JP4004550B2 - メタノールの製造 - Google Patents
メタノールの製造 Download PDFInfo
- Publication number
- JP4004550B2 JP4004550B2 JP50188599A JP50188599A JP4004550B2 JP 4004550 B2 JP4004550 B2 JP 4004550B2 JP 50188599 A JP50188599 A JP 50188599A JP 50188599 A JP50188599 A JP 50188599A JP 4004550 B2 JP4004550 B2 JP 4004550B2
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- JP
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- Prior art keywords
- gas
- synthesis
- methanol
- steam
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 177
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 239000007789 gas Substances 0.000 claims abstract description 150
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 115
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 114
- 239000003054 catalyst Substances 0.000 claims abstract description 52
- 239000000203 mixture Substances 0.000 claims abstract description 36
- 238000000034 method Methods 0.000 claims abstract description 31
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 27
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 27
- 238000002407 reforming Methods 0.000 claims abstract description 27
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 24
- 239000001257 hydrogen Substances 0.000 claims abstract description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000002485 combustion reaction Methods 0.000 claims abstract description 17
- 230000006835 compression Effects 0.000 claims abstract description 12
- 238000007906 compression Methods 0.000 claims abstract description 12
- 238000001816 cooling Methods 0.000 claims abstract description 10
- 229910002090 carbon oxide Inorganic materials 0.000 claims abstract description 7
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract 2
- 238000000629 steam reforming Methods 0.000 claims description 13
- 239000000567 combustion gas Substances 0.000 claims description 11
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- 230000003134 recirculating effect Effects 0.000 claims 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 5
- 238000000926 separation method Methods 0.000 abstract description 5
- 238000001193 catalytic steam reforming Methods 0.000 abstract 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 28
- 239000000047 product Substances 0.000 description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
- 239000002826 coolant Substances 0.000 description 11
- 238000010438 heat treatment Methods 0.000 description 11
- 239000000376 reactant Substances 0.000 description 11
- 238000011084 recovery Methods 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 150000002431 hydrogen Chemical class 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 238000004821 distillation Methods 0.000 description 6
- 239000000446 fuel Substances 0.000 description 6
- 238000010791 quenching Methods 0.000 description 6
- 239000003345 natural gas Substances 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 238000009835 boiling Methods 0.000 description 4
- 230000000171 quenching effect Effects 0.000 description 4
- 238000006057 reforming reaction Methods 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000012043 crude product Substances 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- KYYSIVCCYWZZLR-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)molybdenum Chemical compound [Co+2].[O-][Mo]([O-])(=O)=O KYYSIVCCYWZZLR-UHFFFAOYSA-N 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-M hydrosulfide Chemical compound [SH-] RWSOTUBLDIXVET-UHFFFAOYSA-M 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D7/10—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged one within the other, e.g. concentrically
- F28D7/12—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged one within the other, e.g. concentrically the surrounding tube being closed at one end, e.g. return type
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- C—CHEMISTRY; METALLURGY
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
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- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
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- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
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- C—CHEMISTRY; METALLURGY
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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- C01B2203/0465—Composition of the impurity
- C01B2203/0495—Composition of the impurity the impurity being water
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- C01B2203/061—Methanol production
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- C—CHEMISTRY; METALLURGY
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C—CHEMISTRY; METALLURGY
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- C01B2203/0827—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel at least part of the fuel being a recycle stream
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- C—CHEMISTRY; METALLURGY
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
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- C—CHEMISTRY; METALLURGY
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- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C—CHEMISTRY; METALLURGY
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/1041—Composition of the catalyst
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- C01B2203/1052—Nickel or cobalt catalysts
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- C—CHEMISTRY; METALLURGY
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/1205—Composition of the feed
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- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/1264—Catalytic pre-treatment of the feed
- C01B2203/127—Catalytic desulfurisation
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
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- C—CHEMISTRY; METALLURGY
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
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- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9712209.7A GB9712209D0 (en) | 1997-06-13 | 1997-06-13 | Methanol |
| GB9712209.7 | 1997-06-13 | ||
| PCT/GB1998/001670 WO1998056744A1 (en) | 1997-06-13 | 1998-06-08 | Production of methanol |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2002504111A JP2002504111A (ja) | 2002-02-05 |
| JP2002504111A5 JP2002504111A5 (enExample) | 2005-10-06 |
| JP4004550B2 true JP4004550B2 (ja) | 2007-11-07 |
Family
ID=10814024
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50188599A Expired - Fee Related JP4004550B2 (ja) | 1997-06-13 | 1998-06-08 | メタノールの製造 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6255357B1 (enExample) |
| EP (1) | EP0988267B1 (enExample) |
| JP (1) | JP4004550B2 (enExample) |
| AT (1) | ATE252071T1 (enExample) |
| AU (1) | AU728230B2 (enExample) |
| CA (1) | CA2289643C (enExample) |
| DE (1) | DE69818996T2 (enExample) |
| DK (1) | DK0988267T3 (enExample) |
| GB (1) | GB9712209D0 (enExample) |
| NO (1) | NO325283B1 (enExample) |
| WO (1) | WO1998056744A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11001547B2 (en) | 2015-12-04 | 2021-05-11 | Mitsubishi Heavy Industries Engineering, Ltd. | System and method for producing methanol |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2365019A (en) * | 2000-06-06 | 2002-02-13 | Ici Plc | Primary steam reforming plant |
| JP4959074B2 (ja) * | 2001-07-19 | 2012-06-20 | 三菱重工業株式会社 | メタノールの製造方法 |
| JP4781612B2 (ja) * | 2003-04-18 | 2011-09-28 | 三菱重工業株式会社 | メタノールの製造方法 |
| JP4496950B2 (ja) * | 2004-01-09 | 2010-07-07 | 株式会社日立製作所 | 改質炉システム |
| RU2254322C1 (ru) * | 2004-02-05 | 2005-06-20 | Юнусов Рауф Раисович | Способ получения метанола из газа газовых и газоконденсатных месторождений |
| AU2012227278B2 (en) * | 2005-09-23 | 2014-06-05 | Heatric | Multiple reactor chemical production system |
| AU2006339054B2 (en) * | 2005-09-23 | 2012-07-12 | Heatric | Multiple reactor chemical production system |
| CA2623390C (en) | 2005-09-23 | 2011-08-23 | Heatric | Multiple reactor chemical production system |
| US20080260631A1 (en) | 2007-04-18 | 2008-10-23 | H2Gen Innovations, Inc. | Hydrogen production process |
| US9083020B2 (en) * | 2009-09-04 | 2015-07-14 | Lg Fuel Cell Systems Inc. | Reducing gas generators and methods for generating reducing gas |
| KR101777597B1 (ko) | 2010-12-22 | 2017-09-27 | 대우조선해양 주식회사 | 해상용 메탄올 생산 시스템 |
| CN102220903B (zh) * | 2011-05-30 | 2014-01-01 | 重庆大学 | 基于甲烷燃烧-重整的提高燃气轮机循环热力性能的方法 |
| CN102322353B (zh) * | 2011-05-30 | 2014-01-01 | 重庆大学 | 一种提高燃气轮机循环热效率的方法 |
| CN102213142B (zh) * | 2011-05-30 | 2014-01-01 | 重庆大学 | 基于甲烷重整提高燃气轮机再热循环热效率的方法 |
| BR112014024394B1 (pt) * | 2012-03-30 | 2021-05-25 | Monsanto Technology Llc | reformador de álcool para reformar álcool para mistura de gás incluindo hidrogênio |
| US9255051B2 (en) | 2013-03-15 | 2016-02-09 | Gas Technologies Llc | Efficiency, flexibility, and product value of a direct alkanes to oxygenates process |
| US20140275634A1 (en) | 2013-03-15 | 2014-09-18 | Gas Technologies Llc | Ether Blends Via Reactive Distillation |
| US9174903B2 (en) | 2013-03-15 | 2015-11-03 | Gas Technologies Llc | Reactive scrubbing for upgrading product value, simplifying process operation and product handling |
| WO2015050991A1 (en) | 2013-10-01 | 2015-04-09 | Gas Technologies L.L.C. | Diesel fuel composition |
| KR101790102B1 (ko) | 2014-08-04 | 2017-10-25 | 한국화학연구원 | 이산화탄소의 배출을 저감시킬 수 있는 고효율 메탄올 생산 방법 |
| EP3181218A1 (de) * | 2015-12-15 | 2017-06-21 | L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Produktgassammelleitungssystem für einen dampfreformer |
| CN105756782A (zh) * | 2016-04-15 | 2016-07-13 | 浙江大学 | 一种太阳能化学回热燃气轮机系统及其方法 |
| RU2616977C1 (ru) * | 2016-05-26 | 2017-04-19 | Андрей Владиславович Курочкин | Установка синтеза метанола |
| RU2619101C1 (ru) * | 2016-05-26 | 2017-05-12 | Андрей Владиславович Курочкин | Установка получения метанола из углеводородного сырья |
| CN109996760B (zh) * | 2016-10-25 | 2022-09-02 | 法国德西尼布 | 用于重整的催化剂管 |
| EP3714971B1 (en) | 2019-03-28 | 2022-02-02 | Sener, Ingeniería y Sistemas, S.A. | System for methanol production from a synthesis gas rich in hydrogen and co2/co |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4239693A (en) * | 1979-06-22 | 1980-12-16 | Foster Wheeler Energy Corporation | Process for production of methanol |
| GB8803766D0 (en) * | 1988-02-18 | 1988-03-16 | Ici Plc | Methanol |
| GB9000389D0 (en) * | 1990-01-08 | 1990-03-07 | Ici Plc | Steam reforming |
| US5177114A (en) * | 1990-04-11 | 1993-01-05 | Starchem Inc. | Process for recovering natural gas in the form of a normally liquid carbon containing compound |
| US5472986A (en) * | 1994-11-08 | 1995-12-05 | Starchem, Inc. | Methanol production process using a high nitrogen content synthesis gas with a hydrogen recycle |
-
1997
- 1997-06-13 GB GBGB9712209.7A patent/GB9712209D0/en active Pending
-
1998
- 1998-06-08 EP EP98928431A patent/EP0988267B1/en not_active Expired - Lifetime
- 1998-06-08 DE DE69818996T patent/DE69818996T2/de not_active Expired - Lifetime
- 1998-06-08 WO PCT/GB1998/001670 patent/WO1998056744A1/en not_active Ceased
- 1998-06-08 AU AU80263/98A patent/AU728230B2/en not_active Ceased
- 1998-06-08 AT AT98928431T patent/ATE252071T1/de not_active IP Right Cessation
- 1998-06-08 JP JP50188599A patent/JP4004550B2/ja not_active Expired - Fee Related
- 1998-06-08 DK DK98928431T patent/DK0988267T3/da active
- 1998-06-08 CA CA002289643A patent/CA2289643C/en not_active Expired - Fee Related
-
1999
- 1999-12-10 NO NO19996105A patent/NO325283B1/no not_active IP Right Cessation
- 1999-12-13 US US09/459,843 patent/US6255357B1/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11001547B2 (en) | 2015-12-04 | 2021-05-11 | Mitsubishi Heavy Industries Engineering, Ltd. | System and method for producing methanol |
Also Published As
| Publication number | Publication date |
|---|---|
| NO996105D0 (no) | 1999-12-10 |
| GB9712209D0 (en) | 1997-08-13 |
| EP0988267B1 (en) | 2003-10-15 |
| DE69818996T2 (de) | 2004-09-02 |
| JP2002504111A (ja) | 2002-02-05 |
| US6255357B1 (en) | 2001-07-03 |
| CA2289643A1 (en) | 1998-12-17 |
| AU8026398A (en) | 1998-12-30 |
| WO1998056744A1 (en) | 1998-12-17 |
| CA2289643C (en) | 2007-08-28 |
| ATE252071T1 (de) | 2003-11-15 |
| EP0988267A1 (en) | 2000-03-29 |
| NO325283B1 (no) | 2008-03-17 |
| DK0988267T3 (da) | 2004-01-19 |
| NO996105L (no) | 1999-12-10 |
| DE69818996D1 (de) | 2003-11-20 |
| AU728230B2 (en) | 2001-01-04 |
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