JP4266388B2 - 改良された除草剤組成物 - Google Patents
改良された除草剤組成物 Download PDFInfo
- Publication number
- JP4266388B2 JP4266388B2 JP50374692A JP50374692A JP4266388B2 JP 4266388 B2 JP4266388 B2 JP 4266388B2 JP 50374692 A JP50374692 A JP 50374692A JP 50374692 A JP50374692 A JP 50374692A JP 4266388 B2 JP4266388 B2 JP 4266388B2
- Authority
- JP
- Japan
- Prior art keywords
- composition
- salt
- fatty acid
- water
- phosphonomethylglycine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 125
- 230000002363 herbicidal effect Effects 0.000 title claims description 37
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000000194 fatty acid Substances 0.000 claims abstract description 51
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 50
- 229930195729 fatty acid Natural products 0.000 claims abstract description 50
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 42
- 150000003839 salts Chemical class 0.000 claims abstract description 38
- 238000000034 method Methods 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000004094 surface-active agent Substances 0.000 claims abstract description 18
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 13
- 239000005562 Glyphosate Substances 0.000 claims description 31
- 229940097068 glyphosate Drugs 0.000 claims description 31
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical group [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 29
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 20
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 15
- 230000000694 effects Effects 0.000 claims description 14
- -1 fatty acid salt Chemical class 0.000 claims description 14
- 239000000654 additive Substances 0.000 claims description 11
- 150000001412 amines Chemical class 0.000 claims description 10
- 239000005643 Pelargonic acid Substances 0.000 claims description 8
- 239000003760 tallow Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 5
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical group [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 5
- 229920006395 saturated elastomer Polymers 0.000 claims description 5
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 4
- 239000002585 base Substances 0.000 claims description 4
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical group CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims description 4
- 230000007774 longterm Effects 0.000 claims description 4
- 230000000007 visual effect Effects 0.000 claims description 4
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 3
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims description 2
- NRZWQKGABZFFKE-UHFFFAOYSA-N trimethylsulfonium Chemical group C[S+](C)C NRZWQKGABZFFKE-UHFFFAOYSA-N 0.000 claims description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims 2
- 239000004471 Glycine Substances 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 abstract description 29
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- 239000004615 ingredient Substances 0.000 abstract description 6
- 238000009472 formulation Methods 0.000 abstract description 5
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- 239000000417 fungicide Substances 0.000 abstract description 3
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- 230000000845 anti-microbial effect Effects 0.000 abstract 1
- 230000000361 pesticidal effect Effects 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 9
- 150000004671 saturated fatty acids Chemical class 0.000 description 8
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- 239000003795 chemical substances by application Substances 0.000 description 6
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- 240000001505 Cyperus odoratus Species 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 5
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- 235000001602 Digitaria X umfolozi Nutrition 0.000 description 4
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- 235000006830 Digitaria didactyla Nutrition 0.000 description 4
- 235000005804 Digitaria eriantha ssp. eriantha Nutrition 0.000 description 4
- 235000010823 Digitaria sanguinalis Nutrition 0.000 description 4
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- 238000013019 agitation Methods 0.000 description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 4
- 235000011130 ammonium sulphate Nutrition 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 238000007046 ethoxylation reaction Methods 0.000 description 4
- 230000035784 germination Effects 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
- 235000007319 Avena orientalis Nutrition 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 240000001949 Taraxacum officinale Species 0.000 description 3
- 235000005187 Taraxacum officinale ssp. officinale Nutrition 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 3
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
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- 235000003441 saturated fatty acids Nutrition 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 3
- GNKZMNRKLCTJAY-UHFFFAOYSA-N 4'-Methylacetophenone Chemical compound CC(=O)C1=CC=C(C)C=C1 GNKZMNRKLCTJAY-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241001414720 Cicadellidae Species 0.000 description 2
- 241000234642 Festuca Species 0.000 description 2
- 241000234643 Festuca arundinacea Species 0.000 description 2
- 241000213996 Melilotus Species 0.000 description 2
- 235000000839 Melilotus officinalis subsp suaveolens Nutrition 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 2
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- ZEKANFGSDXODPD-UHFFFAOYSA-N glyphosate-isopropylammonium Chemical compound CC(C)N.OC(=O)CNCP(O)(O)=O ZEKANFGSDXODPD-UHFFFAOYSA-N 0.000 description 2
- 229960004488 linolenic acid Drugs 0.000 description 2
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 2
- 230000004060 metabolic process Effects 0.000 description 2
- 150000002763 monocarboxylic acids Chemical class 0.000 description 2
- 229960002446 octanoic acid Drugs 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 description 1
- QMNWYGTWTXOQTP-UHFFFAOYSA-N 1h-triazin-6-one Chemical compound O=C1C=CN=NN1 QMNWYGTWTXOQTP-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-DOMIDYPGSA-N 2-(2,4-dichlorophenoxy)acetic acid Chemical compound OC(=O)[14CH2]OC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-DOMIDYPGSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- GEHMBYLTCISYNY-UHFFFAOYSA-N Ammonium sulfamate Chemical compound [NH4+].NS([O-])(=O)=O GEHMBYLTCISYNY-UHFFFAOYSA-N 0.000 description 1
- 235000007320 Avena fatua Nutrition 0.000 description 1
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 1
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 244000052363 Cynodon dactylon Species 0.000 description 1
- 241001124144 Dermaptera Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 241001149911 Isopoda Species 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241000244206 Nematoda Species 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical class [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229940100389 Sulfonylurea Drugs 0.000 description 1
- 235000015360 Taraxacum officinale ssp. ceratophorum Nutrition 0.000 description 1
- WHKUVVPPKQRRBV-UHFFFAOYSA-N Trasan Chemical compound CC1=CC(Cl)=CC=C1OCC(O)=O WHKUVVPPKQRRBV-UHFFFAOYSA-N 0.000 description 1
- 241000219793 Trifolium Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 235000005373 Uvularia sessilifolia Nutrition 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000005515 coenzyme Substances 0.000 description 1
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- 238000012937 correction Methods 0.000 description 1
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- 238000007865 diluting Methods 0.000 description 1
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- 239000000975 dye Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
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- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000005414 inactive ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- LZGUHMNOBNWABZ-UHFFFAOYSA-N n-nitro-n-phenylnitramide Chemical compound [O-][N+](=O)N([N+]([O-])=O)C1=CC=CC=C1 LZGUHMNOBNWABZ-UHFFFAOYSA-N 0.000 description 1
- 230000017074 necrotic cell death Effects 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002777 nucleoside Substances 0.000 description 1
- 125000003835 nucleoside group Chemical group 0.000 description 1
- 239000002773 nucleotide Substances 0.000 description 1
- 125000003729 nucleotide group Chemical group 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 235000020777 polyunsaturated fatty acids Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- QDIGBJJRWUZARS-UHFFFAOYSA-M potassium;decanoate Chemical compound [K+].CCCCCCCCCC([O-])=O QDIGBJJRWUZARS-UHFFFAOYSA-M 0.000 description 1
- WQEDQSDEIXNCCI-UHFFFAOYSA-M potassium;nonanoate Chemical compound [K+].CCCCCCCCC([O-])=O WQEDQSDEIXNCCI-UHFFFAOYSA-M 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 150000003212 purines Chemical class 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003230 pyrimidines Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000026267 regulation of growth Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003516 soil conditioner Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- YROXIXLRRCOBKF-UHFFFAOYSA-N sulfonylurea Chemical class OC(=N)N=S(=O)=O YROXIXLRRCOBKF-UHFFFAOYSA-N 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- BFGQTWYXWNCTSX-UHFFFAOYSA-N triazine-4,5-dione Chemical compound O=C1C=NN=NC1=O BFGQTWYXWNCTSX-UHFFFAOYSA-N 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Medicines Containing Plant Substances (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US63859091A | 1991-01-08 | 1991-01-08 | |
| US638,590 | 1991-01-08 | ||
| PCT/US1991/009621 WO1992011764A1 (en) | 1991-01-08 | 1991-12-20 | Improved herbicidal formulation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH06504060A JPH06504060A (ja) | 1994-05-12 |
| JP4266388B2 true JP4266388B2 (ja) | 2009-05-20 |
Family
ID=24560644
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50374692A Expired - Lifetime JP4266388B2 (ja) | 1991-01-08 | 1991-12-20 | 改良された除草剤組成物 |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US5994269A (enExample) |
| EP (1) | EP0566648B2 (enExample) |
| JP (1) | JP4266388B2 (enExample) |
| AT (1) | ATE124206T1 (enExample) |
| AU (1) | AU662892B2 (enExample) |
| CA (1) | CA2097913C (enExample) |
| DE (1) | DE69110907T3 (enExample) |
| DK (1) | DK0566648T3 (enExample) |
| FI (1) | FI104879B (enExample) |
| WO (1) | WO1992011764A1 (enExample) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2588350B2 (ja) * | 1990-11-02 | 1997-03-05 | セイファ インコーポレイテッド | 改良型脂肪酸系除草剤組成物 |
| US6930075B1 (en) | 1990-11-02 | 2005-08-16 | Monsanto Technology, Llc | Fatty acid-based herbicidal composition |
| EP0577914A1 (en) * | 1992-07-08 | 1994-01-12 | Monsanto Europe S.A./N.V. | Improved glyphosate compositions and their use |
| US5389598A (en) * | 1993-12-17 | 1995-02-14 | Monsanto Company | Aqueous concentrate formulations having reduced eye irritancy |
| WO1997041730A1 (en) * | 1996-05-08 | 1997-11-13 | Mycogen Corporation | Novel herbicidally-active concentrates |
| TW453855B (en) * | 1996-11-07 | 2001-09-11 | Sankyo Co | Plant growth regulator |
| US5919733A (en) * | 1997-04-04 | 1999-07-06 | W. Neudorff Gmbh Kg | Non-staining herbicidal soap |
| US6066786A (en) * | 1998-06-17 | 2000-05-23 | Pure Seed Testing, Inc. | Glyphosate tolerant fescue grasses |
| JP2000159615A (ja) * | 1998-09-25 | 2000-06-13 | Sankyo Co Ltd | 抑草剤 |
| US6432878B1 (en) | 1999-01-15 | 2002-08-13 | Cognis Corporation | Adjuvant composition |
| CA2409745A1 (en) | 2000-05-22 | 2001-12-06 | Monsanto Technology, Llc | Reaction systems for making n-(phosphonomethyl)glycine compounds |
| US6407319B1 (en) | 2000-06-07 | 2002-06-18 | Pure Seed Testing, Inc. | Kentucky bluegrass variety known as ‘North Star’ |
| US6372966B1 (en) | 2000-06-07 | 2002-04-16 | Pure Seed Testing Inc. | Kentucky bluegrass variety known as ‘Brilliant’ |
| US6503869B1 (en) * | 2000-08-21 | 2003-01-07 | Falcon Lab Llc | Enhanced post-emergent herbicidal compositions containing ammonium salts and methods of using the same |
| US6441223B1 (en) | 2000-11-30 | 2002-08-27 | Monsanto Technology Llc | Method of making phosphorus-containing compounds and products thereof |
| US6608003B2 (en) | 2000-12-01 | 2003-08-19 | Falcon Lab Llc | Herbicidal solutions comprising fatty acid ammonium salts and dicarboxylic acid diesters and methods of using the same |
| NO313262B1 (no) * | 2000-12-22 | 2002-09-09 | Norsk Hydro As | Produktformulering og fremgangsmåte for å forbedre effekten av systemiske herbicider |
| US6423887B1 (en) | 2001-03-14 | 2002-07-23 | Pure Seed Testing, Inc. | Glyphosate tolerant fescue grass variety |
| US6413909B1 (en) | 2001-06-20 | 2002-07-02 | Larry L. Walker | Herbicide composition for control of rye grass and vetch in preplant burndown |
| AUPR682201A0 (en) * | 2001-08-03 | 2001-08-30 | Nufarm Limited | Glyphosate composition |
| BRPI0509541A (pt) | 2004-03-30 | 2007-09-18 | Monsanto Technology Llc | métodos para controlar agentes patógenos de planta utilizando n-fosfonometilglicina |
| JP2006056784A (ja) * | 2004-08-17 | 2006-03-02 | Sankyo Agro Kk | 安定化された水性除草剤組成物 |
| DE602005011454D1 (de) | 2004-08-19 | 2009-01-15 | Monsanto Technology Llc | Herbizide glyphosatsalzusammensetzung |
| MX2007003193A (es) * | 2004-09-17 | 2007-05-16 | Monsanto Technology Llc | Formulaciones de glifosato con sintomas de quemado temprano. |
| US7223718B2 (en) * | 2005-03-07 | 2007-05-29 | Falcon Lab Llc | Enhanced glyphosate herbicidal concentrates |
| CA2608206C (en) | 2005-05-24 | 2015-11-24 | Monsanto Technology Llc | Herbicide compatibility improvement |
| US10555527B2 (en) | 2009-05-18 | 2020-02-11 | Monsanto Technology Llc | Use of glyphosate for disease suppression and yield enhancement in soybean |
| US9980490B1 (en) | 2014-06-05 | 2018-05-29 | Falcon Lab, Llc | Method of disinfecting bacterial contaminated surfaces or removing bacteria from contaminated surfaces |
| GB2541935B (en) * | 2015-09-07 | 2020-05-20 | Naturiol Bangor Ltd | Insecticide/miticide composition |
| US10426163B1 (en) | 2019-01-07 | 2019-10-01 | Falcon Lab, Llc | Bactericidal method of using compounds of fatty acids and ammonium fatty acid salts |
| JP7420449B2 (ja) * | 2019-11-05 | 2024-01-23 | アース製薬株式会社 | 除草剤組成物 |
| US20230047569A1 (en) * | 2019-12-31 | 2023-02-16 | 0903608 B.C. Ltd. | Pesticidal complex compositions for synergistic delivery of pesticidal active ingredients and methods of selection thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4840659A (en) | 1971-03-10 | 1989-06-20 | Monsanto Company | N-Phosphonomethylglycine phytotoxicant compositions |
| US3799758A (en) * | 1971-08-09 | 1974-03-26 | Monsanto Co | N-phosphonomethyl-glycine phytotoxicant compositions |
| US3977860A (en) * | 1971-08-09 | 1976-08-31 | Monsanto Company | Herbicidal compositions and methods employing esters of N-phosphonomethylglycine |
| US3870503A (en) | 1973-10-03 | 1975-03-11 | Hawaiian Sugar Planters Assoc | Ripening of sugarcane by use of n-valeric acid |
| US4405531A (en) | 1975-11-10 | 1983-09-20 | Monsanto Company | Salts of N-phosphonomethylglycine |
| US4159901A (en) * | 1977-05-16 | 1979-07-03 | Monsanto Company | Corrosion inhibited agricultural compositions |
| US4134754A (en) | 1978-03-23 | 1979-01-16 | Gulf Oil Corporation | Method of combating wild oats |
| WO1979000838A1 (en) * | 1978-03-28 | 1979-10-18 | Michael James Sampson | New plant technique |
| US4411693A (en) * | 1981-03-26 | 1983-10-25 | Monsanto Company | Flowable herbicides |
| US4395275A (en) * | 1981-06-19 | 1983-07-26 | Monsanto Company | Mono and diesters of N-phosphonomethylglycinates as herbicides |
| US4486358A (en) | 1982-06-24 | 1984-12-04 | Ciba-Geigy Corporation | Process for producing N-phosphonomethylglycine |
| DE3247050A1 (de) * | 1982-12-20 | 1984-06-20 | Bayer Ag, 5090 Leverkusen | Herbizide mittel |
| ES8603901A1 (es) * | 1983-07-27 | 1986-01-01 | Rhone Poulenc Agrochimie | Procedimiento de preparacion de sulfonamidas con grupo ansinometilfosfonico |
| EP0149034A3 (en) | 1983-12-21 | 1989-01-04 | Teijin Limited | Regulation of plant metalbolism by alpha,beta- or beta,gamma-unsaturated carboxylic acids or derivatives thereof |
| FR2576181B1 (fr) * | 1985-01-23 | 1987-04-03 | Rhone Poulenc Agrochimie | Melanges herbicides a base de compose de type n-(phosphonomethylglycyl) |
| WO1989003178A1 (en) * | 1987-10-16 | 1989-04-20 | Safer, Inc. | Biodegradable herbicidal composition |
| US4904645A (en) | 1988-01-27 | 1990-02-27 | Safer, Ltd. | Environmentally safe, broad spectrum insecticide |
| US4966728A (en) | 1988-08-26 | 1990-10-30 | Basf Corporation | Adjuvants for use with postemergent herbicides |
| NZ231897A (en) * | 1988-12-30 | 1992-09-25 | Monsanto Co | Dry water-soluble granular composition comprising glyphosate and a liquid surfactant |
| US4975110A (en) * | 1989-10-13 | 1990-12-04 | Safer, Inc. | Fatty acid based herbicidal compositions |
| US5035741A (en) * | 1989-10-13 | 1991-07-30 | Safer, Inc. | Fatty acid based emulsifiable concentrate having herbicidal activity |
| JP2588350B2 (ja) † | 1990-11-02 | 1997-03-05 | セイファ インコーポレイテッド | 改良型脂肪酸系除草剤組成物 |
| US5196044A (en) * | 1991-01-08 | 1993-03-23 | Mycogen Corporation | Process and composition for controlling weeds |
| MY111437A (en) * | 1992-07-31 | 2000-05-31 | Monsanto Co | Improved glyphosate herbicide formulation. |
| US5389598A (en) * | 1993-12-17 | 1995-02-14 | Monsanto Company | Aqueous concentrate formulations having reduced eye irritancy |
| US5750468A (en) | 1995-04-10 | 1998-05-12 | Monsanto Company | Glyphosate formulations containing etheramine surfactants |
| US5700759A (en) * | 1995-06-07 | 1997-12-23 | Mycogen Corporation | Process and composition for controlling weeds comprising a C7 -C20 |
-
1991
- 1991-12-20 DK DK92903567.3T patent/DK0566648T3/da active
- 1991-12-20 AU AU91705/91A patent/AU662892B2/en not_active Ceased
- 1991-12-20 EP EP92903567A patent/EP0566648B2/en not_active Expired - Lifetime
- 1991-12-20 CA CA002097913A patent/CA2097913C/en not_active Expired - Lifetime
- 1991-12-20 WO PCT/US1991/009621 patent/WO1992011764A1/en not_active Ceased
- 1991-12-20 AT AT92903567T patent/ATE124206T1/de not_active IP Right Cessation
- 1991-12-20 JP JP50374692A patent/JP4266388B2/ja not_active Expired - Lifetime
- 1991-12-20 DE DE69110907T patent/DE69110907T3/de not_active Expired - Lifetime
-
1993
- 1993-07-07 FI FI933122A patent/FI104879B/fi not_active IP Right Cessation
-
1997
- 1997-01-29 US US08/790,400 patent/US5994269A/en not_active Expired - Fee Related
-
1999
- 1999-03-08 US US09/264,569 patent/US6468944B1/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0566648A1 (en) | 1993-10-27 |
| US5994269A (en) | 1999-11-30 |
| JPH06504060A (ja) | 1994-05-12 |
| DE69110907T3 (de) | 2002-03-28 |
| CA2097913C (en) | 2002-08-20 |
| DE69110907T2 (de) | 1996-02-01 |
| DK0566648T4 (enExample) | 2001-09-17 |
| ATE124206T1 (de) | 1995-07-15 |
| AU662892B2 (en) | 1995-09-21 |
| US6468944B1 (en) | 2002-10-22 |
| FI104879B (fi) | 2000-04-28 |
| DE69110907D1 (de) | 1995-08-03 |
| FI933122L (fi) | 1993-07-07 |
| WO1992011764A1 (en) | 1992-07-23 |
| FI933122A0 (fi) | 1993-07-07 |
| EP0566648B2 (en) | 2001-05-30 |
| DK0566648T3 (da) | 1995-12-04 |
| EP0566648B1 (en) | 1995-06-28 |
| AU9170591A (en) | 1992-08-17 |
| CA2097913A1 (en) | 1992-07-09 |
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