JP2009050235A - Foaming oil-in-water emulsified product - Google Patents

Foaming oil-in-water emulsified product Download PDF

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JP2009050235A
JP2009050235A JP2007222299A JP2007222299A JP2009050235A JP 2009050235 A JP2009050235 A JP 2009050235A JP 2007222299 A JP2007222299 A JP 2007222299A JP 2007222299 A JP2007222299 A JP 2007222299A JP 2009050235 A JP2009050235 A JP 2009050235A
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oil
parts
water emulsion
water
fatty acid
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Kazutaka Ito
一孝 伊藤
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Fuji Oil Co Ltd
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Fuji Oil Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a foaming oil-in-water emulsified product free from causing deformation, cracking, roughness of texture, discoloration, or flavor deterioration, even if freezing in a whipped condition or decorating on a cake and thawing, and having excellent flavor and freeze resistance, and to provide a method for producing the emulsified product. <P>SOLUTION: This foaming oil-in-water emulsified product which contains oil and fat, water, and an emulsifier is such that the water content is 55-73 wt.%, the oil and fat content is 25-43 wt.%, and 55 wt.% or more of the oil and fat is lauric oil and fat whose SFC at 10°C is 65-98%. The emulsified product has an overrun of 50-140%. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、起泡性水中油型乳化物及びその製造法に関し、さらに詳細にはホイップ状態で凍結保存後、解凍しても風味が損なわれたり、組織が劣化したりせず、しかも口どけ良好な凍結用ホイップドクリームを得るための起泡性水中油型乳化物に関する。   The present invention relates to a foamable oil-in-water emulsion and a method for producing the same, and more specifically, after refrigerated in a whipped state, the flavor does not deteriorate or the tissue does not deteriorate even if thawed, and the mouth is squeezed. The present invention relates to a foamable oil-in-water emulsion for obtaining a good whipped cream for freezing.

従来、ケーキやデザートなどにナッペしたりデコレーションするために用いるホイップドクリームは衛生的にも機能的にも劣化が激しいことから、凍結保存することが提案されている。しかしながら凍結、解凍という温度変化によってホイップドクリームの品質には多くの悪影響がでる。たとえばデコレーションされたケーキが凍結解凍後、型崩れまたはひび割れあるいは組織の荒れあるいは変色、風味劣化が起こるといった現象である。
従来、ショ糖を多く配合すると外観の劣化に効果があることは知られていたが甘すぎてしまうという欠点を有していた。ショ糖の代わりに種々の糖を利用することが提案されている。
例えば、特許文献1では、油脂8〜60重量%、糖アルコール類5〜50重量%、糖アルコール類を除く無脂固形物2〜18重量%及び有効量の乳化剤、増粘剤、風味料と水を含み、該水対糖アルコールの重量比が1対0.1〜1.5であることを特徴とするホイップ後(含気後)冷解凍を行っても冷凍前の物性を全く損なうことのない起泡性水中油型乳化物が提案されている。
また、特許文献2では、油脂35〜55重量%、無脂乳固形分1〜10重量%、ポリグリセリン脂肪酸エステルを含む乳化剤0.1〜2重量%、ソルビトール及び/又は平均分子量が500以下の還元澱粉糖化物1〜10重量%、シクロデキストリン0.2〜2重量%及び水を含有することを特徴とするクリーム状組成物が提案されている。
しかしながらこれらのものでは糖アルコール類に由来する独特の風味を有しスッキリ感に欠け、品質上まだ十分ではなかった。
そして、特許文献3では、油相部と水相部からなり、前記油相部中に油脂としてパーム核油分別高融点部を含有する、水中油型乳化油脂組成物が提案されているが、これも実施例を見ると液糖15部、上白糖10部を含有する水中油型乳化油脂組成物であり特許文献1及び特許文献2と類似したものである。
Conventionally, whipped cream used for napping and decorating cakes and desserts has been proposed to be frozen and preserved because it is highly sanitary and functionally deteriorated. However, temperature changes such as freezing and thawing have many negative effects on the quality of whipped cream. For example, the decorated cake may be deformed or cracked, rough or discolored or discolored, or deteriorated in flavor after freezing and thawing.
Conventionally, it has been known that adding a large amount of sucrose has an effect on deterioration of the appearance, but it has a drawback of being too sweet. It has been proposed to use various sugars instead of sucrose.
For example, in Patent Document 1, fats and oils 8 to 60% by weight, sugar alcohols 5 to 50% by weight, non-fat solids excluding sugar alcohols 2 to 18% by weight, and effective amounts of emulsifiers, thickeners, flavors and the like It contains water and the weight ratio of the water to sugar alcohol is 1 to 0.1 to 1.5, and the physical properties before freezing are completely impaired even after cold thawing after whipping (after aeration) There is proposed a foamable oil-in-water emulsion free from water.
Moreover, in patent document 2, fats and oils 35-55 weight%, non-fat milk solid content 1-10 weight%, the emulsifier 0.1-2 weight% containing polyglycerol fatty acid ester, sorbitol and / or average molecular weight are 500 or less. A cream-like composition characterized by containing 1 to 10% by weight of a reduced starch saccharified product, 0.2 to 2% by weight of cyclodextrin and water has been proposed.
However, these products have a unique flavor derived from sugar alcohols, lack a refreshing feeling, and are still insufficient in quality.
And in Patent Document 3, an oil-in-water emulsified oil and fat composition comprising an oil phase part and an aqueous phase part and containing a palm kernel oil fractionation high melting point part as an oil and fat in the oil phase part has been proposed. This is also an oil-in-water emulsified oil / fat composition containing 15 parts of liquid sugar and 10 parts of upper white sugar, which is similar to Patent Documents 1 and 2.

特開昭57−47457号公報JP 57-47457 A 特開平06−269256号公報Japanese Patent Laid-Open No. 06-269256 特開2006−304713号公報JP 2006-304713 A

本発明の目的は、起泡性水中油型乳化物に予め糖類を使用するのではなく、ホイップを行う際に適度な甘味を付与するための糖類を加配(例えばショ糖を7〜12重量%)してホイップし、ホイップさせた状態もしくはこれをケーキ等にデコレーションした状態で凍結保存し解凍しても、型崩れまたはひび割れあるいは組織の荒れ、風味劣化が防止された、優れた風味の凍結耐性を有する起泡性水中油型乳化物及びその製造法を提供する事にある。   The object of the present invention is not to use a saccharide in advance in the foamable oil-in-water emulsion, but to add a saccharide for imparting an appropriate sweetness when whipping (for example, 7 to 12% by weight of sucrose). ), Whipped, or whipped or decorated in a cake, etc., even if frozen and thawed, it has been prevented from losing its shape, cracking, roughing of the structure, and flavor deterioration. It is providing the foamable oil-in-water type emulsion which has, and its manufacturing method.

本発明者らは鋭意研究を行った結果、従来の凍結用ホイップドクリームとして使用される起泡性水中油型乳化物は凍結保存し解凍した場合、型崩れまたはひび割れあるいは組織の荒れを防止するために水中油型乳化物中に糖類を少なくとも10重量%以上含有させるのが常識的に考えられていた。
しかしながら、油脂及び蛋白質を含む水中油型乳化物に糖類が共存して特に滅菌処理された場合、蛋白質と糖質が反応してフレッシュ感に欠けるものになるという新たな知見並びに油脂分25〜43重量%の低油分でラウリン系油脂を主成分として使用しながら、特定の乳化剤を選択使用しオーバーランを特定の範囲に調整することによって本願発明の目的を達成できることを見出した。
そして、ホイップを行う際に適度な甘味を付与するための糖類を加配(例えばショ糖を7〜12重量%)し、ホイップ後、凍結解凍した状態において、外観の変化が防止された、優れた風味の凍結耐性を有する起泡性水中油型乳化物を完成するに至った。
即ち、本発明の第1は、油脂、水及び乳化剤を含む水中油型乳化物において、水分量が55〜73重量%であり、油脂分が25〜43重量%であって、油脂中の55重量%以上が10℃におけるSFCが65〜98%の範囲のラウリン系油脂であることを特徴とする起泡性水中油型乳化物である。第2は、乳化剤がレシチン、ショ糖飽和脂肪酸エステル、ソルビタン不飽和脂肪酸エステル、ソルビタン飽和脂肪酸エステル、ポリグリセリン不飽和脂肪酸エステル及びポリグリセリン飽和脂肪酸エステルから少なくとも3種以上を含む、第1記載の起泡性水中油型乳化物である。第3は、オーバーランが50〜140%である、第1又は第2記載の起泡性水中油型乳化物である。第4は、第1〜第3の何れか1に記載の起泡性水中油型乳化物の、凍結用ホイップドクリームとしての使用である。第5は、第1〜第3の何れか1に記載の起泡性水中油型乳化物100部に対して糖類2〜40部加配し、ホイップ後得られた起泡物をスポンジにナッペし、凍結後解凍するケーキ製造のための起泡性水中油型乳化物である。第6は、第1〜第3の何れか1に記載の起泡性水中油型乳化物100部に対して糖類2〜40部加配し、ホイップ後得られた起泡物をスポンジにナッペし、凍結後解凍するケーキの製造法である。
As a result of intensive research, the present inventors have prevented foaming oil-in-water emulsions used as conventional whipped creams for freezing to lose shape, cracks or rough tissues when frozen and thawed. For this reason, it has been commonly considered to contain at least 10% by weight of saccharides in an oil-in-water emulsion.
However, a new finding that when a saccharide is coexisting in an oil-in-water emulsion containing fats and oils and sterilized in particular, the protein reacts with the sugars, resulting in a lack of freshness and a fat content of 25 to 43. It has been found that the object of the present invention can be achieved by selectively using a specific emulsifier and adjusting the overrun to a specific range while using lauric fat as a main component at a low oil content of wt%.
And when whipping, a sugar for imparting an appropriate sweetness was added (for example, 7 to 12% by weight of sucrose), and after whipping, freezing and thawing were prevented. A foamable oil-in-water emulsion having a flavor freezing resistance has been completed.
That is, according to the first aspect of the present invention, in an oil-in-water emulsion containing fats and oils, water and an emulsifier, the water content is 55 to 73% by weight, the fats and oils content is 25 to 43% by weight, and 55 in the fats and oils. It is a foamable oil-in-water emulsion characterized by being a lauric oil or fat having an SFC in the range of 65 to 98% at 10 ° C. by weight or more. Second, the emulsifier contains at least three kinds of lecithin, sucrose saturated fatty acid ester, sorbitan unsaturated fatty acid ester, sorbitan saturated fatty acid ester, polyglycerin unsaturated fatty acid ester and polyglycerin saturated fatty acid ester. It is a foamy oil-in-water emulsion. The third is the foamable oil-in-water emulsion according to the first or second, wherein the overrun is 50 to 140%. 4th is use of the foamable oil-in-water emulsion as described in any one of 1st-3rd as a whipped cream for freezing. Fifth, 2 to 40 parts of sugar is added to 100 parts of the foamable oil-in-water emulsion according to any one of the first to third, and the foam obtained after whipping is napped onto a sponge. A foamable oil-in-water emulsion for making a cake that thaws after freezing. Sixth, 2 to 40 parts of sugar is added to 100 parts of the foamable oil-in-water emulsion according to any one of the first to third, and the foamed substance obtained after whipping is napped onto a sponge. This is a method for producing a cake that is thawed after freezing.

ホイップさせた状態もしくはこれをケーキ等にデコレーションした状態で凍結保存し解凍しても、型崩れまたはひび割れあるいは組織の荒れ、風味劣化が防止された、優れた風味特にフレッシュ感のある凍結耐性を有する起泡性水中油型乳化物及びその製造法を提供することが可能になった。   Even if it is frozen and stored in a whipped state or decorated in a cake, etc., it loses its shape, cracks, rough structure, and flavor deterioration, and has an excellent flavor, especially a freezing resistance with a fresh feeling. It has become possible to provide a foamable oil-in-water emulsion and a method for producing the same.

本発明の起泡性水中油型乳化物は、油脂、水及び乳化剤を含む水中油型乳化物であって、流動状態の乳化物であり、”ホイップ用クリーム”と呼ばれたりもする。これを泡立器具、または専用のミキサーを用いて空気を抱き込ませるように攪拌したとき、俗に”ホイップドクリーム”または”ホイップクリーム”と称される、起泡状態を呈するものとなる。
本発明の起泡性水中油型乳化物は、油脂、水及び乳化剤を含む水中油型乳化物において、水分量が55〜73重量%であり、油脂分が25〜43重量%であって、油脂中の55重量%以上が10℃におけるSFCが65〜98%の範囲のラウリン系油脂であることが必要である。
本発明の油脂としては、油脂中の55重量%以上が10℃におけるSFCが65〜98%の範囲であり、好ましくは68〜98%の範囲であり、更に好ましくは70〜95%の範囲のラウリン系油脂である。
ラウリン系油脂が55重量%未満の場合は、凍結耐性が劣る起泡性水中油型乳化物となる。
ラウリン系油脂としては例えば、ヤシ油、パーム核油、これらを分別して得られるパーム核オレイン、パーム核ステアリン等の分別油、及びこれらの硬化油等が挙げられ、これらから選ばれる1種又は2種以上を用いることができ特に、起泡性水中油型乳化物の保形性の点で、硬化ヤシ油、硬化パーム核油、硬化パーム核オレイン、パーム核ステアリン、硬化パーム核ステアリン、パーム核の2段分画した中融点画分の極度硬化油が好ましい。
The foamable oil-in-water emulsion of the present invention is an oil-in-water emulsion containing fats and oils, water and an emulsifier, is a fluidized emulsion, and is sometimes referred to as “whipping cream”. When this is stirred using a foaming device or a dedicated mixer so that air is entrapped, a foamed state commonly referred to as “whipped cream” or “whipped cream” is exhibited.
The foamable oil-in-water emulsion of the present invention is an oil-in-water emulsion containing oil and fat, water and an emulsifier, having a moisture content of 55 to 73 wt% and an oil and fat content of 25 to 43 wt%, It is necessary that 55% by weight or more in the fat / oil is a lauric fat / oil having an SFC in the range of 65 to 98% at 10 ° C.
As the fats and oils of the present invention, 55% by weight or more in the fats and oils is SFC at 10 ° C. in the range of 65 to 98%, preferably in the range of 68 to 98%, more preferably in the range of 70 to 95%. It is a lauric oil.
When the lauric fat is less than 55% by weight, it becomes a foamable oil-in-water emulsion having poor freezing resistance.
Examples of lauric fats and oils include palm oil, palm kernel oil, fractionated oils such as palm kernel olein and palm kernel stearin obtained by fractionating these, and hardened oils thereof. In particular, in terms of shape retention of the foamable oil-in-water emulsion, hardened palm oil, hardened palm kernel oil, hardened palm kernel olein, palm kernel stearin, hardened palm kernel stearin, palm kernel An extremely hardened oil having a medium melting point fraction obtained by two-stage fractionation is preferred.

ラウリン系油脂以外の油脂としては、動植物性油脂及びそれらの硬化油脂の単独又は2種以上の混合物或いはこれらのものに種々の化学処理又は物理処理を施したものが例示できる。かかる油脂としては、大豆油、綿実油、コーン油、サフラワー油、オリーブ油、パーム油、菜種油、米ぬか油、ゴマ油、カポック油、カカオ脂、乳脂、ラード、魚油、鯨油等の各種の動植物油脂及びそれらの硬化油、分別油、エステル交換油等の加工油脂(融点15〜40℃程度のもの)が例示できる。
また、油脂分が25〜43重量%であり、好ましくは27〜40重量%、さらに好ましくは29〜36重量%である。油脂が25重量%未満の場合は、水中油型乳化物を起泡する際の起泡性が悪化する傾向にある。43重量%を超える場合は起泡性水中油型乳化物の凍結解凍後の食感が悪い傾向になる。
Examples of fats and oils other than lauric fats and oils include animal and vegetable fats and oils and their hardened fats and oils, or a mixture of two or more thereof, or those obtained by subjecting these to various chemical treatments or physical treatments. Such fats and oils include soybean oil, cottonseed oil, corn oil, safflower oil, olive oil, palm oil, rapeseed oil, rice bran oil, sesame oil, kapok oil, cocoa butter, milk fat, lard, fish oil, whale oil, and various animal and vegetable fats and oils Oils and oils such as hardened oil, fractionated oil and transesterified oil (melting point of about 15 to 40 ° C.).
Moreover, fats and oils are 25 to 43 weight%, Preferably it is 27 to 40 weight%, More preferably, it is 29 to 36 weight%. When the fats and oils are less than 25% by weight, the foamability when foaming the oil-in-water emulsion tends to deteriorate. When it exceeds 43% by weight, the texture of the foamable oil-in-water emulsion after freezing and thawing tends to be poor.

本発明においては、水分量が55〜73重量%であり且つ油脂分が25〜43重量%である必要があって、好ましくは非脂固形分が2〜15重量%である。
水分量が多すぎると水中油型乳化物を起泡する際の起泡性が悪化する傾向にある。水分量が少なすぎると水中油型乳化物の粘度が高くなり、エージング中に可塑化現象(ボテ)を生じ易い傾向になる。
非脂固形分としては無脂乳固形分、糖類、食物繊維、多糖類、乳化剤、塩類が例示できる
本発明の無脂乳固形分とは、牛乳の全固形分から乳脂肪分を差引いた成分をいい、牛乳、脱脂乳、加糖練乳、無糖練乳、全脂粉乳、脱脂粉乳、バターミルク、バターミルクパウダー、ホエー、ホエーパウダー、カゼイン、カゼインナトリウム、ラクトアルブミン、生クリーム等の乳由来の原料が例示でき、これらの単独または2種以上混合使用するのが好ましい。
本発明においては無脂乳固形分の使用量が大きく起泡性水中油型乳化物の風味、乳化安定性、凍結耐性に寄与している。
そして、無脂乳固形分以外の非脂固形分である糖類、食物繊維、多糖類、乳化剤、塩類は無脂乳固形分の補助的成分と位置づけでき使用量としては概ね0.5〜5重量%が好ましい。
In the present invention, it is necessary that the water content is 55 to 73% by weight and the fat and oil content is 25 to 43% by weight, and preferably the non-fat solid content is 2 to 15% by weight.
When there is too much moisture content, it exists in the tendency for the foamability at the time of foaming an oil-in-water emulsion to deteriorate. If the amount of water is too small, the viscosity of the oil-in-water emulsion increases, and a plasticization phenomenon (bottom) tends to occur during aging.
Examples of non-fat solids include non-fat milk solids, sugars, dietary fibers, polysaccharides, emulsifiers, and salts. The non-fat milk solids of the present invention are components obtained by subtracting milk fat from the total solids of milk. Good milk, skim milk, sweetened condensed milk, unsweetened condensed milk, whole milk powder, skim milk powder, buttermilk, buttermilk powder, whey, whey powder, casein, sodium caseinate, lactalbumin, fresh cream, etc. It can illustrate, and it is preferable to use these individually or in mixture of 2 or more types.
In the present invention, the amount of non-fat milk solids used is large and contributes to the flavor, emulsification stability and freezing resistance of the foamable oil-in-water emulsion.
And saccharides, dietary fiber, polysaccharides, emulsifiers and salts that are non-fat solids other than non-fat milk solids can be positioned as auxiliary components of the non-fat milk solids, and the amount used is generally 0.5 to 5 wt. % Is preferred.

無脂乳固形分量としては1〜10重量%が好ましく、より好ましくは2〜8重量%、更に好ましくは3〜6重量%である。無脂乳固形分が1重量%より低い場合は、水中油型乳化物の乳化安定性が悪くなり、乳味感も少なくなって風味が悪くなる。10重量%を超える場合は、水中油型乳化物の粘度が高くなり、エージング中に可塑化現象(ボテ)を生じ易い傾向になる。   The non-fat milk solid content is preferably 1 to 10% by weight, more preferably 2 to 8% by weight, and still more preferably 3 to 6% by weight. When the non-fat milk solid content is lower than 1% by weight, the emulsification stability of the oil-in-water emulsion is deteriorated, the milky feeling is reduced, and the flavor is deteriorated. When it exceeds 10% by weight, the viscosity of the oil-in-water emulsion increases, and a plasticization phenomenon (bottom) tends to occur during aging.

本発明の糖類は、ショ糖、果糖、ブドウ糖、乳糖、麦芽糖、転化糖、トレハロース、ソルビトール、コーンシロップ、水あめ、デキストリン等が例示できる。
本発明の食物繊維としては、小麦、果実、大豆の食物繊維が例示できる。
本発明の多糖類は、カラギーナン、キサンタンガム、ジェランガム、ペクチン、タマリンド、グアガム、アラビアガム、ローカストビーンガム、寒天、ファーセラン、結晶セルロース、微結晶セルロース、カルボキシメチルセルロースなどが挙げられ、これらを単独で用いても良いし、2種以上を併用しても良い。
Examples of the saccharide of the present invention include sucrose, fructose, glucose, lactose, maltose, invert sugar, trehalose, sorbitol, corn syrup, starch syrup, and dextrin.
Examples of dietary fiber of the present invention include wheat, fruit and soybean dietary fiber.
Examples of the polysaccharide of the present invention include carrageenan, xanthan gum, gellan gum, pectin, tamarind, guar gum, gum arabic, locust bean gum, agar, farcelan, crystalline cellulose, microcrystalline cellulose, carboxymethyl cellulose, and the like. Or two or more of them may be used in combination.

本発明の乳化剤は、レシチン、ショ糖飽和脂肪酸エステル、ソルビタン不飽和脂肪酸エステル、ソルビタン飽和脂肪酸エステル、ポリグリセリン不飽和脂肪酸エステル及びポリグリセリン飽和脂肪酸エステルから少なくとも3種以上を含むのが好ましい。
更にショ糖飽和脂肪酸エステルとしてはHLB値が4〜16の範囲のものが好ましい。また、ソルビタン不飽和脂肪酸エステルとしては主要な構成脂肪酸がオレイン酸であり、エステル化度が1〜3であるのが好ましい。ソルビタン飽和脂肪酸エステルとしては主要な構成構成脂肪酸はパルミチン酸及びステアリン酸であり、エステル化度が1〜3であるのが好ましい。ポリグリセリン不飽和脂肪酸エステルとしては主要な構成脂肪酸がオレイン酸であり、グリセリンの重合度が2〜10であり、エステル化度が1〜10であるのが好ましい。ポリグリセリン飽和脂肪酸エステルとしては主要な構成脂肪酸がミリスチン酸、パルミチン酸及びステアリン酸から1種以上選択されるものであり、グリセリンの重合度が2〜10であり、エステル化度が1〜10であるのが好ましい。
また、上記乳化剤に必要に応じて、従来より使用されてきた、モノグリセライド、上記ソルビタン脂肪酸エステル以外のソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、上記ショ糖飽和脂肪酸以外のショ糖脂肪酸エステルの合成乳化剤を使用することができる。
The emulsifier of the present invention preferably contains at least three or more of lecithin, sucrose saturated fatty acid ester, sorbitan unsaturated fatty acid ester, sorbitan saturated fatty acid ester, polyglycerin unsaturated fatty acid ester and polyglycerin saturated fatty acid ester.
Furthermore, as a sucrose saturated fatty acid ester, the thing whose HLB value is the range of 4-16 is preferable. Moreover, as sorbitan unsaturated fatty acid ester, it is preferable that the main constituent fatty acid is oleic acid and the degree of esterification is 1 to 3. As the sorbitan saturated fatty acid ester, the main constituent fatty acids are palmitic acid and stearic acid, and the degree of esterification is preferably 1 to 3. As the polyglycerol unsaturated fatty acid ester, the main constituent fatty acid is oleic acid, the polymerization degree of glycerol is preferably 2 to 10, and the esterification degree is preferably 1 to 10. As the polyglycerol saturated fatty acid ester, one or more main fatty acids are selected from myristic acid, palmitic acid and stearic acid, the polymerization degree of glycerol is 2 to 10, and the esterification degree is 1 to 10. Preferably there is.
Moreover, monoglycerides, sorbitan fatty acid esters other than the sorbitan fatty acid esters, propylene glycol fatty acid esters, polyoxyethylene sorbitan fatty acid esters, and sucrose other than the sucrose saturated fatty acids, which have been conventionally used, as necessary for the emulsifiers. Synthetic emulsifiers of fatty acid esters can be used.

本発明の起泡性水中油型乳化物については、各種塩類を使用するのが好ましく、ヘキサメタリン酸塩、第2リン酸塩、クエン酸ナトリウム、ポリリン酸塩、重曹等を単独又は2種以上混合使用することが望ましい。
その他所望により香料、着色剤、保存料等を使用することができる。
For the foamable oil-in-water emulsion of the present invention, it is preferable to use various salts, and hexametaphosphate, diphosphate, sodium citrate, polyphosphate, sodium bicarbonate, etc. alone or in combination of two or more. It is desirable to use it.
In addition, a fragrance, a colorant, a preservative and the like can be used as desired.

本発明の起泡性水中油型乳化物の製造法としては、一般的なクリーム類を製造する要領で行うことができる。具体的には油脂25〜43重量%、非脂固形分2〜15重量%、及び水を主要原料とするこれらのものを混合し、予備乳化、殺菌又は滅菌処理し均質化処理することにより得ることができる。
起泡性水中油型乳化物の保存性の点で滅菌処理することが好ましい。
As a manufacturing method of the foamable oil-in-water emulsion of this invention, it can carry out in the procedure which manufactures general creams. Specifically, it is obtained by mixing 25 to 43% by weight of fats and oils, 2 to 15% by weight of non-fat solids, and those mainly containing water, pre-emulsifying, sterilizing or sterilizing and homogenizing. be able to.
It is preferable to sterilize the foamable oil-in-water emulsion from the viewpoint of storage stability.

滅菌処理には、間接加熱方式と直接加熱方式の2種類があり、間接加熱処理する装置としてはAPVプレート式UHT処理装置(APV株式会社製)、CP−UHT滅菌装置(クリマティー・パッケージ株式会社製)、ストルク・チューブラー型滅菌装置(ストルク株式会社製)、コンサーム掻取式UHT滅菌装置(テトラパック・アルファラベル株式会社製)等が例示できるが、特にこれらにこだわるものではない。また、直接加熱式滅菌装置としては、超高温滅菌装置(岩井機械工業(株)製)、ユーペリゼーション滅菌装置(テトラパック・アルファラバル株式会社製)、VTIS滅菌装置(テトラパック・アルファラバル株式会社製)、ラギアーUHT滅菌装置(ラギアー株式会社製)、パラリゼーター(パッシュ・アンド・シルケーボーグ株式会社製)等のUHT滅菌装置が例示でき、これらの何れの装置を使用してもよい。   There are two types of sterilization treatment: indirect heating method and direct heating method. APV plate type UHT treatment device (manufactured by APV Co., Ltd.), CP-UHT sterilization device (Climati Package Co., Ltd.) Manufactured), Stork tubular type sterilizer (manufactured by STORK Co., Ltd.), Concer scraping type UHT sterilizer (manufactured by Tetra Pak Alpha Label Co., Ltd.), etc., but not particularly limited to these. Direct heating sterilizers include ultra-high temperature sterilizers (Iwai Kikai Kogyo Co., Ltd.), operation sterilizers (Tetra Pak Alfa Laval Co., Ltd.), and VTIS sterilizers (Tetra Pak Alfa Laval Co., Ltd.). UHT sterilizers such as Ragia UHT sterilizer (manufactured by Ragia Co., Ltd.), Paralyzer (manufactured by Pash and Silkeborg Co., Ltd.), and any of these devices may be used.

本発明の起泡性水中油型乳化物は、オーバーランが50〜140%、好ましくは60〜130%、更に好ましくは70〜130%、最も好ましくは80〜120%であることが好ましい。オーバーランが高すぎる場合には食感が軽すぎたり、風味の乏しいものになる傾向がある。オーバーランが低すぎる場合には食感が重たくなりすぎ、良好な風味、口溶け感が得難くなる。
本発明の起泡性水中油型乳化物は糖類を加配しホイップして凍結用ホイップドクリームを得るのであるが、起泡物をナイロン袋やプラスチック容器に充填し凍結後解凍して使用しても良いし、スポンジと共に使用しても良い。
The foamable oil-in-water emulsion of the present invention preferably has an overrun of 50 to 140%, preferably 60 to 130%, more preferably 70 to 130%, and most preferably 80 to 120%. If the overrun is too high, the texture tends to be too light or the flavor tends to be poor. When the overrun is too low, the texture becomes too heavy, and it becomes difficult to obtain a good flavor and a feeling of melting in the mouth.
In the foamable oil-in-water emulsion of the present invention, saccharides are added and whipped to obtain a whipped cream for freezing, but the foamed product is filled into a nylon bag or a plastic container and thawed after freezing. Or may be used with a sponge.

スポンジと共に使用する場合は、本発明の起泡性水中油型乳化物は、起泡性水中油型乳化物100部に対して糖類2〜40部加配し、ホイップ後得られた起泡物をスポンジにナッペし、凍結後解凍するケーキ製造のための起泡性水中油型乳化物である。
また、起泡性水中油型乳化物100部に対して糖類2〜40部加配し、ホイップ後得られた起泡物をスポンジにナッペし、凍結後解凍するケーキの製造法である。
ここで使用する糖類は、ショ糖、果糖、ブドウ糖、乳糖、麦芽糖、転化糖、トレハロース、ソルビトール、コーンシロップ、水あめが例示できる。風味の点からショ糖換算で甘味度が3〜16、好ましくは5〜14、さらに好ましくは6〜12に加配するのが好ましい。
When used with a sponge, the foamable oil-in-water emulsion of the present invention is prepared by adding 2 to 40 parts of saccharide to 100 parts of the foamable oil-in-water emulsion, and adding the foamed material obtained after whipping. It is a foamable oil-in-water emulsion for making cakes that nappe to a sponge and thaw after freezing.
Moreover, it is a manufacturing method of the cake which distributes 2-40 parts of saccharides with respect to 100 parts of foamable oil-in-water emulsions, naps the foam obtained after whipping to sponge, and thaws after freezing.
Examples of the saccharide used here include sucrose, fructose, glucose, lactose, maltose, invert sugar, trehalose, sorbitol, corn syrup, and syrup. In terms of flavor, the sweetness is preferably 3 to 16, preferably 5 to 14, and more preferably 6 to 12 in terms of sucrose.

以下に本発明の実施例を示し本発明をより詳細に説明するが、本発明の精神は以下の実施例に限定されるものではない。なお、例中、%及び部は、いずれも重量基準を意味する。特に、添加剤の添加順序或いは油相を水相へ又は水相を油相へ加える等の乳化順序が以下の例示によって限定されるものではないことは言うまでもない。また、結果については以下の方法で評価した。
A 水中油型乳化物の油脂分、水分、粘度、ボテテスト(水中油型乳化物の安定性)を評価した。方法は、
粘度:水中油型乳化物の粘度の測定は、B型粘度計(株式会社東京計器製)にて、2号ローター、60rpmの条件下で行った。
ボテテスト:水中油型乳化物を100ml容ビーカーに50g採り、20℃で2時間インキュベートし、その後5分間攪拌した時のボテの発生の有無を確認した。
EXAMPLES The present invention will be described in more detail with reference to the following examples, but the spirit of the present invention is not limited to the following examples. In the examples, “%” and “part” mean weight basis. In particular, it goes without saying that the order of addition of the additives or the emulsification order of adding the oil phase to the water phase or the water phase to the oil phase is not limited by the following examples. The results were evaluated by the following method.
A The oil and fat content, water content, viscosity, and bottest (stability of the oil-in-water emulsion) of the oil-in-water emulsion were evaluated. The method is
Viscosity: The viscosity of the oil-in-water emulsion was measured with a B-type viscometer (manufactured by Tokyo Keiki Co., Ltd.) under the conditions of No. 2 rotor and 60 rpm.
Botte test: 50 g of an oil-in-water emulsion was taken in a 100 ml beaker, incubated at 20 ° C. for 2 hours, and then checked for the presence or absence of boiling when stirred for 5 minutes.

B 水中油型乳化物を起泡させた場合の評価方法
(1)ホイップタイム:水中油型乳化物1kgをホバードミキサー(HOBART CORPORATION製 MODEL N−5)3速(300rpm)にてホイップし、最適起泡状態に達するまでの時間及び、同2速(130rpm)にて緩やかに混ぜた時間
(2)オーバーラン:[(一定容積の水中油型乳化物重量)ー(一定容積の起泡後の起泡物重量)]÷(一定容積の起泡後の起泡物重量)×100
(3)保形性:造花した起泡物を15℃で24時間放置した場合の美しさ
四段階評価 A;良好 B;やや良好
C;やや悪い D;悪い(実用的でない)
(4)離水:上記保形性評価と同時に離水状態を評価
四段階評価 A; 無し B;殆ど無し
C; 有り D;非常に多い

C 凍結耐性の評価方法
起泡したクリームをスポンジ等にナッペし、凍結、解凍した場合の表面の状態を観察。ただし、凍結条件は−25℃、10日間放置、また解凍条件は15℃で放置し、1日後、2日後の状態を観察した。
(1)解凍後の保形:造花した起泡物を放置した場合の美しさ
四段階評価 ◎;良好 ○;やや良好
△;やや悪い ×;悪い(実用的でない)
(2)解凍後の組織の荒れ
四段階評価 ◎; 無し ○;殆ど無し
△; 有り ×;非常に多い
(3)解凍後のひび割れ
四段階評価 ◎; 無し ○;殆ど無し
△; 有り ×;非常に多い
B. Evaluation method when foaming oil-in-water emulsion (1) Whip time: 1 kg of oil-in-water emulsion is whipped at 3rd speed (300 rpm) by Hovard mixer (MODEL N-5, manufactured by HOBART CORPORATION) Time to reach the optimal foaming state and time of gentle mixing at the second speed (130 rpm) (2) Overrun: [(weight of oil-in-water emulsion of constant volume)-(after foaming of constant volume Foam weight)] ÷ (foam weight after foaming a certain volume) × 100
(3) Shape retention: Beauty when artificial foam is left at 15 ° C. for 24 hours Four-step evaluation A: Good B: Somewhat good
C: Slightly bad D: Bad (not practical)
(4) Water separation: Evaluation of water separation at the same time as the above-mentioned shape retention evaluation Four-stage evaluation A; None B; Almost none
C; Yes D; Very many

C Evaluation method of freezing resistance Nappe the foamed cream to a sponge, etc., and observe the surface condition when frozen and thawed. However, the freezing condition was left at −25 ° C. for 10 days, and the thawing condition was left at 15 ° C., and the state after 1 day and 2 days later was observed.
(1) Shape retention after thawing: beauty when artificial foam is left as it is Four-step evaluation ◎; Good ○; Slightly good
△: Slightly bad ×: Bad (not practical)
(2) Roughness of tissue after thawing Four-step evaluation ◎; None ○; Almost none
△; Yes ×: Very large (3) Cracks after thawing Four-stage evaluation ◎; None ○; Almost none
△; Yes ×; Very many

使用油脂のSFC測定値
起泡性水中油型乳化物の調製に使用した油脂、パーム核油(融点29℃)、硬化パーム核油(融点38℃)、硬化ヤシ油(融点31℃)、パーム分別硬化油(融点31℃)、大豆硬化油(35℃)についてSFC値を測定した。
油脂のSFC(固体脂含量)の測定法は、IUPAC2.150(Solid Content Determination in Fats by NMR)に準じて行なった。
結果を表1に纏めた。

Figure 2009050235
SFC measured value of used fats and oils used for preparation of foamable oil-in-water emulsion, palm kernel oil (melting point 29 ° C), hardened palm kernel oil (melting point 38 ° C), hardened palm oil (melting point 31 ° C), palm SFC values were measured for fractionated hardened oil (melting point 31 ° C.) and soybean hardened oil (35 ° C.).
The measurement method of SFC (solid fat content) of fats and oils was performed according to IUPAC 2.150 (Solid Content Determination in Fats by NMR).
The results are summarized in Table 1.
Figure 2009050235

実施例1
パーム核油(融点29℃)20.0部、硬化パーム核油(融点38℃)5.0部、パーム分別硬化油(融点31℃)5.0部にレシチン0.25部、ポリグリセリン不飽和脂肪酸エステル(阪本薬品工業(株)製、商品名SYグリスターMO−3S)0.01部を添加混合溶解し油相とする。
これとは別に水60.65部に、脱脂粉乳3.5部、ショ糖飽和脂肪酸エステル(三菱化学フーズ(株)製、 商品名:S−570)0.12部、ポリグリセリン飽和脂肪酸エステル(阪本薬品工業(株)製、商品名SYグリスターMS−5S)0.05部、ヘキサメタリン酸ナトリウム0.2部、重曹0.02部、キサンタンガム0.05部、グァーガム0.05部、ミルクフレーバー0.1部を溶解し水相を調製する。
上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、144℃において4秒間の直接加熱方式による滅菌処理を行った後、40Kg/cm2 の均質化圧力で均質化して、直ちに10℃に冷却した。冷却後約24時間エージングして、起泡性水中油型乳化物を得た。
この起泡性水中油型乳化物1kgに80gのグラニュー糖を加えて上記ホイップ方法にてホイップし、上記の方法に従いオーバーラン、保形性、離水の測定を行った。またこのホイップドクリームをスポンジケーキにデコレーションし−25℃の冷凍庫で10日間保存後、15℃の定温室で解凍し1日後と2日後上記の方法に従って外観の観察、保形性、組織の荒れ、ひび割れおよび風味を評価した。結果を表2に纏めた。
Example 1
20.0 parts of palm kernel oil (melting point 29 ° C.), 5.0 parts of hardened palm kernel oil (melting point 38 ° C.), 5.0 parts of palm fractionated hardened oil (melting point 31 ° C.), 0.25 part of lecithin, polyglycerin-free 0.01 part of a saturated fatty acid ester (Sakamoto Yakuhin Kogyo Co., Ltd., trade name SY Glister MO-3S) is added, mixed and dissolved to obtain an oil phase.
Separately, 60.65 parts of water, 3.5 parts of skim milk powder, sucrose saturated fatty acid ester (Mitsubishi Chemical Foods, Inc., trade name: S-570) 0.12 part, polyglycerin saturated fatty acid ester ( Sakamoto Pharmaceutical Co., Ltd., trade name SY Glister MS-5S) 0.05 parts, sodium hexametaphosphate 0.2 parts, sodium bicarbonate 0.02 parts, xanthan gum 0.05 parts, guar gum 0.05 parts, milk flavor 0 Dissolve 1 part to prepare aqueous phase.
The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by a direct heating method at 144 ° C. for 4 seconds using an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.). After the run, it was homogenized at a homogenization pressure of 40 kg / cm 2 and immediately cooled to 10 ° C. After cooling, the mixture was aged for about 24 hours to obtain a foamable oil-in-water emulsion.
80 g of granulated sugar was added to 1 kg of this foamable oil-in-water emulsion and whipped by the above whipping method, and overrun, shape retention and water separation were measured according to the above methods. Also, this whipped cream is decorated in a sponge cake, stored in a freezer at -25 ° C for 10 days, thawed in a constant temperature room at 15 ° C, and after 1 and 2 days, observation of appearance, shape retention, and rough structure according to the above methods The cracks and flavor were evaluated. The results are summarized in Table 2.

実施例2〜実施例4
実施例2
パーム核油(融点29℃)20.0部を26.0部とし、硬化パーム核油(融点38℃)5.0部を7.0部とし、パーム分別硬化油(融点31℃)5.0部を7.0部とし水を調整した以外は実施例1と同様な配合で同様な処理を行い実施例1と同様に評価した。結果を表2に纏めた。
実施例3
パーム核油(融点29℃)20.0部を23.0部とし、パーム分別硬化油(融点31℃)5.0部を8.0部とし水を調整した以外は実施例1と同様な配合で同様な処理を行い実施例1と同様に評価した。結果を表2に纏めた。
実施例4
パーム核油(融点29℃)20.0部を26.0部とし、硬化パーム核油(融点38℃)5.0部を7.0部とし、パーム分別硬化油(融点31℃)5.0部を7.0部とし水を調整した以外は実施例1と同様な配合で同様な処理を行い実施例1と同様に評価した。結果を表2に纏めた。
Example 2 to Example 4
Example 2
4. 20.0 parts of palm kernel oil (melting point: 29 ° C.) is 26.0 parts, 5.0 parts of hardened palm kernel oil (melting point: 38 ° C.) is 7.0 parts, and fractionated hardened palm oil (melting point: 31 ° C.) Evaluation was performed in the same manner as in Example 1, except that 0 part was 7.0 parts and water was adjusted, and the same treatment was performed with the same composition as in Example 1. The results are summarized in Table 2.
Example 3
Example 1 except that 20.0 parts of palm kernel oil (melting point 29 ° C.) was 23.0 parts, and 5.0 parts of palm fractionated hardened oil (melting point 31 ° C.) was 8.0 parts and water was adjusted. The same treatment was performed for the blending, and the same evaluation as in Example 1 was performed. The results are summarized in Table 2.
Example 4
4. 20.0 parts of palm kernel oil (melting point: 29 ° C.) is 26.0 parts, 5.0 parts of hardened palm kernel oil (melting point: 38 ° C.) is 7.0 parts, and fractionated hardened palm oil (melting point: 31 ° C.) Evaluation was performed in the same manner as in Example 1, except that 0 part was 7.0 parts and water was adjusted, and the same treatment was performed with the same composition as in Example 1. The results are summarized in Table 2.

実施例1〜実施例4の配合と評価を表2に纏めた。

Figure 2009050235
The formulations and evaluations of Examples 1 to 4 are summarized in Table 2.
Figure 2009050235

実施例5
実施例1のパーム核油(融点29℃)20.0部を硬化ヤシ油(融点31℃)20.0部に代えた以外は実施例1と同様な配合で同様な処理を行い実施例1と同様に評価した。結果を表3に纏めた。
実施例6
実施例2のパーム核油(融点29℃)15.0部を硬化ヤシ油(融点31℃)15.0部に代えた以外は実施例2と同様な配合で同様な処理を行い実施例2と同様に評価した。結果を表3に纏めた。
実施例7
実施例3のパーム核油(融点29℃)23.0部を硬化ヤシ油(融点31℃)23.0部に代えた以外は実施例3と同様な配合で同様な処理を行い実施例3と同様に評価した。結果を表3に纏めた。
実施例8
実施例4のパーム核油(融点29℃)26.0部を硬化ヤシ油(融点31℃)26.0部に代えた以外は実施例4と同様な配合で同様な処理を行い実施例4と同様に評価した。結果を表3に纏めた。
Example 5
Example 1 was carried out in the same manner as in Example 1 except that 20.0 parts of palm kernel oil (melting point: 29 ° C.) in Example 1 was replaced with 20.0 parts of hardened palm oil (melting point: 31 ° C.). And evaluated in the same manner. The results are summarized in Table 3.
Example 6
Example 2 was performed in the same manner as in Example 2 except that 15.0 parts of palm kernel oil (melting point: 29 ° C.) of Example 2 was replaced with 15.0 parts of hardened palm oil (melting point: 31 ° C.). And evaluated in the same manner. The results are summarized in Table 3.
Example 7
Example 3 was carried out in the same manner as in Example 3 except that 23.0 parts of palm kernel oil (melting point: 29 ° C.) in Example 3 was replaced with 23.0 parts of hardened palm oil (melting point: 31 ° C.). And evaluated in the same manner. The results are summarized in Table 3.
Example 8
Example 4 was carried out in the same manner as in Example 4 except that 26.0 parts of palm kernel oil (melting point: 29 ° C.) in Example 4 were replaced with 26.0 parts of hardened palm oil (melting point: 31 ° C.). And evaluated in the same manner. The results are summarized in Table 3.

実施例5〜実施例8の配合と評価を表3に纏めた。

Figure 2009050235
The composition and evaluation of Examples 5 to 8 are summarized in Table 3.
Figure 2009050235

実施例9
実施例1において、ポリグリセリン不飽和脂肪酸エステル(阪本薬品工業(株)製、商品名SYグリスターMO−3S)0.01部をソルビタン不飽和脂肪酸エステル(理研ビタミン(株)製、商品名ポエムO−80V)0.04部に、ポリグリセリン飽和脂肪酸エステル(阪本薬品工業(株)製、商品名SYグリスターMS−5S)0.05部をソルビタン飽和脂肪酸エステル(理研ビタミン(株)製、商品名ポエムS−60V)0.05部に代えた以外は実施例1と同様な配合で同様な処理を行い実施例1と同様に評価した。結果を表4に纏めた。
実施例10
実施例2において、ポリグリセリン不飽和脂肪酸エステル(阪本薬品工業(株)製、商品名SYグリスターMO−3S)0.01部をソルビタン不飽和脂肪酸エステル(理研ビタミン(株)製、商品名ポエムO−80V)0.04部に、ポリグリセリン飽和脂肪酸エステル(阪本薬品工業(株)製、商品名SYグリスターMS−5S)0.05部をソルビタン飽和脂肪酸エステル(理研ビタミン(株)製、商品名ポエムS−60V)0.05部に代えた以外は実施例2と同様な配合で同様な処理を行い実施例1と同様に評価した。結果を表4に纏めた。
実施例11
実施例9において、ソルビタン飽和脂肪酸エステル(理研ビタミン(株)製、商品名ポエムS−60V)0.05部を使用しない以外は実施例9と同様な配合で同様な処理を行い実施例1と同様に評価した。結果を表4に纏めた。
実施例12
実施例9において、ソルビタン不飽和脂肪酸エステル(理研ビタミン(株)製、商品名ポエムO−80V)0.04部を使用しない以外は実施例9と同様な配合で同様な処理を行い実施例1と同様に評価した。結果を表4に纏めた。
Example 9
In Example 1, 0.01 part of polyglycerin unsaturated fatty acid ester (Sakamoto Yakuhin Kogyo Co., Ltd., trade name SY Glister MO-3S) was dissolved in sorbitan unsaturated fatty acid ester (Riken Vitamin Co., Ltd., trade name Poem O). -80V) 0.04 part, polyglycerin saturated fatty acid ester (Sakamoto Yakuhin Kogyo Co., Ltd., trade name SY Glister MS-5S) 0.05 part sorbitan saturated fatty acid ester (Riken Vitamin Co., Ltd., trade name) (Poem S-60V) The same treatment was carried out in the same manner as in Example 1 except that the amount was changed to 0.05 part, and evaluation was performed in the same manner as in Example 1. The results are summarized in Table 4.
Example 10
In Example 2, 0.01 part of polyglycerin unsaturated fatty acid ester (Sakamoto Yakuhin Kogyo Co., Ltd., trade name SY Glister MO-3S) was dissolved in sorbitan unsaturated fatty acid ester (Riken Vitamin Co., Ltd., trade name Poem O). -80V) 0.04 part, polyglycerin saturated fatty acid ester (Sakamoto Yakuhin Kogyo Co., Ltd., trade name SY Glister MS-5S) 0.05 part sorbitan saturated fatty acid ester (Riken Vitamin Co., Ltd., trade name) (Poem S-60V) Except that the amount was changed to 0.05 part, the same treatment as in Example 2 was performed and the same evaluation as in Example 1 was performed. The results are summarized in Table 4.
Example 11
In Example 9, the same treatment was carried out as in Example 1 except that 0.05 part of sorbitan saturated fatty acid ester (trade name Poem S-60V, manufactured by Riken Vitamin Co., Ltd.) was not used. Evaluation was performed in the same manner. The results are summarized in Table 4.
Example 12
In Example 9, the same treatment was performed as in Example 9 except that 0.04 part of sorbitan unsaturated fatty acid ester (manufactured by Riken Vitamin Co., Ltd., trade name Poem O-80V) was not used. And evaluated in the same manner. The results are summarized in Table 4.

実施例9〜実施例12の配合と評価を表4に纏めた。

Figure 2009050235
The formulations and evaluations of Examples 9 to 12 are summarized in Table 4.
Figure 2009050235

実施例13
実施例1において、ポリグリセリン飽和脂肪酸エステル(阪本薬品工業(株)製、商品名SYグリスターMS−5S)0.05部を使用せず、ショ糖飽和脂肪酸エステル(三菱化学フーズ(株)製、 商品名:S−570)0.12部を0.15部に代えた以外は実施例1と同様な配合で同様な処理を行い実施例1と同様に評価した。結果を表5に纏めた。
実施例14
実施例1において、ポリグリセリン不飽和脂肪酸エステル(阪本薬品工業(株)製、商品名SYグリスターMO−3S)0.01部を使用しない以外は実施例1と同様な配合で同様な処理を行い実施例1と同様に評価した。結果を表5に纏めた。
実施例15
実施例1に、果物の食物繊維であるヘルバセルAQプラスCF−D(大日本住友製薬(株)製)0.5部を使用した以外は実施例1と同様な配合で同様な処理を行い実施例1と同様に評価した。結果を表5に纏めた。
実施例16
実施例1に、小麦の食物繊維であるウィートブランP(日清製粉(株))0.5部を使用した以外は実施例1と同様な配合で同様な処理を行い実施例1と同様に評価した。結果を表5に纏めた。
Example 13
In Example 1, 0.05 part of polyglycerin saturated fatty acid ester (Sakamoto Yakuhin Kogyo Co., Ltd., trade name SY Glister MS-5S) was not used, but sucrose saturated fatty acid ester (Mitsubishi Chemical Foods Co., Ltd., (Product name: S-570) The same treatment as in Example 1 was carried out in the same manner as in Example 1 except that 0.12 part was changed to 0.15 part, and evaluation was made in the same manner as in Example 1. The results are summarized in Table 5.
Example 14
In Example 1, the same treatment as in Example 1 was performed except that 0.01 part of polyglycerol unsaturated fatty acid ester (Sakamoto Yakuhin Kogyo Co., Ltd., trade name SY Glyster MO-3S) was not used. Evaluation was performed in the same manner as in Example 1. The results are summarized in Table 5.
Example 15
The same treatment as in Example 1 was performed except that 0.5 part of Herbacel AQ plus CF-D (manufactured by Dainippon Sumitomo Pharma Co., Ltd.), which is a dietary fiber of fruit, was used in Example 1. Evaluation was performed in the same manner as in Example 1. The results are summarized in Table 5.
Example 16
The same treatment as in Example 1 was performed in the same manner as in Example 1 except that 0.5 part of Wheat Blanc P (Nisshin Flour Milling Co., Ltd.), which is a dietary fiber of wheat, was used in Example 1. evaluated. The results are summarized in Table 5.

実施例13〜実施例16の配合と評価を表5に纏めた。

Figure 2009050235
The formulations and evaluations of Examples 13 to 16 are summarized in Table 5.
Figure 2009050235

比較例1
実施例1のパーム核油(融点29℃)20.0部、硬化パーム核油(融点38℃)5.0部、パーム分別硬化油(融点31℃)5.0部を其々パーム核油(融点29℃)15.0部、硬化パーム核油(融点38℃)4.0部、パーム分別硬化油(融点31℃)4.0部に代え水を調整した以外は実施例1と同様な配合で同様な処理を行い実施例1と同様に評価した。結果を表6に纏めた。
比較例2
実施例1のパーム核油(融点29℃)20.0部、硬化パーム核油(融点38℃)5.0部、パーム分別硬化油(融点31℃)5.0部を其々パーム核油(融点29℃)30.0部、硬化パーム核油(融点38℃)7.0部、パーム分別硬化油(融点31℃)8.0部に代え水を調整した以外は実施例1と同様な配合で同様な処理を行い実施例1と同様に評価した。結果を表6に纏めた。
比較例3
実施例1において、パーム核油(融点29℃)20.0部、硬化パーム核油(融点38℃)5.0部、パーム分別硬化油(融点31℃)5.0部を其々パーム核油(融点29℃)10.0部、硬化パーム核油(融点38℃)5.0部、パーム分別硬化油(融点31℃)15.0部に代えた以外は実施例1と同様な配合で同様な処理を行い実施例1と同様に評価した。結果を表6に纏めた。
比較例4
実施例1のパーム核油(融点29℃)20.0部、硬化パーム核油(融点38℃)5.0部、パーム分別硬化油(融点31℃)5.0部を其々パーム核油(融点29℃)12.0部、大豆硬化油(融点35℃)23.0部に代え水を調整した以外は実施例1と同様な配合で同様な処理を行い実施例1と同様に評価した。結果を表6に纏めた。
比較例5
実施例5の硬化ヤシ油(融点31℃)20.0部、硬化パーム核油(融点38℃)5.0部、パーム分別硬化油(融点31℃)5.0部を其々硬化ヤシ油(融点31℃)12.0部、大豆硬化油(融点35℃)23.0部に代え水を調整した以外は実施例5と同様な配合で同様な処理を行い実施例5と同様に評価した。結果を表6に纏めた。
Comparative Example 1
Palm kernel oil of Example 1 (melting point 29 ° C.) 20.0 parts, hardened palm kernel oil (melting point 38 ° C.) 5.0 parts, palm fractionated hardened oil (melting point 31 ° C.) 5.0 parts, respectively. (Melting point 29 ° C.) 15.0 parts, Hardened palm kernel oil (melting point 38 ° C.) 4.0 parts, Palm fractionated hardened oil (melting point 31 ° C.) 4.0 parts The same treatment was carried out with various formulations, and the same evaluation as in Example 1 was conducted. The results are summarized in Table 6.
Comparative Example 2
Palm kernel oil of Example 1 (melting point 29 ° C.) 20.0 parts, hardened palm kernel oil (melting point 38 ° C.) 5.0 parts, palm fractionated hardened oil (melting point 31 ° C.) 5.0 parts, respectively. (Melting point 29 ° C.) 30.0 parts, Hardened palm kernel oil (melting point 38 ° C.) 7.0 parts, Palm fractionated hardened oil (melting point 31 ° C.) 8.0 parts, except that water was adjusted The same treatment was carried out with various formulations, and the same evaluation as in Example 1 was conducted. The results are summarized in Table 6.
Comparative Example 3
In Example 1, 20.0 parts of palm kernel oil (melting point 29 ° C.), 5.0 parts of hardened palm kernel oil (melting point 38 ° C.), 5.0 parts of palm fractionated hardened oil (melting point 31 ° C.) Formulation similar to Example 1, except that 10.0 parts of oil (melting point 29 ° C.), 5.0 parts of hardened palm kernel oil (melting point 38 ° C.), and 15.0 parts of palm fractionated hardened oil (melting point 31 ° C.) In the same manner as in Example 1, the same treatment was carried out. The results are summarized in Table 6.
Comparative Example 4
Palm kernel oil of Example 1 (melting point 29 ° C.) 20.0 parts, hardened palm kernel oil (melting point 38 ° C.) 5.0 parts, palm fractionated hardened oil (melting point 31 ° C.) 5.0 parts, respectively. (Melting point 29 ° C.) 12.0 parts, soybean treatment oil (melting point 35 ° C.) 23.0 parts were replaced with water, and the same treatment was performed with the same composition as in Example 1 except that water was adjusted. did. The results are summarized in Table 6.
Comparative Example 5
Hardened coconut oil of Example 5 (melting point 31 ° C.) 20.0 parts, hardened palm kernel oil (melting point 38 ° C.) 5.0 parts, and palm fractionated hardened oil (melting point 31 ° C.) 5.0 parts, respectively. (Melting point 31 ° C.) 12.0 parts, soybean treatment oil (melting point 35 ° C.) 23.0 parts was replaced with water, and the same treatment was carried out with the same composition as in Example 5 and evaluated in the same manner as in Example 5. did. The results are summarized in Table 6.

比較例1〜比較例5の配合と評価を表6に纏めた。

Figure 2009050235
Table 6 summarizes the formulations and evaluations of Comparative Examples 1 to 5.
Figure 2009050235

本発明は、ホイップさせた状態もしくはこれをケーキ等にデコレーションした状態で冷凍保存し解凍しても、型崩れまたはひび割れあるいは組織の荒れを起こすことなく、優れた風味の凍結耐性を有する起泡性水中油型乳化物及びその製造法に関するものである。   The present invention is a foaming property that has excellent flavor freezing resistance without causing loss of shape, cracking or roughening of the structure even when frozen and thawed in a whipped state or decorated in a cake or the like. The present invention relates to an oil-in-water emulsion and a method for producing the same.

Claims (6)

油脂、水及び乳化剤を含む水中油型乳化物において、水分量が55〜73重量%であり、油脂分が25〜43重量%であって、油脂中の55重量%以上が10℃におけるSFCが65〜98%の範囲のラウリン系油脂であることを特徴とする起泡性水中油型乳化物。 In an oil-in-water emulsion containing fats and oils, water and an emulsifier, the water content is 55 to 73% by weight, the fats and oils content is 25 to 43% by weight, and 55% by weight or more in the fats and oils is SFC at 10 ° C. A foamable oil-in-water emulsion characterized by being a lauric fat in the range of 65 to 98%. 乳化剤がレシチン、ショ糖飽和脂肪酸エステル、ソルビタン不飽和脂肪酸エステル、ソルビタン飽和脂肪酸エステル、ポリグリセリン不飽和脂肪酸エステル及びポリグリセリン飽和脂肪酸エステルから少なくとも3種以上を含む、請求項1記載の起泡性水中油型乳化物。 The foaming water according to claim 1, wherein the emulsifier comprises at least three kinds of lecithin, sucrose saturated fatty acid ester, sorbitan unsaturated fatty acid ester, sorbitan saturated fatty acid ester, polyglycerol unsaturated fatty acid ester and polyglycerol saturated fatty acid ester. Oil-type emulsion. オーバーランが50〜140%である、請求項1又は請求項2記載の起泡性水中油型乳化物。 The foamable oil-in-water emulsion according to claim 1 or 2, wherein the overrun is 50 to 140%. 請求項1〜請求項3の何れか1項に記載の起泡性水中油型乳化物の、凍結用ホイップドクリームとしての使用。 Use of the foamable oil-in-water emulsion according to any one of claims 1 to 3 as a whipped cream for freezing. 請求項1〜請求項3の何れか1項に記載の起泡性水中油型乳化物100部に対して糖類2〜40部加配し、ホイップ後得られた起泡物をスポンジにナッペし、凍結後解凍するケーキ製造のための起泡性水中油型乳化物。 2 to 40 parts of saccharide is added to 100 parts of the foamable oil-in-water emulsion according to any one of claims 1 to 3, and the foam obtained after whipping is napped onto a sponge. A foamable oil-in-water emulsion for making a cake that thaws after freezing. 請求項1〜請求項3の何れか1項に記載の起泡性水中油型乳化物100部に対して糖類2〜40部加配し、ホイップ後得られた起泡物をスポンジにナッペし、凍結後解凍するケーキの製造法。 2 to 40 parts of saccharide is added to 100 parts of the foamable oil-in-water emulsion according to any one of claims 1 to 3, and the foam obtained after whipping is napped onto a sponge. A method for making cakes that thaw after freezing.
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