JP2020524203A - 潜在性硬化剤及び硬化性ポリウレタン組成物 - Google Patents
潜在性硬化剤及び硬化性ポリウレタン組成物 Download PDFInfo
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- JP2020524203A JP2020524203A JP2019569949A JP2019569949A JP2020524203A JP 2020524203 A JP2020524203 A JP 2020524203A JP 2019569949 A JP2019569949 A JP 2019569949A JP 2019569949 A JP2019569949 A JP 2019569949A JP 2020524203 A JP2020524203 A JP 2020524203A
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Classifications
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- C07D413/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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Abstract
Description
nは、1、2又は3であり、
Zは、アルキル又はアルコキシ基で置換され、且つ、合計で12〜26個の炭素原子を有するアリール残基であり、
Aは、15〜10000g/molの範囲内の分子量を有するn価有機残基であり、
Xは、O若しくはS又はNR0(ここで、R0は1〜18個の炭素原子を有する一価有機残基である)であり、並びに
Yは、任意選択により置換されている1,2−エチレン又は1,3−プロピレン残基であり、
ここで、A及びYは、n=1である場合、4〜10個の炭素原子を有する三価残基に結合していてもよい)
の化合物を提供する。
の残基でもあり得る。
− 式(III)のアミンが、化学量論的に用いられるか、又は、特にXH基に関して化学量論的過剰量で用いられる式(IV)のアルデヒドと組み合わされて、反応混合物がもたらされ、
− 並びに、存在する縮合水及びいずれかの溶剤が、上記の組み合わせるステップの最中又はその後に、任意選択により、その加熱及び/又は減圧の適用といった好適な方法により、反応混合物から除去される
ように実施される。
− 少なくとも1つの式(I)の化合物、並びに
− 少なくとも1つのポリイソシアネート及び/又はイソシアネート基を含有する少なくとも1つのポリウレタンポリマー
を含む組成物を提供する。
− 芳香族ジ又はトリイソシアネート、好ましくはジフェニルメタン4,4’−若しくは2,4’−若しくは2,2’−ジイソシアネート又はこれらの異性体の任意の混合物(MDI)、トリレン2,4−若しくは2,6−ジイソシアネート又はこれらの異性体の任意の混合物(TDI)、MDIとMDI同族体(ポリマーMDI又はPMDI)との混合物、フェニレン1,3−若しくは1,4−ジイソシアネート、2,3,5,6−テトラメチル−1,4−ジイソシアナトベンゼン、ナフタレン1,5−ジイソシアネート(NDI)、3,3’−ジメチル−4,4’−ジイソシアナトジフェニル(TODI)、ジアニシジンジイソシアネート(DADI)、トリス(4−イソシアナトフェニル)メタンまたトリス(4−イソシアナトフェニル)チオホスフェート;好ましくはMDI又はTDI;
− 脂肪族、脂環式又はアリール脂肪族ジ又はトリイソシアネート、好ましくはテトラメチレン1,4−ジイソシアネート、2−メチルペンタメチレン1,5−ジイソシアネート、ヘキサメチレン1,6−ジイソシアネート(HDI)、2,2,4−及び/若しくは2,4,4−トリメチルヘキサメチレン1,6−ジイソシアネート(TMDI)、デカメチレン1,10−ジイソシアネート、ドデカメチレン1,12−ジイソシアネート、リジンジイソシアネート若しくはリジンエステルジイソシアネート、シクロヘキサン1,3−若しくは1,4−ジイソシアネート、1−メチル−2,4−及び/若しくは2,6−ジイソシアナトシクロヘキサン(H6TDI)、1−イソシアナト−3,3,5−トリメチル−5−イソシアナトメチルシクロヘキサン(IPDI)、ペルヒドロジフェニルメタン2,4’−及び/若しくは4,4’−ジイソシアネート(H12MDI)、1,3−若しくは1,4−ビス(イソシアナトメチル)シクロヘキサン、m−若しくはp−キシリレンジイソシアネート、テトラメチルキシリレン1,3−若しくは1,4−ジイソシアネート、1,3,5−トリス(イソシアナトメチル)ベンゼン、ビス(1−イソシアナト−1−メチルエチル)ナフタレン、特に3,6−ビス(9−イソシアナトノニル)−4,5−ジ(1−ヘプテニル)シクロヘキセン(ジメリルジイソシアネート)などのダイマー若しくはトリマー脂肪酸イソシアネート;好ましくはH12MDI又はHDI又はIPDI;
− 述べられたジ又はトリイソシアネートの、とりわけHDI、IPDI、MDI又はTDIに由来するオリゴマー又は誘導体、とりわけウレトジオン、若しくはイソシアヌレート、若しくはイミノオキサジアジンジオン基又はこれらの中の様々な基を含有するオリゴマー;又はエステル、若しくはウレア、若しくはウレタン、若しくはビウレット、若しくはアロファネート、若しくはカルボジイミド、若しくはウレトンイミン、若しくはオキサジアジントリオン基又はこれらの中の様々な基を含有する二官能性又は多官能性誘導体。実際には、この種のポリイソシアネートは、典型的には、異なる程度のオリゴマー化及び/又は化学構造を有する物質の混合物である。それらは、とりわけ2.1〜4.0の平均NCO官能性を有する。
− ポリエーテルポリオール、とりわけポリオキシアルキレンジオール及び/若しくはポリオキシアルキレントリオール、とりわけエチレンオキシド、又は1,2−プロピレンオキシド、又は1,2−若しくは2,3−ブチレンオキシド、又はオキセタン、又はテトラヒドロフラン、又はそれらの混合物の重合生成物。ここで、これらは、2個以上の活性水素原子を有するスターター分子、とりわけ水、アンモニア又は多数のOH若しくはNH基を有する化合物、例えばエタン−1,2−ジオール、プロパン−1,2−若しくは−1,3−ジオール、ネオペンチルグリコール、ジエチレングリコール、トリエチレングリコール、異性体ジプロピレングリコール若しくはトリプロピレングリコール、異性体ブタンジオール、ペンタンジオール、ヘキサンジオール、ヘプタンジオール、オクタンジオール、ノナンジオール、デカンジオール、ウンデカンジオール、シクロヘキサン−1,3−若しくは−1,4−ジメタノール、ビスフェノールA、水素化ビスフェノールA、1,1,1−トリメチロールエタン、1,1,1−トリメチロールプロパン、グリセロール又はアニリン又は前述の化合物の混合物などのスターター分子を用いて重合され得る。同様に、ポリマー粒子がその中に分散したポリエーテルポリオール、とりわけスチレン/アクリロニトリル(SAN)粒子、又はポリウレア、又はポリヒドラゾジカルボンアミド(PHD)粒子が分散したものが好適である。
− 公知の方法、とりわけヒドロキシカルボン酸若しくはラクトンの重縮合又は脂肪族及び/若しくは芳香族ポリカルボン酸と二価若しくは多価アルコールとの重縮合によって調製され、オリゴエステロールとも呼ばれるポリエステルポリオール。特に1,2−エタンジオール、ジエチレングリコール、1,2−プロパンジオール、ジプロピレングリコール、1,4−ブタンジオール、1,5−ペンタンジオール、1,6−ヘキサンジオール、ネオペンチルグリコール、グリセロール、1,1,1−トリメチロールプロパン又は前述のアルコール混合物などの二価アルコールと、特にコハク酸、グルタル酸、アジピン酸、スベリン酸、セバシン酸、ドデカンジカルボン酸、マレイン酸、フマル酸、フタル酸、イソフタル酸、テレフタル酸若しくはヘキサヒドロフタル酸又は前述の酸の混合物との反応からのポリエステルジオール又は特にε−カプロラクトンなどのラクトンからのポリエステルポリオールが好ましい。アジピン酸又はセバシン酸又はドデカンジカルボン酸と、ヘキサンジオール又はネオペンチルグリコールとからのポリエステルポリオールが特に好ましい。
− 例えば、− ポリエステルポリオールを形成するために使用される − 上述のアルコールと、ジアルキルカーボネート、ジアリールカーボネート又はホスゲンとの反応によって得られるようなポリカーボネートポリオール。
− 少なくとも2個のヒドロキシル基を有し、且つ上記のタイプのポリエーテル、ポリエステル及び/又はポリカーボネート構造を有する少なくとも2つの異なるブロック、とりわけポリエーテルポリエステルポリオールを有するブロックコポリマー。
− ポリアクリレートポリオール及びポリメタクリレートポリオール。
− ポリヒドロキシ官能性脂肪及び油、例えば天然脂肪及び油、とりわけヒマシ油;又は天然脂肪及び油の化学修飾によって得られるポリオール − 油脂化学ポリオールと呼ばれる −、例えば不飽和油のエポキシ化及びその後のカルボン酸若しくはアルコールでの開環によって得られるエポキシポリエステル又はエポキシポリエーテル又は不飽和油のヒドロホルミル化及び水素化によって得られるポリオール;又はアルコール分解若しくはオゾン分解などの分解プロセス及びこのようにして得られたその分解生成物若しくは誘導体の、例えばエステル交換若しくは二量化による、その後の化学結合によって天然脂肪及び油から得られるポリオール。天然脂肪及び油の好適な分解生成物は、とりわけ、脂肪酸及び脂肪アルコール並びにまた脂肪酸エステル、とりわけメチルエステル(FAME)であり、それらは、例えば、ヒドロホルミル化及び水素化によってヒドロキシ脂肪酸エステルに誘導体化することができる。
− オリゴヒドロカーボンオールとも呼ばれる、ポリ炭化水素ポリオール、例えばポリヒドロキシ官能性ポリオレフィン、ポリイソブチレン、ポリイソプレン;例えば、Kraton Polymerによって製造されるようなポリヒドロキシ官能性エチレン/プロピレン、エチレン/ブチレン又はエチレン/プロピレン/ジエンコポリマー;アニオン重合からとりわけまた調製することができる、ジエン、とりわけ1,3−ブタジエンのポリヒドロキシ官能性ポリマー;1,3−ブタジエンなどのジエン若しくはジエン混合物と、スチレン、アクリロニトリル、塩化ビニル、酢酸ビニル、ビニルアルコール、イソブチレン及びイソプレンなどのビニルモノマーとのポリヒドロキシ官能性コポリマー、例えばエポキシド若しくはアミノアルコールと、カルボキシル末端アクリロニトリル/ブタジエンコポリマーとから、例えば調製可能なようなポリヒドロキシ官能性アクリロニトリル/ブタジエンコポリマー(Emerald Performance Materialsから、例えばHypro(登録商標)CTBN若しくはCTBNX若しくはETBN名で商業的に入手可能な);並びにジエンの水素化ポリヒドロキシ官能性ポリマー若しくはコポリマー。
− 無機若しくは有機顔料、とりわけ二酸化チタン、酸化クロム又は酸化鉄;
− 繊維、とりわけガラス繊維、炭素繊維、金属繊維、セラミック繊維、ポリアミド繊維若しくはポリエチレン繊維などのポリマー繊維又は羊毛、セルロース、大麻若しくはサイザル麻などの天然繊維;
− 染料;
− 乾燥剤、とりわけモレキュラーシーブ粉末、酸化カルシウム、p−トシルイソシアネート、モノマージイソシアネートなどの高反応性イソシアネート又はオルトギ酸エステル;
− 接着促進剤、とりわけオルガノアルコキシシラン、とりわけ特に3−グリシドキシプロピルトリメトキシシラン若しくは3−グリシドキシプロピルトリエトキシシランなどのエポキシシラン、(メタ)アクリロシラン、アンヒドリドシラン、カルバマトシラン、アルキルシラン若しくはイミノシラン又はこれらのシランのオリゴマー形態或いはチタネート;
− 潜在性硬化剤又は架橋剤、とりわけ式(I)に従わないアルジミン、ケチミン、エナミン又はオキサゾリジン;
− イソシアネート基の反応を加速するさらなる触媒、とりわけスズ、亜鉛、ビスマス、鉄、アルミニウム、モリブデン、ジオキソモリブデン、チタン、ジルコニウム若しくはカリウムの塩、石鹸若しくは錯体、とりわけスズ(II)2−エチルヘキサノエート、スズ(II)ネオデカノエート、亜鉛(II)アセテート、亜鉛(II)2−エチルヘキサノエート、亜鉛(II)ラウレート、亜鉛(II)アセチルアセトナート、アルミニウムラクテート、アルミニウムオレエート、ジイソプロポキシチタンビス(エチルアセトアセテート)若しくはカリウムアセテート;第三級アミノ基を含有する化合物、とりわけN−エチルジイソプロピルアミン、N,N,N’,N’−テトラメチルアルキレンジアミン、ペンタメチルアルキレントリアミン及びその高級同族体、ビス(N,N−ジエチルアミノエチル)アジペート、トリス(3−ジメチルアミノプロピル)アミン、1,4−ジアザビシクロ[2.2.2]オクタン(DABCO)、1,8−ジアザビシクロ[5.4.0]ウンデカ−7−エン(DBU)、1,5−ジアザビシクロ[4.3.0]ノナ−5−エン(DBN)、N−アルキルモルホリン、N,N’−ジメチルピペラジン;4−ジメチルアミノピリジン、N−メチルイミダゾール、N−ビニルイミダゾール若しくは1,2−ジメチルイミダゾールなどの芳香族窒素化合物;水酸化ベンジルトリメチルアンモニウムなどの有機アンモニウム化合物又はアルコキシル化第三級アミン;公知の金属若しくはアミン触媒の改質である、「遅延作用」触媒と呼ばれるもの;
− レオロジー調整剤、とりわけ増粘剤、とりわけベントナイトなどの層状シリケート、ヒマシ油の誘導体、水素化ヒマシ油、ポリアミド、ポリアミドワックス、ポリウレタン、ウレア化合物、ヒュームドシリカ、セルロースエーテル又は疎水的に改質されたポリオキシエチレン;
− 天然樹脂、ロジン、セラック、アマニ油、ヒマシ油又は大豆油などの脂肪又は油;
− 非反応性ポリマー、とりわけエチレン、プロピレン、ブチレン、イソブチレン、イソプレン、酢酸ビニル若しくはアルキル(メタ)アクリレートからの、とりわけ不飽和モノマーのホモポリマー若しくはコポリマー、とりわけポリエチレン(PE)、ポリプロピレン(PP)、ポリイソブチレン、エチレン/酢酸ビニルコポリマー(EVA)又はアタクチックポリ−α−オレフィン(APAO);
− 難燃性物質、とりわけ既に述べられた水酸化アルミニウム若しくは水酸化マグネシウム及びまた特に有機リン酸エステル、例えば特にトリエチルホスフェート、トリクレジルホスフェート、トリフェニルホスフェート、ジフェニルクレジルホスフェート、イソデシルジフェニルホスフェート、トリス(1,3−ジクロロ−2−プロピル)ホスフェート、トリス(2−クロロエチル)ホスフェート、トリス(2−エチルヘキシル)ホスフェート、トリス(クロロイソプロピル)ホスフェート、トリス(クロロプロピル)ホスフェート、イソプロピル化トリフェニルホスフェート、異なる程度のイソプロピル化のモノ、ビス若しくはトリス(イソプロピルフェニル)ホスフェート、レゾルシノールビス(ジフェニルホスフェート)、ビスフェノールAビス(ジフェニルホスフェート)などの有機リン酸エステル又はアンモニウムポリホスフェート;
− 添加剤、とりわけ湿潤剤、レベリング剤、消泡剤、脱気剤、酸化、熱、光若しくはUV放射線に対する安定剤又は殺生物剤;
又は水分硬化組成物に習慣的に使用されるさらなる物質。
bは2又は3であり、
Gは、任意選択によりエーテル酸素を含有し、及び、28〜6,000g/molの範囲内の分子量を有する、b価の脂肪族、脂環式又はアリール脂肪族ヒドロカルビル残基であり、
R4は、7〜17個の炭素原子を有するアルキル残基、特に、11個の炭素原子を有する直鎖アルキル残基であり、
並びに、Zは既述の定義を有する)
を有することが好ましい。
− ガラス、ガラスセラミック、コンクリート、モルタル、繊維セメント、とりわけ繊維セメント板、煉瓦、タイル、石膏、とりわけ石膏板又は花崗岩若しくは大理石などの天然石;
− PCC(ポリマー改質セメントモルタル)又はECC(エポキシ樹脂改質セメントモルタル)をベースとする修理又はレベリングコンパウンド;
− 表面仕上げ金属を含む、アルミニウム、銅、鉄、スチール、非鉄金属又は亜鉛めっき若しくはクロムめっき金属などの合金などの金属又は合金;
− アスファルト又はビチューメン;
− 皮革、織物、紙、木材、フェノール樹脂、メラミン樹脂若しくはエポキシ樹脂などの樹脂で接合された木質系材料、樹脂/織物複合材料又はポリマー複合材料と呼ばれるさらなる材料;
− 各場合に未処理の若しくは例えばプラズマ、コロナ若しくは火炎によって表面処理された、硬質及び軟質PVC、ポリカーボネート、ポリスチレン、ポリエステル、ポリアミド、PMMA、ABS、SAN、エポキシ樹脂、フェノール樹脂、PUR、POM、TPO、PE、PP、EPM若しくはEPDMなどのプラスチック;
− 炭素繊維強化プラスチック(CFP)、ガラス繊維強化プラスチック(GFP)及びシート成形コンパウンド(SMC)などの繊維強化プラスチック;
− EPS、XPS、PUR、PIR、ロックウール、ガラスウール若しくは発泡ガラスでとりわけできた絶縁発泡体;
− 被覆若しくは塗装基材、とりわけ塗装タイル、被覆コンクリート、粉体塗装した金属若しくは合金又は塗装金属シート;
− ペイント又はワニス、とりわけ自動車トップコート
である。
の少なくとも1つのアルデヒドの使用を提供する。
アルデヒド−1: HF−BF3、主に分岐型である4−(C10〜14−アルキル)ベンズアルデヒドを含有するC10〜14−アルキルベンゼンにより触媒されたホルミル化から得られた分割したアルデヒド混合物。(平均アルデヒド換算重量290g/eq)
ベンズアルデヒド(106.1g/mol)
イソブチルアルデヒド(72.1g/mol)
2,2−ジメチル−3−ラウロイルオキシプロパナール(284.4g/mol)
アルデヒド−1は、式(IV)のアルデヒドの混合物である。
ベンズアルデヒド及び2,2−ジメチル−3−ラウロイルオキシプロパナールは、式(IV)に従うものではない。
アミン価(ブロックされたアミノ基を含む)は、滴定(クリスタルバイオレットに対して酢酸中の0.1N HClO4を使用)により測定した。
丸底フラスコ中における63.09gのジエタノールアミンの初期仕込み物に、178.09gのアルデヒド−1及び0.50gのサリチル酸を添加し、反応混合物を、80℃、減圧下に、すべての水が除去されるまで撹拌した。141.6mg KOH/gのアミン価を有する黄褐色の液体を得た。
FT−IR:2954,2923,2871,2857,1704,1607,1509,1465,1425,1378,1343,1298,1213,1174,1045,1018,937,884,825,722.
窒素雰囲気下に、丸底フラスコ中における、上記のとおり調製した37.80gのオキサゾリジンA−1の初期仕込み物を加熱した。80℃で、8.33gのヘキサメチレン1,6−ジイソシアネートを滴下し、次いで、混合物を、80℃で、IR分光分析によりこれ以上イソシアネート基が検出されなくなるまで撹拌した。室温で液体であり、60℃で16.9Pa・sの粘度、及び、116.4mg KOH/gのアミン価を有する高粘度の黄色の油を得た。蓋をした容器の中で18カ月の貯蔵期間の後、粘稠度及び粘度は変化していなかった。
FT−IR:2955,2923,2853,1704,1634,1532,1463,1376,1352,1242,1213,1178,1105,1057,1019,825,772,722.
各端部に末端2−ヒドロキシプロピルアミノ基を有し、及び、約350g/molの平均分子量を有する44.50gのポリオキシプロピレン(Huntsman製のJeffamine(登録商標)C−346)の初期仕込み物に、丸底フラスコ中において、80.00gのアルデヒド−1及び0.50gのサリチル酸を添加し、反応混合物を、80℃、減圧下に、すべての水が除去されるまで撹拌した。20℃で1.1Pa・sの粘度、及び、111.8mg KOH/gのアミン価を有する黄褐色の液体を得た。
FT−IR:2957,2923,2870,2853,1726,1704,1645,1606,1575,1456,1375,1304,1212,1194,1168,1094,1062,1017,826,722.
丸底フラスコ中における、本明細書に後述のとおり調製した29.79gのN−(3−(2−メチルフェニルオキシ)−2−ヒドロキシ−1−プロピル)プロパン−1,2−ジアミンの初期仕込み物に、80.00gのアルデヒド−1及び0.50gのサリチル酸を添加し、反応混合物を、80℃、減圧下に、すべての水が除去されるまで撹拌した。20℃で3.0Pa・sの粘度、及び、116.5mg KOH/gのアミン価を有するオレンジ色の液体を得た。
FT−IR:2955,2923,2870,2853,1704,1645,1605,1495,1461,1378,1304,1245,1213,1168,1122,1051,1018,826,748,722.
丸底フラスコ中における、本明細書に後述のとおり調製した35.05gのN−(3−(2−メチルフェニルオキシ)−2−ヒドロキシ−1−プロピル)−2(4)−メチルペンタン−1,5−ジアミンの初期仕込み物に、80.00gのアルデヒド−1及び0.50gのサリチル酸を添加し、反応混合物を80℃、減圧下にロータリーエバポレータで、すべての水が除去されるまで撹拌した。20℃で3.1Pa・sの粘度、及び、112.0mg KOH/gのアミン価を有するオレンジ色の液体を得た。
FT−IR:2955,2923,2870,2853,1704,1647,1605,1495,1461,1377,1304,1245,1168,1122,1051,1038,1018,827,748,712.
丸底フラスコ中における、約240g/molの平均分子量を有する30.16gのポリオキシプロピレンジアミン(Huntsman製のJeffamine(登録商標)D−230)の初期仕込み物を、70℃に加熱した。撹拌しながら、37.55gのフェニルグリシジルエーテルをゆっくりと添加し、次いで、混合物を80℃で2時間、窒素雰囲気下に撹拌して、ビス(α,β−ヒドロキシルアミン)を形成した。この反応生成物に、80.00gのアルデヒド−1及び0.50gのサリチル酸を添加し、反応混合物を、80℃、減圧下に、すべての水が除去されるまで撹拌した。20℃で3.5Pa・sの粘度、及び、100.9mg KOH/gのアミン価を有する黄褐色の液体を得た。
FT−IR:2956,2923,2870,2853,1704,1645,1600,1587,1496,1456,1376,1301,1244,1170,1101,1077,1042,1018,827,752,690.
手法はオキサゾリジンA−6に記載したものであったが、ただし、約2,000g/molの平均分子量を有する250.00gのポリオキシプロピレンジアミン(Huntsman製のJeffamine(登録商標)D−2000)を、約240g/molの平均分子量を有するポリオキシプロピレンジアミンの代わりに用いた。20℃で1.8Pa・sの粘度、及び、31.3mg KOH/gのアミン価を有するオレンジ色の液体を得た。
FT−IR:2968,2926,2897,2858,1704,1601,1497,1456,1372,1343,1245,1098,1015,925,828,753,691.
丸底フラスコ中における、16.97gのメチルペンタンジオールジアクリレート(Sartomer製のSR341)の初期仕込み物に、9.16gのエタノールアミンを添加し、反応混合物を50℃に加熱し、2時間撹拌して、ビス(α,β−ヒドロキシルアミン)を形成した。この反応生成物に、45.83gのアルデヒド−1及び0.50gのサリチル酸を添加し、反応混合物を、80℃、減圧下に、すべての水が除去されるまで撹拌した。20℃で1.6Pa・sの粘度、及び、121.0mg KOH/gのアミン価を有する黄褐色の液体を得た。
FT−IR:2955,2923,2871,2853,1734,1704,1647,1607,1458,1378,1301,1212,1179,1109,1054,1018,826,722.
手法はオキサゾリジンA−8に記載したものであったが、ただし、11.27gの3−アミノ−1−プロパノールをエタノールアミンの代わりに用いた。20℃で2.9Pa・sの粘度、及び、118.6mg KOH/gのアミン価を有する黄褐色の液体を得た。
FT−IR:2954,2923,2853,1734,1705,1461,1378,1305,1177,1157,1117,1079,1051,977,924,826,781,722.
水分離装置(ディーンスターク装置)を備える丸底フラスコ中における5.21gのN−(2−アミノエチル)エタノールアミンの初期仕込み物に、30.56gのアルデヒド−1、50mlのシクロヘキサン及び0.10gのサリチル酸を添加し、反応混合物を、還流下に120℃で、すべての水が分離されるまで沸騰させた。その後、反応混合物を冷却及びろ過し、揮発性成分を減圧下にロータリーエバポレータで、80℃で除去した。20℃で1.1Pa・sの粘度、及び、160.2mg KOH/gのアミン価を有するオレンジ色の液体を得た。
FT−IR:2955,2920,2852,1705,1647,1608,1572,1457,1377,1343,1301,1220,1174,1138,1060,1018,986,962,826,722.
丸底フラスコ中における、11.62gのN,N’−ジエチルエチレンジアミンの初期仕込み物に、撹拌しながら、32.01gのアルデヒド−1を添加した。その後、反応混合物から、80℃、減圧下にロータリーエバポレータで反応水を除去した。20℃で0.09Pa・sの粘度、及び、265.7mg KOH/gのアミン価を有するオレンジ色の液体を得た。
FT−IR:2957,2924,2871,2853,2792,2525,1706,1607,1508,1465,1423,1377,1340,1280,1226,1164,1055,1019,995,958,861,824,805,722.
丸底フラスコ中における、24.04gのN,N’−ジベンジルエチレンジアミンの初期仕込み物に、撹拌しながら、32.01gのアルデヒド−1を添加した。その後、反応混合物から、80℃、減圧下にロータリーエバポレータで、反応水を除去した。20℃で1.41Pa・sの粘度、及び、210.4mg KOH/gのアミン価を有するオレンジ色の液体を得た。
FT−IR:3085,3062,2954,2923,2870,2852,2792,2722,2520,1804,1705,1605,1507,1453,1423,1377,1338,1295,1248,1212,1153,1120,1072,1028,975,911,861,827,735,690,667.
水分離装置(ディーンスターク装置)を備える丸底フラスコ中における11.72gのN−ブチルエタノールアミンの初期仕込み物に、29.68gのアルデヒド−1.75mlのシクロヘキサン及び0.10gのサリチル酸を添加し、反応混合物を、還流下に120℃で、すべての水が分離されるまで沸騰させた。その後、反応混合物を冷却及びろ過し、揮発性成分を減圧下にロータリーエバポレータで、80℃で除去した。20℃で0.07Pa・sの粘度、及び、142.1mg KOH/gのアミン価を有する黄褐色の液体を得た。
FT−IR:2955,2921,2854,2800,1706,1614,1576,1464,1426,1377,1341,1296,1217,1178,1152,1067,1019,957,925,826,741,722.
丸底フラスコ中における、13.92g(50mmol)の3−グリシドキシプロピルトリエトキシシラン(Evonik製のDynasylan(登録商標)GLYEO)の初期仕込み物に、22.14g(100mmol)の3−アミノプロピルトリエトキシシラン(Evonik製のDynasylan(登録商標)AMEO)を添加し、混合物を70℃で、エポキシ基が転換されるまで撹拌した。その後、30.56gのアルデヒド−1を添加し、反応混合物から、80℃、減圧下にロータリーエバポレータで反応水を除去した。20℃で0.35Pa・sの粘度、及び、87.6mg KOH/gのアミン価を有する薄いオレンジ色の液体を得た。
FT−IR:2957,2924,2854,1705,1647,1607,1573,1508,1456,1389,1343,1297,1166,1102,1076,1017,954,827,774.
手法はオキサゾリジンA−1に記載したものであったが、ただし、64.95gのベンズアルデヒドをアルデヒド−1の代わりに用いた。288.2mg KOH/gのアミン価を有する薄い茶色の液体を得た。
窒素雰囲気下に、丸底フラスコ中における、上記のとおり調製した37.80gのオキサゾリジンB−1の初期仕込み物を加熱した。80℃で、8.33gのヘキサメチレン1,6−ジイソシアネートを滴下し、次いで、混合物を、80℃で、IR分光分析によりこれ以上イソシアネート基が検出されなくなるまで撹拌した。得られたものは、室温で固体であり、及び、181.4mg KOH/gのアミン価を有し、60℃で583.5Pa・sの粘度を有する黄色の物質であった。
手法はオキサゾリジンA−3に記載したものであったが、ただし、29.18gのベンズアルデヒドをアルデヒド−1の代わりに用いた。20℃で1.9Pa・sの粘度、及び、219.4mg KOH/gのアミン価を有する薄い茶色の液体を得た。
手法はオキサゾリジンA−4に記載したものであったが、ただし、29.18gのベンズアルデヒドをアルデヒド−1の代わりに用いた。得られたものは、20℃で1,945Pa・sの粘度、及び、249.0mg KOH/gのアミン価を有する粘性の濃いオレンジ色の油であり、これは、室温で静置したところ、数週間の間にゆっくりと固化した。
手法はオキサゾリジンA−5に記載したものであったが、ただし、29.18gのベンズアルデヒドをアルデヒド−1の代わりに用いた。20℃で93.5Pa・sの粘度、及び、226.0mg KOH/gのアミン価を有するオレンジ色の油を得た。
手法はオキサゾリジンA−6に記載したものであったが、ただし、29.18gのベンズアルデヒドをアルデヒド−1の代わりに用いた。20℃で84.5Pa・sの粘度、及び、161.0mg KOH/gのアミン価を有するオレンジ色の油を得た。
手法はオキサゾリジンA−7に記載したものであったが、ただし、29.18gのベンズアルデヒドをアルデヒド−1の代わりに用いた。20℃で2.0Pa・sの粘度、及び、40.9mg KOH/gのアミン価を有するオレンジ色の液体を得た。
手法はオキサゾリジンA−8に記載したものであったが、ただし、16.72gのベンズアルデヒドをアルデヒド−1の代わりに用いた。20℃で2.0Pa・sの粘度、及び、216.6mg KOH/gのアミン価を有する黄褐色の液体を得た。
手法はオキサゾリジンA−9に記載したものであったが、ただし、16.72gのベンズアルデヒドをアルデヒド−1の代わりに用いた。20℃で10.5Pa・sの粘度、及び、205.1mg KOH/gのアミン価を有する黄褐色の液体を得た。
水分離装置(ディーンスターク装置)を備える丸底フラスコ中における15.00gのN−(2−アミノエチル)エタノールアミンの初期仕込み物に、32.10gのベンズアルデヒド、50mlのシクロヘキサン及び0.10gのサリチル酸を添加し、反応混合物を、還流下に120℃で、すべての水が分離されるまで沸騰させた。その後、反応混合物を冷却及びろ過し、揮発性成分を減圧下にロータリーエバポレータで、80℃で除去した。20℃で0.83Pa・sの粘度、及び、385.1mg KOH/gのアミン価を有するオレンジ色の液体を得た。
手法はオキサゾリジンA−1に記載したものであったが、ただし、174.65gの2,2−ジメチル−3−ラウロイルオキシプロパナールをアルデヒド−1の代わりに用いた。141.2mg KOH/gのアミン価を有する黄褐色の液体を得た。
窒素雰囲気下に、丸底フラスコ中における、上記のとおり調製した39.73gのオキサゾリジンL−1の初期仕込み物を加熱した。80℃で、8.33gのヘキサメチレン1,6−ジイソシアネートを滴下し、次いで、混合物を、80℃で、IR分光分析によりこれ以上イソシアネート基が検出されなくなるまで撹拌した。20℃で6Pa・sの粘度、及び、115.2mg KOH/gのアミン価を有する黄褐色の液体を得た。
窒素雰囲気下に、丸底フラスコ中における15.92gのN−(2−ヒドロキシエチル)−2−イソプロピルオキサゾリジン(Incorez製のIncozol 3)の初期仕込み物を加熱した。80℃で、8.33gのヘキサメチレン1,6−ジイソシアネートを滴下し、次いで、混合物を、80℃で、IR分光分析によりこれ以上イソシアネート基が検出されなくなるまで撹拌した。得られたものは、20℃で36Pa・sの粘度、及び、220.0mg KOH/gのアミン価を有する黄褐色の液体であり、これは、数週間の内に結晶化し、さらなる使用のためには溶融させる必要があった。
水分離装置(ディーンスタークトラップ)を備える丸底フラスコ中における15.00gのN−(2−アミノエチル)エタノールアミンの初期仕込み物に、21.81gのイソブチルアルデヒド、50mlのシクロヘキサン及び0.10gのサリチル酸を添加し、反応混合物を、還流下に120℃で、すべての水が分離されるまで沸騰させた。その後、反応混合物を冷却及びろ過し、揮発性成分を減圧下にロータリーエバポレータで、80℃で除去した。20℃で0.01Pa・sの粘度、及び、521.7mg KOH/gのアミン価を有する黄褐色の液体を得た。
Incorez製のN−ブチルエタノールアミン及び2−エチルヘキサナール系のモノオキサゾリジン。
最初に、50.00gの2,2−ジメチル−3−ラウロイルオキシプロパナールを丸底フラスコ中に窒素雰囲気下で仕込んだ。撹拌しながら、13.93gの3−アミノメチル−3,5,5−トリメチルシクロヘキシルアミンを添加し、次いで、揮発性成分を、80℃及び10mbarの減圧下で除去した。20℃で0.2Pa・sの粘度、及び、153.0mg KOH/gのアミン価を有する薄い黄色の無臭の液体を得た。
ポリマーP1:
400gのポリオキシプロピレンジオール(Acclaim(登録商標)4200、Covestro製;OH価28.5mg KOH/g)及び52gのジフェニルメタン4,4’−ジイソシアネート(Desmodur(登録商標)44 MC L、Covestro製の)を80℃で公知の方法によって反応させて、室温で液体であり、1.85重量%の遊離イソシアネート基の含有量を有するNCO−末端ポリウレタンポリマーを得た。
590gのポリオキシプロピレンジオール(Acclaim(登録商標)4200、Covestro製;OH価28.5mg KOH/g)、1180gのポリオキシプロピレン/ポリオキシエチレントリオール(Caradol(登録商標)MD34−02、Shell製;OH価35.0mg KOH/g)及び230gのイソホロンジイソシアネート(Vestanat(登録商標)IPDI、Evonik製)を80℃で公知の方法によって反応させて、室温で液体であり、2.10重量%の遊離イソシアネート基の含有量を有するNCO−末端ポリウレタンポリマーを得た。
356gのポリオキシプロピレンジオール(Acclaim(登録商標)4200、Covestro製;OH価28.5mg KOH/g)、100gのポリオキシプロピレントリオール(Acclaim(登録商標)6300、Covestro製;OH価28.0mg KOH/g)、並びに、80/20の比率でのトリレン2,4−及び2,6−ジイソシアネートの混合物40g(Desmodur(登録商標)T80、Covestro製)を、公知の方法により80℃で反応させて、室温で液体であり、及び、1.80重量%の遊離イソシアネート基含有量を有するNCO−末端ポリウレタンポリマーを得た。
300.0gのポリオキシプロピレン/ポリオキシエチレンジオール(Desmophen(登録商標)L300、Covestro製;OH価190.0mg KOH/g)及び228.8gのイソホロンジイソシアネート(Vestanat(登録商標)IPDI、Evonik製)を60℃で公知の方法によって反応させて、室温で液体であり、7.91重量%の遊離イソシアネート基の含有量を有するNCO−末端ポリウレタンポリマーを得た。
1300gのポリオキシプロピレンジオール(Covestro製のAcclaim(登録商標)4200N;OH価28.5mg KOH/g)、2600gのポリオキシプロピレントリオール(Shell製のCaradol(登録商標)MD34−02;OH価35.0mg KOH/g)、600gのジフェニルメタン4,4’−ジイソシアネート(Covestro製のDesmodur(登録商標)44MC L)及び500gのフタル酸ジイソデシル(Palatinol(登録商標)Z、BASF)を、80℃で反応させて、2.05重量%の遊離イソシアネート基含有量を有するNCO−末端ポリウレタンポリマーを得た。
組成物Z1〜Z27:
各組成物について、表1〜表2に明記される原料を、1分間3000rpmで水分を排除した遠心ミキサー(SpeedMixerTM DAC 150、FlackTek Inc.)を用いて(重量部単位で)明記される量で混合した。各組成物を次のとおり試験した。
各組成物について、表3に明記されている原料を、明記されている量(重量部)で、防湿しながら3000rpmで1分間、遠心ミキサー(SpeedMixer(商標)DAC 150、FlackTek Inc.)を用いて混合し、防湿して保管した。
各組成物について、表4に明記されている原料を、明記されている量(重量部)で、防湿しながら3000rpmで1分間、遠心ミキサー(SpeedMixer(商標)DAC 150,FlackTek Inc.)を用いて混合し、防湿して貯蔵した。
可塑剤の移行の尺度として、厚紙における斑点の形成を判定した。この目的のために、各組成物を、15mmの直径及び4mmの高さの丸いベース領域を有するように厚紙片に塗布し、7日間標準気候条件下で保管した。その後、厚紙上の各組成物の周囲に濃い卵形の染みが形成された。その寸法(高さ及び幅)を計測し、表4において移行として報告した。
組成物Z37〜Z40:
各組成物について、105.0重量部のポリマーP5、組成物Z28について記載した増粘剤60.0重量部、30.0重量部のフタル酸ジイソデシル、100.0重量部のチョーク、7.0重量部のシリカ(Evonik製のAerosil(登録商標)R972)、表5中に記載の重量部のオキサゾリジンA−13又はIncozol 2(Incorez製)、及び、2.0重量部のサリチル酸溶液(ジオクチルアジペート中に5重量%)及び1.0重量部のDBTDL溶液(フタル酸ジイソデシル中の5重量%のジブチル錫ジラウレート)を防湿しながら遠心ミキサーを用いて混合し、防湿して貯蔵した。
貯蔵安定性の尺度として、粘度(1日 室温)は生成の次の日に測定し、粘度(7日 室温)は室温で蓋をした容器中において7日間貯蔵した後に測定し、及び、粘度(7日 60℃)は、上記のとおり60℃の循環オーブン中における蓋をした容器において7日間貯蔵した後に測定した。
活性化剤−1:
2.5gのオキサゾリジンA−14を250gの乾燥酢酸エチル中に溶解し、防湿して貯蔵した。
1.5gのオキサゾリジンA−14を、窒素雰囲気下に、150gのポリマーP1と混合し、防湿して貯蔵した。
125.0gのSika(登録商標)Primer−209 N(イソシアネート基を含有する着色されたプライマー、Sika Schweiz AG製)を、21.2gのオキサゾリジンA−14と混合し、防湿して貯蔵した。
1(=きわめて良好)は、95%超の凝集破壊を表す
2(=良好)は75%〜95%の凝集破壊を表す
Claims (15)
- Aが、酸素又は窒素又はケイ素原子を有していてもよく、及び、15〜6,000g/molの範囲内の分子量を有していてもよい、n価の脂肪族、脂環式又はアリール脂肪族ヒドロカルビル残基であることを特徴とする、請求項1に記載の化合物。
- Rが分岐型残基であることを特徴とする、請求項3に記載の化合物。
- Rが、主に分岐の4−デシル、4−ウンデシル、4−ドデシル、4−トリデシル及び4−テトラデシル残基から選択される、請求項3に記載の化合物の混合物。
- イソシアネート基を含有する組成物のための潜在性硬化剤としての、請求項1〜10のいずれか一項に記載の化合物の少なくとも1種の使用。
- −請求項1〜10のいずれか一項に記載の化合物の少なくとも1種、並びに
−少なくとも1つのポリイソシアネート及び/又はイソシアネート基を含有する少なくとも1種のポリウレタンポリマー
を含む組成物。 - 接着剤又はシーラント又はコーティングであることを特徴とする、請求項14に記載の組成物。
- 用いられる前記式(IV)のアルデヒドが、4−デシルベンズアルデヒド、4−ウンデシルベンズアルデヒド、4−ドデシルベンズアルデヒド、4−トリデシルベンズアルデヒド及び4−テトラデシルベンズアルデヒドであって、そのアルキル残基が主に分岐型であるものを含む混合物である、ことを特徴とする、請求項14に記載の使用。
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CN115003720A (zh) * | 2020-02-03 | 2022-09-02 | Sika技术股份公司 | 对塑料有良好粘结性的聚氨酯组合物 |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6426571A (en) * | 1987-06-24 | 1989-01-27 | Smithkline Beckman Corp | Leukotriene antagonist |
JPH10226720A (ja) * | 1997-02-17 | 1998-08-25 | Yokohama Rubber Co Ltd:The | 一液湿気硬化型ポリウレタン樹脂組成物 |
JP2004107370A (ja) * | 2002-09-13 | 2004-04-08 | Yokohama Rubber Co Ltd:The | 一液湿気硬化型ポリウレタン樹脂組成物およびその製造方法 |
US20100152394A1 (en) * | 2008-12-12 | 2010-06-17 | Andrew Slark | Reactive hot melt adhesive |
WO2013179915A1 (ja) * | 2012-05-29 | 2013-12-05 | 三菱瓦斯化学株式会社 | 芳香族アルデヒド、並びに該芳香族アルデヒドを含有するエポキシ樹脂硬化剤及びエポキシ樹脂組成物 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4021659A1 (de) | 1990-07-07 | 1992-01-09 | Bayer Ag | Bisoxazolane, im wesentlichen aus diesen bestehende oxazolangemische, ein verfahren zu deren herstellung und ihre verwendung als haerter fuer isocyanatgruppen aufweisende kunststoffvorlaeufer |
US6103849A (en) * | 1994-06-27 | 2000-08-15 | Bayer Corporation | Storage stable, heat curable polyurethane compositions |
JP3705615B2 (ja) | 1994-07-26 | 2005-10-12 | 横浜ゴム株式会社 | ウレタンオキサゾリジン |
US6495653B1 (en) * | 1998-04-17 | 2002-12-17 | Sanyo Chemical Industries, Ltd. | Curable composition and cured article thereof |
IL129583A (en) * | 1999-04-25 | 2005-05-17 | Kenneth I Sawyer | Diesters of oligobutyleneglycol and amidine benzoic acid and their use for preparation of moisture-curable, storage-stable, one-part polyurethane/urea compositions |
JP2002194048A (ja) | 2000-12-26 | 2002-07-10 | Yokohama Rubber Co Ltd:The | 1液湿気硬化性ウレタン樹脂組成物 |
EP1384709A1 (de) | 2002-07-26 | 2004-01-28 | Sika Technology AG | Polyaldimine |
EP1384735A1 (de) * | 2002-07-26 | 2004-01-28 | Sika Technology AG | Polyaldimin enthaltende Polyurethanzusammensetzung |
AU2003235705A1 (en) * | 2002-01-18 | 2003-07-30 | Sika Technology Ag | Two-constituent polyurethane composition having high early strength |
EP2072550A1 (de) * | 2007-12-21 | 2009-06-24 | Sika Technology AG | Härtbare Zusammensetzungen mit verminderter Ausgasung |
EP2327733A1 (en) * | 2009-10-30 | 2011-06-01 | Sika Technology AG | Non-Crystallising Bis-Oxazolidines |
-
2018
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6426571A (en) * | 1987-06-24 | 1989-01-27 | Smithkline Beckman Corp | Leukotriene antagonist |
JPH10226720A (ja) * | 1997-02-17 | 1998-08-25 | Yokohama Rubber Co Ltd:The | 一液湿気硬化型ポリウレタン樹脂組成物 |
JP2004107370A (ja) * | 2002-09-13 | 2004-04-08 | Yokohama Rubber Co Ltd:The | 一液湿気硬化型ポリウレタン樹脂組成物およびその製造方法 |
US20100152394A1 (en) * | 2008-12-12 | 2010-06-17 | Andrew Slark | Reactive hot melt adhesive |
WO2013179915A1 (ja) * | 2012-05-29 | 2013-12-05 | 三菱瓦斯化学株式会社 | 芳香族アルデヒド、並びに該芳香族アルデヒドを含有するエポキシ樹脂硬化剤及びエポキシ樹脂組成物 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP7431236B2 (ja) | 2018-12-17 | 2024-02-14 | シーカ テクノロジー アクチェンゲゼルシャフト | オキサゾリジンを含有する湿気硬化性ポリウレタン組成物 |
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