JP2019502004A - ポリマー粉体の製造方法 - Google Patents
ポリマー粉体の製造方法 Download PDFInfo
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- JP2019502004A JP2019502004A JP2018533751A JP2018533751A JP2019502004A JP 2019502004 A JP2019502004 A JP 2019502004A JP 2018533751 A JP2018533751 A JP 2018533751A JP 2018533751 A JP2018533751 A JP 2018533751A JP 2019502004 A JP2019502004 A JP 2019502004A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/16—Auxiliary treatment of granules
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B13/00—Conditioning or physical treatment of the material to be shaped
- B29B13/02—Conditioning or physical treatment of the material to be shaped by heating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B13/00—Conditioning or physical treatment of the material to be shaped
- B29B13/02—Conditioning or physical treatment of the material to be shaped by heating
- B29B13/021—Heat treatment of powders
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B13/00—Conditioning or physical treatment of the material to be shaped
- B29B13/10—Conditioning or physical treatment of the material to be shaped by grinding, e.g. by triturating; by sieving; by filtering
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/141—Processes of additive manufacturing using only solid materials
- B29C64/153—Processes of additive manufacturing using only solid materials using layers of powder being selectively joined, e.g. by selective laser sintering or melting
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
- B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/16—Auxiliary treatment of granules
- B29B2009/165—Crystallizing granules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2071/00—Use of polyethers, e.g. PEEK, i.e. polyether-etherketone or PEK, i.e. polyetherketone or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G2650/28—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
- C08G2650/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing oxygen in addition to the ether group
- C08G2650/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing oxygen in addition to the ether group containing ketone groups, e.g. polyarylethylketones, PEEK or PEK
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
- C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
- C08G65/4012—Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Thermal Sciences (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Composite Materials (AREA)
- Civil Engineering (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Optics & Photonics (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
Description
−A−C(=O)−B−C(=O)− I
−A−C(=O)−D−C(=O)− II
ここで、Aはp,p’−Ph−O−Ph基であり、Phはフェニレン基であり、Bはp−フェニレンであり、Dはm−フェニレンである。ポリマー中の式I:式IIの異性体比(通常T:I比と称される)は、ポリマーの全体結晶度を変化させるように選択することができる。T:I比は通常50:50〜90:10の範囲であり、ある実施形態においては60:40〜80:20の範囲である。例えば80:20のような高いT:I比は、例えば60:40のような低いT:I比と比較して高い結晶度を提供する。好ましいT:I比には80:20、70:30及び60:40が含まれ、60:40が特に好ましい。また、T:I比が異なるPEKKポリマーの混合物も本開示の範囲内である。
PEKKペレットを160℃〜300℃の範囲の温度、好ましくは180℃〜290℃の範囲の温度に、少なくとも10%の結晶度を有する半晶質PEKKペレットを製造するのに足りる時間、加熱し;
前記半晶質PEKKペレットを粉砕して約10ミクロン〜約150ミクロンの範囲の中位粒子直径を有するPEKK粉体を製造し;そして
前記PEKK粉体を約275℃〜約290℃、好ましくは280℃〜290℃の範囲の温度に加熱して被熱処理PEKK粉体を製造する。
PEKK反応器フレークを押出機で溶融加工し、この押出物を細断することによって、2〜10mmの直径のペレットにする。押出加工温度は一般的に300〜400℃、好ましくは320〜350℃だった。製造されたペレットは、微細構造において非晶質、即ち結晶度0〜5%だった。
Claims (20)
- PEKKペレットを160℃〜300℃の範囲の温度、好ましくは180℃〜290℃の範囲の温度に、少なくとも10%の結晶度を有する半晶質PEKKペレットを製造するのに足りる時間、加熱し;
前記半晶質PEKKペレットを粉砕して約10ミクロン〜約150ミクロンの範囲の中位粒子直径を有するPEKK粉体を製造し;そして
前記PEKK粉体を約275℃〜約290℃、好ましくは280℃〜290℃の範囲の温度に加熱して被熱処理PEKK粉体を製造する:
ことを含む、方法。 - 前記PEKKペレットが5%以下の結晶度を有する、請求項1に記載の方法。
- 前記PEKKペレットが非晶質である、請求項2に記載の方法。
- 前記PEKKペレットのT:I異性体比が50:50〜90:10、好ましくは60:40〜80:20の範囲、より一層好ましくは60:40である、請求項1に記載の方法。
- 前記PEKKペレットを約180℃〜約250℃の温度に加熱する、請求項1に記載の方法。
- 前記PEKKペレットが約1mm〜約10mm、好ましくは2mm〜5mmの中位粒子直径を有する、請求項1に記載の方法。
- 前記PEKKペレットを少なくとも5分間加熱する、請求項1〜6のいずれかに記載の方法。
- 前記PEKKペレットを5〜30分間加熱する、請求項1に記載の方法。
- 前記非晶質PEKKペレットがさらに1種以上の添加剤を含む、請求項1に記載の方法。
- 前記添加剤が酸化防止剤、流動促進剤、カーボンナノチューブ、カーボンブラック又はそれらの組合せである、請求項9に記載の方法。
- 前記非晶質PEKKペレットが1種以上の添加剤を10重量%まで含む、請求項9に記載の方法。
- 前記非晶質PEKKペレットが実質的に添加剤フリーである、請求項1に記載の方法。
- 前記粉砕をハンマーミル、アトリションミル、ピン留めディスクミル又はジェットミルで実施する、請求項1に記載の方法。
- 前記粉砕を周囲条件下又は冷却条件下で実施する、請求項1に記載の方法。
- 前記PEKK粉体が約30ミクロン〜約100ミクロン、好ましくは約50ミクロンの中位粒子直径を有する、請求項1に記載の方法。
- 前記被熱処理PEKK粉体が0.35g/cm3〜0.90g/cm3の範囲の嵩密度を有する、請求項1に記載の方法。
- 前記被熱処理PEKK粉体が0.4g/cm3〜0.5g/cm3の範囲の嵩密度を有する、請求項1に記載の方法。
- 30ミクロン〜約100ミクロンの範囲の中位粒子直径、0.40g/cm3〜0.50g/cm3の範囲の嵩密度を有する被熱処理PEKK粉体であって、該粉体の粒子が実質的に規則的な形状である、前記粉体。
- 請求項1に従って製造された被熱処理PEKK粉体をレーザー焼結して物品を製造することを含む、方法。
- 請求項19の方法に従って製造された物品。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US201562271449P | 2015-12-28 | 2015-12-28 | |
US62/271,449 | 2015-12-28 | ||
PCT/US2016/067922 WO2017116885A1 (en) | 2015-12-28 | 2016-12-21 | Processes for producing polymer powders |
Publications (2)
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JP2019502004A true JP2019502004A (ja) | 2019-01-24 |
JP6906526B2 JP6906526B2 (ja) | 2021-07-21 |
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JP2018533751A Active JP6906526B2 (ja) | 2015-12-28 | 2016-12-21 | ポリマー粉体の製造方法 |
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US (1) | US10882215B2 (ja) |
EP (2) | EP3397441B1 (ja) |
JP (1) | JP6906526B2 (ja) |
KR (1) | KR102613603B1 (ja) |
CN (1) | CN108367459B (ja) |
BR (1) | BR112018010987A2 (ja) |
ES (1) | ES2932999T3 (ja) |
WO (1) | WO2017116885A1 (ja) |
Families Citing this family (12)
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EP3681687A4 (en) * | 2017-09-15 | 2021-06-02 | Arkema, Inc. | PROCESS FOR GENERATIVE MANUFACTURING WITH PEKK EXTRUSION AND PRODUCTS |
JP7071865B2 (ja) * | 2018-04-23 | 2022-05-19 | ヘクセル コーポレイション | ポリマー粉末およびそれを使用する方法 |
EP3594266A1 (en) * | 2018-07-10 | 2020-01-15 | Hexcel Corporation | Polymer powder and method of using the same |
EP3820662A4 (en) * | 2018-07-11 | 2022-06-08 | Arkema, Inc. | METHOD AND APPARATUS FOR HEAT TREATMENT OF A POLYMER POWDER |
US20210394438A1 (en) * | 2018-11-13 | 2021-12-23 | Solvay Specialty Polymers Usa, Llc | Additive manufacturing method for making a three-dimensional object using selective laser sintering |
FR3093666B1 (fr) * | 2019-03-15 | 2022-01-14 | Arkema France | Procédé de fabrication par frittage d'une poudre à base de poly-aryl-éther-cétone(s) en partie recyclée |
EP3812416A1 (en) | 2019-10-23 | 2021-04-28 | Acondicionamiento Tarrasense | Process for producing polymers in powder form |
EP3825345A1 (en) * | 2019-11-19 | 2021-05-26 | Arkema France | Improved powder for additive manufacturing |
CN111145961A (zh) * | 2019-12-30 | 2020-05-12 | 山东凯盛新材料股份有限公司 | 聚醚酮酮漆包线的制备方法 |
EP4008742A1 (en) * | 2020-12-04 | 2022-06-08 | Arkema France | Pulverulent composition based on paek(s), sintering construction process and object derived therefrom |
CN114373586B (zh) * | 2021-12-30 | 2024-04-05 | 重庆沃特智成新材料科技有限公司 | 漆包线及其制备方法、用电设备 |
GB202218077D0 (en) | 2022-12-01 | 2023-01-18 | Victrex Mfg Ltd | Method of making particles |
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- 2016-12-21 KR KR1020187021791A patent/KR102613603B1/ko active IP Right Grant
- 2016-12-21 ES ES16882388T patent/ES2932999T3/es active Active
- 2016-12-21 EP EP16882388.8A patent/EP3397441B1/en active Active
- 2016-12-21 JP JP2018533751A patent/JP6906526B2/ja active Active
- 2016-12-21 WO PCT/US2016/067922 patent/WO2017116885A1/en active Application Filing
- 2016-12-21 CN CN201680071847.6A patent/CN108367459B/zh active Active
- 2016-12-21 US US16/066,320 patent/US10882215B2/en active Active
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JP2008524356A (ja) * | 2004-12-21 | 2008-07-10 | エボニック デグサ ゲーエムベーハー | 微細粒のポリアリーレンエーテルケトン粉末 |
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Also Published As
Publication number | Publication date |
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ES2932999T3 (es) | 2023-01-30 |
US20200164546A1 (en) | 2020-05-28 |
WO2017116885A1 (en) | 2017-07-06 |
CN108367459A (zh) | 2018-08-03 |
KR20180099802A (ko) | 2018-09-05 |
JP6906526B2 (ja) | 2021-07-21 |
EP3397441B1 (en) | 2022-09-14 |
EP4112261A1 (en) | 2023-01-04 |
KR102613603B1 (ko) | 2023-12-15 |
EP3397441A1 (en) | 2018-11-07 |
BR112018010987A2 (pt) | 2018-12-04 |
US10882215B2 (en) | 2021-01-05 |
EP3397441A4 (en) | 2019-08-21 |
CN108367459B (zh) | 2022-02-18 |
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