JP3822888B2 - 陰イオン吸着炭素材料の製造装置 - Google Patents
陰イオン吸着炭素材料の製造装置 Download PDFInfo
- Publication number
- JP3822888B2 JP3822888B2 JP2004244656A JP2004244656A JP3822888B2 JP 3822888 B2 JP3822888 B2 JP 3822888B2 JP 2004244656 A JP2004244656 A JP 2004244656A JP 2004244656 A JP2004244656 A JP 2004244656A JP 3822888 B2 JP3822888 B2 JP 3822888B2
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- Prior art keywords
- carbon material
- anion
- cacl
- solution
- adsorption
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003575 carbonaceous material Substances 0.000 title claims description 124
- 238000001179 sorption measurement Methods 0.000 title claims description 84
- 150000001450 anions Chemical class 0.000 title claims description 62
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 229910001510 metal chloride Inorganic materials 0.000 claims description 48
- 238000003763 carbonization Methods 0.000 claims description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 239000002994 raw material Substances 0.000 claims description 25
- 238000001035 drying Methods 0.000 claims description 19
- 238000010000 carbonizing Methods 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 13
- 125000000524 functional group Chemical group 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- 238000005342 ion exchange Methods 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 7
- 229910021645 metal ion Inorganic materials 0.000 claims description 6
- 150000001247 metal acetylides Chemical class 0.000 claims description 3
- 239000000243 solution Substances 0.000 description 82
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 63
- 239000003610 charcoal Substances 0.000 description 54
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 43
- 239000002023 wood Substances 0.000 description 31
- -1 nitrate ions Chemical class 0.000 description 25
- 150000002500 ions Chemical class 0.000 description 24
- 230000008929 regeneration Effects 0.000 description 23
- 238000011069 regeneration method Methods 0.000 description 23
- JVMRPSJZNHXORP-UHFFFAOYSA-N ON=O.ON=O.ON=O.N Chemical compound ON=O.ON=O.ON=O.N JVMRPSJZNHXORP-UHFFFAOYSA-N 0.000 description 21
- 238000012360 testing method Methods 0.000 description 19
- 238000005406 washing Methods 0.000 description 19
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 18
- 241000196324 Embryophyta Species 0.000 description 16
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 16
- 239000012086 standard solution Substances 0.000 description 15
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 14
- 239000000460 chlorine Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 13
- 238000012545 processing Methods 0.000 description 13
- 238000010438 heat treatment Methods 0.000 description 11
- 230000008569 process Effects 0.000 description 10
- 239000011148 porous material Substances 0.000 description 8
- 239000011780 sodium chloride Substances 0.000 description 8
- 238000007598 dipping method Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910002651 NO3 Inorganic materials 0.000 description 6
- 229910001424 calcium ion Inorganic materials 0.000 description 6
- 238000007654 immersion Methods 0.000 description 6
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 5
- 239000003957 anion exchange resin Substances 0.000 description 5
- 238000011109 contamination Methods 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 239000011737 fluorine Substances 0.000 description 5
- 239000008188 pellet Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- 241000218645 Cedrus Species 0.000 description 3
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 3
- 239000003463 adsorbent Substances 0.000 description 3
- 229910052785 arsenic Inorganic materials 0.000 description 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000001172 regenerating effect Effects 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 235000018185 Betula X alpestris Nutrition 0.000 description 2
- 235000018212 Betula X uliginosa Nutrition 0.000 description 2
- 241001672694 Citrus reticulata Species 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000004720 fertilization Effects 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000003673 groundwater Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000010871 livestock manure Substances 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 244000080767 Areca catechu Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 241000218631 Coniferophyta Species 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000002154 agricultural waste Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 238000005349 anion exchange Methods 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 229940043430 calcium compound Drugs 0.000 description 1
- 150000001674 calcium compounds Chemical class 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 229910001634 calcium fluoride Inorganic materials 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000005539 carbonized material Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009264 composting Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 150000002736 metal compounds Chemical group 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000000618 nitrogen fertilizer Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000004045 organic chlorine compounds Chemical class 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000026683 transduction Effects 0.000 description 1
- 238000010361 transduction Methods 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Images
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- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Carbon And Carbon Compounds (AREA)
Priority Applications (14)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004244656A JP3822888B2 (ja) | 2004-08-25 | 2004-08-25 | 陰イオン吸着炭素材料の製造装置 |
CN2004800361714A CN1890027B (zh) | 2003-12-05 | 2004-12-03 | 阴离子吸附用炭材料及其制造方法和制造装置 |
CA2546477A CA2546477C (fr) | 2003-12-05 | 2004-12-03 | Matiere carbonee adsorbant les anions, et procede et dispositif de production de celle-ci |
KR1020067012241A KR100795118B1 (ko) | 2003-12-05 | 2004-12-03 | 음이온 흡착 탄소 재료와 그 제조 방법 |
EP14002650.1A EP2805764A3 (fr) | 2003-12-05 | 2004-12-03 | Matière carbonée adsorbant les anions, procédé de fabrication et installations de fabrication associés |
BRPI0419283-4A BRPI0419283B1 (pt) | 2003-12-05 | 2004-12-03 | Método para produzir um material carbônico adsorvente de ânion e material carbônico adsorvente de ânion |
PCT/JP2004/018058 WO2005053846A1 (fr) | 2003-12-05 | 2004-12-03 | Matiere carbonee adsorbant les anions, et procede et dispositif de production de celle-ci |
CN2007101617403A CN101185877B (zh) | 2003-12-05 | 2004-12-03 | 阴离子吸附用炭材料及其制造方法和制造装置 |
US10/581,578 US20070123420A1 (en) | 2003-12-05 | 2004-12-03 | Anion adsorbing carbon material, as well as manufacturing method and manufacturing facilities for same |
BRPI0417351-1A BRPI0417351A (pt) | 2003-12-05 | 2004-12-03 | material carbÈnico adsorvente aniÈnico, bem como processo de produção e instalação de produção para o mesmo |
EP07020839A EP1878490A3 (fr) | 2003-12-05 | 2004-12-03 | Matériau de carbone adsorbant les anions et procédé et appareil pour sa fabrication |
KR1020077018982A KR100834410B1 (ko) | 2003-12-05 | 2004-12-03 | 음이온 흡착 탄소 재료와 그 제조 방법 |
EP04819945A EP1707266A4 (fr) | 2003-12-05 | 2004-12-03 | Matiere carbonee adsorbant les anions, et procede et dispositif de production de celle-ci |
US11/923,429 US8222182B2 (en) | 2003-12-05 | 2007-10-24 | Anion adsorbing carbon material, as well as manufacturing method and manufacturing facilities for same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004244656A JP3822888B2 (ja) | 2004-08-25 | 2004-08-25 | 陰イオン吸着炭素材料の製造装置 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2006061770A JP2006061770A (ja) | 2006-03-09 |
JP2006061770A5 JP2006061770A5 (fr) | 2006-04-20 |
JP3822888B2 true JP3822888B2 (ja) | 2006-09-20 |
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Application Number | Title | Priority Date | Filing Date |
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JP2004244656A Expired - Lifetime JP3822888B2 (ja) | 2003-12-05 | 2004-08-25 | 陰イオン吸着炭素材料の製造装置 |
Country Status (1)
Country | Link |
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JP (1) | JP3822888B2 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104071788A (zh) * | 2014-07-02 | 2014-10-01 | 浙江大学 | 基于CaCl2改进的秸秆活性炭的制备方法及其用途 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6482693B1 (ja) * | 2018-01-31 | 2019-03-13 | 株式会社村上開明堂 | 陰イオン吸着剤および陰イオン吸着剤の製造方法 |
-
2004
- 2004-08-25 JP JP2004244656A patent/JP3822888B2/ja not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104071788A (zh) * | 2014-07-02 | 2014-10-01 | 浙江大学 | 基于CaCl2改进的秸秆活性炭的制备方法及其用途 |
CN104071788B (zh) * | 2014-07-02 | 2016-03-30 | 浙江大学 | 基于CaCl2改进的秸秆活性炭的制备方法及其用途 |
Also Published As
Publication number | Publication date |
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JP2006061770A (ja) | 2006-03-09 |
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