JP5283302B2 - Foamable oil-in-water emulsion - Google Patents

Foamable oil-in-water emulsion Download PDF

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JP5283302B2
JP5283302B2 JP2004078093A JP2004078093A JP5283302B2 JP 5283302 B2 JP5283302 B2 JP 5283302B2 JP 2004078093 A JP2004078093 A JP 2004078093A JP 2004078093 A JP2004078093 A JP 2004078093A JP 5283302 B2 JP5283302 B2 JP 5283302B2
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oil
acid
parts
water emulsion
water
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JP2005237354A (en
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裕之 市山
博志 日高
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Fuji Oil Co Ltd
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Priority to KR1020067014880A priority patent/KR101202052B1/en
Priority to EP05703871A priority patent/EP1716765A4/en
Priority to US10/584,298 priority patent/US8034392B2/en
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Description

本発明は、ケーキ等のデコレーションやサンド等に用いられる起泡性水中油型乳化物(ホイップクリーム)に関する。更に詳しくは蛍光灯等の光照射による異味、異臭の品質の劣化が少ない起泡性水中油型乳化物に関する。   The present invention relates to a foamable oil-in-water emulsion (whipped cream) used for decoration such as cake or sand. More specifically, the present invention relates to a foamable oil-in-water emulsion with little deterioration in quality of off-flavors and off-flavors caused by light irradiation from a fluorescent lamp or the like.

近年、デパート地下の洋菓子店、コンビニエンスストア、スーパーマーケット等では、蛍光灯によって強い光を長時間照射しながら種々の食品をショーケースに陳列して販売している。ケーキ等のデコレーションやサンド等に用いられる起泡性水中油型乳化物もこれらの食品の中の一つにあげられる。このとき、照射される光から与えられるエネルギーによって、陳列されている食品中の成分が変化し、異味、異臭が生じる。このようにして異味、異臭が生じることによって食品の品質が劣化する現象は、一般的に光劣化と呼ばれており、食品の風味を著しく損ねて商品価値を下落させるために、光劣化防止対策は品質保持の上で大きな問題となっている。この光劣化を防止するために、特許文献1では、ミリセチン類とクエルセチン類を特定の配合比でもって併用したり、特許文献2では、プロポリスを使用したり、特許文献3では、クロロゲン酸、カフェー酸、フェルラ酸から選ばれる少なくとも1種を使用するなど、さまざまな風味劣化防止剤が光劣化の抑制作用を有する物質として食品中に添加されてきたが、添加しすぎるとそのもの自体の風味が出てしまうなど使用量が限定され、こと起泡性水中油型乳化物においてはそれだけでは十分な効果を得ることが出来なかった。   In recent years, in pastry stores, convenience stores, supermarkets, etc. in department stores, various foods are displayed and sold in a showcase while irradiating with strong light with a fluorescent lamp for a long time. Foamable oil-in-water emulsions used for decorations such as cakes and sands are one of these foods. At this time, the components in the displayed food are changed by the energy applied from the irradiated light, resulting in a taste and a strange odor. The phenomenon that the quality of food deteriorates due to the occurrence of off-flavors and odors in this way is generally called photo-degradation, and is a measure to prevent photo-degradation in order to significantly impair the flavor of food and reduce the product value. Is a major problem in maintaining quality. In order to prevent this photodegradation, in Patent Document 1, myricetins and quercetin are used in combination at a specific mixing ratio, in Patent Document 2, propolis is used, and in Patent Document 3, chlorogenic acid and caffeine are used. Various flavor deterioration inhibitors, such as the use of at least one selected from acids and ferulic acids, have been added to foods as substances that have the effect of inhibiting photodegradation. The amount of use was limited, and in particular, a foamable oil-in-water emulsion could not provide a sufficient effect.

特開2003−33164号公報JP 2003-33164 A 特開平11−341971号公報Japanese Patent Laid-Open No. 11-341971 特開平10−183164号公報Japanese Patent Laid-Open No. 10-183164

本発明の目的は、ケーキ等のデコレーションやサンド等に用いられる起泡性水中油型乳化物において、蛍光灯等の光照射下に晒せれても異味、異臭の品質の劣化が少なく、風味に優れた起泡性水中油型乳化物を提供する事にある。   The object of the present invention is to provide a foamable oil-in-water emulsion for use in decorations such as cakes and sand, etc. The object is to provide an excellent foamable oil-in-water emulsion.

本発明者らは上記課題に対して、鋭意研究を行った結果、水中油型乳化物中に使用する油脂において、油脂中の構成脂肪酸がある特定範囲の油脂を使用した場合において、光照射下に晒せれても異味、異臭の品質の劣化が少ないという光劣化耐性を有することを見出した。また、特定の風味劣化防止剤と組み合わせることによって更に品質の劣化が抑えられることを見出し本発明を完成するに至った。
即ち本発明の第1は、蛍光灯照射下に陳列される食品用途であって、油脂、無脂乳固形分、水及び乳化剤を含む水中油型乳化物において、油脂として、油脂中の構成脂肪酸の脂肪酸組成が、酪酸、カプロン酸の合計量が2%以下であり、ラウリン酸、パルミチン酸の合計量が50%以上であり、オレイン酸、リノール酸、リノレン酸の合計量が40%以下であり、且つリノール酸、リノレン酸の合計量が4%以下である油脂であり、風味劣化防止剤由来のトコフェロール、ルチン、茶抽出物の3種を使用し、トコフェロールの使用量が0.001〜1重量%であり、ルチンの使用量が、0.0001〜0.3重量%であり、茶抽出物の使用量が、0.00005〜0.1重量%であり、乳化剤が構成脂肪酸に不飽和脂肪酸を含まないものである、蛍光灯照射下に生じる異味、異臭の低減された起泡性水中油型乳化物である。第2は、オーバーランが60〜300%である、第1記載の起泡性水中油型乳化物である。
As a result of diligent research on the above problems, the inventors of the present invention, in the oil and fat used in the oil-in-water emulsion, when using a specific range of oil and fat in the oil and fat, under light irradiation It has been found that it has a light deterioration resistance that there is little deterioration in the quality of off-flavors and off-flavors even when exposed to light. Moreover, it discovered that quality degradation could be further suppressed by combining with a specific flavor degradation inhibitor, and completed the present invention.
That is, the first of the present invention is a food application displayed under irradiation of a fluorescent lamp, and in an oil-in-water emulsion containing oil and fat, nonfat milk solids, water and an emulsifier, the constituent fatty acid in the oil and fat is used as the oil and fat. The total amount of butyric acid and caproic acid is 2% or less, the total amount of lauric acid and palmitic acid is 50% or more, and the total amount of oleic acid, linoleic acid, and linolenic acid is 40% or less. Yes, and the total amount of linoleic acid and linolenic acid is 4% or less, tocopherol derived from the flavor deterioration inhibitor, rutin, and tea extract are used, and the amount of tocopherol used is 0.001 1% by weight , the amount of rutin used is 0.0001 to 0.3% by weight , the amount of tea extract used is 0.00005 to 0.1% by weight , and the emulsifier is not included in the constituent fatty acids. Does not contain saturated fatty acids Off-taste produced under fluorescent lamp illumination is reduced foamable oil-in-water emulsion of odor. The second is the foamable oil-in-water emulsion according to the first, wherein the overrun is 60 to 300% .

ケーキ等のデコレーションやサンド等に用いられる起泡性水中油型乳化物において、蛍光灯等の光照射下に晒せれても異味、異臭の品質の劣化が少なく、風味に優れた起泡性水中油型乳化物を提供する事が可能になった。   In foaming oil-in-water emulsions used for decorations such as cakes and sand, foaming water with excellent flavor and little deterioration in quality of off-flavors and off-flavors even when exposed to light such as fluorescent lights It has become possible to provide oil-type emulsions.

本発明の起泡性水中油型乳化物は、油脂、無脂乳固形分、水及び乳化剤を含む水中油型乳化物であって、流動状態の乳化物であり、”ホイップ用クリーム”と呼ばれたりもする。これを泡立器具、または専用のミキサーを用いて空気を抱き込ませるように攪拌したとき、俗に”ホイップドクリーム”または”ホイップクリーム”と称される、起泡状態を呈するものとなる。   The foamable oil-in-water emulsion of the present invention is an oil-in-water emulsion containing fats and oils, non-fat milk solids, water and an emulsifier, and is a fluid emulsion, and is called “whipping cream” There are also. When this is stirred using a foaming device or a dedicated mixer so that air is entrapped, a foamed state commonly referred to as “whipped cream” or “whipped cream” is exhibited.

本発明の油脂としては、油脂中の構成脂肪酸の脂肪酸組成が、酪酸、カプロン酸の合計量が2%以下であり、ラウリン酸、パルミチン酸の合計量が40%以上であり、オレイン酸、リノール酸、リノレン酸の合計量が50%以下であり、且つリノール酸、リノレン酸の合計量が5%以下である油脂であれば何れの油脂も選択使用することが出来る。好ましくは、油脂中の構成脂肪酸の脂肪酸組成が、酪酸、カプロン酸の合計量が2%以下であり、ラウリン酸、パルミチン酸の合計量が50%以上であり、オレイン酸、リノール酸、リノレン酸の合計量が40%以下であり、且つリノール酸、リノレン酸の合計量が4%以下である油脂が好ましい。具体的には、動植物性油脂及びそれらの硬化油脂の単独又は2種以上の混合物或いはこれらのものに種々の化学処理又は物理処理を施したものが例示できる。かかる油脂としては、大豆油、綿実油、コーン油、サフラワー油、オリーブ油、パーム油、菜種油、米ぬか油、ゴマ油、カポック油、ヤシ油、パーム核油、乳脂、ラード、魚油、鯨油等の各種の動植物油脂及びそれらの硬化油、分別油、エステル交換油等の加工油脂(融点15〜40℃程度のもの)が例示できる。
油脂分は10〜48重量%、好ましくは13〜45重量%、更に15〜42重量%が好ましい。油脂分が上限を超える場合は起泡性水中油型乳化物がボテ(可塑化状態)易くなり、下限未満では起泡性、保形性が悪化する傾向になる。
As the fats and oils of the present invention, the fatty acid composition of the constituent fatty acids in the fats and oils is that the total amount of butyric acid and caproic acid is 2% or less, the total amount of lauric acid and palmitic acid is 40% or more, oleic acid, linole Any oil and fat can be selected and used as long as the total amount of acid and linolenic acid is 50% or less and the total amount of linoleic acid and linolenic acid is 5% or less. Preferably, the fatty acid composition of the constituent fatty acids in the fat is such that the total amount of butyric acid and caproic acid is 2% or less, the total amount of lauric acid and palmitic acid is 50% or more, oleic acid, linoleic acid, linolenic acid Is preferably 40% or less and the total amount of linoleic acid and linolenic acid is 4% or less. Specific examples include animal and vegetable fats and oils and their hardened fats and oils, or a mixture of two or more thereof, or those obtained by subjecting these to various chemical treatments or physical treatments. Such fats and oils include soybean oil, cottonseed oil, corn oil, safflower oil, olive oil, palm oil, rapeseed oil, rice bran oil, sesame oil, kapok oil, coconut oil, palm kernel oil, milk fat, lard, fish oil, whale oil, etc. Examples include animal and vegetable oils and fats, processed oils and fats such as hydrogenated oils, fractionated oils, and transesterified oils (melting points of about 15 to 40 ° C.).
The fat and oil content is 10 to 48% by weight, preferably 13 to 45% by weight, and more preferably 15 to 42% by weight. When the oil and fat content exceeds the upper limit, the foamable oil-in-water emulsion tends to be stabbed (plasticized state), and when it is less than the lower limit, the foamability and shape retention tend to deteriorate.

本発明の無脂乳固形分としては、牛乳の全固形分から乳脂肪分を差引いた成分をいい、生乳、牛乳、脱脂乳、生クリーム、濃縮乳、無糖練乳、加糖練乳、全脂粉乳、脱脂粉乳、バターミルクパウダー、ホエー蛋白、カゼイン、カゼインナトリウム等の乳由来の原料が例示でき、無脂乳固形分が1〜14重量%が好ましく、さらに好ましくは2〜12重量%、最も好ましくは4〜10重量%である。無脂乳固形分が1重量%より低い場合は、水中油型乳化物の乳化安定性が悪くなり、乳味感も少なくなって風味が悪くなる。14重量%を超える場合は、水中油型乳化物の粘度が高くなり、コストも高くなり、量に見合った効果が得難くなる。   The non-fat milk solid content of the present invention refers to a component obtained by subtracting the milk fat content from the total solid content of milk, raw milk, cow milk, skim milk, fresh cream, concentrated milk, sugar-free condensed milk, sweetened condensed milk, whole milk powder, Non-fat dry milk, buttermilk powder, whey protein, casein, sodium casein and other raw materials can be exemplified, and the non-fat milk solid content is preferably 1 to 14% by weight, more preferably 2 to 12% by weight, most preferably 4 to 10% by weight. When the non-fat milk solid content is lower than 1% by weight, the emulsification stability of the oil-in-water emulsion is deteriorated, the milky feeling is reduced, and the flavor is deteriorated. When it exceeds 14% by weight, the viscosity of the oil-in-water emulsion is increased, the cost is increased, and it is difficult to obtain an effect commensurate with the amount.

本発明の乳化剤としては、起泡性水中油型乳化物を調製する際に通常使用する乳化剤を適宜選択使用することが出来る。例えば、レシチン、モノグリセライド、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ショ糖脂肪酸エステル等の合成乳化剤が例示でき、これらの乳化剤の中から1種又は2種以上を選択して適宜使用することができる。これらの乳化剤のうち、光照射下に晒せれても異味、異臭の品質の劣化が少ないという点で、乳化剤中の構成脂肪酸に不飽和脂肪酸を含まない乳化剤を使用するのが好ましい。   As the emulsifier of the present invention, an emulsifier usually used in preparing a foamable oil-in-water emulsion can be appropriately selected and used. For example, synthetic emulsifiers such as lecithin, monoglyceride, sorbitan fatty acid ester, propylene glycol fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, sucrose fatty acid ester can be exemplified, and one or two of these emulsifiers The above can be selected and used appropriately. Among these emulsifiers, it is preferable to use an emulsifier that does not contain an unsaturated fatty acid as a constituent fatty acid in the emulsifier, in that there is little deterioration in the quality of off-flavors and odors even when exposed to light.

本発明の起泡性水中油型乳化物は、トコフェロール、ルチン、茶抽出物から選ばれる少なくとも1種以上の風味劣化防止剤を含むことが好ましい。
本発明のトコフェロールとしては、それ自体既知のものであり、市販品として入手可能である。これらは天然の植物から抽出した精製品でも未精製品でもよく、合成品でも良い。また、δ−トコフェロール等の単品でもα、β、γ、δ−トコフェロール等の混合物でも良い。また、油脂、デキストリン等により希釈された製剤でも良い。市販品としては理研ビタミン株式会社製の(商品名:理研オイルスーパー80、トコフェロール64%含有)などが例示できる。
本発明の起泡性水中油型乳化物に用いるトコフェロールの使用量については0.001〜1%、好ましくは0.005〜0.7%、最も好ましくは0.01〜0.5%の範囲で使用するのが望ましい。
トコフェロールの使用量が下限未満の場合は、期待される効果は得られにくく、上限を超える場合には起泡性水中油型乳化物の風味、色調が悪くなる。
The foamable oil-in-water emulsion of the present invention preferably contains at least one flavor deterioration inhibitor selected from tocopherol, rutin, and tea extract.
The tocopherol of the present invention is known per se and is available as a commercial product. These may be refined products extracted from natural plants, immature products, or synthetic products. Further, it may be a single product such as δ-tocopherol or a mixture of α, β, γ, δ-tocopherol and the like. Moreover, the formulation diluted with fats and oils, dextrin, etc. may be sufficient. Examples of commercially available products include those manufactured by Riken Vitamin Co., Ltd. (trade name: Riken Oil Super 80, containing 64% tocopherol).
About the usage-amount of the tocopherol used for the foamable oil-in-water emulsion of this invention 0.001-1%, Preferably it is 0.005-0.7%, Most preferably, it is the range of 0.01-0.5%. It is desirable to use in.
When the amount of tocopherol used is less than the lower limit, the expected effect is difficult to obtain, and when the amount exceeds the upper limit, the flavor and color tone of the foamable oil-in-water emulsion deteriorates.

本発明のルチンとしては、それ自体既知の物であり、市販品として入手可能である。ルチンは元来、水にはほとんど溶けないため、その利用が遅れていた。本発明では酵素処理されたことにより、水溶性を格段に高められたものが適しており、東洋精糖株式会社製の(商品名:αGルチンPS、ルチン82%含有)が例示できる。
本発明の起泡性水中油型乳化物に用いるルチンの使用量については、0.0001〜0.3%、好ましくは0.001〜0.1%、最も好ましくは0.003〜0.05%の範囲で使用するのが好ましい。ルチンの使用量が下限未満の場合は、期待される効果は得られにくく、上限を超える場合には起泡性水中油型乳化物の風味が悪くなる。
The rutin of the present invention is known per se and is available as a commercial product. Rutin was originally insoluble in water, so its use was delayed. In the present invention, those that have been markedly improved in water solubility by being treated with an enzyme are suitable, and examples include (trade name: αG rutin PS, containing 82% rutin) manufactured by Toyo Seika Co., Ltd.
The amount of rutin used in the foamable oil-in-water emulsion of the present invention is 0.0001 to 0.3%, preferably 0.001 to 0.1%, most preferably 0.003 to 0.05. It is preferable to use in the range of%. When the amount of rutin used is less than the lower limit, the expected effect is difficult to obtain, and when it exceeds the upper limit, the flavor of the foamable oil-in-water emulsion becomes poor.

本発明の茶抽出物としては、緑茶、ウーロン茶、紅茶等の茶葉またはその加工品の抽出物であり、新しいものを熱エタノールまたは熱水で抽出したものが好ましい。茶抽出物としては市販茶抽出物が使用でき、太陽化学株式会社製の「サンカトール」などがあげられる。本発明では太陽化学株式会社製の(商品名:スーパーエマルジョンTSM−09、茶抽出物0.15%含有、トコフェロール8%含有)が例示できる。
本発明の起泡性水中油型乳化物に用いる茶抽出物の使用量については、0.00005〜0.1%、好ましくは0.00005〜0.05%、最も好ましくは0.00008〜0.03%の範囲で使用するのが好ましい。茶抽出物の使用量が下限未満の場合は、期待される効果は得られにくく、上限を超える場合には起泡性水中油型乳化物の風味が悪くなる。
The tea extract of the present invention is an extract of tea leaves such as green tea, oolong tea, black tea or the like, or a processed product thereof, and a fresh one extracted with hot ethanol or hot water is preferable. As the tea extract, a commercially available tea extract can be used, such as “Sankator” manufactured by Taiyo Kagaku Co., Ltd. Examples of the present invention include (trade name: Super Emulsion TSM-09, containing 0.15% tea extract, containing 8% tocopherol) manufactured by Taiyo Kagaku Co., Ltd.
About the usage-amount of the tea extract used for the foamable oil-in-water emulsion of this invention, it is 0.00005-0.1%, Preferably it is 0.00005-0.05%, Most preferably, it is 0.00008-0. It is preferably used in the range of 0.03%. When the amount of the tea extract used is less than the lower limit, the expected effect is difficult to obtain, and when it exceeds the upper limit, the flavor of the foamable oil-in-water emulsion becomes worse.

本発明の起泡性水中油型乳化物に使用する上記風味劣化防止剤は、トコフェロール、ルチン、茶抽出物を有効成分として含有する事により所望の効果が得られるが、必要に応じて公知の抗酸化剤(L−アスコルビン酸等)、香味劣化防止剤(クロロゲン酸、リンゴポリフェノール、ヒマワリ抽出物、ヤマモモ抽出物等)、金属封鎖剤(グルコン酸、コウジ酸、フィチン酸、ポリリン酸、キチン、キトサン等)等を使用することもできる。   The flavor deterioration preventing agent used in the foamable oil-in-water emulsion of the present invention can provide a desired effect by containing tocopherol, rutin, and tea extract as active ingredients, but is known as necessary. Antioxidants (L-ascorbic acid, etc.), flavor deterioration inhibitors (chlorogenic acid, apple polyphenol, sunflower extract, bayberry extract, etc.), sequestering agents (gluconic acid, kojic acid, phytic acid, polyphosphoric acid, chitin, Chitosan etc.) can also be used.

本発明の起泡性水中油型乳化物に使用する上記風味劣化防止剤の添加時期は、特に限定されないが、起泡性水中油型乳化物が光劣化を受ける前に予め添加しておくことが必要であって、起泡性水中油型乳化物を調製する際に添加してもよいし、起泡性水中油型乳化物を調製した後、ホイップする際に添加してもよい。好ましくは、起泡性水中油型乳化物を調製する際に各種原料とともに配合することが望ましい。   The timing of adding the flavor deterioration inhibitor used in the foamable oil-in-water emulsion of the present invention is not particularly limited, but should be added before the foamable oil-in-water emulsion undergoes photodegradation. May be added when preparing the foamable oil-in-water emulsion, or may be added when whipping after preparing the foamable oil-in-water emulsion. Preferably, it is desirable to blend with various raw materials when preparing a foamable oil-in-water emulsion.

本発明の起泡性水中油型乳化物は、オーバーランが60〜300%、好ましくは60〜250%、更に好ましくは60〜200%、最も好ましくは60〜150%であることが好ましい。オーバーランが高すぎる場合には食感が軽すぎたり、風味の乏しいものになる傾向がある。オーバーランが低すぎる場合には食感が重たくなりすぎ、良好な風味、口溶け感が得難くなる。   The foamable oil-in-water emulsion of the present invention preferably has an overrun of 60 to 300%, preferably 60 to 250%, more preferably 60 to 200%, and most preferably 60 to 150%. If the overrun is too high, the texture tends to be too light or the flavor tends to be poor. When the overrun is too low, the texture becomes too heavy, and it becomes difficult to obtain a good flavor and a feeling of melting in the mouth.

本発明の起泡性水中油型乳化物については、各種塩類を使用することが出来る。塩類としては、ヘキサメタリン酸塩、第2リン酸塩、クエン酸ナトリウム、ポリリン酸塩、重曹等を単独又は2種以上混合使用することが好ましい。その他所望により糖類、安定剤、香料、着色料、保存料等を使用することが出来る。   Various salts can be used for the foamable oil-in-water emulsion of the present invention. As the salts, it is preferable to use hexametaphosphate, diphosphate, sodium citrate, polyphosphate, sodium bicarbonate and the like alone or in combination. In addition, saccharides, stabilizers, fragrances, coloring agents, preservatives and the like can be used as desired.

本発明の起泡性水中油型乳化物の製造法としては、油脂、無脂乳固形分、乳化剤及び水を主要原料とするこれらの原料を混合後、予備乳化、殺菌又は滅菌処理し均質化処理することにより得ることができる。起泡性水中油型乳化物の保存性の点で滅菌処理することが好ましい。具体的には、各種原料を60〜70℃で20分間予備乳化した後(乳化装置はホモミキサー)、必要により0〜250Kg/cm2の条件下にて均質化(乳化装置は均質機)する。次いで超高温瞬間殺菌処理(UHT)した後、再度、0〜300Kg/cm2の条件化にて均質化し、冷却後、約24時間エージングする。 As the method for producing the foamable oil-in-water emulsion of the present invention, after mixing these raw materials mainly containing fats and oils, non-fat milk solids, emulsifiers and water, pre-emulsification, sterilization or sterilization treatment and homogenization It can be obtained by processing. It is preferable to sterilize the foamable oil-in-water emulsion from the viewpoint of storage stability. Specifically, after preliminarily emulsifying various raw materials at 60 to 70 ° C. for 20 minutes (the emulsifying device is a homomixer), the material is homogenized under the condition of 0 to 250 kg / cm 2 as necessary (the emulsifying device is a homogenizer). . Next, after ultra-high temperature instant sterilization (UHT), it is homogenized again under the condition of 0 to 300 kg / cm 2 , and after cooling, it is aged for about 24 hours.

超高温瞬間(UHT)殺菌には、間接加熱方式と直接加熱方式の2種類があり、間接加熱処理する装置としてはAPVプレート式UHT処理装置(APV株式会社製)、CP-UHT滅菌装置(クリマティー・パッケージ株式会社製)、ストルク・チューブラー型滅菌装置(ストルク株式会社製)、コンサーム掻取式UHT滅菌装置(テトラパック・アルファラベル株式会社製)等が例示できるが、特にこれらにこだわるものではない。また、直接加熱式滅菌装置としては、超高温滅菌装置(岩井機械工業(株)製)、ユーペリゼーション滅菌装置(テトラパック・アルファラバル株式会社製)、VTIS滅菌装置(テトラパック・アルファラバル株式会社製)、ラギアーUHT滅菌装置(ラギアー株式会社製)、パラリゼーター(パッシュ・アンド・シルケーボーグ株式会社製)等のUHT滅菌装置が例示でき、これらの何れの装置を使用してもよい。   There are two types of ultra-high temperature instant (UHT) sterilization: indirect heating method and direct heating method. As an indirect heat treatment device, APV plate type UHT treatment device (manufactured by APV Co., Ltd.), CP-UHT sterilization device (clima) Tea package Co., Ltd.), Torque / tubular sterilizer (Stork Co., Ltd.), Concer scraping type UHT sterilizer (Tetra Pak Alpha Label Co., Ltd.), etc. is not. Direct heating sterilizers include ultra-high temperature sterilizers (Iwai Kikai Kogyo Co., Ltd.), operation sterilizers (Tetra Pak Alfa Laval Co., Ltd.), and VTIS sterilizers (Tetra Pak Alfa Laval shares). UHT sterilizers such as Ragia UHT sterilizer (manufactured by company), Ragiazer (manufactured by Ragia Co., Ltd.), Paralyzer (manufactured by Pash & Silkeborg Co., Ltd.), and any of these apparatuses may be used.

以下に本発明の実施例を示し本発明をより詳細に説明するが、本発明の精神は以下の実施例に限定されるものではない。なお、例中、%及び部は、いずれも重量基準を意味する。
特に、添加剤の添加順序或いは油相を水相へ又は水相を油相へ加える等の乳化順序が以下の例示によって限定されるものではないことは言うまでもない。また、結果については以下の方法で評価した。
EXAMPLES The present invention will be described in more detail with reference to the following examples, but the spirit of the present invention is not limited to the following examples. In the examples, “%” and “part” mean weight basis.
In particular, it goes without saying that the order of addition of the additives or the emulsification order of adding the oil phase to the water phase or the water phase to the oil phase is not limited by the following examples. The results were evaluated by the following method.

水中油型乳化物を起泡させた場合の評価方法
(1)ホイップタイム:水中油型乳化物1kgをホバードミキサー(HOBART CORPORATION製 MODEL N−5)3速(300rpm)にてホイップし、最適起泡状態に達するまでの時間。
(2)オーバーラン:[(一定容積の水中油型乳化物重量)ー(一定容積の起泡後の起泡物重量)]÷(一定容積の起泡後の起泡物重量)×100
(3)保形性:造花した起泡物を15℃で24時間保存した場合の美しさを調べる。優れている順に、「良好」、「可」、「不可」の三段階にて評価をつける。
(4)風味:専門パネラー20名により官能評価を行う。ホイップ直後の風味評価と光照射後の風味評価の2種類を行った。光照射試験は、蛍光灯照射(照度4000Lx)、温度5℃にて72時間保存後評価した。風味評価は、優れている順に「5」、「4」、「3」、「2」、「1」の五段階にて評価を行い、平均化した評価を結果とした。
Evaluation method when foaming oil-in-water emulsion (1) Whip time: 1 kg of oil-in-water emulsion is whipped at 3rd speed (300 rpm) by Hovard mixer (MODEL N-5 manufactured by HOBART CORPORATION). Time to reach foaming condition.
(2) Overrun: [(weight of oil-in-water emulsion of a certain volume) − (weight of foam after a certain volume of foaming)] ÷ (weight of foam after a certain volume of foaming) × 100
(3) Shape retention: The beauty when the artificial foam is stored at 15 ° C. for 24 hours is examined. In order of superiority, give a rating in three stages: “Good”, “Yes”, and “No”.
(4) Flavor: Sensory evaluation is performed by 20 professional panelists. Two kinds of flavor evaluation immediately after whipping and flavor evaluation after light irradiation were performed. The light irradiation test was evaluated after storage for 72 hours at a fluorescent lamp irradiation (illuminance of 4000 Lx) and a temperature of 5 ° C. The flavor evaluation was evaluated in five stages of “5”, “4”, “3”, “2”, “1” in order of superiority, and the averaged evaluation was the result.

実験例1
起泡性水中油型乳化物の調製に使用した油脂、パーム中融点部(融点34℃)、硬化パーム核油(融点34℃)、硬化ヤシ油(融点32℃)、乳脂、硬化大豆油(融点31℃)、硬化菜種油(融点35℃)について油脂中の構成脂肪酸の組成を常法に従いこれらの油脂をメチルエステル化してガスクロマトグラム法にて分析を行い、分析チャートの面積割合より組成とその割合を求めた。
求めた脂肪酸のうち、酪酸+カプロン酸、ラウリン酸+パルミチン酸、オレイン酸+リノール酸+リノレン酸、リノール酸+リノレン酸の割合を表1に纏めた。
Experimental example 1
Fats and oils used in the preparation of foamable oil-in-water emulsions, palm middle melting point (melting point 34 ° C), hardened palm kernel oil (melting point 34 ° C), hardened coconut oil (melting point 32 ° C), milk fat, hardened soybean oil ( (Melting point 31 ° C.), hardened rapeseed oil (melting point 35 ° C.), the composition of the constituent fatty acids in the fats and oils is methyl esterified according to a conventional method and analyzed by gas chromatogram method. The percentage was determined.
Among the obtained fatty acids, the ratios of butyric acid + caproic acid, lauric acid + palmitic acid, oleic acid + linoleic acid + linolenic acid, and linoleic acid + linolenic acid are summarized in Table 1.

Figure 0005283302
Figure 0005283302

実施例1
パーム中融点部(融点34℃)25.0部、硬化パーム核油5.0部を融解混合し油相とする。これとは別に水64.7部に脱脂粉乳5.0部、モノミリスチン酸ペンタグリセリン0.2部、メタリン酸ナトリウム0.1部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、起泡性水中油型乳化物を得た。この乳化物を上記のホイップ方法に従って評価した。結果を表2に纏めた。
Example 1
25.0 parts of the middle melting point of palm (melting point 34 ° C.) and 5.0 parts of hardened palm kernel oil are melt-mixed to obtain an oil phase. Separately, 5.0 parts of skim milk powder, 0.2 parts of pentaglyceryl monomyristate and 0.1 part of sodium metaphosphate are dissolved in 64.7 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain a foamable oil-in-water emulsion. This emulsion was evaluated according to the whipping method described above. The results are summarized in Table 2.

実施例2
パーム中融点部(融点34℃)25.0部、硬化パーム核油5.0部にレシチン0.3部を添加混合溶解し油相とする。これとは別に水64.4部に脱脂粉乳5.0部、ショ糖脂肪酸エステル0.2部、メタリン酸ナトリウム0.1部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、起泡性水中油型乳化物を得た。この乳化物を上記のホイップ方法に従って評価した。結果を表2に纏めた。
Example 2
An oil phase is obtained by adding, mixing and dissolving 0.3 part of lecithin to 25.0 parts of the middle melting point (melting point 34 ° C.) of palm and 5.0 parts of hardened palm kernel oil. Separately, 5.0 parts of skim milk powder, 0.2 part of sucrose fatty acid ester, and 0.1 part of sodium metaphosphate are dissolved in 64.4 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain a foamable oil-in-water emulsion. This emulsion was evaluated according to the whipping method described above. The results are summarized in Table 2.

実施例3
パーム中融点部(融点34℃)20.0部、硬化パーム核油(融点34℃)20.0部を融解混合し油相とする。これとは別に水54.7部に脱脂粉乳5.0部、モノミリスチン酸ペンタグリセリン0.2部、メタリン酸ナトリウム0.1部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、起泡性水中油型乳化物を得た。この乳化物を上記のホイップ方法に従って評価した。結果を表2に纏めた。
Example 3
Melting and mixing 20.0 parts of the middle melting point of palm (melting point 34 ° C.) and 20.0 parts of hardened palm kernel oil (melting point 34 ° C.) to obtain an oil phase. Separately from this, 5.0 parts of skim milk powder, 0.2 parts of pentaglyceryl monomyristate and 0.1 part of sodium metaphosphate are dissolved in 54.7 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain a foamable oil-in-water emulsion. This emulsion was evaluated according to the whipping method described above. The results are summarized in Table 2.

実施例4
硬化パーム核油(融点34℃)40.0部にレシチン0.3部を添加混合溶解し油相とする。これとは別に水54.4部に脱脂粉乳5.0部、ショ糖脂肪酸エステル0.2部、メタリン酸ナトリウム0.1部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、起泡性水中油型乳化物を得た。この乳化物を上記のホイップ方法に従って評価した。結果を表2に纏めた。
Example 4
Add 0.3 parts of lecithin to 40.0 parts of hardened palm kernel oil (melting point: 34 ° C.) and dissolve to obtain an oil phase. Separately, 5.0 parts of skim milk powder, 0.2 part of sucrose fatty acid ester and 0.1 part of sodium metaphosphate are dissolved in 54.4 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain a foamable oil-in-water emulsion. This emulsion was evaluated according to the whipping method described above. The results are summarized in Table 2.

Figure 0005283302
Figure 0005283302

実施例5
硬化ヤシ油(融点32℃)40.0部にレシチン0.3部を添加混合溶解し油相とする。これとは別に水54.4部に脱脂粉乳5.0部、ショ糖脂肪酸エステル0.2部、メタリン酸ナトリウム0.1部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、起泡性水中油型乳化物を得た。この乳化物を上記のホイップ方法に従って評価した。結果を表3に纏めた。
Example 5
Add 0.3 parts of lecithin to 40.0 parts of hardened coconut oil (melting point: 32 ° C.) and dissolve to obtain an oil phase. Separately, 5.0 parts of skim milk powder, 0.2 part of sucrose fatty acid ester and 0.1 part of sodium metaphosphate are dissolved in 54.4 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain a foamable oil-in-water emulsion. This emulsion was evaluated according to the whipping method described above. The results are summarized in Table 3.

比較例1
起泡性水中油型乳化物によく使用されている硬化大豆油(融点31℃)で以下の方法において起泡性水中油型乳化物を調製した。
硬化大豆油(融点31℃)40.0部にレシチン0.3部を添加混合溶解し油相とする。これとは別に水54.4部に脱脂粉乳5.0部、ショ糖脂肪酸エステル0.2部、メタリン酸ナトリウム0.1部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、起泡性水中油型乳化物を得た。この乳化物を上記のホイップ方法に従って評価した。結果を表3に纏めた。
Comparative Example 1
A foamable oil-in-water emulsion was prepared in the following manner using hydrogenated soybean oil (melting point 31 ° C.) often used for foamable oil-in-water emulsions.
Add 0.3 parts of lecithin to 40.0 parts of hardened soybean oil (melting point 31 ° C.), mix and dissolve to obtain an oil phase. Separately, 5.0 parts of skim milk powder, 0.2 part of sucrose fatty acid ester and 0.1 part of sodium metaphosphate are dissolved in 54.4 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain a foamable oil-in-water emulsion. This emulsion was evaluated according to the whipping method described above. The results are summarized in Table 3.

比較例2
硬化大豆油(融点31℃)20.0部、硬化パーム核油(融点34℃)20.0部にレシチン0.3部を添加混合溶解し油相とする。これとは別に水54.4部に脱脂粉乳5.0部、ショ糖脂肪酸エステル0.2部、メタリン酸ナトリウム0.1部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、起泡性水中油型乳化物を得た。この乳化物を上記のホイップ方法に従って評価した。結果を表3に纏めた。
Comparative Example 2
Add 0.3 parts of lecithin to 20.0 parts of hardened soybean oil (melting point: 31 ° C.) and 20.0 parts of hardened palm kernel oil (melting point: 34 ° C.) to make an oil phase. Separately, 5.0 parts of skim milk powder, 0.2 part of sucrose fatty acid ester and 0.1 part of sodium metaphosphate are dissolved in 54.4 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain a foamable oil-in-water emulsion. This emulsion was evaluated according to the whipping method described above. The results are summarized in Table 3.

比較例3
硬化菜種油(融点35℃)20.0部、硬化パーム核油(融点34℃)20.0部にレシチン0.3部を添加混合溶解し油相とする。これとは別に水54.4部に脱脂粉乳5.0部、ショ糖脂肪酸エステル0.2部、メタリン酸ナトリウム0.1部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、起泡性水中油型乳化物を得た。この乳化物を上記のホイップ方法に従って評価した。結果を表3に纏めた。
Comparative Example 3
Add 0.3 parts of lecithin to 20.0 parts of hardened rapeseed oil (melting point 35 ° C.) and 20.0 parts of hardened palm kernel oil (melting point 34 ° C.) to dissolve and make an oil phase. Separately, 5.0 parts of skim milk powder, 0.2 part of sucrose fatty acid ester and 0.1 part of sodium metaphosphate are dissolved in 54.4 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain a foamable oil-in-water emulsion. This emulsion was evaluated according to the whipping method described above. The results are summarized in Table 3.

Figure 0005283302
Figure 0005283302

比較例4
市販の生クリーム(よつ葉乳業株式会社製、油脂分47%、無脂乳固形分5%)を実施例1と同様な方法でホイップし評価した。結果を表4に纏めた。
別途、この生クリームをチャーニングして乳脂肪を取り出し実験例1で示した方法に準じて、乳脂中の構成脂肪酸を測定し、結果は先の表1に示した。
Comparative Example 4
A commercially available fresh cream (manufactured by Yotsuba Milk Industry Co., Ltd., oil / fat content 47%, non-fat milk solid content 5%) was whipped and evaluated in the same manner as in Example 1. The results are summarized in Table 4.
Separately, this fresh cream was charred to extract milk fat, and the constituent fatty acids in the milk fat were measured according to the method shown in Experimental Example 1, and the results are shown in Table 1 above.

比較例5
市販の生クリーム(よつ葉乳業株式会社製、油脂分47%、無脂乳固形分5%)85部、水14.2部、脱脂粉乳0.75部、ショ糖脂肪酸エステル0.05部を混合し、65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、起泡性水中油型乳化物を得た。この乳化物を上記のホイップ方法に従って評価した。結果を表4に纏めた。
Comparative Example 5
Mixing 85 parts of commercially available fresh cream (Yotsuha Milk Industry Co., Ltd., oil / fat content 47%, non-fat milk solid content 5%), water 14.2 parts, skim milk powder 0.75 parts, sucrose fatty acid ester 0.05 parts The mixture was stirred at 65 ° C. for 30 minutes with a homomixer and pre-emulsified, and then sterilized by direct heating at 145 ° C. for 4 seconds with an ultra-high temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.), and then 50 kg Homogenized at a homogenization pressure of / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain a foamable oil-in-water emulsion. This emulsion was evaluated according to the whipping method described above. The results are summarized in Table 4.

Figure 0005283302
Figure 0005283302

実施例6
パーム中融点部(融点34℃)25.0部、硬化パーム核油5.0部にトコフェーロール(商品名:理研オイルスーパー80、理研ビタミン株式会社製、;トコフェロール64%含有)0.1部を添加混合溶解し油相とする。これとは別に水64.7部に脱脂粉乳5.0部、モノミリスチン酸ペンタグリセリン0.2部、ルチン(商品名:αGルチンPS、東洋精糖株式会社製、;ルチン82%含有)0.01部、茶抽出物(商品名:スーパーエマルジョンTSM−09、太陽化学株式会社製、;茶抽出物0.15%含有、トコフェロール8%含有)0.1部、メタリン酸ナトリウム0.1部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、起泡性水中油型乳化物を得た。この乳化物を上記のホイップ方法に従って評価した。結果を表5に纏めた。
Example 6
Tocopherol (trade name: Riken Oil Super 80, manufactured by Riken Vitamin Co., Ltd .; containing 64% of tocopherol) 0.15 parts of palm middle melting point (melting point 34 ° C.) 25.0 parts, hardened palm kernel oil 5.0 parts Add and dissolve the part to make the oil phase. Separately from this, 64.7 parts of water, 5.0 parts of skim milk powder, 0.2 parts of pentaglyceryl monomyristate, rutin (trade name: αG rutin PS, manufactured by Toyo Seika Co., Ltd .; containing 82% rutin) 01 parts, tea extract (trade name: Super Emulsion TSM-09, Taiyo Kagaku Co., Ltd .; containing 0.15% tea extract and 8% tocopherol), 0.1 part sodium metaphosphate Dissolve to prepare the aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain a foamable oil-in-water emulsion. This emulsion was evaluated according to the whipping method described above. The results are summarized in Table 5.

実施例7
パーム中融点部(融点34℃)25.0部、硬化パーム核油5.0部にトコフェーロール(商品名:理研オイルスーパー80、理研ビタミン株式会社製、;トコフェロール64%含有)0.1部を添加混合溶解し油相とする。これとは別に水64.7部に脱脂粉乳5.0部、モノミリスチン酸ペンタグリセリン0.2部、メタリン酸ナトリウム0.1部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、起泡性水中油型乳化物を得た。この乳化物を上記のホイップ方法に従って評価した。結果を表5に纏めた。
Example 7
Tocopherol (trade name: Riken Oil Super 80, manufactured by Riken Vitamin Co., Ltd .; containing 64% of tocopherol) 0.15 parts of palm middle melting point (melting point 34 ° C.) 25.0 parts, hardened palm kernel oil 5.0 parts Add and dissolve the part to make the oil phase. Separately, 5.0 parts of skim milk powder, 0.2 parts of pentaglyceryl monomyristate and 0.1 part of sodium metaphosphate are dissolved in 64.7 parts of water to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain a foamable oil-in-water emulsion. This emulsion was evaluated according to the whipping method described above. The results are summarized in Table 5.

実施例8
パーム中融点部(融点34℃)25.0部、硬化パーム核油5.0部を融解混合し油相とする。これとは別に水64.7部に脱脂粉乳5.0部、モノミリスチン酸ペンタグリセリン0.2部、ルチン(商品名:αGルチンPS、東洋精糖株式会社製、;ルチン82%含有)0.01部、メタリン酸ナトリウム0.1部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、起泡性水中油型乳化物を得た。この乳化物を上記のホイップ方法に従って評価した。結果を表5に纏めた。
Example 8
25.0 parts of the middle melting point of palm (melting point 34 ° C.) and 5.0 parts of hardened palm kernel oil are melt-mixed to obtain an oil phase. Separately from this, 64.7 parts of water, 5.0 parts of skim milk powder, 0.2 parts of pentaglyceryl monomyristate, rutin (trade name: αG rutin PS, manufactured by Toyo Seika Co., Ltd .; containing 82% rutin) An aqueous phase is prepared by dissolving 01 parts and 0.1 parts of sodium metaphosphate. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain a foamable oil-in-water emulsion. This emulsion was evaluated according to the whipping method described above. The results are summarized in Table 5.

実施例9
パーム中融点部(融点34℃)25.0部、硬化パーム核油5.0部を融解混合し油相とする。これとは別に水64.7部に脱脂粉乳5.0部、モノミリスチン酸ペンタグリセリン0.2部、茶抽出物(商品名:スーパーエマルジョンTSM−09、太陽化学株式会社製、;茶抽出物0.15%含有、トコフェロール8%含有)0.1部、メタリン酸ナトリウム0.1部を溶解し水相を調製する。上記油相と水相を65℃で30分間ホモミキサーで攪拌し予備乳化した後、超高温滅菌装置(岩井機械工業(株)製)によって、145℃において4秒間の直接加熱方式による滅菌処理を行った後、50Kg/cm2 の均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、起泡性水中油型乳化物を得た。この乳化物を上記のホイップ方法に従って評価した。結果を表5に纏めた。
Example 9
25.0 parts of the middle melting point of palm (melting point 34 ° C.) and 5.0 parts of hardened palm kernel oil are melt-mixed to obtain an oil phase. Separately from this, 64.7 parts of water, 5.0 parts of skim milk powder, 0.2 parts of pentaglyceryl monomyristate, tea extract (trade name: Super Emulsion TSM-09, manufactured by Taiyo Chemical Co., Ltd .; tea extract 0.1 parts containing 0.15%, containing 8% tocopherol) 0.1 parts and 0.1 parts of sodium metaphosphate are dissolved to prepare an aqueous phase. The oil phase and aqueous phase are stirred with a homomixer at 65 ° C. for 30 minutes and pre-emulsified, and then sterilized by an ultrahigh temperature sterilizer (Iwai Kikai Kogyo Co., Ltd.) for 4 seconds at 145 ° C. After the run, it was homogenized at a homogenization pressure of 50 kg / cm 2 and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain a foamable oil-in-water emulsion. This emulsion was evaluated according to the whipping method described above. The results are summarized in Table 5.

実施例10
実施例1で得た起泡性水中油型乳化物をホイップする際に、乳化物100部に対して、トコフェーロール(商品名:理研オイルスーパー80、理研ビタミン株式会社製、;トコフェロール64%含有)0.1部、ルチン(商品名:αGルチンPS、東洋精糖株式会社製、;ルチン82%含有)0.01部、茶抽出物(商品名:スーパーエマルジョンTSM−09、太陽化学株式会社製、;茶抽出物0.15%含有、トコフェロール8%含有)0.1部を混合し上記のホイップ方法に従って評価した。結果を表5に纏めた。
Example 10
When whipping the foamable oil-in-water emulsion obtained in Example 1, tocopherol (trade name: Riken Oil Super 80, manufactured by Riken Vitamin Co., Ltd .; tocopherol 64% with respect to 100 parts of the emulsion; 0.1 part, rutin (trade name: αG rutin PS, manufactured by Toyo Seika Co., Ltd .; containing 82% rutin), tea extract (trade name: Super Emulsion TSM-09, Taiyo Kagaku Co., Ltd.) 0.1 parts (manufactured; containing 0.15% tea extract and 8% tocopherol) were mixed and evaluated according to the above whipping method. The results are summarized in Table 5.

Figure 0005283302
Figure 0005283302

本発明は、ケーキ等のデコレーションやサンド等に用いられる起泡性水中油型乳化物(ホイップクリーム)に関する。更に詳しくは蛍光灯等の光照射による異味、異臭の品質の劣化が少ない起泡性水中油型乳化物に関する。   The present invention relates to a foamable oil-in-water emulsion (whipped cream) used for decoration such as cake or sand. More specifically, the present invention relates to a foamable oil-in-water emulsion with little deterioration in quality of off-flavors and off-flavors caused by light irradiation such as fluorescent lamps.

Claims (2)

蛍光灯照射下に陳列される食品用途であって、油脂、無脂乳固形分、水及び乳化剤を含む水中油型乳化物において、油脂として、油脂中の構成脂肪酸の脂肪酸組成が、酪酸、カプロン酸の合計量が2%以下であり、ラウリン酸、パルミチン酸の合計量が50%以上であり、オレイン酸、リノール酸、リノレン酸の合計量が40%以下であり、且つリノール酸、リノレン酸の合計量が4%以下である油脂であり、風味劣化防止剤由来のトコフェロール、ルチン、茶抽出物の3種を使用し、トコフェロールの使用量が0.001〜1重量%であり、ルチンの使用量が、0.0001〜0.3重量%であり、茶抽出物の使用量が、0.00005〜0.1重量%であり、乳化剤が構成脂肪酸に不飽和脂肪酸を含まないものである、蛍光灯照射下に生じる異味、異臭の低減された起泡性水中油型乳化物。 For use in foods that are displayed under fluorescent light irradiation, and in oil-in-water emulsions containing fats and oils, non-fat milk solids, water and emulsifiers, the fatty acid composition of the constituent fatty acids in the fats is butyric acid, capron The total amount of acid is 2% or less, the total amount of lauric acid and palmitic acid is 50% or more, the total amount of oleic acid, linoleic acid and linolenic acid is 40% or less, and linoleic acid and linolenic acid Is a fat and oil having a total amount of 4% or less, using 3 types of tocopherol, rutin, and tea extract derived from the flavor deterioration inhibitor, and the amount of tocopherol used is 0.001 to 1% by weight , The amount used is 0.0001 to 0.3% by weight , the amount of tea extract used is 0.00005 to 0.1% by weight , and the emulsifier does not contain unsaturated fatty acids in the constituent fatty acids. Live under fluorescent light That off-taste, odor reduced foamable oil-in-water emulsion of. オーバーランが60〜300%である、請求項1記載の起泡性水中油型乳化物。The foamable oil-in-water emulsion according to claim 1, wherein the overrun is 60 to 300%.
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