JP3943735B2 - Manufacturing method of build-up type multilayer printed wiring board - Google Patents

Manufacturing method of build-up type multilayer printed wiring board Download PDF

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Publication number
JP3943735B2
JP3943735B2 JP31544898A JP31544898A JP3943735B2 JP 3943735 B2 JP3943735 B2 JP 3943735B2 JP 31544898 A JP31544898 A JP 31544898A JP 31544898 A JP31544898 A JP 31544898A JP 3943735 B2 JP3943735 B2 JP 3943735B2
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Japan
Prior art keywords
resin
copper foil
masking
exposed
printed wiring
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JP31544898A
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Japanese (ja)
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JP2000124611A (en
Inventor
裕昭 仲見
桂 小川
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Kyocera Chemical Corp
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Kyocera Chemical Corp
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Description

【0001】
【発明の属する技術分野】
本発明は、電気機器、電子機器、コンピューター、通信機器等に用いられるビルドアップ型多層プリント配線板の製造方法に関するものである。
【0002】
【従来の技術】
最近のセット機器の薄型・小型化の進展により、高密度実装、配線を実現し得るビルドアップ型多層プリント配線板が注目されている。その製造の1工程として、銅箔キャリー付樹脂シートを用いた熱圧成形を繰り返すことによって、順次、絶縁層と配線層とを多層に積上げをしていくビルドアップ工程がある。このビルドアップ工程において、絶縁層の材料がガラス基材を含めない樹脂単体であることに起因して、下記の3 点の高密度配線化の歩留りを損なう問題点がクローズアップされてきた。
【0003】
第一点は、銅箔キャリーの片面に樹脂を塗布、乾燥した後、所定のワークサイズへの切断、それの積載といった過程で、銅箔面への樹脂切断粉の付着による回路形成歩留の低下である。
【0004】
第二点は、ビルドアップ型多層板の配線仕様が従来型のものに対して厳しく、成形時の銅箔面打痕等の発生による外観歩留が低下する。
【0005】
第三点は、銅箔キャリー付樹脂シートが、従来型のガラス基材プリプレグに比べてのその絶縁層厚が薄く、また、ガラス基材を有しないため、弾性率又はクッション性が少ないため、内層回路基板の凹凸の影響を受けやすく、成形時に銅箔のシワ、パターンの浮き出しおよび打痕を発生させ、歩留を低下させることである。
【0006】
【発明が解決しようとする課題】
本発明は、上記の問題点を鑑みてなされたもので、その目的とするところは、前述した銅箔キャリー付樹脂シートを用いるビルドアップ型多層プリント配線板を、銅箔のシワ、パターンの浮き出しおよび打痕の発生がなく、歩留りよく生産できる製造方法を提供することにある。
【0007】
【課題を解決するための手段】
本発明者は、上記の目的を達成しようと鋭意検討を重ねた結果、ビルドアップ型多層プリント配線板の外層用銅箔キャリー付樹脂シートにおける銅露出面に、予めPETフィルムなどの保護マスキングを施したものを用い、かつ、樹脂露出面に離型性保護フィルムを用いれば、多層板製造において、成形時のシワ、パターンの浮き出しおよび打痕などの発生による外観歩留りの低下を少なくでき、かつ、銅箔カット時の樹脂粉の影響を受けないため、回路形成時の歩留り低下の阻止に役立つことを見いだして、本発明を完成するに至った。
【0008】
すなわち、本発明は、
予め片面あるいは両面に導体回路パターンが形成された内層回路基板の片面あるいは両面に、銅箔キャリー付樹脂シートを重ねたものを、金型プレートに挟んで熱圧成形を行う工程を繰り返して配線層を積み重ねる多層プリント配線板の製造方法において、上記銅箔キャリー付樹脂シートとして、銅箔キャリー付樹脂シートにおける銅露出面と樹脂露出面の両方にそれぞれの保護マスキングを施したマスキング銅箔付樹脂シートを使用することを特徴とする多層プリント配線板の製造方法である。
【0009】
以下、本発明を詳細に説明する。
【0010】
本発明に用いる内層回路基板としては、ガラス、アスベスト等の無機繊維やポリエステル、ポリアミド、ポリビニルアルコール、アクリル等の有機合成繊維や木綿等の天然繊維からなる織布、不織布、マットあるいは紙等の基材に、フェノール樹脂、クレゾール樹脂、エポキシ樹脂、不飽和ポリエステル樹脂、メラミン樹脂、ポリイミド、ポリブタジエン、ポリアミド、ポリアミドイミド、ポリスルフォン、ポリフェニレンサルファイド、ポリフェニレンオキサイド、ポリブチレンテレフタレート、ポリエーテルエーテルケトン、フッ素樹脂等の単独、変性物、混合物等の樹脂を含浸乾燥したプリプレグの所要枚数を重ね、その上面および又は下面に銅箔を配設一体化してなる電気用積層板であって、その銅箔に電気回路を形成したものである。
【0011】
本発明における銅箔キャリー付樹脂シートに用いる銅箔としては、電解銅箔、圧延銅箔いずれでもよく、特に制限されるものではなく、銅箔厚さは、一般的に0.006 〜0.07mm程度のものである。銅箔への塗布に用いる樹脂に関しては、前述した内層回路基板の例示含浸樹脂と同様の分野範疇のものが使用され、特に制限されるものではない。銅箔キャリー付樹脂シートの製造については、銅箔の片面に所定厚さの樹脂を常法により塗布乾燥して製造することができる。
【0012】
本発明に用いる銅露出面の保護マスキングは、通常のポリエチレンテレフタレートフィルム(PETフィルム)などの合成樹脂製耐熱性フィルムであるが、特に限定されるものではない。使用するPETフィルムの厚さは、10μm〜150 μmの範囲が好適である。その厚さが10μm未満では、成形時のクッション性の影響
(効果)が少なく、成形時の銅箔シワ、パターンの浮き出し、打痕の発生への抑制効果が十分ではなく、また、厚さが150 μmを超えると成形時の材料のズレ出しが懸念されるので好ましくない。
【0013】
樹脂露出面の保護マスキングは、通常のポリエチレンテレフタレートフィルム(PETフィルム)、OPPフィルム、離型紙等の離型性を有するフィルムが挙げられ、特に限定されるものではないが、シートカット時に発塵等の有害性がなく、また、樹脂面と熱融着による貼合せ時に特にカール及び離型剥離強度に実用上の問題のないものであればよい。
【0014】
保護マスキングの銅箔への貼合せはフィルム片面に粘着剤を付着させて行うものである。貼合せ工程は、一般的に、反対面の樹脂シート用樹脂を塗布する前に行う方が好ましいが、樹脂シート用樹脂の塗布乾燥後でも可能である。粘着剤の種類は、特に限定されるものではないが、樹脂シート用樹脂の塗布、乾燥工程及び多層積層工程で問題がなく、かつ成形後、銅箔面からの剥離が可能で特に粘着樹脂転写等のトラブルがないことが要求される。
【0015】
保護マスキングの樹脂面への貼合せは、樹脂シート用樹脂の塗布、乾燥後に通常、熱ロールを通して樹脂を融着させて離型性フィルムを貼り合わせるものであるが、特に条件等限定されるものではなく、適度の剥離強度を有して、貼合せ後のシートカット化に耐えるものであり、その後の成形時の貼合せ前に問題なく離型性フィルムが剥がせればよい。
【0016】
マスキング銅箔付樹脂シートは、内層板の寸法に合わせて所定のワークサイズにカットして準備する。プレス成形に関しては、通常の多層用多段プレスを用いてクッション等の副資材は、特に成形に問題がなければ、常法にて行うことができ、限定されるものではない。
【0017】
【作用】
本発明の多層プリント配線板の製造方法は、所定の保護マスキングを使用しているため、、かつカット時の樹脂粉及び銅箔粉の発生抑制、成形時の銅箔シワ、パターンの浮き出しの発生抑制および打痕等の銅箔外観の歩留り向上に寄与できる有効な方法となり得る。
【0018】
【実施例】
次に、本発明を実施例によって具体的に説明するが、本発明は、これらの実施例によって限定されるものではない。
【0019】
実施例
ガラス布基材エポキシ樹脂両面銅張積層板(総厚0.5 mm、銅箔厚さ35μm)の両面銅箔に電気回路を形成して内層板を得た。
【0020】
一方、銅箔(12μm厚)の一面にPETフィルム(38μm厚)を粘着剤で貼り合わせたPET保護フィルム付銅箔のTFB−4−434AS(藤森工業株式会社製、商品名)に、エポキシ樹脂を厚さ80μmとなるように塗布乾燥して銅箔面マスキング銅箔付樹脂シートを得た。
【0021】
次に、上記銅箔面マスキング銅箔付樹脂シートにおける樹脂露出面に、PETフィルム(30μm厚)を重ね、熱ロールを用いて熱融着させることにより、所望の両面マスキング銅箔付き樹脂シートを得た。この両面マスキング銅箔付樹脂シートは、前記内層板のサイズに合わせてシートカット化しておく。
【0022】
シートカットした両面マスキング銅箔付樹脂シートは、その樹脂面のPETフィルムだけを剥がし、前記内層板の上下面にそれぞれ、そのマスキング銅箔面を外側にして積載しSUS板に挟んで1 組とする。そのようにした積載組10組を成形圧30kgf/cm2 ,温度170 ℃×120 分間の条件で多段成形し、次いで銅箔面マスキングを剥離して、多層プリント配線板を100 枚製造した。
【0023】
比較例1
実施例において、両面マスキング銅箔付樹脂シートに換えて両面のPETフィルムを用いない銅箔付樹脂シート(銅箔12μm厚、エポキシ樹脂厚さ80μm)を用いた以外は、実施例と同様にして多層プリント配線板を100 枚製造した。
【0024】
比較例2
実施例において、銅箔面マスキング(片面のみ)銅箔付樹脂シートの段階でシートカットした材料を用いた以外は、実施例と同様にして多層プリント配線板を100 枚製造した。
【0025】
こうして得られた実施例及び比較例1,2の多層プリント配線板について、外観の打痕等の歩留り及び銅箔のシワ、内層パターンの浮き出しのレベルを確認した。その結果を表1に示したが、本発明は、銅箔外観の歩留り及び内層回路の浮き出しが良好、また、外層パターン形成の歩留りが良好であることが確認できた。
【0026】
【表1】

Figure 0003943735
【0027】
【発明の効果】
以上の説明および表1から明らかなように、本発明の多層プリント配線板の製造方法によれば、成形時の銅箔のシワ、パターンの浮き出し発生を抑制し、銅箔外観の歩留を向上した多層プリント配線板が製造できる。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a method for manufacturing a build-up type multilayer printed wiring board used for electrical equipment, electronic equipment, computers, communication equipment and the like.
[0002]
[Prior art]
Due to the recent progress in thinning and downsizing of set equipment, a build-up type multilayer printed wiring board that can realize high-density mounting and wiring is attracting attention. As one process of the manufacture, there is a build-up process in which insulating layers and wiring layers are sequentially stacked in layers by repeating hot pressing using a resin sheet with a copper foil carry. In this build-up process, due to the fact that the material of the insulating layer is a single resin that does not include a glass substrate, the following three problems that impair the yield of high-density wiring have been highlighted.
[0003]
The first point is the application of the resin to one side of the copper foil carrier, drying, cutting into a predetermined workpiece size, and loading it in the process of circuit formation yield due to adhesion of resin cutting powder to the copper foil surface. It is a decline.
[0004]
The second point is that the wiring specifications of the build-up type multilayer board are stricter than those of the conventional type, and the appearance yield is reduced due to the occurrence of a copper foil surface dent or the like during molding.
[0005]
The third point is that the resin sheet with a copper foil carry has a thin insulating layer thickness compared to a conventional glass substrate prepreg, and since it does not have a glass substrate, it has a low elastic modulus or cushioning property. It is easy to be affected by the unevenness of the inner layer circuit board, and causes wrinkles of the copper foil, embossing of the pattern and dents at the time of molding to lower the yield.
[0006]
[Problems to be solved by the invention]
The present invention has been made in view of the above-mentioned problems. The object of the present invention is to provide a build-up type multilayer printed wiring board using the above-mentioned resin sheet with a copper foil carry, wrinkles of copper foil, and embossing of patterns. It is another object of the present invention to provide a manufacturing method that can be produced with high yield without generating dents.
[0007]
[Means for Solving the Problems]
As a result of intensive studies to achieve the above-mentioned object, the present inventor previously performed protective masking such as a PET film on the copper exposed surface of the resin sheet with a copper foil carrier for the outer layer of the build-up type multilayer printed wiring board. And using a releasable protective film on the exposed resin surface can reduce the decrease in appearance yield due to the occurrence of wrinkles during patterning, embossing of patterns and dents, etc. Since it is not affected by the resin powder at the time of cutting the copper foil, it has been found useful for preventing a decrease in yield during circuit formation, and the present invention has been completed.
[0008]
That is, the present invention
A wiring layer by repeating a process of hot-pressure molding by sandwiching a metal plate with a copper foil carry resin sheet on one or both sides of an inner circuit board on which a conductor circuit pattern has been previously formed on one or both sides. In the method for manufacturing a multilayer printed wiring board in which the copper foil is stacked, the resin sheet with a copper foil carrying the protective mask on both the copper exposed surface and the resin exposed surface of the resin sheet with the copper foil carry as the resin sheet with the copper foil carry It is the manufacturing method of the multilayer printed wiring board characterized by using this.
[0009]
Hereinafter, the present invention will be described in detail.
[0010]
Examples of the inner layer circuit board used in the present invention include inorganic fibers such as glass and asbestos, organic synthetic fibers such as polyester, polyamide, polyvinyl alcohol, and acrylic, and natural fibers such as cotton, woven fabrics, nonwoven fabrics, mats, and papers. For materials, phenol resin, cresol resin, epoxy resin, unsaturated polyester resin, melamine resin, polyimide, polybutadiene, polyamide, polyamideimide, polysulfone, polyphenylene sulfide, polyphenylene oxide, polybutylene terephthalate, polyether ether ketone, fluorine resin, etc. A laminated sheet for electrical use in which a required number of prepregs impregnated and dried with a resin such as a single product, a modified product, a mixture, etc. are laminated and a copper foil is disposed and integrated on the upper surface and / or the lower surface thereof. Formed .
[0011]
The copper foil used for the resin sheet with a copper foil carry in the present invention may be either an electrolytic copper foil or a rolled copper foil, and is not particularly limited, and the copper foil thickness is generally about 0.006 to 0.07 mm. Is. Regarding the resin used for application to the copper foil, those in the same field category as the exemplary impregnated resin of the inner layer circuit board described above are used, and are not particularly limited. About manufacture of the resin sheet with a copper foil carry, it can manufacture by apply | coating and drying resin of predetermined thickness to the single side | surface of copper foil by a conventional method.
[0012]
The protective masking of the exposed copper surface used in the present invention is a synthetic resin heat-resistant film such as a normal polyethylene terephthalate film (PET film), but is not particularly limited. The thickness of the PET film to be used is preferably in the range of 10 μm to 150 μm. If the thickness is less than 10 μm, there is little influence (effect) of the cushioning property at the time of molding, copper foil wrinkles at the time of molding, pattern relief, and the effect of suppressing the occurrence of dents are not sufficient, and the thickness is If it exceeds 150 μm, the material may be displaced during molding, which is not preferable.
[0013]
The protective masking of the exposed resin surface includes a film having releasability such as a normal polyethylene terephthalate film (PET film), an OPP film, a release paper, and the like. As long as it has no practical problem in curling and release peel strength particularly when bonded to the resin surface by thermal fusion.
[0014]
Lamination of protective masking to copper foil is performed by attaching an adhesive to one side of the film. In general, the laminating step is preferably performed before applying the resin for the resin sheet on the opposite surface, but can be performed even after application and drying of the resin for the resin sheet. The type of pressure-sensitive adhesive is not particularly limited, but there is no problem in the application of the resin for the resin sheet, the drying process and the multi-layer lamination process, and it can be peeled off from the copper foil surface after molding. It is required that there is no trouble such as.
[0015]
Lamination of protective masking on the resin surface is usually performed by applying resin for resin sheet and drying, and then bonding the release film by fusing the resin through a hot roll. Instead, it has an appropriate peel strength and can withstand sheet cutting after lamination, and the releasable film may be peeled off without any problems before lamination at the time of subsequent molding.
[0016]
The resin sheet with masking copper foil is prepared by cutting into a predetermined workpiece size according to the dimensions of the inner layer plate. With respect to press molding, a secondary material such as a cushion using a normal multi-stage press for a multilayer can be carried out in a conventional manner unless there is a problem with molding, and is not limited.
[0017]
[Action]
The manufacturing method of the multilayer printed wiring board of the present invention uses a predetermined protective masking, and suppresses the generation of resin powder and copper foil powder at the time of cutting, copper foil wrinkles at the time of molding, occurrence of pattern embossing It can be an effective method that can contribute to improving the yield of copper foil appearance such as suppression and dents.
[0018]
【Example】
EXAMPLES Next, although an Example demonstrates this invention concretely, this invention is not limited by these Examples.
[0019]
Example An electric circuit was formed on a double-sided copper foil of a glass cloth base epoxy resin double-sided copper-clad laminate (total thickness 0.5 mm, copper foil thickness 35 μm) to obtain an inner layer plate.
[0020]
On the other hand, TFB-4-434AS (trade name, manufactured by Fujimori Kogyo Co., Ltd.), a copper foil with a PET protective film in which a PET film (38 μm thickness) is bonded to one side of a copper foil (12 μm thickness) with an adhesive, is an epoxy resin. Was coated and dried to a thickness of 80 μm to obtain a resin sheet with a copper foil masking copper foil.
[0021]
Next, a resin sheet with a desired double-sided masking copper foil is obtained by overlaying a PET film (30 μm thick) on the resin exposed surface of the resin sheet with copper foil surface masking copper foil and heat-sealing using a hot roll. Obtained. This resin sheet with double-side masking copper foil is cut into sheets according to the size of the inner layer plate.
[0022]
The sheet-cut resin sheet with double-sided masking copper foil peels only the PET film on the resin surface, and is stacked on the upper and lower surfaces of the inner layer plate with the masking copper foil surface facing outside and sandwiched between SUS plates. To do. Ten such stacked groups were molded in multiple stages under a molding pressure of 30 kgf / cm 2 and a temperature of 170 ° C. × 120 minutes, and then the copper foil surface masking was peeled off to produce 100 multilayer printed wiring boards.
[0023]
Comparative Example 1
In the examples, the resin sheet with copper foil (copper foil 12 μm thickness, epoxy resin thickness 80 μm) that does not use a double-sided PET film was used instead of the double-sided masking resin sheet with copper foil. 100 multilayer printed wiring boards were manufactured.
[0024]
Comparative Example 2
In the example, 100 multilayer printed wiring boards were produced in the same manner as in the example except that the material cut in the copper foil surface masking (only one side) resin sheet with copper foil was used.
[0025]
With respect to the multilayer printed wiring boards of Examples and Comparative Examples 1 and 2 thus obtained, the yield such as the dents on the appearance, the wrinkles of the copper foil, and the level of protrusion of the inner layer pattern were confirmed. The results are shown in Table 1, and it was confirmed that the yield of the copper foil appearance and the inner layer circuit was excellent, and the yield of forming the outer layer pattern was good in the present invention.
[0026]
[Table 1]
Figure 0003943735
[0027]
【The invention's effect】
As is clear from the above description and Table 1, according to the method for manufacturing a multilayer printed wiring board of the present invention, the occurrence of copper foil wrinkles and pattern embossing during molding is suppressed, and the yield of copper foil appearance is improved. A multilayer printed wiring board can be manufactured.

Claims (2)

予め片面あるいは両面に導体回路パターンが形成された内層回路基板の片面あるいは両面に、銅箔キャリー付樹脂シートを重ねたものを、金型プレートに挟んで熱圧成形を行う工程を繰り返して配線層を積み重ねる多層プリント配線板の製造方法において、上記銅箔キャリー付樹脂シートとして、銅箔面に予め保護マスキングを施し、その後樹脂を塗布・乾燥し、その樹脂面に保護マスキングを施した銅露出面と樹脂露出面の両方にそれぞれの保護マスキングを施したマスキング銅箔付樹脂シートを使用し、マスキング銅箔付樹脂シートにおける樹脂露出面の保護マスキングは、それを成形前に剥がし、銅露出面の保護マスキングは、それを成形後に剥がすことを特徴とするビルドアップ型多層プリント配線板の製造方法。A wiring layer by repeating a process of hot-pressure molding by sandwiching a metal plate with a copper foil carry resin sheet on one or both sides of an inner circuit board on which a conductor circuit pattern has been previously formed on one or both sides. In the method of manufacturing a multilayer printed wiring board in which the copper foil is stacked, as the resin sheet with the copper foil carry, a copper mask surface is previously subjected to protective masking, and then the resin is coated and dried, and the exposed copper surface is subjected to protective masking on the resin surface Use the resin sheet with masking copper foil with both protective masking on both the resin exposed surface and the resin exposed surface, and remove the protective masking of the resin exposed surface of the resin sheet with masking copper foil before molding, Protective masking is a method for producing a build-up type multilayer printed wiring board, wherein the masking is removed after molding. マスキング銅箔付樹脂シートにおける銅露出面の保護マスキングは、銅露出面に粘着させた厚さ10μm〜150 μmのポリエチレンテレフタレートフィルムであり、樹脂露出面の保護マスキングは、樹脂露出面における樹脂を融着させた離型性フィルムである請求項1記載のビルドアップ型多層プリント配線板の製造方法。The protective masking of the exposed copper surface in the resin sheet with masking copper foil is a polyethylene terephthalate film with a thickness of 10 μm to 150 μm adhered to the exposed copper surface. The protective masking of the exposed resin surface melts the resin on the exposed resin surface. 2. The method for producing a build-up type multilayer printed wiring board according to claim 1, wherein the film is a peelable film.
JP31544898A 1998-10-19 1998-10-19 Manufacturing method of build-up type multilayer printed wiring board Expired - Fee Related JP3943735B2 (en)

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JP2013115316A (en) * 2011-11-30 2013-06-10 Shin Etsu Polymer Co Ltd Manufacturing method of wiring board
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