WO2015025730A1 - Whipped cream and method for producing same - Google Patents

Whipped cream and method for producing same Download PDF

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Publication number
WO2015025730A1
WO2015025730A1 PCT/JP2014/070905 JP2014070905W WO2015025730A1 WO 2015025730 A1 WO2015025730 A1 WO 2015025730A1 JP 2014070905 W JP2014070905 W JP 2014070905W WO 2015025730 A1 WO2015025730 A1 WO 2015025730A1
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WIPO (PCT)
Prior art keywords
oil
mass
weight
whipped cream
less
Prior art date
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PCT/JP2014/070905
Other languages
French (fr)
Japanese (ja)
Inventor
加藤 健二
Original Assignee
株式会社カネカ
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 株式会社カネカ filed Critical 株式会社カネカ
Priority to JP2014559595A priority Critical patent/JP5721918B1/en
Priority to CN201480045837.6A priority patent/CN105473000B/en
Publication of WO2015025730A1 publication Critical patent/WO2015025730A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/003Compositions other than spreads
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L19/00Products from fruits or vegetables; Preparation or treatment thereof
    • A23L19/03Products from fruits or vegetables; Preparation or treatment thereof consisting of whole pieces or fragments without mashing the original pieces
    • A23L19/07Fruit waste products, e.g. from citrus peel or seeds
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L19/00Products from fruits or vegetables; Preparation or treatment thereof
    • A23L19/09Mashed or comminuted products, e.g. pulp, purée, sauce, or products made therefrom, e.g. snacks
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L23/00Soups; Sauces; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L9/00Puddings; Cream substitutes; Preparation or treatment thereof
    • A23L9/20Cream substitutes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L9/00Puddings; Cream substitutes; Preparation or treatment thereof
    • A23L9/20Cream substitutes
    • A23L9/22Cream substitutes containing non-milk fats but no proteins other than milk proteins

Definitions

  • the present invention relates to whipped cream and a method for producing the same, and more particularly to a whipped cream that can be distributed at room temperature and a method for producing the same.
  • Whipped cream is widely used as a filling material in bakery products such as bread and confectionery, and in foods such as baked goods such as pudding and mousse.
  • the whipped cream includes a water-in-oil type cream (so-called butter cream) and an oil-in-water type cream.
  • Water-in-oil type creams have been widely used in ordinary temperature distribution foods such as bread and confectionery because of their good stability at normal temperatures.
  • the water-in-oil type cream has a problem in that the use of fats and oils with a high melting point deteriorates mouth melting.
  • Patent Document 1 discloses a polyglycerin fatty acid ester containing 50% by weight or more of a lauric fat and oil in a fat and oil component, an oily phase having a specific SFC value, a protein component and a sugar phase, and a polymerization degree of 4 to 10. Are mixed as an emulsifier, pre-emulsified, homogenized, and sterilized, and a method for producing an oil-in-water emulsified fat having a foaming property with a water activity value of 0.96 or less is disclosed.
  • Patent Document 2 discloses that the proportion of lauric acid residues in the total fatty acid residues constituting all triglycerides in fats and oils is 30 to 60% by mass, and the fatty acid residues constituting individual triglycerides in the fats and oils
  • the proportion of the triglycerides having a total number of carbon atoms of 42 to 49 is 20 to 45% by mass of the total triglycerides in the fat and oil, and the number of carbon atoms of the fatty acid residues constituting the individual triglycerides in the fat and oil
  • a foamable oil-in-water emulsified fat / oil composition in which the proportion of triglycerides having a total of 50 to 62 is 4 to 15% by mass of the total triglycerides in the oil or fat.
  • skim milk powder or skim concentrated milk containing casein protein is used as a protein component.
  • the viscosity is set to 2 to 5
  • the desired overrun whipped cream cannot be obtained by thickening, solidifying and whipping.
  • Patent Document 3 as an oil-in-water emulsion that can be whipped by mixing with an acidic taste material, it is composed of 40 to 80% by weight of an aqueous phase and 20 to 60% by weight of an oil phase, and 0.05 to 10% by weight. % Whey protein, 0.2-5% by weight skim milk solids, and an acid-resistant oil-in-water emulsion containing a total phosphate and citrate weight of less than 0.01% by weight is disclosed. ing. However, since the oil-in-water emulsion has a low sugar content, it does not have a quality that allows it to be distributed at room temperature.
  • the product can be stably produced by scorching due to heat sterilization during production. There is a problem that you can not.
  • Patent Document 4 discloses that an oil-in-water emulsion containing water, fats and oils, whey protein, and an emulsifier contains 0.03 to 0.4% by weight of whey protein and does not contain lecithin as an emulsifier.
  • An oil-in-water emulsion having acid resistance and foaming resistance is disclosed, which includes a polyglycerin fatty acid ester whose constituent fatty acid is oleic acid and a sucrose fatty acid ester having an HLB value in the range of 4 to 15.
  • Patent Document 5 discloses fats and oils, protein having a specific mass ratio of casein protein / whey protein, lecithin, a specific average glycerin polymerization degree and a specific HLB polyglycerin saturated fatty acid ester, dietary fiber and / or chemical process.
  • a whipped cream composition containing starch and having a flavor and performance as a normal whipped cream and further having acid resistance and freeze resistance is disclosed.
  • all the examples of Patent Documents 4 and 5 use only hardened palm kernel oil (34 ° C.) or a mixed oil of palm kernel oil and palm kernel hardened oil (8: 2), it is blended with an acidic substance.
  • the whipped cream that has been whipped is harder and easier to tighten with time, and there is a problem that there is a lot of water separation.
  • the object of the present invention is to be able to whip even by mixing various acidic taste materials such as fruit sauce, fruit juice, yogurt, etc., with good mouth-melting and wateriness, excellent shape retention and low temperature separation Whipped cream and a method for producing the same.
  • the present invention includes less than 0.1% by weight of casein protein, 0.1% by weight to 1.0% by weight of whey protein, and 0.05% by weight to 0.5% by weight of polyglycerol fatty acid ester of HLB12 or more.
  • a whipped cream obtained by foaming a mixture comprising a foamable oil-in-water emulsified oil / fat composition and an acidic flavoring material in a weight ratio ranging from 90:10 to 30:70, Including 10% by weight to 30% by weight of fats and oils, 20% by weight to 50% by weight of carbohydrates and 25% by weight to 60% by weight of water, and having a pH of 2.0 to 5.5, 70% by weight or more and 90% by weight or less of palm kernel stearin and coconut oil and / or palm kernel oil, extremely hardened palm oil, extremely hardened low rapeseed oil, and extremely hardened hyelsin rapeseed oil Chosen contains at least one and a 20 / 80-80 / 20 in the range of the mixed oil at a weight ratio
  • 10 g of the whipped cream is put in a plastic cup container, 1 g of the one kept at 25 ° C. for 3 days is taken, and 1 g of a mixture obtained by mixing with 9 g of physiological saline is mixed with 20 g of a standard agar medium. After culturing at 37 ° C. for 2 days, the number of colonies is counted, and the value obtained by multiplying the number of colonies by 10 is 10 4 or less.
  • the present invention comprises less than 0.1% by mass of casein protein, 0.1% by mass to 1.0% by mass of whey protein, and 0.05% by mass to 0.5% by mass of polyglycerol fatty acid ester of HLB12 or more.
  • the step of preparing a foamable oil-in-water emulsified oil / fat composition, a step of preparing an acidic taste material, the foamable oil-in-water emulsified oil / fat composition and the acid taste material are 90:10 to Mixing at a weight ratio in the range of 30:70 to obtain a mixture, and foaming the mixture to obtain a whipped cream, wherein the whipped cream is 10% by weight to 30% by weight of fats and oils, It contains 20% by mass or more and 50% by mass or less of saccharides and 25% by mass or more and 60% by mass or less of water, and has a pH of 2.0 or more and 5.5 or less.
  • the coconut oil and / or palm kernel oil was mixed with at least one selected from the group consisting of extremely hardened palm oil, extremely hardened low rapeseed rapeseed oil and extremely hardened hyelsin rapeseed oil at a mass ratio in the range of 20/80 to 80/20. It is a manufacturing method of whipped cream which contains 10 mass% or more and 30 mass% or less of random transesterification oils of fats and oils.
  • the present invention can be whipped even by mixing various acidic taste materials such as fruit sauce, fruit juice, yogurt, etc., has good mouth melting and wateriness, has excellent shape retention, and can be distributed at room temperature with little water separation. Whipped cream and a method for producing the same can be provided.
  • the whipped cream is formed by foaming a mixture containing a foamable oil-in-water emulsified oil and fat composition and an acidic taste material.
  • the pH of the whipped cream is 2.0 or more and 5.5 or less, preferably 2.5 or more and 5.0 or less, more preferably 3.0 or more and 4.9 or less. If the pH is less than 2.0, the acidity may be too strong. On the other hand, if the pH is more than 5.5, the flavor of the acidic flavoring material may be weak.
  • the pH of the whipped cream is measured using pH METER (“F-52” manufactured by Horiba, Ltd.).
  • the overrun of whipped cream is preferably 100% or more, more preferably 130 to 180%. If the overrun is less than 100%, melting in the mouth may be felt, which is not preferable. Note that the whipped cream overrun is the percentage of the air contained in the whipped cream.
  • the foamable oil-in-water emulsified oil / fat composition and the acidic taste material are mixed to a specific amount, and the resulting mixture is placed in a 100 cm 3 container, Measure.
  • the mixture is whipped until reaching a suitable hardness for topping, and the resulting whipped cream is put into a 100 cm 3 container and the mass is measured. Based on these measured values, the overrun can be obtained by the following equation.
  • Overrun (%) [(mass of a mixture of a certain volume of foamable oil-in-water emulsified oil and fat composition and acidic taste ingredients) ⁇ (mass of a certain volume of whipped cream)] ⁇ (constant volume of whipped Mass of docream) x 100 ⁇ Foaming oil-in-water emulsified oil and fat composition>
  • the foamable oil-in-water emulsified oil / fat composition used for the whipped cream in one embodiment of the present invention includes a water phase mainly composed of water and an oil phase mainly composed of fats and oils. Oil droplets composed of phases are dispersed.
  • the oil phase can contain fats and oils, emulsifiers, fragrances, colorants and the like.
  • Oils and fats include vegetable oils such as rapeseed oil, corn oil, cottonseed oil, palm oil, palm kernel oil, palm oil, soybean oil, sunflower oil, safflower oil, olive oil, milk fat, beef fat, pork fat, fish oil, etc.
  • the animal fats and oils can be exemplified, and those obtained by subjecting these to processing such as hardening, fractionation, and transesterification can also be used. These fats and oils can be used alone or in combination of two or more.
  • palm kernel oil hydrogenated palm kernel oil, palm oil, hydrogenated palm oil, palm kernel olein, palm kernel stearin, hydrogenated palm kernel stearin, palm oil, palm olein, palm double olein, palm mid-melting point and their vegetable properties
  • a partially hardened oil or fat an extremely hardened oil, or a random transesterified oil thereof.
  • it preferably comprises palm kernel stearin and a specific transesterified oil.
  • the transesterified oil is a random transesterified oil of coconut oil and / or palm kernel oil and at least one selected from the group consisting of extremely hardened palm oil, extremely hardened low erucin rapeseed oil and extremely hardened hyelin rapeseed oil.
  • the random transesterified oil comprises 20/80 to 80/20 of coconut oil and / or palm kernel oil and at least one selected from the group consisting of extremely hardened palm oil, extremely hardened low erucin rapeseed oil and extremely hardened hyelin rapeseed oil. Random transesterified oils and fats mixed at a mass ratio in the range are preferable, and the ratio is more preferably 40/60 to 60/40.
  • the method for producing the transesterified oil is not particularly limited, and can be produced using a general method.
  • a chemical method that causes a random transesterification reaction by adding 0.01 to 1.0% by mass of sodium methylate or sodium ethylate with respect to the raw oil or fat an enzymatic method that performs transesterification using an enzyme such as lipase Etc. can be used.
  • the content of the oil and fat is preferably 10% by mass or more and 30% by mass or less, and more preferably 15% by mass or more and 25% by mass or less in the whole whipped cream. If the oil or fat is less than 10% by mass, the overrun may not be increased and the shape retention may be deteriorated. On the other hand, if it exceeds 30% by mass, the melted mouth may be heavy and feel oily.
  • palm kernel stearin 70 mass% or more and 90 mass% or less, palm oil and / or palm kernel oil, extremely hardened palm oil, extremely hardened low rapeseed oil, and extremely hardened It is preferable that 10 mass% or more and 30 mass% or less of random transesterified oil with at least 1 sort (s) chosen from the group which consists of Hyelsin rapeseed oil is included. If the content of palm kernel stearin is less than 70% by mass, the melt in the mouth may be heavy and feel oily, and if it exceeds 90% by mass, it may become hard and easy to tighten after whipping.
  • the random transesterified oil is less than 10% by mass, it may become hard and easy to tighten after whipping, and if it exceeds 30% by mass, the mouth melt may be heavy and feel oily.
  • the content of palm kernel stearin is more preferably 78% by mass to 88% by mass, and the content of random transesterified oil is more preferably 12% by mass to 22% by mass.
  • the oil phase can contain an emulsifier that is soluble in the oil phase. Being soluble in the oil phase means that the HLB of the emulsifier is 8 or less.
  • emulsifiers contained in the oil phase include glycerin fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, soybean lecithin, egg yolk lecithin, fractionated lecithins thereof, and enzymatically decomposed lysolecithin And lecithins such as modified lecithin, and at least one of them can be used. Among these, it is preferable to use lecithin and sucrose fatty acid ester in combination.
  • the content of lecithin is preferably 0.01% by mass or more and 0.15% by mass or less, and more preferably 0.02% by mass or more and 0.1% by mass or less in the entire foamable oil-in-water emulsified oil / fat composition. If it is less than 0.01% by mass, the shape retention may be deteriorated, and if it exceeds 0.15% by mass, the whipped cream may become hard and change easily with time.
  • Emulsion stability can be improved by using sucrose fatty acid ester.
  • the content of the sucrose fatty acid ester is preferably 0.01% by mass or more and 0.2% by mass or less, and more preferably 0.02% by mass or more and 0.15% by mass or less in the entire foamable oil-in-water emulsified oil / fat composition. preferable. If it is less than 0.01% by mass, the emulsion stability may be deteriorated, and if it exceeds 0.2% by mass, bitterness may appear and the flavor may be impaired.
  • the oil phase can contain a coloring agent, a fragrance
  • the colorant and the fragrance are not particularly limited as long as they are for foods, and can be appropriately used as necessary.
  • the aqueous phase can contain water, carbohydrates, milk proteins, emulsifiers and various additives.
  • the aqueous phase contains water.
  • the content of water is preferably 25% by mass or more and 60% by mass or less, and more preferably 30% by mass or more and 50% by mass or less in the whole whipped cream. If it is less than 25% by mass, the wateriness may be impaired, and if it exceeds 60% by mass, it may rot during normal temperature distribution.
  • the aqueous phase contains carbohydrates.
  • Carbohydrates are obtained by removing dietary fiber from carbohydrates, monosaccharides such as glucose and fructose, disaccharides such as sugar, lactose and maltose, polysaccharides more than trisaccharides such as oligosaccharides, dextrin and starch, and reduction.
  • sugar alcohols such as maltose starch syrup, erythritol, xylitol, maltitol, xanthan gum, guar gum, carrageenan, agar, gelatin, tamarind gum, locust bean gum, alginic acids, pectin, cellulose and derivatives thereof.
  • sugars such as glucose, sugar, lactose, maltose and oligosaccharide, and thickeners such as xanthan gum, guar gum and carrageenan.
  • Sugar content is 20% by mass or more and 50% by mass or less in the whole whipped cream, and preferably 30% by mass or more and 40% by mass or less. If it is less than 20% by mass, it may rot during distribution at room temperature, and if it exceeds 50% by mass, the sweetness may become too strong or the wateriness may be impaired.
  • the aqueous phase contains only whey protein or whey protein and casein protein as milk protein.
  • Casein protein is a protein that precipitates when the pH of milk is adjusted to pH 4.6 at 20 ° C., and refers to four types of proteins, ⁇ S1 casein, ⁇ S2 casein, ⁇ casein, ⁇ casein, and ⁇ casein.
  • protein containing casein protein includes raw milk, milk, special milk, partially skimmed milk, skim milk, processed milk, cream, butter, cheese, ice cream, concentrated milk, skimmed concentrated milk, non-sugared milk, and nothing. Derived from milk and dairy products defined in ministerial ordinances (Ministerial Ordinance for Milk) such as sugar skim milk, sweetened milk, sweetened skim milk, whole milk powder, skimmed milk powder, cream powder, etc.
  • Milk protein such as total milk protein separated and fractionated by ion-exchange resin treatment, etc. Milk was added and solubilized by adding salt to casein protein precipitated by acidifying the pH of milk.
  • casein protein salts such as casein sodium, casein calcium, casein potassium, and casein magnesium.
  • Casein protein is preferably as low as possible to impart acid resistance, and its content is preferably less than 0.1% by mass, more preferably less than 0.05% by mass in the entire foamable oil-in-water emulsified fat composition. Most preferably, it does not contain. If the content of casein protein exceeds 0.1% by mass, the acidic taste ingredients are mixed and the pH is adjusted to 2-5 to thicken, solidify, and even when whipped, a desired overrun whipped cream is obtained. It may not be possible.
  • Whey protein is a protein fraction present in whey when milk is adjusted to pH 4.6 at 20 ° C., and examples thereof include cheese whey and casein whey.
  • the whey protein concentrate which is made from milk by desalting, concentrating, drying, and pulverizing the remaining cream, casein fraction, or cheese curd residue, has a high whey protein content and is easy to use. preferable.
  • the content of whey protein is preferably 0.1% by mass or more and 1.0% by mass or less, and more preferably 0.3% by mass or more and 0.8% by mass or less in the entire foamable oil-in-water emulsified oil / fat composition. preferable. If it is less than 0.1% by mass, emulsification may become unstable. If it exceeds 1.0% by mass, there may be cases where the product cannot be stably produced due to scorching due to heat sterilization during the production of the foamable oil-in-water emulsified oil / fat composition.
  • the aqueous phase includes an emulsifier that is soluble in the aqueous phase. Being soluble in the aqueous phase means that the HLB of the emulsifier is 6 or more.
  • the aqueous phase always contains polyglycerin fatty acid ester of HLB 12 or more as an emulsifier.
  • the polyglycerol fatty acid ester is an esterification product of polyglycerol obtained by polymerizing glycerol and a fatty acid.
  • HLB is preferably 12 or more and 18 or less, and more preferably 13 or more and 16 or less. Less than HLB12, when the foaming oil-in-water emulsified oil / fat composition is insufficient in the effect of suppressing scorch during heat sterilization during the production of the foamable oil-in-water emulsified oil / fat composition, and the foamable oil-in-water emulsified oil / fat composition cannot be stably produced There is. Polyglycerol fatty acid esters exceeding HLB18 are not generally sold and are difficult to obtain.
  • the average degree of glycerol polymerization of the polyglycerol fatty acid ester is preferably 6 to 10, and more preferably 10. If the degree of polymerization is less than 6, even if the HLB is 12 or more, the effect of suppressing burning in heat sterilization during production may be insufficient. Those having a degree of polymerization exceeding 10 are generally not sold and are difficult to obtain.
  • the degree of esterification is preferably 1 to 3, and more preferably 1 to 2.
  • the degree of esterification refers to the number of fatty acid molecules bound to one molecule of polyglycerol.
  • the degree of esterification is less than 1, it will contain a large amount of non-esterified polyglycerin, resulting in unstable emulsification, or suppression of scorch during heat sterilization during the production of a foamable oil-in-water emulsified oil composition.
  • the effect may be insufficient.
  • the degree of esterification exceeds 3, even if the HLB is 12 or more, the effect of suppressing scorch during heat sterilization during the production of a foamable oil-in-water emulsified oil and fat composition becomes insufficient.
  • the main constituent fatty acid is preferably stearic acid or oleic acid, more preferably stearic acid.
  • polyglycerin fatty acid esters of HLB 12 or higher examples include hexaglycerin monolaurate, decaglycerin monostearate, etc.
  • hexaglycerin monostearate is particularly prominent in suppressing the burning of proteins during heat sterilization. It is preferable.
  • the content of the polyglycerin fatty acid ester of HLB 12 or more is preferably 0.05% by mass or more and 0.5% by mass or less, and more preferably 0.1% by mass or more and 0.4% in the foamable oil-in-water emulsified oil / fat composition. It is below mass%.
  • the content of the polyglycerin fatty acid ester is less than 0.05% by mass, the effect of suppressing the burning of protein during heat sterilization may be insufficient.
  • it exceeds 0.5 mass% the flavor of a whipped cream may worsen.
  • the aqueous phase can further contain an emulsifier other than the polyglycerin fatty acid ester of HLB 12 or higher.
  • the emulsifier include glycerin fatty acid ester, polyglycerin fatty acid ester of less than HLB 12, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, soybean lecithin, egg yolk lecithin, and fractionated lecithin thereof, and further enzymatic degradation.
  • lecithins such as modified lecithin such as lysolecithin, and at least one of these can be used.
  • sucrose fatty acid esters are preferably used.
  • Emulsion stability can be improved by using sucrose fatty acid ester.
  • the content of the sucrose fatty acid ester is preferably 0.01% by mass or more and 0.2% by mass or less, and more preferably 0.02% by mass or more and 0.15% by mass or less in the entire foamable oil-in-water emulsified oil / fat composition. preferable. If it is less than 0.01% by mass, the emulsion stability may be deteriorated, and if it exceeds 0.2% by mass, bitterness may appear and the flavor may be impaired.
  • the aqueous phase can contain salts, shelf life improvers, colorants and fragrances in addition to casein protein, whey protein, polyglycerin fatty acid ester, saccharide and emulsifier.
  • salts include sodium chloride, potassium chloride, calcium chloride, sodium carbonate, sodium hydrogen carbonate, potassium carbonate, sodium phosphate, sodium hydrogen phosphate, potassium phosphate, potassium hydrogen phosphate, sodium hexanemetaphosphate, sodium citrate , Potassium citrate, calcium citrate, sodium tartrate, potassium tartrate, sodium hydrogen tartrate, potassium hydrogen tartrate, sodium lactate, potassium lactate, sodium malate, potassium malate, sodium succinate, potassium succinate, potassium sorbate, stear
  • Examples thereof include calcium phosphate.
  • the salt content can be appropriately adjusted within a range not impairing the effects of the present invention.
  • shelf life improver examples include glycine, lysozyme, polylysine, sodium acetate and the like.
  • glycine and lysozyme in a mass ratio of 2: 1 to 100: 1 in a range of 0.1% by mass to 5% by mass in the whole whipped cream.
  • the shelf life improver can be added to the aqueous phase of the foamable oil-in-water emulsified oil or fat composition or a mixture containing the foamable oil-in-water emulsified oil and fat composition and the acidic taste material.
  • Coloring and flavoring are not particularly limited as long as they are for food, and can be used as needed.
  • Acidic taste ingredients include strawberry, blueberry, pine, passion fruit, orange, apple, white peach, yellow peach, grape, guava, papaya, melon, watermelon, grapefruit, lemon, mango, raspberry, lychee, apricot, citron, mandarin orange , Kiwi, figs, cassis, acerola, prunes, pears, pears, processed fruit juices, concentrated juices, fruit purees, fruit sauces, jams, pastes, adipic acid, citric acid, gluconic acid, apples
  • organic acids such as acid, tartaric acid, acetic acid, lactic acid, carbonic acid, succinic acid, fumaric acid and phosphoric acid, fermented foods such as yogurt, fermented milk, fermented fruit juice and wine, and beverages such as coffee.
  • the content of the acidic taste material is preferably 10% by mass or more and 70% by mass or less, and preferably 20% by mass or more and 60% by mass or less in the whole whipped cream in order to suitably adjust the pH of the whipped cream. More preferably it is.
  • the mass ratio of the foamable oil-in-water emulsified oil / fat composition to the acidic taste material in the whipped cream is preferably 90:10 to 30:70.
  • the method for producing whipped cream comprises less than 0.1% by weight of casein protein, 0.1% by weight to 1.0% by weight of whey protein, and polyglycerol fatty acid ester 0 of HLB 12 or more.
  • the oil-and-fat random transesterified oil mixed at a mass ratio in the range of 80/20 is contained in an amount of 10% by mass to 30% by mass.
  • Step of preparing a foamable oil-in-water emulsified oil / fat composition First, a predetermined amount of an oil-soluble raw material such as an oil-soluble emulsifier, a fragrance, and a colorant is mixed with an oil and fat heated and melted at 50 to 80 ° C. to obtain an oil phase part.
  • an oil-soluble raw material such as an oil-soluble emulsifier, a fragrance, and a colorant
  • water-based raw materials such as polyglycerin fatty acid esters of HLB 12 or higher, water-soluble emulsifiers, casein proteins, whey proteins, sugars, salts, thickeners, fragrances, etc. are stirred and dissolved in hot water at 50 to 70 ° C. Get the phase.
  • An oil phase part is added to the water phase part and pre-emulsified.
  • each treatment usually performed in the production of a foamable oil-in-water emulsified oil and fat composition such as refinement, homogenization, preheating, sterilization, primary cooling, homogenization, secondary cooling, tertiary cooling, aging, etc.
  • a foamable oil-in-water emulsified oil / fat composition can be obtained.
  • Acidic taste ingredients include strawberry, blueberry, pine, passion fruit, orange, apple, white peach, yellow peach, grape, guava, papaya, melon, watermelon, grapefruit, lemon, mango, raspberry, lychee, apricot, citron, mandarin orange Fruits such as kiwi, fig, cassis, acerola, prunes, pears and pears can be used as they are.
  • fruit juices, concentrated fruit juices, fruit purees, fruit sauces, jams and pastes obtained by processing these fruits can be used.
  • organic acids such as adipic acid, citric acid, gluconic acid, malic acid, tartaric acid, acetic acid, lactic acid, carbonic acid, succinic acid, fumaric acid, phosphoric acid, fermented foods such as yogurt, fermented milk, fermented fruit juice, wine Beverages such as coffee can be used.
  • Step of obtaining a mixture The foaming oil-in-water emulsified oil / fat composition and the acidic taste material are mixed at a weight ratio in the range of 90:10 to 30:70, preferably in the weight ratio of 80:20 to 40:60. Mixing is performed using a mixer or the like to obtain a mixture adjusted to have a pH of 2.0 or more and 5.5 or less.
  • the obtained mixture is whipped using an open whipper or a closed continuous whipping machine until reaching a suitable hardness for topping to obtain a whipped cream.
  • the aqueous phase part was produced by dissolving in the part.
  • the oil phase part was added to the water phase part and mixed, and then pre-emulsified for 20 minutes. Thereafter, the mixture was treated at a pressure of 4 MPa using a high-pressure homogenizer and then sterilized at 142 ° C. for 4 seconds using a UHT sterilizer. Then, it processed with the pressure of 6 MPa again using the high-pressure homogenizer, Then, what was cooled to 5 degreeC with the cooler was filled in the container, and the foamable oil-in-water type emulsified oil-fat composition was obtained.
  • transesterification oil (1) of palm oil and extremely hardened palm oil 70 parts by mass: 30 parts by mass
  • transesterified between palm oil and extremely hardened Hyelsin rapeseed oil 50 parts by mass: 50 parts by mass.
  • a foamable oil-in-water emulsified oil and fat composition was obtained in the same manner as in Production Example 2 except that the oil (2) was changed.
  • transesterification oil (1) of palm oil and extremely hardened palm oil 70 parts by mass: 30 parts by mass
  • palm oil and extremely hardened low rapeseed rapeseed oil 50 parts by mass: 50 parts by mass
  • a foamable oil-in-water emulsified oil and fat composition was obtained in the same manner as in Production Example 2 except that the oil (3) was changed.
  • Palm kernel stearin “Panel kernel stearin” manufactured by Kaneka Corporation (2) Middle melting point of palm: “Middle melting point of palm” manufactured by Kaneka Corporation (3) Transesterified oil (1): “Transesterified oil / fat (transesterified oil / fat of palm oil and extremely hardened palm oil (70 parts by mass: 30 parts by mass))” manufactured by Kaneka Corporation (4) Transesterified oil (2): “Transesterified oil / fat (transesterified oil / fat of coconut oil and extremely hardened Hyelsin rapeseed oil (50 parts by mass: 50 parts by mass))” manufactured by Kaneka Corporation (5) Polyglycerol fatty acid ester (HLB4): “Sunfat PS-66 (average degree of glycerol polymerization: 6, main constituent fatty acid: stearic acid, degree of esterification: 6)” manufactured by Taiyo Kagaku (6) Sucrose fatty acid ester (HLB1): “P-170” manufactured by Mitsubishi Chemical Food
  • Whey protein concentrate “WPC80 (casein protein 0 mass%, whey protein 46.5 mass%)” manufactured by Warrnambool (10) Polyglycerin fatty acid ester (HLB13.4): “MSW-7S (Moisture 60%, polyglycerin fatty acid ester 40%, average degree of glycerin polymerization: 10, produced by Sakamoto Yakuhin Kogyo Co., Ltd.), main constituent fatty acid: stearic acid, esterification Degree: 1) " (11) Polyglycerin fatty acid ester (HLB11.6): “MS-5S (average degree of glycerin polymerization: 6, main constituent fatty acid: stearic acid, degree of esterification: 1)” manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.
  • Sucrose fatty acid ester (HLB16): “P-1670” manufactured by Mitsubishi Chemical Foods (13) Granulated sugar: “Granu Sugar FNGMS” manufactured by Fuji Nippon Seika Co., Ltd. (14) Maltose: “Saint Marto Midori” manufactured by Hayashibara (15) Lactose: “Lactose HILMA FINE GRAIND” manufactured by HILMA (16) Xanthan gum: “Novazan 200 mesh” manufactured by Archer Daniels Midland (17) Guar gum: “Guar gum XS-5000” manufactured by Seiwasha (18) Trisodium citrate: “Purified sodium citrate” manufactured by Fuso Chemical Industry Co., Ltd.
  • Glycine "Glycine” manufactured by Showa Denko (20) Lysozyme: “Egg white lysozyme” manufactured by Eisai Food Chemical Co., Ltd. (24) Hardened palm oil (melting point: 34 ° C.): “Hardened palm oil (melting point: 34 ° C.)” manufactured by Kaneka Corporation (25) Transesterified oil (3): “Transesterified oil and fat (transesterified oil and fat of coconut oil and extremely hardened low rapeseed rapeseed oil (50 parts by mass: 50 parts by mass)” manufactured by Kaneka Corporation (26) Polyglycerin fatty acid ester (HLB8.8): “MO-3S (average degree of glycerin polymerization: 4, main constituent fatty acid: oleic acid, degree of esterification: 1)” manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.
  • Polyglycerin fatty acid ester (HLB12.9): “MO-7S (average glycerin polymerization degree: 10, main constituent fatty acid: oleic acid, esterification degree: 1)” manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.
  • A The rate of increase in pressure due to UHT sterilization is less than 10%, there is no adhesion of protein to the injection part, and there is no problem in production.
  • B The rate of increase in pressure due to UHT sterilization is 10% or more and less than 20%, and a slight amount of protein adheres to the injection part, but there is no problem in production.
  • C The rate of increase in pressure due to UHT sterilization is 20% or more and less than 40%, protein adhesion to the injection part is seen, and there is a problem in stable production.
  • D The rate of increase in pressure due to UHT sterilization is 40% or more, protein adhesion to the injection part is often observed, and stable production cannot be achieved.
  • Production Example 11 was unable to produce a foamable oil-in-water emulsified oil / fat composition because of the large amount of protein adhering to the injection part.
  • Example 1 0.7 kg of the foamable oil-in-water emulsified oil and fat composition prepared in Production Example 13 and 0.3 kg of fruit sauce strawberry were mixed, and Hobart mixer (“N-50 (5 coats)” manufactured by Hobart Japan Co., Ltd.) was whipped until it reached a suitable hardness for topping at 2nd speed to obtain a whipped cream.
  • Hobart mixer (“N-50 (5 coats)” manufactured by Hobart Japan Co., Ltd.) was whipped until it reached a suitable hardness for topping at 2nd speed to obtain a whipped cream.
  • Examples 2 to 9, 14 and 15, Comparative Examples 1 to 4 Whipped cream was prepared in the same manner as in Example 1 except that the type of foamable oil-in-water emulsified oil / fat composition was changed according to the formulation shown in Table 2.
  • Example 18 According to the composition shown in Table 3, whipped cream was prepared by whipping in the same manner as in Example 1 except that the type of acidic taste material was changed.
  • Example 7 (Comparative Examples 7 and 8) Whipped in the same manner as in Example 1 except that the type of foamable oil-in-water emulsified oil and fat composition and the type of acidic taste material were changed according to the formulation shown in Table 3 to produce a whipped cream. .
  • the foaming oil-in-water emulsified oil / fat composition and the acidic taste material are mixed with a Hobart mixer (“N-50 (5 coats)” manufactured by Hobart Japan Co., Ltd.) and whipped at a second speed.
  • the time required to reach an appropriate hardness for topping was taken as the evaluation value.
  • the hardness suitable for topping is a columnar plunger having a diameter of 16 mm using a creep meter ("RE2-30005S", manufactured by Yamaden Co., Ltd.) after putting the sample immediately after whipping into a container.
  • the hardness is such that the maximum load when penetrating 1 cm at a speed of 5 mm / s is 0.30 to 0.40 N.
  • Overrun (%) [(mass of a mixture of a certain volume of foamable oil-in-water emulsified oil and fat composition and acidic taste ingredients) ⁇ (mass of a certain volume of whipped cream)] ⁇ (constant volume of whipped Mass of docream) x 100 ⁇ Evaluation of shape retention of whipped cream>
  • the whipped cream obtained in the examples and comparative examples is packed in a squeezed bag, and the outlet is a star-shaped base (number of cuts: 8).
  • a transparent plastic cup container has a height of about 6 cm and a bottom diameter of about 7 cm. Then, about 40g was squeezed into a triangular pyramid shape while swirling so as not to create a cavity as much as possible, and the height was measured.
  • 70% or more has commercial properties, and less than 70% has no commercial properties.
  • ⁇ Evaluation of water removal from whipped cream> The whipped cream obtained in the examples and comparative examples is packed in a squeezed bag, and the outlet is a star-shaped base (number of cuts: 8).
  • a transparent plastic cup container has a height of about 6 cm and a bottom diameter of about 7 cm. Then, about 40 g was squeezed into a triangular pyramid shape while swirling so as not to create a cavity as much as possible. Thereafter, the mass of water separation accumulated at the bottom of the polycup when stored at 25 ° C. for 24 hours was measured, and the water separation rate (%) relative to the whipped cream was taken as the evaluation value of water separation.
  • C The water separation rate is 5% or more and less than 10%.
  • D The water separation rate is 10% or more.
  • ⁇ Comprehensive evaluation> Based on the evaluation results for hygiene, shape retention, melting in mouth, and wateriness, comprehensive evaluation was performed.
  • the evaluation criteria at that time are as follows.
  • C Hygiene is less than 1000, and one or more is C and the rest is A or B in the evaluation of mold retention, melting in the mouth and wateriness.
  • D Hygiene is 1000 or more, or one or more of the evaluation of mold retention, melting in the mouth, and wateriness is D.
  • Example 2 transesterified oil and fat of coconut oil and extremely hardened palm oil (70 parts by mass: 30 parts by mass)) and 3 (transesterified oil and fat of coconut oil and extremely hardened Hyelsin rapeseed oil (50 parts by mass: 50 parts by mass)) All of the whipped creams had very good evaluation results in all items as in Example 1.
  • the whipped cream of Example 4 was obtained by reducing fats and oils to 15.5% by mass, and although the shape retention was slightly inferior, it was a good result.
  • the whipped cream of Example 9 is obtained by adding a shelf life improver.
  • the number of general viable bacteria is 10 cells / g or less even when stored at 25 ° C. for 5 days. It was.
  • the main constituent fatty acid of the polyglycerin fatty acid ester of HLB 12 or more is oleic acid, and the overrun was lower than that of Example 2 and the wateriness was inferior.
  • the whipped cream of Example 15 was obtained by changing soy lecithin to polyglycerin fatty acid ester whose main constituent fatty acid was oleic acid, and its shape retention was inferior to that of Example 2.
  • the whipped cream of Comparative Example 1 was obtained by adding skim milk powder, increased in viscosity during whipping, reached an overrun of only 90%, and lacked wateriness, which was not preferable.
  • the whipped cream of Comparative Example 2 had a large amount of oil and fat added and a small amount of sugar, and was poorly melted in the mouth. In addition, it was spoiled when stored at 25 ° C. for 3 days.
  • the whipped cream of Comparative Example 3 uses a middle melting point of palm and a transesterified oil of coconut oil and extremely hardened palm oil (70 parts by mass: 30 parts by mass) as fats and oils.
  • the moldability and melting in the mouth were poor, and there was much water separation.
  • the whipped cream of Comparative Example 4 was obtained by using only hardened palm oil / fat as the oil / fat, which became harder with time after whipping and the cream was tightened, and there was much water separation.
  • the whipped creams of Examples 2, 16 and 17 use the foamable oil-in-water emulsified oil / fat composition of Production Example 2 and have a fruit sauce strawberry content in the range of 20 to 50% by mass. It was a good evaluation result.
  • the whipped creams of Comparative Examples 3, 5 and 6 use the foamable oil-in-water emulsified oil / fat composition of Production Example 1 and have a fruit sauce strawberry content in the range of 20 to 50% by mass, In all cases, there was much water separation.
  • Example 18 (acidic taste material is concentrated fruit juice Valencia orange) and Example 19 (acidic taste material is yogurt) has good evaluation results regardless of the blending ratio and type of the acidic taste material. Met.
  • Comparative Example 7 the acidic flavoring material is concentrated fruit juice Valencia Orange
  • Comparative Example 8 the acidic flavoring material is yogurt
  • the whipped cream according to the present invention can be used for topping and filling of room temperature distribution type foods such as bread and pastry as well as eating as it is.

Abstract

 Provided are whipped cream that can be whipped even when an acidic flavoring material is admixed, that melts in the mouth and has good freshness, that has excellent shape retention, and that can flow at normal temperature with little syneresis; and a method for producing the same. Whipped cream obtained by foaming a mixture containing a foamable oil-in-water emulsified fat composition containing less than 0.1 mass% of casein protein, from 0.1 to 1.0 mass% of whey protein, and from 0.05 to 0.5 mass% of polyglycerin fatty acid ester having an HBL of 12 or higher, and an acidic flavoring material in a weight ratio in the 90/10-30/70 range, wherein the whipped cream contains from 10 to 30 mass% of fat, from 20 to 50 mass% of sugar, and from 25 to 60 mass% of water, the pH is from 2.0 to 5.5, and the total fats contain from 70 to 90 mass% of palm kernel stearin and from 10 to 30 mass% of random transesterified oil of fats obtained by mixing coconut oil and/or palm kernel oil and at least one selected from the group consisting of extremely hydrogenated palm oil, extremely hydrogenated low-erucin rapeseed oil, and extremely hydrogenated high-erucin rapeseed oil in a mass ratio in the 20/80-80/20 range.

Description

ホイップドクリームおよびその製造方法Whipped cream and method for producing the same
 本発明はホイップドクリームおよびその製造方法に関し、特に常温流通可能なホイップドクリームおよびその製造方法に関する。 The present invention relates to whipped cream and a method for producing the same, and more particularly to a whipped cream that can be distributed at room temperature and a method for producing the same.
 ホイップドクリームは、パンや洋菓子などのベーカリー製品、あるいはプリンやムースなどの洋生菓子などの食品においてフィリング材として広く用いられている。ホイップドクリームには、油中水型のクリーム(いわゆるバタークリーム)と、水中油型のクリームとがある。油中水型のクリームは、常温での安定性が良好なため、パンや洋菓子などの常温流通型食品において、広く使用されてきた。しかし、油中水型のクリームは融点の高い油脂を使用すると口溶けが悪化するという問題があった。 Whipped cream is widely used as a filling material in bakery products such as bread and confectionery, and in foods such as baked goods such as pudding and mousse. The whipped cream includes a water-in-oil type cream (so-called butter cream) and an oil-in-water type cream. Water-in-oil type creams have been widely used in ordinary temperature distribution foods such as bread and confectionery because of their good stability at normal temperatures. However, the water-in-oil type cream has a problem in that the use of fats and oils with a high melting point deteriorates mouth melting.
 近年、市場の高級化志向と流通網の発達を背景に、常温流通型食品にあっても口溶けが良好で水々しさがあり、フルーツソース、果汁、ヨーグルト等の各種の酸性呈味素材を混合してもホイップできるバラエティー豊かな風味の水中油型のクリームが求められてきた。 In recent years, with the trend toward high-end markets and the development of distribution networks, even ordinary-temperature distribution-type foods have good mouth melting and wateriness, and are mixed with various acidic taste ingredients such as fruit sauce, fruit juice, and yogurt Even so, a variety of flavored oil-in-water creams that can be whipped have been demanded.
 特許文献1には、油脂成分中ラウリン系油脂を50重量%以上含み、且つ特定のSFC値を持つ油脂、蛋白質成分、糖類を含む水相、および重合度が4~10であるポリグリセリン脂肪酸エステルを乳化剤として混合し、予備乳化、均質化、殺菌して、水分活性値が0.96以下の起泡性を有する水中油型乳化油脂の製造方法が開示されている。 Patent Document 1 discloses a polyglycerin fatty acid ester containing 50% by weight or more of a lauric fat and oil in a fat and oil component, an oily phase having a specific SFC value, a protein component and a sugar phase, and a polymerization degree of 4 to 10. Are mixed as an emulsifier, pre-emulsified, homogenized, and sterilized, and a method for producing an oil-in-water emulsified fat having a foaming property with a water activity value of 0.96 or less is disclosed.
 特許文献2には、油脂中の全トリグリセライドを構成する全脂肪酸残基のうちラウリン酸残基の占める割合が30~60質量%であり、且つ該油脂中の個々のトリグリセライドを構成する脂肪酸残基の炭素原子数の合計が42~49であるトリグリセライドの占める割合が油脂中の全トリグリセライドの20~45質量%であり、且つ該油脂中の個々のトリグリセライドを構成する脂肪酸残基の炭素原子数の合計が50~62であるトリグリセライドの占める割合が油脂中の全トリグリセライドの4~15質量%である起泡性水中油型乳化脂用油脂組成物が開示されている。 Patent Document 2 discloses that the proportion of lauric acid residues in the total fatty acid residues constituting all triglycerides in fats and oils is 30 to 60% by mass, and the fatty acid residues constituting individual triglycerides in the fats and oils The proportion of the triglycerides having a total number of carbon atoms of 42 to 49 is 20 to 45% by mass of the total triglycerides in the fat and oil, and the number of carbon atoms of the fatty acid residues constituting the individual triglycerides in the fat and oil There is disclosed a foamable oil-in-water emulsified fat / oil composition in which the proportion of triglycerides having a total of 50 to 62 is 4 to 15% by mass of the total triglycerides in the oil or fat.
 しかし、特許文献1および2のすべての実施例では、蛋白質成分としてカゼイン蛋白質を含有する脱脂粉乳や脱脂濃縮乳を使用しているため、水中油型乳化油脂に酸性呈味素材を混合してpHを2~5にすると増粘、固化し、ホイップしても所望のオーバーランのホイップドクリームを得ることはできない。 However, in all Examples of Patent Documents 1 and 2, skim milk powder or skim concentrated milk containing casein protein is used as a protein component. When the viscosity is set to 2 to 5, the desired overrun whipped cream cannot be obtained by thickening, solidifying and whipping.
 特許文献3には、酸性呈味素材と混合してホイップできる水中油型乳化物として、40~80重量%の水相と、20~60重量%の油相からなり、0.05~10重量%の乳清蛋白質、0.2~5重量%の脱脂乳固形を含み、リン酸塩およびクエン酸塩の総重量が0.01重量%未満である耐酸性の水中油型乳化物が開示されている。しかし、該水中油型乳化物は糖質の含有量が少ないため、常温流通できる品質を有していない。また、仮に該水中油型乳化物中の水や油脂を減らして、糖質を添加することで常温流通の品質を目指しても、製造時の加熱殺菌で焦げが生じ安定して生産することができないという問題がある。 In Patent Document 3, as an oil-in-water emulsion that can be whipped by mixing with an acidic taste material, it is composed of 40 to 80% by weight of an aqueous phase and 20 to 60% by weight of an oil phase, and 0.05 to 10% by weight. % Whey protein, 0.2-5% by weight skim milk solids, and an acid-resistant oil-in-water emulsion containing a total phosphate and citrate weight of less than 0.01% by weight is disclosed. ing. However, since the oil-in-water emulsion has a low sugar content, it does not have a quality that allows it to be distributed at room temperature. Moreover, even if aiming at the quality of normal temperature distribution by reducing the water and fats and oils in the oil-in-water emulsion and adding saccharides, the product can be stably produced by scorching due to heat sterilization during production. There is a problem that you can not.
 特許文献4には、水、油脂、乳清蛋白、乳化剤を含む水中油型乳化物において、乳清蛋白質を0.03~0.4重量%含むとともに、乳化剤としてレシチンを添加しないで、主要な構成脂肪酸がオレイン酸であるポリグリセリン脂肪酸エステル及びHLB値が4~15の範囲にあるショ糖脂肪酸エステルを含む耐酸性及び起泡性を有する水中油型乳化物が開示されている。また、特許文献5には、油脂、カゼインタンパク質/ホエータンパク質が特定の質量比であるタンパク質、レシチン、特定の平均グリセリン重合度と特定のHLBであるポリグリセリン飽和脂肪酸エステル、食物繊維および/または化工澱粉を含有する、通常のホイップクリームとしての風味と性能とを有し、更に耐酸性と凍結耐性を有するホイップクリーム組成物が開示されている。しかし、特許文献4および5のすべての実施例では、硬化パーム核油(34℃)やパーム核油とパーム核硬化油脂の混合油(8:2)しか用いていないため、酸性物質とブレンドしてホイップしたホイップドクリームは経時的に硬くなって締まり易く、離水が多いという問題がある。 Patent Document 4 discloses that an oil-in-water emulsion containing water, fats and oils, whey protein, and an emulsifier contains 0.03 to 0.4% by weight of whey protein and does not contain lecithin as an emulsifier. An oil-in-water emulsion having acid resistance and foaming resistance is disclosed, which includes a polyglycerin fatty acid ester whose constituent fatty acid is oleic acid and a sucrose fatty acid ester having an HLB value in the range of 4 to 15. Patent Document 5 discloses fats and oils, protein having a specific mass ratio of casein protein / whey protein, lecithin, a specific average glycerin polymerization degree and a specific HLB polyglycerin saturated fatty acid ester, dietary fiber and / or chemical process. A whipped cream composition containing starch and having a flavor and performance as a normal whipped cream and further having acid resistance and freeze resistance is disclosed. However, since all the examples of Patent Documents 4 and 5 use only hardened palm kernel oil (34 ° C.) or a mixed oil of palm kernel oil and palm kernel hardened oil (8: 2), it is blended with an acidic substance. The whipped cream that has been whipped is harder and easier to tighten with time, and there is a problem that there is a lot of water separation.
特開平10-155448号公報JP-A-10-155448 特開2007-282535号公報JP 2007-282535 A 特開2000-262236号公報JP 2000-262236 A 国際公開第06/035543号International Publication No. 06/035543 特開平08-154612号公報Japanese Patent Laid-Open No. 08-154612
 本発明の目的は、フルーツソース、果汁、ヨーグルト等の各種の酸性呈味素材を混合してもホイップでき、かつ口溶けおよび水々しさが良好で、保型性に優れ、離水の少ない常温流通可能なホイップドクリームおよびその製造方法を提供することである。 The object of the present invention is to be able to whip even by mixing various acidic taste materials such as fruit sauce, fruit juice, yogurt, etc., with good mouth-melting and wateriness, excellent shape retention and low temperature separation Whipped cream and a method for producing the same.
 本発明は、カゼイン蛋白質0.1質量%未満、乳清蛋白質0.1質量%以上1.0質量%以下およびHLB12以上のポリグリセリン脂肪酸エステル0.05質量%以上0.5質量%以下を含む起泡性水中油型乳化油脂組成物と酸性呈味素材とを90:10~30:70の範囲の重量比で含む混合物を起泡してなるホイップドクリームであって、該ホイップドクリームは油脂10質量%以上30質量%以下、糖質20質量%以上50質量%以下および水25質量%以上60質量%以下を含み、pHが2.0以上5.5以下であり、該油脂全体中、パーム核ステアリンを70質量%以上90質量%以下並びに、ヤシ油及び/又はパーム核油と、極度硬化パーム油、極度硬化ローエルシン菜種油および極度硬化ハイエルシン菜種油からなる群より選ばれる少なくとも1種とを20/80~80/20の範囲の質量比で混合した油脂のランダムエステル交換油を10質量%以上30質量%以下含有する。 The present invention includes less than 0.1% by weight of casein protein, 0.1% by weight to 1.0% by weight of whey protein, and 0.05% by weight to 0.5% by weight of polyglycerol fatty acid ester of HLB12 or more. A whipped cream obtained by foaming a mixture comprising a foamable oil-in-water emulsified oil / fat composition and an acidic flavoring material in a weight ratio ranging from 90:10 to 30:70, Including 10% by weight to 30% by weight of fats and oils, 20% by weight to 50% by weight of carbohydrates and 25% by weight to 60% by weight of water, and having a pH of 2.0 to 5.5, 70% by weight or more and 90% by weight or less of palm kernel stearin and coconut oil and / or palm kernel oil, extremely hardened palm oil, extremely hardened low rapeseed oil, and extremely hardened hyelsin rapeseed oil Chosen contains at least one and a 20 / 80-80 / 20 in the range of the mixed oil at a weight ratio of random interesterified oil to 30 to 10 mass%.
 好ましい態様では、前記ホイップドクリームをポリカップ容器に10g入れ、25℃で3日間保持したものを1gとり、9gの生理食塩水に混合して得られる混合液1gを標準寒天培地20gに混釈し、37℃で2日間培養してコロニー数をカウントし、コロニー数を10倍した値が10以下である。 In a preferred embodiment, 10 g of the whipped cream is put in a plastic cup container, 1 g of the one kept at 25 ° C. for 3 days is taken, and 1 g of a mixture obtained by mixing with 9 g of physiological saline is mixed with 20 g of a standard agar medium. After culturing at 37 ° C. for 2 days, the number of colonies is counted, and the value obtained by multiplying the number of colonies by 10 is 10 4 or less.
 また本発明は、カゼイン蛋白質0.1質量%未満、乳清蛋白質0.1質量%以上1.0質量%以下およびHLB12以上のポリグリセリン脂肪酸エステル0.05質量%以上0.5質量%以下を含む起泡性水中油型乳化油脂組成物を準備する工程と、酸性呈味素材を準備する工程と、該起泡性水中油型乳化油脂組成物と該酸性呈味素材とを90:10~30:70の範囲の重量比で混合して混合物を得る工程と、該混合物を起泡してホイップドクリームを得る工程とを備え、前記ホイップドクリームは油脂10質量%以上30質量%以下、糖質20質量%以上50質量%以下および水25質量%以上60質量%以下を含み、pHが2.0以上5.5以下であり、該油脂全体中、パーム核ステアリンを70質量%以上90質量%以下並びに、ヤシ油及び/又はパーム核油と、極度硬化パーム油、極度硬化ローエルシン菜種油および極度硬化ハイエルシン菜種油からなる群より選ばれる少なくとも1種とを20/80~80/20の範囲の質量比で混合した油脂のランダムエステル交換油を10質量%以上30質量%以下含有する、ホイップドクリームの製造方法である。 Further, the present invention comprises less than 0.1% by mass of casein protein, 0.1% by mass to 1.0% by mass of whey protein, and 0.05% by mass to 0.5% by mass of polyglycerol fatty acid ester of HLB12 or more. The step of preparing a foamable oil-in-water emulsified oil / fat composition, a step of preparing an acidic taste material, the foamable oil-in-water emulsified oil / fat composition and the acid taste material are 90:10 to Mixing at a weight ratio in the range of 30:70 to obtain a mixture, and foaming the mixture to obtain a whipped cream, wherein the whipped cream is 10% by weight to 30% by weight of fats and oils, It contains 20% by mass or more and 50% by mass or less of saccharides and 25% by mass or more and 60% by mass or less of water, and has a pH of 2.0 or more and 5.5 or less. Less than mass%, The coconut oil and / or palm kernel oil was mixed with at least one selected from the group consisting of extremely hardened palm oil, extremely hardened low rapeseed rapeseed oil and extremely hardened hyelsin rapeseed oil at a mass ratio in the range of 20/80 to 80/20. It is a manufacturing method of whipped cream which contains 10 mass% or more and 30 mass% or less of random transesterification oils of fats and oils.
 本発明によれば、フルーツソース、果汁、ヨーグルト等の各種の酸性呈味素材を混合してもホイップでき、かつ口溶けおよび水々しさが良好で、保型性に優れ、離水の少ない常温流通可能なホイップドクリームおよびその製造方法を提供することができる。 According to the present invention, it can be whipped even by mixing various acidic taste materials such as fruit sauce, fruit juice, yogurt, etc., has good mouth melting and wateriness, has excellent shape retention, and can be distributed at room temperature with little water separation. Whipped cream and a method for producing the same can be provided.
 <ホイップドクリーム>
 本発明の一実施の形態において、ホイップドクリームは、起泡性水中油型乳化油脂組成物と酸性呈味素材とを含む混合物を起泡してなる。
<Whipped cream>
In one embodiment of the present invention, the whipped cream is formed by foaming a mixture containing a foamable oil-in-water emulsified oil and fat composition and an acidic taste material.
 ホイップドクリームのpHは、2.0以上5.5以下であり、好ましくは2.5以上5.0以下、より好ましくは3.0以上4.9以下である。pHが2.0未満では酸味が強すぎる場合があり、一方、5.5を超えると酸性呈味材の風味が弱い場合があり好ましくない。 The pH of the whipped cream is 2.0 or more and 5.5 or less, preferably 2.5 or more and 5.0 or less, more preferably 3.0 or more and 4.9 or less. If the pH is less than 2.0, the acidity may be too strong. On the other hand, if the pH is more than 5.5, the flavor of the acidic flavoring material may be weak.
 ホイップドクリームのpHの測定は、pH METER(株式会社堀場製作所製「F-52」)を用いて行う。 The pH of the whipped cream is measured using pH METER (“F-52” manufactured by Horiba, Ltd.).
 ホイップドクリームのオーバーランは、100%以上が好ましく、130~180%がより好ましい。オーバーランが100%未満であると口溶けが重く感じる場合があり好ましくない。なお、ホイップドクリームのオーバーランとは、ホイップドクリームに含まれる空気の割合を%で示したものである。 The overrun of whipped cream is preferably 100% or more, more preferably 130 to 180%. If the overrun is less than 100%, melting in the mouth may be felt, which is not preferable. Note that the whipped cream overrun is the percentage of the air contained in the whipped cream.
 オーバーランの測定は、はじめに、起泡性水中油型乳化油脂組成物と酸性呈味素材とを合わせて特定量になるように混合し、得られた混合液を100cmの容器に入れ、質量を測る。該混合液をトッピングするのに適度な硬さに到達するまでホイップし、得られたホイップドクリームを100cmの容器に入れ、質量を測る。そしてこれらの測定値を基に、次式でオーバーランを求めることができる。 For the measurement of overrun, first, the foamable oil-in-water emulsified oil / fat composition and the acidic taste material are mixed to a specific amount, and the resulting mixture is placed in a 100 cm 3 container, Measure. The mixture is whipped until reaching a suitable hardness for topping, and the resulting whipped cream is put into a 100 cm 3 container and the mass is measured. Based on these measured values, the overrun can be obtained by the following equation.
 オーバーラン(%)=[(一定容積の起泡性水中油型乳化油脂組成物と酸性呈味素材の混合液の質量)-(一定容積のホイップドクリームの質量)]÷(一定容積のホイップドクリームの質量)×100
 <起泡性水中油型乳化油脂組成物>
 本発明の一実施の形態におけるホイップドクリームに用いる起泡性水中油型乳化油脂組成物は、水を主体とする水相と、油脂を主体とする油相とを含み、水相中に油相からなる油滴が分散している。
Overrun (%) = [(mass of a mixture of a certain volume of foamable oil-in-water emulsified oil and fat composition and acidic taste ingredients) − (mass of a certain volume of whipped cream)] ÷ (constant volume of whipped Mass of docream) x 100
<Foaming oil-in-water emulsified oil and fat composition>
The foamable oil-in-water emulsified oil / fat composition used for the whipped cream in one embodiment of the present invention includes a water phase mainly composed of water and an oil phase mainly composed of fats and oils. Oil droplets composed of phases are dispersed.
 <油相>
 油相は、油脂、乳化剤、香料および着色料などを含むことができる。
<Oil phase>
The oil phase can contain fats and oils, emulsifiers, fragrances, colorants and the like.
 (油脂)
 油脂としては、ナタネ油、コーン油、綿実油、パーム油、パーム核油、ヤシ油、大豆油、ひまわり油、サフラワー油、オリーブ油等の植物性油脂や、乳脂肪、牛脂、豚脂、魚油等の動物性油脂が例示でき、これらを硬化、分別、エステル交換等の加工処理を行ったものも用いることができる。これらの油脂は単独でも用いることができるし、2種類以上を組み合わせて用いることもできる。中でも、パーム核油、硬化パーム核油、ヤシ油、硬化ヤシ油、パーム核オレイン、パーム核ステアリン、硬化パーム核ステアリン、パーム油、パームオレイン、パームダブルオレイン、パーム中融点部やこれらの植物性油脂の部分硬化油、または極度硬化油、これらのランダムエステル交換油を用いることが好ましい。特に、パーム核ステアリンと特定のエステル交換油からなることが好ましい。前記エステル交換油は、ヤシ油及び/又はパーム核油と、極度硬化パーム油、極度硬化ローエルシン菜種油および極度硬化ハイエルシン菜種油からなる群より選ばれる少なくとも1種とのランダムエステル交換油であることがより好ましい。前記ランダムエステル交換油は、ヤシ油及び/又はパーム核油と、極度硬化パーム油、極度硬化ローエルシン菜種油および極度硬化ハイエルシン菜種油からなる群より選ばれる少なくとも1種とを20/80~80/20の範囲の質量比で混合した油脂のランダムエステル交換油であることが好ましく、該比は40/60~60/40がより好ましい。
(Oil and fat)
Oils and fats include vegetable oils such as rapeseed oil, corn oil, cottonseed oil, palm oil, palm kernel oil, palm oil, soybean oil, sunflower oil, safflower oil, olive oil, milk fat, beef fat, pork fat, fish oil, etc. The animal fats and oils can be exemplified, and those obtained by subjecting these to processing such as hardening, fractionation, and transesterification can also be used. These fats and oils can be used alone or in combination of two or more. Among them, palm kernel oil, hydrogenated palm kernel oil, palm oil, hydrogenated palm oil, palm kernel olein, palm kernel stearin, hydrogenated palm kernel stearin, palm oil, palm olein, palm double olein, palm mid-melting point and their vegetable properties It is preferable to use a partially hardened oil or fat, an extremely hardened oil, or a random transesterified oil thereof. In particular, it preferably comprises palm kernel stearin and a specific transesterified oil. More preferably, the transesterified oil is a random transesterified oil of coconut oil and / or palm kernel oil and at least one selected from the group consisting of extremely hardened palm oil, extremely hardened low erucin rapeseed oil and extremely hardened hyelin rapeseed oil. preferable. The random transesterified oil comprises 20/80 to 80/20 of coconut oil and / or palm kernel oil and at least one selected from the group consisting of extremely hardened palm oil, extremely hardened low erucin rapeseed oil and extremely hardened hyelin rapeseed oil. Random transesterified oils and fats mixed at a mass ratio in the range are preferable, and the ratio is more preferably 40/60 to 60/40.
 エステル交換油の製造方法は特に限定なく、一般的な方法を用いて製造することができる。たとえば、ナトリウムメチラート、ナトリウムエチラートを原料油脂に対して0.01~1.0質量%添加することでランダムエステル交換反応を起こす化学法、リパーゼなどの酵素を用いてエステル交換を行なう酵素法などを用いることができる。 The method for producing the transesterified oil is not particularly limited, and can be produced using a general method. For example, a chemical method that causes a random transesterification reaction by adding 0.01 to 1.0% by mass of sodium methylate or sodium ethylate with respect to the raw oil or fat, an enzymatic method that performs transesterification using an enzyme such as lipase Etc. can be used.
 油脂の含有量は、ホイップドクリーム全体中10質量%以上30質量%以下が好ましく、15質量%以上25質量%以下がより好ましい。油脂が10質量%未満であると、オーバーランが高くならずに保型性が悪くなる場合がある。また、30質量%を超えると口溶けが重く、油っぽく感じる場合がある。 The content of the oil and fat is preferably 10% by mass or more and 30% by mass or less, and more preferably 15% by mass or more and 25% by mass or less in the whole whipped cream. If the oil or fat is less than 10% by mass, the overrun may not be increased and the shape retention may be deteriorated. On the other hand, if it exceeds 30% by mass, the melted mouth may be heavy and feel oily.
 起泡性水中油型乳化油脂組成物の油脂成分中、パーム核ステアリン70質量%以上90質量%以下並びに、ヤシ油及び/又はパーム核油と、極度硬化パーム油、極度硬化ローエルシン菜種油および極度硬化ハイエルシン菜種油からなる群より選ばれる少なくとも1種とのランダムエステル交換油10質量%以上30質量%以下を含むことが好ましい。パーム核ステアリンの含有量が70質量%未満であると、口溶けが重く、油っぽく感じる場合があり、90質量%を超えると、ホイップ後に硬く締まりやすくなる場合がある。また、ランダムエステル交換油が10質量%未満であると、ホイップ後に硬く締まりやすくなる場合があり、30質量%を超えると、口溶けが重く油っぽく感じる場合がある。パーム核ステアリンの含有量は78質量%以上88質量%以下がさらに好ましく、ランダムエステル交換油の含有量は12質量%以上22質量%以下がさらに好ましい。 Among the oil and fat components of the foamable oil-in-water emulsified oil and fat composition, palm kernel stearin 70 mass% or more and 90 mass% or less, palm oil and / or palm kernel oil, extremely hardened palm oil, extremely hardened low rapeseed oil, and extremely hardened It is preferable that 10 mass% or more and 30 mass% or less of random transesterified oil with at least 1 sort (s) chosen from the group which consists of Hyelsin rapeseed oil is included. If the content of palm kernel stearin is less than 70% by mass, the melt in the mouth may be heavy and feel oily, and if it exceeds 90% by mass, it may become hard and easy to tighten after whipping. Further, if the random transesterified oil is less than 10% by mass, it may become hard and easy to tighten after whipping, and if it exceeds 30% by mass, the mouth melt may be heavy and feel oily. The content of palm kernel stearin is more preferably 78% by mass to 88% by mass, and the content of random transesterified oil is more preferably 12% by mass to 22% by mass.
 (乳化剤)
 油相は、油相に溶解可能な乳化剤を含有することができる。油相に溶解可能とは、乳化剤のHLBが8以下であることを意味する。
(emulsifier)
The oil phase can contain an emulsifier that is soluble in the oil phase. Being soluble in the oil phase means that the HLB of the emulsifier is 8 or less.
 油相に含まれる乳化剤としては、たとえばグリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、大豆レシチン、卵黄レシチン、及びこれらの分画レシチン、酵素分解したリゾレシチンといった改質レシチンなどのレシチン類が挙げられ、これらを少なくとも1種用いることができる。中でも、レシチンとショ糖脂肪酸エステルを併用することが好ましい。 Examples of emulsifiers contained in the oil phase include glycerin fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, soybean lecithin, egg yolk lecithin, fractionated lecithins thereof, and enzymatically decomposed lysolecithin And lecithins such as modified lecithin, and at least one of them can be used. Among these, it is preferable to use lecithin and sucrose fatty acid ester in combination.
 レシチンの含有量は、起泡性水中油型乳化油脂組成物全体中、0.01質量%以上0.15質量%以下が好ましく、0.02質量%以上0.1質量%以下がより好ましい。0.01質量%未満であると、保型性が悪くなる場合があり、0.15質量%を超えると、ホイップドクリームが経時的に硬く変化しやすくなる場合がある。 The content of lecithin is preferably 0.01% by mass or more and 0.15% by mass or less, and more preferably 0.02% by mass or more and 0.1% by mass or less in the entire foamable oil-in-water emulsified oil / fat composition. If it is less than 0.01% by mass, the shape retention may be deteriorated, and if it exceeds 0.15% by mass, the whipped cream may become hard and change easily with time.
 ショ糖脂肪酸エステルを使用することで、乳化安定性を向上することができる。ショ糖脂肪酸エステルの含有量は、起泡性水中油型乳化油脂組成物全体中0.01質量%以上0.2質量%以下が好ましく、0.02質量%以上0.15質量%以下がより好ましい。0.01質量%未満であると、乳化安定性が悪くなる場合があり、0.2質量%を超えると、苦みが出てきて風味を損なう場合がある。 Emulsion stability can be improved by using sucrose fatty acid ester. The content of the sucrose fatty acid ester is preferably 0.01% by mass or more and 0.2% by mass or less, and more preferably 0.02% by mass or more and 0.15% by mass or less in the entire foamable oil-in-water emulsified oil / fat composition. preferable. If it is less than 0.01% by mass, the emulsion stability may be deteriorated, and if it exceeds 0.2% by mass, bitterness may appear and the flavor may be impaired.
 (各種添加剤)
 油相は、油脂、乳化剤の他に、各種添加剤として着色料や香料などを含むことができる。着色料や香料は、食品用であれば特に限定はなく、必要に応じて適宜使用することができる。
(Various additives)
The oil phase can contain a coloring agent, a fragrance | flavor, etc. as various additives other than fats and oils and an emulsifier. The colorant and the fragrance are not particularly limited as long as they are for foods, and can be appropriately used as necessary.
 <水相>
 水相は、水、糖質、乳蛋白質、乳化剤および各種添加剤を含むことができる。
<Water phase>
The aqueous phase can contain water, carbohydrates, milk proteins, emulsifiers and various additives.
 (水)
 水相は水を含む。水の含有量はホイップドクリーム全体中25質量%以上60質量%以下が好ましく、30質量%以上50質量%以下がより好ましい。25質量%未満であると水々しさが損なわれる場合があり、60質量%を超えると常温流通時に腐敗する場合がある。
(water)
The aqueous phase contains water. The content of water is preferably 25% by mass or more and 60% by mass or less, and more preferably 30% by mass or more and 50% by mass or less in the whole whipped cream. If it is less than 25% by mass, the wateriness may be impaired, and if it exceeds 60% by mass, it may rot during normal temperature distribution.
 (糖質)
 水相は糖質を含む。糖質とは、炭水化物から食物繊維を除いたものであり、ぶどう糖、果糖などの単糖類、砂糖、乳糖、麦芽糖などの二糖類、オリゴ糖、デキストリン、でんぷんなどの三糖類以上の多糖類、還元麦芽糖水飴、エリスリトール、キシリトール、マルチトールなどの糖アルコール、キサンタンガム、グアーガム、カラギーナン、寒天、ゼラチン、タマリンドガム、ローカストビーンガム、アルギン酸類、ペクチン、セルロースおよびその誘導体などが挙げられる。中でも、ぶどう糖、砂糖、乳糖、麦芽糖およびオリゴ糖などの糖類、キサンタンガム、グアーガムおよびカラギーナンなどの増粘剤を用いることが好ましい。
(Sugar)
The aqueous phase contains carbohydrates. Carbohydrates are obtained by removing dietary fiber from carbohydrates, monosaccharides such as glucose and fructose, disaccharides such as sugar, lactose and maltose, polysaccharides more than trisaccharides such as oligosaccharides, dextrin and starch, and reduction. Examples thereof include sugar alcohols such as maltose starch syrup, erythritol, xylitol, maltitol, xanthan gum, guar gum, carrageenan, agar, gelatin, tamarind gum, locust bean gum, alginic acids, pectin, cellulose and derivatives thereof. Among them, it is preferable to use sugars such as glucose, sugar, lactose, maltose and oligosaccharide, and thickeners such as xanthan gum, guar gum and carrageenan.
 糖質の含有量は、ホイップドクリーム全体中20質量%以上50質量%以下であり、30質量%以上40質量%以下が好ましい。20質量%未満であると、常温流通時に腐敗する場合があり、50質量%を超えると甘味が強くなりすぎる場合や、水々しさが損なわれる場合がある。 Sugar content is 20% by mass or more and 50% by mass or less in the whole whipped cream, and preferably 30% by mass or more and 40% by mass or less. If it is less than 20% by mass, it may rot during distribution at room temperature, and if it exceeds 50% by mass, the sweetness may become too strong or the wateriness may be impaired.
 (乳蛋白質)
 水相は乳蛋白質として乳清蛋白質のみ、或いは乳清蛋白質及びカゼイン蛋白質を含む。
(Milk protein)
The aqueous phase contains only whey protein or whey protein and casein protein as milk protein.
 カゼイン蛋白質は、乳のpHを20℃でpH4.6にした時に沈殿する蛋白質のことであり、αS1カゼイン、αS2カゼイン、βカゼイン、κカゼイン、γカゼインの4種の蛋白質を指す。たとえば、カゼイン蛋白質を含有する蛋白質として、生乳、牛乳、特別牛乳、部分脱脂乳、脱脂乳、加工乳、クリーム、バター、チーズ、アイスクリーム類、濃縮乳、脱脂濃縮乳、無糖れん乳、無糖脱脂れん乳、加糖れん乳、加糖脱脂れん乳、全粉乳、脱脂粉乳、クリームパウダーなど、乳及び乳製品の成分規格等に関する省令(乳等省令)に定義される乳及び乳製品に由来する乳蛋白質、トータルミルクプロテインのようなUF膜やイオン交換樹脂処理等により分離、分画した乳由来の蛋白質、乳のpHを酸性にして沈殿したカゼイン蛋白質に、塩類を添加して可溶化させたカゼインナトリウム、カゼインカルシウム、カゼインカリウム、カゼインマグネシウムのようなカゼイン蛋白質の塩類などが挙げられる。 Casein protein is a protein that precipitates when the pH of milk is adjusted to pH 4.6 at 20 ° C., and refers to four types of proteins, αS1 casein, αS2 casein, β casein, κ casein, and γ casein. For example, protein containing casein protein includes raw milk, milk, special milk, partially skimmed milk, skim milk, processed milk, cream, butter, cheese, ice cream, concentrated milk, skimmed concentrated milk, non-sugared milk, and nothing. Derived from milk and dairy products defined in ministerial ordinances (Ministerial Ordinance for Milk) such as sugar skim milk, sweetened milk, sweetened skim milk, whole milk powder, skimmed milk powder, cream powder, etc. Milk protein, milk protein such as total milk protein separated and fractionated by ion-exchange resin treatment, etc. Milk was added and solubilized by adding salt to casein protein precipitated by acidifying the pH of milk. Examples include casein protein salts such as casein sodium, casein calcium, casein potassium, and casein magnesium.
 カゼイン蛋白質は耐酸性を付与するためには少ない程良く、その含有量は、起泡性水中油型乳化油脂組成物全体中0.1質量%未満が好ましく、0.05質量%未満がより好ましく、含有しないことが最も好ましい。カゼイン蛋白質の含有量が0.1質量%を超えると、酸性呈味素材を混合してpHを2~5にすると増粘、固化し、ホイップしても所望のオーバーランのホイップドクリームを得ることはできない場合がある。 Casein protein is preferably as low as possible to impart acid resistance, and its content is preferably less than 0.1% by mass, more preferably less than 0.05% by mass in the entire foamable oil-in-water emulsified fat composition. Most preferably, it does not contain. If the content of casein protein exceeds 0.1% by mass, the acidic taste ingredients are mixed and the pH is adjusted to 2-5 to thicken, solidify, and even when whipped, a desired overrun whipped cream is obtained. It may not be possible.
 乳清蛋白質は、乳を20℃でpH4.6にした際の乳清中に存在する蛋白画分であり、たとえば、チーズホエー、カゼインホエー等が例示できる。中でも牛乳から、クリーム、カゼインが分画された残り、またはチーズカードを絞った残りを脱塩、濃縮、乾燥して粉末化したホエー蛋白濃縮物が、ホエー蛋白質含量が高く且つ使用しやすい為に好ましい。 Whey protein is a protein fraction present in whey when milk is adjusted to pH 4.6 at 20 ° C., and examples thereof include cheese whey and casein whey. Above all, the whey protein concentrate, which is made from milk by desalting, concentrating, drying, and pulverizing the remaining cream, casein fraction, or cheese curd residue, has a high whey protein content and is easy to use. preferable.
 乳清蛋白質の含有量は、起泡性水中油型乳化油脂組成物全体中、0.1質量%以上1.0質量%以下が好ましく、0.3質量%以上0.8質量%以下がより好ましい。0.1質量%未満であると、乳化が不安定になる場合がある。1.0質量%を超えると、起泡性水中油型乳化油脂組成物製造時の加熱殺菌で焦げが生じ安定して生産することができない場合がある。 The content of whey protein is preferably 0.1% by mass or more and 1.0% by mass or less, and more preferably 0.3% by mass or more and 0.8% by mass or less in the entire foamable oil-in-water emulsified oil / fat composition. preferable. If it is less than 0.1% by mass, emulsification may become unstable. If it exceeds 1.0% by mass, there may be cases where the product cannot be stably produced due to scorching due to heat sterilization during the production of the foamable oil-in-water emulsified oil / fat composition.
 (乳化剤)
 水相は、水相に溶解可能な乳化剤を含む。水相に溶解可能とは、乳化剤のHLBが6以上であることを意味する。
(emulsifier)
The aqueous phase includes an emulsifier that is soluble in the aqueous phase. Being soluble in the aqueous phase means that the HLB of the emulsifier is 6 or more.
 水相は乳化剤として、HLB12以上のポリグリセリン脂肪酸エステルを必ず含む。ポリグリセリン脂肪酸エステルは、グリセリンを重合したポリグリセリンと脂肪酸とのエステル化生成物である。HLBは、HLB12以上18以下が好ましく、13以上16以下がより好ましい。HLB12未満では、起泡性水中油型乳化油脂組成物の製造時の加熱殺菌での焦げ抑制効果が不十分で、起泡性水中油型乳化油脂組成物を安定して生産することができない場合がある。HLB18を超えるポリグリセリン脂肪酸エステルは一般には販売されておらず、入手が困難である。 The aqueous phase always contains polyglycerin fatty acid ester of HLB 12 or more as an emulsifier. The polyglycerol fatty acid ester is an esterification product of polyglycerol obtained by polymerizing glycerol and a fatty acid. HLB is preferably 12 or more and 18 or less, and more preferably 13 or more and 16 or less. Less than HLB12, when the foaming oil-in-water emulsified oil / fat composition is insufficient in the effect of suppressing scorch during heat sterilization during the production of the foamable oil-in-water emulsified oil / fat composition, and the foamable oil-in-water emulsified oil / fat composition cannot be stably produced There is. Polyglycerol fatty acid esters exceeding HLB18 are not generally sold and are difficult to obtain.
 ポリグリセリン脂肪酸エステルの平均グリセリン重合度は、6~10が好ましく、10がより好ましい。重合度が6未満では、HLBが12以上であっても製造時の加熱殺菌での焦げ抑制効果が不十分となる場合がある。重合度が10を超えるものは一般には販売されておらず、入手が困難である。また、エステル化度は1~3が好ましく、1~2がより好ましい。ここでエステル化度とは、ポリグリセリン1分子に結合する脂肪酸の分子数を指す。エステル化度が1未満では、エステル化されていないポリグリセリンを多く含むこととなり、乳化が不安定となる場合や、起泡性水中油型乳化油脂組成物の製造時の加熱殺菌での焦げ抑制効果が不十分となる場合がある。エステル化度が3を超えると、HLBが12以上であっても起泡性水中油型乳化油脂組成物の製造時の加熱殺菌での焦げ抑制効果が不十分となる。さらに、主要構成脂肪酸は、ステアリン酸、オレイン酸が好ましく、ステアリン酸がより好ましい。 The average degree of glycerol polymerization of the polyglycerol fatty acid ester is preferably 6 to 10, and more preferably 10. If the degree of polymerization is less than 6, even if the HLB is 12 or more, the effect of suppressing burning in heat sterilization during production may be insufficient. Those having a degree of polymerization exceeding 10 are generally not sold and are difficult to obtain. The degree of esterification is preferably 1 to 3, and more preferably 1 to 2. Here, the degree of esterification refers to the number of fatty acid molecules bound to one molecule of polyglycerol. If the degree of esterification is less than 1, it will contain a large amount of non-esterified polyglycerin, resulting in unstable emulsification, or suppression of scorch during heat sterilization during the production of a foamable oil-in-water emulsified oil composition. The effect may be insufficient. When the degree of esterification exceeds 3, even if the HLB is 12 or more, the effect of suppressing scorch during heat sterilization during the production of a foamable oil-in-water emulsified oil and fat composition becomes insufficient. Further, the main constituent fatty acid is preferably stearic acid or oleic acid, more preferably stearic acid.
 HLB12以上のポリグリセリン脂肪酸エステルとしては、ヘキサグリセリンモノラウレート、デカグリセリンモノステアレート等が挙げられ、これらの中でも、特にヘキサグリセリンモノステアレートが、加熱殺菌時の蛋白質の焦げ抑制効果が顕著であり好ましい。 Examples of polyglycerin fatty acid esters of HLB 12 or higher include hexaglycerin monolaurate, decaglycerin monostearate, etc. Among these, hexaglycerin monostearate is particularly prominent in suppressing the burning of proteins during heat sterilization. It is preferable.
 HLB12以上のポリグリセリン脂肪酸エステルの含有量は、起泡性水中油型乳化油脂組成物中0.05質量%以上0.5質量%以下が好ましく、より好ましくは0.1質量%以上0.4質量%以下である。ポリグリセリン脂肪酸エステルの含有量が0.05質量%未満であると、加熱殺菌時の蛋白質の焦げ抑制効果が不十分となる場合ある。0.5質量%を超えるとホイップドクリームの風味が悪くなる場合がある。 The content of the polyglycerin fatty acid ester of HLB 12 or more is preferably 0.05% by mass or more and 0.5% by mass or less, and more preferably 0.1% by mass or more and 0.4% in the foamable oil-in-water emulsified oil / fat composition. It is below mass%. When the content of the polyglycerin fatty acid ester is less than 0.05% by mass, the effect of suppressing the burning of protein during heat sterilization may be insufficient. When it exceeds 0.5 mass%, the flavor of a whipped cream may worsen.
 水相は、HLB12以上のポリグリセリン脂肪酸エステル以外の乳化剤をさらに含有することができる。該乳化剤としては、たとえばグリセリン脂肪酸エステル、HLB12未満のポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、大豆レシチン、卵黄レシチン、及びこれらの分画レシチン、更には酵素分解したリゾレシチンといった改質レシチンなどのレシチン類が挙げられ、これらを少なくとも1種用いることができる。中でも、ショ糖脂肪酸エステルを用いることが好ましい。 The aqueous phase can further contain an emulsifier other than the polyglycerin fatty acid ester of HLB 12 or higher. Examples of the emulsifier include glycerin fatty acid ester, polyglycerin fatty acid ester of less than HLB 12, sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, soybean lecithin, egg yolk lecithin, and fractionated lecithin thereof, and further enzymatic degradation. Examples include lecithins such as modified lecithin such as lysolecithin, and at least one of these can be used. Of these, sucrose fatty acid esters are preferably used.
 ショ糖脂肪酸エステルを使用することで、乳化安定性を向上することができる。ショ糖脂肪酸エステルの含有量は、起泡性水中油型乳化油脂組成物全体中0.01質量%以上0.2質量%以下が好ましく、0.02質量%以上0.15質量%以下がより好ましい。0.01質量%未満であると、乳化安定性が悪くなる場合があり、0.2質量%を超えると、苦みが出てきて風味を損なう場合がある。 Emulsion stability can be improved by using sucrose fatty acid ester. The content of the sucrose fatty acid ester is preferably 0.01% by mass or more and 0.2% by mass or less, and more preferably 0.02% by mass or more and 0.15% by mass or less in the entire foamable oil-in-water emulsified oil / fat composition. preferable. If it is less than 0.01% by mass, the emulsion stability may be deteriorated, and if it exceeds 0.2% by mass, bitterness may appear and the flavor may be impaired.
 (各種添加剤)
 水相は、カゼイン蛋白質、乳清蛋白質、ポリグリセリン脂肪酸エステル、糖質、乳化剤の他に、塩類、日持ち向上剤、着色料や香料を含むことができる。
(Various additives)
The aqueous phase can contain salts, shelf life improvers, colorants and fragrances in addition to casein protein, whey protein, polyglycerin fatty acid ester, saccharide and emulsifier.
 塩類としては、たとえば塩化ナトリウム、塩化カリウム、塩化カルシウム、炭酸ナトリウム、炭酸水素ナトリム、炭酸カリウム、リン酸ナトリウム、リン酸水素ナトリウム、リン酸カリウム、リン酸水素カリウム、ヘキサンメタリン酸ナトリウム、クエン酸ナトリウム、クエン酸カリウム、クエン酸カルシウム、酒石酸ナトリウム、酒石酸カリウム、酒石酸水素ナトリム、酒石酸水素カリウム、乳酸ナトリウム、乳酸カリウム、リンゴ酸ナトリム、リンゴ酸カリウム、コハク酸ナトリウム、コハク酸カリウム、ソルビン酸カリウム、ステアリン酸カルシウム等が挙げられる。塩類の含有量は、本発明の効果を損なわない範囲で適宜調整することができる。 Examples of salts include sodium chloride, potassium chloride, calcium chloride, sodium carbonate, sodium hydrogen carbonate, potassium carbonate, sodium phosphate, sodium hydrogen phosphate, potassium phosphate, potassium hydrogen phosphate, sodium hexanemetaphosphate, sodium citrate , Potassium citrate, calcium citrate, sodium tartrate, potassium tartrate, sodium hydrogen tartrate, potassium hydrogen tartrate, sodium lactate, potassium lactate, sodium malate, potassium malate, sodium succinate, potassium succinate, potassium sorbate, stear Examples thereof include calcium phosphate. The salt content can be appropriately adjusted within a range not impairing the effects of the present invention.
 日持ち向上剤としては、たとえばグリシン、リゾチーム、ポリリジン、酢酸ナトリウムなどが挙げられる。たとえば、グリシンとリゾチームを質量比で2:1~100:1の範囲で、ホイップドクリーム全体中0.1質量%以上5質量%以下の範囲で添加することが好ましい。なお、該日持ち向上剤は、起泡性水中油型乳化油脂組成物の水相、または起泡性水中油型乳化油脂組成物と酸性呈味素材とを含む混合物に添加することができる。 Examples of the shelf life improver include glycine, lysozyme, polylysine, sodium acetate and the like. For example, it is preferable to add glycine and lysozyme in a mass ratio of 2: 1 to 100: 1 in a range of 0.1% by mass to 5% by mass in the whole whipped cream. The shelf life improver can be added to the aqueous phase of the foamable oil-in-water emulsified oil or fat composition or a mixture containing the foamable oil-in-water emulsified oil and fat composition and the acidic taste material.
 着色料や香料は、食品用であれば特に限定はなく、必要に応じて適宜使用することができる。 Coloring and flavoring are not particularly limited as long as they are for food, and can be used as needed.
 <酸性呈味素材>
 酸性呈味素材としては、イチゴ、ブルーベリー、パイン、パッションフルーツ、オレンジ、リンゴ、白桃、黄桃、ブドウ、グァバ、パパイア、メロン、スイカ、グレープフルーツ、レモン、マンゴー、ラズベリー、ライチ、あんず、ゆず、みかん、キウイ、いちじく、カシス、アセロラ、プルーン、梨、洋ナシなどの果実、またこれらを加工した果汁、濃縮果汁、フルーツピューレ、フルーツソース、ジャム、ペーストや、アジピン酸、クエン酸、グルコン酸、リンゴ酸、酒石酸、酢酸、乳酸、炭酸、コハク酸、フマル酸、リン酸などの有機酸や、ヨーグルト、発酵乳、発酵果汁、ワインなどの発酵食品やコーヒーなどの飲料が挙げられる。
<Acid taste material>
Acidic taste ingredients include strawberry, blueberry, pine, passion fruit, orange, apple, white peach, yellow peach, grape, guava, papaya, melon, watermelon, grapefruit, lemon, mango, raspberry, lychee, apricot, citron, mandarin orange , Kiwi, figs, cassis, acerola, prunes, pears, pears, processed fruit juices, concentrated juices, fruit purees, fruit sauces, jams, pastes, adipic acid, citric acid, gluconic acid, apples Examples thereof include organic acids such as acid, tartaric acid, acetic acid, lactic acid, carbonic acid, succinic acid, fumaric acid and phosphoric acid, fermented foods such as yogurt, fermented milk, fermented fruit juice and wine, and beverages such as coffee.
 酸性呈味素材の含有量は、ホイップドクリームのpHを好適に調整するために、ホイップドクリーム全体中10質量%以上70質量%以下であることが好ましく、20質量%以上60質量%以下であることがさらに好ましい。そして、ホイップドクリーム中の前記起泡性水中油型乳化油脂組成物と酸性呈味素材との質量比は、90:10~30:70であることが好ましい。 The content of the acidic taste material is preferably 10% by mass or more and 70% by mass or less, and preferably 20% by mass or more and 60% by mass or less in the whole whipped cream in order to suitably adjust the pH of the whipped cream. More preferably it is. The mass ratio of the foamable oil-in-water emulsified oil / fat composition to the acidic taste material in the whipped cream is preferably 90:10 to 30:70.
 <ホイップドクリームの製造方法>
 本発明の一実施の形態において、ホイップドクリームの製造方法は、カゼイン蛋白質0.1質量%未満、乳清蛋白質0.1質量%以上1.0質量%以下およびHLB12以上のポリグリセリン脂肪酸エステル0.05質量%以上0.5質量%以下を含む起泡性水中油型乳化油脂組成物を準備する工程と、酸性呈味素材を準備する工程と、該起泡性水中油型乳化油脂組成物と該酸性呈味素材とを90:10~30:70の範囲の重量比で混合して混合物を得る工程と、該混合物を起泡してホイップドクリームを得る工程とを備え、前記ホイップドクリームは油脂10質量%以上30質量%以下、糖質20質量%以上50質量%以下および水25質量%以上60質量%以下を含み、pHが2.0以上5.5以下であり、該油脂全体中、パーム核ステアリンを70質量%以上90質量%以下並びに、ヤシ油及び/又はパーム核油と、極度硬化パーム油、極度硬化ローエルシン菜種油および極度硬化ハイエルシン菜種油からなる群より選ばれる少なくとも1種とを20/80~80/20の範囲の質量比で混合した油脂のランダムエステル交換油を10質量%以上30質量%以下含有する。
<Method for producing whipped cream>
In one embodiment of the present invention, the method for producing whipped cream comprises less than 0.1% by weight of casein protein, 0.1% by weight to 1.0% by weight of whey protein, and polyglycerol fatty acid ester 0 of HLB 12 or more. A step of preparing a foamable oil-in-water emulsified oil / fat composition containing 0.05% by mass or more and 0.5% by mass or less, a step of preparing an acidic taste material, and the foamable oil-in-water emulsified oil / fat composition And the acidic taste material at a weight ratio in the range of 90:10 to 30:70 to obtain a mixture, and foaming the mixture to obtain a whipped cream, the whipped The cream contains 10% by mass to 30% by mass of fats and oils, 20% by mass to 50% by mass of carbohydrates and 25% by mass to 60% by mass of water, and has a pH of 2.0 to 5.5. The entire palm kernel 70/90% by weight of allin and at least one selected from the group consisting of coconut oil and / or palm kernel oil and extremely hardened palm oil, extremely hardened low cinnamon rapeseed oil and extremely hardened hyelin rapeseed oil The oil-and-fat random transesterified oil mixed at a mass ratio in the range of 80/20 is contained in an amount of 10% by mass to 30% by mass.
 (起泡性水中油型乳化油脂組成物を準備する工程)
 はじめに、50~80℃に加温融解した油脂に油溶性乳化剤、香料、着色料などの油溶性原料を所定量混合して油相部を得る。一方、50~70℃の温水にHLB12以上のポリグリセリン脂肪酸エステルや水溶性乳化剤、カゼイン蛋白質、乳清蛋白質、糖質、塩類、増粘剤、香料などの水系原料を所定量攪拌溶解して水相部を得る。該水相部に油相部を添加し、予備乳化する。
(Step of preparing a foamable oil-in-water emulsified oil / fat composition)
First, a predetermined amount of an oil-soluble raw material such as an oil-soluble emulsifier, a fragrance, and a colorant is mixed with an oil and fat heated and melted at 50 to 80 ° C. to obtain an oil phase part. On the other hand, water-based raw materials such as polyglycerin fatty acid esters of HLB 12 or higher, water-soluble emulsifiers, casein proteins, whey proteins, sugars, salts, thickeners, fragrances, etc. are stirred and dissolved in hot water at 50 to 70 ° C. Get the phase. An oil phase part is added to the water phase part and pre-emulsified.
 その後、微細化、均質化、予備加熱、殺菌、1次冷却、均質化、2次冷却、3次冷却、エージングなどの起泡性水中油型乳化油脂組成物の製造において通常行われる各処理を行うことにより、起泡性水中油型乳化油脂組成物を得ることができる。 Thereafter, each treatment usually performed in the production of a foamable oil-in-water emulsified oil and fat composition such as refinement, homogenization, preheating, sterilization, primary cooling, homogenization, secondary cooling, tertiary cooling, aging, etc. By performing, a foamable oil-in-water emulsified oil / fat composition can be obtained.
 (酸性呈味素材を準備する工程)
 酸性呈味素材を準備する。酸性呈味素材としては、イチゴ、ブルーベリー、パイン、パッションフルーツ、オレンジ、リンゴ、白桃、黄桃、ブドウ、グァバ、パパイア、メロン、スイカ、グレープフルーツ、レモン、マンゴー、ラズベリー、ライチ、あんず、ゆず、みかん、キウイ、いちじく、カシス、アセロラ、プルーン、梨、洋ナシなどの果実をそのまま用いることができる。またこれらの果実を加工した果汁、濃縮果汁、フルーツピューレ、フルーツソース、ジャム、ペーストを用いることができる。さらに、アジピン酸、クエン酸、グルコン酸、リンゴ酸、酒石酸、酢酸、乳酸、炭酸、コハク酸、フマル酸、リン酸などの有機酸や、ヨーグルト、発酵乳、発酵果汁、ワインなどの発酵食品やコーヒーなどの飲料を用いることができる。
(Process of preparing acidic taste ingredients)
Prepare acidic taste ingredients. Acidic taste ingredients include strawberry, blueberry, pine, passion fruit, orange, apple, white peach, yellow peach, grape, guava, papaya, melon, watermelon, grapefruit, lemon, mango, raspberry, lychee, apricot, citron, mandarin orange Fruits such as kiwi, fig, cassis, acerola, prunes, pears and pears can be used as they are. In addition, fruit juices, concentrated fruit juices, fruit purees, fruit sauces, jams and pastes obtained by processing these fruits can be used. In addition, organic acids such as adipic acid, citric acid, gluconic acid, malic acid, tartaric acid, acetic acid, lactic acid, carbonic acid, succinic acid, fumaric acid, phosphoric acid, fermented foods such as yogurt, fermented milk, fermented fruit juice, wine Beverages such as coffee can be used.
 (混合物を得る工程)
 起泡性水中油型乳化油脂組成物と酸性呈味素材とを90:10~30:70の範囲の重量比、好ましくは80:20~40:60の範囲の重量比で、混合装置やプレッシャーミキサーなどを用いて混合して、pHが2.0以上5.5以下となるように調整された混合物を得る。
(Step of obtaining a mixture)
The foaming oil-in-water emulsified oil / fat composition and the acidic taste material are mixed at a weight ratio in the range of 90:10 to 30:70, preferably in the weight ratio of 80:20 to 40:60. Mixing is performed using a mixer or the like to obtain a mixture adjusted to have a pH of 2.0 or more and 5.5 or less.
 (ホイップドクリームを得る工程)
 得られた混合物をオープン式ホイッパーや密閉式連続ホイップマシンを用いて、トッピングするのに適度な硬さに到達するまでホイップして、ホイップドクリームを得る。
(Process of obtaining whipped cream)
The obtained mixture is whipped using an open whipper or a closed continuous whipping machine until reaching a suitable hardness for topping to obtain a whipped cream.
 以下に実施例を示し、本発明をより具体的に説明するが、本発明はこれらの実施例に何ら限定されるものではない。なお、実施例において「部」や「%」は質量基準である。 Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited to these examples. In the examples, “parts” and “%” are based on mass.
 <起泡性水中油型乳化油脂組成物の作製>
 (製造例1)
 表1に示す配合に従って、起泡性水中油型乳化油脂組成物を作製した。即ち、パーム中融点部27.0質量部とヤシ油と極度硬化パーム油(70質量部:30質量部)のエステル交換油(1)5.0質量部に、ポリグリセリン脂肪酸エステル(HLB=4)0.2質量部、ショ糖脂肪酸エステル(HLB=1.0)0.04質量部、大豆レシチン0.04質量部を添加し、65℃で溶解して油相部を作製した。
<Preparation of foamable oil-in-water emulsified oil / fat composition>
(Production Example 1)
A foamable oil-in-water emulsified oil / fat composition was prepared according to the formulation shown in Table 1. That is, the polyglycerol fatty acid ester (HLB = 4) was added to 5.0 parts by mass of transesterified oil (1) of 27.0 parts by mass of the middle melting point of palm, palm oil and extremely hardened palm oil (70 parts by mass: 30 parts by mass). ) 0.2 part by mass, 0.04 part by mass of sucrose fatty acid ester (HLB = 1.0) and 0.04 part by mass of soybean lecithin were added and dissolved at 65 ° C. to prepare an oil phase part.
 一方、ホエー蛋白濃縮物0.3質量部、ポリグリセリン脂肪酸エステル(HLB=13.4)0.4質量部、ショ糖脂肪酸エステル(HLB=16.0)0.03質量部、グラニュー糖11.0質量部、マルトース10.0質量部、乳糖6.0質量部、キサンタンガム0.002質量部、グアーガム0.015質量部およびクエン酸三ナトリウム0.15質量部を60℃の水39.823質量部に溶解して水相部を作製した。 On the other hand, 0.3 parts by weight of whey protein concentrate, 0.4 parts by weight of polyglycerol fatty acid ester (HLB = 13.4), 0.03 parts by weight of sucrose fatty acid ester (HLB = 16.0), 11. 0 parts by weight, 10.0 parts by weight of maltose, 6.0 parts by weight of lactose, 0.002 parts by weight of xanthan gum, 0.015 parts by weight of guar gum and 0.15 parts by weight of trisodium citrate 39.823 parts by weight of water at 60 ° C. The aqueous phase part was produced by dissolving in the part.
 上記水相部に油相部を加えて混合した後20分間予備乳化し、その後、高圧ホモジナイザーを用いて4MPaの圧力で処理した後に、UHT殺菌機を用いて142℃で4秒間殺菌処理した。その後、再び高圧ホモジナイザーを用いて6MPaの圧力で処理し、その後、冷却機で5℃まで冷却したものを容器に充填し、起泡性水中油型乳化油脂組成物を得た。 The oil phase part was added to the water phase part and mixed, and then pre-emulsified for 20 minutes. Thereafter, the mixture was treated at a pressure of 4 MPa using a high-pressure homogenizer and then sterilized at 142 ° C. for 4 seconds using a UHT sterilizer. Then, it processed with the pressure of 6 MPa again using the high-pressure homogenizer, Then, what was cooled to 5 degreeC with the cooler was filled in the container, and the foamable oil-in-water type emulsified oil-fat composition was obtained.
 (製造例2)
 表1に示す配合に従い、パーム中融点部をパーム核ステアリンにした以外は、製造例1と同様にして起泡性水中油型乳化油脂組成物を得た。
(Production Example 2)
According to the composition shown in Table 1, a foamable oil-in-water emulsified oil and fat composition was obtained in the same manner as in Production Example 1 except that the palm melting point was changed to palm kernel stearin.
 (製造例3)
 表1に示す配合に従い、ヤシ油と極度硬化パーム油(70質量部:30質量部)のエステル交換油(1)をヤシ油と極度硬化ハイエルシン菜種油(50質量部:50質量部)のエステル交換油(2)に変更した以外は、製造例2と同様にして起泡性水中油型乳化油脂組成物を得た。
(Production Example 3)
According to the formulation shown in Table 1, transesterification oil (1) of palm oil and extremely hardened palm oil (70 parts by mass: 30 parts by mass) is transesterified between palm oil and extremely hardened Hyelsin rapeseed oil (50 parts by mass: 50 parts by mass). A foamable oil-in-water emulsified oil and fat composition was obtained in the same manner as in Production Example 2 except that the oil (2) was changed.
 (製造例4)
 表1に示す配合に従い、油脂の添加量を32.0質量部から22.2質量部に減少し、油脂の減少分を糖質と水で、全体量を調整した以外は、製造例2と同様にして起泡性水中油型乳化油脂組成物を得た。
(Production Example 4)
According to the formulation shown in Table 1, the addition amount of fats and oils was reduced from 32.0 parts by weight to 22.2 parts by weight, and the reduced amount of fats and oils was adjusted with saccharides and water, and the whole amount was adjusted. Similarly, a foamable oil-in-water emulsified oil / fat composition was obtained.
 (製造例5、6)
 表1に示す配合に従い、ホエー蛋白濃縮物の添加量を変更し、水で全体量を調整した以外は、製造例2と同様にして起泡性水中油型乳化油脂組成物を得た。
(Production Examples 5 and 6)
According to the formulation shown in Table 1, a foamable oil-in-water emulsified oil / fat composition was obtained in the same manner as in Production Example 2, except that the amount of whey protein concentrate added was changed and the total amount was adjusted with water.
 (製造例7、8)
 表1に示す配合に従い、ポリグリセリン脂肪酸エステル(HLB=13.4)の添加量を変更し、水で全体量を調整した以外は、製造例2と同様にして起泡性水中油型乳化油脂組成物を得た。
(Production Examples 7 and 8)
In accordance with the formulation shown in Table 1, the foamable oil-in-water type emulsified oil and fat was prepared in the same manner as in Production Example 2, except that the amount of polyglycerol fatty acid ester (HLB = 13.4) was changed and the total amount was adjusted with water. A composition was obtained.
 (製造例9)
 表1に示す配合に従い、グリシンとリゾチームを添加し、水で全体量を調整した以外は、製造例2と同様にして起泡性水中油型乳化油脂組成物を得た。
(Production Example 9)
A foamable oil-in-water emulsified oil and fat composition was obtained in the same manner as in Production Example 2 except that glycine and lysozyme were added according to the formulation shown in Table 1 and the total amount was adjusted with water.
 (製造例10)
 表1に示す配合に従い、脱脂粉乳を添加し、乳糖を減らして全体量を調整した以外は、製造例2と同様にして起泡性水中油型乳化油脂組成物を得た。
(Production Example 10)
A foamable oil-in-water emulsified oil / fat composition was obtained in the same manner as in Production Example 2, except that skim milk powder was added and the total amount was adjusted by reducing lactose according to the formulation shown in Table 1.
 (製造例11)
 表1に示す配合に従い、ポリグリセリン脂肪酸エステルのHLBを13.4から11.6に変更した以外は、製造例2と同様の操作を行ったが、加熱殺菌時に蛋白質の焦げが発生し、起泡性水中油型乳化油脂組成物を作製できなかった。
(Production Example 11)
According to the formulation shown in Table 1, except that the HLB of the polyglycerin fatty acid ester was changed from 13.4 to 11.6, the same operation as in Production Example 2 was performed. A foamable oil-in-water emulsified oil / fat composition could not be produced.
 (製造例12)
 表1に示す配合に従い、油脂の添加量を32.0質量部から45.0質量部に増加し、グラニュー糖とマルトースを添加せず、乳糖と水で全体量を調整した以外は、製造例2と同様にして起泡性水中油型乳化油脂組成物を得た。
(Production Example 12)
According to the formulation shown in Table 1, the addition amount of fats and oils was increased from 32.0 parts by mass to 45.0 parts by mass, the granulated sugar and maltose were not added, and the whole amount was adjusted with lactose and water. In the same manner as in No. 2, a foamable oil-in-water emulsified oil / fat composition was obtained.
 (製造例13)
 表1に示す配合に従い、ヤシ油と極度硬化パーム油(70質量部:30質量部)のエステル交換油(1)をヤシ油と極度硬化ローエルシン菜種油(50質量部:50質量部)のエステル交換油(3)に変更した以外は、製造例2と同様にして起泡性水中油型乳化油脂組成物を得た。
(Production Example 13)
According to the formulation shown in Table 1, transesterification oil (1) of palm oil and extremely hardened palm oil (70 parts by mass: 30 parts by mass) is transesterified between palm oil and extremely hardened low rapeseed rapeseed oil (50 parts by mass: 50 parts by mass). A foamable oil-in-water emulsified oil and fat composition was obtained in the same manner as in Production Example 2 except that the oil (3) was changed.
 (製造例14)
 表1に示す配合に従い、主要構成脂肪酸がステアリン酸のポリグリセリン脂肪酸エステル(HLB13.4)を主要構成脂肪酸がオレイン酸のポリグリセリン脂肪酸エステル(HLB12.9)にした以外は、製造例2と同様にして起泡性水中油型乳化油脂組成物を得た。
(Production Example 14)
According to the formulation shown in Table 1, the same as in Production Example 2 except that the main constituent fatty acid is stearic acid polyglycerin fatty acid ester (HLB13.4) and the main constituent fatty acid is oleic acid polyglycerin fatty acid ester (HLB12.9). Thus, a foamable oil-in-water emulsified oil / fat composition was obtained.
 (製造例15)
 表1に示す配合に従い、大豆レシチンを主要構成脂肪酸がオレイン酸のポリグリセリン脂肪酸エステル(HLB8.8)にした以外は、製造例2と同様にして起泡性水中油型乳化油脂組成物を得た。
(Production Example 15)
In accordance with the formulation shown in Table 1, a foamable oil-in-water emulsified oil / fat composition was obtained in the same manner as in Production Example 2, except that soybean lecithin was changed to polyglycerin fatty acid ester (HLB8.8) whose main constituent fatty acid was oleic acid. It was.
 (製造例16)
 表1に示す配合に従い、パーム中油融点部とエステル交換油を、硬化パーム油(融点34℃)にした以外は、製造例1と同様にして起泡性水中油型乳化油脂組成物を得た。
(Production Example 16)
In accordance with the formulation shown in Table 1, a foamable oil-in-water emulsified oil / fat composition was obtained in the same manner as in Production Example 1, except that the palm oil melting point and the transesterified oil were hardened palm oil (melting point: 34 ° C.). .
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
(1)パーム核ステアリン:カネカ社製「パームカーネルステアリン」
(2)パーム中融点部:カネカ社製「パーム中融点部」
(3)エステル交換油(1):カネカ社製「エステル交換油脂(ヤシ油と極度硬化パーム油(70質量部:30質量部)のエステル交換油脂)」
(4)エステル交換油(2):カネカ社製「エステル交換油脂(ヤシ油と極度硬化ハイエルシン菜種油(50質量部:50質量部)のエステル交換油脂)」
(5)ポリグリセリン脂肪酸エステル(HLB4):太陽化学社製「サンファットPS-66(平均グリセリン重合度:6、主要構成脂肪酸:ステアリン酸、エステル化度:6)」
(6)ショ糖脂肪酸エステル(HLB1):三菱化学フーズ社製「P-170」
(7)大豆レシチン:ADM社製「Yelkin TS」
(8)脱脂粉乳:よつ葉乳業社製「脱脂粉乳(カゼイン蛋白質28.5質量%、乳清蛋白質7.1質量%)」
(9)ホエー蛋白濃縮物:Warrnambool社製「WPC80(カゼイン蛋白質0質量%、乳清蛋白質46.5質量%)」
(10)ポリグリセリン脂肪酸エステル(HLB13.4):阪本薬品工業社製「MSW-7S(水分60%、ポリグリセリン脂肪酸エステル40%、平均グリセリン重合度:10、主要構成脂肪酸:ステアリン酸、エステル化度:1)」
(11)ポリグリセリン脂肪酸エステル(HLB11.6):阪本薬品工業社製「MS-5S(平均グリセリン重合度:6、主要構成脂肪酸:ステアリン酸、エステル化度:1)」
(12)ショ糖脂肪酸エステル(HLB16):三菱化学フーズ社製「P-1670」
(13)グラニュー糖:フジ日本精糖社製「グラニュ糖FNGMS」
(14)マルトース:林原社製「サンマルトミドリ」
(15)乳糖:HILMAR社製「ラクトースHILMAR FINE GRAIND」(16)キサンタンガム:Archer Daniels Midland社製「ノヴァザン200メッシュ」
(17)グアーガム:星和社製「グアーガムXS-5000」
(18)クエン酸三ナトリウム:扶桑化学工業社製「精製クエン酸ナトリウム」
(19)グリシン:昭和電工社製「グリシン」
(20)リゾチーム:エーザイフード・ケミカル社製「卵白リゾチーム」
(24)硬化パーム油(融点34℃):カネカ社製「硬化パーム油(融点34℃)」
(25)エステル交換油(3):カネカ社製「エステル交換油脂(ヤシ油と極度硬化ローエルシン菜種油(50質量部:50質量部)のエステル交換油脂)」
(26)ポリグリセリン脂肪酸エステル(HLB8.8):阪本薬品工業社製「MO-3S(平均グリセリン重合度:4、主要構成脂肪酸:オレイン酸、エステル化度:1)」
(27)ポリグリセリン脂肪酸エステル(HLB12.9):阪本薬品工業社製「MO-7S(平均グリセリン重合度:10、主要構成脂肪酸:オレイン酸、エステル化度:1)」
 <起泡性水中油型乳化油脂組成物の加熱殺菌時の蛋白質の焦げ発生の有無の検討>
 製造例1~12の起泡性水中油型乳化油脂組成物を100kg/Hrの流量で作製時の、UHT殺菌開始直後のUHT殺菌機入口圧力に対する起泡性水中油型乳化油脂組成物100kgをUHT殺菌処理した後のUHT殺菌機入口圧力の上昇率、およびUHT殺菌機のインジェクション部への焦げた蛋白質の付着度合いを目視で評価した。その際の評価基準は、以下の通りであった。
A:UHT殺菌による圧力の上昇率が10%未満であり、インジェクション部への蛋白質の付着がなく、生産には問題が全くない。
B:UHT殺菌による圧力の上昇率が10%以上20%未満であり、インジェクション部への蛋白質の付着が若干見られるが、生産には問題ない。
C:UHT殺菌による圧力の上昇率が20%以上40%未満であり、インジェクション部への蛋白質の付着が見られ、安定して生産するには問題がある。
D:UHT殺菌による圧力の上昇率が40%以上であり、インジェクション部への蛋白質の付着が多く見られ、安定して生産できない。
(1) Palm kernel stearin: “Panel kernel stearin” manufactured by Kaneka Corporation
(2) Middle melting point of palm: “Middle melting point of palm” manufactured by Kaneka Corporation
(3) Transesterified oil (1): “Transesterified oil / fat (transesterified oil / fat of palm oil and extremely hardened palm oil (70 parts by mass: 30 parts by mass))” manufactured by Kaneka Corporation
(4) Transesterified oil (2): “Transesterified oil / fat (transesterified oil / fat of coconut oil and extremely hardened Hyelsin rapeseed oil (50 parts by mass: 50 parts by mass))” manufactured by Kaneka Corporation
(5) Polyglycerol fatty acid ester (HLB4): “Sunfat PS-66 (average degree of glycerol polymerization: 6, main constituent fatty acid: stearic acid, degree of esterification: 6)” manufactured by Taiyo Kagaku
(6) Sucrose fatty acid ester (HLB1): “P-170” manufactured by Mitsubishi Chemical Foods
(7) Soy lecithin: “Yelkin TS” manufactured by ADM
(8) Nonfat dry milk: “Fatfat dry milk (28.5% by mass of casein protein, 7.1% by mass of whey protein)” manufactured by Yotsuba Milk Industry Co., Ltd.
(9) Whey protein concentrate: “WPC80 (casein protein 0 mass%, whey protein 46.5 mass%)” manufactured by Warrnambool
(10) Polyglycerin fatty acid ester (HLB13.4): “MSW-7S (Moisture 60%, polyglycerin fatty acid ester 40%, average degree of glycerin polymerization: 10, produced by Sakamoto Yakuhin Kogyo Co., Ltd.), main constituent fatty acid: stearic acid, esterification Degree: 1) "
(11) Polyglycerin fatty acid ester (HLB11.6): “MS-5S (average degree of glycerin polymerization: 6, main constituent fatty acid: stearic acid, degree of esterification: 1)” manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.
(12) Sucrose fatty acid ester (HLB16): “P-1670” manufactured by Mitsubishi Chemical Foods
(13) Granulated sugar: “Granu Sugar FNGMS” manufactured by Fuji Nippon Seika Co., Ltd.
(14) Maltose: “Saint Marto Midori” manufactured by Hayashibara
(15) Lactose: “Lactose HILMA FINE GRAIND” manufactured by HILMA (16) Xanthan gum: “Novazan 200 mesh” manufactured by Archer Daniels Midland
(17) Guar gum: "Guar gum XS-5000" manufactured by Seiwasha
(18) Trisodium citrate: “Purified sodium citrate” manufactured by Fuso Chemical Industry Co., Ltd.
(19) Glycine: "Glycine" manufactured by Showa Denko
(20) Lysozyme: “Egg white lysozyme” manufactured by Eisai Food Chemical Co., Ltd.
(24) Hardened palm oil (melting point: 34 ° C.): “Hardened palm oil (melting point: 34 ° C.)” manufactured by Kaneka Corporation
(25) Transesterified oil (3): “Transesterified oil and fat (transesterified oil and fat of coconut oil and extremely hardened low rapeseed rapeseed oil (50 parts by mass: 50 parts by mass)” manufactured by Kaneka Corporation
(26) Polyglycerin fatty acid ester (HLB8.8): “MO-3S (average degree of glycerin polymerization: 4, main constituent fatty acid: oleic acid, degree of esterification: 1)” manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.
(27) Polyglycerin fatty acid ester (HLB12.9): “MO-7S (average glycerin polymerization degree: 10, main constituent fatty acid: oleic acid, esterification degree: 1)” manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.
<Examination of the presence or absence of protein scorching during heat sterilization of a foamable oil-in-water emulsified oil and fat composition>
When producing the foamable oil-in-water emulsified oil / fat compositions of Production Examples 1 to 12 at a flow rate of 100 kg / Hr, 100 kg of the foamable oil-in-water emulsified oil / fat composition against the UHT sterilizer inlet pressure immediately after the start of UHT sterilization The rate of increase in the inlet pressure of the UHT sterilizer after the UHT sterilization treatment and the degree of adhesion of the burned protein to the injection part of the UHT sterilizer were visually evaluated. The evaluation criteria at that time were as follows.
A: The rate of increase in pressure due to UHT sterilization is less than 10%, there is no adhesion of protein to the injection part, and there is no problem in production.
B: The rate of increase in pressure due to UHT sterilization is 10% or more and less than 20%, and a slight amount of protein adheres to the injection part, but there is no problem in production.
C: The rate of increase in pressure due to UHT sterilization is 20% or more and less than 40%, protein adhesion to the injection part is seen, and there is a problem in stable production.
D: The rate of increase in pressure due to UHT sterilization is 40% or more, protein adhesion to the injection part is often observed, and stable production cannot be achieved.
 なお、評価結果は表1に示す。
 <評価結果>
 製造例1~10,12~16は、加熱殺菌時の蛋白質の付着がないか、または若干の付着であり、生産には問題がなかった。
The evaluation results are shown in Table 1.
<Evaluation results>
In Production Examples 1 to 10, and 12 to 16, there was no or slight adhesion of protein during heat sterilization, and there was no problem in production.
 製造例11は、インジェクション部への蛋白質の付着が多く、起泡性水中油型乳化油脂組成物を製造できなかった。 Production Example 11 was unable to produce a foamable oil-in-water emulsified oil / fat composition because of the large amount of protein adhering to the injection part.
 <ホイップドクリームの作製>
 (実施例1)
 製造例13で作製した起泡性水中油型乳化油脂組成物0.7kgとフルーツソースイチゴ0.3kgとを混合し、ホバートミキサー(ホバート・ジャパン株式会社製「N-50(5コート)」)を用いて2速でトッピングするのに適度な硬さに到達するまでホイップしホイップドクリームを得た。
<Preparation of whipped cream>
Example 1
0.7 kg of the foamable oil-in-water emulsified oil and fat composition prepared in Production Example 13 and 0.3 kg of fruit sauce strawberry were mixed, and Hobart mixer (“N-50 (5 coats)” manufactured by Hobart Japan Co., Ltd.) Was whipped until it reached a suitable hardness for topping at 2nd speed to obtain a whipped cream.
 (実施例2~9、14及び15、比較例1~4)
 表2に示す配合に従い、起泡性水中油型乳化油脂組成物の種類を変更した以外は、実施例1と同様の方法でホイップし、ホイップドクリームを作製した。
(Examples 2 to 9, 14 and 15, Comparative Examples 1 to 4)
Whipped cream was prepared in the same manner as in Example 1 except that the type of foamable oil-in-water emulsified oil / fat composition was changed according to the formulation shown in Table 2.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
(21)フルーツソースイチゴ:カネカ社製「ストロベリーソース100」(pH3.6、糖質59%、水分40%)
 (実施例16、17)
 表3に示す配合に従い、起泡性水中油型乳化油脂組成物の種類と、起泡性水中油型乳化油脂組成物とフルーツソースイチゴのブレンド比率を変更した以外は、実施例1と同様の方法でホイップし、ホイップドクリームを作製した。
(21) Fruit sauce strawberry: "Strawberry sauce 100" (pH 3.6, sugar 59%, moisture 40%) manufactured by Kaneka Corporation
(Examples 16 and 17)
According to the composition shown in Table 3, the same as in Example 1 except that the type of foamable oil-in-water emulsified oil and fat composition and the blend ratio of the foamable oil-in-water emulsified oil and fat composition and the fruit sauce strawberry were changed. Whipped by the method to prepare whipped cream.
 (実施例18、19)
 表3に示す配合に従い、酸性呈味素材の種類を変更した以外は、実施例1と同様の方法でホイップし、ホイップドクリームを作製した。
(Examples 18 and 19)
According to the composition shown in Table 3, whipped cream was prepared by whipping in the same manner as in Example 1 except that the type of acidic taste material was changed.
 (比較例5、6)
 表3に示す配合に従い、起泡性水中油型乳化油脂組成物の種類と、起泡性水中油型乳化油脂組成物とフルーツソースイチゴのブレンド比率を変更した以外は、実施例1と同様の方法でホイップし、ホイップドクリームを作製した。
(Comparative Examples 5 and 6)
According to the composition shown in Table 3, the same as in Example 1 except that the type of foamable oil-in-water emulsified oil and fat composition and the blend ratio of the foamable oil-in-water emulsified oil and fat composition and the fruit sauce strawberry were changed. Whipped by the method to prepare whipped cream.
 (比較例7、8)
 表3に示す配合に従い、起泡性水中油型乳化油脂組成物の種類と、酸性呈味素材の種類を変更した以外は、実施例1と同様の方法でホイップし、ホイップドクリームを作製した。
(Comparative Examples 7 and 8)
Whipped in the same manner as in Example 1 except that the type of foamable oil-in-water emulsified oil and fat composition and the type of acidic taste material were changed according to the formulation shown in Table 3 to produce a whipped cream. .
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
(21)フルーツソースイチゴ:カネカ社製「ストロベリーソース100」(pH3.6、糖質59%、水分40%)
(22)濃縮果汁バレンシアオレンジ:日本果実加工社製「バレンシアオレンジ濃縮混濁果汁冷凍」(pH3.5、糖質55%、水分43%)
(23)ヨーグルト:カネカ社製「ララクールS500」(pH3.8、糖質54%、水分43%)
 <pHの評価>
 実施例及び比較例で得られたホイップドクリームのpHを、pH METER(株式会社堀場製作所製「F-52」)を用いて測定した。
(21) Fruit sauce strawberry: "Strawberry sauce 100" (pH 3.6, sugar 59%, moisture 40%) manufactured by Kaneka Corporation
(22) Concentrated fruit juice Valencia orange: “Valencia orange concentrated turbid fruit juice frozen” manufactured by Nippon Fruit Processing Co., Ltd. (pH 3.5, sugar 55%, moisture 43%)
(23) Yogurt: “Laracour S500” manufactured by Kaneka Corporation (pH 3.8, sugar 54%, moisture 43%)
<Evaluation of pH>
The pH of the whipped cream obtained in Examples and Comparative Examples was measured using pH METER (“F-52” manufactured by Horiba, Ltd.).
 <ホイップ時間の評価>
 ホイップ時間は、ホバートミキサー(ホバート・ジャパン株式会社製「N-50(5コート)」)で、起泡性水中油型乳化油脂組成物と酸性呈味素材とを混合し、2速でホイップし、トッピングするのに適度な硬さに到達するまでの時間を評価値とした。ここで、トッピングするのに適度な硬さとは、ホイップ直後のサンプルを容器に入れた後、クリープメーター(「RE2-33005S」、株式会社山電製)を用いて直径16mmの円柱状のプランジャーにて、速度5mm/sの速さで1cm貫入時の最大荷重が0.30~0.40Nになる硬さのことである。
<Evaluation of whipping time>
For whipping time, the foaming oil-in-water emulsified oil / fat composition and the acidic taste material are mixed with a Hobart mixer (“N-50 (5 coats)” manufactured by Hobart Japan Co., Ltd.) and whipped at a second speed. The time required to reach an appropriate hardness for topping was taken as the evaluation value. Here, the hardness suitable for topping is a columnar plunger having a diameter of 16 mm using a creep meter ("RE2-30005S", manufactured by Yamaden Co., Ltd.) after putting the sample immediately after whipping into a container. In this case, the hardness is such that the maximum load when penetrating 1 cm at a speed of 5 mm / s is 0.30 to 0.40 N.
 <オーバーランの評価>
 ホバートミキサー(ホバート・ジャパン株式会社製「N-50(5コート)」)で、起泡性水中油型乳化油脂組成物と酸性呈味素材とを混合し、得られた混合液を100cmの容器に入れ、質量を測った。該混合液を2速でホイップし、トッピングするのに適度な硬さに到達するまでホイップし、得られたホイップドクリームを100cmの容器に入れ、質量を測った。そしてそれら測定値を基に、次式でオーバーランを求めた。
<Evaluation of overrun>
In a Hobart mixer (“N-50 (5 coat)” manufactured by Hobart Japan Co., Ltd.), the foamable oil-in-water emulsified oil / fat composition and the acidic taste material are mixed, and the resulting mixture is 100 cm 3 . We put in container and weighed. The mixture was whipped at the second speed, whipped until reaching a hardness suitable for topping, and the obtained whipped cream was put into a 100 cm 3 container, and the mass was measured. And based on these measured values, the overrun was calculated | required by following Formula.
 オーバーラン(%)=[(一定容積の起泡性水中油型乳化油脂組成物と酸性呈味素材の混合液の質量)-(一定容積のホイップドクリームの質量)]÷(一定容積のホイップドクリームの質量)×100
 <ホイップドクリームの保型性の評価>
 実施例及び比較例で得られたホイップドクリームを絞り袋に詰め、出口が星型の口金(切り込みの個数8個)を用いて、透明なポリカップ容器に高さ6cm程度、底辺の直径7cm程度で、できるだけ空洞ができないように渦を巻きながら三角錐状に約40g絞り、高さを測定した。その後、25℃で24時間保持した時の高さを測定し、初期の高さが何%残っているかを保型性の評価値とした。70%以上は商品性があり、70%未満は商品性がない。
A:90%以上100%以下。
B:80%以上90%未満。
C:70%以上80%未満。
D:70%未満。
Overrun (%) = [(mass of a mixture of a certain volume of foamable oil-in-water emulsified oil and fat composition and acidic taste ingredients) − (mass of a certain volume of whipped cream)] ÷ (constant volume of whipped Mass of docream) x 100
<Evaluation of shape retention of whipped cream>
The whipped cream obtained in the examples and comparative examples is packed in a squeezed bag, and the outlet is a star-shaped base (number of cuts: 8). A transparent plastic cup container has a height of about 6 cm and a bottom diameter of about 7 cm. Then, about 40g was squeezed into a triangular pyramid shape while swirling so as not to create a cavity as much as possible, and the height was measured. Thereafter, the height when held at 25 ° C. for 24 hours was measured, and the percentage of the initial height remaining was determined as the evaluation value of the shape retention property. 70% or more has commercial properties, and less than 70% has no commercial properties.
A: 90% or more and 100% or less.
B: 80% or more and less than 90%.
C: 70% or more and less than 80%.
D: Less than 70%.
 <ホイップドクリームの離水の評価>
 実施例及び比較例で得られたホイップドクリームを絞り袋に詰め、出口が星型の口金(切り込みの個数8個)を用いて、透明なポリカップ容器に高さ6cm程度、底辺の直径7cm程度で、できるだけ空洞ができないように渦を巻きながら三角錐状に約40g絞った。その後、25℃で24時間保管した時のポリカップ底部に溜まった離水の質量を測定し、ホイップドクリームに対する離水率(%)を離水の評価値とした。
A:離水率が0%。
B:離水率が0%を超えて、5%未満。
C:離水率が5%以上10%未満。
D:離水率が10%以上。
<Evaluation of water removal from whipped cream>
The whipped cream obtained in the examples and comparative examples is packed in a squeezed bag, and the outlet is a star-shaped base (number of cuts: 8). A transparent plastic cup container has a height of about 6 cm and a bottom diameter of about 7 cm. Then, about 40 g was squeezed into a triangular pyramid shape while swirling so as not to create a cavity as much as possible. Thereafter, the mass of water separation accumulated at the bottom of the polycup when stored at 25 ° C. for 24 hours was measured, and the water separation rate (%) relative to the whipped cream was taken as the evaluation value of water separation.
A: Water separation rate is 0%.
B: The water separation rate exceeds 0% and is less than 5%.
C: The water separation rate is 5% or more and less than 10%.
D: The water separation rate is 10% or more.
 <ホイップドクリームの衛生(25℃、製造後3日目)の評価>
 実施例及び比較例で得られたホイップドクリームをポリカップ容器に約10g入れ、25℃で3日間保持したものを1gとり、9gの生理食塩水に混合した。混合液1gを標準寒天培地20gに混釈し、37℃で2日間培養してコロニー数をカウントし、コロニー数を10倍したものを評価結果とした。
<Evaluation of hygiene of whipped cream (25 ° C., 3 days after production)>
About 10 g of the whipped cream obtained in Examples and Comparative Examples was put in a plastic cup container, and 1 g of the whipped cream maintained at 25 ° C. for 3 days was taken and mixed with 9 g of physiological saline. 1 g of the mixed solution was mixed with 20 g of a standard agar medium, cultured at 37 ° C. for 2 days, the number of colonies was counted, and an evaluation result was obtained by multiplying the number of colonies by 10.
 <ホイップドクリームの口溶けの評価>
 口溶けの評価は、実施例及び比較例で得られたホイップドクリームを熟練したパネラー8名に食べてもらって官能評価を行い、それを平均して評価結果とした。その際の評価基準は以下の通りである。
A:口溶けがかなり軽く、好ましい。
B:口溶けが軽く、好ましい。
C:口溶けがやや重く、あまり好ましくない。
D:口溶けが重く、好ましくない。
<Evaluation of melting whipped cream>
For the evaluation of melting in the mouth, sensory evaluation was conducted by eating eight whipped creams obtained in Examples and Comparative Examples by skilled panelists, and the results were averaged to obtain evaluation results. The evaluation criteria at that time are as follows.
A: Melting in the mouth is quite light and preferable.
B: Melting in the mouth is light and preferable.
C: Melting in the mouth is somewhat heavy and not very preferable.
D: Melting in the mouth is heavy and not preferable.
 <ホイップドクリームの水々しさの評価>
 水々しさの評価は、実施例及び比較例で得られたホイップドクリームを熟練したパネラー8名に食べてもらって官能評価を行い、それを平均して評価結果とした。その際の評価基準は以下の通りである。
A:かなり水々しく、好ましい。
B:水々しく、好ましい。
C:やや水々しくなく、あまり好ましくない。
D:水々しくなく、好ましくない。
<Evaluation of freshness of whipped cream>
The evaluation of freshness was performed by having eight skilled panelists eat the whipped cream obtained in Examples and Comparative Examples, and performing sensory evaluation, and averaging the results. The evaluation criteria at that time are as follows.
A: It is quite watery and preferable.
B: Watery and preferable.
C: It is not so watery and is not very preferable.
D: It is not fresh and is not preferable.
 <総合評価>
 衛生、保型性、口溶け、水々しさの各評価結果を基に、総合評価を行った。その際の評価基準は以下の通りである。
A:衛生が1000未満で、保型性、口溶け、水々しさの評価が全てAのもの。
B:衛生が1000未満で、保型性、口溶け、水々しさの評価で1つ以上がBで、残りがAのもの。
C:衛生が1000未満で、保型性、口溶け、水々しさの評価で1つ以上がCで、残りがAまたはBのもの。
D:衛生が1000以上、もしくは保型性、口溶け、水々しさの評価のうち1つ以上がDのもの。
<Comprehensive evaluation>
Based on the evaluation results for hygiene, shape retention, melting in mouth, and wateriness, comprehensive evaluation was performed. The evaluation criteria at that time are as follows.
A: Hygiene is less than 1000, and the evaluation of mold retention, melting in the mouth and wateriness are all of A.
B: Hygiene is less than 1000, and one or more is B and the rest is A in the evaluation of mold retention, melting in the mouth, and wateriness.
C: Hygiene is less than 1000, and one or more is C and the rest is A or B in the evaluation of mold retention, melting in the mouth and wateriness.
D: Hygiene is 1000 or more, or one or more of the evaluation of mold retention, melting in the mouth, and wateriness is D.
 <評価結果>
 実施例1のホイップドクリームのホイップ時間は6分41秒で、オーバーラン、25℃での保型性、衛生(25℃、製造後3日目)、口溶け及び水々しさは極めて良好であった。
<Evaluation results>
The whipped time of the whipped cream of Example 1 was 6 minutes and 41 seconds, and the overrun, the shape retention at 25 ° C., the hygiene (25 ° C., 3 days after production), the melting in the mouth and the wateriness were very good. It was.
 実施例2(ヤシ油と極度硬化パーム油(70質量部:30質量部)のエステル交換油脂)および3(ヤシ油と極度硬化ハイエルシン菜種油(50質量部:50質量部)のエステル交換油脂)のホイップドクリームは、何れも実施例1と同様に、全ての項目で極めて良好な評価結果であった。 Example 2 (transesterified oil and fat of coconut oil and extremely hardened palm oil (70 parts by mass: 30 parts by mass)) and 3 (transesterified oil and fat of coconut oil and extremely hardened Hyelsin rapeseed oil (50 parts by mass: 50 parts by mass)) All of the whipped creams had very good evaluation results in all items as in Example 1.
 実施例4のホイップドクリームは油脂を15.5質量%に減らしたものであり、保型性が若干劣ったものの、良好な結果であった。 The whipped cream of Example 4 was obtained by reducing fats and oils to 15.5% by mass, and although the shape retention was slightly inferior, it was a good result.
 実施例5(ホエー蛋白濃縮物の添加量が0.14質量%)、実施例6(ホエー蛋白濃縮物の添加量が1.2質量%)、実施例7(ポリグリセリン脂肪酸エステル(HLB=13.4)の添加量が0.13質量%)、実施例8(ポリグリセリン脂肪酸エステル(HLB=13.4)の添加量が1.25質量%)のホイップドクリームも、若干劣る項目があるものの、良好な評価結果であった。 Example 5 (addition amount of whey protein concentrate is 0.14% by mass), Example 6 (addition amount of whey protein concentrate is 1.2% by mass), Example 7 (polyglycerin fatty acid ester (HLB = 13) .4) is 0.13% by mass), and the whipped cream of Example 8 (polyglycerin fatty acid ester (HLB = 13.4) is 1.25% by mass) has slightly inferior items. However, it was a good evaluation result.
 実施例9のホイップドクリームは日持ち向上剤を添加したものであり、ホイップドクリームとして良好であることに加え、25℃で5日間保存しても一般生菌数は10個/g以下であった。 The whipped cream of Example 9 is obtained by adding a shelf life improver. In addition to being good as a whipped cream, the number of general viable bacteria is 10 cells / g or less even when stored at 25 ° C. for 5 days. It was.
 実施例14のホイップドクリームはHLB12以上のポリグリセリン脂肪酸エステルの主要構成脂肪酸がオレイン酸のものであり、実施例2に比べオーバーランが低く、水々しさが劣った。 In the whipped cream of Example 14, the main constituent fatty acid of the polyglycerin fatty acid ester of HLB 12 or more is oleic acid, and the overrun was lower than that of Example 2 and the wateriness was inferior.
 実施例15のホイップドクリームは大豆レシチンを主要構成脂肪酸がオレイン酸のポリグリセリン脂肪酸エステルに変えたものであり、実施例2に比べ保型性が劣った。 The whipped cream of Example 15 was obtained by changing soy lecithin to polyglycerin fatty acid ester whose main constituent fatty acid was oleic acid, and its shape retention was inferior to that of Example 2.
 比較例1のホイップドクリームは脱脂粉乳を添加したものであり、ホイップ時に増粘し、オーバーランが90%にしか達せず、水々しさも不足しておりホイップドクリームとしては好ましくなかった。 The whipped cream of Comparative Example 1 was obtained by adding skim milk powder, increased in viscosity during whipping, reached an overrun of only 90%, and lacked wateriness, which was not preferable.
 比較例2のホイップドクリームは油脂の添加量が多く、糖質の添加量が少ないものであり、口溶けが劣ったことに加え、25℃で3日保存すると腐敗した。 The whipped cream of Comparative Example 2 had a large amount of oil and fat added and a small amount of sugar, and was poorly melted in the mouth. In addition, it was spoiled when stored at 25 ° C. for 3 days.
 比較例3のホイップドクリームは油脂にパーム中融点部と、ヤシ油と極度硬化パーム油(70質量部:30質量部)のエステル交換油脂を使用したものであり、実施例2に比べて保型性と口溶けが劣り、離水が多かった。 The whipped cream of Comparative Example 3 uses a middle melting point of palm and a transesterified oil of coconut oil and extremely hardened palm oil (70 parts by mass: 30 parts by mass) as fats and oils. The moldability and melting in the mouth were poor, and there was much water separation.
 比較例4のホイップドクリームは油脂に硬化パーム油脂のみを使用したものであり、ホイップ後に経時的に硬くなってクリームが締まり、離水も多かった。 The whipped cream of Comparative Example 4 was obtained by using only hardened palm oil / fat as the oil / fat, which became harder with time after whipping and the cream was tightened, and there was much water separation.
 実施例2、16および17のホイップドクリームは、製造例2の起泡性水中油型乳化油脂組成物を使用し、フルーツソースイチゴの配合率が20~50質量%の範囲のものであり、良好な評価結果であった。 The whipped creams of Examples 2, 16 and 17 use the foamable oil-in-water emulsified oil / fat composition of Production Example 2 and have a fruit sauce strawberry content in the range of 20 to 50% by mass. It was a good evaluation result.
 比較例3、5および6のホイップドクリームは、製造例1の起泡性水中油型乳化油脂組成物を使用し、フルーツソースイチゴの配合率が20~50質量%の範囲のものであり、何れも離水が多かった。 The whipped creams of Comparative Examples 3, 5 and 6 use the foamable oil-in-water emulsified oil / fat composition of Production Example 1 and have a fruit sauce strawberry content in the range of 20 to 50% by mass, In all cases, there was much water separation.
 実施例18(酸性呈味素材が濃縮果汁バレンシアオレンジ)および実施例19(酸性呈味素材がヨーグルト)のホイップドクリームは、酸性呈味素材の配合率やその種類に関わらず、良好な評価結果であった。 The whipped cream of Example 18 (acidic taste material is concentrated fruit juice Valencia orange) and Example 19 (acidic taste material is yogurt) has good evaluation results regardless of the blending ratio and type of the acidic taste material. Met.
 比較例7(酸性呈味素材が濃縮果汁バレンシアオレンジ)および比較例8(酸性呈味素材がヨーグルト)のホイップドクリームは、離水が多かった。 The whipped cream of Comparative Example 7 (the acidic flavoring material is concentrated fruit juice Valencia Orange) and Comparative Example 8 (the acidic flavoring material is yogurt) had a lot of water separation.
 本発明のホイップドクリームは、そのまま食することはもちろんのこと、パンや洋菓子などの常温流通型食品のトッピングやフィリングに利用できる。 The whipped cream according to the present invention can be used for topping and filling of room temperature distribution type foods such as bread and pastry as well as eating as it is.

Claims (3)

  1.  カゼイン蛋白質0.1質量%未満、乳清蛋白質0.1質量%以上1.0質量%以下およびHLB12以上のポリグリセリン脂肪酸エステル0.05質量%以上0.5質量%以下を含む起泡性水中油型乳化油脂組成物と酸性呈味素材とを90:10~30:70の範囲の重量比で含む混合物を起泡してなるホイップドクリームであって、
     前記ホイップドクリームは油脂10質量%以上30質量%以下、糖質20質量%以上50質量%以下および水25質量%以上60質量%以下を含み、pHが2.0以上5.5以下であり、前記油脂全体中、パーム核ステアリンを70質量%以上90質量%以下並びに、ヤシ油及び/又はパーム核油と、極度硬化パーム油、極度硬化ローエルシン菜種油および極度硬化ハイエルシン菜種油からなる群より選ばれる少なくとも1種とを20/80~80/20の範囲の質量比で混合した油脂のランダムエステル交換油を10質量%以上30質量%以下含有する、ホイップドクリーム。
    Foamable water containing less than 0.1% by weight of casein protein, 0.1% by weight to 1.0% by weight of whey protein and 0.05% by weight to 0.5% by weight of polyglycerol fatty acid ester of HLB12 or more A whipped cream formed by foaming a mixture containing an oil-type emulsified oil and fat composition and an acidic taste material in a weight ratio in the range of 90:10 to 30:70,
    The whipped cream contains 10% to 30% by weight of fats and oils, 20% to 50% by weight of carbohydrates and 25% to 60% by weight of water, and has a pH of 2.0 to 5.5. In the whole oil and fat, the palm kernel stearin is selected from the group consisting of 70% by mass to 90% by mass and coconut oil and / or palm kernel oil, extremely hardened palm oil, extremely hardened low erucin rapeseed oil and extremely hardened hyelin rapeseed oil. A whipped cream containing 10% by mass or more and 30% by mass or less of a random transesterified oil and fat mixed with at least one of them in a mass ratio in the range of 20/80 to 80/20.
  2.  前記ホイップドクリームをポリカップ容器に10g入れ、25℃で3日間保持したものを1gとり、9gの生理食塩水に混合して得られる混合液1gを標準寒天培地20gに混釈し、37℃で2日間培養してコロニー数をカウントし、コロニー数を10倍した値が10以下である、請求項1に記載のホイップドクリーム。 10 g of the whipped cream is put in a plastic cup container, and 1 g of the mixture kept at 25 ° C. for 3 days is taken, and 1 g of a mixed solution obtained by mixing with 9 g of physiological saline is mixed with 20 g of a standard agar medium at 37 ° C. The whipped cream according to claim 1, wherein a value obtained by culturing for 2 days, counting the number of colonies, and multiplying the number of colonies by 10 is 10 4 or less.
  3.  カゼイン蛋白質0.1質量%未満、乳清蛋白質0.1質量%以上1.0質量%以下およびHLB12以上のポリグリセリン脂肪酸エステル0.05質量%以上0.5質量%以下を含む起泡性水中油型乳化油脂組成物を準備する工程と、
     酸性呈味素材を準備する工程と、
     前記起泡性水中油型乳化油脂組成物と前記酸性呈味素材とを90:10~30:70の範囲の重量比で混合して混合物を得る工程と、
     前記混合物を起泡してホイップドクリームを得る工程とを備え、
     前記ホイップドクリームは油脂10質量%以上30質量%以下、糖質20質量%以上50質量%以下および水25質量%以上60質量%以下を含み、pHが2.0以上5.5以下であり、
     前記油脂全体中、パーム核ステアリンを70質量%以上90質量%以下並びに、ヤシ油及び/又はパーム核油と、極度硬化パーム油、極度硬化ローエルシン菜種油および極度硬化ハイエルシン菜種油からなる群より選ばれる少なくとも1種とを20/80~80/20の範囲の質量比で混合した油脂のランダムエステル交換油を10質量%以上30質量%以下含有する、ホイップドクリームの製造方法。
    Foamable water containing less than 0.1% by weight of casein protein, 0.1% by weight to 1.0% by weight of whey protein and 0.05% by weight to 0.5% by weight of polyglycerol fatty acid ester of HLB12 or more Preparing an oil-type emulsified oil and fat composition;
    A step of preparing an acidic taste material;
    Mixing the foamable oil-in-water emulsified oil and fat composition and the acidic taste material at a weight ratio in the range of 90:10 to 30:70 to obtain a mixture;
    Foaming the mixture to obtain a whipped cream,
    The whipped cream contains 10% to 30% by weight of fats and oils, 20% to 50% by weight of carbohydrates and 25% to 60% by weight of water, and has a pH of 2.0 to 5.5. ,
    70% by weight or more and 90% by weight or less of palm kernel stearin, and at least selected from the group consisting of palm oil and / or palm kernel oil, extremely hardened palm oil, extremely hardened low rapeseed rapeseed oil and extremely hardened Hyelsin rapeseed oil. A method for producing whipped cream, comprising 10% by mass or more and 30% by mass or less of a random transesterified oil and fat mixed with one type at a mass ratio in the range of 20/80 to 80/20.
PCT/JP2014/070905 2013-08-19 2014-08-07 Whipped cream and method for producing same WO2015025730A1 (en)

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JP2018019610A (en) * 2016-08-01 2018-02-08 太陽油脂株式会社 Oil-and-fat composition for compound cream
JP2018033349A (en) * 2016-08-30 2018-03-08 学校法人神奈川大学 Foamable emulsion composition, foamable composition, foamed substance, method for improving foamability, foamability improving agent, and method for adjusting solidity of foam
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JPWO2022107803A1 (en) * 2020-11-17 2022-05-27
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JP2018033349A (en) * 2016-08-30 2018-03-08 学校法人神奈川大学 Foamable emulsion composition, foamable composition, foamed substance, method for improving foamability, foamability improving agent, and method for adjusting solidity of foam
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