JP2017518251A5 - - Google Patents
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- Publication number
- JP2017518251A5 JP2017518251A5 JP2016571258A JP2016571258A JP2017518251A5 JP 2017518251 A5 JP2017518251 A5 JP 2017518251A5 JP 2016571258 A JP2016571258 A JP 2016571258A JP 2016571258 A JP2016571258 A JP 2016571258A JP 2017518251 A5 JP2017518251 A5 JP 2017518251A5
- Authority
- JP
- Japan
- Prior art keywords
- range
- zeolitic material
- cha
- sio
- absorption band
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000463 material Substances 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 16
- 239000002245 particle Substances 0.000 claims description 16
- 238000010521 absorption reaction Methods 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 9
- -1 trimethyl-cyclohexylammonium compound Chemical class 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 239000013078 crystal Substances 0.000 claims description 5
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 4
- 238000002425 crystallisation Methods 0.000 claims description 4
- 230000008025 crystallization Effects 0.000 claims description 4
- 238000002835 absorbance Methods 0.000 claims description 2
- 238000002329 infrared spectrum Methods 0.000 claims description 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims 5
- 239000010457 zeolite Substances 0.000 claims 5
- 238000005004 MAS NMR spectroscopy Methods 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 102000035195 Peptidases Human genes 0.000 claims 1
- 108091005804 Peptidases Proteins 0.000 claims 1
- 230000002745 absorbent Effects 0.000 claims 1
- 239000002250 absorbent Substances 0.000 claims 1
- YOUGRGFIHBUKRS-UHFFFAOYSA-N benzyl(trimethyl)azanium Chemical compound C[N+](C)(C)CC1=CC=CC=C1 YOUGRGFIHBUKRS-UHFFFAOYSA-N 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- PAFZNILMFXTMIY-UHFFFAOYSA-O cyclohexylammonium Chemical compound [NH3+]C1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-O 0.000 claims 1
- 230000010354 integration Effects 0.000 claims 1
- 238000005342 ion exchange Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000002808 molecular sieve Substances 0.000 claims 1
- 235000019833 protease Nutrition 0.000 claims 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 15
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 10
- 125000005842 heteroatom Chemical group 0.000 description 9
- 125000000623 heterocyclic group Chemical group 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 6
- 125000001424 substituent group Chemical group 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 150000004645 aluminates Chemical class 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 4
- 238000001354 calcination Methods 0.000 description 4
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 description 4
- 229910052676 chabazite Inorganic materials 0.000 description 4
- 150000004703 alkoxides Chemical class 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 125000006526 (C1-C2) alkyl group Chemical group 0.000 description 1
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 1
- 125000006274 (C1-C3)alkoxy group Chemical group 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical group 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000005346 substituted cycloalkyl group Chemical group 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- PUGUQINMNYINPK-UHFFFAOYSA-N tert-butyl 4-(2-chloroacetyl)piperazine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCN(C(=O)CCl)CC1 PUGUQINMNYINPK-UHFFFAOYSA-N 0.000 description 1
- OBROYCQXICMORW-UHFFFAOYSA-N tripropoxyalumane Chemical compound [Al+3].CCC[O-].CCC[O-].CCC[O-] OBROYCQXICMORW-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14171324.8 | 2014-06-05 | ||
| EP14171324 | 2014-06-05 | ||
| PCT/EP2015/062377 WO2015185625A2 (en) | 2014-06-05 | 2015-06-03 | Cha type zeolitic materials and methods for their preparation using combinations of cycloalkyl- and tetraalkylammonium compounds |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2017518251A JP2017518251A (ja) | 2017-07-06 |
| JP2017518251A5 true JP2017518251A5 (https=) | 2018-07-12 |
| JP6698555B2 JP6698555B2 (ja) | 2020-05-27 |
Family
ID=50846880
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016571258A Active JP6698555B2 (ja) | 2014-06-05 | 2015-06-03 | Ｃｈａ型ゼオライト材料、並びに、シクロアルキル−及びテトラアルキルアンモニウム化合物を使用するそれらの製造方法 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US10315924B2 (https=) |
| EP (1) | EP3152162B1 (https=) |
| JP (1) | JP6698555B2 (https=) |
| KR (1) | KR102410485B1 (https=) |
| CN (1) | CN106660024B (https=) |
| BR (1) | BR112016028226B1 (https=) |
| CA (1) | CA2951064C (https=) |
| MX (1) | MX379278B (https=) |
| PL (1) | PL3152162T3 (https=) |
| RU (1) | RU2678676C2 (https=) |
| WO (1) | WO2015185625A2 (https=) |
| ZA (1) | ZA201608280B (https=) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016128917A1 (en) | 2015-02-12 | 2016-08-18 | Basf Se | Process for the preparation of a dealuminated zeolitic material having the bea framework structure |
| WO2016177814A1 (en) | 2015-05-04 | 2016-11-10 | Basf Se | Process for the preparation of melonal |
| US10737239B2 (en) | 2015-11-27 | 2020-08-11 | Basf Se | Ultrafast high space-time-yield synthesis of metal-organic frameworks |
| EP3178788A1 (en) | 2015-12-08 | 2017-06-14 | Basf Se | A tin-containing zeolitic material having a bea framework structure |
| JP6949842B2 (ja) * | 2015-12-09 | 2021-10-13 | ビーエーエスエフ コーポレーション | Ｃｈａ型ゼオライト材料、並びにシクロアルキル−、及びエチルトリメチルアンモニウム化合物の組み合わせを用いるそれらの製造方法 |
| CN109195911B (zh) * | 2016-05-23 | 2023-04-07 | 东曹株式会社 | Cha型沸石和其制造方法 |
| CN109562363B (zh) | 2016-06-13 | 2022-02-25 | 巴斯夫公司 | 催化剂复合材料及其在选择性催化还原NOx中的应用 |
| EP3519354A1 (en) | 2016-09-30 | 2019-08-07 | Johnson Matthey Public Limited Company | A novel zeolite synthesis with a fluoride source |
| JP6320658B1 (ja) * | 2016-10-25 | 2018-05-09 | 日揮触媒化成株式会社 | 基材コート用チャバザイト型ゼオライト |
| MY190284A (en) * | 2017-10-11 | 2022-04-12 | Tosoh Corp | Metal-containing cha-type zeolite and method for producing the same |
| EP3728120A1 (en) | 2017-12-21 | 2020-10-28 | Basf Se | A fast batch process for preparing a zeolitic material having framework type cha |
| JP6526847B1 (ja) * | 2018-01-12 | 2019-06-05 | エヌ・イーケムキャット株式会社 | 排ガス浄化触媒及びその製造方法 |
| CN110240179B (zh) * | 2018-03-09 | 2021-05-07 | 国家能源投资集团有限责任公司 | Sapo-34分子筛及其制备方法和应用 |
| WO2020025799A1 (en) | 2018-08-02 | 2020-02-06 | Basf Se | Process for a continuous synthesis of zeolitic materials using seed crystals loaded with organotemplate |
| WO2020109292A1 (en) | 2018-11-27 | 2020-06-04 | Basf Se | Mechanochemical activation in zeolite synthesis |
| WO2020109290A1 (en) | 2018-11-27 | 2020-06-04 | Basf Se | Solvent-free mechanochemical activation in zeolite synthesis |
| WO2020127425A1 (en) | 2018-12-19 | 2020-06-25 | Basf Se | Cha type zeolitic materials and methods for their preparation |
| WO2020225409A1 (en) | 2019-05-09 | 2020-11-12 | Basf Se | Process for a continuous synthesis of a cha zeolitic material from an emulsion |
| US20230150827A1 (en) * | 2020-04-07 | 2023-05-18 | Basf Se | Zeolite of a new framework structure type and production thereof |
| CN116685400A (zh) | 2020-12-09 | 2023-09-01 | 巴斯夫公司 | 包含Cu和Fe交换的沸石的SCR催化剂的制备方法，所述催化剂，包含所述催化剂的系统和使用所述催化剂的排气处理 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4544538A (en) | 1982-07-09 | 1985-10-01 | Chevron Research Company | Zeolite SSZ-13 and its method of preparation |
| US4610854A (en) * | 1982-10-29 | 1986-09-09 | Chevron Research Company | Zeolite SSZ-15 and process for preparing the same |
| ES2279105T3 (es) * | 2002-03-15 | 2007-08-16 | Exxonmobil Chemical Patents, Inc. | Chabacita rica en silice, su sintesis y su utilizacion en la conversion de compuestos oxigenados en olefinas. |
| US7247287B2 (en) * | 2003-06-11 | 2007-07-24 | Exxonmobil Chemical Patents Inc. | Synthesis of aluminophosphates and silicoaluminophosphates |
| US8048402B2 (en) | 2005-08-18 | 2011-11-01 | Exxonmobil Chemical Patents Inc. | Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins |
| WO2008033229A2 (en) | 2006-09-15 | 2008-03-20 | Exxonmobil Research And Engineering Company | A method of making porous crystalline materials |
| ES2685497T3 (es) | 2006-09-25 | 2018-10-09 | Chevron U.S.A. Inc. | Preparación de tamices moleculares utilizando un agente director de estructura y un catión de amonio cuaternario de N,N,N-trialquil bencilo |
| US20080159950A1 (en) | 2006-12-27 | 2008-07-03 | Miller Stephen J | Preparation of molecular sieve ssz-13 |
| ES2465004T3 (es) | 2008-05-21 | 2014-06-04 | Basf Se | Procedimiento de síntesis directa de zeolitas que contienen Cu que tienen una estructura de CHA |
| US8409546B2 (en) * | 2009-11-24 | 2013-04-02 | Basf Se | Process for the preparation of zeolites having B-CHA structure |
| CN102665902A (zh) * | 2009-11-24 | 2012-09-12 | 巴斯夫欧洲公司 | 制备具有cha结构的沸石的方法 |
| JP5895510B2 (ja) * | 2010-12-22 | 2016-03-30 | 東ソー株式会社 | チャバザイト型ゼオライト及びその製造方法、銅が担持されている低シリカゼオライト、及び、そのゼオライトを含む窒素酸化物還元除去触媒、並びに、その触媒を使用する窒素酸化物還元除去方法 |
| US9636667B2 (en) * | 2012-06-04 | 2017-05-02 | Basf Se | CHA-type zeolite materials and methods for their preparation using cycloalkyammonium compounds |
| CN104520235A (zh) * | 2012-06-04 | 2015-04-15 | 巴斯夫欧洲公司 | Cha型沸石材料及其使用环烷基铵化合物的制备 |
-
2015
- 2015-06-03 US US15/315,636 patent/US10315924B2/en active Active
- 2015-06-03 JP JP2016571258A patent/JP6698555B2/ja active Active
- 2015-06-03 RU RU2016152444A patent/RU2678676C2/ru active
- 2015-06-03 KR KR1020177000261A patent/KR102410485B1/ko active Active
- 2015-06-03 BR BR112016028226-4A patent/BR112016028226B1/pt active IP Right Grant
- 2015-06-03 PL PL15737992T patent/PL3152162T3/pl unknown
- 2015-06-03 CN CN201580041845.8A patent/CN106660024B/zh active Active
- 2015-06-03 CA CA2951064A patent/CA2951064C/en active Active
- 2015-06-03 MX MX2016016060A patent/MX379278B/es unknown
- 2015-06-03 EP EP15737992.6A patent/EP3152162B1/en active Active
- 2015-06-03 WO PCT/EP2015/062377 patent/WO2015185625A2/en not_active Ceased
-
2016
- 2016-11-30 ZA ZA2016/08280A patent/ZA201608280B/en unknown
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