JP4278525B2 - 安定化されたポリマーの製造方法 - Google Patents
安定化されたポリマーの製造方法 Download PDFInfo
- Publication number
- JP4278525B2 JP4278525B2 JP2004011533A JP2004011533A JP4278525B2 JP 4278525 B2 JP4278525 B2 JP 4278525B2 JP 2004011533 A JP2004011533 A JP 2004011533A JP 2004011533 A JP2004011533 A JP 2004011533A JP 4278525 B2 JP4278525 B2 JP 4278525B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- zirconium
- bis
- cyclopentadienyl
- tetraphenylborate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 34
- 229920000642 polymer Polymers 0.000 title claims description 23
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 230000008569 process Effects 0.000 title claims description 5
- -1 amine compounds Chemical class 0.000 claims description 262
- 238000006116 polymerization reaction Methods 0.000 claims description 62
- 150000001875 compounds Chemical class 0.000 claims description 48
- 229910052726 zirconium Inorganic materials 0.000 claims description 31
- 239000003054 catalyst Substances 0.000 claims description 23
- 239000012968 metallocene catalyst Substances 0.000 claims description 17
- 229910052751 metal Inorganic materials 0.000 claims description 16
- 239000002184 metal Substances 0.000 claims description 16
- 230000000737 periodic effect Effects 0.000 claims description 15
- 229910052723 transition metal Inorganic materials 0.000 claims description 15
- 150000003624 transition metals Chemical class 0.000 claims description 15
- 239000000178 monomer Substances 0.000 claims description 11
- 229910052719 titanium Inorganic materials 0.000 claims description 11
- 229910052735 hafnium Inorganic materials 0.000 claims description 7
- 230000000087 stabilizing effect Effects 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052772 Samarium Inorganic materials 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- 239000004711 α-olefin Substances 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 description 83
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 56
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 41
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 30
- 239000003381 stabilizer Substances 0.000 description 28
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 24
- 125000000217 alkyl group Chemical group 0.000 description 22
- 150000001450 anions Chemical class 0.000 description 21
- 125000001145 hydrido group Chemical group *[H] 0.000 description 21
- 238000005469 granulation Methods 0.000 description 20
- 230000003179 granulation Effects 0.000 description 20
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 19
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 18
- 125000003118 aryl group Chemical group 0.000 description 17
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 16
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 16
- 150000002430 hydrocarbons Chemical group 0.000 description 15
- 239000003446 ligand Substances 0.000 description 15
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
- 229910052782 aluminium Inorganic materials 0.000 description 14
- 125000005843 halogen group Chemical group 0.000 description 14
- 239000002904 solvent Substances 0.000 description 14
- 239000010936 titanium Substances 0.000 description 14
- 238000011282 treatment Methods 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000003963 antioxidant agent Substances 0.000 description 12
- 235000006708 antioxidants Nutrition 0.000 description 12
- 125000004429 atom Chemical group 0.000 description 12
- 229910052698 phosphorus Inorganic materials 0.000 description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 11
- 239000007983 Tris buffer Substances 0.000 description 11
- 125000003545 alkoxy group Chemical group 0.000 description 11
- 239000002245 particle Substances 0.000 description 11
- 125000001424 substituent group Chemical group 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 10
- 229910052710 silicon Inorganic materials 0.000 description 10
- 239000010703 silicon Substances 0.000 description 10
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 9
- 239000004927 clay Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 9
- 239000011574 phosphorus Substances 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 8
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 239000004743 Polypropylene Substances 0.000 description 7
- 239000000654 additive Substances 0.000 description 7
- 150000001336 alkenes Chemical class 0.000 description 7
- 230000003078 antioxidant effect Effects 0.000 description 7
- 150000001768 cations Chemical class 0.000 description 7
- 229910052801 chlorine Inorganic materials 0.000 description 7
- 239000002734 clay mineral Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 7
- 229920000098 polyolefin Polymers 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- 125000002877 alkyl aryl group Chemical group 0.000 description 6
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 6
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 6
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 6
- YWWDBCBWQNCYNR-UHFFFAOYSA-N trimethylphosphine Chemical compound CP(C)C YWWDBCBWQNCYNR-UHFFFAOYSA-N 0.000 description 6
- 239000002841 Lewis acid Substances 0.000 description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- 125000003342 alkenyl group Chemical group 0.000 description 5
- 125000005018 aryl alkenyl group Chemical group 0.000 description 5
- 125000003710 aryl alkyl group Chemical group 0.000 description 5
- 125000004104 aryloxy group Chemical group 0.000 description 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 150000001721 carbon Chemical group 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 5
- 150000002367 halogens Chemical class 0.000 description 5
- 125000003454 indenyl group Chemical class C1(C=CC2=CC=CC=C12)* 0.000 description 5
- 238000005342 ion exchange Methods 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 150000007517 lewis acids Chemical class 0.000 description 5
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 5
- 239000010955 niobium Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000002530 phenolic antioxidant Substances 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 239000012798 spherical particle Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 229910052718 tin Inorganic materials 0.000 description 5
- 150000003623 transition metal compounds Chemical class 0.000 description 5
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 5
- 239000008096 xylene Substances 0.000 description 5
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 4
- NQMUGNMMFTYOHK-UHFFFAOYSA-N 1-methoxynaphthalene Chemical compound C1=CC=C2C(OC)=CC=CC2=C1 NQMUGNMMFTYOHK-UHFFFAOYSA-N 0.000 description 4
- IIJHUYBZCHWWOZ-UHFFFAOYSA-N C(C)C1(C=CC=C1)[Zr]C1(C=CC=C1)CC Chemical compound C(C)C1(C=CC=C1)[Zr]C1(C=CC=C1)CC IIJHUYBZCHWWOZ-UHFFFAOYSA-N 0.000 description 4
- NYTVYUMUZSEDHG-UHFFFAOYSA-N C1=CC2=CC=CC=C2C1[Zr](=C(C)C)C1C2=CC=CC=C2C=C1 Chemical compound C1=CC2=CC=CC=C2C1[Zr](=C(C)C)C1C2=CC=CC=C2C=C1 NYTVYUMUZSEDHG-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 4
- 235000010290 biphenyl Nutrition 0.000 description 4
- 239000004305 biphenyl Substances 0.000 description 4
- 125000001309 chloro group Chemical group Cl* 0.000 description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 4
- IYYZUPMFVPLQIF-UHFFFAOYSA-N dibenzothiophene Chemical compound C1=CC=C2C3=CC=CC=C3SC2=C1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 description 4
- 239000002609 medium Substances 0.000 description 4
- 229910052752 metalloid Inorganic materials 0.000 description 4
- 150000002738 metalloids Chemical class 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 4
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 4
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 4
- 229910052902 vermiculite Inorganic materials 0.000 description 4
- 239000010455 vermiculite Substances 0.000 description 4
- 235000019354 vermiculite Nutrition 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- NJNGPXRQMNQRLL-UHFFFAOYSA-N C(C)(C)=[Zr](C1C=CC=C1)C1C=CC=C1 Chemical compound C(C)(C)=[Zr](C1C=CC=C1)C1C=CC=C1 NJNGPXRQMNQRLL-UHFFFAOYSA-N 0.000 description 3
- WBUJRBXYIVVCNN-UHFFFAOYSA-N C(C)C1=C(C(=C(C1(C)[Zr]C1(C(=C(C(=C1CC)C)C)C)C)C)C)C Chemical compound C(C)C1=C(C(=C(C1(C)[Zr]C1(C(=C(C(=C1CC)C)C)C)C)C)C)C WBUJRBXYIVVCNN-UHFFFAOYSA-N 0.000 description 3
- WJZMFTYEIIOPIC-UHFFFAOYSA-N C1(C=CC=C1)[Zr]C1C=CC2=CC=CC=C12 Chemical compound C1(C=CC=C1)[Zr]C1C=CC2=CC=CC=C12 WJZMFTYEIIOPIC-UHFFFAOYSA-N 0.000 description 3
- VHNNPTGLWYHNHE-UHFFFAOYSA-N C1=CC2=CC=CC=C2C1[Zr]C1C2=CC=CC=C2C=C1 Chemical compound C1=CC2=CC=CC=C2C1[Zr]C1C2=CC=CC=C2C=C1 VHNNPTGLWYHNHE-UHFFFAOYSA-N 0.000 description 3
- BRHODLBZJKAKRN-UHFFFAOYSA-N C1=CC=CC1[Zr](C)(C)C1C=CC=C1 Chemical compound C1=CC=CC1[Zr](C)(C)C1C=CC=C1 BRHODLBZJKAKRN-UHFFFAOYSA-N 0.000 description 3
- OLYFEVQPCGPWKL-UHFFFAOYSA-N C1=CC=CC1[Zr]([SiH](C)C)C1C=CC=C1 Chemical compound C1=CC=CC1[Zr]([SiH](C)C)C1C=CC=C1 OLYFEVQPCGPWKL-UHFFFAOYSA-N 0.000 description 3
- OJTASADKSHOQHQ-UHFFFAOYSA-N C=[Zr](C1C=CC=C1)C1C=CC=C1 Chemical compound C=[Zr](C1C=CC=C1)C1C=CC=C1 OJTASADKSHOQHQ-UHFFFAOYSA-N 0.000 description 3
- MBVIIPUAENVLDG-UHFFFAOYSA-N CC1(C=CC=C1)[Zr]C1(C=CC=C1)C Chemical compound CC1(C=CC=C1)[Zr]C1(C=CC=C1)C MBVIIPUAENVLDG-UHFFFAOYSA-N 0.000 description 3
- VRGAOYALVRANFN-UHFFFAOYSA-N CC1=C(C(=C(C1(C)[Zr]C1C=CC=C1)C)C)C Chemical compound CC1=C(C(=C(C1(C)[Zr]C1C=CC=C1)C)C)C VRGAOYALVRANFN-UHFFFAOYSA-N 0.000 description 3
- DUNYJZDMGMKWMC-UHFFFAOYSA-N CC1=C(C)C(C)([Zr]C2(C)C=CC(C)=C2C)C=C1 Chemical compound CC1=C(C)C(C)([Zr]C2(C)C=CC(C)=C2C)C=C1 DUNYJZDMGMKWMC-UHFFFAOYSA-N 0.000 description 3
- RVEYJJWOHLDJPA-UHFFFAOYSA-N CC1=C(C)C(C)=C(C)C1(C)[Zr]C1(C)C(C)=C(C)C(C)=C1C Chemical compound CC1=C(C)C(C)=C(C)C1(C)[Zr]C1(C)C(C)=C(C)C(C)=C1C RVEYJJWOHLDJPA-UHFFFAOYSA-N 0.000 description 3
- BDLXNUKTLKNYRE-UHFFFAOYSA-N CC1=C(C)C(C)=C(C)C1[Zr]C1C(C)=C(C)C(C)=C1C Chemical compound CC1=C(C)C(C)=C(C)C1[Zr]C1C(C)=C(C)C(C)=C1C BDLXNUKTLKNYRE-UHFFFAOYSA-N 0.000 description 3
- MSVMXTWPQBFQQF-UHFFFAOYSA-N C[Zr](C1C=CC=C1)C1C=CC=C1 Chemical compound C[Zr](C1C=CC=C1)C1C=CC=C1 MSVMXTWPQBFQQF-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical class [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical group CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- JFWBIRAGFWPMTI-UHFFFAOYSA-N [Zr].[CH]1C=CC=C1 Chemical compound [Zr].[CH]1C=CC=C1 JFWBIRAGFWPMTI-UHFFFAOYSA-N 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000003368 amide group Chemical group 0.000 description 3
- 229910052787 antimony Inorganic materials 0.000 description 3
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 239000000460 chlorine Chemical class 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 125000004093 cyano group Chemical group *C#N 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000002612 dispersion medium Substances 0.000 description 3
- 125000003709 fluoroalkyl group Chemical group 0.000 description 3
- 125000004407 fluoroaryl group Chemical group 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 3
- 229910000271 hectorite Inorganic materials 0.000 description 3
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 3
- 125000001072 heteroaryl group Chemical group 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 229910052901 montmorillonite Inorganic materials 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229910052758 niobium Inorganic materials 0.000 description 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 3
- 229910052755 nonmetal Inorganic materials 0.000 description 3
- 229910000273 nontronite Inorganic materials 0.000 description 3
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 3
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 3
- 239000002685 polymerization catalyst Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 229910000275 saponite Inorganic materials 0.000 description 3
- 229910000276 sauconite Inorganic materials 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 229910052715 tantalum Inorganic materials 0.000 description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 3
- DQVXWCCLFKMJTQ-UHFFFAOYSA-N (4-methylphenoxy)boronic acid Chemical compound CC1=CC=C(OB(O)O)C=C1 DQVXWCCLFKMJTQ-UHFFFAOYSA-N 0.000 description 2
- CRUILBNAQILVHZ-UHFFFAOYSA-N 1,2,3-trimethoxybenzene Chemical compound COC1=CC=CC(OC)=C1OC CRUILBNAQILVHZ-UHFFFAOYSA-N 0.000 description 2
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 2
- JTPNRXUCIXHOKM-UHFFFAOYSA-N 1-chloronaphthalene Chemical compound C1=CC=C2C(Cl)=CC=CC2=C1 JTPNRXUCIXHOKM-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- NPDACUSDTOMAMK-UHFFFAOYSA-N 4-Chlorotoluene Chemical compound CC1=CC=C(Cl)C=C1 NPDACUSDTOMAMK-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 229910017008 AsF 6 Inorganic materials 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- KFRIPBOVARWFNK-UHFFFAOYSA-N C(C)(C)=[Zr](C1=CC=CC=2C3=CC=CC=C3CC1=2)C1C=CC=C1 Chemical compound C(C)(C)=[Zr](C1=CC=CC=2C3=CC=CC=C3CC1=2)C1C=CC=C1 KFRIPBOVARWFNK-UHFFFAOYSA-N 0.000 description 2
- JAKYKQHNJUDFCT-UHFFFAOYSA-N C1=CC=C2C([Zr])C=CC2=C1 Chemical compound C1=CC=C2C([Zr])C=CC2=C1 JAKYKQHNJUDFCT-UHFFFAOYSA-N 0.000 description 2
- SKTBBXWJJOQKBV-UHFFFAOYSA-N CC1=C(C(C=C1)(C)[Zr]C1C=CC=C1)C Chemical compound CC1=C(C(C=C1)(C)[Zr]C1C=CC=C1)C SKTBBXWJJOQKBV-UHFFFAOYSA-N 0.000 description 2
- CFNUQMQNJWFIEL-UHFFFAOYSA-N CC1=CC=CC1(C)[Zr]C1(C)C=CC=C1C Chemical compound CC1=CC=CC1(C)[Zr]C1(C)C=CC=C1C CFNUQMQNJWFIEL-UHFFFAOYSA-N 0.000 description 2
- NXNNTBTYTUJMHX-UHFFFAOYSA-N C[Si](C)(C)C1(C=CC=C1)[Zr]C1(C=CC=C1)[Si](C)(C)C Chemical compound C[Si](C)(C)C1(C=CC=C1)[Zr]C1(C=CC=C1)[Si](C)(C)C NXNNTBTYTUJMHX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 2
- 229910052779 Neodymium Inorganic materials 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 229910052777 Praseodymium Inorganic materials 0.000 description 2
- 229910018286 SbF 6 Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 229910052776 Thorium Inorganic materials 0.000 description 2
- 229910052770 Uranium Inorganic materials 0.000 description 2
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 2
- CAZRWGNQBORTDL-UHFFFAOYSA-L [Cl-].[Cl-].C1(C=CC=C1)[Zr+2]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Cl-].[Cl-].C1(C=CC=C1)[Zr+2]C1(C(=C(C(=C1)C)C)C)C CAZRWGNQBORTDL-UHFFFAOYSA-L 0.000 description 2
- SLARNVPEXUQXLR-UHFFFAOYSA-L [Cl-].[Cl-].CC1=C(C)C(C)([Zr++]C2(C)C=CC(C)=C2C)C=C1 Chemical compound [Cl-].[Cl-].CC1=C(C)C(C)([Zr++]C2(C)C=CC(C)=C2C)C=C1 SLARNVPEXUQXLR-UHFFFAOYSA-L 0.000 description 2
- HWNAAHGOKTZECO-UHFFFAOYSA-L [Cl-].[Cl-].[Zr+2].C[SiH](C1(C(=C(C(=C1)C)C)C)C)C Chemical compound [Cl-].[Cl-].[Zr+2].C[SiH](C1(C(=C(C(=C1)C)C)C)C)C HWNAAHGOKTZECO-UHFFFAOYSA-L 0.000 description 2
- CWSNYHWTGQZSCH-UHFFFAOYSA-N [Zr]C Chemical compound [Zr]C CWSNYHWTGQZSCH-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000010306 acid treatment Methods 0.000 description 2
- DZBUGLKDJFMEHC-UHFFFAOYSA-N acridine Chemical compound C1=CC=CC2=CC3=CC=CC=C3N=C21 DZBUGLKDJFMEHC-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 125000005234 alkyl aluminium group Chemical group 0.000 description 2
- 125000004414 alkyl thio group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 125000001118 alkylidene group Chemical group 0.000 description 2
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- 229920001585 atactic polymer Polymers 0.000 description 2
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- QARVLSVVCXYDNA-UHFFFAOYSA-N bromobenzene Chemical compound BrC1=CC=CC=C1 QARVLSVVCXYDNA-UHFFFAOYSA-N 0.000 description 2
- 125000005998 bromoethyl group Chemical group 0.000 description 2
- 125000005997 bromomethyl group Chemical group 0.000 description 2
- 125000004799 bromophenyl group Chemical group 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- MSZJEPVVQWJCIF-UHFFFAOYSA-N butylazanide Chemical group CCCC[NH-] MSZJEPVVQWJCIF-UHFFFAOYSA-N 0.000 description 2
- YKYOUMDCQGMQQO-UHFFFAOYSA-L cadmium dichloride Chemical compound Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 description 2
- OKIIEJOIXGHUKX-UHFFFAOYSA-L cadmium iodide Chemical compound [Cd+2].[I-].[I-] OKIIEJOIXGHUKX-UHFFFAOYSA-L 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 239000012876 carrier material Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 125000002603 chloroethyl group Chemical group [H]C([*])([H])C([H])([H])Cl 0.000 description 2
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 2
- 125000000068 chlorophenyl group Chemical group 0.000 description 2
- 229910052620 chrysotile Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- VPUGDVKSAQVFFS-UHFFFAOYSA-N coronene Chemical compound C1=C(C2=C34)C=CC3=CC=C(C=C3)C4=C4C3=CC=C(C=C3)C4=C2C3=C1 VPUGDVKSAQVFFS-UHFFFAOYSA-N 0.000 description 2
- IDASTKMEQGPVRR-UHFFFAOYSA-N cyclopenta-1,3-diene;zirconium(2+) Chemical compound [Zr+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 IDASTKMEQGPVRR-UHFFFAOYSA-N 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- LOKCKYUBKHNUCV-UHFFFAOYSA-L dichlorozirconium;methylcyclopentane Chemical compound Cl[Zr]Cl.C[C]1[CH][CH][CH][CH]1.C[C]1[CH][CH][CH][CH]1 LOKCKYUBKHNUCV-UHFFFAOYSA-L 0.000 description 2
- 229910001649 dickite Inorganic materials 0.000 description 2
- QKIUAMUSENSFQQ-UHFFFAOYSA-N dimethylazanide Chemical compound C[N-]C QKIUAMUSENSFQQ-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 2
- 125000003784 fluoroethyl group Chemical group [H]C([H])(F)C([H])([H])* 0.000 description 2
- 125000004216 fluoromethyl group Chemical group [H]C([H])(F)* 0.000 description 2
- 125000001207 fluorophenyl group Chemical group 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 229910052621 halloysite Inorganic materials 0.000 description 2
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 150000004678 hydrides Chemical class 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 229910052900 illite Inorganic materials 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 125000006303 iodophenyl group Chemical group 0.000 description 2
- 125000002510 isobutoxy group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])O* 0.000 description 2
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000000654 isopropylidene group Chemical group C(C)(C)=* 0.000 description 2
- 229920001580 isotactic polymer Polymers 0.000 description 2
- 229910052622 kaolinite Inorganic materials 0.000 description 2
- CYPPCCJJKNISFK-UHFFFAOYSA-J kaolinite Chemical compound [OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[O-][Si](=O)O[Si]([O-])=O CYPPCCJJKNISFK-UHFFFAOYSA-J 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- UKJARPDLRWBRAX-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine Chemical compound C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 UKJARPDLRWBRAX-UHFFFAOYSA-N 0.000 description 2
- 229930014626 natural product Natural products 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 description 2
- 150000002843 nonmetals Chemical class 0.000 description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 2
- 229910052625 palygorskite Inorganic materials 0.000 description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- 230000037048 polymerization activity Effects 0.000 description 2
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 229910052706 scandium Inorganic materials 0.000 description 2
- WFSPUOYRSOLZIS-UHFFFAOYSA-N silane zirconium Chemical compound [SiH4].[Zr] WFSPUOYRSOLZIS-UHFFFAOYSA-N 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 125000004434 sulfur atom Chemical group 0.000 description 2
- 229920001576 syndiotactic polymer Polymers 0.000 description 2
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 2
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- CWBIFDGMOSWLRQ-UHFFFAOYSA-N trimagnesium;hydroxy(trioxido)silane;hydrate Chemical compound O.[Mg+2].[Mg+2].[Mg+2].O[Si]([O-])([O-])[O-].O[Si]([O-])([O-])[O-] CWBIFDGMOSWLRQ-UHFFFAOYSA-N 0.000 description 2
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical group C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- QGMCRJZYVLHHHB-UHFFFAOYSA-N (1,2,2,6,6-pentamethylpiperidin-4-yl) octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 QGMCRJZYVLHHHB-UHFFFAOYSA-N 0.000 description 1
- YEYCMBWKTZNPDH-UHFFFAOYSA-N (2,2,6,6-tetramethylpiperidin-4-yl) benzoate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)C1=CC=CC=C1 YEYCMBWKTZNPDH-UHFFFAOYSA-N 0.000 description 1
- JMUOXOJMXILBTE-UHFFFAOYSA-N (2,2,6,6-tetramethylpiperidin-4-yl) octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 JMUOXOJMXILBTE-UHFFFAOYSA-N 0.000 description 1
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
- RGASRBUYZODJTG-UHFFFAOYSA-N 1,1-bis(2,4-ditert-butylphenyl)-2,2-bis(hydroxymethyl)propane-1,3-diol dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C RGASRBUYZODJTG-UHFFFAOYSA-N 0.000 description 1
- APQIUTYORBAGEZ-UHFFFAOYSA-N 1,1-dibromoethane Chemical compound CC(Br)Br APQIUTYORBAGEZ-UHFFFAOYSA-N 0.000 description 1
- XIMWQAKEMQUMTK-UHFFFAOYSA-N 1,2,3,4,5,5-hexamethylcyclopenta-1,3-diene Chemical compound CC1=C(C)C(C)(C)C(C)=C1C XIMWQAKEMQUMTK-UHFFFAOYSA-N 0.000 description 1
- KEIFWROAQVVDBN-UHFFFAOYSA-N 1,2-dihydronaphthalene Chemical compound C1=CC=C2C=CCCC2=C1 KEIFWROAQVVDBN-UHFFFAOYSA-N 0.000 description 1
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 1
- OSIHYASBAJHECK-UHFFFAOYSA-L 1,2-dimethylcyclopenta-1,3-diene;zirconium(4+);dichloride Chemical compound [Cl-].[Cl-].[Zr+4].CC1=C(C)[C-]=CC1.CC1=C(C)[C-]=CC1 OSIHYASBAJHECK-UHFFFAOYSA-L 0.000 description 1
- MYMKXVFDVQUQLG-UHFFFAOYSA-N 1,3,7,9-tetratert-butyl-11-fluoro-5-methyl-5h-benzo[d][1,3,2]benzodioxaphosphocine Chemical compound CC1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP(F)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C MYMKXVFDVQUQLG-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- BDGQFHLWTLKCHD-UHFFFAOYSA-N 1-N'-butyl-1-N'-(1,2,2,6,6-pentamethylpiperidin-4-yl)-1-N-(1,3,5-triazin-2-yl)undecane-1,1-diamine Chemical compound C(CCC)N(C1CC(N(C(C1)(C)C)C)(C)C)C(CCCCCCCCCC)NC1=NC=NC=N1 BDGQFHLWTLKCHD-UHFFFAOYSA-N 0.000 description 1
- RHZKURUHABLFKQ-UHFFFAOYSA-N 1-N'-butyl-1-N'-(2,2,6,6-tetramethylpiperidin-4-yl)-1-(1,3,5-triazin-2-yl)undecane-1,1-diamine Chemical compound C(CCC)N(C1CC(NC(C1)(C)C)(C)C)C(CCCCCCCCCC)(N)C1=NC=NC=N1 RHZKURUHABLFKQ-UHFFFAOYSA-N 0.000 description 1
- DLKQHBOKULLWDQ-UHFFFAOYSA-N 1-bromonaphthalene Chemical compound C1=CC=C2C(Br)=CC=CC2=C1 DLKQHBOKULLWDQ-UHFFFAOYSA-N 0.000 description 1
- XRPKZMVAXPQSCL-UHFFFAOYSA-N 1-cyclopenta-1,3-dien-1-ylethanone Chemical compound CC(=O)C1=CC=CC1 XRPKZMVAXPQSCL-UHFFFAOYSA-N 0.000 description 1
- ZIACSQWFETZIFO-UHFFFAOYSA-N 1-cyclopenta-1,3-dien-1-ylpropan-1-one Chemical compound CCC(=O)C1=CC=CC1 ZIACSQWFETZIFO-UHFFFAOYSA-N 0.000 description 1
- APWZAIZNWQFZBK-UHFFFAOYSA-N 1-ethoxynaphthalene Chemical compound C1=CC=C2C(OCC)=CC=CC2=C1 APWZAIZNWQFZBK-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- MSCMTEUGNSACKQ-UHFFFAOYSA-N 1-piperidin-4-yloxycarbonylbutane-1,1,2-tricarboxylic acid Chemical compound CCC(C(=O)O)C(C(=O)O)(C(=O)O)C(=O)OC1CCNCC1 MSCMTEUGNSACKQ-UHFFFAOYSA-N 0.000 description 1
- RZPAXISDLOEXPI-UHFFFAOYSA-N 1-propylcyclopenta-1,3-diene Chemical group CCCC1=CC=CC1 RZPAXISDLOEXPI-UHFFFAOYSA-N 0.000 description 1
- IKMBXKGUMLSBOT-UHFFFAOYSA-M 2,3,4,5,6-pentafluorobenzenesulfonate Chemical compound [O-]S(=O)(=O)C1=C(F)C(F)=C(F)C(F)=C1F IKMBXKGUMLSBOT-UHFFFAOYSA-M 0.000 description 1
- BSYJHYLAMMJNRC-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-ol Chemical compound CC(C)(C)CC(C)(C)O BSYJHYLAMMJNRC-UHFFFAOYSA-N 0.000 description 1
- PFEFOYRSMXVNEL-UHFFFAOYSA-N 2,4,6-tritert-butylphenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 PFEFOYRSMXVNEL-UHFFFAOYSA-N 0.000 description 1
- NWYNDVYHFKEDQU-UHFFFAOYSA-N 2-(2,2,6,6-tetramethylpiperidin-4-yl)butane-1,1,1,2-tetracarboxylic acid Chemical compound OC(=O)C(C(O)=O)(C(O)=O)C(CC)(C(O)=O)C1CC(C)(C)NC(C)(C)C1 NWYNDVYHFKEDQU-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- UUINYPIVWRZHAG-UHFFFAOYSA-N 2-(4,6-diphenyl-1,3,5-triazin-2-yl)-5-methoxyphenol Chemical compound OC1=CC(OC)=CC=C1C1=NC(C=2C=CC=CC=2)=NC(C=2C=CC=CC=2)=N1 UUINYPIVWRZHAG-UHFFFAOYSA-N 0.000 description 1
- CASASSNKDLUUEN-UHFFFAOYSA-N 2-[1-oxo-1-(1,2,2,6,6-pentamethylpiperidin-4-yl)oxy-3-(1,2,2,6,6-pentamethylpiperidin-4-yl)oxycarbonylhexadecan-3-yl]-2-tridecylbutanedioic acid Chemical compound CCCCCCCCCCCCCC(CC(O)=O)(C(CCCCCCCCCCCCC)(CC(OC1CC(C)(C)N(C)C(C)(C)C1)=O)C(OC1CC(C)(C)N(C)C(C)(C)C1)=O)C(O)=O CASASSNKDLUUEN-UHFFFAOYSA-N 0.000 description 1
- CFYIDYJMMLPAIK-UHFFFAOYSA-N 2-[2,4-bis(2-methylbutan-2-yl)phenyl]-3,5-ditert-butyl-4-hydroxybenzoic acid Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC=C1C1=C(C(O)=O)C=C(C(C)(C)C)C(O)=C1C(C)(C)C CFYIDYJMMLPAIK-UHFFFAOYSA-N 0.000 description 1
- OVFNLCOUYWXMMV-UHFFFAOYSA-N 2-tert-butyl-4-[14-(5-tert-butyl-4-hydroxy-2-methylphenyl)-17,17-di(tridecyl)triacontan-14-yl]-5-methylphenol dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(CCCCCCCCCCCCC)(CCC(CCCCCCCCCCCCC)(CCCCCCCCCCCCC)CCCCCCCCCCCCC)C1=CC(C(C)(C)C)=C(O)C=C1C OVFNLCOUYWXMMV-UHFFFAOYSA-N 0.000 description 1
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- SHDUFLICMXOBPA-UHFFFAOYSA-N 3,9-bis(2,4,6-tritert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(C(C)(C)C)=C1OP1OCC2(COP(OC=3C(=CC(=CC=3C(C)(C)C)C(C)(C)C)C(C)(C)C)OC2)CO1 SHDUFLICMXOBPA-UHFFFAOYSA-N 0.000 description 1
- WBWXVCMXGYSMQA-UHFFFAOYSA-N 3,9-bis[2,4-bis(2-phenylpropan-2-yl)phenoxy]-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C=1C=C(OP2OCC3(CO2)COP(OC=2C(=CC(=CC=2)C(C)(C)C=2C=CC=CC=2)C(C)(C)C=2C=CC=CC=2)OC3)C(C(C)(C)C=2C=CC=CC=2)=CC=1C(C)(C)C1=CC=CC=C1 WBWXVCMXGYSMQA-UHFFFAOYSA-N 0.000 description 1
- YGMBONASMVDXEN-UHFFFAOYSA-N 3-(benzotriazol-2-yl)-5-tert-butyl-4-hydroxybenzoic acid Chemical compound CC(C)(C)C1=CC(C(O)=O)=CC(N2N=C3C=CC=CC3=N2)=C1O YGMBONASMVDXEN-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- HPFWYRKGZUGGPB-UHFFFAOYSA-N 4,6-dichloro-n-(2,4,4-trimethylpentan-2-yl)-1,3,5-triazin-2-amine Chemical compound CC(C)(C)CC(C)(C)NC1=NC(Cl)=NC(Cl)=N1 HPFWYRKGZUGGPB-UHFFFAOYSA-N 0.000 description 1
- UQAMDAUJTXFNAD-UHFFFAOYSA-N 4-(4,6-dichloro-1,3,5-triazin-2-yl)morpholine Chemical compound ClC1=NC(Cl)=NC(N2CCOCC2)=N1 UQAMDAUJTXFNAD-UHFFFAOYSA-N 0.000 description 1
- STEYNUVPFMIUOY-UHFFFAOYSA-N 4-Hydroxy-1-(2-hydroxyethyl)-2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CC(O)CC(C)(C)N1CCO STEYNUVPFMIUOY-UHFFFAOYSA-N 0.000 description 1
- QWJWPDHACGGABF-UHFFFAOYSA-N 5,5-dimethylcyclopenta-1,3-diene Chemical compound CC1(C)C=CC=C1 QWJWPDHACGGABF-UHFFFAOYSA-N 0.000 description 1
- UWSMKYBKUPAEJQ-UHFFFAOYSA-N 5-Chloro-2-(3,5-di-tert-butyl-2-hydroxyphenyl)-2H-benzotriazole Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O UWSMKYBKUPAEJQ-UHFFFAOYSA-N 0.000 description 1
- OWXXKGVQBCBSFJ-UHFFFAOYSA-N 6-n-[3-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]-[2-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]-[3-[[4,6-bis[butyl-(1,2,2,6,6-pentamethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]ami Chemical compound N=1C(NCCCN(CCN(CCCNC=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)C=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)C=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)=NC(N(CCCC)C2CC(C)(C)N(C)C(C)(C)C2)=NC=1N(CCCC)C1CC(C)(C)N(C)C(C)(C)C1 OWXXKGVQBCBSFJ-UHFFFAOYSA-N 0.000 description 1
- HNKNVHRXMLUJGX-UHFFFAOYSA-N 6-n-[3-[[4,6-bis[butyl-(2,2,6,6-tetramethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]-[2-[[4,6-bis[butyl-(2,2,6,6-tetramethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]-[3-[[4,6-bis[butyl-(2,2,6,6-tetramethylpiperidin-4-yl)amino]-1,3,5-triazin-2-yl]amino]pro Chemical compound N=1C(NCCCN(CCN(CCCNC=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)NC(C)(C)C2)N(CCCC)C2CC(C)(C)NC(C)(C)C2)C=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)NC(C)(C)C2)N(CCCC)C2CC(C)(C)NC(C)(C)C2)C=2N=C(N=C(N=2)N(CCCC)C2CC(C)(C)NC(C)(C)C2)N(CCCC)C2CC(C)(C)NC(C)(C)C2)=NC(N(CCCC)C2CC(C)(C)NC(C)(C)C2)=NC=1N(CCCC)C1CC(C)(C)NC(C)(C)C1 HNKNVHRXMLUJGX-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical class [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- WPDAVTSOEQEGMS-UHFFFAOYSA-N 9,10-dihydroanthracene Chemical compound C1=CC=C2CC3=CC=CC=C3CC2=C1 WPDAVTSOEQEGMS-UHFFFAOYSA-N 0.000 description 1
- PQJUJGAVDBINPI-UHFFFAOYSA-N 9H-thioxanthene Chemical compound C1=CC=C2CC3=CC=CC=C3SC2=C1 PQJUJGAVDBINPI-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 1
- 239000007848 Bronsted acid Substances 0.000 description 1
- ZUKISFQHJPRJGF-UHFFFAOYSA-N C(C)[Zr](C1C=CC=C1)C1C(=C(C(=C1C)C)C)C Chemical compound C(C)[Zr](C1C=CC=C1)C1C(=C(C(=C1C)C)C)C ZUKISFQHJPRJGF-UHFFFAOYSA-N 0.000 description 1
- ZGUJLGOYHFQXIB-UHFFFAOYSA-N C(C1=CC=CC=C1)[Zr]CC1=CC=CC=C1.C[SiH](C1C(=C(C(=C1C)C)C)C)C Chemical compound C(C1=CC=CC=C1)[Zr]CC1=CC=CC=C1.C[SiH](C1C(=C(C(=C1C)C)C)C)C ZGUJLGOYHFQXIB-UHFFFAOYSA-N 0.000 description 1
- OKFODUJKKYIZDV-UHFFFAOYSA-N C(CC)[N-]CCC.C(CC)[N-]CCC.C(CC)[N-]CCC.C1(C=CC2=CC=CC=C12)[Zr+3] Chemical compound C(CC)[N-]CCC.C(CC)[N-]CCC.C(CC)[N-]CCC.C1(C=CC2=CC=CC=C12)[Zr+3] OKFODUJKKYIZDV-UHFFFAOYSA-N 0.000 description 1
- SRKQBIWCHCXGOJ-UHFFFAOYSA-N C1(=CC=CC=C1)[Si](C1=CC=CC=C1)(C1=CC=CC=C1)[Zr]C Chemical compound C1(=CC=CC=C1)[Si](C1=CC=CC=C1)(C1=CC=CC=C1)[Zr]C SRKQBIWCHCXGOJ-UHFFFAOYSA-N 0.000 description 1
- ZVSYRGCAFXIXDJ-UHFFFAOYSA-N C1(C=CC=C1)[Zr](C)([Si](C)(C)C)C1C=CC=C1 Chemical compound C1(C=CC=C1)[Zr](C)([Si](C)(C)C)C1C=CC=C1 ZVSYRGCAFXIXDJ-UHFFFAOYSA-N 0.000 description 1
- FTPSFIFDLWZNOL-UHFFFAOYSA-N C1(C=CC=C1)[Zr](CC1=CC=CC=C1)([Si](C)(C)C)C1C=CC=C1 Chemical compound C1(C=CC=C1)[Zr](CC1=CC=CC=C1)([Si](C)(C)C)C1C=CC=C1 FTPSFIFDLWZNOL-UHFFFAOYSA-N 0.000 description 1
- LPTOEGJQHOZZFC-UHFFFAOYSA-N C1(C=CC=C1)[Zr](C[Si](C)(C)C)([Si](C)(C)C)C1C=CC=C1 Chemical compound C1(C=CC=C1)[Zr](C[Si](C)(C)C)([Si](C)(C)C)C1C=CC=C1 LPTOEGJQHOZZFC-UHFFFAOYSA-N 0.000 description 1
- YYDKZOGGRJOZSV-UHFFFAOYSA-N C1(C=CC=C1)[Zr]([Si](C)(C)C)C1C=CC=C1 Chemical compound C1(C=CC=C1)[Zr]([Si](C)(C)C)C1C=CC=C1 YYDKZOGGRJOZSV-UHFFFAOYSA-N 0.000 description 1
- JCBHGTBOAGRXKA-UHFFFAOYSA-N C1(C=CC=C1)[Zr]C1(C(=C(C(=C1)C)C)C)C Chemical compound C1(C=CC=C1)[Zr]C1(C(=C(C(=C1)C)C)C)C JCBHGTBOAGRXKA-UHFFFAOYSA-N 0.000 description 1
- AGKZDUBMFACJPR-UHFFFAOYSA-L C12=CC=CC=C2C2=CC=CC=C2C1[Zr](Cl)(Cl)(=C(C)C)C1C=CC=C1 Chemical compound C12=CC=CC=C2C2=CC=CC=C2C1[Zr](Cl)(Cl)(=C(C)C)C1C=CC=C1 AGKZDUBMFACJPR-UHFFFAOYSA-L 0.000 description 1
- RQDMEYLMEMRZME-UHFFFAOYSA-N C=1C=CC=CC=1C[Zr]CC1=CC=CC=C1 Chemical compound C=1C=CC=CC=1C[Zr]CC1=CC=CC=C1 RQDMEYLMEMRZME-UHFFFAOYSA-N 0.000 description 1
- CPNALZXLUFBDPN-UHFFFAOYSA-N C=C.C1=CC2=CC=CC=C2C1[Zr]C1C2=CC=CC=C2C=C1 Chemical compound C=C.C1=CC2=CC=CC=C2C1[Zr]C1C2=CC=CC=C2C=C1 CPNALZXLUFBDPN-UHFFFAOYSA-N 0.000 description 1
- XJTQEAXBIXXILJ-UHFFFAOYSA-L CC(C)=[Zr](Cl)(Cl)(C1C=CC=C1)C1=CC=CC2=C1CC1=CC=CC=C21 Chemical compound CC(C)=[Zr](Cl)(Cl)(C1C=CC=C1)C1=CC=CC2=C1CC1=CC=CC=C21 XJTQEAXBIXXILJ-UHFFFAOYSA-L 0.000 description 1
- GHUNGDAEQRFFMV-UHFFFAOYSA-L CC(C)=[Zr](Cl)(Cl)(C1C=CC=C1)C1C=CC=C1 Chemical compound CC(C)=[Zr](Cl)(Cl)(C1C=CC=C1)C1C=CC=C1 GHUNGDAEQRFFMV-UHFFFAOYSA-L 0.000 description 1
- PYLJALCCEVZPPL-UHFFFAOYSA-N CC(C)C1=CC(C(C(C)=C2)[Zr](C)(C(C(C)=C3)C4=C3C(C(C)C)=CC(C(C)C)=C4)[SiH2]C3=CC=CC=C3)=C2C(C(C)C)=C1.Cl.Cl Chemical compound CC(C)C1=CC(C(C(C)=C2)[Zr](C)(C(C(C)=C3)C4=C3C(C(C)C)=CC(C(C)C)=C4)[SiH2]C3=CC=CC=C3)=C2C(C(C)C)=C1.Cl.Cl PYLJALCCEVZPPL-UHFFFAOYSA-N 0.000 description 1
- BCAJCQNTAVAVGU-UHFFFAOYSA-K CC1(C(C)=C(C)C(C)=C1)[SiH](C)C.[NH-]CC1=CC=CC=C1.[Cl-].[Cl-].[Cl-].Cl.[Zr+4] Chemical compound CC1(C(C)=C(C)C(C)=C1)[SiH](C)C.[NH-]CC1=CC=CC=C1.[Cl-].[Cl-].[Cl-].Cl.[Zr+4] BCAJCQNTAVAVGU-UHFFFAOYSA-K 0.000 description 1
- LHHAUUVITWQDQI-UHFFFAOYSA-L CC1=C(C)C(C)(C(C)=C1C)[Zr](Cl)(Cl)C1C=CC=C1 Chemical compound CC1=C(C)C(C)(C(C)=C1C)[Zr](Cl)(Cl)C1C=CC=C1 LHHAUUVITWQDQI-UHFFFAOYSA-L 0.000 description 1
- OXLXAPYJCPFBFT-UHFFFAOYSA-L CC1=CC(C)(C=C1)[Zr](Cl)(Cl)C1(C)C=CC(C)=C1 Chemical compound CC1=CC(C)(C=C1)[Zr](Cl)(Cl)C1(C)C=CC(C)=C1 OXLXAPYJCPFBFT-UHFFFAOYSA-L 0.000 description 1
- HIJNJTBRRQPINW-UHFFFAOYSA-L CC1=CC=C(C=C1)S(=O)(=O)[O-].CC1=CC=C(C=C1)S(=O)(=O)[O-].C1(C=CC=C1)[Zr+2]C1C=CC=C1 Chemical compound CC1=CC=C(C=C1)S(=O)(=O)[O-].CC1=CC=C(C=C1)S(=O)(=O)[O-].C1(C=CC=C1)[Zr+2]C1C=CC=C1 HIJNJTBRRQPINW-UHFFFAOYSA-L 0.000 description 1
- XUVJWPHRYPZAJW-UHFFFAOYSA-N CCCC.OP(O)O.OP(O)O.OP(O)O Chemical compound CCCC.OP(O)O.OP(O)O.OP(O)O XUVJWPHRYPZAJW-UHFFFAOYSA-N 0.000 description 1
- BEMMTNKEKWCPAI-UHFFFAOYSA-N CC[Zr](C1C=CC=C1)C1C=CC=C1 Chemical compound CC[Zr](C1C=CC=C1)C1C=CC=C1 BEMMTNKEKWCPAI-UHFFFAOYSA-N 0.000 description 1
- UXGOWQHFCBIPLK-UHFFFAOYSA-L CC[Zr](Cl)(Cl)(C1C=CC=C1)C1C=CC=C1 Chemical compound CC[Zr](Cl)(Cl)(C1C=CC=C1)C1C=CC=C1 UXGOWQHFCBIPLK-UHFFFAOYSA-L 0.000 description 1
- MPJLHVOQWLKMRN-UHFFFAOYSA-L C[SiH](C)[Zr](Cl)(Cl)(C1C=CC=C1)C1c2ccccc2-c2ccccc12 Chemical compound C[SiH](C)[Zr](Cl)(Cl)(C1C=CC=C1)C1c2ccccc2-c2ccccc12 MPJLHVOQWLKMRN-UHFFFAOYSA-L 0.000 description 1
- VWOTWOPAYZNLIU-UHFFFAOYSA-L C[SiH]C.Cl[Zr](Cl)(C1C=CC=C1)C1C=CC=C1 Chemical compound C[SiH]C.Cl[Zr](Cl)(C1C=CC=C1)C1C=CC=C1 VWOTWOPAYZNLIU-UHFFFAOYSA-L 0.000 description 1
- OXYKMNKFNWHIPQ-UHFFFAOYSA-N C[Zr](C)(C1C=CC=C1)C1C=CC=C1.Cl.Cl Chemical compound C[Zr](C)(C1C=CC=C1)C1C=CC=C1.Cl.Cl OXYKMNKFNWHIPQ-UHFFFAOYSA-N 0.000 description 1
- NVZOLHDRKMPIRA-UHFFFAOYSA-L C[Zr](Cl)(Cl)(C1C=CC=C1)C1C=CC=C1 Chemical compound C[Zr](Cl)(Cl)(C1C=CC=C1)C1C=CC=C1 NVZOLHDRKMPIRA-UHFFFAOYSA-L 0.000 description 1
- HRCNWDPGYQRDAF-UHFFFAOYSA-N C[Zr]C1C=CC=C1 Chemical compound C[Zr]C1C=CC=C1 HRCNWDPGYQRDAF-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- LDKQIYIAJNASMS-UHFFFAOYSA-L Cl[Zr](Cl)(=C)(C1C=CC=C1)C1C=CC=C1 Chemical compound Cl[Zr](Cl)(=C)(C1C=CC=C1)C1C=CC=C1 LDKQIYIAJNASMS-UHFFFAOYSA-L 0.000 description 1
- 229920001651 Cyanoacrylate Polymers 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 1
- 229910052692 Dysprosium Inorganic materials 0.000 description 1
- 229910052691 Erbium Inorganic materials 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- HRKDNCWZNBPNLR-UHFFFAOYSA-N FC(F)(F)C1(C=CC=C1)[Zr]C1(C=CC=C1)C(F)(F)F Chemical compound FC(F)(F)C1(C=CC=C1)[Zr]C1(C=CC=C1)C(F)(F)F HRKDNCWZNBPNLR-UHFFFAOYSA-N 0.000 description 1
- NTCFODQKHHRWIT-UHFFFAOYSA-N FC(F)(F)[Zr](C1C=CC=C1)C1C=CC=C1 Chemical compound FC(F)(F)[Zr](C1C=CC=C1)C1C=CC=C1 NTCFODQKHHRWIT-UHFFFAOYSA-N 0.000 description 1
- DACWJSISQYFKIP-UHFFFAOYSA-N FC(S(=O)(=O)OOCC)(F)F.C1(C=CC=C1)[Zr]C1C=CC=C1 Chemical compound FC(S(=O)(=O)OOCC)(F)F.C1(C=CC=C1)[Zr]C1C=CC=C1 DACWJSISQYFKIP-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical class FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229910052689 Holmium Inorganic materials 0.000 description 1
- 239000002879 Lewis base Substances 0.000 description 1
- 229910052765 Lutetium Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 229910052781 Neptunium Inorganic materials 0.000 description 1
- XKHQQROWOLSGLJ-UHFFFAOYSA-N OC1=C(C(C)(C)C=2C=C(C=C(C2)N2N=C3C(=N2)C=CC=C3)C(C)(C)C3=CC=CC=C3)C=CC=C1.OC1=C(C=C(C=C1)C(C)(C)CC(C)(C)C)N1N=C3C(=N1)C=CC=C3 Chemical compound OC1=C(C(C)(C)C=2C=C(C=C(C2)N2N=C3C(=N2)C=CC=C3)C(C)(C)C3=CC=CC=C3)C=CC=C1.OC1=C(C=C(C=C1)C(C)(C)CC(C)(C)C)N1N=C3C(=N1)C=CC=C3 XKHQQROWOLSGLJ-UHFFFAOYSA-N 0.000 description 1
- QAEPIAHUOVJOOM-UHFFFAOYSA-N OP(O)OP(O)O.C(CCCCCCCC)C1=C(C=CC=C1)C(O)(C(CO)(CO)CO)C1=C(C=CC=C1)CCCCCCCCC Chemical compound OP(O)OP(O)O.C(CCCCCCCC)C1=C(C=CC=C1)C(O)(C(CO)(CO)CO)C1=C(C=CC=C1)CCCCCCCCC QAEPIAHUOVJOOM-UHFFFAOYSA-N 0.000 description 1
- MOABYHZDQQELLG-UHFFFAOYSA-N OP(O)OP(O)O.C(CCCCCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCCCCC Chemical compound OP(O)OP(O)O.C(CCCCCCCCCCCC)C(O)(C(CO)(CO)CO)CCCCCCCCCCCCC MOABYHZDQQELLG-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229910052774 Proactinium Inorganic materials 0.000 description 1
- DRFDPXKCEWYIAW-UHFFFAOYSA-M Risedronate sodium Chemical compound [Na+].OP(=O)(O)C(P(O)([O-])=O)(O)CC1=CC=CN=C1 DRFDPXKCEWYIAW-UHFFFAOYSA-M 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052771 Terbium Inorganic materials 0.000 description 1
- 229910052775 Thulium Inorganic materials 0.000 description 1
- SLGBZMMZGDRARJ-UHFFFAOYSA-N Triphenylene Natural products C1=CC=C2C3=CC=CC=C3C3=CC=CC=C3C2=C1 SLGBZMMZGDRARJ-UHFFFAOYSA-N 0.000 description 1
- 235000018936 Vitellaria paradoxa Nutrition 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- DCBNMBIOGUANTC-UHFFFAOYSA-N [5-[(5-benzoyl-4-hydroxy-2-methoxyphenyl)methyl]-2-hydroxy-4-methoxyphenyl]-phenylmethanone Chemical compound COC1=CC(O)=C(C(=O)C=2C=CC=CC=2)C=C1CC(C(=CC=1O)OC)=CC=1C(=O)C1=CC=CC=C1 DCBNMBIOGUANTC-UHFFFAOYSA-N 0.000 description 1
- YVNTUTUOQJXUOU-UHFFFAOYSA-L [Cl-].[Cl-].C(C)C1=C(C(=C(C1(C)[Zr+2]C1(C(=C(C(=C1CC)C)C)C)C)C)C)C Chemical compound [Cl-].[Cl-].C(C)C1=C(C(=C(C1(C)[Zr+2]C1(C(=C(C(=C1CC)C)C)C)C)C)C)C YVNTUTUOQJXUOU-UHFFFAOYSA-L 0.000 description 1
- LBKBUQUIRJQWLH-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)CC=[Zr+2](C1C=CC=C1)C1C2=CC=CC=C2C=2C=CC=CC1=2 Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)CC=[Zr+2](C1C=CC=C1)C1C2=CC=CC=C2C=2C=CC=CC1=2 LBKBUQUIRJQWLH-UHFFFAOYSA-L 0.000 description 1
- UWCVVTLRDNFXER-UHFFFAOYSA-L [Cl-].[Cl-].C1(C=CC=C1)[Zr+2]C1(C(=C(C=C1)C)C)C Chemical compound [Cl-].[Cl-].C1(C=CC=C1)[Zr+2]C1(C(=C(C=C1)C)C)C UWCVVTLRDNFXER-UHFFFAOYSA-L 0.000 description 1
- NOQWABVRFAHTQD-UHFFFAOYSA-L [Cl-].[Cl-].C12=CC=CCC2CCC1[Zr+2]C1C2=CC=CCC2CC1 Chemical compound [Cl-].[Cl-].C12=CC=CCC2CCC1[Zr+2]C1C2=CC=CCC2CC1 NOQWABVRFAHTQD-UHFFFAOYSA-L 0.000 description 1
- NWBSMOHZFZYBLB-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2](=C(C)C)C1C2=CC=CC=C2C=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2](=C(C)C)C1C2=CC=CC=C2C=C1 NWBSMOHZFZYBLB-UHFFFAOYSA-L 0.000 description 1
- DHOIFLAXQKMNNF-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2](C1C2=CC=CC=C2C=C1)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2](C1C2=CC=CC=C2C=C1)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 DHOIFLAXQKMNNF-UHFFFAOYSA-L 0.000 description 1
- DPXFROCZZRXAGW-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]([GeH](C)C)C1C2=CC=CC=C2C=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]([GeH](C)C)C1C2=CC=CC=C2C=C1 DPXFROCZZRXAGW-UHFFFAOYSA-L 0.000 description 1
- FJMJPZLXUXRLLD-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1 FJMJPZLXUXRLLD-UHFFFAOYSA-L 0.000 description 1
- RLEZACANRPOGPQ-UHFFFAOYSA-L [Cl-].[Cl-].C1CC2CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CCC2CC1 Chemical compound [Cl-].[Cl-].C1CC2CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CCC2CC1 RLEZACANRPOGPQ-UHFFFAOYSA-L 0.000 description 1
- AWXKEFJIQBQSSC-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC(C)([Zr++]C2(C)C=C(C)C(C)=C2)C=C1C Chemical compound [Cl-].[Cl-].CC1=CC(C)([Zr++]C2(C)C=C(C)C(C)=C2)C=C1C AWXKEFJIQBQSSC-UHFFFAOYSA-L 0.000 description 1
- XRMLSJOTMSZVND-UHFFFAOYSA-L [Cl-].[Cl-].CC1=CC=CC1(C)[Zr++]C1(C)C=CC=C1C Chemical compound [Cl-].[Cl-].CC1=CC=CC1(C)[Zr++]C1(C)C=CC=C1C XRMLSJOTMSZVND-UHFFFAOYSA-L 0.000 description 1
- PCGLKNXWLGQMKK-UHFFFAOYSA-L [Cl-].[Cl-].CC=1C(=C(C(C1)(C)[Zr+3]=C)C)C.C(C)[NH-] Chemical compound [Cl-].[Cl-].CC=1C(=C(C(C1)(C)[Zr+3]=C)C)C.C(C)[NH-] PCGLKNXWLGQMKK-UHFFFAOYSA-L 0.000 description 1
- AGOQJVFOUDVVEZ-UHFFFAOYSA-L [Cl-].[Cl-].C[SiH](C)[Zr++](C1C(C)=Cc2c1cc(C)cc2C)C1C(C)=Cc2c1cc(C)cc2C Chemical compound [Cl-].[Cl-].C[SiH](C)[Zr++](C1C(C)=Cc2c1cc(C)cc2C)C1C(C)=Cc2c1cc(C)cc2C AGOQJVFOUDVVEZ-UHFFFAOYSA-L 0.000 description 1
- XCLXCDFTDRJVTQ-UHFFFAOYSA-L [Cl-].[Cl-].FC(F)(F)[Zr+2](C1C=CC=C1)C1C=CC=C1 Chemical compound [Cl-].[Cl-].FC(F)(F)[Zr+2](C1C=CC=C1)C1C=CC=C1 XCLXCDFTDRJVTQ-UHFFFAOYSA-L 0.000 description 1
- YQBHNIGHIXUSAO-UHFFFAOYSA-K [Cl-].[Cl-].[Cl-].FC(F)(F)C1(C=CC=C1)[Zr+3]C1(C=CC=C1)C(F)(F)F Chemical compound [Cl-].[Cl-].[Cl-].FC(F)(F)C1(C=CC=C1)[Zr+3]C1(C=CC=C1)C(F)(F)F YQBHNIGHIXUSAO-UHFFFAOYSA-K 0.000 description 1
- OKPFRHMGNFRBIW-UHFFFAOYSA-L [SiH](c1ccccc1)c1ccccc1.Cl[Zr](Cl)(C1C=CC=C1)C1c2ccccc2-c2ccccc12 Chemical compound [SiH](c1ccccc1)c1ccccc1.Cl[Zr](Cl)(C1C=CC=C1)C1c2ccccc2-c2ccccc12 OKPFRHMGNFRBIW-UHFFFAOYSA-L 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 229910052768 actinide Inorganic materials 0.000 description 1
- 150000001255 actinides Chemical class 0.000 description 1
- 229910052767 actinium Inorganic materials 0.000 description 1
- QQINRWTZWGJFDB-UHFFFAOYSA-N actinium atom Chemical compound [Ac] QQINRWTZWGJFDB-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000012773 agricultural material Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910001583 allophane Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- 125000000649 benzylidene group Chemical group [H]C(=[*])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 description 1
- RSOILICUEWXSLA-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 RSOILICUEWXSLA-UHFFFAOYSA-N 0.000 description 1
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-HORUIINNSA-N bis[cyclopentadiene] Chemical compound C1C2[C@H]3CC=C[C@H]3C1C=C2 HECLRDQVFMWTQS-HORUIINNSA-N 0.000 description 1
- 238000012661 block copolymerization Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical class BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- 125000004063 butyryl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- KDKNVCQXFIBDBD-UHFFFAOYSA-N carbanide;1,2,3,4,5-pentamethylcyclopentane;zirconium(2+) Chemical group [CH3-].[CH3-].[Zr+2].C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]1[C](C)[C](C)[C](C)[C]1C KDKNVCQXFIBDBD-UHFFFAOYSA-N 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910001919 chlorite Inorganic materials 0.000 description 1
- 229910052619 chlorite group Inorganic materials 0.000 description 1
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
- QZHPTGXQGDFGEN-UHFFFAOYSA-N chromene Chemical compound C1=CC=C2C=C[CH]OC2=C1 QZHPTGXQGDFGEN-UHFFFAOYSA-N 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- NLCKLZIHJQEMCU-UHFFFAOYSA-N cyano prop-2-enoate Chemical class C=CC(=O)OC#N NLCKLZIHJQEMCU-UHFFFAOYSA-N 0.000 description 1
- RBCCTANMTRBHDT-UHFFFAOYSA-N cyclopenta-1,3-dien-1-yl(phenyl)methanone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC1 RBCCTANMTRBHDT-UHFFFAOYSA-N 0.000 description 1
- KTPNQKDTYCBNCC-UHFFFAOYSA-N cyclopenta-1,3-diene-1-carbonitrile Chemical compound N#CC1=CC=CC1 KTPNQKDTYCBNCC-UHFFFAOYSA-N 0.000 description 1
- PBEWNPDBTAIIFH-UHFFFAOYSA-L cyclopenta-1,3-diene;oxolane;trifluoromethanesulfonate;zirconium(4+) Chemical compound [Zr+4].C1CCOC1.C=1C=C[CH-]C=1.C=1C=C[CH-]C=1.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F PBEWNPDBTAIIFH-UHFFFAOYSA-L 0.000 description 1
- QRUYYSPCOGSZGQ-UHFFFAOYSA-L cyclopentane;dichlorozirconium Chemical compound Cl[Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1 QRUYYSPCOGSZGQ-UHFFFAOYSA-L 0.000 description 1
- SSLYIXHGTXGSJZ-UHFFFAOYSA-L cyclopentane;dichlorozirconium;indene Chemical compound Cl[Zr]Cl.[CH]1[CH][CH][CH][CH]1.C1=CC=C[C]2[CH][CH][CH][C]21 SSLYIXHGTXGSJZ-UHFFFAOYSA-L 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000008121 dextrose Substances 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- TXCDCPKCNAJMEE-UHFFFAOYSA-N dibenzofuran Chemical compound C1=CC=C2C3=CC=CC=C3OC2=C1 TXCDCPKCNAJMEE-UHFFFAOYSA-N 0.000 description 1
- LBVWYGNGGJURHQ-UHFFFAOYSA-N dicarbon Chemical group [C-]#[C+] LBVWYGNGGJURHQ-UHFFFAOYSA-N 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- MIILMDFFARLWKZ-UHFFFAOYSA-L dichlorozirconium;1,2,3,4,5-pentamethylcyclopentane Chemical compound [Cl-].[Cl-].CC1=C(C)C(C)=C(C)C1(C)[Zr+2]C1(C)C(C)=C(C)C(C)=C1C MIILMDFFARLWKZ-UHFFFAOYSA-L 0.000 description 1
- IVTQDRJBWSBJQM-UHFFFAOYSA-L dichlorozirconium;indene Chemical compound C1=CC2=CC=CC=C2C1[Zr](Cl)(Cl)C1C2=CC=CC=C2C=C1 IVTQDRJBWSBJQM-UHFFFAOYSA-L 0.000 description 1
- NMAKPIATXQEXBT-UHFFFAOYSA-N didecyl phenyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OC1=CC=CC=C1 NMAKPIATXQEXBT-UHFFFAOYSA-N 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical group CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- UZBQIPPOMKBLAS-UHFFFAOYSA-N diethylazanide Chemical compound CC[N-]CC UZBQIPPOMKBLAS-UHFFFAOYSA-N 0.000 description 1
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 1
- ZCGNNESZWJPBLW-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite 2-[2-(2-hydroxyphenyl)propan-2-yl]-3,4,5,6-tetra(tridecyl)phenol Chemical compound OP(O)OP(O)O.CCCCCCCCCCCCCC1=C(CCCCCCCCCCCCC)C(CCCCCCCCCCCCC)=C(O)C(C(C)(C)C=2C(=CC=CC=2)O)=C1CCCCCCCCCCCCC ZCGNNESZWJPBLW-UHFFFAOYSA-N 0.000 description 1
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical group CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical group CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 1
- 125000006575 electron-withdrawing group Chemical group 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000005677 ethinylene group Chemical group [*:2]C#C[*:1] 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 125000004705 ethylthio group Chemical group C(C)S* 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- RMBPEFMHABBEKP-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2C3=C[CH]C=CC3=CC2=C1 RMBPEFMHABBEKP-UHFFFAOYSA-N 0.000 description 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Chemical class 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000002363 hafnium compounds Chemical class 0.000 description 1
- GVOLZAKHRKGRRM-UHFFFAOYSA-N hafnium(4+) Chemical compound [Hf+4] GVOLZAKHRKGRRM-UHFFFAOYSA-N 0.000 description 1
- VUVZASHBYYMLRC-UHFFFAOYSA-N heptane-2,3-diol Chemical compound CCCCC(O)C(C)O VUVZASHBYYMLRC-UHFFFAOYSA-N 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- NZYMWGXNIUZYRC-UHFFFAOYSA-N hexadecyl 3,5-ditert-butyl-4-hydroxybenzoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NZYMWGXNIUZYRC-UHFFFAOYSA-N 0.000 description 1
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical group C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 1
- 239000002815 homogeneous catalyst Substances 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 150000002443 hydroxylamines Chemical class 0.000 description 1
- GWWYBYNZFWRRSG-UHFFFAOYSA-N hydroxyphosphanyloxyphosphinous acid;1,2,3,4-tetrakis(2,4-ditert-butylphenyl)biphenylene Chemical compound OPOPO.CC(C)(C)C1=CC(C(C)(C)C)=CC=C1C(C(=C1C=2C(=CC(=CC=2)C(C)(C)C)C(C)(C)C)C=2C(=CC(=CC=2)C(C)(C)C)C(C)(C)C)=C(C=2C3=CC=CC=2)C3=C1C1=CC=C(C(C)(C)C)C=C1C(C)(C)C GWWYBYNZFWRRSG-UHFFFAOYSA-N 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910001867 inorganic solvent Inorganic materials 0.000 description 1
- 239000003049 inorganic solvent Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Chemical class 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 150000007527 lewis bases Chemical class 0.000 description 1
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052899 lizardite Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 235000011147 magnesium chloride Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 150000002696 manganese Chemical class 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- AQYCWSHDYILNJO-UHFFFAOYSA-N methyl 6-methyl-3-oxo-4h-1,4-benzoxazine-8-carboxylate Chemical compound N1C(=O)COC2=C1C=C(C)C=C2C(=O)OC AQYCWSHDYILNJO-UHFFFAOYSA-N 0.000 description 1
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 125000006606 n-butoxy group Chemical group 0.000 description 1
- 125000004708 n-butylthio group Chemical group C(CCC)S* 0.000 description 1
- XQOIBQBPAXOVGP-UHFFFAOYSA-N n-ethyl-2-methylpropan-2-amine Chemical group CCNC(C)(C)C XQOIBQBPAXOVGP-UHFFFAOYSA-N 0.000 description 1
- 125000001298 n-hexoxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000006608 n-octyloxy group Chemical group 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004712 n-pentylthio group Chemical group C(CCCC)S* 0.000 description 1
- 125000003506 n-propoxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004706 n-propylthio group Chemical group C(CC)S* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- ZCYXXKJEDCHMGH-UHFFFAOYSA-N nonane Chemical compound CCCC[CH]CCCC ZCYXXKJEDCHMGH-UHFFFAOYSA-N 0.000 description 1
- BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 1
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- AXRSHKZFNKUGQB-UHFFFAOYSA-N octyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCC)OC1=CC=CC=C1 AXRSHKZFNKUGQB-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000005580 one pot reaction Methods 0.000 description 1
- 238000000879 optical micrograph Methods 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 125000002097 pentamethylcyclopentadienyl group Chemical group 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical compound C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- DLRJIFUOBPOJNS-UHFFFAOYSA-N phenetole Chemical compound CCOC1=CC=CC=C1 DLRJIFUOBPOJNS-UHFFFAOYSA-N 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- XMGMFRIEKMMMSU-UHFFFAOYSA-N phenylmethylbenzene Chemical group C=1C=CC=CC=1[C]C1=CC=CC=C1 XMGMFRIEKMMMSU-UHFFFAOYSA-N 0.000 description 1
- 239000011990 phillips catalyst Substances 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- 125000005328 phosphinyl group Chemical group [PH2](=O)* 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
- XLROVYAPLOFLNU-UHFFFAOYSA-N protactinium atom Chemical compound [Pa] XLROVYAPLOFLNU-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- GDESWOTWNNGOMW-UHFFFAOYSA-N resorcinol monobenzoate Chemical compound OC1=CC=CC(OC(=O)C=2C=CC=CC=2)=C1 GDESWOTWNNGOMW-UHFFFAOYSA-N 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000008279 sol Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 229920000576 tactic polymer Polymers 0.000 description 1
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
- GVIJJXMXTUZIOD-UHFFFAOYSA-N thianthrene Chemical compound C1=CC=C2SC3=CC=CC=C3SC2=C1 GVIJJXMXTUZIOD-UHFFFAOYSA-N 0.000 description 1
- 125000005309 thioalkoxy group Chemical group 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- IBPRKWGSNXMCOI-UHFFFAOYSA-N trimagnesium;disilicate;hydrate Chemical compound O.[Mg+2].[Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IBPRKWGSNXMCOI-UHFFFAOYSA-N 0.000 description 1
- 229940030010 trimethoxybenzene Drugs 0.000 description 1
- 125000005580 triphenylene group Chemical group 0.000 description 1
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 description 1
- SGKKYCDALBXNCG-UHFFFAOYSA-N tris[2-tert-butyl-4-(3-tert-butyl-4-hydroxy-5-methylphenyl)sulfanyl-5-methylphenyl] phosphite Chemical compound CC(C)(C)C1=C(O)C(C)=CC(SC=2C(=CC(OP(OC=3C(=CC(SC=4C=C(C(O)=C(C)C=4)C(C)(C)C)=C(C)C=3)C(C)(C)C)OC=3C(=CC(SC=4C=C(C(O)=C(C)C=4)C(C)(C)C)=C(C)C=3)C(C)(C)C)=C(C=2)C(C)(C)C)C)=C1 SGKKYCDALBXNCG-UHFFFAOYSA-N 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
- QSGNKXDSTRDWKA-UHFFFAOYSA-N zirconium dihydride Chemical compound [ZrH2] QSGNKXDSTRDWKA-UHFFFAOYSA-N 0.000 description 1
- QMBQEXOLIRBNPN-UHFFFAOYSA-L zirconocene dichloride Chemical compound [Cl-].[Cl-].[Zr+4].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 QMBQEXOLIRBNPN-UHFFFAOYSA-L 0.000 description 1
Description
{[(R1 )(R2 M)a ]an+ an/q[LQm ]q-} (A)
〔式中、aは1又は2を表わし、そしてn及びqは互いに独立して、各々1ないし4の整数を表わし、Mは元素の周期律表の4族〜11族に属する一価ないし四価金属のカチオンを表わし、mは価L+qに相当する整数を表わし、Qはハロゲン原子を表わし、Lは二価ないし七価金属又は非金属を表わし、R1 はπ−アレーンを表わし、そしてR2 はπ−アレーン又はπ−アレーンのアニオンを表わす〕
で表わされる化合物である。特に適するπ−アレーンR1 及びR2 は、6個ないし24個の炭素原子を有する芳香族基又は3個ないし30個の炭素原子を有するヘテロ芳香族基であり、これらの基は、1回又はそれより多くの回数、同一又は異なる一価基、例えばハロゲン原子(好ましくは塩素原子又は臭素原子)、又は炭素原子数1ないし8のアルキル基、炭素原子数1ないし8のアルコキシ基、シアノ基、炭素原子数1ないし8のアルキルチオ基、炭素原子数2ないし6のモノカルボン酸アルキルエステル基、フェニル基、炭素原子数2ないし5のアルカノイル基又はベンゾイル基により置換されていてもよい。これらのπ−アレーン基は、単環式系,縮合多環式系又は非縮合多環式系であってよく、後者の系においては、環は直接又は架橋基、例えば−S−基又は−O−基を介して結合していてよい。π−アレーンのアニオンとしてのR2 は、上記種類π−アレーンのアニオン、例えばインデニルアニオン、及び特に、シクロペンタジエニルアニオンであってよく、前記アニオンも、1回又はそれより多くの回数、同一又は異なる一価基、例えば炭素原子数1ないし8のアルキル基、炭素原子数2ないし6のモノカルボン酸アルキルエステル基、シアノ基、炭素原子数2ないし5のアルカノイル基又はベンゾイル基により置換されていてもよい。
{[(R1 )(R2 M)a ]an+ an/q[X]q-} (B)
で表わされる化合物を、アニオン[LQm ]q-の塩と反応させることにより製造することができる〔ここで、a,m,n,q,R1 ,R2 ,M及びLは、式(A)で定義された意味と同じ意味を表わし、そして[X]q-は[LQm ]q-と異なるアニオンを表わす〕。
{[(R1 ′)(R2 M)a ]} (C)
で表わされる化合物の両方〔ここで、a及びMは上記で定義された意味と同じ意味を表わし、そしてR1 ′はπ−アレーン又はπ−アレーンのアニオンを表わし、そしてR2 はπ−アレーンのアニオンを表わす〕は、ルイス酸の存在下で、同一又は異なるπ−アレーンを、周期律表の4族〜11族に属する金属の塩と反応させることにより、製造することができる。式(A),(B)及び(C)で表わされる化合物も、ルイス酸の存在下で、これらの化合物をπ−アレーン〔これは、R1 及び/又はR2 、又はR1 ′と異なる〕と反応させることにより、配位子交換を行うために適している。これらの場合において、nは好ましくは2を表わし、そして特に好ましくは1を表わす。
a)アルミノキサン
使用されるアルミノキサンは、線状型としては、好ましくは次式(IV)で表わされる化合物であり、及び/又は環状型としては、好ましくは次式(V)で表わされる化合物であり、式(IV)及び(V)において、基Rは同一又は異なり、そして炭素原子数1ないし6のアルキル基、炭素原子数6ないし18のアリール基、ベンジル基又は水素原子を表わし、そしてpは2ないし50の整数、好ましくは10ないし35の整数を表わす。
(CpR1aH5-a)p(CpR2bH5-b)qMR3r [VI]
[(CpR1aH5-a)p(CpR2bH5-b)qMR3rLm]n+[R4] [VII]
(ここで、CpR1aH5-aおよびCpR2bH5-bは、シクロペンタジエニル(Cp)基の誘導体を示す。)
ビス(メチルシクロペンタジエニル)ジルコニウムジクロライド、ビス(エチルシクロペンタジエニル)ジルコニウムジクロライド、ビス(メチルシクロペンタジエニル)ジルコニウムジメチル、ビス(エチルシクロペンタジエニル)ジルコニウムジメチル、ビス(メチルシクロペンタジエニル)ジルコニウム二水素化物、ビス(エチルシクロペンタジエニル)ジルコニウム二水素化物、ビス(ジメチルシクロペンタジエニル)ジルコニウムジクロライド、ビス(トリメチルシクロペンタジエニル)ジルコニウムジクロライド、ビス(テトラメチルシクロペンタジエニル)ジルコニウムジクロライド、ビス(エチルテトラメチルシクロペンタジエニル)ジルコニウムジクロライド、ビス(インデニル)ジルコニウムジクロライド、ビス(ジメチルシクロペンタジエニル)ジルコニウムジメチル、ビス(トリメチルシクロペンタジエニル)ジルコニウムジメチル、ビス(テトラメチルシクロペンタジエニル)ジルコニウムジメチル、ビス(エチルテトラメチルシクロペンタジエニル)ジルコニウムジメチル、ビス(インデニル)ジルコニウムジメチル、ビス(ジメチルシクロペンタジエニル)ジルコニウム二水素化物、ビス(トリメチルシクロペンタジエニル)ジルコニウム二水素化物、ビス(エチルテトラメチルシクロペンタジエニル)ジルコニウム二水素化物、ビス(トリメチルシリルシクロペンタジエニル)ジルコニウムジメチル、ビス(トリメチルシリルシクロペンタジエニル)ジルコニウム二水素化物、ビス(トリフルオロメチルシクロペンタジエニル)ジルコニウムジクロライド、ビス(トリフルオロメチルシクロペンタジエニル)ジルコニウムジメチル、ビス(トリフルオロメチルシクロペンタジエニル)ジルコニウム二水素化物、イソプロピリデン−ビス(インデニル)ジルコニウムジクロライド
ビス(メチルシクロペンタジエニル)ジルコニウム(クロライド)(テトラフェニルボレート)テトラヒドロフラン錯体、ビス(エチルシクロペンタジエニル)ジルコニウム(クロライド)(テトラフェニルボレート)テトラヒドロフラン錯体、ビス(メチルシクロペンタジエニル)ジルコニウム(メチル)(テトラフェニルボレート)テトラヒドロフラン錯体、ビス(エチルシクロペンタジエニル)ジルコニウム(メチル)(テトラフェニルボレート)テトラヒドロフラン錯体、ビス(メチルシクロペンタジエニル)ジルコニウム(ヒドリド)(テトラフェニルボレート)テトラヒドロフラン錯体、ビス(エチルシクロペンタジエニル)ジルコニウム(ヒドリド)(テトラフェニルボレート)テトラヒドロフラン錯体、ビス(ジメチルシクロペンタジエニル)ジルコニウム(クロライド)(テトラフェニルボレート)テトラヒドロフラン錯体、ビス(トリメチルシクロペンタジエニル)ジルコニウム(クロライド)(テトラフェニルボレート)テトラヒドロフラン錯体、ビス(テトラメチルシクロペンタジエニル)ジルコニウム(クロライド)(テトラフェニルボレート)テトラヒドロフラン錯体、ビス(エチルテトラメチルシクロペンタジエニル)ジルコニウム(クロライド)(テトラフェニルボレート)テトラヒドロフラン錯体
(添加剤の前処理)
トルエン50mlにトリイソブチルアルミニウムと表1記載の安定剤を官能基のモル比で6:5となるように合計で5.0g加え室温で2時間撹拌することにより、触媒に対して不活性化した安定剤溶液を得た。
比較例1−1〜1−4は、トリイソブチルアルミニウム処理せずに単独で用いた。
窒素置換した1000mlオートクレーブにトルエン300mlを加えた。表1記載の安定剤溶液を1ml(安定剤として100mg)、メチルアルミノキサン(東ソー・ファインケム社製MMAO-3A:アルミニウムとして9mmol)およびエチレンビス(テトラヒドロインデニル)ジルコニウムクロライド1.28mgを溶解したトルエン溶液2mlを順次加えた。オートクレーブ内をプロピレン雰囲気に置換し、プロピレンで5kgf/cm2Gの圧力をかけ、50℃で1.5時間重合反応を行った。反応液にエタノール50mlを加え重合反応を停止させた後、減圧脱溶媒を行い、次いで、真空中、60℃でポリマーを一昼夜乾燥することによりポリプロピレンパウダーを得た。
得られたポリプロピレンの収量および分子量により、触媒活性への影響を評価した。分子量は、ゲルパーミエーションクロマトグラフ(装置:ウォーターズ社製GPC2000型、カラム:ウォーターズ社製Styragel HT6E 2本とStyragelHT2 1本、測定温度135℃、溶媒:オルトジクロロベンゼン、濃度:6mg/10g)により重量平均分子量を測定した。
得られたポリプロピレン粉末について100℃ギアオーブンでの120時間後および240時間後の分子量変化により安定化効果を評価した。
Claims (7)
- 遷移金属からなるメタロセン触媒を用いてエチレン性不飽和結合を有するモノマーを重合する際に、ヒンダードアミン化合物の1種以上をトリアルキルアルミニウム化合物と予め混合したのちに、重合前に触媒系又は重合系に添加することを特徴とする安定化ポリマーの製造方法。
- 上記トリアルキルアルミニウム化合物がトリイソブチルアルミニウムである請求項1記載のポリマーの製造方法。
- 遷移金属が周期表3族〜11族の金属である請求項1記載のポリマーの製造方法。
- 遷移金属が周期表3族、4族、5族、8族または10族の金属である請求項1記載のポリマーの製造方法。
- 遷移金属がTi、Zr、Hf、V、Fe、Ni、Pd、Pt、YまたはSmである請求項1記載のポリマーの製造方法。
- エチレン性不飽和結合を有するモノマーがα−オレフィンである請求項1記載のポリマーの製造方法。
- エチレン性不飽和結合を有するモノマーがエチレンである請求項1記載のポリマーの製造方法。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004011533A JP4278525B2 (ja) | 2004-01-20 | 2004-01-20 | 安定化されたポリマーの製造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004011533A JP4278525B2 (ja) | 2004-01-20 | 2004-01-20 | 安定化されたポリマーの製造方法 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009027428A Division JP5322681B2 (ja) | 2009-02-09 | 2009-02-09 | 安定化されたポリマーの製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2005206625A JP2005206625A (ja) | 2005-08-04 |
JP4278525B2 true JP4278525B2 (ja) | 2009-06-17 |
Family
ID=34898198
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004011533A Expired - Lifetime JP4278525B2 (ja) | 2004-01-20 | 2004-01-20 | 安定化されたポリマーの製造方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP4278525B2 (ja) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4866624B2 (ja) * | 2005-03-09 | 2012-02-01 | 日本ポリプロ株式会社 | オレフィン重合用固体触媒成分、オレフィン重合用触媒、およびこれを用いたポリオレフィンの製造方法 |
JP5501962B2 (ja) * | 2008-06-05 | 2014-05-28 | 株式会社Adeka | アルミニウムフェノキシド化合物を用いた安定化ポリマーの製造方法。 |
JP5596327B2 (ja) * | 2009-01-28 | 2014-09-24 | 株式会社Adeka | 食品・医療・水道用パイプ用途のポリオレフィン系樹脂組成物 |
US8779015B2 (en) | 2009-09-04 | 2014-07-15 | Adeka Corporation | Method for recycling of phenolic antioxidant agent, process for production of olefin polymer, polyolefin powder, and fibers |
JP2011052176A (ja) * | 2009-09-04 | 2011-03-17 | Adeka Corp | フェノール系酸化防止剤の再生方法およびオレフィン重合体 |
JP5808885B2 (ja) * | 2009-09-04 | 2015-11-10 | 株式会社Adeka | オレフィン重合体の製造方法 |
JP5710186B2 (ja) * | 2010-09-10 | 2015-04-30 | 株式会社Adeka | 安定化ポリマーの製造方法 |
JP5574916B2 (ja) * | 2010-10-26 | 2014-08-20 | 三井化学株式会社 | オレフィン重合体の製造方法 |
BR122019017983B1 (pt) | 2010-11-16 | 2021-01-12 | Adeka Corporation | método de produção de um tecido falso a partir de pelo menos uma olefina |
BR112013022263B1 (pt) | 2011-03-02 | 2020-12-08 | Adeka Corporation | processo para a produção de película laminada e composição de resina para revestimento de membros |
JP2013199551A (ja) | 2012-03-23 | 2013-10-03 | Adeka Corp | 家電材料用及び自動車内装材料用オレフィン樹脂組成物の製造方法 |
US20160251497A1 (en) | 2013-10-21 | 2016-09-01 | Adeka Corporation | Method for producing stabilized polymer |
JP6909594B2 (ja) | 2017-03-03 | 2021-07-28 | 株式会社Adeka | 安定化されたオレフィン系樹脂組成物の製造方法 |
-
2004
- 2004-01-20 JP JP2004011533A patent/JP4278525B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JP2005206625A (ja) | 2005-08-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101725004B1 (ko) | 혼성 담지 메탈로센 촉매 및 이를 이용한 가공성이 우수한 폴리올레핀 수지 | |
Huang et al. | Ziegler-Natta catalysts for olefin polymerization: mechanistic insights from metallocene systems | |
EP0128045B1 (en) | Process and catalyst for producing poly-ethylene having a broad molecular weight distribution | |
AU744887B2 (en) | New homogeneous olefin polymerization catalyst composition | |
KR100527018B1 (ko) | 중합 촉매 조성물 및 중합 방법 | |
DE69127811T3 (de) | Verfahren zur herstellung von olefinpolymeren | |
JP4278525B2 (ja) | 安定化されたポリマーの製造方法 | |
JPH09505340A (ja) | 重合用触媒系、その製造方法及び使用 | |
JP2002515521A (ja) | 混合触媒及び重合プロセスにおけるそれらの使用 | |
BRPI0822091B1 (pt) | Método de polimerização | |
JPH11335499A (ja) | プロペンの重合体及びその製造方法、並びにその使用方法 | |
JP5140625B2 (ja) | プロピレン系樹脂組成物及びそれを用いた食品容器、医療部材 | |
US6160072A (en) | Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes | |
JPH06179776A (ja) | 広範な融点範囲を有するポリオレフィン成形組成物とその調製方法及びその利用 | |
EP1572762B1 (en) | High molecular weight polypropylene process | |
US20040254316A1 (en) | Polymerization processes using antistatic agents | |
JPH04264110A (ja) | ポリオレフィンの製造方法 | |
JP3489207B2 (ja) | エチレン/α−オレフィン共重合体の製造方法 | |
US6252019B1 (en) | Process for polymerizing tactioselective polyolefins in condensed phase using hafnocenes | |
JP5322681B2 (ja) | 安定化されたポリマーの製造方法 | |
JP2023026642A (ja) | 分岐状ポリプロピレン系重合体 | |
JP6213179B2 (ja) | 押出しラミネート用ポリプロピレン系樹脂組成物および積層体 | |
JP3405784B2 (ja) | ポリオレフィンの製造方法 | |
JPH05112683A (ja) | プロピレン共重合体組成物 | |
JP2002532580A (ja) | 触媒改質剤及びオレフィンの重合におけるそれらの使用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20061130 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20081113 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20081216 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20090209 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20090310 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20090310 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120319 Year of fee payment: 3 |
|
R151 | Written notification of patent or utility model registration |
Ref document number: 4278525 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R151 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20120319 Year of fee payment: 3 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130319 Year of fee payment: 4 |
|
EXPY | Cancellation because of completion of term |