JP4149997B2 - 剛性容器の酸素検出システム - Google Patents
剛性容器の酸素検出システム Download PDFInfo
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Description
本明細書では、「剛性容器」およびその類似物は、食品または非食品産物(例えば、固体または液体の産物)のような産物を入れることができ、空の時にそれらの形状が実質的に保たれる容器を表す。しかし、これらの容器には、ある程度の柔軟性または柔らかさがあってもよい。剛性容器の例は、PETまたは他のタイプのボトル、特に、アルコール性または非アルコール性飲料、調味料、ローションなどの販売用にデザインされたもの;食品トレイ、例えば、発泡もしくは固体ポリスチレン、結晶化ポリスチレン(CPS)、PET、ポリプロピレン、またはポリエチレンからなるもの;全体のパッケージまたは容器の一部分としての、トレイを伴う蓋(lidstock);ライナー、ラベル、もしくは、ポリマー材料および/または蒸着基材からなる類似物をもつ板紙のカートン;スタンディングパウチ(このようなパウチがそれらの形状を空の時に実質的に保つ場合);である。
− 任意の適切な手段、例えば接着(例えば、感圧接着、ヒートシール、RFシールなど)により、パッチをボトルに張り付けることができる;
− パッチは、それが無ければ通常のものであるシュリンクスリーブまたはラベル(例えば、2リットルの飲料容器、ビールおよびワインのボトルなどの外側表面に販売のために現在装着されているもの)の一部分であり得る;
− パッチは、それが無ければ通常のものであるラベル上の小さな目印(eye−spot)の形を取り得る。
− パッチの厚さは変わり得る(図に示されている厚さは分かり易くするために誇張されている);
− パッチは適当な任意の大きさと形状寸法であり得る;また
− ボトルの内側表面上に取り付けることに比べて、パッチを付けること(例えば、ボトルの押出または充填作業の間に)が相対的に容易であるという理由で、また、ボトルの外側から機械または目視により読み取る、または検出することが相対的に容易であるという理由で、パッチがボトルの外側表面上にあることが好ましい。
a)それらの酸素濃度の変化に対する応答は、予想可能で、線形で、完全に可逆的である。線形性は、較正と、定量的にモニタするために望ましい。可逆性により、パッケージングおよび保管過程の任意の段階で、酸素濃度をモニタできる;
b)それらは、目標範囲内で酸素濃度に感応する。範囲は、0%と5%の酸素の間(例えば0%と1%の間、あるいは、0から1000ppmの間)を含む。必要に応じて、異なる範囲と感応性をもつインジケータの組合せを、このような範囲を広げるために用いてもよい;
c)それらは、使用される状態において、酸素濃度の変化に素早く応答する。酸素濃度の変化に対するルミネセント化合物の典型的な応答時間は、0℃から25℃の間の温度範囲に渡って、雰囲気の変化から1分以内である;
d)それらは、容易にモニタされる振動数範囲でルミネセンスを示す。高価でない励起探査装置(interogative device)を使用して、(複数の)インジケータは、好ましくは可視の、適切な励起および発光振動数をもつべきである;
e)それらは、酸素濃度変化に選択的に応答し、染料含有パッケージング材料に浸透し得る二酸化炭素のような他のガスに対して感応性でない;
f)それらは、使用および保管状態の下で安定である。光安定性は望ましいが、必要とされない。温度安定性、および湿度の変化に対する安定性は望ましく、好ましい;
g)それらは、透明であるか、あるいは、それらが使用されるパッケージングに色彩適合性(color−compatibility)がある。色彩適合性は、例えば、インジケータが印刷画像の全てまたは一部をなす場合に重要である。別個のパッチが使用される実施形態においては、透明性または色彩適合性は、通常、重要でない;
h)それらは、良好なコーティングおよび/または印刷性を示し、また/あるいは、押出しても問題ない;また
i)インジケータは、全体としてのパッケージング材料のコストをできるだけ低くするために、比較的低濃度で有効である。
I = 測定強度
PO2 = 測定酸素分圧
P1/2 = 強度の半減期での酸素分圧
この方程式の逆数を取り、その分数を明らかにして強度比または明るさ(B)を表すことができる:
方法1.酸素が存在する状態でルミネセンス強度を測定し、それを酸素が存在しない状態のルミネセンスに対する比で表す。この測定法のための装置は、いくつかの光学機器の供給元(例えば、Ocean Optics,Dunedin,Florida)から一般に市販されている。
Tanθ=2πfτ
ここで、τは発光寿命であり、fは変調周波数である。最大の位相差は、f=(1/2π)(τ1τ2)−1/2(τ1およびτ2は消光される、および消光されない化学種の寿命である)で起こる。このデータは、Stern−Volmer式の次の別の形に用いられる:
τ0/τ=1+kSVPO2
ここで、τ0は、酸素がない状態でのルミネセンス寿命であり、kSVは、Stern−Volmer消光定数であり、PO2は酸素分圧である。
Claims (16)
- a)ASTM D 3985に従い、25℃、相対湿度0%、1atmで、100cc/m2/24hr以下の酸素透過率をもつ酸素バリア;
b)酸素スカベンジャ;および
c)ルミネセント化合物を含む酸素インジケータ;
を含み、
酸素インジケータが酸素バリア層により容器を囲む環境中の酸素及び容器内の(存在する場合)ヘッドスペースの酸素から実質的にシールドされており、
酸素インジケータは印刷画像の全体または一部分を含み、かつ、
酸素スカベンジャおよび酸素インジケータは、i)互いに隣接する層中に、または、ii)ブレンドとして単一の層中に、配置されている、
ボトル壁。 - a)ASTM D 3985に従い、25℃、相対湿度0%、1atmで、100cc/m2/24hr以下の酸素透過率をもつ前記酸素バリアを含む第1の層;
b)前記酸素スカベンジャを含む第2の層;および
c)ルミネセント化合物を含む前記酸素インジケータを含む、第2の層に隣接する、第3の層;
を含む請求項1に記載のボトル壁。 - a)ASTM D 3985に従い、25℃、相対湿度0%、1atmで、100cc/m2/24hr以下の酸素透過率をもつ前記酸素バリアを含む第1の層;
b)ルミネセント化合物を含む前記酸素インジケータを含む第2の層;および
c)前記酸素スカベンジャを含む、第2の層に隣接する、第3の層;
を含む請求項1に記載のボトル壁。 - ASTM D 3985に従い、25℃、相対湿度0%、1atmで、100cc/m2/24hr以下の酸素透過率をもつ前記酸素バリアを含む第4の層を含む請求項2および3のいずれか一項に記載のボトル壁。
- a)ASTM D 3985に従い、25℃、相対湿度0%、1atmで、100cc/m2/24hr以下の酸素透過率をもつ前記酸素バリアを含む第1の層;および
b)前記酸素スカベンジャと、ルミネセント化合物を含む前記酸素インジケータとのブレンドを含む第2の層;
を含む請求項1に記載のボトル壁。 - a)i)ASTM D 3985に従い、25℃、相対湿度0%、1atmで、100cc/m2/24hr以下の酸素透過率をもつ前記酸素バリア、および
ii)前記酸素スカベンジャ、
のブレンド;ならびに
b)ルミネセント化合物を含む前記酸素インジケータを含み、前記ブレンドに付着したパッチ;
を含む請求項1に記載のボトル壁。 - a)トレイフランジを含むトレイであって、ルミネセント化合物を含む酸素インジケータを含むトレイ;および
b)ASTM D 3985に従い、25℃、相対湿度0%、1atmで、100cc/m2/24hr以下の酸素透過率をもつ酸素バリアと、酸素スカベンジャとを含む蓋(lidstock);
を含む剛性容器。 - a)ルミネセント化合物を含む前記酸素インジケータを含むトレイライナーと、トレイフランジとを含むトレイ;ならびに
b)ASTM D 3985に従い、25℃、相対湿度0%、1atmで、100cc/m2/24hr以下の酸素透過率をもつ酸素バリアと、酸素スカベンジャとを含む蓋;
を含む請求項7に記載の剛性容器。 - 前記酸素バリアおよび前記酸素スカベンジャが別々の層に配置されている請求項7または8に記載の剛性容器。
- a)ルミネセント化合物を含む酸素インジケータ、および酸素スカベンジャを含むトレイライナーと、トレイフランジとを含むトレイ;ならびに
b)ASTM D 3985に従い、25℃、相対湿度0%、1atmで、100cc/m2/24hr以下の酸素透過率をもつ酸素バリアを含む蓋;
を含む剛性容器。 - 前記酸素インジケータと前記酸素スカベンジャが別々の層に配置される請求項10に記載の剛性容器。
- a)酸素スカベンジャを含むトレイライナーと、トレイフランジとを含むトレイ;ならびに
b)ルミネセント化合物を含む酸素インジケータを含み、前記トレイフランジに付着したパッチ;
を含む剛性容器。 - 前記パッチが、ASTM D 3985に従い、25℃、相対湿度0%、1atmで、100cc/m2/24hr以下の酸素透過率をもつ酸素バリアを含む請求項12に記載の剛性容器。
- 前記蓋がシーラントを含む請求項7から11のいずれか一項に記載の剛性容器。
- 前記トレイライナーがシーラントを含む請求項8、10、11、12および13のいずれか一項に記載の剛性容器。
- a)i)ASTM D 3985に従い、25℃、相対湿度0%、1atmで、100cc/m2/24hr以下の酸素透過率をもつ酸素バリア、
ii)酸素スカベンジャ、および
iii)ルミネセント化合物を含む酸素インジケータ、
を含むフィルム;ならびに
b)前記a)のフィルムがライナーとして付着する板紙基材;
を含む板紙カートン。
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US43147502P | 2002-12-06 | 2002-12-06 | |
US10/719,625 US7368153B2 (en) | 2002-12-06 | 2003-11-21 | Oxygen detection system for a rigid container |
PCT/US2003/038901 WO2004052644A2 (en) | 2002-12-06 | 2003-12-08 | Oxygen detection system for a rigid container |
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JP2006508872A JP2006508872A (ja) | 2006-03-16 |
JP4149997B2 true JP4149997B2 (ja) | 2008-09-17 |
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US (1) | US7368153B2 (ja) |
EP (1) | EP1567333A2 (ja) |
JP (1) | JP4149997B2 (ja) |
AU (1) | AU2003297718B2 (ja) |
BR (1) | BR0317043A (ja) |
CA (1) | CA2508345A1 (ja) |
MX (1) | MXPA05005689A (ja) |
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-
2003
- 2003-11-21 US US10/719,625 patent/US7368153B2/en not_active Expired - Lifetime
- 2003-12-08 AU AU2003297718A patent/AU2003297718B2/en not_active Ceased
- 2003-12-08 CA CA002508345A patent/CA2508345A1/en not_active Abandoned
- 2003-12-08 JP JP2004559401A patent/JP4149997B2/ja not_active Expired - Fee Related
- 2003-12-08 NZ NZ540217A patent/NZ540217A/en not_active IP Right Cessation
- 2003-12-08 BR BR0317043-8A patent/BR0317043A/pt unknown
- 2003-12-08 MX MXPA05005689A patent/MXPA05005689A/es active IP Right Grant
- 2003-12-08 WO PCT/US2003/038901 patent/WO2004052644A2/en active Application Filing
- 2003-12-08 EP EP03796783A patent/EP1567333A2/en not_active Withdrawn
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JP2006508872A (ja) | 2006-03-16 |
US20040131806A1 (en) | 2004-07-08 |
CA2508345A1 (en) | 2004-06-24 |
US7368153B2 (en) | 2008-05-06 |
WO2004052644A3 (en) | 2004-09-02 |
BR0317043A (pt) | 2005-10-25 |
WO2004052644A2 (en) | 2004-06-24 |
MXPA05005689A (es) | 2005-07-26 |
AU2003297718A1 (en) | 2004-06-30 |
AU2003297718B2 (en) | 2009-01-29 |
EP1567333A2 (en) | 2005-08-31 |
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