JP2024532841A - アルカンからオレフィンへの脱水素のための触媒及びプロセス - Google Patents

アルカンからオレフィンへの脱水素のための触媒及びプロセス Download PDF

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JP2024532841A
JP2024532841A JP2024509475A JP2024509475A JP2024532841A JP 2024532841 A JP2024532841 A JP 2024532841A JP 2024509475 A JP2024509475 A JP 2024509475A JP 2024509475 A JP2024509475 A JP 2024509475A JP 2024532841 A JP2024532841 A JP 2024532841A
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volume
reaction zone
alkanes
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Japanese (ja)
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JP2024532841A5 (cg-RX-API-DMAC10.html
Inventor
フェラーリ、ダニエラ
ビー. フィッシュ、バリー
ブラン、ケビン
ポルフェイト、グレン
エル. チョン、チェン
シャルマ、マニッシュ
キリリン、アレクセイ
ホイェツキ、アダム
マレク、アンジェイ
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Dow Global Technologies LLC
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Dow Global Technologies LLC
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Publication of JP2024532841A publication Critical patent/JP2024532841A/ja
Publication of JP2024532841A5 publication Critical patent/JP2024532841A5/ja
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20—Vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20—Vanadium, niobium or tantalum
    • C07C2523/22—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/31—Chromium, molybdenum or tungsten combined with bismuth
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1081—Alkanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012—Pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
JP2024509475A 2021-08-23 2022-08-17 アルカンからオレフィンへの脱水素のための触媒及びプロセス Pending JP2024532841A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US202163236003P 2021-08-23 2021-08-23
US63/236,003 2021-08-23
PCT/US2022/075067 WO2023028433A1 (en) 2021-08-23 2022-08-17 Catalyst and process for the dehydrogenation of alkanes to olefins

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JP2024532841A true JP2024532841A (ja) 2024-09-10
JP2024532841A5 JP2024532841A5 (cg-RX-API-DMAC10.html) 2025-08-21

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US (1) US20240352341A1 (cg-RX-API-DMAC10.html)
EP (1) EP4392396A1 (cg-RX-API-DMAC10.html)
JP (1) JP2024532841A (cg-RX-API-DMAC10.html)
KR (1) KR20240050384A (cg-RX-API-DMAC10.html)
CN (1) CN117858861A (cg-RX-API-DMAC10.html)
CA (1) CA3229599A1 (cg-RX-API-DMAC10.html)
WO (1) WO2023028433A1 (cg-RX-API-DMAC10.html)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2024531961A (ja) * 2021-08-23 2024-09-03 ダウ グローバル テクノロジーズ エルエルシー アルカンからオレフィンへの脱水素のための触媒及びプロセス
EP4424415A1 (en) * 2023-02-28 2024-09-04 Dow Global Technologies LLC Catalyst and process for the dehydrogenation of alkanes to olefins

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08198782A (ja) * 1994-10-18 1996-08-06 Basf Ag オレフィン系不飽和化合物を製造するための再生方法
JPH10175885A (ja) * 1996-04-25 1998-06-30 Mitsubishi Chem Corp エチレンの製造方法
JP2003201260A (ja) * 2001-12-04 2003-07-18 Rohm & Haas Co アルカンからオレフィン、不飽和カルボン酸および不飽和ニトリルを調製するための改良されたプロセス
JP2004504288A (ja) * 2000-07-18 2004-02-12 ビーエーエスエフ アクチェンゲゼルシャフト 不均一系触媒作用によりプロパンを気相酸化することによるアクリル酸の製造方法
JP2008501515A (ja) * 2004-06-09 2008-01-24 ビーエーエスエフ アクチェンゲゼルシャフト 多金属酸化物材料の製造方法
EP2179790A1 (en) * 2008-10-21 2010-04-28 Sued-Chemie AG Bismuth-containing mixed oxide catalysts
JP2015533341A (ja) * 2012-10-19 2015-11-24 インスティテュート メキシカーノ デル ペテロレオ エチレンへのエタンの酸化脱水素及びこのようなプロセスのための触媒としての多金属混合酸化物の調製
WO2021124004A1 (en) * 2019-12-20 2021-06-24 Nova Chemicals (International) S.A. Removal of carbon monoxide, oxygen and acetylene from an oxidative dehydrogenation process
JP2024531961A (ja) * 2021-08-23 2024-09-03 ダウ グローバル テクノロジーズ エルエルシー アルカンからオレフィンへの脱水素のための触媒及びプロセス

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4524236A (en) * 1984-06-28 1985-06-18 Union Carbide Corporation Process for oxydehydrogenation of ethane to ethylene
US20050176985A1 (en) * 2003-11-13 2005-08-11 Bogan Leonard E.Jr. Processes for the preparation of olefins, unsaturated carboxylic acids and unsaturated nitriles from alkanes
DE102005022798A1 (de) * 2005-05-12 2006-11-16 Basf Ag Verfahren zur Herstellung wenigstens eines Zielproduktes durch partielle Oxidation und/oder Ammoxidation von Propylen
WO2013148006A1 (en) 2012-03-28 2013-10-03 Rohm And Haas Company Process for making ethylene and acetic acid

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08198782A (ja) * 1994-10-18 1996-08-06 Basf Ag オレフィン系不飽和化合物を製造するための再生方法
JPH10175885A (ja) * 1996-04-25 1998-06-30 Mitsubishi Chem Corp エチレンの製造方法
JP2004504288A (ja) * 2000-07-18 2004-02-12 ビーエーエスエフ アクチェンゲゼルシャフト 不均一系触媒作用によりプロパンを気相酸化することによるアクリル酸の製造方法
JP2003201260A (ja) * 2001-12-04 2003-07-18 Rohm & Haas Co アルカンからオレフィン、不飽和カルボン酸および不飽和ニトリルを調製するための改良されたプロセス
JP2008501515A (ja) * 2004-06-09 2008-01-24 ビーエーエスエフ アクチェンゲゼルシャフト 多金属酸化物材料の製造方法
EP2179790A1 (en) * 2008-10-21 2010-04-28 Sued-Chemie AG Bismuth-containing mixed oxide catalysts
JP2015533341A (ja) * 2012-10-19 2015-11-24 インスティテュート メキシカーノ デル ペテロレオ エチレンへのエタンの酸化脱水素及びこのようなプロセスのための触媒としての多金属混合酸化物の調製
WO2021124004A1 (en) * 2019-12-20 2021-06-24 Nova Chemicals (International) S.A. Removal of carbon monoxide, oxygen and acetylene from an oxidative dehydrogenation process
JP2024531961A (ja) * 2021-08-23 2024-09-03 ダウ グローバル テクノロジーズ エルエルシー アルカンからオレフィンへの脱水素のための触媒及びプロセス

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Publication number Publication date
WO2023028433A1 (en) 2023-03-02
KR20240050384A (ko) 2024-04-18
US20240352341A1 (en) 2024-10-24
EP4392396A1 (en) 2024-07-03
CN117858861A (zh) 2024-04-09
CA3229599A1 (en) 2023-03-02

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