JP2021107481A - ポリプロピレン樹脂組成物 - Google Patents
ポリプロピレン樹脂組成物 Download PDFInfo
- Publication number
- JP2021107481A JP2021107481A JP2019238676A JP2019238676A JP2021107481A JP 2021107481 A JP2021107481 A JP 2021107481A JP 2019238676 A JP2019238676 A JP 2019238676A JP 2019238676 A JP2019238676 A JP 2019238676A JP 2021107481 A JP2021107481 A JP 2021107481A
- Authority
- JP
- Japan
- Prior art keywords
- polypropylene resin
- liquid crystal
- resin composition
- aromatic liquid
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- -1 Polypropylene Polymers 0.000 title claims abstract description 132
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 82
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 82
- 239000011342 resin composition Substances 0.000 title claims abstract description 46
- 125000003118 aryl group Chemical group 0.000 claims abstract description 85
- 229920000106 Liquid crystal polymer Polymers 0.000 claims abstract description 66
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 claims abstract description 66
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims description 56
- 239000011347 resin Substances 0.000 claims description 56
- 229910019142 PO4 Inorganic materials 0.000 claims description 27
- 239000010452 phosphate Substances 0.000 claims description 27
- 125000004432 carbon atom Chemical group C* 0.000 claims description 19
- 239000004973 liquid crystal related substance Substances 0.000 claims description 10
- 229920001225 polyester resin Polymers 0.000 claims description 10
- 239000004645 polyester resin Substances 0.000 claims description 10
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000013078 crystal Substances 0.000 claims description 7
- 125000004429 atom Chemical group 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 238000002347 injection Methods 0.000 claims description 4
- 239000007924 injection Substances 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052788 barium Inorganic materials 0.000 claims description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 4
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 42
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 40
- 239000000047 product Substances 0.000 description 36
- 238000000034 method Methods 0.000 description 34
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 26
- 239000000178 monomer Substances 0.000 description 22
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 21
- 238000006116 polymerization reaction Methods 0.000 description 15
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 14
- KAUQJMHLAFIZDU-UHFFFAOYSA-N 6-Hydroxy-2-naphthoic acid Chemical compound C1=C(O)C=CC2=CC(C(=O)O)=CC=C21 KAUQJMHLAFIZDU-UHFFFAOYSA-N 0.000 description 13
- VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- 239000008188 pellet Substances 0.000 description 11
- 238000005452 bending Methods 0.000 description 10
- 150000002430 hydrocarbons Chemical group 0.000 description 10
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 10
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 10
- 238000004898 kneading Methods 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 8
- 238000000465 moulding Methods 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 8
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- 125000003545 alkoxy group Chemical group 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 7
- 125000005843 halogen group Chemical group 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 6
- 229920001400 block copolymer Polymers 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000001746 injection moulding Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 238000000071 blow moulding Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 235000013305 food Nutrition 0.000 description 5
- 239000011256 inorganic filler Substances 0.000 description 5
- 229910003475 inorganic filler Inorganic materials 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 5
- 239000012766 organic filler Substances 0.000 description 5
- 239000005022 packaging material Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- ZHROMWXOTYBIMF-UHFFFAOYSA-M sodium;1,3,7,9-tetratert-butyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C ZHROMWXOTYBIMF-UHFFFAOYSA-M 0.000 description 5
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- 229920002943 EPDM rubber Polymers 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 150000004820 halides Chemical class 0.000 description 4
- 230000001771 impaired effect Effects 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 238000006068 polycondensation reaction Methods 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 239000004711 α-olefin Substances 0.000 description 4
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- 239000005711 Benzoic acid Substances 0.000 description 3
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 238000012685 gas phase polymerization Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- MNZMMCVIXORAQL-UHFFFAOYSA-N naphthalene-2,6-diol Chemical compound C1=C(O)C=CC2=CC(O)=CC=C21 MNZMMCVIXORAQL-UHFFFAOYSA-N 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- KZGROEDUAFPSGN-UHFFFAOYSA-N (2,4-ditert-butylphenyl) dihydrogen phosphate Chemical compound CC(C)(C)C1=CC=C(OP(O)(O)=O)C(C(C)(C)C)=C1 KZGROEDUAFPSGN-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
- IJFXRHURBJZNAO-UHFFFAOYSA-N 3-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC(O)=C1 IJFXRHURBJZNAO-UHFFFAOYSA-N 0.000 description 2
- BCEQKAQCUWUNML-UHFFFAOYSA-N 4-hydroxybenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC=C(O)C(C(O)=O)=C1 BCEQKAQCUWUNML-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000004974 Thermotropic liquid crystal Substances 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 150000004984 aromatic diamines Chemical class 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000011437 continuous method Methods 0.000 description 2
- 229920003244 diene elastomer Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 229920003049 isoprene rubber Polymers 0.000 description 2
- QWDJLDTYWNBUKE-UHFFFAOYSA-L magnesium bicarbonate Chemical compound [Mg+2].OC([O-])=O.OC([O-])=O QWDJLDTYWNBUKE-UHFFFAOYSA-L 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000012968 metallocene catalyst Substances 0.000 description 2
- 239000012778 molding material Substances 0.000 description 2
- VAMFXQBUQXONLZ-UHFFFAOYSA-N n-alpha-eicosene Natural products CCCCCCCCCCCCCCCCCCC=C VAMFXQBUQXONLZ-UHFFFAOYSA-N 0.000 description 2
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 229920002725 thermoplastic elastomer Polymers 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- 238000007666 vacuum forming Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000013585 weight reducing agent Substances 0.000 description 2
- PPTXVXKCQZKFBN-UHFFFAOYSA-N (S)-(-)-1,1'-Bi-2-naphthol Chemical group C1=CC=C2C(C3=C4C=CC=CC4=CC=C3O)=C(O)C=CC2=C1 PPTXVXKCQZKFBN-UHFFFAOYSA-N 0.000 description 1
- GGQHNQQPLWRNHD-UHFFFAOYSA-N 1,3,7,9-tetratert-butyl-11-hydroxy-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP(O)(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C GGQHNQQPLWRNHD-UHFFFAOYSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- YFOOEYJGMMJJLS-UHFFFAOYSA-N 1,8-diaminonaphthalene Chemical compound C1=CC(N)=C2C(N)=CC=CC2=C1 YFOOEYJGMMJJLS-UHFFFAOYSA-N 0.000 description 1
- DDAPSNKEOHDLKB-UHFFFAOYSA-N 1-(2-aminonaphthalen-1-yl)naphthalen-2-amine Chemical group C1=CC=C2C(C3=C4C=CC=CC4=CC=C3N)=C(N)C=CC2=C1 DDAPSNKEOHDLKB-UHFFFAOYSA-N 0.000 description 1
- 229940106006 1-eicosene Drugs 0.000 description 1
- FIKTURVKRGQNQD-UHFFFAOYSA-N 1-eicosene Natural products CCCCCCCCCCCCCCCCCC=CC(O)=O FIKTURVKRGQNQD-UHFFFAOYSA-N 0.000 description 1
- OHLSHRJUBRUKAN-UHFFFAOYSA-N 2,3-dihydroxyterephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(O)=C1O OHLSHRJUBRUKAN-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- LODHFNUFVRVKTH-ZHACJKMWSA-N 2-hydroxy-n'-[(e)-3-phenylprop-2-enoyl]benzohydrazide Chemical compound OC1=CC=CC=C1C(=O)NNC(=O)\C=C\C1=CC=CC=C1 LODHFNUFVRVKTH-ZHACJKMWSA-N 0.000 description 1
- WVDGHGISNBRCAO-UHFFFAOYSA-N 2-hydroxyisophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1O WVDGHGISNBRCAO-UHFFFAOYSA-N 0.000 description 1
- ROGIWVXWXZRRMZ-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1 ROGIWVXWXZRRMZ-UHFFFAOYSA-N 0.000 description 1
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 1
- AJHPGXZOIAYYDW-UHFFFAOYSA-N 3-(2-cyanophenyl)-2-[(2-methylpropan-2-yl)oxycarbonylamino]propanoic acid Chemical compound CC(C)(C)OC(=O)NC(C(O)=O)CC1=CC=CC=C1C#N AJHPGXZOIAYYDW-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- VZQSBJKDSWXLKX-UHFFFAOYSA-N 3-(3-hydroxyphenyl)phenol Chemical group OC1=CC=CC(C=2C=C(O)C=CC=2)=C1 VZQSBJKDSWXLKX-UHFFFAOYSA-N 0.000 description 1
- GSYIVQLTSZFJRV-UHFFFAOYSA-N 3-(4-carboxyphenyl)benzoic acid Chemical group C1=CC(C(=O)O)=CC=C1C1=CC=CC(C(O)=O)=C1 GSYIVQLTSZFJRV-UHFFFAOYSA-N 0.000 description 1
- BWBGEYQWIHXDKY-UHFFFAOYSA-N 3-(4-hydroxyphenyl)phenol Chemical group C1=CC(O)=CC=C1C1=CC=CC(O)=C1 BWBGEYQWIHXDKY-UHFFFAOYSA-N 0.000 description 1
- ALKYHXVLJMQRLQ-UHFFFAOYSA-N 3-Hydroxy-2-naphthoate Chemical compound C1=CC=C2C=C(O)C(C(=O)O)=CC2=C1 ALKYHXVLJMQRLQ-UHFFFAOYSA-N 0.000 description 1
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 1
- 229940018563 3-aminophenol Drugs 0.000 description 1
- FMRQKJAIESQKBU-UHFFFAOYSA-N 4-(3-amino-7-thiabicyclo[4.1.0]hepta-2,4-dien-6-yl)phenol Chemical compound C1=CC(N)=CC2SC21C1=CC=C(O)C=C1 FMRQKJAIESQKBU-UHFFFAOYSA-N 0.000 description 1
- NEQFBGHQPUXOFH-UHFFFAOYSA-N 4-(4-carboxyphenyl)benzoic acid Chemical group C1=CC(C(=O)O)=CC=C1C1=CC=C(C(O)=O)C=C1 NEQFBGHQPUXOFH-UHFFFAOYSA-N 0.000 description 1
- FDHZNXYLISNHCG-UHFFFAOYSA-N 4-[2-(4-carboxyphenyl)phenyl]benzoic acid Chemical group C1(=CC=C(C=C1)C(=O)O)C=1C(=CC=CC1)C1=CC=C(C=C1)C(=O)O FDHZNXYLISNHCG-UHFFFAOYSA-N 0.000 description 1
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- SMAMQSIENGBTRV-UHFFFAOYSA-N 5-hydroxynaphthalene-2-carboxylic acid Chemical compound OC1=CC=CC2=CC(C(=O)O)=CC=C21 SMAMQSIENGBTRV-UHFFFAOYSA-N 0.000 description 1
- FEIQOMCWGDNMHM-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid Chemical compound OC(=O)C=CC=CC1=CC=CC=C1 FEIQOMCWGDNMHM-UHFFFAOYSA-N 0.000 description 1
- NZTPZUIIYNYZKT-UHFFFAOYSA-N 6-aminonaphthalene-2-carboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(N)=CC=C21 NZTPZUIIYNYZKT-UHFFFAOYSA-N 0.000 description 1
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- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
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- VVNXEADCOVSAER-UHFFFAOYSA-N lithium sodium Chemical compound [Li].[Na] VVNXEADCOVSAER-UHFFFAOYSA-N 0.000 description 1
- UADIOTAIECKQLQ-UHFFFAOYSA-M lithium;1,3,7,9-tetratert-butyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Li+].C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C UADIOTAIECKQLQ-UHFFFAOYSA-M 0.000 description 1
- PEZYITXKFBTLBI-UHFFFAOYSA-M lithium;1,9-ditert-butyl-3,7-diethyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Li+].C1C2=CC(CC)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(CC)C=C2C(C)(C)C PEZYITXKFBTLBI-UHFFFAOYSA-M 0.000 description 1
- DOPGPJUHBPZWQJ-UHFFFAOYSA-M lithium;1,9-ditert-butyl-3,7-dimethyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Li+].C1C2=CC(C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C)C=C2C(C)(C)C DOPGPJUHBPZWQJ-UHFFFAOYSA-M 0.000 description 1
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
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- 229910052618 mica group Inorganic materials 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- KQSABULTKYLFEV-UHFFFAOYSA-N naphthalene-1,5-diamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1N KQSABULTKYLFEV-UHFFFAOYSA-N 0.000 description 1
- VAWFFNJAPKXVPH-UHFFFAOYSA-N naphthalene-1,6-dicarboxylic acid Chemical compound OC(=O)C1=CC=CC2=CC(C(=O)O)=CC=C21 VAWFFNJAPKXVPH-UHFFFAOYSA-N 0.000 description 1
- FZZQNEVOYIYFPF-UHFFFAOYSA-N naphthalene-1,6-diol Chemical compound OC1=CC=CC2=CC(O)=CC=C21 FZZQNEVOYIYFPF-UHFFFAOYSA-N 0.000 description 1
- WPUMVKJOWWJPRK-UHFFFAOYSA-N naphthalene-2,7-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=CC2=CC(C(=O)O)=CC=C21 WPUMVKJOWWJPRK-UHFFFAOYSA-N 0.000 description 1
- DFQICHCWIIJABH-UHFFFAOYSA-N naphthalene-2,7-diol Chemical compound C1=CC(O)=CC2=CC(O)=CC=C21 DFQICHCWIIJABH-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
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- 229920002223 polystyrene Polymers 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- YWSUSMUSZKSAAQ-UHFFFAOYSA-M potassium;1,3,7,9-tetratert-butyl-5-methyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [K+].CC1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C YWSUSMUSZKSAAQ-UHFFFAOYSA-M 0.000 description 1
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- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000012321 sodium triacetoxyborohydride Substances 0.000 description 1
- DVSGVEPIPBNASD-UHFFFAOYSA-M sodium;1,3,7,9-tetramethyl-11-oxido-5-(2,4,4-trimethylpentan-2-yl)-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].O1P([O-])(=O)OC2=C(C)C=C(C)C=C2C(C(C)(C)CC(C)(C)C)C2=CC(C)=CC(C)=C21 DVSGVEPIPBNASD-UHFFFAOYSA-M 0.000 description 1
- SIJVPMATBIKDTJ-UHFFFAOYSA-M sodium;1,3,7,9-tetramethyl-11-oxido-5-propyl-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].O1P([O-])(=O)OC2=C(C)C=C(C)C=C2C(CCC)C2=CC(C)=CC(C)=C21 SIJVPMATBIKDTJ-UHFFFAOYSA-M 0.000 description 1
- DFALJHQMUXBUQC-UHFFFAOYSA-M sodium;1,3,7,9-tetramethyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].O1P([O-])(=O)OC2=C(C)C=C(C)C=C2CC2=CC(C)=CC(C)=C21 DFALJHQMUXBUQC-UHFFFAOYSA-M 0.000 description 1
- ZTDRYKIXYNNYGS-UHFFFAOYSA-M sodium;1,3,7,9-tetratert-butyl-11-oxido-5-(2,4,4-trimethylpentan-2-yl)-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].CC(C)(C)CC(C)(C)C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C ZTDRYKIXYNNYGS-UHFFFAOYSA-M 0.000 description 1
- LMQXJKGCJVYPNJ-UHFFFAOYSA-M sodium;1,3,7,9-tetratert-butyl-11-oxido-5-propyl-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].CCCC1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C LMQXJKGCJVYPNJ-UHFFFAOYSA-M 0.000 description 1
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Images
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Abstract
Description
〔1〕ポリプロピレン樹脂100質量部に対して、全芳香族液晶ポリマー1〜100質量部、および有機リン酸エステル塩化合物0.001〜5質量部を含有するポリプロピレン樹脂組成物。
〔2〕有機リン酸エステル塩化合物は、リチウム、ナトリウム、カリウム、マグネシウム、カルシウム、バリウムおよびアルミニウムから選択される1種以上の金属原子を含む有機リン酸エステル塩化合物である、〔1〕に記載のポリプロピレン樹脂組成物。
〔3〕全芳香族液晶ポリマーの結晶融解温度は260℃未満である、〔1〕または〔2〕に記載のポリプロピレン樹脂組成物。
〔4〕全芳香族液晶ポリマーは、式(I)および式(II)
〔5〕全芳香族液晶ポリマーは、式(I)〜(IV)
で表される繰返し単位から構成される全芳香族液晶ポリエステル樹脂である、〔1〕〜〔4〕のいずれかに記載のポリプロピレン樹脂組成物。
〔6〕Ar1およびAr2は、それぞれ互いに独立して、式(1)〜(4)
〔7〕有機リン酸エステル塩化合物は、式(V)
および/または式(VI)
で表される化合物である、〔1〕〜〔6〕のいずれかに記載のポリプロピレン樹脂組成物。
〔8〕〔1〕〜〔7〕のいずれかに記載のポリプロピレン樹脂組成物から構成される成形品。
〔9〕成形品が、射出成形品、フィルム、シートまたは中空成形体である、〔8〕に記載の成形品。
1)4−ヒドロキシ安息香酸/6−ヒドロキシ−2−ナフトエ酸、
2)4−ヒドロキシ安息香酸/テレフタル酸/4,4’−ジヒドロキシビフェニル、
3)4−ヒドロキシ安息香酸/テレフタル酸/イソフタル酸/4,4’−ジヒドロキシビフェニル、
4)4−ヒドロキシ安息香酸/テレフタル酸/イソフタル酸/4,4’−ジヒドロキシビフェニル/ハイドロキノン、
5)4−ヒドロキシ安息香酸/テレフタル酸/ハイドロキノン、
6)6−ヒドロキシ−2−ナフトエ酸/テレフタル酸/ハイドロキノン、
7)4−ヒドロキシ安息香酸/6−ヒドロキシ−2−ナフトエ酸/テレフタル酸/4,4’−ジヒドロキシビフェニル、
8)6−ヒドロキシ−2−ナフトエ酸/テレフタル酸/4,4’−ジヒドロキシビフェニル、
9)4−ヒドロキシ安息香酸/6−ヒドロキシ−2−ナフトエ酸/テレフタル酸/ハイドロキノン、
10)4−ヒドロキシ安息香酸/6−ヒドロキシ−2−ナフトエ酸/テレフタル酸/ハイドロキノン/4,4’−ジヒドロキシビフェニル、
11)4−ヒドロキシ安息香酸/2,6−ナフタレンジカルボン酸/4,4’−ジヒドロキシビフェニル、
12)4−ヒドロキシ安息香酸/テレフタル酸/2,6−ナフタレンジカルボン酸/ハイドロキノン、
13)4−ヒドロキシ安息香酸/2,6−ナフタレンジカルボン酸/ハイドロキノン、
14)4−ヒドロキシ安息香酸/6−ヒドロキシ−2−ナフトエ酸/2,6−ナフタレンジカルボン酸/ハイドロキノン、
15)4−ヒドロキシ安息香酸/テレフタル酸/2,6−ナフタレンジカルボン酸/ハイドロキノン/4,4’−ジヒドロキシビフェニル、
16)4−ヒドロキシ安息香酸/テレフタル酸/4−アミノフェノール、
17)6−ヒドロキシ−2−ナフトエ酸/テレフタル酸/4−アミノフェノール、
18)4−ヒドロキシ安息香酸/6−ヒドロキシ−2−ナフトエ酸/テレフタル酸/4−アミノフェノール、
19)4−ヒドロキシ安息香酸/テレフタル酸/4,4’−ジヒドロキシビフェニル/4−アミノフェノール、
20)4−ヒドロキシ安息香酸/テレフタル酸/2,6−ナフタレンジカルボン酸/4,4’−ジヒドロキシビフェニル。
21)4−ヒドロキシ安息香酸/6−ヒドロキシ−2−ナフトエ酸/イソフタル酸/2,6−ナフタレンジカルボン酸/4,4’−ジヒドロキシビフェニル。
また、本発明のポリプロピレン樹脂組成物に使用する有機リン酸エステル塩化合物は、以下の式(V)
および/または(VI)
で表される有機リン酸エステル塩化合物であるのがより好ましい。
で表わされる化合物がより好ましく、式(VIII)
で表わされる化合物が特に好ましい。
トルクメーター付き攪拌装置および留出管を備えた反応容器に、4−ヒドロキシ安息香酸349.3g(40モル%)、6−ヒドロキシ−2−ナフトエ酸476.0g(40モル%)、ハイドロキノン69.7g(10モル%)およびテレフタル酸105.0g(10モル%)を仕込み、さらに全単量体の水酸基量(モル)に対して1.03倍モルの無水酢酸を仕込んで、次の条件で脱酢酸重合を行った。
ポリプロピレン樹脂として以下のものを使用した。
PP−1:ホモポリプロピレン(プライムポリマー社製プライムポリプロ(登録商標)J105G)
PP−2:ブロックポリプロピレン(プライムポリマー社製プライムポリプロ(登録商標)J715M)
有機リン酸エステル塩化合物として以下のものを使用した。
PA−1:ADEKA社製アデカスタブNA−21(ヒドロキシアルミニウム−ビス[2,2−メチレン−ビス(4,6−ジ−t−ブチル)フォスフェート)
PA−2:ADEKA社製アデカスタブNA−11(ナトリウム−2,2’−メチレン−ビス(4,6−ジ−t−ブチルフェニル)フォスフェート)
ソルビトール系化合物として以下のものを使用した。
SO−1:ミリケン社製NX−8000
型締め力100トンの電動射出成形機(ファナック社製ロボショットS−2000i−100B)を用いて、シリンダー温度230℃、金型温度20℃で射出成形し、高さ62mm、上部フランジ径86mm、側面肉厚0.7mmの容器状成形品を得た。得られた成形品の側面部を、ハサミで縦2cm、横1cmにカットした試験片をトレーサーボードの上に置き、下から透過光を当てて、全芳香族液晶ポリマーの分散状態を確認した。各試験片において、目視にて凝集物(全芳香族液晶ポリマー)の最大粒子を選定し、粒子径1mm未満はデジタルマイクロスコープ(キーエンス社製VHX−5000)を用いて、粒子径1mm以上はデジタルノギス(マツトヨ社製CD−10CPX)を用いて、それぞれ長径を計測した。
ASTM D−1238に準拠して、測定温度230℃、2.16kg荷重で測定した。
射出成形機(日精樹脂工業(株)製UH1000−110)を用いて、シリンダー温度250℃、金型温度40℃で、長さ80.0mm、幅10.0mm、厚さ4.0mmの短冊状試験片に成形し、これを用いてISO−178に準拠して測定した。
射出成形機(日精樹脂工業(株)製UH1000−110)にて、厚み3.2mmのASTM1号ダンベル試験片の成形用キャビティの両端にそれぞれゲートを設けた金型を用いて、シリンダー温度250℃、金型温度40℃で成形を行い、ダンベル試験片中央部分にウェルドが意図的に形成された試験片を成形し、これを用いてASTM D790に準拠して測定した。
曲げ強度および曲げ弾性率の測定に用いたものと同じ短冊状試験片を用いて、ISO−75に準拠し、荷重0.45MPa、昇温速度2℃/分で測定した。
曲げ強度および曲げ弾性率の測定に用いたものと同じ短冊状試験片に、セロハンテープ(ニチバン(株)製セロテープ(登録商標)CT−24)を貼付面積が500mm2(50mm×10mm)となるように指で押し付けて密着させた後に、長手方向で、180°の方向に100mm/秒の速度で引き剥がした。試験片表面の剥離した部分をスキャナーで読み取り、キーエンス製VHX−900F通信ソフトにて解析し剥離面積を算出した。上記剥離面積を上記貼付面積で除した値を剥離面積率(%)とした。 剥離面積率(%)が小さいほど、耐テープ剥離性に優れる。
ポリプロピレン樹脂(PP−1、PP−2)、全芳香族液晶ポリマー(LCP−1)、有機リン酸エステル塩化合物(PA−1、PA−2)およびソルビトール系化合物(SO−1)を、表1〜2に示す含有量となるように配合して、2軸押出機(東芝機械(株)、TEM35BS)を用いて、シリンダー温度250℃で溶融混練して、ポリプロピレン樹脂組成物のペレットを得た。
Claims (9)
- ポリプロピレン樹脂100質量部に対して、
全芳香族液晶ポリマー1〜100質量部、および
有機リン酸エステル塩化合物0.001〜5質量部を含有するポリプロピレン樹脂組成物。 - 有機リン酸エステル塩化合物は、リチウム、ナトリウム、カリウム、マグネシウム、カルシウム、バリウムおよびアルミニウムから選択される1種以上の金属原子を含む有機リン酸エステル塩化合物である、請求項1に記載のポリプロピレン樹脂組成物。
- 全芳香族液晶ポリマーの結晶融解温度は260℃未満である、請求項1または2に記載のポリプロピレン樹脂組成物。
- 請求項1〜7のいずれかに記載のポリプロピレン樹脂組成物から構成される成形品。
- 成形品が、射出成形品、フィルム、シートまたは中空成形体である、請求項8に記載の成形品。
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