JP2021017426A - 水中油型乳化化粧料及びその製造方法 - Google Patents
水中油型乳化化粧料及びその製造方法 Download PDFInfo
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- JP2021017426A JP2021017426A JP2019135340A JP2019135340A JP2021017426A JP 2021017426 A JP2021017426 A JP 2021017426A JP 2019135340 A JP2019135340 A JP 2019135340A JP 2019135340 A JP2019135340 A JP 2019135340A JP 2021017426 A JP2021017426 A JP 2021017426A
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- oil
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- emulsifier
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Landscapes
- Cosmetics (AREA)
Abstract
Description
[1]疎水化表面処理された微粒子金属酸化物、親油性乳化剤、アクリル酸ナトリウム/アクリロイルジメチルタウリンナトリウム共重合体及び液状油を含む油相に、
親水性乳化剤を含む水相を添加して、
転相乳化することにより、
水中油型乳化化粧料を得る工程を含む、水中油型乳化化粧料の製造方法。
[2]疎水化表面処理された微粒子金属酸化物と、
親油性乳化剤と、
アクリル酸ナトリウム/アクリロイルジメチルタウリンナトリウム共重合体と、
液状油と、
親水性乳化剤と
を含む、転相乳化物である、水中油型乳化化粧料。
[3]前記親水性乳化剤は、HLBが8以上の親水性乳化剤である、[1]〜[2]のいずれか1項に記載の方法又は化粧料。
[4]前記疎水化表面処理された微粒子金属酸化物の含有量は、5質量%〜20質量%である、[1]〜[3]のいずれか1項に記載の方法又は化粧料。
[5]前記親油性乳化剤及び前記親水性乳化剤の合計含有量が2質量%未満である、[1]〜[4]のいずれか1項に記載の方法又は化粧料。
[6]前記水中油型乳化化粧料は、さらに紫外線吸収剤を含む、[2]〜[5]のいずれか1項に記載の化粧料。
[7]前記水中油型乳化化粧料は、油性成分の合計含有量が15質量%以上である、[2]〜[6]のいずれか1項に記載の化粧料。
[8]前記水中油型乳化化粧料は、粘度が10,000mPa・s以下であり、及び/又は体積平均粒子径が9.5μm以下である、[2]〜[7]のいずれか1項に記載の化粧料。
[9]前記水中油型乳化化粧料は、日焼け止め乳液である、[2]〜[8]のいずれか1項に記載の化粧料。
「含有量」は、濃度と同義であり、化粧料の全体量に対する成分の量の割合を意味する。本明細書では、別段の定めがない限り、含有量の単位は「質量%(wt%)」を意味する。
数値範囲の「〜」は、本明細書において、その前後の数値を含む範囲であり、例えば、「0質量%〜100質量%」は、0質量%以上であり、かつ、100質量%以下である範囲を意味する。
「使用感」は、化粧料を皮膚へ塗布する際に感じる潤い及びのびの軽さからなる群から選ばれる少なくとも1種の感覚を意味する。また、「潤い」は、皮膚に塗布している最中、しっとりしながらも油性感を感じずに、みずみずしく感じることをいう。「のびの軽さ」は、皮膚に塗布している際に、抵抗感が少なく、タッチが軽く感じることをいう。「潤い」及び「のびの軽さ」は、後述する実施例に記載の使用感評価により評価及び確認できる。
「(メタ)アクリル酸」は、アクリル酸及びメタクリル酸を包含する総称である。
本発明の一態様の方法は、水中油型乳化化粧料を製造するための方法である。
本発明の一態様の方法は、疎水化表面処理された微粒子金属酸化物、親油性乳化剤、アクリル酸ナトリウム/アクリロイルジメチルタウリンナトリウム共重合体及び液状油を含む油相に、親水性乳化剤及び基剤である水を含む水相を添加して、転相乳化することにより、水中油型乳化化粧料を得る工程を少なくとも含む。
本発明の一態様の化粧料は、本発明の一態様の方法によって得られる、水中油型乳化化粧料である。
(1−1)実施例1〜実施例11の化粧料
表1に示した処方に従い、以下の手順により、実施例1〜実施例11の化粧料を調製した。なお、表中の数値は、質量%(wt%)を表わす。
表1に示した処方に従い、上記(1−1)と同様にして、比較例1〜比較例4の化粧料を得た。
表1に示した処方に従い、上記(1−1)と同様にして、油相及び水相をそれぞれ調製した。
表1に示した処方に従い、上記(1−1)と同様にして、参考例1〜参考例3の化粧料を得た。
化粧料を目視及び顕微鏡で観察して、均一な乳化状態を確認できた場合は「○」とし、均一な乳化状態を確認できなかった場合は「×」と評価した。
化粧料を精製水で希釈し、レーザー回折粒度分布計(「SALD−2000J」又は「(SALD−2300」;島津製作所社製)を用いて、屈折率1.60−0.10iにて乳化粒子の体積平均粒子径(平均値±標準偏差)を測定した。また、顕微鏡(「BX41」;OLYMPUS社製)、及び500万画素の高精細顕微鏡用デジタルカメラ(「DP26」;OLYMPUS社製)を用いて、乳化の状態を撮影した。
pHは、常法に従ってpHメーター(「pH METER F−22」;堀場製作所社製)を使用して測定した。
粘度は、BM型粘度計(「VISCOMETER TVB−25L」;東機産業社製)を使用して測定した。測定条件は、SPINDLE No.M3、20rpmとした。調製直後の化粧料について、測定開始から3分後の粘度値(mPa・s)を読み取った。
SPFは、以下の手順によりSPFアナライザー(「HM021224 UV−1000S」;Labsphere社製)を用いて測定した。
化粧料をガラス製の規格ビンに充填し、40℃で1ヵ月保管した後、目視にて相分離の有無を確認して、相分離が起きていない場合は「○」とし、相分離が起きている場合は「×」と評価した。
訓練を受けたパネラー4名を対象として、化粧料を直接的に皮膚へ塗布することにより、対照品1を用いて、「潤い」及び「のびの軽さ」を下記の基準により点数をつけてパネラー間の平均点及び標準偏差を求めた。
「対照品1」:
油剤であるトリエチルヘキサノインが10wt%であること以外は実施例2と組成が同一であり、かつ、順相乳化により得られた水中油型乳化化粧料
各項目の評価基準:
2点 対照品1より優れている
1点 対照品1と同程度
0点 対照品1より劣る
(3−1)乳化状態
乳化状態の観察結果を表1に示す。
実施例2、比較例5、比較例6及び参考例4の化粧料の粒子径の測定結果を図1に示す。図1に示すとおり、転相乳化による実施例2の化粧料は、順相乳化によるその他の化粧料に比べて、粒子径が小さいことがわかった。
実施例2、実施例4及び実施例8〜実施例11の化粧料のpH及び粘度を測定した結果を表2に示す。
実施例2、実施例4、実施例6、比較例5、比較例6、参考例1及び参考例4の化粧料のSPFの測定結果を表3に示す。
実施例2、実施例4、実施例6及び実施例8〜実施例11の化粧料の安定性を調べたところ、保管期間を通じて相分離は確認されず、すべて「○」と評価された。
実施例2、比較例5及び参考例4の化粧料について使用感を評価したところ、実施例2の化粧料は、パネラーの全てが「潤い」及び「のびの軽さ」について対照品1よりも優れている(2点)と評価した。それに対して、比較例5の化粧料は、「潤い」又は「のびの軽さ」が対照品1と同程度(1点)又は劣っている(0点)と評価したパネラーがいた。したがって、実施例2の化粧料は、「潤い」及び「のびの軽さ」に関する使用感について、比較例5の化粧料よりも優れたものであることがわかった。一方、実施例2及び参考例4の化粧料を比べると、「潤い」については両者においてほとんど差異はみられなかったが、「のびの軽さ」は明らかに実施例2の化粧料が優れていた。
疎水化表面処理された微粒子金属酸化物、親油性乳化剤、アクリル酸ナトリウム/アクリロイルジメチルタウリンナトリウム共重合体及び液状油を含む油相に、親水性乳化剤を含む水相を添加して、転相乳化することにより得られた水中油型乳化化粧料は、紫外線防御効果がありながら、比較的多量の油性成分を含有しつつも、乳化剤の含有量を低減してなるものであり、さらに粒子径が細かく、使用感が優れたものであり得ることがわかった。
Claims (9)
- 疎水化表面処理された微粒子金属酸化物、親油性乳化剤、アクリル酸ナトリウム/アクリロイルジメチルタウリンナトリウム共重合体及び液状油を含む油相に、
親水性乳化剤を含む水相を添加して、
転相乳化することにより、
水中油型乳化化粧料を得る工程を含む、水中油型乳化化粧料の製造方法。 - 疎水化表面処理された微粒子金属酸化物と、
親油性乳化剤と、
アクリル酸ナトリウム/アクリロイルジメチルタウリンナトリウム共重合体と、
液状油と、
親水性乳化剤と
を含む、転相乳化物である、水中油型乳化化粧料。 - 前記親水性乳化剤は、HLBが8以上の親水性乳化剤である、請求項1〜2のいずれか1項に記載の方法又は化粧料。
- 前記疎水化表面処理された微粒子金属酸化物の含有量は、5質量%〜20質量%である、請求項1〜3のいずれか1項に記載の方法又は化粧料。
- 前記親油性乳化剤及び前記親水性乳化剤の合計含有量が2質量%未満である、請求項1〜4のいずれか1項に記載の方法又は化粧料。
- 前記水中油型乳化化粧料は、さらに紫外線吸収剤を含む、請求項2〜5のいずれか1項に記載の化粧料。
- 前記水中油型乳化化粧料は、油性成分の合計含有量が15質量%以上である、請求項2〜6のいずれか1項に記載の化粧料。
- 前記水中油型乳化化粧料は、粘度が10,000mPa・s以下であり、及び/又は体積平均粒子径が9.5μm以下である、請求項2〜7のいずれか1項に記載の化粧料。
- 前記水中油型乳化化粧料は、日焼け止め乳液である、請求項2〜8のいずれか1項に記載の化粧料。
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