JP2019502649A - ポリエーテルアミン及びアルキレンアミンの同時製造 - Google Patents
ポリエーテルアミン及びアルキレンアミンの同時製造 Download PDFInfo
- Publication number
- JP2019502649A JP2019502649A JP2017561250A JP2017561250A JP2019502649A JP 2019502649 A JP2019502649 A JP 2019502649A JP 2017561250 A JP2017561250 A JP 2017561250A JP 2017561250 A JP2017561250 A JP 2017561250A JP 2019502649 A JP2019502649 A JP 2019502649A
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- JP
- Japan
- Prior art keywords
- mixture
- polyol
- initiator
- polyetheramine
- alkyleneamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 78
- 229920005862 polyol Polymers 0.000 claims abstract description 47
- 150000003077 polyols Chemical class 0.000 claims abstract description 47
- 239000003999 initiator Substances 0.000 claims abstract description 37
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 36
- 238000002844 melting Methods 0.000 claims abstract description 33
- 230000008018 melting Effects 0.000 claims abstract description 33
- 238000000034 method Methods 0.000 claims abstract description 31
- 239000003822 epoxy resin Substances 0.000 claims abstract description 29
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 29
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 230000008569 process Effects 0.000 claims abstract description 14
- 238000009472 formulation Methods 0.000 claims abstract description 13
- 229920002396 Polyurea Polymers 0.000 claims abstract description 8
- 239000007787 solid Substances 0.000 claims abstract description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 26
- 239000003054 catalyst Substances 0.000 claims description 25
- 238000006268 reductive amination reaction Methods 0.000 claims description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 17
- 229920001228 polyisocyanate Polymers 0.000 claims description 16
- 239000005056 polyisocyanate Substances 0.000 claims description 16
- 229910021529 ammonia Inorganic materials 0.000 claims description 13
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 11
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 10
- 125000002947 alkylene group Chemical group 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 7
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 4
- 229920002261 Corn starch Polymers 0.000 claims description 4
- 239000008120 corn starch Substances 0.000 claims description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 4
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 3
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 claims description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 3
- 229930006000 Sucrose Natural products 0.000 claims description 3
- 239000005720 sucrose Substances 0.000 claims description 3
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-FBXFSONDSA-N Allitol Chemical compound OC[C@H](O)[C@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-FBXFSONDSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 2
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 claims description 2
- JVWLUVNSQYXYBE-UHFFFAOYSA-N Ribitol Natural products OCC(C)C(O)C(O)CO JVWLUVNSQYXYBE-UHFFFAOYSA-N 0.000 claims description 2
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-GUCUJZIJSA-N galactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-GUCUJZIJSA-N 0.000 claims description 2
- 239000008101 lactose Substances 0.000 claims description 2
- 229960001855 mannitol Drugs 0.000 claims description 2
- HOVAGTYPODGVJG-ZFYZTMLRSA-N methyl alpha-D-glucopyranoside Chemical compound CO[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HOVAGTYPODGVJG-ZFYZTMLRSA-N 0.000 claims description 2
- 229920000909 polytetrahydrofuran Polymers 0.000 claims description 2
- HEBKCHPVOIAQTA-ZXFHETKHSA-N ribitol Chemical compound OC[C@H](O)[C@H](O)[C@H](O)CO HEBKCHPVOIAQTA-ZXFHETKHSA-N 0.000 claims description 2
- 239000000811 xylitol Substances 0.000 claims description 2
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims description 2
- 235000010447 xylitol Nutrition 0.000 claims description 2
- 229960002675 xylitol Drugs 0.000 claims description 2
- 230000000977 initiatory effect Effects 0.000 claims 1
- -1 alkylene amine Chemical class 0.000 abstract description 32
- 150000001412 amines Chemical class 0.000 abstract description 9
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 230000015572 biosynthetic process Effects 0.000 abstract description 4
- 238000003786 synthesis reaction Methods 0.000 abstract description 4
- 238000005576 amination reaction Methods 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 14
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 13
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 12
- 150000002118 epoxides Chemical group 0.000 description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 239000004593 Epoxy Substances 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 239000012948 isocyanate Substances 0.000 description 9
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 229910052759 nickel Inorganic materials 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 229920006389 polyphenyl polymer Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 5
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical class ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 125000002993 cycloalkylene group Chemical group 0.000 description 5
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 125000005442 diisocyanate group Chemical group 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 4
- 150000002513 isocyanates Chemical class 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 125000002015 acyclic group Chemical group 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 150000002357 guanidines Chemical class 0.000 description 3
- 125000000623 heterocyclic group Chemical group 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
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- 239000000600 sorbitol Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 2
- OECTYKWYRCHAKR-UHFFFAOYSA-N 4-vinylcyclohexene dioxide Chemical compound C1OC1C1CC2OC2CC1 OECTYKWYRCHAKR-UHFFFAOYSA-N 0.000 description 2
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
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- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000001588 bifunctional effect Effects 0.000 description 2
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- 235000013877 carbamide Nutrition 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 229930003836 cresol Natural products 0.000 description 2
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 2
- 238000007590 electrostatic spraying Methods 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
- WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 description 2
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- 239000012535 impurity Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 239000012263 liquid product Substances 0.000 description 2
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
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- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
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- 239000002243 precursor Substances 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
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- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
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- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- VBDLPHLSTPGTKW-UHFFFAOYSA-N (3-methyl-7-oxabicyclo[4.1.0]heptan-4-yl)methyl 8-(3-octyloxiran-2-yl)octanoate Chemical compound CCCCCCCCC1OC1CCCCCCCC(=O)OCC1C(C)CC2OC2C1 VBDLPHLSTPGTKW-UHFFFAOYSA-N 0.000 description 1
- KYVBNYUBXIEUFW-UHFFFAOYSA-N 1,1,3,3-tetramethylguanidine Chemical compound CN(C)C(=N)N(C)C KYVBNYUBXIEUFW-UHFFFAOYSA-N 0.000 description 1
- LINDOXZENKYESA-UHFFFAOYSA-N 1,2-dimethylguanidine Chemical compound CNC(N)=NC LINDOXZENKYESA-UHFFFAOYSA-N 0.000 description 1
- VYMPLPIFKRHAAC-UHFFFAOYSA-N 1,2-ethanedithiol Chemical compound SCCS VYMPLPIFKRHAAC-UHFFFAOYSA-N 0.000 description 1
- DEWLEGDTCGBNGU-UHFFFAOYSA-N 1,3-dichloropropan-2-ol Chemical compound ClCC(O)CCl DEWLEGDTCGBNGU-UHFFFAOYSA-N 0.000 description 1
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- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
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- 230000003068 static effect Effects 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
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- 239000011135 tin Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 150000004992 toluidines Chemical class 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
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- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
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Abstract
Description
本出願は、2016年1月12日に出願された米国仮出願第62/277,522号(その内容全体は引用することにより本明細書にここに明白に組み込まれる)の35 U.S.C.119(e)の下での利益を主張する。
該当なし。
本開示は、アルコキシル化アルコール及び高融点ポリオールをアミノ化することによるポリエーテルアミン及びアルキレンアミン混合物の製造方法を提供する。該アミン混合物は、エポキシ樹脂の硬化若しくはポリ尿素の合成におけるような多様な応用で使用しうる。
アルコキシル化アルコールのアミノ化は従来技術で長く認識されている方法である。それは一般に、水素化触媒の存在下及び通常は水素の存在下のアンモニアとのアルコキシル化アルコールの反応に関する。その後製造されるポリエーテルアミンは、例えば、エポキシ樹脂の硬化剤として若しくはポリアミド及びポリ尿素の合成における原料として多くの用途を見出す。
本出願は、ポリエーテルアミン及びアルキレンアミン混合物の新規な同時製造(co−preparing)方法を記述する。該方法は、アルコキシル化アルコールを、還元的アミノ化段階における高融点ポリオールの溶媒として及び高融点ポリオールとの共反応体として利用する。ポリエーテルアミン及びアルキレンアミン混合物は、エポキシ樹脂製剤を形成するためエポキシ樹脂と組合せうるか、若しくはポリ尿素を形成するため有機ポリイソシアネートと反応させうる。
本明細書に出現する場合、「含んでなる(こと)(comprising)」という用語及びその派生語は、それが本明細書に開示されようとされなかろうと、いずれかの追加の成分、段階若しくは手順の存在を排除することを意図していない。いかなる疑いも回避するため、「含んでなる(こと)(comprising)」という用語の使用により本明細書で特許請求される全部の組成物は、逆に述べられない限りいかなる付加的な添加物、補助物質若しくは化合物も包含しうる。対象的に、「より本質的になる(こと)(consisting essentially of)」という用語は、本明細書に出現する場合、実施可能性のために不可欠でないものを除き、いかなる他の成分、段階若しくは手順もいかなる後続する引用の範囲からも除外し、また、「よりなる(こと)(consisting of)」という用語は、使用される場合、具体的に言葉で描写若しくは列挙されないいかなる成分、段階若しくは手順も除外する。「若しくは(又は、或いは)(or)」という用語は、別の方法で述べられない限り、列挙されるメンバーを個別に並びにいずれかの組合せで指す。
媒を実質的に含まずに実施しうる。
式中、各AOは同一若しくは異なることができ、かつ、それぞれ、独立に若しくは相互にエチレンオキシ、プロピレンオキシ若しくはブチレンオキシであることができ、y及びzはそれぞれ独立に0から6までの数字例えば0、1、2、3、4、5若しくは6であることができ、式中y及びzの少なくとも一方が1若しくはより大きく、y+zは1と12の間の数字例えば1、2、3、4、5、6、7、8、9、10、11、12であることができ、並びにXは直鎖若しくは分枝状C2−C18アルキレン、例えばC2−C12アルキレン及び具体的にはC2−C6アルキレン、若しくはC3−C12シクロアルキレン例えばC4−C8シクロアルキレン及び具体的にはC5−C8シクロアルキレン、若しくはC2−C4アルキレン−C3−C12シクロアルキレン例えばC2−C4アルキレン−C5−C6シクロアルキレン、若しくはC2−C4アルキレン−C3−C12シクロアルキレン−C2−C4アルキレン、例えばC2−C4アルキレン−C5−C6シクロアルキレン−C2−C4アルキレンでありうる。
αd−グルコシド;コーンスターチ;ショ糖;乳糖;d−マンニトール;無水ソルビトール;ズルシトール:エリスリトール;トレイトール;アラビニトール:キシリトール;リビトール;アリトール;アルトリトール;グリトール;ガラクチトール;タリトール;マルチトール、イソマルチトール;ラクチトール;トリメチロールプロパン;トリメチロールエタン;イノシトール;グルコース;フルクトース;及びそれらの混合物でありうる。特定の一態様において、高融点ポリオールは、大気圧下で最低約80℃、他の態様において最低約90℃、一方なお他の態様において最低約100℃の融点を有する化合物である。
レンアミン混合物を提供するために分画しうる。
要素として使用し得る。該製剤は、例えば混合することにより構成要素を接触させることにより使用の前若しくは中に製造し得、また、それは、例えば刷毛塗り、吹付、浸漬 塗布、押出、印刷、静電吹付などにより、いかなる種類の表面(1若しくは複数)にもまた塗布し得、そしてそれからその後硬化して硬化素材を形成することができる。
ビスフェノールS)、アルコキシル化ビスフェノールA、F若しくはS、トリオール延長化(triol extended)ビスフェノールA、F若しくはS、及び臭素化ビスフェノールA、F若しくはS、水素化ビスフェノールA、F若しくはS、フェノールのグリシジルエーテル、並びにペンダント基若しくは鎖をもつフェノール、フェノールノボラック及びクレゾールノボラックのようなホルムアルデヒドとのフェノール若しくはクレゾールの酸性条件下で得られる縮合生成物、又はシロキサンジグリシジルに基づくものを包含する。
ン水素原子を含有するアミンとのエピクロロヒドリンの反応生成物の脱塩化水素化(dehydrochlorination)により得ることが可能である。これらのアミンは、例えばn−ブチルアミン、アニリン、トルイジン、m−キシレンジアミン、ビス(4−アミノフェニル)メタン若しくはビス(4−メチルアミノフェニル)メタンでありうる。ポリ(N−グリシジル)化合物の他の例は、エチレン尿素若しくは1,3−プロピレン尿素のようなシクロアルキレン尿素のN,N’−ジグリシジル誘導体、及び5,5−ジメチルヒダントインのようなヒダントインのN,N’−ジグリシジル誘導体を包含する。ポリ(S−グリシジル)化合物の例は、ジチオール例えばエタン−1,2−ジチオール若しくはビス(4−メルカプトメチルフェニル)エーテル由来のジ−S−グリシジル誘導体である。
pre−reacted adducts)、の使用もまた考えられる。
℃で硬化される。当業者は、本開示の利益を伴い、より低い温度及び/若しくはより短い硬化時間を使用して所望の硬化特性に達する方法を認識するであろう。
International,LLCから全部入手可能であるRUBINATE(登録商標)9480、RUBINATE(登録商標)9484及びRUBINATE(登録商標)9495ブランド製品として商業的に入手可能なもののようなMDIに基づく準プレポリマー(quasi prepolymer)を包含する。Bayer Material Scienceから入手可能なMONDUR(登録商標)MLイソシアネートのような液化MDIもまた、イソシアネートの全部若しくは一部として使用しうる。
ネート混合物がこれらに典型的であり、そのうちそれらの約20ないし約95重量パーセントが4,4’−異性体であり、残部は、約2.1から約3.5個までの平均官能性を有する、より高分子量及び官能性のポリメチレンポリフェニルポリイソシアネートである。これらイソシアネート混合物は既知の商業的に入手可能な物質であり、そして米国特許第3,362,979号明細書に記述される方法により製造し得る。好ましい一芳香族ポリイソシアネートはメチレンビス(4−フェニルイソシアネート)すなわち「MDI」である。純粋なMDI、MDIの準プレポリマー、修飾された純粋なMDIなどが本発明のポリ尿素を製造するのに有用である。純粋なMDIは固体であり、そして従って使用するためにしばしば不便であるため、MDIすなわちメチレンビス(4−フェニルイソシアネート)に基づく液体生成物を本明細書で使用する。引用することにより本明細書に組み込まれる米国特許第3,394,164号明細書は液体MI生成物を記述する。より一般的には、ウレトンイミン修飾された純粋なMDIもまた包含される。この生成物は純粋な蒸溜されたMDIを触媒の存在下に加熱することにより作成する。該液体生成物は純粋なMDI及び修飾MDIの混合物である。有機ポリイソシアネートという用語は、活性水素含有物質を有するイソシアネート若しくはポリイソシアネートの準プレポリマーもまた包含する。
Claims (10)
- (a)アルコキシル化アルコール開始剤、及び分子あたり2から8個までのヒドロキシル基を有する固体高融点ポリオールを混合及び加熱して液体ポリオール開始剤混合物を形成すること;並びに(b)該液体ポリオール開始剤混合物を還元的アミノ化区画に充填し、そして還元的アミノ化触媒及びアンモニアの存在下に該液体ポリオール開始剤混合物を還元的にアミノ化して、ポリエーテルアミン及びアルキレンアミン混合物を形成することを含んでなる、ポリエーテルアミン及びアルキレンアミン混合物の同時製造方法。
- アルコキシル化アルコール開始剤が、アルコール及びアルキレンオキシドの付加から形成されるポリオキシアルキレンポリオールである、請求項1に記載の方法。
- アルコールが、エチレングリコール、プロピレングリコール、トリプロピレングリコール、ネオペンチルグリコール、ポリテトラメチレンエーテルグリコール、1,3−ブタンジオール、1,4−ブタンジオール若しくは1,4−シクロヘキサンジメタノールである、請求項2に記載の方法。
- 高融点ポリオールが、ネオペンチルグリコール;ペンタエリスリトール;ジペンタエリスリトール;トリペンタエリスリトール;コーンスターチのメチルαd−グルコシド;コーンスターチ;ショ糖;乳糖;d−マンニトール;無水ソルビトール;ズルシトール;エリスリトール;トレイトール;アラビニトール;キシリトール;リビトール;アリトール;アルトリトール;グリトール;ガラクチトール;タリトール;マルチトール、イソマルチトール;ラクチトール;トリメチロールプロパン;トリメチロールエタン;イノシトール;グルコース;フルクトース;及びそれらの混合物である、請求項1に記載の方法。
- アルコキシル化アルコール開始剤:高融点ポリオールの重量比が51:49に等しいか若しくはそれより大きい、請求項1に記載の方法。
- 高融点ポリオール:アルコキシル化アルコール開始剤の重量比が51:49に等しいか若しくはそれより大きい、請求項1に記載の方法。
- 液体ポリオール開始剤混合物が水及び溶媒を実質的に含まない、請求項1に記載の方法。
- (a)アルコキシル化アルコール開始剤及び分子あたり2から8個までのヒドロキシル基を有する固体高融点ポリオールを混合及び加熱して液体ポリオール開始剤混合物を形成すること;並びに(b)該液体ポリオール開始剤混合物を還元的アミノ化区画に充填し、そして還元的アミノ化触媒及びアンモニアの存在下に該液体ポリオール開始剤混合物を還元的にアミノ化してポリエーテルアミン及びアルキレンアミン混合物を形成することにより得られる、ポリエーテルアミン及びアルキレンアミン混合物。
- エポキシ樹脂並びに請求項8に記載のポリエーテルアミン及びアルキレンアミン混合物を含んでなるエポキシ樹脂製剤。
- 請求項8に記載のポリエーテルアミン及びアルキレンアミン混合物を有機ポリイソシアネートと反応させることを含んでなる、ポリ尿素の形成方法。
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US201662277522P | 2016-01-12 | 2016-01-12 | |
US62/277,522 | 2016-01-12 | ||
PCT/US2016/064052 WO2017123333A1 (en) | 2016-01-12 | 2016-11-30 | Co-preparation of polyetheramines and alkylene amines |
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BR112017025485A2 (pt) | 2018-08-07 |
US20180312624A1 (en) | 2018-11-01 |
KR102627551B1 (ko) | 2024-01-23 |
JP6843770B2 (ja) | 2021-03-17 |
US11015015B2 (en) | 2021-05-25 |
KR20180101998A (ko) | 2018-09-14 |
WO2017123333A1 (en) | 2017-07-20 |
MX2017015276A (es) | 2018-02-19 |
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