかった。
(Comparative Example 7)
Using the foamable oil-in-water emulsified oil composition obtained in Comparative Example 3 and maintained at 5 ° C., whipped creams were obtained in the same manner as in Examples 8 to 14 and the results are summarized in Table 1. It was. As shown in Table 1, the whipped cream obtained by whipping the foamable oil-in-water emulsified oil and fat composition (Comparative Example 3) had relatively good flavor and overrun, but the whipping time was long. Koshi's evaluation was bad and the physical properties were not satisfactory.

(比較例8)
比較例4で得られ、5℃に維持されていた起泡性水中油型乳化油脂組成物を用いてそれぞれ実施例8〜14と同様にしてホイップドクリームを得、その結果を表1にまとめた。表1の通り、起泡性水中油型乳化油脂組成物(比較例4)をホイップして得られたホイップドクリームは、ホイップ時間、オーバーラン、コシの評価は良好であったものの、カゼインナトリウム独特の異味が強く感じられ、満足できる風味ではなかった。
(Comparative Example 8)
Using the foamable oil-in-water emulsified oil composition obtained in Comparative Example 4 and maintained at 5 ° C., whipped cream was obtained in the same manner as in Examples 8 to 14, and the results are summarized in Table 1. It was. As shown in Table 1, the whipped cream obtained by whipping the foamable oil-in-water emulsified oil / fat composition (Comparative Example 4) showed good evaluation of whipping time, overrun and stiffness, but sodium caseinate. A unique taste was felt strongly, and it was not a satisfactory flavor.

Claims (3)

起泡性水中油型乳化油脂組成物全体中、糖アルコール及び溶融塩を実質的に含有せず、カゼインナトリウム含量が0.01重量%以下で、乳蛋白質を2〜4重量%且つホエー蛋白質を0.3〜0.9重量%含有し、さらにカゼインカリウムを0.1〜1重量%含有することを特徴とする起泡性水中油型乳化油脂組成物。 In the whole foamable oil-in-water emulsified oil / fat composition, sugar alcohol and molten salt are not substantially contained, sodium casein content is 0.01% by weight or less, milk protein is 2 to 4% by weight and whey protein is added. A foamable oil-in-water emulsified oil / fat composition containing 0.3 to 0.9% by weight and further containing 0.1 to 1% by weight of casein potassium. 起泡性水中油型乳化油脂組成物全体中の油脂含量が15〜45重量%である請求項1に記載の起泡性水中油型乳化油脂組成物。 2. The foamable oil-in-water emulsified oil / fat composition according to claim 1, wherein the total content of the foamable oil-in-water emulsified oil / fat composition is 15 to 45 wt%. 請求項1又は2に記載の起泡性水中油型乳化油脂組成物をホイップしてなるホイップドクリーム。 The whipped cream formed by whipping the foamable oil-in-water type emulsified oil-fat composition of Claim 1 or 2.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107027898A (en) * 2017-04-26 2017-08-11 上海海融食品科技股份有限公司 One kind is planted butter cream and its ultra high temperature short time sterilization preparation method
JP2017184637A (en) * 2016-04-01 2017-10-12 株式会社Adeka Foamable oil-in-water type emulsified oil and fat composition
JP2019129791A (en) * 2018-02-01 2019-08-08 森永乳業株式会社 Composition for forming foam, long life food, foamed product, food, and manufacturing method therefor
WO2019189727A1 (en) * 2018-03-29 2019-10-03 株式会社カネカ Foamable oil-in-water type emulsified oil or fat composition
JP2019172377A (en) * 2016-04-07 2019-10-10 大日本印刷株式会社 Cleaning and sterilization method of beverage filling device and device thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017184637A (en) * 2016-04-01 2017-10-12 株式会社Adeka Foamable oil-in-water type emulsified oil and fat composition
JP2019172377A (en) * 2016-04-07 2019-10-10 大日本印刷株式会社 Cleaning and sterilization method of beverage filling device and device thereof
CN107027898A (en) * 2017-04-26 2017-08-11 上海海融食品科技股份有限公司 One kind is planted butter cream and its ultra high temperature short time sterilization preparation method
JP2019129791A (en) * 2018-02-01 2019-08-08 森永乳業株式会社 Composition for forming foam, long life food, foamed product, food, and manufacturing method therefor
WO2019189727A1 (en) * 2018-03-29 2019-10-03 株式会社カネカ Foamable oil-in-water type emulsified oil or fat composition

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