JP4316885B2 - オレフィン重合のための触媒組成物およびその調製方法 - Google Patents
オレフィン重合のための触媒組成物およびその調製方法 Download PDFInfo
- Publication number
- JP4316885B2 JP4316885B2 JP2002564974A JP2002564974A JP4316885B2 JP 4316885 B2 JP4316885 B2 JP 4316885B2 JP 2002564974 A JP2002564974 A JP 2002564974A JP 2002564974 A JP2002564974 A JP 2002564974A JP 4316885 B2 JP4316885 B2 JP 4316885B2
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- Prior art keywords
- magnesium
- vanadium
- catalyst composition
- compound
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000003054 catalyst Substances 0.000 title claims description 62
- 239000000203 mixture Substances 0.000 title claims description 43
- 238000006116 polymerization reaction Methods 0.000 title claims description 29
- 150000001336 alkenes Chemical class 0.000 title claims description 7
- 238000000034 method Methods 0.000 title claims description 7
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims description 5
- 238000002360 preparation method Methods 0.000 title description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 31
- 239000005977 Ethylene Substances 0.000 claims description 31
- 239000002243 precursor Substances 0.000 claims description 29
- 239000011949 solid catalyst Substances 0.000 claims description 25
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 22
- 239000004800 polyvinyl chloride Substances 0.000 claims description 22
- 229910052720 vanadium Inorganic materials 0.000 claims description 17
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 17
- -1 aluminum compound Chemical class 0.000 claims description 16
- 239000011777 magnesium Substances 0.000 claims description 14
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 12
- 229910052749 magnesium Inorganic materials 0.000 claims description 12
- 150000002681 magnesium compounds Chemical class 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 150000003682 vanadium compounds Chemical class 0.000 claims description 10
- 229910021552 Vanadium(IV) chloride Inorganic materials 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- 239000012018 catalyst precursor Substances 0.000 claims description 9
- 150000003623 transition metal compounds Chemical class 0.000 claims description 9
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 9
- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 claims description 9
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 8
- JBIQAPKSNFTACH-UHFFFAOYSA-K vanadium oxytrichloride Chemical compound Cl[V](Cl)(Cl)=O JBIQAPKSNFTACH-UHFFFAOYSA-K 0.000 claims description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- QUXHCILOWRXCEO-UHFFFAOYSA-M magnesium;butane;chloride Chemical compound [Mg+2].[Cl-].CCC[CH2-] QUXHCILOWRXCEO-UHFFFAOYSA-M 0.000 claims description 6
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 claims description 6
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 150000002430 hydrocarbons Chemical group 0.000 claims description 5
- 239000002861 polymer material Substances 0.000 claims description 5
- 229910052723 transition metal Inorganic materials 0.000 claims description 5
- 150000003624 transition metals Chemical class 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 4
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims description 4
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 4
- HKJYVRJHDIPMQB-UHFFFAOYSA-N propan-1-olate;titanium(4+) Chemical compound CCCO[Ti](OCCC)(OCCC)OCCC HKJYVRJHDIPMQB-UHFFFAOYSA-N 0.000 claims description 4
- 229910021551 Vanadium(III) chloride Inorganic materials 0.000 claims description 3
- ZFCJLQRNVAABBF-UHFFFAOYSA-N ethanolate vanadium(4+) Chemical compound [V+4].CC[O-].CC[O-].CC[O-].CC[O-] ZFCJLQRNVAABBF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 125000005843 halogen group Chemical group 0.000 claims description 3
- 150000002367 halogens Chemical group 0.000 claims description 3
- YCJBFDACUZRMEO-UHFFFAOYSA-N propan-1-olate vanadium(4+) Chemical compound [V+4].CCC[O-].CCC[O-].CCC[O-].CCC[O-] YCJBFDACUZRMEO-UHFFFAOYSA-N 0.000 claims description 3
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 claims description 3
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 claims description 3
- HQYCOEXWFMFWLR-UHFFFAOYSA-K vanadium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[V+3] HQYCOEXWFMFWLR-UHFFFAOYSA-K 0.000 claims description 3
- RTAQCQOZRWKSTQ-UHFFFAOYSA-N CC(C)C[Mg]CC(C)C Chemical compound CC(C)C[Mg]CC(C)C RTAQCQOZRWKSTQ-UHFFFAOYSA-N 0.000 claims description 2
- ABXKXVWOKXSBNR-UHFFFAOYSA-N CCC[Mg]CCC Chemical compound CCC[Mg]CCC ABXKXVWOKXSBNR-UHFFFAOYSA-N 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 claims description 2
- YHNWUQFTJNJVNU-UHFFFAOYSA-N magnesium;butane;ethane Chemical compound [Mg+2].[CH2-]C.CCC[CH2-] YHNWUQFTJNJVNU-UHFFFAOYSA-N 0.000 claims description 2
- KXDANLFHGCWFRQ-UHFFFAOYSA-N magnesium;butane;octane Chemical compound [Mg+2].CCC[CH2-].CCCCCCC[CH2-] KXDANLFHGCWFRQ-UHFFFAOYSA-N 0.000 claims description 2
- DLPASUVGCQPFFO-UHFFFAOYSA-N magnesium;ethane Chemical compound [Mg+2].[CH2-]C.[CH2-]C DLPASUVGCQPFFO-UHFFFAOYSA-N 0.000 claims description 2
- YCCXQARVHOPWFJ-UHFFFAOYSA-M magnesium;ethane;chloride Chemical compound [Mg+2].[Cl-].[CH2-]C YCCXQARVHOPWFJ-UHFFFAOYSA-M 0.000 claims description 2
- RVOYYLUVELMWJF-UHFFFAOYSA-N magnesium;hexane Chemical compound [Mg+2].CCCCC[CH2-].CCCCC[CH2-] RVOYYLUVELMWJF-UHFFFAOYSA-N 0.000 claims description 2
- GBRJQTLHXWRDOV-UHFFFAOYSA-M magnesium;hexane;chloride Chemical compound [Mg+2].[Cl-].CCCCC[CH2-] GBRJQTLHXWRDOV-UHFFFAOYSA-M 0.000 claims description 2
- KMYFNYFIPIGQQZ-UHFFFAOYSA-N magnesium;octane Chemical compound [Mg+2].CCCCCCC[CH2-].CCCCCCC[CH2-] KMYFNYFIPIGQQZ-UHFFFAOYSA-N 0.000 claims description 2
- DQZLQYHGCKLKGU-UHFFFAOYSA-N magnesium;propane Chemical compound [Mg+2].C[CH-]C.C[CH-]C DQZLQYHGCKLKGU-UHFFFAOYSA-N 0.000 claims description 2
- 239000004711 α-olefin Substances 0.000 claims 2
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- 150000004796 dialkyl magnesium compounds Chemical class 0.000 claims 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 75
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 54
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 44
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 27
- 229910052757 nitrogen Inorganic materials 0.000 description 22
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 16
- 229910052739 hydrogen Inorganic materials 0.000 description 16
- 239000001257 hydrogen Substances 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 12
- 239000002245 particle Substances 0.000 description 12
- 239000007787 solid Substances 0.000 description 12
- 239000002904 solvent Substances 0.000 description 12
- 238000003786 synthesis reaction Methods 0.000 description 12
- 239000002002 slurry Substances 0.000 description 11
- 238000010926 purge Methods 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 9
- 239000012265 solid product Substances 0.000 description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 8
- 238000001816 cooling Methods 0.000 description 8
- 239000000377 silicon dioxide Substances 0.000 description 8
- 229910052719 titanium Inorganic materials 0.000 description 8
- 239000010936 titanium Substances 0.000 description 8
- 235000011147 magnesium chloride Nutrition 0.000 description 7
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 229910001629 magnesium chloride Inorganic materials 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 239000006228 supernatant Substances 0.000 description 4
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 3
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 229940029284 trichlorofluoromethane Drugs 0.000 description 3
- UXQAEOWCSOPBLF-UHFFFAOYSA-N 2,2,3,3-tetramethyloctane Chemical compound CCCCCC(C)(C)C(C)(C)C UXQAEOWCSOPBLF-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- FJBFPHVGVWTDIP-UHFFFAOYSA-N dibromomethane Chemical compound BrCBr FJBFPHVGVWTDIP-UHFFFAOYSA-N 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- ITNVWQNWHXEMNS-UHFFFAOYSA-N methanolate;titanium(4+) Chemical compound [Ti+4].[O-]C.[O-]C.[O-]C.[O-]C ITNVWQNWHXEMNS-UHFFFAOYSA-N 0.000 description 2
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 2
- 229920001470 polyketone Polymers 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- SVKKEKNENWCQAE-UHFFFAOYSA-N ClC(CCC[O-])(Cl)Cl.[Ti+4].ClC(CCC[O-])(Cl)Cl.ClC(CCC[O-])(Cl)Cl.ClC(CCC[O-])(Cl)Cl Chemical compound ClC(CCC[O-])(Cl)Cl.[Ti+4].ClC(CCC[O-])(Cl)Cl.ClC(CCC[O-])(Cl)Cl.ClC(CCC[O-])(Cl)Cl SVKKEKNENWCQAE-UHFFFAOYSA-N 0.000 description 1
- CVRSYMVPBQDCPT-UHFFFAOYSA-N ClC(CC[O-])(Cl)Cl.[Ti+4].ClC(CC[O-])(Cl)Cl.ClC(CC[O-])(Cl)Cl.ClC(CC[O-])(Cl)Cl Chemical compound ClC(CC[O-])(Cl)Cl.[Ti+4].ClC(CC[O-])(Cl)Cl.ClC(CC[O-])(Cl)Cl.ClC(CC[O-])(Cl)Cl CVRSYMVPBQDCPT-UHFFFAOYSA-N 0.000 description 1
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000006165 cyclic alkyl group Chemical group 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- YCOZIPAWZNQLMR-UHFFFAOYSA-N heptane - octane Natural products CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 239000002815 homogeneous catalyst Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002901 organomagnesium compounds Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920005638 polyethylene monopolymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- RQFFFBTUVWONIK-UHFFFAOYSA-N titanium(4+) trichloromethanolate Chemical compound [Ti+4].[O-]C(Cl)(Cl)Cl.[O-]C(Cl)(Cl)Cl.[O-]C(Cl)(Cl)Cl.[O-]C(Cl)(Cl)Cl RQFFFBTUVWONIK-UHFFFAOYSA-N 0.000 description 1
- PGPVJNIERCISDC-UHFFFAOYSA-N titanium(4+);2,2,2-trichloroethanolate Chemical compound [Ti+4].[O-]CC(Cl)(Cl)Cl.[O-]CC(Cl)(Cl)Cl.[O-]CC(Cl)(Cl)Cl.[O-]CC(Cl)(Cl)Cl PGPVJNIERCISDC-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01102731A EP1231224B1 (en) | 2001-02-07 | 2001-02-07 | Catalyst composition for polymerization of olefins and method for preparing the same |
| PCT/EP2002/000931 WO2002064646A1 (en) | 2001-02-07 | 2002-01-30 | Catalyst composition for polmerization of olefins and method for preparing the same |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004526014A JP2004526014A (ja) | 2004-08-26 |
| JP2004526014A5 JP2004526014A5 (https=) | 2005-12-22 |
| JP4316885B2 true JP4316885B2 (ja) | 2009-08-19 |
Family
ID=8176412
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002564974A Expired - Fee Related JP4316885B2 (ja) | 2001-02-07 | 2002-01-30 | オレフィン重合のための触媒組成物およびその調製方法 |
Country Status (7)
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| US (1) | US7001862B2 (https=) |
| EP (1) | EP1231224B1 (https=) |
| JP (1) | JP4316885B2 (https=) |
| CN (1) | CN1216918C (https=) |
| DE (1) | DE60104809T2 (https=) |
| GC (1) | GC0000319A (https=) |
| WO (1) | WO2002064646A1 (https=) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1291366B1 (en) | 2001-09-03 | 2010-03-17 | Saudi Basic Industries Corporation | Catalyst composition for polymerization of olefins and process using this composition |
| DE60204306T2 (de) * | 2002-07-12 | 2005-10-20 | Saudi Basic Industries Corp. | Geträgerter Ziegler - Metallocenepolymerisationskatalysator und dessen Benutzung für die Polymerisation von Olefinen |
| US7662894B2 (en) * | 2006-12-19 | 2010-02-16 | Saudi Bosic Industries Corporation | Polymer supported metallocene catalyst composition for polymerizing olefins |
| CN105732699B (zh) * | 2014-12-10 | 2018-07-13 | 中国石油天然气股份有限公司 | 烷氧基钒化合物及其制备方法和应用 |
| CN109836524B (zh) * | 2017-11-27 | 2022-03-29 | 中国石油天然气股份有限公司 | 催化剂组合物、乙烯-α-烯烃聚合物及其制备方法 |
| CN108031490A (zh) * | 2017-12-21 | 2018-05-15 | 浙江大学 | 一种乙烯齐聚制备线性α-烯烃的助催化剂合成方法及乙烯齐聚工艺 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1098011B (it) * | 1978-08-08 | 1985-08-31 | Euteco Spa | Catalizzatori supportati per la omo- o co-polimerizzazione di affa-olefine |
| US4508842A (en) | 1983-03-29 | 1985-04-02 | Union Carbide Corporation | Ethylene polymerization using supported vanadium catalyst |
| US4900706A (en) * | 1987-03-17 | 1990-02-13 | Sumitomo Chemical Company, Limited | Process for producing olefin polymers and catalyst used therein |
| US5118648A (en) * | 1988-10-05 | 1992-06-02 | Mobil Oil Corporation | Particulate polymer-supported olefin polymerization catalyst |
| IT1240613B (it) * | 1990-03-26 | 1993-12-17 | Enichem Anic Spa | Catalizzatore supportato per la polimerizzazione e la copolimerizzazione di composti olefinicamente insaturi, e procedimento di (co) polimerizzazione impiegante lo stesso |
| US5362824A (en) * | 1991-12-13 | 1994-11-08 | Mobil Oil Corporation | Olefin polymerization catalysts |
| US5198399A (en) * | 1992-01-17 | 1993-03-30 | Quantum Chemical Corporation | Polymerization catalyst and method |
| FI112233B (fi) * | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
| GB9309458D0 (en) * | 1993-05-07 | 1993-06-23 | Bp Chem Int Ltd | Process |
| BE1007040A3 (fr) * | 1993-05-25 | 1995-02-28 | Solvay | Support de catalyseur et catalyseur de polymerisation des alpha-olefines; procedes pour leur obtention et polymerisation des alpha-olefines en presence du catalyseur. |
| FR2707650B1 (fr) * | 1993-07-13 | 1995-08-25 | Bp Chemicals Snc | Procédé de préparation d'un catalyseur de polymérisation des oléfines. |
| US5534472A (en) | 1995-03-29 | 1996-07-09 | Quantum Chemical Corporation | Vanadium-containing catalyst system |
| CA2215829A1 (en) * | 1995-03-29 | 1996-10-03 | Quantum Chemical Corporation | Polymer-supported catalyst for olefin polymerization |
| US5670439A (en) | 1995-03-29 | 1997-09-23 | Quantum Chemical Corporation | Vanadium-containing catalyst system |
| US5661095A (en) * | 1995-06-06 | 1997-08-26 | Quantum Chemical Corporation | Olefin polymerization catalyst component supported on a copolymer of an olefin and an unsaturated silane |
| US5916982A (en) * | 1995-09-29 | 1999-06-29 | Nippon Oil Co., Ltd. | Process for the production of polyolefins |
| DE69601025T2 (de) * | 1995-11-08 | 1999-06-24 | Borealis Ag, Schwechat-Mannswoerth | Trägerkatalysator für die Olefinpolymerisation |
| US6417130B1 (en) * | 1996-03-25 | 2002-07-09 | Exxonmobil Oil Corporation | One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization |
| DE19707236A1 (de) * | 1997-02-24 | 1998-08-27 | Targor Gmbh | Katalysatorzusammensetzung |
| DE19808253A1 (de) * | 1998-02-27 | 1999-09-02 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| DE69923287T2 (de) * | 1998-10-16 | 2005-06-09 | Saudi Basic Industries Corp. | Hochaktive,geträgerte ziegler-natta katalysatorsysteme für die olefinpolymerisation |
| US6403520B1 (en) * | 1999-09-17 | 2002-06-11 | Saudi Basic Industries Corporation | Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst |
| US6288182B1 (en) * | 1999-10-12 | 2001-09-11 | Saudi Basic Industries Corporation | Supported metallocene catalyst system for olefin polymerization |
| AU2001219847A1 (en) * | 2000-12-15 | 2002-06-24 | Beijing Research Institute Of Chemical Industry, Sinopec | Spherical catalyst for (co)polymerization of ethylene, preparation and use of the same |
| EP1291366B1 (en) * | 2001-09-03 | 2010-03-17 | Saudi Basic Industries Corporation | Catalyst composition for polymerization of olefins and process using this composition |
-
2001
- 2001-02-07 EP EP01102731A patent/EP1231224B1/en not_active Expired - Lifetime
- 2001-02-07 DE DE60104809T patent/DE60104809T2/de not_active Expired - Lifetime
-
2002
- 2002-01-30 US US10/470,465 patent/US7001862B2/en not_active Expired - Fee Related
- 2002-01-30 WO PCT/EP2002/000931 patent/WO2002064646A1/en not_active Ceased
- 2002-01-30 JP JP2002564974A patent/JP4316885B2/ja not_active Expired - Fee Related
- 2002-01-30 CN CN02804438XA patent/CN1216918C/zh not_active Expired - Fee Related
- 2002-02-06 GC GCP20021842 patent/GC0000319A/en active
Also Published As
| Publication number | Publication date |
|---|---|
| DE60104809D1 (de) | 2004-09-16 |
| WO2002064646A1 (en) | 2002-08-22 |
| CN1216918C (zh) | 2005-08-31 |
| EP1231224B1 (en) | 2004-08-11 |
| US20040106513A1 (en) | 2004-06-03 |
| EP1231224A1 (en) | 2002-08-14 |
| GC0000319A (en) | 2006-11-01 |
| JP2004526014A (ja) | 2004-08-26 |
| DE60104809T2 (de) | 2005-01-05 |
| CN1489603A (zh) | 2004-04-14 |
| US7001862B2 (en) | 2006-02-21 |
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