JP4034355B2 - 熱安定な非アジド系の、自動車用エアバッグ用の推進剤 - Google Patents
熱安定な非アジド系の、自動車用エアバッグ用の推進剤 Download PDFInfo
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- JP4034355B2 JP4034355B2 JP50888898A JP50888898A JP4034355B2 JP 4034355 B2 JP4034355 B2 JP 4034355B2 JP 50888898 A JP50888898 A JP 50888898A JP 50888898 A JP50888898 A JP 50888898A JP 4034355 B2 JP4034355 B2 JP 4034355B2
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- JP
- Japan
- Prior art keywords
- mixture
- gas generating
- weight
- gas
- nitroguanidine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 150000001540 azides Chemical class 0.000 title claims description 27
- 239000003380 propellant Substances 0.000 title description 11
- 239000000203 mixture Substances 0.000 claims description 119
- 239000007789 gas Substances 0.000 claims description 95
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 54
- 239000000446 fuel Substances 0.000 claims description 34
- IDCPFAYURAQKDZ-UHFFFAOYSA-N 1-nitroguanidine Chemical compound NC(=N)N[N+]([O-])=O IDCPFAYURAQKDZ-UHFFFAOYSA-N 0.000 claims description 27
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 27
- 150000003839 salts Chemical class 0.000 claims description 26
- -1 alkaline earth metal salts Chemical class 0.000 claims description 24
- 239000007800 oxidant agent Substances 0.000 claims description 24
- KJUGUADJHNHALS-UHFFFAOYSA-N 1H-tetrazole Substances C=1N=NNN=1 KJUGUADJHNHALS-UHFFFAOYSA-N 0.000 claims description 19
- 238000002485 combustion reaction Methods 0.000 claims description 18
- 230000001590 oxidative effect Effects 0.000 claims description 18
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 11
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 7
- 239000003513 alkali Substances 0.000 claims description 6
- 239000002893 slag Substances 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 239000004927 clay Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 3
- 229910001964 alkaline earth metal nitrate Inorganic materials 0.000 claims description 3
- 239000002826 coolant Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 229910001963 alkali metal nitrate Inorganic materials 0.000 claims description 2
- FGHAZDVJHATENE-UHFFFAOYSA-N [N-]=[N+]=[N-].[N-]=[N+]=[N-].[N-]=[N+]=[N-].[NH6+3] Chemical compound [N-]=[N+]=[N-].[N-]=[N+]=[N-].[N-]=[N+]=[N-].[NH6+3] FGHAZDVJHATENE-UHFFFAOYSA-N 0.000 claims 2
- 239000003607 modifier Substances 0.000 claims 2
- XLXWQTRKKYVWBJ-UHFFFAOYSA-N nitric acid;1,1,2-triaminoguanidine Chemical compound O[N+]([O-])=O.N\N=C(\N)N(N)N XLXWQTRKKYVWBJ-UHFFFAOYSA-N 0.000 claims 2
- 150000003536 tetrazoles Chemical class 0.000 description 22
- 150000003852 triazoles Chemical class 0.000 description 22
- 239000008188 pellet Substances 0.000 description 17
- 239000007787 solid Substances 0.000 description 13
- 239000002360 explosive Substances 0.000 description 10
- 150000001412 amines Chemical class 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 239000011230 binding agent Substances 0.000 description 8
- NDEMNVPZDAFUKN-UHFFFAOYSA-N guanidine;nitric acid Chemical compound NC(N)=N.O[N+]([O-])=O.O[N+]([O-])=O NDEMNVPZDAFUKN-UHFFFAOYSA-N 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- HURPOIVZCDCEEE-UHFFFAOYSA-N n-(2h-tetrazol-5-yl)nitramide Chemical compound [O-][N+](=O)NC=1N=NNN=1 HURPOIVZCDCEEE-UHFFFAOYSA-N 0.000 description 7
- 239000002341 toxic gas Substances 0.000 description 7
- ULRPISSMEBPJLN-UHFFFAOYSA-N 2h-tetrazol-5-amine Chemical compound NC1=NN=NN1 ULRPISSMEBPJLN-UHFFFAOYSA-N 0.000 description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 231100000252 nontoxic Toxicity 0.000 description 5
- 230000003000 nontoxic effect Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- ZGZLYKUHYXFIIO-UHFFFAOYSA-N 5-nitro-2h-tetrazole Chemical compound [O-][N+](=O)C=1N=NNN=1 ZGZLYKUHYXFIIO-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 239000012265 solid product Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- MOKRDWKSHLLYKM-UHFFFAOYSA-N 2-hydrazinyl-2-oxoacetamide Chemical compound NNC(=O)C(N)=O MOKRDWKSHLLYKM-UHFFFAOYSA-N 0.000 description 3
- YXFWFUSVDJIVIV-UHFFFAOYSA-N 4-nitro-2h-triazole Chemical compound [O-][N+](=O)C=1C=NNN=1 YXFWFUSVDJIVIV-UHFFFAOYSA-N 0.000 description 3
- YTNLBRCAVHCUPD-UHFFFAOYSA-N 5-(1$l^{2},2,3,4-tetrazol-5-yl)-1$l^{2},2,3,4-tetrazole Chemical compound [N]1N=NN=C1C1=NN=N[N]1 YTNLBRCAVHCUPD-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- YIKSCQDJHCMVMK-UHFFFAOYSA-N Oxamide Chemical compound NC(=O)C(N)=O YIKSCQDJHCMVMK-UHFFFAOYSA-N 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 150000001342 alkaline earth metals Chemical class 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- HAMNKKUPIHEESI-UHFFFAOYSA-N aminoguanidine Chemical class NNC(N)=N HAMNKKUPIHEESI-UHFFFAOYSA-N 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 150000002357 guanidines Chemical class 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052755 nonmetal Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 235000010333 potassium nitrate Nutrition 0.000 description 3
- 239000004323 potassium nitrate Substances 0.000 description 3
- KPTSBKIDIWXFLF-UHFFFAOYSA-N 1,1,2-triaminoguanidine Chemical compound NN=C(N)N(N)N KPTSBKIDIWXFLF-UHFFFAOYSA-N 0.000 description 2
- FQQQSNAVVZSYMB-UHFFFAOYSA-N 1,1-diaminoguanidine Chemical compound NN(N)C(N)=N FQQQSNAVVZSYMB-UHFFFAOYSA-N 0.000 description 2
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 description 2
- CEYAABCXMIRIGC-UHFFFAOYSA-N 3-nitro-1h-1,2,4-triazol-5-amine Chemical compound NC1=NC([N+]([O-])=O)=NN1 CEYAABCXMIRIGC-UHFFFAOYSA-N 0.000 description 2
- MTAYYBKXNAEQOK-UHFFFAOYSA-N 5-(2h-tetrazol-5-yl)-2h-tetrazole Chemical compound N1N=NC(C2=NNN=N2)=N1 MTAYYBKXNAEQOK-UHFFFAOYSA-N 0.000 description 2
- QJTIRVUEVSKJTK-UHFFFAOYSA-N 5-nitro-1,2-dihydro-1,2,4-triazol-3-one Chemical compound [O-][N+](=O)C1=NC(=O)NN1 QJTIRVUEVSKJTK-UHFFFAOYSA-N 0.000 description 2
- KLSJWNVTNUYHDU-UHFFFAOYSA-N Amitrole Chemical class NC1=NC=NN1 KLSJWNVTNUYHDU-UHFFFAOYSA-N 0.000 description 2
- 235000015842 Hesperis Nutrition 0.000 description 2
- 235000012633 Iberis amara Nutrition 0.000 description 2
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 235000019399 azodicarbonamide Nutrition 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 150000001728 carbonyl compounds Chemical class 0.000 description 2
- XEVRDFDBXJMZFG-UHFFFAOYSA-N carbonyl dihydrazine Chemical compound NNC(=O)NN XEVRDFDBXJMZFG-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- 238000004200 deflagration Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 2
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- GWDHDCZHOJHGSW-UHFFFAOYSA-N n-(2h-triazol-4-yl)nitramide Chemical compound [O-][N+](=O)NC=1C=NNN=1 GWDHDCZHOJHGSW-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 description 2
- 125000003831 tetrazolyl group Chemical group 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 125000001425 triazolyl group Chemical group 0.000 description 2
- 239000000015 trinitrotoluene Substances 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- JGZAFSFVZSXXCJ-ONEGZZNKSA-N (E)-bis(2H-tetrazol-5-yl)diazene Chemical compound N(=N\C1=NN=NN1)/C1=NN=NN1 JGZAFSFVZSXXCJ-ONEGZZNKSA-N 0.000 description 1
- QLSWIGRIBOSFMV-UHFFFAOYSA-N 1h-pyrrol-2-amine Chemical class NC1=CC=CN1 QLSWIGRIBOSFMV-UHFFFAOYSA-N 0.000 description 1
- KZFDKINRISJFCO-UHFFFAOYSA-N 2-[(8-methyl-8-azabicyclo[3.2.1]octan-3-yl)oxy-phenylmethyl]aniline Chemical compound CN1C(C2)CCC1CC2OC(C=1C(=CC=CC=1)N)C1=CC=CC=C1 KZFDKINRISJFCO-UHFFFAOYSA-N 0.000 description 1
- LATARDKGGAXMRS-UHFFFAOYSA-N 2-nitro-1h-1,2,4-triazol-3-one Chemical compound [O-][N+](=O)N1NC=NC1=O LATARDKGGAXMRS-UHFFFAOYSA-N 0.000 description 1
- FTBBGQKRYUTLMP-UHFFFAOYSA-N 2-nitro-1h-pyrrole Chemical compound [O-][N+](=O)C1=CC=CN1 FTBBGQKRYUTLMP-UHFFFAOYSA-N 0.000 description 1
- SXMBECNFEHPCNP-UHFFFAOYSA-N 3,5-dinitro-1h-1,2,4-triazole Chemical compound [O-][N+](=O)C1=NNC([N+]([O-])=O)=N1 SXMBECNFEHPCNP-UHFFFAOYSA-N 0.000 description 1
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 description 1
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical class C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 description 1
- NVKJOXRVEKMMHS-UHFFFAOYSA-N 5-nitro-1,2,4-triazol-3-one Chemical compound [O-][N+](=O)C1=NC(=O)N=N1 NVKJOXRVEKMMHS-UHFFFAOYSA-N 0.000 description 1
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- 241001561902 Chaetodon citrinellus Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
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- TZRXHJWUDPFEEY-UHFFFAOYSA-N Pentaerythritol Tetranitrate Chemical compound [O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O TZRXHJWUDPFEEY-UHFFFAOYSA-N 0.000 description 1
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- VGGYAUGSUUKNPW-UHFFFAOYSA-N azane N-(2H-tetrazol-5-yl)nitramide Chemical compound C1(=NNN=N1)N[N+](=O)[O-].N VGGYAUGSUUKNPW-UHFFFAOYSA-N 0.000 description 1
- ZKTARFAXHMRZEF-UHFFFAOYSA-N azane;5-(2h-tetrazol-5-yl)-2h-tetrazole Chemical compound N.N.N1N=NC(C2=NNN=N2)=N1 ZKTARFAXHMRZEF-UHFFFAOYSA-N 0.000 description 1
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- ONCCWDRMOZMNSM-FBCQKBJTSA-N compound Z Chemical compound N1=C2C(=O)NC(N)=NC2=NC=C1C(=O)[C@H]1OP(O)(=O)OC[C@H]1O ONCCWDRMOZMNSM-FBCQKBJTSA-N 0.000 description 1
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- SNFOERUNNSHUGP-ZXZARUISSA-N erythrityl tetranitrate Chemical compound [O-][N+](=O)OC[C@@H](O[N+]([O-])=O)[C@@H](O[N+]([O-])=O)CO[N+]([O-])=O SNFOERUNNSHUGP-ZXZARUISSA-N 0.000 description 1
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- JKMRKVRTECEDPV-UHFFFAOYSA-N n-(1h-1,2,4-triazol-5-yl)nitramide Chemical compound [O-][N+](=O)NC1=NC=NN1 JKMRKVRTECEDPV-UHFFFAOYSA-N 0.000 description 1
- QCOXCILKVHKOGO-UHFFFAOYSA-N n-(2-nitramidoethyl)nitramide Chemical compound [O-][N+](=O)NCCN[N+]([O-])=O QCOXCILKVHKOGO-UHFFFAOYSA-N 0.000 description 1
- UAGLZAPCOXRKPH-UHFFFAOYSA-N nitric acid;1,2,3-triaminoguanidine Chemical compound O[N+]([O-])=O.NNC(NN)=NN UAGLZAPCOXRKPH-UHFFFAOYSA-N 0.000 description 1
- TVIRJXQLFRFUCD-UHFFFAOYSA-N nitric acid;2h-tetrazol-5-amine Chemical compound O[N+]([O-])=O.NC1=NN=NN1 TVIRJXQLFRFUCD-UHFFFAOYSA-N 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
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- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 125000000914 phenoxymethylpenicillanyl group Chemical group CC1(S[C@H]2N([C@H]1C(=O)*)C([C@H]2NC(COC2=CC=CC=C2)=O)=O)C 0.000 description 1
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- 239000003507 refrigerant Substances 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- JDFUJAMTCCQARF-UHFFFAOYSA-N tatb Chemical compound NC1=C([N+]([O-])=O)C(N)=C([N+]([O-])=O)C(N)=C1[N+]([O-])=O JDFUJAMTCCQARF-UHFFFAOYSA-N 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- 238000005382 thermal cycling Methods 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06D—MEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
- C06D7/00—Compositions for gas-attacks
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06D—MEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
- C06D5/00—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets
- C06D5/06—Generation of pressure gas, e.g. for blasting cartridges, starting cartridges, rockets by reaction of two or more solids
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Air Bags (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US68166296A | 1996-07-29 | 1996-07-29 | |
| US08/681,662 | 1996-07-29 | ||
| US08/851,503 | 1997-05-05 | ||
| US08/851,503 US6306232B1 (en) | 1996-07-29 | 1997-05-05 | Thermally stable nonazide automotive airbag propellants |
| PCT/US1997/012579 WO1998004507A1 (en) | 1996-07-29 | 1997-07-10 | Thermally stable nonazide automotive airbag propellants |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2002511828A JP2002511828A (ja) | 2002-04-16 |
| JP2002511828A5 JP2002511828A5 (enExample) | 2005-03-10 |
| JP4034355B2 true JP4034355B2 (ja) | 2008-01-16 |
Family
ID=27102700
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50888898A Expired - Fee Related JP4034355B2 (ja) | 1996-07-29 | 1997-07-10 | 熱安定な非アジド系の、自動車用エアバッグ用の推進剤 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6306232B1 (enExample) |
| EP (1) | EP0915813A4 (enExample) |
| JP (1) | JP4034355B2 (enExample) |
| KR (1) | KR19990037948A (enExample) |
| CN (1) | CN1228752A (enExample) |
| AU (1) | AU3803897A (enExample) |
| WO (1) | WO1998004507A1 (enExample) |
Families Citing this family (51)
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| US7575648B1 (en) * | 1996-08-12 | 2009-08-18 | Automotive Systems Laboratory, Inc. | Selective non-catalytic reduction (SNCR) of toxic gaseous effluents |
| US5872329A (en) * | 1996-11-08 | 1999-02-16 | Automotive Systems Laboratory, Inc. | Nonazide gas generant compositions |
| US6074502A (en) * | 1996-11-08 | 2000-06-13 | Automotive Systems Laboratory, Inc. | Smokeless gas generant compositions |
| JP3641343B2 (ja) * | 1997-03-21 | 2005-04-20 | ダイセル化学工業株式会社 | 低残渣エアバッグ用ガス発生剤組成物 |
| CA2318766A1 (en) * | 1998-03-12 | 1999-09-16 | Automotive Systems Laboratory, Inc. | High gas yield non-azide gas generants |
| JPH11292678A (ja) * | 1998-04-15 | 1999-10-26 | Daicel Chem Ind Ltd | エアバッグ用ガス発生剤組成物 |
| US6296724B1 (en) | 1998-07-21 | 2001-10-02 | Trw Inc. | Gas generating composition for an inflatable vehicle occupant protection device |
| US6859799B1 (en) | 1998-11-30 | 2005-02-22 | Gemstar Development Corporation | Search engine for video and graphics |
| DE29821544U1 (de) * | 1998-12-02 | 1999-02-18 | TRW Airbag Systems GmbH & Co. KG, 84544 Aschau | Azidfreie, gaserzeugende Zusammensetzung |
| US6017404A (en) * | 1998-12-23 | 2000-01-25 | Atlantic Research Corporation | Nonazide ammonium nitrate based gas generant compositions that burn at ambient pressure |
| EP1202943A1 (en) * | 1999-07-02 | 2002-05-08 | Automotive Systems Laboratory Inc. | Gas generant compositions containing a silicone coating |
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| JP4248254B2 (ja) * | 2001-04-20 | 2009-04-02 | 日本化薬株式会社 | ガス発生剤組成物 |
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| US20060289096A1 (en) * | 2003-07-25 | 2006-12-28 | Mendenhall Ivan V | Extrudable gas generant |
| US20050082804A1 (en) * | 2003-10-17 | 2005-04-21 | Khandhadia Paresh S. | Filterless airbag module |
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| JP2007534587A (ja) | 2004-03-30 | 2007-11-29 | オートモーティブ システムズ ラボラトリィ、 インク． | ガス生成システム |
| US7667045B2 (en) | 2004-06-02 | 2010-02-23 | Automotive Systems Laboratory, Inc. | Gas generant and synthesis |
| US7811397B2 (en) | 2004-09-27 | 2010-10-12 | Daicel Chemical Industries, Ltd. | Gas generating agent |
| US7686901B2 (en) * | 2004-10-12 | 2010-03-30 | Automotive Systems Laboratory, Inc. | Gas generant compositions |
| WO2006050444A1 (en) * | 2004-11-01 | 2006-05-11 | Automotive Systems Laboratory, Inc. | Water-based synthesis of poly(tetrazoles) |
| US7776169B2 (en) * | 2005-06-01 | 2010-08-17 | Automotive Systems Laboratory, Inc. | Water-based synthesis of poly(tetrazoles) and articles formed therefrom |
| US7654565B2 (en) * | 2005-06-02 | 2010-02-02 | Automotive Systems Laboratory, Inc. | Gas generating system |
| WO2008059318A2 (en) | 2005-07-31 | 2008-05-22 | Automotive Systems Laboratory, Inc. | Water-based synthesis of poly(tetrazoles) and articles formed therefrom |
| WO2007041384A2 (en) * | 2005-09-29 | 2007-04-12 | Automotive Systems Laboratory, Inc. | Gas generant |
| US20090008003A1 (en) * | 2005-09-30 | 2009-01-08 | Burns Sean P | Gas generant |
| US20070169863A1 (en) * | 2006-01-19 | 2007-07-26 | Hordos Deborah L | Autoignition main gas generant |
| US20100326575A1 (en) * | 2006-01-27 | 2010-12-30 | Miller Cory G | Synthesis of 2-nitroimino-5-nitrohexahydro-1,3,5-triazine |
| US7959749B2 (en) * | 2006-01-31 | 2011-06-14 | Tk Holdings, Inc. | Gas generating composition |
| US20070277915A1 (en) * | 2006-05-31 | 2007-12-06 | Hordos Deborah L | Gas generant compositions |
| US20080271825A1 (en) * | 2006-09-29 | 2008-11-06 | Halpin Jeffrey W | Gas generant |
| JP2008201404A (ja) | 2006-12-20 | 2008-09-04 | Tk Holdings Inc | ガス生成システム |
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| US9045380B1 (en) | 2007-10-31 | 2015-06-02 | Tk Holdings Inc. | Gas generating compositions |
| US9556078B1 (en) | 2008-04-07 | 2017-01-31 | Tk Holdings Inc. | Gas generator |
| US8276516B1 (en) | 2008-10-30 | 2012-10-02 | Reynolds Systems, Inc. | Apparatus for detonating a triaminotrinitrobenzene charge |
| DE102010062382A1 (de) | 2009-12-04 | 2011-09-01 | Tk Holdings, Inc. | Gaserzeugungssystem |
| DE102012217718A1 (de) | 2011-09-30 | 2013-04-04 | Diehl Bgt Defence Gmbh & Co. Kg | Pyrotechnische Kaltgasgeneratoren |
| CN103724287A (zh) * | 2012-10-10 | 2014-04-16 | 同济大学 | 1,1’-二羟基-5,5’-联四唑铵盐及其制备方法 |
| US20140150935A1 (en) * | 2012-11-30 | 2014-06-05 | Tk Holdings Inc. | Self-healing additive technology |
| CN105272929A (zh) * | 2015-11-02 | 2016-01-27 | 西安近代化学研究所 | 草酰肼的5-硝基-1,2,4-三唑-5-酮盐化合物 |
| EP3397430A4 (en) | 2015-12-28 | 2020-04-22 | Enhance Technologies, LLC | HEADREST SYSTEMS AND METHOD FOR USE |
| CN109153620B (zh) * | 2016-05-09 | 2021-08-17 | 德力能欧洲有限公司 | 高温启爆器 |
| CN106478323A (zh) * | 2016-10-21 | 2017-03-08 | 重庆大学 | 一种高性能电控固体推进剂及其制备方法 |
| CN110590482A (zh) * | 2019-10-21 | 2019-12-20 | 周昭坤 | 一种用于烟花炮竹的环保火药 |
| CN115594554B (zh) * | 2022-10-28 | 2023-09-01 | 湖北航天化学技术研究所 | 一种液体型三聚氰胺类降速剂及其制备方法和一种固体推进剂 |
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-
1997
- 1997-05-05 US US08/851,503 patent/US6306232B1/en not_active Expired - Lifetime
- 1997-07-10 WO PCT/US1997/012579 patent/WO1998004507A1/en not_active Ceased
- 1997-07-10 CN CN97196919A patent/CN1228752A/zh active Pending
- 1997-07-10 AU AU38038/97A patent/AU3803897A/en not_active Abandoned
- 1997-07-10 JP JP50888898A patent/JP4034355B2/ja not_active Expired - Fee Related
- 1997-07-10 EP EP97934999A patent/EP0915813A4/en not_active Withdrawn
-
1999
- 1999-01-23 KR KR1019997000557A patent/KR19990037948A/ko not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| JP2002511828A (ja) | 2002-04-16 |
| EP0915813A1 (en) | 1999-05-19 |
| EP0915813A4 (en) | 2003-04-02 |
| KR19990037948A (ko) | 1999-05-25 |
| CN1228752A (zh) | 1999-09-15 |
| AU3803897A (en) | 1998-02-20 |
| US6306232B1 (en) | 2001-10-23 |
| WO1998004507A1 (en) | 1998-02-05 |
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