JP2020026520A - ポリカルボジイミド組成物、ポリカルボジイミド組成物の製造方法、水分散組成物、溶液組成物、樹脂組成物および樹脂硬化物 - Google Patents
ポリカルボジイミド組成物、ポリカルボジイミド組成物の製造方法、水分散組成物、溶液組成物、樹脂組成物および樹脂硬化物 Download PDFInfo
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- JP2020026520A JP2020026520A JP2019138079A JP2019138079A JP2020026520A JP 2020026520 A JP2020026520 A JP 2020026520A JP 2019138079 A JP2019138079 A JP 2019138079A JP 2019138079 A JP2019138079 A JP 2019138079A JP 2020026520 A JP2020026520 A JP 2020026520A
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- polycarbodiimide composition
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- polyol
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Abstract
Description
などが挙げられる。
ポリカルボジイミド組成物の製造方法におけるカルボジイミド化反応の終了は、下記の装置および条件にてIRスペクトルを測定することにより、確認した。
測定法: ATR(反射法)
波数範囲: 4000〜400cm−1
分解能 4cm−1
<ポリカルボジイミド組成物のカルボジイミド当量(g/mol)>
ポリカルボジイミド組成物のカルボジイミド当量は、13C−NMRの測定結果より実測値を求めた。また、参考値として、仕込み量からのカルボジイミド当量の計算値を求めた。
装置; ECA−500型(日本電子製)
条件; 測定周波数:125MHz、溶媒:CDCL3、溶質濃度:50質量%
測定温度:室温、スキャン回数8500回
繰返し時間:3.0秒、パルス幅:30°(3.70μ秒)
カルボジイミド基(カルボジイミド基内のN=C=N基)の炭素の帰属ピーク
:139ppm
ウレトンイミン基(ウレトンイミン基内のC=O基、C=N基)の炭素の帰属ピーク
:159ppm、145ppm
アロファネート基(アロファネート基内のC=O基)の炭素の帰属ピーク
:154ppm
ウレタン基(ウレタン基内のC=O基)の炭素の帰属ピーク)
:156ppm
(カルボジイミド当量)={(仕込み固形分重量)―(ウレタン基に対する発生した二酸化炭素のモル比率)×(総アルコール仕込みモル数)×44.01}}/{(ウレタン基に対するカルボジイミド基のモル比率)×(総アルコール仕込みモル数)
なお、ウレタン基に対する発生した二酸化炭素のモル比率とウレタン基に対するカルボジイミド基のモル比率は以下のように算出する。
(ウレタン基に対するカルボジイミド基のモル比率)=(カルボジイミド基の積分値)/{(ウレタン基の積分値)+(アロファネート基の積分値)}
<面積率>
示差屈折率検出器(RID)を装備したゲルパーミエーションクロマトグラフ(GPC)によって、以下のGPC測定条件において得られたクロマトグラムにより、全ピーク面積に対するポリスチレン換算分子量500以下のピーク面積の割合と、全ピーク面積に対するポリスチレン換算分子量1000以下のピーク面積の割合とを、それぞれ求めた。
カラム;LF−804(Shodex社製商品名)3本を直列に連結
カラム温度;40℃
溶離液;テトラヒドロフラン
流量;1.0mL/min
検出方法;示差屈折率
標準物質;標準ポリスチレン
製造例1(ペンタンジイソシアネートの製造)
国際公開パンフレットWO2012/121291号の明細書における実施例1と同じ操作にて、99.9質量%の1,5−ペンタンジイソシアネート(以後PDIと略する場合がある。)を得た。
開始剤としてジプロピレングリコールモノメチルエーテル、触媒として水酸化カリウム(以下、KOH)をそれぞれ用いて、温度110℃、最大反応圧力0.4MPaゲージ(G)において、ポリオール中のエチレンオキシドとプロピレンオキサイドとの質量比が50:50となるように、水酸基価(以下、OHV)が102mgKOH/gまで、これらのアルキレンオキシド(エチレンオキシドおよびプロピレンオキサイド)をランダム付加重合させ、粗製ポリオールを調製した。
・ポリカルボジイミド組成物の製造
撹拌器、温度計、還流管、および窒素導入管を備えた四つ口フラスコに、室温下で、製造例1で得られたペンタメチレンジイソシアネート(PDI)を100.0質量部、PTG−250(ポリテトラメチレンエーテルグリコール、分子量250)を16.2質量部、モノオールA(製造例2で得られたポリオキシエチレン−ポリオキシプロピレンモノメチルエーテル(EO比率50質量%、分子量550))を71.4質量部、装入した。窒素を導入しながら、常圧下で80℃に加温し、4時間撹拌した(ウレタン化工程)。
ポリカルボジイミド組成物をフラスコに入れ、樹脂固形分が40%になるように蒸留水を徐々に加え、撹拌することで、ポリカルボジイミド組成物の水分散体を得た。
得られたポリカルボジイミド組成物の水分散体を硬化剤とした。主剤としてポリウレタンディスパージョン(固形分30質量%、固形分のカルボキシル基当量1122g/mol)を用い、硬化剤中のカルボジイミド基と主剤中のカルボキシル基の当量比が0.5となるように混合し、樹脂組成物を調製した。
PTG−250を21.2質量部、モノオールAを62.0質量部、PMAを740.8質量部使用した以外は実施例1と同じ方法でポリカルボジイミド組成物を得た。得られたポリカルボジイミド組成物の分析値を表1に記載する。
PTG−250を9.5質量部、モノオールAを83.9質量部、PMAを781.9質量部使用した以外は実施例1と同じ方法でポリカルボジイミド組成物を得た。得られたポリカルボジイミド組成物の分析値を表1に記載する。
PTG−250の代わりにPTG−650(ポリテトラメチレンエーテルグリコール、分子量650)を35.1質量部、モノオールAを59.5質量部、PMAを786.4質量部使用した以外は実施例1と同じ方法でポリカルボジイミド組成物を得た。得られたポリカルボジイミド組成物の分析値を表1に記載する。
PTG−250の代わりにPTG−850(ポリテトラメチレンエーテルグリコール、分子量850)を45.9質量部、モノオールAを59.5質量部、PMAを829.6質量部使用した以外は実施例1と同じ方法でポリカルボジイミド組成物を得た。得られたポリカルボジイミド組成物の分析値を表1に記載する。
PTG−250の代わりにPPG−280(ポリプロピレングリコール、分子量280)を18.2質量部、PMAを766.1質量部使用した以外は実施例1と同じ方法でポリカルボジイミド組成物を得た。得られたポリカルボジイミド組成物の分析値を表1に記載する。
モノオールA(製造例2で得られたポリオキシエチレン−ポリオキシプロピレンモノメチルエーテル(EO比率50質量%、分子量550))とイソブタノールとをモル比3:1の割合で混合した。この溶液を、モノオールBとした。
PTG−250の代わりに1,10−DD(1、10−デカンジオール)を11.3質量部、モノオールAを71.4質量部、PMAを738.6質量部使用した以外は実施例1と同じ方法でポリカルボジイミド組成物を得た。得られたポリカルボジイミド組成物の分析値を表1に記載する。
PTG−250の代わりに1,6−HD(1、6−ヘキサンジオール)を7.7質量部、PMAを724.1質量部使用した以外は実施例1と同じ方法でポリカルボジイミド組成物を得た。得られたポリカルボジイミド組成物の分析値を表1に記載する。
PTG−250の代わりにPTG−1500(ポリテトラメチレンエーテルグリコール、分子量1500)を69.5質量部、モノオールAを51.0質量部、PMAを889.9質量部使用した以外は実施例1と同じ方法でポリカルボジイミド組成物を得た。得られたポリカルボジイミド組成物の分析値を表1に記載する。
PTG−250の代わりにPCL 303(プラクセル 303、ポリカプロラクトントリオール、分子量300、ダイセル社製)を13.0質量部、PMAを745.3質量部使用した以外は実施例1と同じ方法でポリカルボジイミド組成物を得た。得られたポリカルボジイミド組成物の分析値を表1に記載する。
PDIの代わりにHDI(ヘキサメチレンジイソシアネート)を100.0質量部、PTG−250を14.9質量部、モノオールAを65.4質量部、PMAを729.1質量部使用した以外は実施例1と同じ方法でポリカルボジイミド組成物を得た。得られたポリカルボジイミド組成物の分析値を表1に記載する。
PMAを1724.1質量部、MPPOを4.0質量部使用した以外は実施例1と同じ方法でポリカルボジイミド組成物を得た。得られたポリカルボジイミド組成物の分析値を表1に記載する。
・ポリカルボジイミド組成物の製造
PTG−250を20.3質量部、モノオールAの代わりにイソブタノール(iBA)を12.0質量部、PMAを537.2質量部使用した以外は実施例1と同じ方法でポリカルボジイミド組成物を得た。得られたポリカルボジイミド組成物の分析値を表1に記載する。
ポリカルボジイミド組成物をフラスコに入れ、樹脂固形分が40%になるように酢酸ブチルを徐々に加え、撹拌することで、ポリカルボジイミド組成物の溶液を得た。
得られたポリカルボジイミド組成物の溶液を硬化剤とした。主剤としてアクリル樹脂(固形分50質量%、固形分のカルボキシル基当量2004g/mol)を用い、硬化剤中のカルボジイミド基と主剤中のカルボキシル基の当量比が0.5となるように混合し、樹脂組成物を調製した。
PTG−250を0.0質量部、モノオールAを101.9質量部、PMAを815.7質量部使用した以外は実施例1と同じ方法でポリカルボジイミド組成物を得た。得られたポリカルボジイミド組成物の分析値を表1に記載する。
PTG−250を24.9質量部、モノオールAを54.9質量部、PMAを727.35質量部使用した以外は実施例1と同じ方法でポリカルボジイミド組成物を得た。得られたポリカルボジイミド組成物の分析値を表1に記載する。
PTG−250を27.0質量部、モノオールAを118.9質量部、PMAを991.8質量部使用した以外は実施例1と同じ方法でポリカルボジイミド組成物を得た。得られたポリカルボジイミド組成物の分析値を表1に記載する。
PTG−250を8.1質量部、ユニオックスM550(ポリオキシエチレンモノメチルエーテル、分子量550、日本油脂社製)を35.7質量部、PMAを583.1質量部使用した以外は実施例1と同じ方法でポリカルボジイミド組成物を得た。得られたポリカルボジイミド組成物の分析値を表1に記載する。
・ポリカルボジイミド組成物の製造
撹拌器、温度計、還流管、および窒素導入管を備えた四つ口フラスコに、室温下で、4,4−ジシクロヘキシルメタンジイソシアネート(H12MDI)を200.0質量部、3−メチル−1−フェニル−2−フォスフォレン−1−オキシド(MPPO)を2.0質量部、封入した。窒素を導入しながら、170℃で7時間反応させ、1分子にカルボジイミド基を3個有し、両末端にイソシアネート基を有するカルボジイミドを得た(カルボジイミド化工程)。
得られたH12MDI由来のポリカルボジイミド組成物をフラスコに入れ、80℃に加温しながら、樹脂固形分が40%になるように蒸留水を徐々に加えた。5分間撹拌した後に冷却することで、ポリカルボジイミド組成物の水分散体を得た。
得られたポリカルボジイミド組成物の水分散体を硬化剤とした。主剤としてカルボキシル基を有する親水性ポリウレタン(ポリウレタンディスパージョン、固形分30質量%、固形分のカルボキシル基当量1122g/mol)を用い、硬化剤中のカルボジイミド基と主剤中のカルボキシル基の当量比が0.5となるように混合し、樹脂組成物を調製した。
特開2018−104605の合成例5に記載の方法に従って、ポリカルボジイミド組成物を合成し、また、各実施例と同様にして、ポリカルボジイミド組成物の水分散体を調製した。
得られたH12MDI由来のポリカルボジイミド組成物をフラスコに入れ、80℃に加温しながら、樹脂固形分が40%になるように蒸留水を徐々に加えた。5分間撹拌した後に冷却することで、ポリカルボジイミド組成物の水分散体を得た。
得られたポリカルボジイミド組成物の水分散体を硬化剤とした。主剤としてカルボキシル基を有する親水性ポリウレタン(ポリウレタンディスパージョン、固形分30質量%、固形分のカルボキシル基当量1122g/mol)を用い、硬化剤中のカルボジイミド基と主剤中のカルボキシル基の当量比が0.5となるように混合し、樹脂組成物を調製した。
<安定性試験>
・熱安定性試験
得られたポリカルボジイミド組成物1.0gを10mLのスクリュー瓶に入れて、窒素ブローをした後に、スクリューキャップで蓋をし、40℃にて保管し、流動性を観測した。評価の基準を下記する。
3:2週間未満で流動性は消失しなかった。
2:1週間以上2週間未満で消失した。
1:1週間未満で流動性は消失した。
250ミルのドクターブレードを用いて、樹脂組成物を標準試験板(JIS−G−3303 SPTE)に塗布した後、80℃で5分間および10分間乾燥させ、さらに室温で1時間乾燥させ、樹脂硬化物からなる塗膜を得た。得られた塗膜を下記の方法で評価した。なお、比較例2は水分散体が得られなかったので、評価しなかった。
塗膜(80℃5分乾燥塗膜)の外観を目視で評価した。評価の基準を下記する。
5:皺はほとんど見られなかった。
4:一部に皺が見られた。
3:多数の皺が見られた。
2:皺や割れが見られた。
1:皺や割れが多く、後述の耐溶剤性の評価が出来なかった。
塗膜(80℃5分乾燥塗膜、および、80℃10分乾燥塗膜)に、水系の樹脂組成物の場合には、メチルエチルケトン、溶剤系の樹脂組成物の場合には50%エタノール水溶液を浸透させたガーゼを、50gの荷重で押し当てながら擦り、塗膜が割れるまでの回数を測定した。評価の基準を下記する。
5:350回以上で塗膜が割れた
4:300回以上350回未満で塗膜が割れた。
3:250回以上300回未満で塗膜が割れた。
2:100回以上250回未満で塗膜が割れた。
1:100回未満で塗膜が割れた。
Claims (10)
- 直鎖脂肪族ジイソシアネートとアルコール類との反応生成物のカルボジイミド変性体を含むポリカルボジイミド組成物であって、
前記アルコール類は、ポリオールおよびモノオールを含み、
前記アルコール類において、前記モノオール由来の水酸基数に対する前記ポリオール由来の水酸基数のモル比(ポリオール由来の水酸基/モノオール由来の水酸基)が2.0未満であり、
前記ポリカルボジイミド組成物のカルボジイミド当量が、300g/mol以上550g/mol未満である
ことを特徴とする、ポリカルボジイミド組成物。 - 前記ポリオールの分子量が、120以上1000以下である
ことを特徴とする、請求項1に記載のポリカルボジイミド組成物。 - 前記ポリオールの平均官能基数が、2である
ことを特徴とする、請求項1または2に記載のポリカルボジイミド組成物。 - 前記直鎖脂肪族ジイソシアネートが、1,5−ペンタンジイソシアネートである
ことを特徴とする、請求項1〜3のいずれか一項に記載のポリカルボジイミド組成物。 - 前記ポリカルボジイミド組成物をゲルパーミエーションクロマトグラフ測定したときのクロマトグラムにおいて、
ポリスチレン換算分子量500以下のピーク面積の、全ピーク面積に対する面積率が、6.5%以下であり、
ポリスチレン換算分子量1000以下のピーク面積の、全ピーク面積に対する面積率が、10.0%以下である
ことを特徴とする、請求項1〜4のいずれか一項に記載のポリカルボジイミド組成物。 - 直鎖脂肪族ジイソシアネートとアルコール類とをウレタン化反応させるウレタン化工程と、
前記ウレタン化工程における反応生成物を、カルボジイミド化触媒の存在下において加熱し、カルボジイミド化反応させるカルボジイミド化工程と
を備え、
前記アルコール類は、ポリオールおよびモノオールを含み、
前記アルコール類において、前記モノオール由来の水酸基数に対する前記ポリオール由来の水酸基数のモル比(ポリオール由来の水酸基/モノオール由来の水酸基)が2.0未満であり、
前記ウレタン化工程において、前記モノオールの水酸基、および、前記ポリオールの水酸基の総量に対する、前記直鎖脂肪族ジイソシアネートのイソシアネート基の当量比(NCO/OH)が、3以上8未満である
ことを特徴とする、ポリカルボジイミド組成物の製造方法。 - 請求項1〜5のいずれか一項に記載のポリカルボジイミド組成物が、
固形分濃度5質量%以上90質量%以下の割合で水に分散された水分散液である
ことを特徴とする、水分散組成物。 - 請求項1〜5のいずれか一項に記載のポリカルボジイミド組成物が、
固形分濃度5質量%以上90質量%以下の割合で有機溶媒に溶解された溶液である
ことを特徴とする、溶液組成物。 - カルボキシル基を有する主剤と、
請求項1〜5のいずれか一項に記載のポリカルボジイミド組成物を含む硬化剤と
を含有することを特徴とする、樹脂組成物。 - 請求項9に記載の樹脂組成物の硬化物であることを特徴とする、樹脂硬化物。
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