JP2022032436A - 揮散性製剤包装用フィルム及びこれを用いた蓋材 - Google Patents
揮散性製剤包装用フィルム及びこれを用いた蓋材 Download PDFInfo
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- JP2022032436A JP2022032436A JP2020136196A JP2020136196A JP2022032436A JP 2022032436 A JP2022032436 A JP 2022032436A JP 2020136196 A JP2020136196 A JP 2020136196A JP 2020136196 A JP2020136196 A JP 2020136196A JP 2022032436 A JP2022032436 A JP 2022032436A
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Abstract
Description
揮散性製剤包装用フィルムの作成:
(シーラント層の調製)
PET樹脂(MA-2101M、(固有粘度;0.62dl/g、水分量;2,900ppm)、ユニチカ株式会社製)100部と、鎖延長剤(AdR4368、BASFジャパン株式会社製)を30質量%含有したPETのマスターバッチ1.5部とをヘンシェルミキサーで混合攪拌した。この混合樹脂を同方向回転2軸押出し機(HMT100(L/D=38、吐出量;650kg/hr、2ベント孔)、日立造船株式会社製)に投入し、押出し温度280℃、ベント孔から-99.99kPaの高真空下で吸引・脱気しながら、二軸延伸PETフィルム(E5100:12μm、東洋紡株式会社製)へ押出し積層し、二軸延伸PETフィルム(12μm)/ヒートシールPET樹脂層(20μm)の積層材(NS-PET20)を作製した。ヒートシールPET樹脂層の結晶化度は9.8%であった。
(水蒸気バリア層の積層)
NS-PETにおける二軸延伸PETフィルム上に、押し出しラミネートの方法によって、アルミ蒸着PET(VMPET、12μm)及び二軸遠心ポリプロピレン樹脂(OPP、20μm)を順次ラミネートして揮散性製剤包装用フィルム(OPP20/VMPET12/NS-PET20)を調製した。
蓋材の評価:
実施例1で作製した揮散性製剤包装用フィルム(OPP20/VMPET12/NS-PET20)を11cm×11cmの大きさに裁断し、下記処方のゲル状芳香剤を収容したPET容器の開口部フランジに載置して150℃、2秒ヒートシールを行って密封した(本発明品1)。比較品として、PET12/AL7/PE30μmのフィルムを用いた(比較品1)。
(処方) (質量%)
シトロネラ精油 5%
カラギーナン 2%
エタノール 7%
香料 2%
ポリオキシエチレン硬化ヒマシ油 5%
イオン交換水 残
合計 100%
11 二軸遠心ポリプロピレン樹脂層
12 アルミ蒸着PET層
13 シーラント層
13a 延伸PETフィルム
13b ヒートシールPET樹脂層
20 PET容器
20a フランジ
30 ゲル状揮散性製剤
100 蓋付揮散性製剤
Claims (16)
- 延伸PETフィルム及び当該延伸PETフィルムの一面に押出し積層された結晶化度が15%未満のPET樹脂層からなるシーラント層と水蒸気バリア層とを備え、シーラント層の延伸PETフィルム上に水蒸気バリア層が積層された揮散性薬剤を含有する揮散性製剤包装用フィルム。
- 水蒸気バリア層が、ポリプロピレン樹脂層、蒸着フィルム又は金属箔のいずれか1種を少なくとも含む請求項1記載の揮散性製剤包装用フィルム。
- ポリプロピレン樹脂層が二軸遠心ポリプロピレン樹脂層である請求項2記載の揮散性製剤包装用フィルム。
- 蒸着フィルムがアルミニウム蒸着PETである請求項2記載の揮散性製剤包装用フィルム。
- 金属箔がアルミ箔である請求項2記載の揮散性製剤包装用フィルム。
- 延伸PETフィルムが、二軸延伸PETフィルムである請求項1~5のいずれかの項記載の揮散性製剤包装用フィルム。
- 延伸PETフィルムの厚みが、7~20μmである請求項1~6のいずれかの項記載の揮散性製剤包装用フィルム。
- 結晶化度が15%未満のPET樹脂が、鎖延長剤を添加したPET樹脂である請求項1~7のいずれかの項記載の揮散性製剤包装用フィルム。
- 結晶化度が15%未満のPET樹脂が、PET樹脂量に対し、0.2~2.0質量%の鎖延長剤を添加したものである請求項1~8のいずれかの項記載の揮散性製剤包装用フィルム。
- 鎖延長剤が、少なくとも2個以上の多官能のエポキシ基を有するものである請求項8または9記載の揮散性製剤包装用フィルム。
- 結晶化度が15%未満のPET樹脂層の厚みが、5~40μmである請求項1~10のいずれかの項記載の揮散性製剤包装用フィルム。
- 揮散性薬剤が、香料、消臭剤、防虫剤、殺虫剤および防カビ剤よりなる群から選ばれる1種または2種以上である請求項1~11のいずれかの項記載の揮散性製剤包装フィルム。
- 揮散性薬剤が、シトロネラ製油、シトロネラール、リモネン、よりなる群から選ばれる1種または2種以上である請求項12記載の揮散性製剤包装フィルム。
- 請求項1~13のいずれかの項記載の揮散性製剤包装用フィルムで形成された蓋材。
- PET樹脂で形成された容器に収容された揮散性製剤用である請求項14記載の蓋材。
- 揮散性製剤が水性ゲルである請求項14または15記載の蓋材。
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