JP2019520194A - Fcc触媒不活性化のための新規な環式金属不活性化ユニットの設計 - Google Patents
Fcc触媒不活性化のための新規な環式金属不活性化ユニットの設計 Download PDFInfo
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- 239000002184 metal Substances 0.000 title claims abstract description 44
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 44
- 125000004122 cyclic group Chemical group 0.000 title claims abstract description 43
- 230000009849 deactivation Effects 0.000 title claims abstract description 35
- 238000013461 design Methods 0.000 title description 5
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- 238000009826 distribution Methods 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 32
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- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 238000012423 maintenance Methods 0.000 claims 2
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- 238000004231 fluid catalytic cracking Methods 0.000 description 13
- 238000005243 fluidization Methods 0.000 description 13
- 238000007789 sealing Methods 0.000 description 8
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- 230000000694 effects Effects 0.000 description 6
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- 238000012986 modification Methods 0.000 description 4
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- 230000008901 benefit Effects 0.000 description 3
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- 238000006243 chemical reaction Methods 0.000 description 3
- 239000000571 coke Substances 0.000 description 3
- 230000008646 thermal stress Effects 0.000 description 3
- 238000009825 accumulation Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
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- 150000001450 anions Chemical group 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical group 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
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- 239000010779 crude oil Substances 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
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- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/06—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with moving sorbents or sorbents dispersed in the oil
- C10G25/09—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with moving sorbents or sorbents dispersed in the oil according to the "fluidised bed" technique
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- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
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- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
- C10G11/182—Regeneration
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- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/12—Recovery of used adsorbent
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- B01J2208/00893—Feeding means for the reactants
- B01J2208/0092—Perforated plates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10G2300/706—Catalytic metal recovery
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Abstract
Description
本出願は、2016年4月29日に出願された米国仮特許出願第62/329,374号に対する優先権の利益を主張し、あらゆる目的のためにその全体が参照により本明細書に組み込まれる。
本発明の一実施形態は、平衡触媒材料の製造のための環式金属不活性化システムユニットに関する。環式金属不活性化システムユニットは、触媒材料を分解及びストリッピングするように構成されたクラッカ容器と、クラッカ容器と流体連通している再生器容器とを含み、再生器容器は触媒材料の再生及び蒸気不活性化のために構成される。
Claims (20)
- 平衡触媒材料を製造するための環式金属不活性化システムユニットであって、
触媒材料を分解及びストリッピングするように構成されたクラッカ容器と、
前記クラッカ容器と流体連通している再生器容器であって、前記触媒材料の再生及び蒸気不活性化のために構成された再生器容器と、を備える、環式金属不活性化システムユニット。 - 前記クラッカ容器及び前記再生器容器が、前記クラッカ容器内の第1の浸漬管及び前記再生器容器内の第2の浸漬管を含む空気圧弁システムを介して互いに流体連通している、請求項1に記載の環式金属不活性化システム。
- 前記クラッカ容器が、前記クラッカ容器の下部領域内に配置された第1の多孔板を含む、請求項1に記載の環式金属不活性化システム。
- 前記第1の多孔板が、前記クラッカ容器の内側底面を含む第1のガス分配領域を画定し、第1のガス入口が、前記第1のガス分配領域内に配置されており、前記第1のガス入口が、前記クラッカ容器に第1のガス源を導入するように構成されている、請求項3に記載の環式金属不活性化システム。
- 前記再生器容器が、前記再生器容器の下部領域内に配置された第2の多孔板を含む、請求項1に記載の環式金属不活性化システム。
- 前記第2の多孔板が、前記再生器容器の内側底面を含む第2のガス分配領域を画定し、第2のガス入口が、前記第2のガス分配領域内に配置されたており、前記第2のガス入口が、前記再生器容器に第2のガス源を導入するように構成されている、請求項5に記載の環式金属不活性化システム。
- 前記第1のガス入口が、前記クラッカ容器の前記第1のガス分配領域内の第1のガスパイプに流体接続されており、前記第1のガスパイプが、前記クラッカ容器の前記第1のガス分配領域内の流入ガスを予熱するためのコイル構造を備える、請求項4に記載の環式金属不活性化システム。
- 前記第2のガス入口が、前記再生器容器の前記第2のガス再分配領域内の第2のガスパイプに流体接続され、前記第2のガスパイプが、前記再生器容器の前記第2のガス再分配領域内の流入ガスを予熱するためのコイル構造を備える、請求項6に記載の環式金属不活性化システム。
- 前記再生器容器と流体連通している経時分配容器をさらに備え、前記経時分配容器が、前記触媒材料の経時変化に基づいて前記触媒材料を分配するために構成されている、請求項1に記載の環式金属不活性化システム。
- 前記クラッカ、再生器、及び経時分配容器が、空気圧弁システムを介して互いに流体連通している、請求項7に記載の環式金属不活性化システム。
- 前記空気圧弁システムが、前記クラッカ容器内の第1の浸漬管、前記再生器容器内の第2の浸漬管、及び前記経時分配容器内の第3の浸漬管を含む、請求項10に記載の環式金属不活性化システム。
- 前記クラッカ容器、再生器容器、及び経時分配容器の各々が、温度維持装置を備え、前記温度維持装置が、各それぞれの容器内に所定のプロセス温度を維持する、請求項9に記載の環式金属不活性化システム。
- 触媒不活性化方法であって、
触媒をクラッカ容器によって分解することと、
前記触媒を再生器容器によって再生することと、
前記触媒の経時変化に少なくとも部分的に基づき前記触媒を経時分配容器によって分配することと、
前記クラッカ容器と、再生器容器と、経時分配容器との間で、前記触媒を1つ以上の浸漬管によって輸送して、前記触媒を不活性化させることと、を含む、方法。 - 前記クラッカ容器及び前記再生器容器が、前記クラッカ容器内の第1の浸漬管及び前記再生器容器内の第2の浸漬管を含む空気圧弁システムを介して互いに流体連通している、請求項13に記載の方法。
- 前記クラッカ容器が、前記クラッカ容器の下部領域内に配置された第1の多孔板を含む、請求項13に記載の方法。
- 前記第1の多孔板が、前記クラッカ容器の内側底面を含む第1のガス分配領域を画定し、第1のガス入口が、前記第1のガス分配領域内に配置されており、前記第1のガス入口が前記クラッカ容器に第1のガス源を導入するように構成されている、請求項15に記載の方法。
- 前記再生器容器が、前記再生器容器の下部領域内に配置された第2の多孔板を備える、請求項13に記載の方法。
- 前記第2の多孔板が、前記再生器容器の内側底面を含む第2のガス分配領域を画定し、第2のガス入口が、前記第2のガス分配領域内に配置されており、前記第2のガス入口が、前記再生器容器に第2のガス源を導入するように構成されている、請求項17に記載の方法。
- 前記第1のガス入口が、前記クラッカ容器の前記第1のガス分配領域内の第1のガスパイプに流体接続されており、前記第1のガスパイプが、前記クラッカ容器の前記第1のガス分配領域内の流入ガスを予熱するためのコイル構造を備える、請求項16に記載の方法。
- 前記第2のガス入口が、前記再生器容器の前記第2のガス再分配領域内の第2のガスパイプに流体接続され、前記第2のガスパイプが、前記再生器容器の前記第2のガス再分配領域内の流入ガスを予熱するためのコイル構造を備える、請求項18に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201662329374P | 2016-04-29 | 2016-04-29 | |
US62/329,374 | 2016-04-29 | ||
PCT/US2017/029825 WO2017189839A1 (en) | 2016-04-29 | 2017-04-27 | New cyclic metal deactivation unit design for fcc catalyst deactivation |
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JP2019520194A true JP2019520194A (ja) | 2019-07-18 |
JP6921119B2 JP6921119B2 (ja) | 2021-08-18 |
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US (3) | US10828614B2 (ja) |
EP (1) | EP3448960B1 (ja) |
JP (1) | JP6921119B2 (ja) |
KR (1) | KR20180132931A (ja) |
CN (1) | CN109153922A (ja) |
BR (1) | BR112018072147A2 (ja) |
ES (1) | ES2939602T3 (ja) |
PL (1) | PL3448960T3 (ja) |
RU (1) | RU2018141870A (ja) |
WO (1) | WO2017189839A1 (ja) |
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- 2017-04-27 CN CN201780026173.2A patent/CN109153922A/zh active Pending
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- 2017-04-27 RU RU2018141870A patent/RU2018141870A/ru not_active Application Discontinuation
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Publication number | Publication date |
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PL3448960T3 (pl) | 2023-03-27 |
EP3448960A1 (en) | 2019-03-06 |
ES2939602T3 (es) | 2023-04-25 |
EP3448960B1 (en) | 2023-02-08 |
US11691116B2 (en) | 2023-07-04 |
CN109153922A (zh) | 2019-01-04 |
US20190134589A1 (en) | 2019-05-09 |
BR112018072147A2 (pt) | 2019-02-12 |
US20220355261A1 (en) | 2022-11-10 |
WO2017189839A1 (en) | 2017-11-02 |
US11446624B2 (en) | 2022-09-20 |
KR20180132931A (ko) | 2018-12-12 |
US20200384432A1 (en) | 2020-12-10 |
RU2018141870A3 (ja) | 2020-05-29 |
RU2018141870A (ru) | 2020-05-29 |
US10828614B2 (en) | 2020-11-10 |
EP3448960A4 (en) | 2020-01-22 |
JP6921119B2 (ja) | 2021-08-18 |
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