JP2019196479A - 樹脂、ワニス組成物、印刷インキ及び印刷物 - Google Patents
樹脂、ワニス組成物、印刷インキ及び印刷物 Download PDFInfo
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- JP2019196479A JP2019196479A JP2019085245A JP2019085245A JP2019196479A JP 2019196479 A JP2019196479 A JP 2019196479A JP 2019085245 A JP2019085245 A JP 2019085245A JP 2019085245 A JP2019085245 A JP 2019085245A JP 2019196479 A JP2019196479 A JP 2019196479A
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- YAQXGBBDJYBXKL-UHFFFAOYSA-N iron(2+);1,10-phenanthroline;dicyanide Chemical compound [Fe+2].N#[C-].N#[C-].C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1 YAQXGBBDJYBXKL-UHFFFAOYSA-N 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 229940107698 malachite green Drugs 0.000 description 1
- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- ZQMHJBXHRFJKOT-UHFFFAOYSA-N methyl 2-[(1-methoxy-2-methyl-1-oxopropan-2-yl)diazenyl]-2-methylpropanoate Chemical compound COC(=O)C(C)(C)N=NC(C)(C)C(=O)OC ZQMHJBXHRFJKOT-UHFFFAOYSA-N 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003471 mutagenic agent Substances 0.000 description 1
- WVFLGSMUPMVNTQ-UHFFFAOYSA-N n-(2-hydroxyethyl)-2-[[1-(2-hydroxyethylamino)-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCO WVFLGSMUPMVNTQ-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 125000004370 n-butenyl group Chemical group [H]\C([H])=C(/[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- JMXROTHPANUTOJ-UHFFFAOYSA-H naphthol green b Chemical compound [Na+].[Na+].[Na+].[Fe+3].C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21.C1=C(S([O-])(=O)=O)C=CC2=C(N=O)C([O-])=CC=C21 JMXROTHPANUTOJ-UHFFFAOYSA-H 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000004957 naphthylene group Chemical group 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- STZXUSSPDVUIMK-UHFFFAOYSA-N nonane-1,9-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OCCCCCCCCCO STZXUSSPDVUIMK-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 125000002868 norbornyl group Chemical group C12(CCC(CC1)C2)* 0.000 description 1
- 125000005574 norbornylene group Chemical group 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000001053 orange pigment Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 229950000688 phenothiazine Drugs 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- WIANIBTWBFSFCC-UHFFFAOYSA-M potassium zinc hydrogen carbonate oxygen(2-) Chemical compound [O-2].[Zn+2].C([O-])(O)=O.[K+] WIANIBTWBFSFCC-UHFFFAOYSA-M 0.000 description 1
- YLLIGHVCTUPGEH-UHFFFAOYSA-M potassium;ethanol;hydroxide Chemical compound [OH-].[K+].CCO YLLIGHVCTUPGEH-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 125000006410 propenylene group Chemical group 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- MWWATHDPGQKSAR-UHFFFAOYSA-N propyne Chemical group CC#C MWWATHDPGQKSAR-UHFFFAOYSA-N 0.000 description 1
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- 239000001057 purple pigment Substances 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- MHVJRKBZMUDEEV-KRFUXDQASA-N sandaracopimaric acid Chemical compound [C@H]1([C@](CCC2)(C)C(O)=O)[C@@]2(C)[C@H]2CC[C@@](C=C)(C)C=C2CC1 MHVJRKBZMUDEEV-KRFUXDQASA-N 0.000 description 1
- YZVSLDRKXBZOMY-KNOXWWKRSA-N sandaracopimaric acid Natural products CC(=C)[C@]1(C)CCC[C@]2(C)[C@H]3CC[C@](C)(C=C)C=C3CC[C@@H]12 YZVSLDRKXBZOMY-KNOXWWKRSA-N 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000003307 slaughter Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 125000005649 substituted arylene group Chemical group 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000005628 tolylene group Chemical group 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 125000006839 xylylene group Chemical group 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- JBCJMTUHAXHILC-UHFFFAOYSA-N zinc;octanoic acid Chemical compound [Zn+2].CCCCCCCC(O)=O JBCJMTUHAXHILC-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Printing Methods (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
(項目1)
構成単位1、
Radは
又は置換若しくは非置換のアリール基である。>
を含む、樹脂。
(項目2)
構成単位2:
であり、
Rb18〜Rb19は、それぞれ独立に
であり、
Rb20はアルキレン基であり、
Rb4、Rb5、Rb9、及びRb13は各構成単位ごとに基が異なっていてもよく、
一般式(A)〜(D)中において
が2個以上含まれる。]
を含む、上記項目に記載の樹脂。
(項目3)
上記項目のいずれか1項に記載の樹脂を含む、ワニス組成物。
(項目4)
上記項目に記載のワニス組成物及び顔料を含む、印刷インキ。
(項目5)
上記項目に記載の印刷インキの硬化層を有する、印刷物。
本開示は、構成単位1、
Radは
又は置換若しくは非置換のアリール基である。>
を含む、樹脂を提供する。
であり、
Rb18〜Rb19は、それぞれ独立に
であり、
Rb20はアルキレン基であり、
Rb4、Rb5、Rb9、及びRb13は各構成単位ごとに基が異なっていてもよく、
一般式(A)〜(D)中において
が2個以上含まれる。]
を含む。
を含む。
式中、Rd1及びRd2は、アルキル基若しくは水素原子であるか、又はRd1及びRd2が一緒になって環構造を形成する基であり、kは1以上の整数であり、Rd3は、水素原子、メチル基又は水酸基であり、Rd4は、OH、CH2OH、CH2CH2OH、CH2OCH3又はCH2OPhであるが、Rd3又はRd4のどちらかが水酸基である。)
を含む。
を含む。
を含む。
等が例示される。
構成単位1は、モノマーとして、エポキシ基含有(メタ)アクリル酸エステルを含む樹脂に対し、ロジン類を含むカルボン酸を反応させた場合、グリシジル変性ロジン類等のエポキシ変性ロジン類と(メタ)アクリル酸との反応物を重合させた場合等にポリマー鎖に含まれる構成単位である。構成単位1は、単独で又は2種以上のものが含まれ得る。
構成単位2は、下記に説明する多官能性モノマーに由来する構成単位である。なお、多官能性モノマーは、単独で又は2種以上が用いられ得る。
構成単位2Aは、モノマーとして、一般式A’
であり、
Rb4’、及びRb5’は各構成単位ごとに基が異なっていてもよく、
一般式(A’)中において
が2個以上含まれる。]
で示される(ポリ)ペンタエリスリトールポリ(アルキレンオキサイド変性又はエポキシ変性)(メタ)アクリレートを用いた場合にポリマー鎖に含まれる構成単位である。
構成単位2Bは、モノマーとして、一般式B’
であり、
Rb9’は各構成単位ごとに基が異なっていてもよく、
一般式(B’)中において
が2個以上含まれる。]
で示される(ポリ)トリメチロールプロパンポリ(アルキレンオキサイド変性又はエポキシ変性)(メタ)アクリレートを用いた場合にポリマー鎖に含まれる構成単位である。
構成単位2Cは、モノマーとして、一般式C’
であり、
Rb13’は各構成単位ごとに基が異なっていてもよく、
一般式(C’)中において
が2個以上含まれる。]
で示されるような(ポリ)グリセリンポリ(アルキレンオキサイド変性又はエポキシ変性)(メタ)アクリレートを用いた場合にポリマー鎖に含まれる構成単位である。
構成単位2Dは、モノマーとして、一般式D’
であり、一般式(D’)中において
が2個以上含まれる。]
で示されるようなイソシアヌレート構造含有モノマーを用いた場合にポリマー鎖に含まれる構成単位である。
構成単位2Eは、モノマーとして、一般式E’
であり、
Rb20’は、アルキレン基である。]
で示されるようなアルキレンジ(アルキレンオキサイド変性又はエポキシ変性)(メタ)アクリレートを用いた場合にポリマー鎖に含まれる構成単位である。
構成単位3は、モノマーとして、アルケニルアリールを用いた場合にポリマー鎖に含まれる構成単位である。アルケニルアリールは、1種又は2種以上を使用可能である。アルケニルアリールは、スチレン、α−メチルスチレン等の他、芳香環に少なくとも1つの炭素数1〜2のアルキル基を有するスチレン等が例示される。
構成単位4は、モノマーとして、(メタ)アクリル酸、N,N−ジアルキル(メタ)アクリルアミド、N,N−ジアルキルアミンアルキル(メタ)アクリレート、(メタ)アクリル酸ヒドロキシアルキルを用いた場合にポリマー鎖に含まれる構成単位である。
構成単位5は、例えば、下記の構造を有する
構成単位6は、モノマーとして、(メタ)アクリル酸又は(メタ)アクリル酸エステルを用いた場合にポリマー鎖に含まれる構成単位である。(メタ)アクリル酸又は(メタ)アクリル酸エステルは、1種又は2種以上を使用可能である。
本開示の樹脂には、構成単位1〜6以外のその他の構成単位も含んでもよい。その他の構成単位は、構成単位1〜4、6以外の(メタ)アクリル酸誘導体に由来する構成単位、連鎖移動剤に由来する構成単位等が例示される。
分子量分布(Mw/Mn)は、例えば重量平均分子量及び数平均分子量を、ゲルパーミエーションクロマトグラフィー(GPC)により適切な溶媒下で測定したポリスチレン換算値として求め、求めた分子量の値から計算するという手順により導出される。
反応性希釈剤は、各種公知のものを用いることができ、1種又は2種以上を併用できる。反応性希釈剤は、
であり、
Rb18’〜Rb19 ’は、それぞれ独立に
であり、
Rb20’はアルキレン基であり、
Rb4’、Rb5’、Rb9’、及びRb13’は各構成単位ごとに基が異なっていてもよく、
一般式(A’)〜(D’)中において
が2個以上含まれる。]
等が例示される。
ワニス組成物中の樹脂の含有量の上限は、ワニス組成物の合計質量に対して、60、59、55、50、45、40、35、30、25、20、15、11質量%等が例示され、下限は、59、55、50、45、40、35、30、25、20、15、11、10質量%等が例示される。ワニス組成物中の樹脂の含有量の範囲は適宜(例えば上記上限及び下限の値から選択して)設定され得る。1つの実施形態において、皮膜強度と硬化性の観点から、ワニス組成物中の樹脂の含有量は、ワニス組成物の合計質量に対して、10〜60質量%が好ましい。
本開示は上記ワニス組成物、必要に応じて光重合開始剤、及び顔料を含む、印刷インキを提供する。
本開示は、上記印刷インキの硬化層を有する、印刷物を提供する。
攪拌機、分水器付き還流冷却管及び温度計と滴下ロートを備えた反応容器に酢酸ブチルと290g仕込んだ。滴下ロートにグリシジルメタクリレート290gを仕込み、2,2’−アゾビスイソブチロニトリルを40g添加した。窒素雰囲気下、121℃、3.0時間 攪拌下滴下重合反応を行い、1時間保温した。その後、水添ロジン(荒川化学製、商品名ハイペールCH)を710g、トリフェニルホスフィン4.0gを添加した後、120℃で12時間撹拌した。その後、常圧で190℃まで昇温しながら溶剤を留去して、50mmHg以下で減圧しながら溶剤を完全に留去して樹脂を得た。
実施例1−1で得られた樹脂1 19.9質量部に対して反応性希釈剤ジトリメチロールプロパンテトラアクリレート60.1質量部を加え、エアーバブリング下、130℃、1時間攪拌溶解し、ワニス組成物を得た。得られたワニス組成物に対して、イルガキュア907(BASF製)を5質量部、MA100(三菱ケミカル(株)製)を15質量部仕込み、3本ローラーで錬肉してインキを調製した。上記配合に基づいて40℃、400rpmにおけるタック値が9±0.5となるよう適宜調整し、印刷インキを得た。
60°に傾けたガラス板の上にインキ1.30mlをのせて、30分放置後のインキの流れを計測した。評価基準は以下の通り。
◎:301mm以上
○:300〜201mm
△:200〜101mm
×:100mm以下
13cm×21cm角に切り取ったOHPフィルムをインコメーターのローラー裏の壁面に貼り付け、ローラー温度を40℃に調整後、ローラーの上にインキを2.6mlのせた。ローラーを1200rpm×2分 回転させフィルムに付着したインキの質量を秤量した。評価基準は以下の通り。
◎:19mg以下
○:20〜59mg
△:60〜99mg
×:100mg以上
塗工したインキを72mJ/cm2の光量でUV照射機に通す作業を1パスとして、硬化するまでパスを繰り返すし、インキを布で擦った時に傷が付かなくなるパス回数を硬化とする。評価基準は以下の通り。
◎:1パスで硬化
○:2〜4パスで硬化
△:5〜7パスで硬化
×:8パス以上で硬化
Claims (5)
- 構成単位1、
Radは
又は置換若しくは非置換のアリール基である。>
を含む、樹脂。 - 構成単位2:
であり、
Rb18〜Rb19は、それぞれ独立に
であり、
Rb20はアルキレン基であり、
Rb4、Rb5、Rb9、及びRb13は各構成単位ごとに基が異なっていてもよく、
一般式(A)〜(D)中において
が2個以上含まれる。]
を含む、請求項1に記載の樹脂。 - 請求項1又は2に記載の樹脂を含む、ワニス組成物。
- 請求項3に記載のワニス組成物及び顔料を含む、印刷インキ。
- 請求項4に記載の印刷インキの硬化層を有する、印刷物。
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JPS6320316A (ja) * | 1986-07-11 | 1988-01-28 | Arakawa Chem Ind Co Ltd | 光硬化性オリゴマーの製法 |
JP2000212232A (ja) * | 1999-01-27 | 2000-08-02 | Arakawa Chem Ind Co Ltd | 活性エネルギ―線硬化性樹脂組成物および剥離帳票シ―ト用コ―ティング剤 |
JP2002289039A (ja) * | 2001-03-22 | 2002-10-04 | Dainippon Printing Co Ltd | 光硬化型導体インキ、電極形成方法及び電極パターン |
WO2007141829A1 (ja) * | 2006-06-02 | 2007-12-13 | Showa Highpolymer Co., Ltd. | 感光性樹脂および感光性樹脂組成物 |
JP2008143941A (ja) * | 2006-12-06 | 2008-06-26 | Showa Highpolymer Co Ltd | 感光性樹脂及びそれを含む感光性樹脂組成物 |
JP2008150528A (ja) * | 2006-12-19 | 2008-07-03 | Kao Corp | インクジェット記録用水系インク |
-
2019
- 2019-04-26 JP JP2019085245A patent/JP7338226B2/ja active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6320316A (ja) * | 1986-07-11 | 1988-01-28 | Arakawa Chem Ind Co Ltd | 光硬化性オリゴマーの製法 |
JP2000212232A (ja) * | 1999-01-27 | 2000-08-02 | Arakawa Chem Ind Co Ltd | 活性エネルギ―線硬化性樹脂組成物および剥離帳票シ―ト用コ―ティング剤 |
JP2002289039A (ja) * | 2001-03-22 | 2002-10-04 | Dainippon Printing Co Ltd | 光硬化型導体インキ、電極形成方法及び電極パターン |
WO2007141829A1 (ja) * | 2006-06-02 | 2007-12-13 | Showa Highpolymer Co., Ltd. | 感光性樹脂および感光性樹脂組成物 |
JP2008143941A (ja) * | 2006-12-06 | 2008-06-26 | Showa Highpolymer Co Ltd | 感光性樹脂及びそれを含む感光性樹脂組成物 |
JP2008150528A (ja) * | 2006-12-19 | 2008-07-03 | Kao Corp | インクジェット記録用水系インク |
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