JP3936422B2 - ゴム変性ポリマー組成物 - Google Patents
ゴム変性ポリマー組成物 Download PDFInfo
- Publication number
- JP3936422B2 JP3936422B2 JP35985696A JP35985696A JP3936422B2 JP 3936422 B2 JP3936422 B2 JP 3936422B2 JP 35985696 A JP35985696 A JP 35985696A JP 35985696 A JP35985696 A JP 35985696A JP 3936422 B2 JP3936422 B2 JP 3936422B2
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- polymer composition
- weight
- acrylonitrile
- mol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 73
- 239000000203 mixture Substances 0.000 title claims abstract description 61
- 150000001875 compounds Chemical class 0.000 claims abstract description 26
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 21
- 239000000178 monomer Substances 0.000 claims abstract description 21
- 229920001971 elastomer Polymers 0.000 claims abstract description 19
- 239000005060 rubber Substances 0.000 claims abstract description 18
- -1 C1-C4 alkyl methacrylates Chemical class 0.000 claims abstract description 15
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 11
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims abstract description 7
- 150000008064 anhydrides Chemical class 0.000 claims abstract description 6
- 229920006345 thermoplastic polyamide Polymers 0.000 claims abstract description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 13
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 5
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 5
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 claims description 4
- 125000005250 alkyl acrylate group Chemical group 0.000 claims 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 25
- 239000004952 Polyamide Substances 0.000 description 23
- 229920002647 polyamide Polymers 0.000 description 23
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 12
- 229920001778 nylon Polymers 0.000 description 11
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 10
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- 229920001897 terpolymer Polymers 0.000 description 9
- 239000004677 Nylon Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 229920002292 Nylon 6 Polymers 0.000 description 5
- 229920002857 polybutadiene Polymers 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229920000299 Nylon 12 Polymers 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229920002877 acrylic styrene acrylonitrile Polymers 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000009863 impact test Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
- LLVWLCAZSOLOTF-UHFFFAOYSA-N 1-methyl-4-[1,4,4-tris(4-methylphenyl)buta-1,3-dienyl]benzene Chemical class C1=CC(C)=CC=C1C(C=1C=CC(C)=CC=1)=CC=C(C=1C=CC(C)=CC=1)C1=CC=C(C)C=C1 LLVWLCAZSOLOTF-UHFFFAOYSA-N 0.000 description 1
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- 150000003923 2,5-pyrrolediones Chemical class 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- BTOVVHWKPVSLBI-UHFFFAOYSA-N 2-methylprop-1-enylbenzene Chemical compound CC(C)=CC1=CC=CC=C1 BTOVVHWKPVSLBI-UHFFFAOYSA-N 0.000 description 1
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
- UFERIGCCDYCZLN-UHFFFAOYSA-N 3a,4,7,7a-tetrahydro-1h-indene Chemical compound C1C=CCC2CC=CC21 UFERIGCCDYCZLN-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 1
- 229920006045 Akulon® Polymers 0.000 description 1
- YAAQEISEHDUIFO-UHFFFAOYSA-N C=CC#N.OC(=O)C=CC=CC1=CC=CC=C1 Chemical compound C=CC#N.OC(=O)C=CC=CC1=CC=CC=C1 YAAQEISEHDUIFO-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 239000004687 Nylon copolymer Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- YMOONIIMQBGTDU-VOTSOKGWSA-N [(e)-2-bromoethenyl]benzene Chemical compound Br\C=C\C1=CC=CC=C1 YMOONIIMQBGTDU-VOTSOKGWSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 150000004984 aromatic diamines Chemical class 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 125000006159 dianhydride group Chemical group 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- FJXWKBZRTWEWBJ-UHFFFAOYSA-N nonanediamide Chemical compound NC(=O)CCCCCCCC(N)=O FJXWKBZRTWEWBJ-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/42—Nitriles
- C08F220/44—Acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1535—Five-membered rings
- C08K5/1539—Cyclic anhydrides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE9501089A BE1009904A3 (nl) | 1995-12-29 | 1995-12-29 | Rubber gemodificeerde polyamide polymeersamenstelling. |
| BE09501089 | 1995-12-29 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH09216989A JPH09216989A (ja) | 1997-08-19 |
| JPH09216989A5 JPH09216989A5 (enExample) | 2004-11-25 |
| JP3936422B2 true JP3936422B2 (ja) | 2007-06-27 |
Family
ID=3889387
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP35985696A Expired - Fee Related JP3936422B2 (ja) | 1995-12-29 | 1996-12-27 | ゴム変性ポリマー組成物 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5948858A (enExample) |
| EP (1) | EP0784080B1 (enExample) |
| JP (1) | JP3936422B2 (enExample) |
| AT (1) | ATE234896T1 (enExample) |
| BE (1) | BE1009904A3 (enExample) |
| DE (1) | DE69626772T2 (enExample) |
| ES (1) | ES2194952T3 (enExample) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR033368A1 (es) * | 2000-05-19 | 2003-12-17 | Bayer Ag | Mezclas de polimeros que contienen poliamida, y polimeros modificados con caucho, uso de las mezclas de polimeros en la produccion de cuerpos moldeados, y cuerpos moldeados, partes de gabinetes, placas de cubierta y piezas para el sector automotriz obtenibles a partir de las mezclas de polimeros |
| DE10259266A1 (de) * | 2002-12-17 | 2004-07-01 | Basf Ag | Thermoplastische Formmassen |
| WO2005033206A1 (de) | 2003-09-13 | 2005-04-14 | Rehau Ag + Co | Polymerzusammensetzung |
| WO2005040281A1 (en) * | 2003-10-10 | 2005-05-06 | Basf Aktiengesellschaft | Thermoplastic molding compositions |
| DE102004004230A1 (de) * | 2004-01-27 | 2005-08-11 | Basf Ag | Thermoplastische Formmassen auf Basis von Styrolcopolymeren und Polyamiden |
| US7718251B2 (en) | 2006-03-10 | 2010-05-18 | Amesbury Group, Inc. | Systems and methods for manufacturing reinforced weatherstrip |
| DE502008001478D1 (de) | 2007-02-19 | 2010-11-18 | Basf Se | Formmassen mit reduzierter anisotropie der schlagzähigkeit |
| EP2393877B1 (de) | 2009-02-06 | 2012-12-05 | Styrolution GmbH | Styrolcopolymere und polyamide enthaltende thermoplastische formmassen |
| WO2010089258A1 (de) | 2009-02-06 | 2010-08-12 | Basf Se | Thermoplastische formmassen auf basis von styrolcopolymeren und polyamiden mit verbesserter witterungsbeständigkeit |
| EP2251377B1 (de) | 2009-05-11 | 2011-07-20 | Basf Se | Verstärkte Styrolcopolymere |
| US20110178205A1 (en) | 2010-01-18 | 2011-07-21 | Martin Weber | Process for producing thermoplastic molding compositions based on styrene copolymers and polyamide with improved toughness |
| ES2444165T3 (es) | 2010-01-18 | 2014-02-24 | Styrolution GmbH | Procedimiento para la producción de materiales de moldeo termoplásticos a base de copolímeros de estireno y poliamida con tenacidad mejorada |
| WO2012065977A1 (de) | 2010-11-18 | 2012-05-24 | Basf Se | Thermoplastische formmassen auf basis von styrolcopolymeren und polyamiden; verfahren zu deren herstellung und deren verwendung |
| KR20130130749A (ko) | 2010-12-20 | 2013-12-02 | 바스프 에스이 | 개선된 저온 인성을 갖는 스티렌 공중합체 및 폴리아미드 기재 열가소성 성형 조성물 |
| EP2760935A1 (de) | 2011-09-29 | 2014-08-06 | Styrolution GmbH | Stabilisierte formmassen aus polyamid und asa-copolymeren |
| WO2013053649A1 (de) | 2011-10-13 | 2013-04-18 | Styrolution GmbH | Stabilisierte polyamid-abs formmassen |
| WO2013104528A1 (de) | 2012-01-11 | 2013-07-18 | Styrolution GmbH | Witterungsstabile thermoplastische formmassen auf basis von styrolcopolymeren und polyamiden mit verbesserter zähigkeit |
| US10329834B2 (en) | 2015-02-13 | 2019-06-25 | Amesbury Group, Inc. | Low compression-force TPE weatherseals |
| ES2774719T3 (es) | 2016-04-20 | 2020-07-22 | Ineos Styrolution Group Gmbh | Masas moldeables termoplásticas no penetrantes, de acción antimicrobiana |
| KR20190054102A (ko) | 2016-09-08 | 2019-05-21 | 이네오스 스티롤루션 그룹 게엠베하 | 선택적 레이저 소결（sls）을 위한 열가소성 중합체 분말 |
| CN106810809B (zh) * | 2016-12-26 | 2019-03-29 | 上海锦湖日丽塑料有限公司 | 超低光泽、超耐低温asa树脂组合物及其制备方法 |
| EP3738985B1 (en) * | 2018-01-09 | 2022-03-02 | Denka Company Limited | Method for producing a maleimide-based copolymer |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2060649B (en) * | 1979-10-04 | 1983-07-13 | Asahi Dow Ltd | Co-grafted polymers |
| DE3120803A1 (de) * | 1981-05-25 | 1982-12-16 | Basf Ag, 6700 Ludwigshafen | Schlagzaehne thermoplastische formmassen |
| US4452931A (en) * | 1982-03-30 | 1984-06-05 | Ube Industries, Ltd. | Flame-retardant polyamide resin composition |
| US4713415A (en) * | 1985-05-10 | 1987-12-15 | Monsanto Company | Rubber modified nylon composition |
| JPS63165451A (ja) * | 1986-12-26 | 1988-07-08 | Mitsubishi Monsanto Chem Co | 耐衝撃性熱可塑性樹脂組成物 |
| EP0402528A3 (en) * | 1989-06-13 | 1991-11-13 | Monsanto Kasei Company | Impact resistant thermoplastic resin composition |
| US5317054A (en) * | 1990-04-27 | 1994-05-31 | Industrial Technology Research Institute | Reinforced polyamide composites |
| US5280060A (en) * | 1990-08-02 | 1994-01-18 | Sumitomo Chemical Company, Limited | Thermoplastic resin composition containing a fluidity modifier |
| GB9224512D0 (en) * | 1992-11-20 | 1993-01-13 | Exxon Chemical Patents Inc | Toughened thermoplastic nylon compositions |
-
1995
- 1995-12-29 BE BE9501089A patent/BE1009904A3/nl not_active IP Right Cessation
-
1996
- 1996-12-23 AT AT96203693T patent/ATE234896T1/de not_active IP Right Cessation
- 1996-12-23 EP EP96203693A patent/EP0784080B1/en not_active Expired - Lifetime
- 1996-12-23 ES ES96203693T patent/ES2194952T3/es not_active Expired - Lifetime
- 1996-12-23 DE DE69626772T patent/DE69626772T2/de not_active Expired - Lifetime
- 1996-12-27 JP JP35985696A patent/JP3936422B2/ja not_active Expired - Fee Related
- 1996-12-27 US US08/774,357 patent/US5948858A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ES2194952T3 (es) | 2003-12-01 |
| JPH09216989A (ja) | 1997-08-19 |
| DE69626772D1 (de) | 2003-04-24 |
| ATE234896T1 (de) | 2003-04-15 |
| BE1009904A3 (nl) | 1997-10-07 |
| EP0784080B1 (en) | 2003-03-19 |
| DE69626772T2 (de) | 2003-09-04 |
| EP0784080A1 (en) | 1997-07-16 |
| US5948858A (en) | 1999-09-07 |
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