JP4386933B2 - Organic waste treatment system - Google Patents

Organic waste treatment system Download PDF

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JP4386933B2
JP4386933B2 JP2007227582A JP2007227582A JP4386933B2 JP 4386933 B2 JP4386933 B2 JP 4386933B2 JP 2007227582 A JP2007227582 A JP 2007227582A JP 2007227582 A JP2007227582 A JP 2007227582A JP 4386933 B2 JP4386933 B2 JP 4386933B2
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pseudomonas
aspergillus
waste
organic waste
bacteria
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定恒 福田
善和 新川
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この発明は、食品加工工程で廃棄される魚介類残渣、鶏糞・豚糞、牛糞などの家畜の糞尿,野菜屑などの農産廃棄物、更には生ゴミなどの動植物性食品残渣といった有機系廃棄物の処理システムに関する。   The present invention relates to organic waste such as seafood residues discarded in food processing, livestock manure such as chicken dung, swine dung, and cow dung, agricultural waste such as vegetable waste, and animal and vegetable food residues such as raw garbage. Related to the processing system.

食品加工工程で廃棄される魚介類残渣、生ゴミなどの動植物性食品残渣、鶏糞・豚糞、牛糞などの家畜の糞尿,野菜屑などの農産廃棄物といった有機系廃棄物は、その殆どが、焼却や埋め立てにより処理されている。しかしながら、大量の魚介類残渣、生ゴミなどは、水分含有量が多く、これを焼却処理する為には大量の燃料を必要とし、極めて不経済であるばかりか、近年高まりつつあるCO2削減の要請にも反する。また、廃棄物量の増大に伴って、埋め立てによる処理も困難になってきており、より多くの廃棄物を回収し、再資源化する方法が講じられている。 Organic waste such as seafood residues, animal and vegetable food residues such as raw garbage, livestock manure such as chicken dung, pork dung, cow dung, and agricultural waste such as vegetable waste, which are discarded in the food processing process, It is processed by incineration or landfill. However, a large amount of seafood residue, raw garbage, etc. have a high water content, and a large amount of fuel is required to incinerate them, which is extremely uneconomical, and has recently been increasing in CO 2 reduction. Contrary to the request. In addition, with the increase in the amount of waste, landfill processing has become difficult, and a method for recovering and recycling more waste is being taken.

例えば、鶏糞・豚糞などの家畜の糞尿,家畜の死骸,枯草や腐敗作物などの農産廃棄物、更には生ゴミなどの動植物性食品残渣といった有機系廃棄物は再資源化することが可能である。   For example, it is possible to recycle organic waste such as animal manure such as chicken manure and pig manure, livestock carcasses, hay and septic crops, and animal and vegetable food residues such as raw garbage. is there.

しかしながら、有機系廃棄物を堆積醗酵させて堆肥として処理する方法では、廃棄物を完全に醗酵させるのに1〜2年程度かかるため、大量の廃棄物を処理するのは困難である。従って、従来の醗酵方法では短期間で効率よく処理して堆肥を得ることができず、大規模農業や、食品加工業などのように、大規模な工業的製造過程で生じる有機廃棄物を処理することは極めて困難であった。   However, in the method of depositing and fermenting organic waste and treating it as compost, it takes about 1 to 2 years to completely ferment the waste, so it is difficult to treat a large amount of waste. Therefore, conventional fermenting methods cannot efficiently process compost in a short period of time, and treat organic waste generated in large-scale industrial manufacturing processes, such as large-scale agriculture and food processing industries. It was extremely difficult to do.

さらに、魚介類残渣にはカドミウム、水銀、砒素等の重金属類が少なからず含まれており、これが醗酵後の堆肥に含まれていると、事実上農作物に使用することができなくなってしまう。また、生ゴミには買い物袋などのポリ袋やプラスチックのトレイなど難分解性の樹脂材料が混入されており、これらが分解されずに残存してしまうと、堆肥としての使用の際に大きな障害となる。   Furthermore, the seafood residue contains a lot of heavy metals such as cadmium, mercury, and arsenic, and if it is contained in the compost after fermentation, it cannot be practically used for agricultural products. In addition, garbage is mixed with persistent plastic materials such as plastic bags such as shopping bags and plastic trays. If these materials remain undecomposed, they will be a major obstacle when used as compost. It becomes.

なお、このような有機廃棄物の処理方法、処理装置としては、例えば特開2000−354852号公報(特許文献1)に記載の方法や、特開平11−290830号公報に記載の装置などが知られているが、何れのものも、使用する菌体の種類と組み合わせが不十分なため、特に魚介類の残渣である水産加工廃棄物や買い物袋などの樹脂材料の分解が困難であり、これらの廃棄物の迅速かつ確実な処理が極めて困難であった。また、廃棄物中に含まれている重金属成分を処理することが困難であるため、前記水産加工廃棄物などのように、重金属成分を多く含む廃棄物を処理すると、残留し、濃縮された重金属成分により、処理後の堆肥を農作物などに使用することができず。資源の有効利用を妨げ、新たな廃棄物を生じる結果となっていた。
特開2000−354852号公報 特開平11−290830号公報
As such organic waste treatment methods and treatment apparatuses, for example, the method described in Japanese Patent Application Laid-Open No. 2000-354852 (Patent Document 1) and the device described in Japanese Patent Application Laid-Open No. 11-290830 are known. However, since the types and combinations of the cells used are insufficient, it is difficult to disassemble resin materials such as seafood processing waste and shopping bags that are residues of seafood. It was extremely difficult to quickly and reliably dispose of the waste. In addition, since it is difficult to treat heavy metal components contained in waste, if waste containing a large amount of heavy metal components such as the above-mentioned fishery processing waste is treated, residual and concentrated heavy metal Due to the ingredients, the compost after treatment cannot be used for crops. As a result, the effective use of resources was hindered and new waste was generated.
JP 2000-354852 A JP 11-290830 A

この発明の目的は、食品加工工程で廃棄される魚介類残渣、鶏糞・豚糞、牛糞などの家畜の糞尿,野菜屑などの農産廃棄物、更には生ゴミなどの動植物性食品残渣といった有機系廃棄物を短時間で効率よく分解、処理することができ、さらには樹脂材料の処理も可能であり、重金属成分を含む破棄物も安全に処理でき、廃棄物の再資源化に有効な有機廃棄物の処理システムを提供することである。   The object of the present invention is to provide organic residues such as seafood residues discarded in food processing processes, livestock manure such as chicken manure / pig manure, cow manure, agricultural waste such as vegetable waste, and animal and vegetable food residues such as raw garbage. Waste can be efficiently decomposed and processed in a short time, and resin materials can be processed. Waste that contains heavy metal components can also be safely processed, and organic waste is effective for recycling waste. It is to provide a material processing system.

本発明は、上記目的を達成するため以下の構成とした。
(1) 菌体を固定するための母材と、少なくとも以下の14属に属する細菌属群を含み、投入された廃棄物が、前記細菌群の発酵作用により分解されて、廃棄物体積を24時間以内に1/100以下にまで減容する有機廃棄物処理システム。
細菌属群
1:streptomyces
2:sulfolobus
3:saccharopolyspola
4:白色腐朽性の担子菌
5:nocordia
6:pseudomonas
7:bacillus
8:cytophaga
9:spotocytophaga
10:cellulomonas
11:clostridum
12:aspergillus
13:penicillium
14:rhizopus
(2) 前記細菌群は
耐熱放線菌として
高温域から中温域の菌であってstreptomyces avermitillis、好酸性古細菌sulfolobus shibatae、およびsaccharopolyspola rectivirgulaから選択される菌を有し、
リグニン分解菌として
白色腐朽性の担子菌、放線菌streptomyces,nocordia、細菌類pseudomonas,bacillus、セルロース分解菌および繊維素分解菌として
滑走細菌cytophaga,spotocytophaga, pseudomonas, bacillus, cellulomonas, streptomyces, nocordiaおよび、嫌気性有芽胞桿菌類clostridumから選択される菌を有し、
脂肪分解菌として
リパーゼを生産分泌する菌である糸状菌aspergillus, penicillium,rhizopus から選択される菌を有し、
枯草菌として
アミラーゼやプロテアーゼの生産菌であるbacillus subtilis から選択される菌を有し、
乳酸菌として
Lactobacillus Plantarumから選択される菌を有する
上記(1)有機廃棄物の処理システム。
(3) 前記細菌群は、下記の種から選択される10種以上、好ましくは20種以上、特に全種を含有する上記(1)または(2)の有機廃棄物の処理システム。
Candida albicans TAX5476
Endomycopsis burtonii
Nocardia asteroides
Bacillus subtillis
Pseudomonas bacterium Rhizobium
Aspergillus niger TAX5061
Rhodospillum rubrum IFO3986
Rhodopseudomonas capsulata
Rhodobacter sphaeroides IFO12203
Chromatium vinosum
Streptomyces albus IFO3710
strepto verticillussp ATCC23654
Nocordia asteroides ATCC19247
Micromonospora chalcea IFO13503
Aspergillus oryzae IFO5770
Mucor hiemalis IFO8567
Saccharomyces cerevisial IFO1346
Candida utilis IFO0619
Lactobacillus Plantarum IFO3070
Pediococcus Halophilus IFO12172
Streptococcus Lactis IFO12007
Streptococcus Faecalis IFO3971
Arthrobacter sp.w 1〜6.
Pseudomonas aeruginosa
Corynebacterium sp.
Comamonas acidovorans
C.acidovorans. TB-35
Pseudomonas glumae
Pseudomonas gladioli
Pseudomonas avenae
Agrobacterium mochiganens
Pseudomonas solanacearum
Pseudomonas fluorescein
Aspergillus flavus
Aspergillus fumigatus
Aspergillus versicolor
Aspergillus penicillioides
(4) 処理前の有機廃棄物に含まれるカドミウム、水銀、砒素の1種または2種以上を含む水溶性の重金属成分の少なくとも一部を、非水溶性(不溶性)に変えて、無害化する上記(1)〜(3)のいずれかの有機廃棄物処理システム。
(5) 前記母材と撹拌装置を有するプール状の発酵槽とを有し、
廃棄物は、10mm以下に処理された後、発酵槽に投入されて発酵作用により分解して減容する上記(1)〜(4)のいずれかの有機廃棄物処理システム。
In order to achieve the above object, the present invention has the following configuration.
(1) It includes a base material for fixing cells and a bacterial genus group belonging to at least the following 14 genera, and the input waste is decomposed by the fermentation action of the bacterial group to reduce the waste volume to 24 Organic waste treatment system that reduces the volume to 1/100 or less within a time.
Bacterial genus group 1: streptomyces
2: sulfolobus
3: saccharopolyspola
4: White decaying basidiomycetes 5: nocordia
6: pseudomononas
7: bacillus
8: cytophaga
9: spocytocytophaga
10: cellulomonas
11: clostridum
12: aspergillus
13: penicillium
14: rhizopus
(2) The bacterial group is a heat-resistant actinomycete, a high-temperature to medium-temperature bacteria, having a bacterium selected from streptomyces avermitillis, acidophilic archaea sulfolobus shibatae, and saccharopolyspola rectivirgula,
White rot basidiomycetes, actinomycetes, streptomyces, nocordia, bacteria pseudomonas, bacillus, cellulose-degrading bacteria and fibrinolytic bacteria, gliding bacteria cytophaga, spotocytophaga, pseudomonas, bacillus, cellulomonas, streptomyces, nocordia Having a bacterium selected from the sex spore-forming fungus clostridum,
As a lipolytic bacterium, it has a bacterium selected from the filamentous fungi aspergillus, penicillium, rhizpus, which produces and secretes lipase,
As a Bacillus subtilis, there is a bacterium selected from bacillus subtilis, which is a bacterium producing amylase and protease,
As lactic acid bacteria
The above (1) organic waste treatment system having a bacterium selected from Lactobacillus Plantarum.
(3) The organic waste treatment system according to (1) or (2), wherein the bacterial group contains 10 or more, preferably 20 or more, particularly all species selected from the following species.
Candida albicans TAX5476
Endomycopsis burtonii
Nocardia asteroides
Bacillus subtillis
Pseudomonas bacterium Rhizobium
Aspergillus niger TAX5061
Rhodospillum rubrum IFO3986
Rhodopseudomonas capsulata
Rhodobacter sphaeroides IFO12203
Chromatium vinosum
Streptomyces albus IFO3710
strepto verticillussp ATCC23654
Nocordia asteroides ATCC19247
Micromonospora chalcea IFO13503
Aspergillus oryzae IFO5770
Mucor hiemalis IFO8567
Saccharomyces cerevisial IFO1346
Candida utilis IFO0619
Lactobacillus Plantarum IFO3070
Pediococcus Halophilus IFO12172
Streptococcus Lactis IFO12007
Streptococcus Faecalis IFO3971
Arthrobacter sp.w 1-6.
Pseudomonas aeruginosa
Corynebacterium sp.
Comamonas acidovorans
C.acidovorans.TB-35
Pseudomonas glumae
Pseudomonas gladioli
Pseudomonas avenae
Agrobacterium mochiganens
Pseudomonas solanacearum
Pseudomonas fluorescein
Aspergillus flavus
Aspergillus fumigatus
Aspergillus versicolor
Aspergillus penicillioides
(4) At least a part of the water-soluble heavy metal component containing one or more of cadmium, mercury, and arsenic contained in the organic waste before treatment is changed to water-insoluble (insoluble) and rendered harmless. The organic waste treatment system according to any one of (1) to (3) above.
(5) having a pool-shaped fermenter having the base material and a stirring device,
The organic waste treatment system according to any one of the above (1) to (4), wherein the waste is treated to 10 mm or less and then introduced into a fermentor and decomposed and reduced in volume by fermentation.

本発明によれば、食品加工工程で廃棄される魚介類残渣、鶏糞・豚糞、牛糞などの家畜の糞尿,野菜屑などの農産廃棄物、更には生ゴミなどの動植物性食品残渣といった有機系廃棄物を短時間で効率よく分解、処理することができ、廃棄物の再資源化に有効な有機廃棄物の処理システムを提供することができる。   According to the present invention, organic residues such as seafood residues discarded in food processing processes, livestock manure such as chicken manure / pig manure, cow manure, agricultural waste such as vegetable waste, and animal and vegetable food residues such as raw garbage It is possible to provide an organic waste processing system that can efficiently decompose and dispose of waste in a short time and is effective in recycling waste.

さらに、買い物袋やトレイ等の樹脂材料系不燃ゴミの処理も可能で、重金属成分を含む廃棄物も安全に処理可能な有機廃棄物の処理システムを提供することができる。   Further, it is possible to provide an organic waste treatment system that can treat non-combustible resin material such as shopping bags and trays and can safely treat waste containing heavy metal components.

本発明の有機廃棄物の処理システムは、菌体を固定するための母材と、少なくとも以下の14属に属する細菌属群を含み、投入された廃棄物が、前記細菌群の発酵作用により分解されて減容するものである。
細菌属群
1:streptomyces
2:sulfolobus
3:saccharopolyspola
4:白色腐朽性の担子菌
5:nocordia
6:pseudomonas
7:bacillus
8:cytophaga
9:spotocytophaga
10:cellulomonas
11:clostridum
12:aspergillus
13:penicillium
14:rhizopus
これら母材と菌体とは混合されて処理槽内に収納される。そして、この処理槽内を適度な温度と湿度に保持しつつ、有機廃棄物を投入し攪拌して処理する。
The organic waste treatment system of the present invention includes a base material for fixing cells and a bacterial genus group belonging to at least the following 14 genera, and the input waste is decomposed by the fermentation action of the bacterial group. The volume is reduced.
Bacterial genus group 1: streptomyces
2: sulfolobus
3: saccharopolyspola
4: White decaying basidiomycetes 5: nocordia
6: pseudomononas
7: bacillus
8: cytophaga
9: spocytocytophaga
10: cellulomonas
11: clostridum
12: aspergillus
13: penicillium
14: rhizopus
These base materials and microbial cells are mixed and stored in the treatment tank. Then, while maintaining the inside of the treatment tank at an appropriate temperature and humidity, the organic waste is introduced and stirred for treatment.

本発明で、菌体の固定、坦持に用いられる母材としては、その表面や内部構造中に下記に記述する菌類を固定、担持することのできるものであれば特に限定されるものではない。具体的には、菌類を固定しやすい多孔物質や、有機系材料、例えばバーク、おがくず、木炭粉、コーヒー粕、もみ殻、米糠から得られるぼかし等を好適に用いることができ、これらの1種又は2種以上を混合して用いることができる。   In the present invention, the base material used for fixing and carrying the bacterial cells is not particularly limited as long as it can fix and carry the fungi described below on the surface or internal structure thereof. . Specifically, porous materials that can easily fix fungi, and organic materials such as bark, sawdust, charcoal powder, coffee cake, rice husk, and rice bran can be suitably used. Or 2 or more types can be mixed and used.

本発明の処理システムでは、母材に固定、担持される細菌として、以下の細菌を含有することが好ましい。   In the treatment system of the present invention, it is preferable to contain the following bacteria as the bacteria fixed and supported on the base material.

耐熱放線菌
高温域から中温域の菌が好ましい。
streptomyces avermitillis
好酸性古細菌sulfolobus shibatae
saccharopolyspola rectivirgula
Heat-resistant actinomycetes High-temperature to medium-temperature bacteria are preferred.
streptomyces avermitillis
Acidophilic archaeon sulfolobus shibatae
saccharopolyspola rectivirgula

リグニン分解菌
白色腐朽性の担子菌、放線菌streptomyces,nocordia,
細菌類pseudomonas,bacillus
セルロース分解菌、繊維素分解菌
滑走細菌
cytophaga,spotocytophaga,pseudomonas,bacillus,cellulomonas,streptomyces,nocordia
嫌気性有芽胞桿菌類clostridum
脂肪分解菌
脂肪の分解は、脂肪分解酵素であるリパーゼの関与によって分解される。リパーゼを生産分泌する菌は、糸状菌aspergillus,penicillium,rhizopus など。
Lignin-degrading bacteria White-roting basidiomycetes, streptomyces, nocordia,
Bacteria pseudomonas, bacillus
Cellulolytic bacteria, fibrinolytic bacteria, gliding bacteria
cytophaga, spotocytophaga, pseudomonas, bacillus, cellulomonas, streptomyces, nocordia
Anaerobic spore mold fungus clostridum
Lipolytic bacteria Fat degradation is broken down by the involvement of lipase, a lipolytic enzyme. The fungi that produce and secrete lipase are aspergillus, penicillium, rhizopus, etc.

枯草菌
bacillus subtilis 真性細菌目の代表で枯れ草や塵埃中などに広く分布する。重要なことはアミラーゼやプロテアーゼの生産菌で、特にプロテアーゼは蛋白質の分解酵素である。アミラーゼは、澱粉の粘度低下と沃素反応の消失をもたらす。
乳酸菌
Lactobacillus Plantarum
Bacillus subtilis
bacillus subtilis An eubacteria representative and widely distributed in dead grass and dust. What is important is an amylase or protease producing bacterium, and in particular, protease is a protein degrading enzyme. Amylase results in reduced viscosity of starch and disappearance of iodine reaction.
Lactic acid bacteria
Lactobacillus Plantarum

以上のように、
(1)streptomyces
(2)sulfolobus
(3)saccharopolyspola
(4)白色腐朽性の担子菌
(5)nocordia
(6)pseudomonas
(7)bacillus
(8)cytophaga
(9)spotocytophaga
(10)cellulomonas
(11)clostridum
(12)aspergillus
(13)penicillium
(14)rhizopus
の14属から選択される14属以上、特に乳酸菌Luctobacillusを含む15属以上に属する菌体を含有することが好ましい。また、これらに属する菌体の種としては、これら以上に多いことが推奨され、好ましくは20種以上、より好ましくは40種以上、さらに好ましくは100種以上、特に200種以上で構成されているとよい結果が得られる。
As above
(1) streptomyces
(2) sulfolobus
(3) saccharopolyspola
(4) White decaying basidiomycetes (5) nocordia
(6) pseudomononas
(7) bacillus
(8) cytophaga
(9) spocytocytophaga
(10) cellulomonas
(11) clostridum
(12) aspergillus
(13) penicillium
(14) rhizopus
It is preferable to contain cells belonging to 14 genera or more selected from 14 genera, particularly 15 genera or more including the lactic acid bacterium Luctobacillus. Further, it is recommended that the number of bacterial cells belonging to these is more than these, preferably 20 or more, more preferably 40 or more, still more preferably 100 or more, particularly 200 or more. A good result is obtained.

特に、生分解性プラスチック分解菌、石油分解菌、ポリエステル分解菌、PUR分解菌、土壌分解微生物、土壌微生物蛍光菌を含有することが望ましい。   In particular, it is desirable to contain biodegradable plastic degrading bacteria, petroleum degrading bacteria, polyester degrading bacteria, PUR degrading bacteria, soil degrading microorganisms, and soil microorganism fluorescent bacteria.

具体的には、下記の種から選択される10種以上、好ましくは20種以上、特に全種を含有するとよい。   Specifically, it is good to contain 10 or more types selected from the following species, preferably 20 or more types, particularly all species.

Candida albicans TAX5476
Endomycopsis burtonii
Nocardia asteroides
Bacillus subtillis
Pseudomonas bacterium Rhizobium
Aspergillus niger TAX5061
Rhodospillum rubrum IFO3986
Rhodopseudomonas capsulata
Rhodobacter sphaeroides IFO12203
Chromatium vinosum
Streptomyces albus IFO3710
strepto verticillussp ATCC23654
Nocordia asteroides ATCC19247
Micromonospora chalcea IFO13503
Aspergillus oryzae IFO5770
Mucor hiemalis IFO8567
Saccharomyces cerevisial IFO1346
Candida utilis IFO0619
Lactobacillus Plantarum IFO3070
Pediococcus Halophilus IFO12172
Streptococcus Lactis IFO12007
Streptococcus Faecalis IFO3971
Arthrobacter sp.w 1〜6.
Pseudomonas aeruginosa
Corynebacterium sp.
Comamonas acidovorans
C.acidovorans. TB-35
Pseudomonas glumae
Pseudomonas gladioli
Pseudomonas avenae
Agrobacterium mochiganens
Pseudomonas solanacearum
Pseudomonas fluorescein
Aspergillus flavus
Aspergillus fumigatus
Aspergillus versicolor
Aspergillus penicillioides
(上記中、属名及び種名の最後に付されている数字は、ATCC、IFO、TAX等の組織が用いる分類用の数字であり、例えばIFO 3986はIFOが分類・収集している微生物の3986番である。)
Candida albicans TAX5476
Endomycopsis burtonii
Nocardia asteroides
Bacillus subtillis
Pseudomonas bacterium Rhizobium
Aspergillus niger TAX5061
Rhodospillum rubrum IFO3986
Rhodopseudomonas capsulata
Rhodobacter sphaeroides IFO12203
Chromatium vinosum
Streptomyces albus IFO3710
strepto verticillussp ATCC23654
Nocordia asteroides ATCC19247
Micromonospora chalcea IFO13503
Aspergillus oryzae IFO5770
Mucor hiemalis IFO8567
Saccharomyces cerevisial IFO1346
Candida utilis IFO0619
Lactobacillus Plantarum IFO3070
Pediococcus Halophilus IFO12172
Streptococcus Lactis IFO12007
Streptococcus Faecalis IFO3971
Arthrobacter sp.w 1-6.
Pseudomonas aeruginosa
Corynebacterium sp.
Comamonas acidovorans
C.acidovorans.TB-35
Pseudomonas glumae
Pseudomonas gladioli
Pseudomonas avenae
Agrobacterium mochiganens
Pseudomonas solanacearum
Pseudomonas fluorescein
Aspergillus flavus
Aspergillus fumigatus
Aspergillus versicolor
Aspergillus penicillioides
(In the above, the numbers attached to the end of the genus name and species name are the numbers for classification used by organizations such as ATCC, IFO, TAX, etc. For example, IFO 3986 is the number of microorganisms classified and collected by IFO. No. 3986.)

これらの分解菌の組み合わせにより、有機物の全ての減容が実現できる。すなわち、本発明では上記14もしくは15属に属する菌類を複数組み合わせて用いることにより、これらが母材中に共生関係を築き、これらの菌の協調作用により、有機物や樹脂材料を迅速に分解するものと思われる。なお、これらの菌の配合率は任意であり、母材や分解する廃棄物の種類などにより、経験則から最適な量を配合すればよい。   By the combination of these decomposing bacteria, it is possible to reduce the volume of all organic substances. That is, in the present invention, by using a combination of a plurality of fungi belonging to the above 14 or 15 genera, they establish a symbiotic relationship in the base material, and rapidly decompose organic substances and resin materials by the cooperative action of these fungi I think that the. Note that the mixing ratio of these bacteria is arbitrary, and an optimal amount may be blended based on empirical rules depending on the base material, the type of waste to be decomposed, and the like.

これらの細菌は、前記母材に対して、好ましくは菌体全量で3〜30質量%程度添加される。添加される菌体の量は、分解すべき廃棄物の質や量で異なり、糖質や澱粉質が主体のもののように比較的分解しやすいものであれば5%以下でも十分な効果が得られる。一方、”イカゴロ”のように分解しにくい水産廃棄物の場合には、15%以上添加することが望ましい。   These bacteria are preferably added in an amount of about 3 to 30% by mass with respect to the base material. The amount of cells added depends on the quality and quantity of the waste to be decomposed, and if it is relatively easy to decompose, such as those mainly composed of sugar and starch, a sufficient effect can be obtained even at 5% or less. It is done. On the other hand, in the case of marine waste that is difficult to decompose, such as “Ikagoro”, it is desirable to add 15% or more.

次に、本発明システムの醗酵条件について説明する。先ず、細菌が添加された母材を適切な温度と湿度に管理する。このときの温度としては、平均温度で25〜50℃、好ましくは30〜45℃とし、湿度は20〜50%、好ましくは30〜40%である。この母材中に廃棄物を投入する。このとき、投入する有機物は、母材の数十分の一とすることが望ましい。具体的には、質量比で母材全量の1/10以下、好ましくは1/20以下、特に1/30以下とするとよい。有機廃棄物投入後、醗酵作用により、母材の温度は上昇し、60〜70℃となるが、上記温度に管理することで適切な醗酵が促される。   Next, the fermentation conditions of the system of the present invention will be described. First, the base material to which bacteria are added is controlled at an appropriate temperature and humidity. The temperature at this time is 25 to 50 ° C., preferably 30 to 45 ° C. in average temperature, and the humidity is 20 to 50%, preferably 30 to 40%. Waste is put into this base material. At this time, it is desirable that the organic material to be input is a few tenths of the base material. Specifically, the mass ratio is 1/10 or less of the total amount of the base material, preferably 1/20 or less, particularly 1/30 or less. After the organic waste is charged, the temperature of the base material rises to 60 to 70 ° C. due to fermentation, and appropriate fermentation is promoted by controlling the temperature.

母材の温度と管理するための手段としては、熱線ヒーター等を用いて、醗酵槽の外部や内部から加熱してもよいし、温風ヒーターを用いて、醗酵槽内に温風を吹き込むようにしてもよい。特に、温風は、母材の湿度管理も使用することができるので好ましい。湿度管理は、前記温風の他、散水などにより適切な条件に整える。   As a means for controlling the temperature of the base material, it may be heated from the outside or inside of the fermentation tank using a hot wire heater or the like, or hot air is blown into the fermentation tank using a hot air heater. It may be. In particular, warm air is preferable because humidity control of the base material can also be used. The humidity control is adjusted to an appropriate condition by watering in addition to the warm air.

醗酵槽としては、所謂バッチ式の醗酵槽が好ましく、後述するようなプール状の槽に、母材を投入して、攪拌、加熱することで、醗酵が行われる。   As a fermenter, what is called a batch-type fermenter is preferable, and fermentation is performed by putting a base material into a pool-like tank as described later, and stirring and heating.

上記条件による醗酵過程で、投入された有機廃棄物はほぼ完全に消失する。ここで消失するとは、極僅かの残渣を残して、水、炭酸ガス、窒素ガスに分解されることをいう。分解は、通常24時間で完全に行われる。また、投入する有機廃棄物の種類により処理時間が異なる。野菜類などの一般家庭残渣は6時間、水産加工場からの魚介類残渣は8〜10時間、肉類なども8〜10時間で分解される。なお、10時間で消失した場合でも、14時間程度は、母材の状態、特に湿度を整えるために次の廃棄物投入は控えるべきである。すなわち、上記のように分解過程で、水分が多量に発生するため、母材中の湿度を上記最適値に調製しなければならない。   In the fermentation process under the above conditions, the input organic waste disappears almost completely. Disappearing here means being decomposed into water, carbon dioxide gas, and nitrogen gas, leaving very little residue. Degradation is usually complete in 24 hours. Further, the treatment time varies depending on the type of organic waste to be input. General household residues such as vegetables are decomposed in 6 hours, seafood residues from the fishery processing plant are decomposed in 8 to 10 hours, and meats are also decomposed in 8 to 10 hours. Even if it disappears in 10 hours, the next waste input should be refrained for about 14 hours in order to adjust the condition of the base material, particularly the humidity. That is, since a large amount of moisture is generated during the decomposition process as described above, the humidity in the base material must be adjusted to the optimum value.

なお、本発明のシステムによれば、貝殻、カニ殻、ウニ殻、カキ貝殻などの通常の有機物処理では分解しにくい無機系の廃棄物も、数日で分解することが可能であり、同様に買い物袋に用いられるポリ袋や、トレイに用いられる樹脂材料も分解することができる。   In addition, according to the system of the present invention, inorganic wastes that are difficult to be decomposed by ordinary organic matter treatment such as shells, crab shells, sea urchin shells, oyster shells can be decomposed in a few days. Plastic bags used for shopping bags and resin materials used for trays can also be decomposed.

本発明のシステムにおいては、有機廃棄物、および上記の無機系廃棄物や樹脂材料を母材中に投入するに際し、分解効率を高めるために廃棄物をチップ状に破砕することが望ましい。特に、貝殻、カニ殻、ウニ殻、カキ貝殻などの無機系廃棄物、ポリ袋や、トレイに用いられる樹脂材料等は、破砕することにより初めて完全な分解が可能になる。破砕片の大きさは、好ましくは最大部分が10mm以下、より好ましくは5mm以下とする。この大きさ以下に調製することで、迅速な分解処理を行うことができる。   In the system of the present invention, it is desirable to crush the waste into chips in order to increase the decomposition efficiency when the organic waste and the above-described inorganic waste or resin material are put into the base material. In particular, inorganic waste such as shells, crab shells, sea urchin shells, oyster shells, plastic bags, resin materials used for trays, and the like can be completely decomposed only after being crushed. The size of the crushed pieces is preferably 10 mm or less, more preferably 5 mm or less at the maximum portion. A quick decomposition process can be performed by preparing below this magnitude | size.

本発明のシステムにより、廃棄物はその投入量の殆どを分解消失させることができる。具体的には、投入された廃棄物体積を1/100以下、好ましくは1/500、特に1/1000以下にまで減容することができる。しかも、一部の残渣を除き、水、炭酸ガス、窒素ガスに分解されるので、環境にも優しく、化石燃料を浪費することもない。しかも、醗酵に伴う腐敗臭の発生や、不快な臭いを生じることもなく、処理施設の構造や、立地条件の自由度も高い。   With the system of the present invention, most of the input amount of waste can be decomposed and lost. Specifically, it is possible to reduce the volume of the input waste to 1/100 or less, preferably 1/500, particularly 1/1000 or less. Moreover, since it is decomposed into water, carbon dioxide gas and nitrogen gas except for some residues, it is environmentally friendly and does not waste fossil fuel. Moreover, there is no generation of rot odor accompanying fermentation or unpleasant odor, and the structure of the treatment facility and the degree of freedom of location conditions are high.

さらに本発明では、上記のような菌の組み合わせにより、カドミウム、水銀、砒素の1種または2種以上を含む水溶性の重金属成分の少なくとも一部を、非水溶性(不溶性)に変えて、無害化することができる。具体的には、処理後の母材や、残渣に含まれる水溶性重金属成分を累積させることなく減少させ、1/1未満、さらには1/2以下、特に1/3以下にまで低減することができる。この作用は、明確に解明されたわけではないが、例えば水に溶けやすい酸化カドミウムや塩化カドミウム、硫酸カドミ、硝酸カドミウム、臭化カドミウムが、分解菌の働きで水に溶けにくい硫化カドミウムや炭酸カドミウムや水酸化カドミウム、あるいは金属錯体などに変化しているものと考えられる。ここで、非水溶性とは、重金属元素測定に際して、試料から水に溶出される重金属成分を水溶性、溶出されないものを非水溶性とする。すなわち、水溶液中に溶出して測定可能な重金属元素以外のもので、重金属イオンとして測定不可能なものとも表現できる。水溶液中に溶出した重金属元素は、原子吸光法やICP−MS法等により測定することができる。   Furthermore, in the present invention, at least a part of the water-soluble heavy metal component containing one or more of cadmium, mercury, and arsenic is changed to water-insoluble (insoluble) by the combination of the above-mentioned bacteria, and is harmless. Can be Specifically, the amount of water-soluble heavy metal components contained in the base material after treatment and the residue is reduced without accumulating, and is reduced to less than 1/1, further less than 1/2, and particularly less than 1/3. Can do. Although this action has not been clearly clarified, for example, cadmium oxide, cadmium chloride, cadmium sulfate, cadmium nitrate, and cadmium bromide, which are easily soluble in water, are cadmium sulfide, cadmium carbonate, It is thought that it has changed to cadmium hydroxide or a metal complex. Here, the term “water-insoluble” means that, when measuring heavy metal elements, heavy metal components eluted from the sample into water are water-soluble, and those that are not eluted are water-insoluble. That is, it can be expressed as something other than a heavy metal element that can be eluted and measured in an aqueous solution and cannot be measured as a heavy metal ion. The heavy metal element eluted in the aqueous solution can be measured by an atomic absorption method, an ICP-MS method, or the like.

次に、本発明システムの醗酵槽及び攪拌装置の具体例を、図を参照しつつ説明する。図1は本発明に用いられる醗酵槽の構造を示す概略断面図である。   Next, specific examples of the fermenter and the stirring device of the system of the present invention will be described with reference to the drawings. FIG. 1 is a schematic cross-sectional view showing the structure of a fermenter used in the present invention.

図において、醗酵槽1は、プール11とこのブール11内を攪拌する撹拌装置3を有する。プール11上には、壁14に支持された屋根15が固定されていて、これら壁14と屋根15でプール11を覆うことで、閉鎖空間を構成し、温度や湿度の管理を容易にしている。   In the figure, the fermenter 1 has a pool 11 and a stirring device 3 for stirring the inside of the boule 11. On the pool 11, a roof 15 supported by the wall 14 is fixed. By covering the pool 11 with the wall 14 and the roof 15, a closed space is formed, and management of temperature and humidity is facilitated. .

好ましくは図2に示すように、屋根15下部にシート16を段張りに張ることで、水蒸気を上部に逃がすと共に、温度を一定に保つことができる。発生した水蒸気は、上に上昇し、屋根棟部15aにある換気装置により行うことができる。また、シート16の両端部には、水受けの溝17が設けられている。このような構造とすることで、効率的な換気と保温が行われると共に、施設の製造コストを抑制することができる。プール11は、図示例のように地面GLよりも深く掘り下げた位置に配置することで、温度の低下を防止することができる。さらに、保温材等を側面や底面周囲に配置してもよい。   Preferably, as shown in FIG. 2, the sheet 16 is stretched under the roof 15 so that the water vapor can escape to the upper part and the temperature can be kept constant. The generated water vapor rises upward and can be performed by a ventilation device in the roof ridge 15a. Further, water receiving grooves 17 are provided at both ends of the sheet 16. With such a structure, efficient ventilation and heat insulation are performed, and the manufacturing cost of the facility can be suppressed. By disposing the pool 11 at a position dug deeper than the ground GL as in the illustrated example, a decrease in temperature can be prevented. Furthermore, you may arrange | position a heat insulating material etc. around a side surface or a bottom face.

図1の例では、プール11の横に配置されたブロア13とこれに接続される配管12a、12bにより、プール11の底から温風が吹き出すようになっている。   In the example of FIG. 1, warm air is blown out from the bottom of the pool 11 by a blower 13 disposed beside the pool 11 and pipes 12 a and 12 b connected thereto.

また、プール11の側壁上には、レール21を摺動する撹拌レール2が取り付けられていて、この撹拌レール2にさらに攪拌機3が取り付けられている。攪拌機3は、螺旋状の攪拌翼を有する2つの攪拌棒31a,31bが取り付けられていて、この撹拌棒31a,31bが回転することで母材を攪拌する。攪拌機3は、車輪34により攪拌レール2上を図面左右方向に自由に移動することでき、さらに攪拌レール2は、図示しない機構によりレール21上を自由に摺動することができるので、プール11内のいかなる位置にも移動することができるようになっている。   A stirring rail 2 that slides on a rail 21 is attached on the side wall of the pool 11, and a stirrer 3 is further attached to the stirring rail 2. The stirrer 3 is provided with two stirring rods 31a and 31b having spiral stirring blades, and the stirring rods 31a and 31b rotate to stir the base material. The stirrer 3 can freely move on the stirring rail 2 in the horizontal direction of the drawing by wheels 34, and the stirring rail 2 can freely slide on the rail 21 by a mechanism (not shown). It can be moved to any position.

攪拌機3の撹拌棒31a,31bは、図3に示すように、アーム35,36により直立した状態から、水平状態にまで姿勢を変えることができ、これにより作業終了時の原点復帰を容易にすると共に、メンテナンス性にも優れている。撹拌棒31a,31bは、螺旋状に攪拌翼が巻き付けられた、中空状の円筒棒であり、その先端からは温風が吹き出すようになっている。この温風は、撹拌棒31a,31bの後端部に取り付けられている翼回転兼送風用のモータ32から、中空部を通して送られる。攪拌機3には、その他、アーム35,36を駆動するために機構や、移動用のモータ33等が備え付けられている。   As shown in FIG. 3, the stirrers 31a and 31b of the stirrer 3 can be changed in posture from an upright state by arms 35 and 36 to a horizontal state, thereby facilitating the return to the origin at the end of the work. At the same time, it has excellent maintainability. The stirring rods 31a and 31b are hollow cylindrical rods in which stirring blades are spirally wound, and hot air is blown out from the tips thereof. This warm air is sent through a hollow portion from a motor 32 for rotating and blowing blades attached to the rear ends of the stirring rods 31a and 31b. In addition, the stirrer 3 is provided with a mechanism for driving the arms 35 and 36, a moving motor 33, and the like.

このような攪拌機3を用いて、プール11内に収容された母材を攪拌し、温風を吹き込むことで、母材の温度と湿度を適切に保つと共に、攪拌も行え、極めて効率よく醗酵管理作業を行うことができる。   Using such a stirrer 3, the base material accommodated in the pool 11 is stirred, and hot air is blown into it, so that the temperature and humidity of the base material can be appropriately maintained and stirring can be performed, so that fermentation management can be performed very efficiently. Work can be done.

次に、廃棄物を破砕ないし粉砕する装置について説明する。図4は本発明に用いられる破砕装置の一例を示した概略断面図である。図において、装置本体は図面左中央に示される変形したL字状の中空構造体であり、その周囲に各部の平面図、断面図や、回転翼62、固定翼63等の展開図が示されている。   Next, an apparatus for crushing or crushing waste will be described. FIG. 4 is a schematic sectional view showing an example of a crushing apparatus used in the present invention. In the figure, the apparatus main body is a deformed L-shaped hollow structure shown in the left center of the drawing, and a plan view of each part, a cross-sectional view, and a development view of the rotary blade 62, fixed blade 63, etc. are shown around it. ing.

図示例の破砕装置5は、廃棄物を投入するためのホッパー51と、四角い筒状の第1処理部外套52と、この第1処理部外套52内に配置された一対の破砕歯車53a,53bを備える。2つの破砕歯車53a,53bのうち一方は、モ−タ54からベルト55を介して駆動され、もう一方は、さらに動力伝達用プーリー56を介して駆動される。このようにして破砕歯車53a,53bは、両者の対向する中央部に向かってそれぞれかみ合うようにして回転し、投入された廃棄物を巻き込んで破砕し、潰しながら、下方に落とし込む。   The crushing device 5 in the illustrated example includes a hopper 51 for feeding waste, a first cylindrical processing outer shell 52, and a pair of crushing gears 53a and 53b disposed in the first processing outer sheath 52. Is provided. One of the two crushing gears 53 a and 53 b is driven from the motor 54 via a belt 55, and the other is further driven via a power transmission pulley 56. In this way, the crushing gears 53a and 53b rotate so as to mesh with each other toward the opposite central portions, and the thrown-in waste is rolled up, crushed, and dropped while being crushed.

破砕歯車53a,53bから排出された廃棄物は、第1処理部外套52から口径が小さくなる連結部56を通って、円筒状の第2処理部外套57内へと導入される。第2処理部外套57内部では、この第2処理部外套57と、所定の間隔のギャップを介して両端部付近の径が小さくなっている破砕ドラム58が配置され、モータ59によりベルトを介して、その回転軸60が駆動されるようになっている。この第2処理部では、廃棄物が、第2処理部外套57と、破砕ドラム58との間のギャップで固形物が破砕されながら斜め下方に移動してゆく。従って、廃棄物はこの第2処理部で、略ギャップ以下の大きさにまで、破砕、破断される。   Waste discharged from the crushing gears 53a and 53b is introduced from the first processing portion outer sheath 52 into the cylindrical second processing portion outer sheath 57 through the connecting portion 56 having a reduced diameter. Inside the second processing portion mantle 57, the second processing portion mantle 57 and a crushing drum 58 having a reduced diameter in the vicinity of both ends through a gap of a predetermined interval are arranged, and the motor 59 passes the belt through the belt. The rotation shaft 60 is driven. In the second processing unit, the waste moves obliquely downward while the solid matter is crushed in the gap between the second processing unit mantle 57 and the crushing drum 58. Therefore, the waste is crushed and broken to a size substantially equal to or smaller than the gap in the second processing section.

第2処理部外套57の下端部(終端部)付近には、放射状に複数の翼を有する回転翼62と、同様に放射状に複数の翼を有する固定翼63とが僅かなギャップを介して備え付けられていて、これらにより第3処理部が構成されている。回転翼62と固定翼63には、複数の突起が所定の間隔を設けて配置されている。また、回転翼62の突起と固定翼63の突起とは、それぞれ対向して交互に配置されるようになっていて、ちょうど一方の突起が、他方の突起のない部分を通って、回転翼62が回転できるようになっている。この回転翼62も、前記破砕ドラム58の回転軸と接続されていて、破砕ドラム58と同様に回転できるようになっている。この第3処理部で廃棄物はさらに破砕、破断される。   In the vicinity of the lower end portion (terminal portion) of the second processing portion mantle 57, a rotary blade 62 having a plurality of blades radially and a fixed blade 63 having a plurality of blades in the same manner are provided through a slight gap. These constitute the third processing unit. A plurality of protrusions are arranged on the rotary blade 62 and the fixed blade 63 at predetermined intervals. Further, the protrusions of the rotor blade 62 and the protrusions of the fixed blade 63 are alternately arranged opposite to each other, and one of the protrusions passes through a portion without the other protrusion, and the rotor blade 62 Can be rotated. The rotor blade 62 is also connected to the rotating shaft of the crushing drum 58 and can be rotated in the same manner as the crushing drum 58. The waste is further crushed and broken in this third processing section.

第2処理部外套57は、支柱を介して固定台61に取り付けられ、これにより装置全体が保持固定されるようになっている。   The second processing portion mantle 57 is attached to the fixing base 61 via a support, so that the entire apparatus is held and fixed.

第3処理部から排出された廃棄物は、第2処理部外套57に固定された扁平な円筒状の第4処理部外套64内を落下するように通過する。第4処理部外套64の下端部付近には、伏せたお椀状の固定破砕ドラム68と、断面が固定破砕ドラム68と同様の曲線となり、放射状に複数の翼を有する回転翼67が僅かなギャップを介して備え付けられていて、これらにより第4処理部が構成されている。   The waste discharged from the third processing unit passes through the flat cylindrical fourth processing unit mantle 64 fixed to the second processing unit mantle 57 so as to fall. In the vicinity of the lower end of the fourth processing portion mantle 64, the obstructed bowl-shaped fixed crushing drum 68 and the cross-section of the rotary blade 67 having a plurality of blades radially have a slight gap. The fourth processing unit is configured by these.

固定破砕ドラム68には放射渦巻き状に突起が形成され、その上に配置された回転翼67が、ギャップを介して回転する。このため、廃棄物は前記渦巻き状の突起の間を、回転翼67に裁断され、擦られるようにして移動し、丁度すり鉢で擦られるように破砕、破断される。   The fixed crushing drum 68 is formed with a radial spiral projection, and a rotary blade 67 disposed thereon rotates through a gap. For this reason, the waste is cut between the spiral projections by the rotary blade 67, moved so as to be rubbed, and crushed and broken so as to be rubbed with just a mortar.

このようにして、投入された廃棄物は、第1処理部から第4処理部を通過することで、順次破砕、破断され、最終的に10mm以下、好ましくは5mm以下の大きさの断片にまで細かくされる。ここで、第1処理部の破砕歯車53a,53bの回転速度は、好ましくは、毎分40〜80回転、特に50〜70回転とするとよい。また、第2処理部のドラム58と第3処理部の回転翼62の回転数は、好ましくは毎分1000〜1400回転、特に1100〜1300回転である。さらに、第4処理部の回転翼67の回転数は、好ましくは毎分800〜1200回転、特に900〜1100回転である。これらの回転方向は交互に異なるようにするとよい。   In this way, the thrown-in waste passes through the first processing section to the fourth processing section, and is sequentially crushed and broken to finally reach a size of 10 mm or less, preferably 5 mm or less. It is finely divided. Here, the rotation speed of the crushing gears 53a and 53b of the first processing unit is preferably 40 to 80 rotations per minute, particularly 50 to 70 rotations. The rotation speed of the drum 58 of the second processing unit and the rotary blade 62 of the third processing unit is preferably 1000 to 1400 rotations per minute, particularly 1100 to 1300 rotations. Furthermore, the rotation speed of the rotary blade 67 of the fourth processing unit is preferably 800 to 1200 rotations per minute, particularly 900 to 1100 rotations. These rotation directions are preferably different from each other.

このようにして、廃棄物中の有機物も、貝殻、蛎殻、カニ殻、ウニ殻等のカルシウム質、キチン質等からなる無機物や、硬質廃棄物、あるいはポリ袋やポリエチレンなどのような樹脂製品も所定の大きさにまで細かく粉砕され、微生物による分解が極めて容易に行えるようになる。   In this way, the organic matter in the waste is also made of calcium, chitin and other inorganic materials such as shells, rice husks, crab shells and sea urchin shells, hard waste, or resin products such as plastic bags and polyethylene. Is finely pulverized to a predetermined size, and can be easily decomposed by microorganisms.

次に、実施例を示し、本発明をより具体的に説明する。   Next, an Example is shown and this invention is demonstrated more concretely.

〔実施例1〕
以下の手順で、7日間の連続処理を行い、処理前後の重金属成分(水銀、ヒ素、カドミウム)の含有量を測定した。
[Example 1]
In the following procedure, continuous treatment was performed for 7 days, and the content of heavy metal components (mercury, arsenic, cadmium) before and after the treatment was measured.

菌床となる母材は、バーク、おがくず、木炭粉、ぼかしをそれぞれ適量混合し、日毎処理容量の30倍である600l(リットル)用意した。この母材に対し、少なくとも下記菌体リストの菌種を含む上記15属に属する処理用培養細菌を所定の割合で配合したものを15重量%投入し、混合した。
〔菌体リスト〕
Candida albicans TAX5476
Endomycopsis burtonii
Nocardia asteroides
Bacillus subtillis
Pseudomonas bacterium Rhizobium
Aspergillus niger TAX5061
Rhodospillum rubrum IFO3986
Rhodopseudomonas capsulata
Rhodobacter sphaeroides IFO12203
Chromatium vinosum
Streptomyces albus IFO3710
strepto verticillussp ATCC23654
Nocordia asteroides ATCC19247
Micromonospora chalcea IFO13503
Aspergillus oryzae IFO5770
Mucor hiemalis IFO8567
Saccharomyces cerevisial IFO1346
Candida utilis IFO0619
Luctobacillus Plantarum IFO3070
Pediococcus Halophilus IFO12172
Streptococcus Lactis IFO12007
Streptococcus Faecalis IFO3971
Arthrobacter sp.w 1〜6.
Pseudomonas aeruginosa
Corynebacterium sp.
Comamonas acidovorans
C.acidovorans. TB-35
Pseudomonas glumae
Pseudomonas gladioli
Pseudomonas avenae
Agrobacterium mochiganens
Pseudomonas solanacearum
Pseudomonas fluorescein
Aspergillus flavus
Aspergillus fumigatus
Aspergillus versicolor
Aspergillus penicillioides
The base material to be used as the fungus bed was prepared by mixing appropriate amounts of bark, sawdust, charcoal powder, and blur, respectively, and preparing 600 l (liter) which is 30 times the daily processing capacity. To this base material, 15% by weight of a mixture of culture bacteria for treatment belonging to the above 15 genera including at least the bacterial species of the following bacterial cell list at a predetermined ratio was added and mixed.
[Bacteria list]
Candida albicans TAX5476
Endomycopsis burtonii
Nocardia asteroides
Bacillus subtillis
Pseudomonas bacterium Rhizobium
Aspergillus niger TAX5061
Rhodospillum rubrum IFO3986
Rhodopseudomonas capsulata
Rhodobacter sphaeroides IFO12203
Chromatium vinosum
Streptomyces albus IFO3710
strepto verticillussp ATCC23654
Nocordia asteroides ATCC19247
Micromonospora chalcea IFO13503
Aspergillus oryzae IFO5770
Mucor hiemalis IFO8567
Saccharomyces cerevisial IFO1346
Candida utilis IFO0619
Luctobacillus Plantarum IFO3070
Pediococcus Halophilus IFO12172
Streptococcus Lactis IFO12007
Streptococcus Faecalis IFO3971
Arthrobacter sp.w 1-6.
Pseudomonas aeruginosa
Corynebacterium sp.
Comamonas acidovorans
C.acidovorans.TB-35
Pseudomonas glumae
Pseudomonas gladioli
Pseudomonas avenae
Agrobacterium mochiganens
Pseudomonas solanacearum
Pseudomonas fluorescein
Aspergillus flavus
Aspergillus fumigatus
Aspergillus versicolor
Aspergillus penicillioides

上記菌体を含む母材に対しイカの内臓を主に含むイカゴロ20kgを投入し、攪拌しながら母材の温度を30〜45℃、湿度を30〜40%に保持した。24時間後に母材を目視により検査したところ、投入したイカゴロの痕跡は確認されず、目視による検査では、完全な消失と認められた。さらに、この母材中にイカゴロ20kgを投入し、同様の操作により24時間後の目視確認を7日間繰り返した。その結果、7日間のイカゴロ繰り返し投入試験では、24時間以内に投入したイカゴロの完全な消失が確認できた。   20 kg of squid goro mainly containing squid internal organs was added to the base material containing the cells, and the temperature of the base material was kept at 30 to 45 ° C. and the humidity was kept at 30 to 40% while stirring. When the base material was visually inspected after 24 hours, no trace of the inserted squid was confirmed, and the visual inspection confirmed that it was completely disappeared. Further, 20 kg of Ikagoro was put into this base material, and visual confirmation after 24 hours was repeated for 7 days by the same operation. As a result, in the 7-day Ikagoro repeated charging test, it was confirmed that Ikagoro that had been charged within 24 hours was completely lost.

処理前の母材およびイカゴロの水銀、砒素、カドミウム含有量と、処理後の母材の水銀、砒素、カドミウム含有量を測定した。測定は財団法人北海道薬剤師会公衆衛生検査センターに依頼し、資料を水溶液中に溶出させ、水銀、砒素は原子吸光法、カドミウムはICP−MS法により測定した。結果を以下の表1に示す。   The mercury, arsenic and cadmium contents of the base material before treatment and Ikagoro and the mercury, arsenic and cadmium contents of the base material after treatment were measured. The measurement was requested from the Hokkaido Pharmacists Association Public Health Inspection Center, and the materials were eluted in an aqueous solution. Mercury and arsenic were measured by the atomic absorption method, and cadmium was measured by the ICP-MS method. The results are shown in Table 1 below.

Figure 0004386933
Figure 0004386933

表1から処理前のイカゴロに含まれるカドミウムは0.74mg/l、処理前の母材に含まれるカドミウムは0.011mg/lであり、イカゴロは総量で140kg投入されているから、1kg=1lとすると、投入された廃棄物の総カドミウム量は0.74×140=103.6mgであり、母材は600リットルあるので、母材の総カドミウム量は0.011×600=6.6mgである。従って、処理後の母材中に存在する総カドミウム量は103.6+6.6=110.2mgとなるはずである。しかし、処理後のカドミウム含有量は、0.065mg/lであり、これを総量にすると0.065×600=39mgであるから、110.2−39=71.2mgのカドミウムが、母材中の微生物により処理されたことになる。これは投入されたイカゴロに含有するカドミウムにだけ着目しても、1/3以下の量に減量されていることになる。また、カドミウム以外の重金属成分、水銀、ヒ素でも同様な効果が認められる。   From Table 1, the cadmium contained in the squid before treatment is 0.74 mg / l, the cadmium contained in the base material before treatment is 0.011 mg / l, and the total amount of squid is 140 kg, so 1 kg = 1 liter As a result, the total amount of cadmium in the input waste is 0.74 × 140 = 103.6 mg and the base material is 600 liters, so the total amount of cadmium in the base material is 0.011 × 600 = 6.6 mg. is there. Therefore, the total amount of cadmium present in the treated matrix should be 103.6 + 6.6 = 110.2 mg. However, the cadmium content after the treatment is 0.065 mg / l, and when this is the total amount, it is 0.065 × 600 = 39 mg. Therefore, 110.2−39 = 71.2 mg of cadmium is contained in the base material. It was processed by the microorganisms. Even if paying attention only to the cadmium contained in the input Ikagoro, the amount is reduced to 1/3 or less. Similar effects are observed with heavy metal components other than cadmium, mercury, and arsenic.

このことは、母材中の微生物の作用により、水溶性の重金属成分が、非水溶性に変化したものと考えられる。このように非水溶性とすることで、有害な重金属成分を無害化することができ、処理後の母材の重金属成分による汚染の影響を無視できる程度に軽減することが可能となる。なお、上記残留重金属成分の含有率は、国の安全基準以下に適合する値である。   This is considered that the water-soluble heavy metal component was changed to water-insoluble due to the action of microorganisms in the base material. By making it water-insoluble as described above, harmful heavy metal components can be rendered harmless, and the influence of contamination by the heavy metal components of the base material after processing can be reduced to a negligible level. In addition, the content rate of the said residual heavy metal component is a value which conforms to a national safety standard or less.

〔実施例2〕
実施例1において、イカゴロに代えて、廃棄物としてホタテウロ、たこ内臓、タラバガニ残渣(主に殻)を、母材中にそれぞれ1日おきに順次投入したが、目視による確認では何れの廃棄物も24時間以内に消失したことが認められた。
[Example 2]
In Example 1, instead of squid goro, scallops, octopus viscera, and king crab residues (mainly shells) were sequentially introduced into the base material every other day. It was observed that it had disappeared within 24 hours.

以上結果から、本発明のシステムは、従来のシステムでは処理し難い水産物残渣等も迅速かつ完全に処理することができ、しかも有害な重金属成分も低減できるので、高効率で安全性の高い有機廃棄物処理を行えることがわかる。   From the above results, the system of the present invention can quickly and completely treat marine product residues and the like that are difficult to treat with conventional systems, and can also reduce harmful heavy metal components, so that organic waste with high efficiency and high safety can be obtained. It can be seen that material processing can be performed.

本発明に用いられる醗酵槽の構造を示す概略断面図である。It is a schematic sectional drawing which shows the structure of the fermenter used for this invention. 醗酵槽となるプール、および屋根、シート等の関係を示す概略断面図である。It is a schematic sectional drawing which shows the relationship between the pool used as a fermenter, a roof, a sheet | seat, etc. 本発明に用いられる撹拌装置の構造を示す図1の一部概略側面図である。It is a partial schematic side view of FIG. 1 which shows the structure of the stirring apparatus used for this invention. 本発明に用いられる破砕装置の一例を示す概略断面図である。It is a schematic sectional drawing which shows an example of the crushing apparatus used for this invention.

符号の説明Explanation of symbols

1 醗酵槽
2 撹拌レール
3 撹拌装置
11 側壁
14 支柱
15 屋根
16 シート
21 レール
31a,31b 撹拌棒
32 モータ
DESCRIPTION OF SYMBOLS 1 Fermenter 2 Stirring rail 3 Stirring apparatus 11 Side wall 14 Support column 15 Roof 16 Sheet 21 Rail 31a, 31b Stirring rod 32 Motor

Claims (5)

菌体を固定するための母材と、少なくとも以下の14属に属する細菌属群を含み、投入された廃棄物が、前記細菌群の発酵作用により分解されて、廃棄物体積を24時間以内に1/100以下にまで減容する有機廃棄物処理システム。
細菌属群
(1)streptomyces
(2)sulfolobus
(3)saccharopolyspola
(4)白色腐朽性の担子菌
(5)nocordia
(6)pseudomonas
(7)bacillus
(8)cytophaga
(9)spotocytophaga
(10)cellulomonas
(11)clostridum
(12)aspergillus
(13)penicillium
(14)rhizopus
The base material for fixing the microbial cells and the bacterial genus group belonging to at least the following 14 genera, the input waste is decomposed by the fermentation action of the bacterial group, the waste volume within 24 hours Organic waste treatment system that reduces volume to 1/100 or less.
Bacterial genus group (1) streptomyces
(2) sulfolobus
(3) saccharopolyspola
(4) White decaying basidiomycetes (5) nocordia
(6) pseudomononas
(7) bacillus
(8) cytophaga
(9) spocytocytophaga
(10) cellulomonas
(11) clostridum
(12) aspergillus
(13) penicillium
(14) rhizopus
前記細菌群は
耐熱放線菌として
高温域から中温域の菌であってstreptomyces avermitillis、好酸性古細菌sulfolobus shibatae、およびsaccharopolyspola rectivirgulaから選択される菌を有し、
リグニン分解菌として
白色腐朽性の担子菌、放線菌streptomyces,nocordia、細菌類pseudomonas,bacillus、セルロース分解菌および繊維素分解菌として
滑走細菌cytophaga,spotocytophaga, pseudomonas, bacillus, cellulomonas, streptomyces, nocordiaおよび、嫌気性有芽胞桿菌類clostridumから選択される菌を有し、
脂肪分解菌として
リパーゼを生産分泌する菌である糸状菌aspergillus, penicillium,rhizopus から選択される菌を有し、
枯草菌として
アミラーゼやプロテアーゼの生産菌であるbacillus subtilis から選択される菌を有し、
乳酸菌として
Lactobacillus Plantarumから選択される菌を有する
請求項1の有機廃棄物の処理システム。
The bacterial group is a heat-resistant actinomycete having a high temperature to a medium temperature range and having a bacterium selected from streptomyces avermitillis, acidophilic archaeon sulfolobus shibatae, and saccharopolyspola rectivirgula,
White rot basidiomycetes, actinomycetes, streptomyces, nocordia, bacteria pseudomonas, bacillus, cellulose-degrading bacteria and fibrinolytic bacteria, gliding bacteria cytophaga, spotocytophaga, pseudomonas, bacillus, cellulomonas, streptomyces, nocordia Having a bacterium selected from the sex spore-forming fungus clostridum,
As a lipolytic bacterium, it has a bacterium selected from the filamentous fungi aspergillus, penicillium, rhizpus, which produces and secretes lipase,
As a Bacillus subtilis, there is a bacterium selected from bacillus subtilis, which is a bacterium producing amylase and protease,
As lactic acid bacteria
The organic waste treatment system according to claim 1, comprising a bacterium selected from Lactobacillus Plantarum.
前記細菌群は、下記の種から選択される20種以上を含有する請求項1または2の有機廃棄物の処理システム。
Candida albicans TAX5476
Endomycopsis burtonii
Nocardia asteroides
Bacillus subtillis
Pseudomonas bacterium Rhizobium
Aspergillus niger TAX5061
Rhodospillum rubrum IFO3986
Rhodopseudomonas capsulata
Rhodobacter sphaeroides IFO12203
Chromatium vinosum
Streptomyces albus IFO3710
strepto verticillussp ATCC23654
Nocordia asteroides ATCC19247
Micromonospora chalcea IFO13503
Aspergillus oryzae IFO5770
Mucor hiemalis IFO8567
Saccharomyces cerevisial IFO1346
Candida utilis IFO0619
Lactobacillus Plantarum IFO3070
Pediococcus Halophilus IFO12172
Streptococcus Lactis IFO12007
Streptococcus Faecalis IFO3971
Arthrobacter sp.w 1〜6.
Pseudomonas aeruginosa
Corynebacterium sp.
Comamonas acidovorans
C.acidovorans. TB-35
Pseudomonas glumae
Pseudomonas gladioli
Pseudomonas avenae
Agrobacterium mochiganens
Pseudomonas solanacearum
Pseudomonas fluorescein
Aspergillus flavus
Aspergillus fumigatus
Aspergillus versicolor
Aspergillus penicillioides
The organic waste treatment system according to claim 1 or 2, wherein the bacterial group contains 20 or more species selected from the following species.
Candida albicans TAX5476
Endomycopsis burtonii
Nocardia asteroides
Bacillus subtillis
Pseudomonas bacterium Rhizobium
Aspergillus niger TAX5061
Rhodospillum rubrum IFO3986
Rhodopseudomonas capsulata
Rhodobacter sphaeroides IFO12203
Chromatium vinosum
Streptomyces albus IFO3710
strepto verticillussp ATCC23654
Nocordia asteroides ATCC19247
Micromonospora chalcea IFO13503
Aspergillus oryzae IFO5770
Mucor hiemalis IFO8567
Saccharomyces cerevisial IFO1346
Candida utilis IFO0619
Lactobacillus Plantarum IFO3070
Pediococcus Halophilus IFO12172
Streptococcus Lactis IFO12007
Streptococcus Faecalis IFO3971
Arthrobacter sp.w 1-6.
Pseudomonas aeruginosa
Corynebacterium sp.
Comamonas acidovorans
C.acidovorans.TB-35
Pseudomonas glumae
Pseudomonas gladioli
Pseudomonas avenae
Agrobacterium mochiganens
Pseudomonas solanacearum
Pseudomonas fluorescein
Aspergillus flavus
Aspergillus fumigatus
Aspergillus versicolor
Aspergillus penicillioides
処理前の有機廃棄物に含まれるカドミウム、水銀、砒素の1種または2種以上を含む水溶性の重金属成分の少なくとも一部を、非水溶性(不溶性)に変えて、無害化する請求項1〜3のいずれかの有機廃棄物処理システム。   2. At least a part of a water-soluble heavy metal component containing one or more of cadmium, mercury, and arsenic contained in organic waste before treatment is changed to water-insoluble (insoluble) so as to be detoxified. Organic waste processing system according to any one of. 前記母材と撹拌装置を有するプール状の発酵槽とを有し、
廃棄物は、10mm以下に処理された後、発酵槽に投入されて発酵作用により分解して減容する請求項1〜4のいずれかの有機廃棄物処理システム。
Having a pool-shaped fermenter having the base material and a stirring device,
The organic waste treatment system according to any one of claims 1 to 4, wherein the waste is treated to 10 mm or less, and then introduced into a fermenter to be decomposed and reduced in volume by fermentation.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101869906A (en) * 2010-06-24 2010-10-27 天津北洋百川生物技术有限公司 Biological in-situ pretreatment method of solid organic wastes
CN109022321A (en) * 2018-08-23 2018-12-18 苏州微宏生物科技有限公司 Microbial bacterial agent and preparation method thereof with high-salt tolerance and oil and grease degradation rate
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