JP2006094801A - Oil-in-water emulsified product containing nonfat milk solid - Google Patents

Oil-in-water emulsified product containing nonfat milk solid Download PDF

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JP2006094801A
JP2006094801A JP2004286294A JP2004286294A JP2006094801A JP 2006094801 A JP2006094801 A JP 2006094801A JP 2004286294 A JP2004286294 A JP 2004286294A JP 2004286294 A JP2004286294 A JP 2004286294A JP 2006094801 A JP2006094801 A JP 2006094801A
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oil
acid
fat milk
water emulsion
fat
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Hiroyuki Ichiyama
裕之 市山
Hiroshi Hidaka
博志 日高
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Fuji Oil Co Ltd
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Fuji Oil Co Ltd
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Priority to JP2004286294A priority Critical patent/JP2006094801A/en
Priority to EP05703871A priority patent/EP1716765A4/en
Priority to KR1020067014880A priority patent/KR101202052B1/en
Priority to PCT/JP2005/000643 priority patent/WO2005070228A1/en
Priority to US10/584,298 priority patent/US8034392B2/en
Priority to TW094119784A priority patent/TWI380781B/en
Priority to MYPI20052872A priority patent/MY137701A/en
Publication of JP2006094801A publication Critical patent/JP2006094801A/en
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Abstract

<P>PROBLEM TO BE SOLVED: To provide an oil-in-water emulsified product containing nonfat milk solid, usable as a substitution of cow milk and concentrated milk, having less quality deterioration of bad taste and odor even if exposing under photo irradiation of a fluorescent lamp, and excellent in flavor. <P>SOLUTION: This oil-in-water emulsified product containing nonfat milk solid contains 1-12 wt.% of oil and fat, 3-26 wt.% of nonfat milk solid and water. The composition of the constituent fatty acid of the oil and fat is such that the total amount of lauric acid and palmitic acid is ≥40%, the total amount of oleic acid, linoleic acid and linolenic acid is ≤50% and the total amount of linoleic acid and linolenic acid is ≤5%. The emulsified product for kneading contains tocopherol and has tolerance to light deterioration. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、牛乳や濃縮乳の代替として使用でき、プリン、ゼリー等のデザート類の上に添加したり、プリン、ババロア、ゼリー等の練り込み用に適した無脂乳固形分含有水中油型乳化物に関する。更に詳しくは蛍光灯等の光照射による異味、異臭の品質の劣化が少ない無脂乳固形分含有水中油型乳化物に関する。   The present invention can be used as an alternative to milk or concentrated milk, and is added to desserts such as pudding and jelly, and is an oil-in-water type containing non-fat milk solids suitable for kneading pudding, bavaria, jelly, etc. It relates to an emulsion. More specifically, the present invention relates to an oil-in-water emulsion containing a non-fat milk solid content with less deterioration in the quality of off-flavors and off-flavors caused by light irradiation from a fluorescent lamp or the like.

プリンは、デザートの一つであり、風味、食感等で子供から大人まで多くの人々に親しまれている。その嗜好性に合わせ需要に応えるべく、様々な原料配合及び製造方法が種々提案されている。プリンは、大きく分けて卵の熱凝固力で固めるカスタードタイプとゲル化剤で固めるゲル化タイプとの2つに大別できる。カスタードタイプは、卵類、乳製品、糖類を主原料として作られる。卵類としては、全卵、卵黄、卵白等が例示できるし、乳製品としては、牛乳、濃縮乳、全脂粉乳、脱脂粉乳、生クリーム、コンパウンドクリーム、植物性クリーム、ナチュラルチーズ、プロセスチーズ、チーズフーズ等が例示できる。牛乳は直接飲料としても使用されるが、プリン、ババロア、ゼリー等への練り込み用素材としても利用されている。ゲル化タイプは、乳製品、ゲル化剤、糖類を主原料として作られる。ゲル化剤としては、ゼラチン、カラギーナン等が例示できる。近年、デパート地下の洋菓子店、コンビニエンスストア、スーパーマーケット等では、蛍光灯によって強い光を長時間照射しながら種々の食品をショーケースに陳列して販売している。プリンもこれらの食品の中の一つにあげられる。このとき、照射される光から与えられるエネルギーによって、陳列されている食品中の成分が変化し、異味、異臭が生じる。このようにして異味、異臭が生じることによって食品の品質が劣化する現象は、一般的に光劣化と呼ばれており、食品の風味を著しく損ねて商品価値を下落させるために、光劣化防止対策は品質保持の上で大きな問題となっている。この光劣化を防止するために、特許文献1では、ミリセチン類とクエルセチン類を特定の配合比でもって併用したり、特許文献2では、プロポリスを使用したり、特許文献3では、クロロゲン酸、カフェー酸、フェルラ酸から選ばれる少なくとも1種を使用するなど、さまざまな風味劣化防止剤が光劣化の抑制作用を有する物質として食品中に添加されてきたが、添加しすぎるとそのもの自体の風味が出てしまうなど使用量が限定される。先に本出願人は油脂分が比較的多い水中油型乳化物において特定の油脂を使用することによって、光照射下に晒されても異味、異臭の品質劣化が少ないという光劣化耐性を有することを見出し特許文献4として出願した。意外にも油脂分の少ない無脂乳固形分含有水中油型乳化物の場合においても光劣化耐性を有することを見出した。   Pudding is one of the desserts and is loved by many people from children to adults because of its flavor and texture. Various raw material blends and manufacturing methods have been proposed in order to meet demand in accordance with the palatability. Purines can be broadly divided into two types: custard types that harden with the thermal coagulation force of eggs and gelling types that harden with gelling agents. The custard type is made mainly from eggs, dairy products and sugars. Examples of eggs include whole eggs, egg yolks, egg whites, and examples of dairy products include milk, concentrated milk, whole milk powder, skim milk powder, fresh cream, compound cream, vegetable cream, natural cheese, processed cheese, Cheese foods etc. can be illustrated. Milk is used directly as a beverage, but it is also used as a material for kneading into pudding, bavarois, jelly and the like. The gelation type is made mainly from dairy products, gelling agents and sugars. Examples of the gelling agent include gelatin and carrageenan. In recent years, in pastry stores, convenience stores, supermarkets, etc. in department stores, various foods are displayed and sold in a showcase while irradiating with strong light with a fluorescent lamp for a long time. Pudding is one of these foods. At this time, the components in the displayed food are changed by the energy applied from the irradiated light, resulting in a nasty taste and odor. The phenomenon of food quality deterioration due to the occurrence of a nasty taste and odor in this way is generally called light degradation, and measures to prevent light degradation in order to seriously impair the flavor of food and reduce the product value. Is a major problem in maintaining quality. In order to prevent this photodegradation, in Patent Document 1, myricetins and quercetins are used in combination at a specific mixing ratio, in Patent Document 2, propolis is used, and in Patent Document 3, chlorogenic acid and caffeine are used. Various flavor deterioration inhibitors, such as the use of at least one selected from acid and ferulic acid, have been added to foods as substances that have the effect of suppressing light degradation. The amount of use is limited. First, the present applicant has a light deterioration resistance such that there is little deterioration in quality of taste and odor even when exposed to light irradiation by using a specific oil in an oil-in-water emulsion with a relatively high fat content. And filed as Patent Document 4. Surprisingly, it has been found that even in the case of an oil-in-water emulsion containing a non-fat milk solid containing a small amount of oil and fat, it has light degradation resistance.

特開2003−33164号公報JP 2003-33164 A 特開平11−341971号公報Japanese Patent Laid-Open No. 11-341971 特開平10−183164号公報Japanese Patent Laid-Open No. 10-183164 特願2004−187656号公報Japanese Patent Application No. 2004-187656

本発明の目的は、牛乳や濃縮乳の代替として使用できる無脂乳固形分含有水中油型乳化物であって、蛍光灯等の光照射下に晒されても異味、異臭の品質の劣化が少なく、風味に優れた無脂乳固形分含有水中油型乳化物を提供することにある。   An object of the present invention is a non-fat milk solid-containing oil-in-water emulsion that can be used as an alternative to milk or concentrated milk, and it has a bad taste and bad smell even when exposed to light irradiation such as a fluorescent lamp. An object of the present invention is to provide an oil-in-water emulsion containing a non-fat milk solid content which is small and excellent in flavor.

本発明者らは上記課題に対して、鋭意研究を行った結果、無脂乳固形分含有水中油型乳化物中に使用する油脂において、油脂中の構成脂肪酸がある特定範囲の油脂を使用した場合において、光照射下に晒されても異味、異臭の品質の劣化が少ないという光劣化耐性を有することを見出した。また、特定の風味劣化防止剤と組み合わせることによって更に品質の劣化が抑えられることを見出し本発明を完成するに至った。
即ち本発明の第1は、油脂、無脂乳固形分及び水を含む無脂乳固形分含有水中油型乳化物において、油脂分が1〜12重量%、無脂乳固形分が3〜26重量%であって、油脂中の構成脂肪酸組成が、ラウリン酸、パルミチン酸の合計量が40%以上であり、オレイン酸、リノール酸、リノレン酸の合計量が50%以下であり、且つリノール酸、リノレン酸の合計量が5%以下である油脂を特徴とする無脂乳固形分含有水中油型乳化物である。第2は更にトコフェロールを含む、第1記載の無脂乳固形分含有水中油型乳化物である。第3は練り込み用である、第1記載の無脂乳固形分含有水中油型乳化物である。第4は、プリン、ババロア、ゼリーの練り込み用である、第1記載の無脂乳固形分含有水中油型乳化物である。
As a result of diligent research on the above problems, the present inventors used a specific range of fats and oils with constituent fatty acids in the fats and oils used in the oil-in-water emulsion containing non-fat milk solids. In some cases, it has been found that even when exposed to light irradiation, it has light deterioration resistance such that there is little deterioration in quality of taste and smell. Moreover, it discovered that quality degradation could be further suppressed by combining with a specific flavor degradation inhibitor, and completed the present invention.
That is, the first aspect of the present invention is a nonfat milk solid-containing oil-in-water emulsion containing fats and oils, nonfat milk solids and water, wherein the fats and oils are 1 to 12% by weight and the nonfat milk solids are 3 to 26. The total fatty acid composition in the fat and oil is 40% or more, and the total amount of oleic acid, linoleic acid, and linolenic acid is 50% or less, and linoleic acid. An oil-in-water emulsion containing a non-fat milk solid content, characterized by an oil having a total amount of linolenic acid of 5% or less. The second is the oil-in-water emulsion containing the non-fat milk solid content according to the first, further comprising tocopherol. The third is the oil-in-water emulsion containing the non-fat milk solid content according to the first, which is for kneading. The fourth is the oil-in-water emulsion containing the non-fat milk solid content according to the first, which is used for kneading pudding, bavalore and jelly.

本発明により、蛍光灯等の光照射下に晒されても異味、異臭の品質の劣化が少なく風味に優れた、光劣化耐性を有する無脂乳固形分含有水中油型乳化物、更に無脂乳固形分含有水中油型乳化物がプリン、ババロア、ゼリー等の練り込み用に用いられる無脂乳固形分含有水中油型乳化物を提供することが可能になった。   According to the present invention, a non-fat milk solid-containing oil-in-water emulsion having light deterioration resistance, which has excellent flavor and little deterioration in quality of off-flavors and off-flavors even when exposed to light such as a fluorescent lamp, and further non-fat It has become possible to provide a non-fat milk solid-containing oil-in-water emulsion in which the milk solid-containing oil-in-water emulsion is used for kneading pudding, bavalore, jelly and the like.

本発明の油脂としては、油脂中の構成脂肪酸の脂肪酸組成が、ラウリン酸、パルミチン酸の合計量が40%以上であり、オレイン酸、リノール酸、リノレン酸の合計量が50%以下であり、且つリノール酸、リノレン酸の合計量が5%以下である油脂であれば何れの油脂も選択使用することが出来る。好ましくは、油脂中の構成脂肪酸組成が、ラウリン酸、パルミチン酸の合計量が50%以上であり、更に好ましくは55%以上であり、オレイン酸、リノール酸、リノレン酸の合計が40%以下、更に好ましくは35%以下であり、リノール酸、リノレン酸の合計が4%以下、更に好ましくは3%以下である油脂が好ましい。具体的には、動植物性油脂及びそれらの硬化油脂の単独又は2種以上の混合物或いはこれらのものに種々の化学処理又は物理処理を施したものが例示できる。かかる油脂としては、大豆油、綿実油、コーン油、サフラワー油、オリーブ油、パーム油、菜種油、米ぬか油、ゴマ油、カポック油、ヤシ油、パーム核油、乳脂、ラード、魚油、鯨油等の各種の動植物油脂及びそれらの硬化油、分別油、エステル交換油等の加工油脂(融点15〜40℃程度のもの)が例示できる。これらの油脂の中では、ヤシ油、パーム核油のラウリン系油脂とパーム油の組み合わせが好ましい。
油脂分が1重量%未満では、乳化物自身にコク味が乏しくなり、プリンに練り込んだ際にはプリンの風味が悪く、また、カスタードプリンにおいては腰の弱い脆い性状のものとなる。また12重量%を超えると濃縮乳らしい物性が得にくくなり、プリンに練り込んだ際には硬い組織となり、プリン本来の食感が得られにくくなり、油っぽいものになってしまう。
As the fats and oils of the present invention, the fatty acid composition of the constituent fatty acids in the fats and oils, the total amount of lauric acid and palmitic acid is 40% or more, the total amount of oleic acid, linoleic acid, linolenic acid is 50% or less, And any fats and oils can be selectively used as long as the total amount of linoleic acid and linolenic acid is 5% or less. Preferably, the constituent fatty acid composition in the fat or oil is such that the total amount of lauric acid and palmitic acid is 50% or more, more preferably 55% or more, and the total of oleic acid, linoleic acid, and linolenic acid is 40% or less, More preferably, it is 35% or less, and fats and oils in which the total of linoleic acid and linolenic acid is 4% or less, more preferably 3% or less are preferred. Specific examples include animal and vegetable fats and oils and their hardened fats and oils, or a mixture of two or more thereof, or those obtained by subjecting these to various chemical treatments or physical treatments. Such fats and oils include soybean oil, cottonseed oil, corn oil, safflower oil, olive oil, palm oil, rapeseed oil, rice bran oil, sesame oil, kapok oil, coconut oil, palm kernel oil, milk fat, lard, fish oil, whale oil, etc. Examples include animal and vegetable oils and fats, processed oils and fats such as hydrogenated oils, fractionated oils, and transesterified oils (melting points of about 15 to 40 ° C.). Among these oils and fats, a combination of palm oil, lauric oil of palm kernel oil and palm oil is preferable.
If the fat and oil content is less than 1% by weight, the emulsion itself has a poor body taste, and when kneaded into pudding, the pudding has a bad taste, and custard pudding has a weak and brittle shape. On the other hand, when the content exceeds 12% by weight, it becomes difficult to obtain physical properties like concentrated milk, and when kneaded into pudding, it becomes a hard structure, making it difficult to obtain the original texture of pudding, resulting in an oily one.

本発明の無脂乳固形分としては、牛乳の全固形分から乳脂肪分を差引いた成分をいい、生乳、牛乳、脱脂乳、生クリーム、濃縮乳、無糖練乳、加糖練乳、全脂粉乳、脱脂粉乳、バターミルクパウダー、ホエー蛋白、カゼイン、カゼインナトリウム等の乳由来の原料が例示でき、無脂乳固形分が3〜26重量%が好ましく、3重量%未満では風味が乏しく、カスタードプリンにおいては充分なゲル化強度が得られないので、保形性が悪化するほか、食感がゼリー様となる。また、26重量%を超えると組織が硬くなりすぎ食感が悪くなるほか、コストも高くなり、量に見合った効果が得られるとは言い難くなる。   The non-fat milk solid content of the present invention refers to a component obtained by subtracting the milk fat content from the total solid content of milk, raw milk, cow milk, skim milk, fresh cream, concentrated milk, sugar-free condensed milk, sweetened condensed milk, whole milk powder, Non-fat dry milk, buttermilk powder, whey protein, casein, sodium casein and other milk-derived raw materials can be exemplified, and the non-fat milk solid content is preferably 3 to 26% by weight, less than 3% by weight has poor flavor, and in custard pudding Since sufficient gelation strength cannot be obtained, shape retention becomes worse and the texture becomes jelly-like. On the other hand, if it exceeds 26% by weight, the tissue becomes too hard and the texture becomes worse, the cost is increased, and it is difficult to say that an effect commensurate with the amount can be obtained.

本発明の乳化剤としては、無脂乳固形分含有水中油型乳化物を調製する際に通常使用する乳化剤を適宜選択使用することが出来る。例えば、レシチン、モノグリセライド、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ショ糖脂肪酸エステル等の合成乳化剤が例示でき、これらの乳化剤の中から1種又は2種以上を選択して適宜使用することができる。これらの乳化剤のうち、光照射下に晒されても異味、異臭の品質の劣化が少ないという点で、乳化剤中の構成脂肪酸に不飽和脂肪酸を含まない乳化剤を使用するのが好ましい。   As the emulsifier of the present invention, an emulsifier usually used when preparing an oil-in-water emulsion containing non-fat milk solids can be appropriately selected and used. Examples include synthetic emulsifiers such as lecithin, monoglyceride, sorbitan fatty acid ester, propylene glycol fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sucrose fatty acid ester, and one or two of these emulsifiers. The above can be selected and used appropriately. Among these emulsifiers, it is preferable to use an emulsifier that does not contain an unsaturated fatty acid as a constituent fatty acid in the emulsifier in that the quality of taste and odor is less deteriorated even when exposed to light.

本発明の無脂乳固形分含有水中油型乳化物は、トコフェロールを風味劣化防止剤として含むことが好ましい。
本発明のトコフェロールとしては、それ自体既知のものであり、市販品として入手可能である。これらは天然の植物から抽出した精製品でも未精製品中に含まれたものでもよく、合成品でも良い。また、δ−トコフェロール等の単品でもα、β、γ、δ−トコフェロール等の混合物でも良いが、好ましくは低α、高δのものが好ましい。また、油脂、デキストリン等により希釈された製剤で使用しても良い。市販品としては理研ビタミン株式会社製の(商品名:理研オイルスーパー80、トコフェロール64%含有)などが例示できる。
本発明の無脂乳固形分含有水中油型乳化物に用いるトコフェロールの使用量については0.05〜1.5重量%、好ましくは0.07〜0.1.3重量%、最も好ましくは0.1〜1.0重量%の範囲で使用するのが望ましい。
トコフェロールの使用量が少ないと、添加の効果は得られにくく、多すぎると無脂乳固形分含有水中油型乳化物の風味、色調が悪くなる。
The oil-in-water emulsion containing non-fat milk solids of the present invention preferably contains tocopherol as a flavor deterioration preventing agent.
The tocopherol of the present invention is known per se and is available as a commercial product. These may be refined products extracted from natural plants, those contained in immature products, or synthetic products. Further, a single product such as δ-tocopherol or a mixture of α, β, γ, δ-tocopherol and the like may be used, but those having low α and high δ are preferable. Moreover, you may use by the formulation diluted with fats and oils, dextrin, etc. Examples of commercially available products include those manufactured by Riken Vitamin Co., Ltd. (trade name: Riken Oil Super 80, containing 64% tocopherol).
The amount of tocopherol used in the non-fat milk solids-containing oil-in-water emulsion of the present invention is 0.05 to 1.5% by weight, preferably 0.07 to 0.1.3% by weight, most preferably 0. It is desirable to use in the range of 1 to 1.0% by weight.
If the amount of tocopherol used is small, the effect of addition is difficult to obtain, and if it is too large, the flavor and color tone of the oil-in-water emulsion containing the non-fat milk solid content will be poor.

本発明の無脂乳固形分含有水中油型乳化物に使用する上記風味劣化防止剤は、トコフェロール有効成分として含有する事により所望の効果が得られるが、必要に応じて公知の抗酸化剤(L−アスコルビン酸等)、香味劣化防止剤(クロロゲン酸、リンゴポリフェノール、ヒマワリ抽出物、ヤマモモ抽出物、ルチン、カテキン等)、金属封鎖剤(グルコン酸、コウジ酸、フィチン酸、ポリリン酸、キチン、キトサン等)等を使用することもできる。   Although the said flavor deterioration inhibitor used for the non-fat milk solid content oil-in-water emulsion of this invention contains a desired effect by containing as a tocopherol active ingredient, well-known antioxidant ( L-ascorbic acid, etc.), flavor deterioration inhibitors (chlorogenic acid, apple polyphenol, sunflower extract, bayberry extract, rutin, catechin, etc.), sequestering agents (gluconic acid, kojic acid, phytic acid, polyphosphoric acid, chitin, Chitosan etc.) can also be used.

本発明の無脂乳固形分含有水中油型乳化物に使用する上記風味劣化防止剤の添加時期は、特に限定されないが、無脂乳固形分含有水中油型乳化物が光劣化を受ける前に予め添加しておくことが必要であって、無脂乳固形分含有水中油型乳化物を調製する際に添加してもよいし、無脂乳固形分含有水中油型乳化物を調製した後、プリン等に練り込む際に添加してもよい。好ましくは、無脂乳固形分含有水中油型乳化物を調製する際に各種原料とともに配合することが望ましい。   The addition timing of the flavor deterioration inhibitor used in the non-fat milk solid-containing oil-in-water emulsion of the present invention is not particularly limited, but before the non-fat milk solid-containing oil-in-water emulsion undergoes photodegradation. It is necessary to add in advance, and may be added when preparing a nonfat milk solid-containing oil-in-water emulsion, or after preparing a nonfat milk solid-containing oil-in-water emulsion It may be added when kneaded into pudding or the like. Preferably, when preparing an oil-in-water emulsion containing a non-fat milk solid content, it is desirable to blend with various raw materials.

本発明の無脂乳固形分含有水中油型乳化物については、各種塩類を使用することが出来る。塩類としては、ヘキサメタリン酸塩、第2リン酸塩、クエン酸ナトリウム、ポリリン酸塩、重曹等を単独又は2種以上混合使用することが好ましい。その他所望により糖類、安定剤、香料、着色料、保存料等を使用することが出来る。   Various salts can be used for the non-fat milk solid-containing oil-in-water emulsion of the present invention. As the salts, it is preferable to use hexametaphosphate, diphosphate, sodium citrate, polyphosphate, sodium bicarbonate or the like alone or in combination. In addition, saccharides, stabilizers, fragrances, coloring agents, preservatives and the like can be used as desired.

本発明の無脂乳固形分含有水中油型乳化物は所望により、使用可能な濃度又は適宜希釈して供用出来る濃縮濃度になるように配合される。牛乳と似た組成としたい場合、油脂分3〜4重量%、無脂乳固形分8〜9重量%、水87〜89重量%の割合で配合するのが好ましい。また、無脂乳固形分含有水中油型乳化物を2〜5倍程度の適当な倍率に希釈して使用するように、予め濃縮された形で提供することも出来る。例えば濃縮乳と似た組成にした場合は油脂分9〜12重量%、無脂乳固形分24〜27重量%、水67〜61重量%とするのが適当である。その際は、乳化剤等の添加量も希釈に応じ、増加することが好ましい。このように適宜に油脂分、無脂乳固形分の割合を調整することが可能であって、あっさりとした風味から濃厚な風味まで適宜選択することが可能である。   The non-fat milk solid-containing oil-in-water emulsion of the present invention is blended so as to have a usable concentration or a concentrated concentration that can be used after appropriately diluted. When it is desired to have a composition similar to that of milk, it is preferably blended at a ratio of 3 to 4% by weight of fat and oil, 8 to 9% by weight of solid content of non-fat milk, and 87 to 89% by weight of water. Moreover, the oil-in-water emulsion containing non-fat milk solid content can also be provided in a pre-concentrated form so as to be diluted to an appropriate magnification of about 2 to 5 times. For example, when the composition is similar to that of concentrated milk, the oil / fat content is 9 to 12% by weight, the non-fat milk solid content is 24 to 27% by weight, and the water is 67 to 61% by weight. In that case, it is preferable that the addition amount of an emulsifier etc. also increases according to dilution. Thus, it is possible to appropriately adjust the ratio of oil and fat and non-fat milk solids, and it is possible to appropriately select from a light flavor to a rich flavor.

本発明の無脂乳固形分含有水中油型乳化物の製造法としては、油脂、無脂乳固形分及び水を主要原料とするこれらの原料を混合後、予備乳化、殺菌又は滅菌処理し均質化処理することにより得ることができる。無脂乳固形分含有水中油型乳化物の保存性の点で滅菌処理することが好ましい。具体的には、各種原料を60〜70℃で20分間予備乳化した後(乳化装置はホモミキサー)、必要により0〜250Kg/cm2の条件下にて均質化(乳化装置は均質機)する。次いで超高温瞬間殺菌処理(UHT)した後、再度、0〜300Kg/cm2の条件化にて均質化し、冷却後、約24時間エージングする。 As a method for producing the oil-in-water emulsion containing the non-fat milk solid content of the present invention, after mixing these raw materials mainly containing oil and fat, non-fat milk solids and water, the mixture is pre-emulsified, sterilized or sterilized to be homogeneous. It can be obtained by performing the conversion process. It is preferable to sterilize from the viewpoint of preservability of the oil-in-water emulsion containing the non-fat milk solid content. Specifically, after preliminarily emulsifying various raw materials at 60 to 70 ° C. for 20 minutes (the emulsifying device is a homomixer), the material is homogenized under the condition of 0 to 250 kg / cm 2 as necessary (the emulsifying device is a homogenizer). . Next, after ultra-high temperature instant sterilization (UHT), it is homogenized again under the condition of 0 to 300 kg / cm 2 , and after cooling, it is aged for about 24 hours.

超高温瞬間(UHT)殺菌には、間接加熱方式と直接加熱方式の2種類があり、間接加熱処理する装置としてはAPVプレート式UHT処理装置(APV株式会社製)、CPーUHT滅菌装置(クリマティー・パッケージ株式会社製)、ストルク・チューブラー型滅菌装置(ストルク株式会社製)、コンサーム掻取式UHT滅菌装置(テトラパック・アルファラベル株式会社製)等が例示できるが、特にこれらにこだわるものではない。また、直接加熱式滅菌装置としては、超高温滅菌装置(岩井機械工業(株)製)、ユーペリゼーション滅菌装置(テトラパック・アルファラバル株式会社製)、VTIS滅菌装置(テトラパック・アルファラバル株式会社製)、ラギアーUHT滅菌装置(ラギアー株式会社製)、パラリゼーター(パッシュ・アンド・シルケーボーグ株式会社製)等のUHT滅菌装置が例示でき、これらの何れの装置を使用してもよい。   There are two types of ultra-high temperature instant (UHT) sterilization: indirect heating method and direct heating method. As an indirect heat treatment device, APV plate type UHT treatment device (manufactured by APV Corporation), CP-UHT sterilization device (Kurima) Tea package Co., Ltd.), Torque / tubular sterilizer (Stork Co., Ltd.), Concer scraping type UHT sterilizer (Tetra Pak Alpha Label Co., Ltd.), etc. is not. Direct heating sterilizers include ultra-high temperature sterilizers (Iwai Kikai Kogyo Co., Ltd.), operation sterilizers (Tetra Pak Alfa Laval Co., Ltd.), and VTIS sterilizers (Tetra Pak Alfa Laval Co., Ltd.). UHT sterilizers such as Ragia UHT sterilizer (manufactured by Ragia Co., Ltd.), Paralyzer (manufactured by Pash and Silkeborg Co., Ltd.), and any of these devices may be used.

本発明の無脂乳固形分含有水中油型乳化物は、上記したように所望により、油脂分、無脂乳固形分を使用可能な範囲で調整でき、牛乳や濃縮乳の代替として使用できる。プリンやコーヒーゼリー、果汁ゼリー、ムース等のデザート類の上に添加して使用しても良いし、練り込み用としても使用でき、プリンや果汁ゼリー、ムース等の練り込み用に適している。   As described above, the non-fat milk solid-containing oil-in-water emulsion of the present invention can be adjusted in a range where the oil and fat and non-fat milk solids can be used as desired, and can be used as an alternative to cow's milk or concentrated milk. It can be used by adding it to desserts such as pudding, coffee jelly, fruit juice jelly, mousse, etc. It can also be used for kneading and is suitable for kneading pudding, fruit juice jelly, mousse and the like.

以下に本発明の実施例を示し本発明をより詳細に説明するが、本発明の精神は以下の実施例に限定されるものではない。なお、例中、%及び部は、いずれも重量基準を意味する。
特に、添加剤の添加順序或いは油相を水相へ又は水相を油相へ加える等の乳化順序が以下の例示によって限定されるものではないことは言うまでもない。また、結果については以下の方法で評価した。
EXAMPLES The present invention will be described in more detail with reference to the following examples, but the spirit of the present invention is not limited to the following examples. In the examples, “%” and “part” mean weight basis.
In particular, it goes without saying that the order of addition of the additives or the emulsification order of adding the oil phase to the water phase or the water phase to the oil phase is not limited by the following examples. The results were evaluated by the following method.

A.無脂乳固形分含有水中油型乳化物の評価方法
プリンやコーヒーゼリー、果汁ゼリー、ムース等のデザート類の上に添加して使用する水中油型乳化物(クリーム)を想定して、リスパック株式会社製のクリーンカップ120BLに無脂乳固形分含有水中油型乳化物を30g入れ、光照射前の風味評価と光照射後の風味評価の2種類を行った。光照射試験は、蛍光灯照射(照度4000Lx)、温度5℃にて12,24,72時間保存後評価した。風味評価は、優れている順に「5」、「4」、「3」、「2」、「1」の五段階にて評価を行い、平均化した評価を結果とした。風味の評価は専門パネラー20名により官能評価を実施した。
B.カスタードプリンでの評価方法
全卵450gとグラニュー糖200gをよくすり合わせる。これに必要に応じ希釈した無脂乳固形分含有水中油型乳化物1000gを火にかけ温めてから加え、網で裏ごししプリン液を得た。これを耐熱性のプリンカップ(株式会社東光製、ポリプロピレン製・半透明樽型90cc)に60g毎に静かに注ぎいれ、オーブン(上火150℃/下火150℃)を用いて、トレイに40℃程のお湯を入れ35分程湯煎焼成し、その後放冷してカスタードプリン得た。風味評価は、光照射前の風味評価と光照射後の風味評価の2種類を行った。光照射試験は、蛍光灯照射(照度4000Lx)、温度5℃にて保存後評価した。風味評価は、優れている順に「5」、「4」、「3」、「2」、「1」の5段階にて評価を行い、平均化した評価を結果とした。風味評価は専門パネラー20名により官能評価を実施した。
A. Evaluation method for oil-in-water emulsions containing non-fat milk solids Lispack shares assuming oil-in-water emulsions (creams) to be added to desserts such as pudding, coffee jelly, fruit juice jelly, and mousse 30 g of non-fat milk solid content-containing oil-in-water emulsion was put into a company-made clean cup 120BL, and two types of flavor evaluation before light irradiation and flavor evaluation after light irradiation were performed. The light irradiation test was evaluated after storage for 12, 24 and 72 hours at a fluorescent lamp irradiation (illuminance 4000 Lx) and a temperature of 5 ° C. The flavor evaluation was evaluated in five stages of “5”, “4”, “3”, “2”, “1” in order of superiority, and the averaged evaluation was the result. The taste was evaluated by sensory evaluation by 20 professional panelists.
B. Evaluation method with custard pudding 450g of whole egg and 200g of granulated sugar are rubbed together. To this, 1000 g of an oil-in-water emulsion containing non-fat milk solids diluted as necessary was heated and heated, and was then screened to obtain a pudding solution. This is gently poured into a heat-resistant pudding cup (Toko Co., Ltd., polypropylene, translucent barrel type 90 cc) every 60 g, and placed in a tray using an oven (top heat 150 ° C./bottom fire 150 ° C.). C. hot water was baked for about 35 minutes and then allowed to cool to obtain custard pudding. Two kinds of flavor evaluation were performed: flavor evaluation before light irradiation and flavor evaluation after light irradiation. The light irradiation test was evaluated after storage at fluorescent lamp irradiation (illuminance 4000 Lx) at a temperature of 5 ° C. The flavor evaluation was evaluated in five stages of “5”, “4”, “3”, “2”, “1” in order of superiority, and the averaged evaluation was the result. Taste evaluation was performed by 20 expert panelists.

実験例1
水中油型乳化物の調製に使用した油脂、パーム中融点部(融点34℃)、硬化パーム核油(融点34℃)、硬化ヤシ油(融点32℃)、硬化大豆油(融点31℃)、硬化菜種油(融点35℃)について油脂中の構成脂肪酸の組成を常法に従いこれらの油脂をメチルエステル化してガスクロマトグラム法にて分析を行い、分析チャートの面積割合より組成とその割合を求めた。
求めた脂肪酸のうち、ラウリン酸+パルミチン酸、オレイン酸+リノール酸+リノレン酸、リノール酸+リノレン酸の割合を表1に纏めた。
Experimental example 1
Oils and fats used in the preparation of the oil-in-water emulsion, palm middle melting point (melting point 34 ° C), hardened palm kernel oil (melting point 34 ° C), hardened palm oil (melting point 32 ° C), hardened soybean oil (melting point 31 ° C), About hardened rapeseed oil (melting point 35 degreeC), the composition of the constituent fatty acid in fats and oils was methyl-esterified according to the conventional method, and it analyzed by the gas chromatogram method, The composition and its ratio were calculated | required from the area ratio of the analysis chart.
Among the obtained fatty acids, the ratios of lauric acid + palmitic acid, oleic acid + linoleic acid + linolenic acid, and linoleic acid + linolenic acid are summarized in Table 1.

Figure 2006094801
Figure 2006094801

実施例1
パーム中融点部(融点34℃)4.5部、硬化パーム核油(融点34℃)4.5部を油相とする。これとは別に水69.7部に脱脂粉乳21.0部、モノミリスチン酸ペンタグリセリン0.1部、メタリン酸ナトリウム0.2部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、無脂乳固形分含有水中油型乳化物を得た。この乳化物を上記のA.無脂乳固形分含有水中油型乳化物の評価方法に従って評価した。結果を表2に纏めた。
Example 1
The oily phase is 4.5 parts of the palm melting point (melting point 34 ° C) and 4.5 parts of hardened palm kernel oil (melting point 34 ° C). Separately, 21.0 parts of skim milk powder, 0.1 part of pentaglyceryl monomyristate and 0.2 part of sodium metaphosphate are dissolved in 69.7 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion containing non-fat milk solids. This emulsion was converted to the above-mentioned A. It evaluated according to the evaluation method of non-fat milk solid content-containing oil-in-water emulsion. The results are summarized in Table 2.

実施例2
パーム中融点部(融点34℃)2.0部、硬化パーム核油(融点34℃)2.0部を油相とする。これとは別に水85.7部に脱脂粉乳10.0部、モノミリスチン酸ペンタグリセリン0.1部、メタリン酸ナトリウム0.2部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、無脂乳固形分含有水中油型乳化物を得た。この乳化物を上記のA.無脂乳固形分含有水中油型乳化物の評価方法に従って評価した。結果を表2に纏めた。
Example 2
An oil phase is 2.0 parts of the middle melting point of palm (melting point 34 ° C) and 2.0 parts of hardened palm kernel oil (melting point 34 ° C). Separately, 10.0 parts of skim milk powder, 0.1 part of pentaglyceryl monomyristate and 0.2 part of sodium metaphosphate are dissolved in 85.7 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion containing non-fat milk solids. This emulsion was converted to the above-mentioned A. It evaluated according to the evaluation method of non-fat milk solid content-containing oil-in-water emulsion. The results are summarized in Table 2.

実施例3
パーム中融点部(融点34℃)6.0部、硬化パーム核油(融点34℃)3.0部を油相とする。これとは別に水75.7部に脱脂粉乳15.0部、モノミリスチン酸ペンタグリセリン0.1部、メタリン酸ナトリウム0.2部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、無脂乳固形分含有水中油型乳化物を得た。この乳化物を上記のA.無脂乳固形分含有水中油型乳化物の評価方法に従って評価した。結果を表2に纏めた。
Example 3
The oil melting point is 6.0 parts of the middle melting point of palm (melting point 34 ° C) and 3.0 parts of hardened palm kernel oil (melting point 34 ° C). Separately, 15.0 parts of skim milk powder, 0.1 part of pentaglyceryl monomyristate and 0.2 part of sodium metaphosphate are dissolved in 75.7 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion containing non-fat milk solids. This emulsion was converted to the above-mentioned A. It evaluated according to the evaluation method of non-fat milk solid content-containing oil-in-water emulsion. The results are summarized in Table 2.

比較例1
無脂乳固形分含有水中油型乳化物の代わりに市販の牛乳(明治乳業株式会社製、油脂分3.7重量%以上、無脂乳固形分8.5重量%以上)を用い、上記のA.無脂乳固形分含有水中油型乳化物の評価方法に従って評価した。評価した結果を表2に纏めた。
Comparative Example 1
Instead of the non-fat milk solid content-containing oil-in-water emulsion, commercially available milk (manufactured by Meiji Dairies Co., Ltd., oil / fat content of 3.7 wt% or more, non-fat milk solid content of 8.5 wt% or more) is used. A. It evaluated according to the evaluation method of non-fat milk solid content-containing oil-in-water emulsion. The evaluation results are summarized in Table 2.

比較例2
無脂乳固形分含有水中油型乳化物の代わりに市販の濃縮乳(よつ葉乳業株式会社製、油脂分10.6重量%、無脂乳固形分25.2重量%)を用い、上記のA.無脂乳固形分含有水中油型乳化物の評価方法に従って評価した。評価した結果を表2に纏めた。
Comparative Example 2
A commercially available concentrated milk (manufactured by Yotsuba Milk Industry Co., Ltd., oil / fat content 10.6% by weight, non-fat milk solid content 25.2% by weight) is used in place of the oil-in-water emulsion containing non-fat milk solids. . It evaluated according to the evaluation method of non-fat milk solid content-containing oil-in-water emulsion. The evaluation results are summarized in Table 2.

表2に実施例1〜実施例3、比較例1、比較例2の配合、評価を纏めた。

Figure 2006094801
Table 2 summarizes the formulations and evaluations of Examples 1 to 3, Comparative Example 1, and Comparative Example 2.
Figure 2006094801

実施例4
パーム中融点部(融点34℃)4.5部、硬化パーム核油(融点34℃)4.5部にトコフェロール(商品名:理研オイルスーパー80、理研ビタミン株式会社製;トコフェロール64%含有)0.15部を添加混合溶解し油相とする。これとは別に水69.6部に脱脂粉乳21.0部、モノミリスチン酸ペンタグリセリン0.1部、メタリン酸ナトリウム0.2部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、無脂乳固形分含有水中油型乳化物を得た。この乳化物を水にて3倍に希釈し、上記B.カスタードプリンを試作した場合の評価方法に従って評価した。結果を表3に纏めた。
Example 4
Tocopherol (trade name: Riken Oil Super 80, manufactured by Riken Vitamin Co., Ltd .; containing 64% tocopherol) 0 to 4.5 parts of palm middle melting point (melting point 34 ° C), 4.5 parts of hardened palm kernel oil (melting point 34 ° C) 15 parts are added, mixed and dissolved to form an oil phase. Separately, 21.0 parts of skim milk powder, 0.1 part of pentaglyceryl monomyristate and 0.2 part of sodium metaphosphate are dissolved in 69.6 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion containing non-fat milk solids. This emulsion was diluted 3 times with water, and B. above. The custard pudding was evaluated according to the evaluation method when prototyped. The results are summarized in Table 3.

実施例5
パーム中融点部(融点34℃)4.5部、硬化パーム核油(融点34℃)4.5部にトコフェロール(商品名:理研オイルスーパー80、理研ビタミン株式会社製;トコフェロール64%含有)0.45部を添加混合溶解し油相とする。これとは別に水69.3部に脱脂粉乳21.0部、モノミリスチン酸ペンタグリセリン0.1部、メタリン酸ナトリウム0.2部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、無脂乳固形分含有水中油型乳化物を得た。この乳化物を水にて3倍に希釈し、上記B.カスタードプリンを試作した場合の評価方法に従って評価した。結果を表3に纏めた。
Example 5
Tocopherol (trade name: Riken Oil Super 80, manufactured by Riken Vitamin Co., Ltd .; containing 64% tocopherol) 0 to 4.5 parts of palm middle melting point (melting point 34 ° C), 4.5 parts of hardened palm kernel oil (melting point 34 ° C) 45 parts are added, mixed and dissolved to form an oil phase. Separately, 21.0 parts of skim milk powder, 0.1 part of pentaglyceryl monomyristate and 0.2 part of sodium metaphosphate are dissolved in 69.3 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion containing non-fat milk solids. This emulsion was diluted 3 times with water, and B. above. The custard pudding was evaluated according to the evaluation method when prototyped. The results are summarized in Table 3.

実施例6
パーム中融点部(融点34℃)4.5部、硬化パーム核油(融点34℃)4.5部にトコフェロール(商品名:理研オイルスーパー80、理研ビタミン株式会社製;トコフェロール64%含有)0.90部を添加混合溶解し油相とする。これとは別に水68.8部に脱脂粉乳21.0部、モノミリスチン酸ペンタグリセリン0.1部、メタリン酸ナトリウム0.2部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、無脂乳固形分含有水中油型乳化物を得た。この乳化物を水にて3倍に希釈し、上記B.カスタードプリンを試作した場合の評価方法に従って評価した。結果を表3に纏めた。
Example 6
Tocopherol (trade name: Riken Oil Super 80, manufactured by Riken Vitamin Co., Ltd .; containing 64% tocopherol) 0 to 4.5 parts of palm middle melting point (melting point 34 ° C), 4.5 parts of hardened palm kernel oil (melting point 34 ° C) 90 parts are added, mixed and dissolved to form an oil phase. Separately, 21.0 parts of skim milk powder, 0.1 part of pentaglyceryl monomyristate and 0.2 part of sodium metaphosphate are dissolved in 68.8 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion containing non-fat milk solids. This emulsion was diluted 3 times with water, and B. above. The custard pudding was evaluated according to the evaluation method when prototyped. The results are summarized in Table 3.

表3に実施例3〜実施例6の配合、評価を纏めた。

Figure 2006094801
Table 3 summarizes the formulations and evaluations of Examples 3 to 6.
Figure 2006094801

比較例3
硬化パーム核油(融点34℃)4.5部、硬化菜種油(融点35℃)4.5部にレシチン0.05部を添加混合溶解し油相とする。これとは別に水69.7部に脱脂粉乳21.0部、ショ糖脂肪酸エステル0.1部、メタリン酸ナトリウム0.2部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、無脂乳固形分含有水中油型乳化物を得た。この乳化物を水にて3倍に希釈し、上記B.カスタードプリンを試作した場合の評価方法に従って評価した。結果を表4に纏めた。
Comparative Example 3
Add 0.05 parts of lecithin to 4.5 parts of hardened palm kernel oil (melting point 34 ° C.) and 4.5 parts of hardened rapeseed oil (melting point 35 ° C.), and dissolve to obtain an oil phase. Separately, 21.0 parts of skim milk powder, 0.1 part of sucrose fatty acid ester and 0.2 part of sodium metaphosphate are dissolved in 69.7 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion containing non-fat milk solids. This emulsion was diluted 3 times with water, and B. above. The custard pudding was evaluated according to the evaluation method when prototyped. The results are summarized in Table 4.

比較例4
硬化菜種油(融点35℃)9.0部にレシチン0.05部を添加混合溶解し油相とする。これとは別に水69.7部に脱脂粉乳21.0部、ショ糖脂肪酸エステル0.1部、メタリン酸ナトリウム0.2部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、100Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、無脂乳固形分含有水中油型乳化物を得た。この乳化物を水にて3倍に希釈し、上記B.カスタードプリンを試作した場合の評価方法に従って評価した。結果を表4に纏めた。
Comparative Example 4
Add 0.05 parts of lecithin to 9.0 parts of hardened rapeseed oil (melting point 35 ° C.) and dissolve to obtain an oil phase. Separately, 21.0 parts of skim milk powder, 0.1 part of sucrose fatty acid ester and 0.2 part of sodium metaphosphate are dissolved in 69.7 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 100 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an oil-in-water emulsion containing non-fat milk solids. This emulsion was diluted 3 times with water, and B. above. The custard pudding was evaluated according to the evaluation method when prototyped. The results are summarized in Table 4.

表4に比較例3、比較例4の配合、評価を纏めた。

Figure 2006094801
Table 4 summarizes the composition and evaluation of Comparative Example 3 and Comparative Example 4.
Figure 2006094801

本発明は、牛乳や濃縮乳の代替として使用でき、プリン、ゼリー等のデザート類の上に添加したり、プリン、ババロア、ゼリー等の練り込み用に適した無脂乳固形分含有水中油型乳化物に関する。更に詳しくは蛍光灯等の光照射による異味、異臭の品質の劣化が少ない無脂乳固形分含有水中油型乳化物に関する。   The present invention can be used as an alternative to milk or concentrated milk, and is added to desserts such as pudding and jelly, and is an oil-in-water type containing non-fat milk solids suitable for kneading pudding, bavaria, jelly, etc. It relates to an emulsion. More specifically, the present invention relates to an oil-in-water emulsion containing a non-fat milk solid content with less deterioration in the quality of off-flavors and off-flavors caused by light irradiation from a fluorescent lamp or the like.

Claims (4)

油脂、無脂乳固形分及び水を含む無脂乳固形分含有水中油型乳化物において、油脂分が1〜12重量%、無脂乳固形分が3〜26重量%であって、油脂中の構成脂肪酸組成が、ラウリン酸、パルミチン酸の合計量が40%以上であり、オレイン酸、リノール酸、リノレン酸の合計量が50%以下であり、且つリノール酸、リノレン酸の合計量が5%以下である油脂を特徴とする無脂乳固形分含有水中油型乳化物。 In an oil-in-water emulsion containing non-fat milk solids containing fats and oils, non-fat milk solids and water, the fats and oils are 1 to 12% by weight, the non-fat milk solids are 3 to 26% by weight, and in the fats and oils The total amount of lauric acid and palmitic acid is 40% or more, the total amount of oleic acid, linoleic acid, and linolenic acid is 50% or less, and the total amount of linoleic acid and linolenic acid is 5 % Oil-in-water emulsion containing a non-fat milk solid content. 更にトコフェロールを含む、請求項1記載の無脂乳固形分含有水中油型乳化物。 Furthermore, the non-fat milk solid content oil-in-water emulsion of Claim 1 containing a tocopherol. 練り込み用である、請求項1記載の無脂乳固形分含有水中油型乳化物。 The oil-in-water emulsion containing the non-fat milk solid content according to claim 1, which is for kneading. プリン、ババロア、ゼリーの練り込み用である、請求項1記載の無脂乳固形分含有水中油型乳化物。 The oil-in-water emulsion containing a non-fat milk solid content according to claim 1, which is used for kneading pudding, bavaria and jelly.
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JP2007037509A (en) * 2005-08-05 2007-02-15 Taiyo Yushi Kk Oil-in-water emulsified oil and fat composition for drink addition
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