JP4065881B2 - 生理学的な清涼効果を有する化合物 - Google Patents
生理学的な清涼効果を有する化合物 Download PDFInfo
- Publication number
- JP4065881B2 JP4065881B2 JP2005081952A JP2005081952A JP4065881B2 JP 4065881 B2 JP4065881 B2 JP 4065881B2 JP 2005081952 A JP2005081952 A JP 2005081952A JP 2005081952 A JP2005081952 A JP 2005081952A JP 4065881 B2 JP4065881 B2 JP 4065881B2
- Authority
- JP
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- Prior art keywords
- mol
- cooling effect
- products
- compounds
- menthyl chloroformate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 0 CC(C)C1C(C*[N+]([O-])O*(*(O)=O)N[C@](C)*)CC(C)CC1 Chemical compound CC(C)C1C(C*[N+]([O-])O*(*(O)=O)N[C@](C)*)CC(C)CC1 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/96—Esters of carbonic or haloformic acids
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Cosmetics (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Medicinal Preparation (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Steroid Compounds (AREA)
- Thermotherapy And Cooling Therapy Devices (AREA)
Description
R1はC4〜C20−アルキル、C5〜C20−シクロアルキルもしくは‐ヘテロシクロアルキル、C5〜C20−アルコキシ、C6〜C12−アリール、C5〜C10−ヘテロアリールまたはC7〜C11−アラールキルを表し、
R2はm+w・n価の脂肪族C1〜C8基、環状脂肪族もしくは異節環状脂肪族のC3〜C15基、芳香脂肪族のC7〜C20基またはアルコキシ含有もしくはアシルオキシ含有脂肪族C3〜C15基を表し、
ZおよびXは相互に独立に−O−、−S−または−NH−を表し、
Yはヒドロキシル、C1〜C10−アルコキシ、C2〜C6−アシルオキシ、アミノ、メルカプトまたは−O−R3−O−を表し、
R3はC1〜C6−アルキレンを表し、
wは基Yの価数、好ましくは1または2を表し、
mおよびnは相互に独立に1ないし8の整数を表し、ただしm+nの和は12を超えない
の少なくとも1種の化合物を含有する生理学的な清涼効果を有する薬剤に関する。
食品:
菓子製品、砂糖菓子、甘味食品(キャンディー、チョコレート)、ワッフル脂肪組成物、アルコール性飲料(ビール、蒸留酒、醸造酒)、非アルコール性飲料(果汁、レモネード、コーラ、乳飲料、ミネラルウォーター、水溶性錠剤)、乳製品、ヨーグルト、アイスクリーム製品、チューインガム、ゼリー製品、マーマレード、ジャムおよびデザート;
化粧剤:
髭剃り用のクリーム、フォーム、ジェルおよび石鹸;任意のアルコールを含有しまたは含有しないアフターシェーブ製品、たとえばローション、乳液、ジェルおよびバルム剤;髭剃り前処理製品、たとえばローション、乳液、クリーム、ジェルおよびバルム剤;スキンケア製品たとえばクリーム、ローション、乳液、ジェル、フォームおよびオイル;皮膚洗浄用製品たとえばクリーム、ローション、トニック、ティシューおよびパッド;皮膚フレッシュ剤製品たとえばジェル、ローションおよびティシュー拭取り剤;香料たとえばオーデコロン、オードトワレ、オードパルファン、エキスおよびスプラッシュコロン;脱臭剤および発汗防止剤製品、たとえばスティック、塗布剤、スプレー、クリームおよびパウダー;日焼け後処理製品、たとえばローション、バルム剤、乳液、ジェル、クリーム、スプレー、シャワージェルおよびシャンプー;リップケア製品たとえばスチックおよびポマード;脱毛用製品たとえばクリームおよびフォーム、フェースマスク;スポーツ用製品たとえばオイル、トニック、乳液、クリーム、ジェル、スプレーおよびバルム剤;毛髪洗浄用製品およびヘアケア製品、たとえばシャンプー、リンス、コンディショナー、トニック、ポマード、オイル、ジェル、クリーム、バルム剤、染料および香料;石鹸類たとえば化粧石鹸および液体石鹸;入浴用製品たとえばオイルバスおよびフォームバス;タルクパウダー;フットケア製品たとえばフットバス、クリーム、ジェル、乳液、スプレー;スキンマッサージ製品たとえばオイル、クリーム、ローション、乳液およびスプレー;口腔および歯牙ケア製品、たとえば歯磨きペースト、歯磨きジェル、口腔洗浄剤、マウススプレー、うがい用配合剤、楊枝、デンタルフロス、義歯洗浄剤、ウォーターピックおよびチューインガム;
タバコ商品:
紙巻タバコ、葉巻タバコ、噛みタバコ、嗅ぎタバコ、パイプタバコ、フィルターチップ;
家庭用製品:
手洗い用液、布、トイレットペーパー、空気浄化剤およびストロー;
医薬配合剤:
殺菌剤軟膏、胃疾患用の抗酸剤、リニメント剤、鎮痛剤、鎮咳剤混合物、のど用ドロップおよびデンタルリンス;
織物処理剤
洗浄剤、織物柔軟剤、織物含浸剤、仕上げ剤。
実施例2
D25 25=1.0750;nD 20=1.4720;αD 25=−59.60°(エタノール中10%濃度)。収率:クロロギ酸メンチルを基準にして理論量の73.4%。
実施例3
実施例4
実施例5
D25 25=1.0154;nD 20=1.4578;αD 25=−62.2°(エタノール中10%濃度)。収率:クロロギ酸メンチルを基準にして理論量の82.1%。
実施例6
融点77.8〜78.6℃;αD 20=−66.3°(エタノール中10%濃度)。
実施例7
実施例8
実施例9
実施例10
実施例11
nD 20=1.4739;αD 20=−50°(エタノール中10%濃度)。
実施例12
実施例13
実施例14
収率:理論量の46.3%。
Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4226043A DE4226043A1 (de) | 1992-08-06 | 1992-08-06 | Mittel mit physiologischem Kühleffekt und für diese Mittel geeignete wirksame Verbindungen |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP21101693A Division JP4020980B2 (ja) | 1992-08-06 | 1993-08-04 | 生理学的な清涼効果を有する化学剤およびこの化学剤に適した活性化合物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2005232184A JP2005232184A (ja) | 2005-09-02 |
JP4065881B2 true JP4065881B2 (ja) | 2008-03-26 |
Family
ID=6464997
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP21101693A Expired - Lifetime JP4020980B2 (ja) | 1992-08-06 | 1993-08-04 | 生理学的な清涼効果を有する化学剤およびこの化学剤に適した活性化合物 |
JP2005081952A Expired - Lifetime JP4065881B2 (ja) | 1992-08-06 | 2005-03-22 | 生理学的な清涼効果を有する化合物 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP21101693A Expired - Lifetime JP4020980B2 (ja) | 1992-08-06 | 1993-08-04 | 生理学的な清涼効果を有する化学剤およびこの化学剤に適した活性化合物 |
Country Status (10)
Country | Link |
---|---|
US (1) | US5703123A (ja) |
EP (1) | EP0583651B1 (ja) |
JP (2) | JP4020980B2 (ja) |
AT (1) | ATE154587T1 (ja) |
AU (1) | AU667556B2 (ja) |
CA (1) | CA2101790A1 (ja) |
DE (2) | DE4226043A1 (ja) |
DK (1) | DK0583651T3 (ja) |
ES (1) | ES2103045T3 (ja) |
GR (1) | GR3024499T3 (ja) |
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KR20230073441A (ko) * | 2021-11-18 | 2023-05-26 | 주식회사 케이티앤지 | 신규한 향미제, 향미제 조성물 및 이를 포함하는 제품 |
WO2023143741A1 (de) | 2022-01-28 | 2023-08-03 | Symrise Ag | Neue kühlstoffe und zubereitungen, die diese enthalten |
WO2023147852A1 (en) | 2022-02-02 | 2023-08-10 | Symrise Ag | Compositions (iii) |
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WO2022207944A2 (en) | 2022-07-11 | 2022-10-06 | Symrise Ag | Novel mixtures and uses of (2e)-3-(1,3-benzodioxol-5-yl)-n-phenyl-n-(tetrahydro-3-furanyl)-2-propenamide |
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Publication number | Priority date | Publication date | Assignee | Title |
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GB1054346A (ja) * | 1964-10-01 | 1900-01-01 | ||
GB1476351A (en) * | 1974-04-17 | 1977-06-10 | Wilkinson Sword Ltd | Compounds having a physiological cooling effect and compo sitions containing them |
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1992
- 1992-08-06 DE DE4226043A patent/DE4226043A1/de not_active Withdrawn
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1993
- 1993-07-26 DK DK93111919.2T patent/DK0583651T3/da active
- 1993-07-26 EP EP93111919A patent/EP0583651B1/de not_active Expired - Lifetime
- 1993-07-26 DE DE59306774T patent/DE59306774D1/de not_active Expired - Lifetime
- 1993-07-26 AT AT93111919T patent/ATE154587T1/de not_active IP Right Cessation
- 1993-07-26 ES ES93111919T patent/ES2103045T3/es not_active Expired - Lifetime
- 1993-07-28 AU AU44256/93A patent/AU667556B2/en not_active Ceased
- 1993-08-03 CA CA002101790A patent/CA2101790A1/en not_active Abandoned
- 1993-08-04 JP JP21101693A patent/JP4020980B2/ja not_active Expired - Lifetime
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1995
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Also Published As
Publication number | Publication date |
---|---|
JP2005232184A (ja) | 2005-09-02 |
CA2101790A1 (en) | 1994-02-07 |
EP0583651A1 (de) | 1994-02-23 |
DE59306774D1 (de) | 1997-07-24 |
GR3024499T3 (de) | 1997-11-28 |
JP4020980B2 (ja) | 2007-12-12 |
JPH06199740A (ja) | 1994-07-19 |
AU667556B2 (en) | 1996-03-28 |
US5703123A (en) | 1997-12-30 |
DE4226043A1 (de) | 1994-02-10 |
ATE154587T1 (de) | 1997-07-15 |
ES2103045T3 (es) | 1997-08-16 |
AU4425693A (en) | 1994-02-10 |
EP0583651B1 (de) | 1997-06-18 |
DK0583651T3 (da) | 1997-12-29 |
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