JP2017517101A - キノンポリハライドフロー電池 - Google Patents
キノンポリハライドフロー電池 Download PDFInfo
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- JP2017517101A JP2017517101A JP2016566261A JP2016566261A JP2017517101A JP 2017517101 A JP2017517101 A JP 2017517101A JP 2016566261 A JP2016566261 A JP 2016566261A JP 2016566261 A JP2016566261 A JP 2016566261A JP 2017517101 A JP2017517101 A JP 2017517101A
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- electrolyte
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- flow battery
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- quinone
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- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 239000003792 electrolyte Substances 0.000 claims abstract description 41
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 30
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000004056 anthraquinones Chemical class 0.000 claims abstract description 10
- 239000011259 mixed solution Substances 0.000 claims abstract description 10
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 claims description 16
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 239000008151 electrolyte solution Substances 0.000 claims description 5
- KHJQQUGSPDBDRM-UHFFFAOYSA-M 1-ethyl-1-methylpyrrolidin-1-ium;bromide Chemical group [Br-].CC[N+]1(C)CCCC1 KHJQQUGSPDBDRM-UHFFFAOYSA-M 0.000 claims description 4
- 239000008139 complexing agent Substances 0.000 claims description 4
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 3
- ACQZVWGQFXXTIX-UHFFFAOYSA-M 4-ethyl-4-methylmorpholin-4-ium;bromide Chemical compound [Br-].CC[N+]1(C)CCOCC1 ACQZVWGQFXXTIX-UHFFFAOYSA-M 0.000 claims description 2
- 239000007773 negative electrode material Substances 0.000 claims 1
- 239000007774 positive electrode material Substances 0.000 claims 1
- 229910052979 sodium sulfide Inorganic materials 0.000 abstract 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 abstract 1
- 239000012528 membrane Substances 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 229910052794 bromium Inorganic materials 0.000 description 5
- 238000004146 energy storage Methods 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000003115 supporting electrolyte Substances 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- ZRXYMHTYEQQBLN-UHFFFAOYSA-N [Br].[Zn] Chemical compound [Br].[Zn] ZRXYMHTYEQQBLN-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- -1 bromine ions Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910001456 vanadium ion Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000012864 cross contamination Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
- H01M8/184—Regeneration by electrochemical means
- H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0568—Liquid materials characterised by the solutes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/96—Carbon-based electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/20—Indirect fuel cells, e.g. fuel cells with redox couple being irreversible
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
- H01M2004/8684—Negative electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
- H01M2004/8689—Positive electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Chemical & Material Sciences (AREA)
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- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Fuel Cell (AREA)
- Hybrid Cells (AREA)
Abstract
Description
本特許は、キノン臭素フロー電池のコストが相対的に高く、電池の電圧が相対的に低いという課題が改善されるように技術を改善することにより、キノンポリハライドフロー電池の概念を提案する。
別段指定しない限り、実施例及び比較例の電池をアセンブルするために多孔膜を採用した。
電解液調製及び電池アセンブリ:
正電解液:1M HCl+0.5M臭化N−メチルエチルピロリジニウム+1M臭化ナトリウム、40mL;
負電解液:1M HCl+0.5M臭化N−メチルエチルピロリジニウム+1Mアントラキノン溶液、40mL。順番に、正エンドプレート、正極3×3cm2、カーボンフェルト、膜、カーボンフェルト、負極黒鉛板3×3cm2及び負エンドプレートによって単電池をアセンブルした。
電解液流量:5mL/分;充放電電流密度:20mA/cm2;電池のサイクル安定性を図1に示す。
電解液調製及び電池アセンブリ:
正電解液:0.5M H2SO4+1M臭化ナトリウム、40mL;
負電解液:0.5M H2SO4+1Mアントラキノン溶液、40mL。順番に、正エンドプレート、正極3×3cm2、カーボンフェルト、膜、カーボンフェルト、負極黒鉛板3×3cm2及び負エンドプレートによって単電池をアセンブルした。
電池試験:
電解液流量:5mL/分;充放電電流密度:20mA/cm2;電池のサイクル安定性を図2に示す。
Claims (8)
- 電池モジュール、正電解液を貯蔵する貯蔵槽、負電解液を貯蔵する貯蔵槽、循環ポンプ及びパイプからなり、前記電池モジュールが、二、三又は三よりも多い直列の単電池の区分によって形成され;単電池が正極、セパレータ及び負極を含む、キノンポリハライドフロー電池であって、前記正電解液が塩酸と臭化ナトリウムとの混合溶液であり、前記負電解液が塩酸とアントラキノンとの混合溶液であることを特徴とする、キノンポリハライドフロー電池。
- 前記正電解液が0.5〜2M塩酸と0.5〜2M臭化ナトリウムとの混合溶液であることを特徴とする、請求項1記載のキノンポリハライドフロー電池。
- 前記負電解液が0.5〜2M塩酸と0.5〜1Mアントラキノンとの混合溶液であることを特徴とする、請求項1記載のキノンポリハライドフロー電池。
- 前記正電解液及び負電解液が第四級アンモニウム塩分子臭素錯化剤を0.1〜1M含有することを特徴とする、請求項1記載のキノンポリハライドフロー電池。
- 前記第四級アンモニウム塩分子臭素錯化剤が臭化N−メチルエチルピロリジニウム(MEP)又は臭化N−メチルエチルモルホリニウムであることを特徴とする、請求項3記載のキノンポリハライドフロー電池。
- 前記正極物質及び負極物質が活性炭フェルトであることを特徴とする、請求項1記載のキノンポリハライドフロー電池。
- 前記セパレータが多孔膜又は稠密な膜であることを特徴とする、請求項1記載のキノンポリハライドフロー電池。
- 単電池が、正エンドプレート、正極、セパレータ、負極及び負エンドプレートを含むことを特徴とする、請求項1記載のキノンポリハライドフロー電池。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410653131.XA CN105679985B (zh) | 2014-11-17 | 2014-11-17 | 一种醌多卤化物液流电池 |
CN201410653131.X | 2014-11-17 | ||
PCT/CN2015/092059 WO2016078492A1 (zh) | 2014-11-17 | 2015-10-16 | 一种醌多卤化物液流电池 |
Publications (2)
Publication Number | Publication Date |
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JP2017517101A true JP2017517101A (ja) | 2017-06-22 |
JP6247778B2 JP6247778B2 (ja) | 2017-12-13 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016566261A Active JP6247778B2 (ja) | 2014-11-17 | 2015-10-16 | キノンポリハライドフロー電池 |
Country Status (6)
Country | Link |
---|---|
US (1) | US10446867B2 (ja) |
EP (1) | EP3223354B1 (ja) |
JP (1) | JP6247778B2 (ja) |
CN (1) | CN105679985B (ja) |
AU (1) | AU2015349218B2 (ja) |
WO (1) | WO2016078492A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2020021732A (ja) * | 2018-08-02 | 2020-02-06 | ユナイテッド テクノロジーズ コーポレイションUnited Technologies Corporation | レドックスフロー電池、およびレドックスフロー電池のための方法 |
US11271226B1 (en) | 2020-12-11 | 2022-03-08 | Raytheon Technologies Corporation | Redox flow battery with improved efficiency |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111293355A (zh) * | 2018-12-07 | 2020-06-16 | 河南大学 | 蒽醌在锂氧电池中的应用及其得到的蒽醌锂氧电池 |
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2014
- 2014-11-17 CN CN201410653131.XA patent/CN105679985B/zh active Active
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2015
- 2015-10-16 US US15/302,440 patent/US10446867B2/en active Active
- 2015-10-16 AU AU2015349218A patent/AU2015349218B2/en active Active
- 2015-10-16 JP JP2016566261A patent/JP6247778B2/ja active Active
- 2015-10-16 EP EP15861860.3A patent/EP3223354B1/en active Active
- 2015-10-16 WO PCT/CN2015/092059 patent/WO2016078492A1/zh active Application Filing
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CN102035007A (zh) * | 2009-09-25 | 2011-04-27 | 中国人民解放军63971部队 | 一种水溶性有机电对液流电池 |
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JP2015534708A (ja) * | 2012-09-26 | 2015-12-03 | プレジデント アンド フェローズ オブ ハーバード カレッジ | 低分子有機化合物ベースのフロー電池 |
US20140370403A1 (en) * | 2013-06-17 | 2014-12-18 | University Of Southern California | Inexpensive metal-free organic redox flow battery (orbat) for grid-scale storage |
JP2016533613A (ja) * | 2013-09-26 | 2016-10-27 | プレジデント アンド フェローズ オブ ハーバード カレッジ | キノン及びヒドロキノン系フロー電池 |
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JP6247778B2 (ja) | 2017-12-13 |
US10446867B2 (en) | 2019-10-15 |
EP3223354A4 (en) | 2018-07-04 |
EP3223354B1 (en) | 2019-11-13 |
CN105679985A (zh) | 2016-06-15 |
US20170025700A1 (en) | 2017-01-26 |
AU2015349218B2 (en) | 2021-01-21 |
AU2015349218A1 (en) | 2016-11-03 |
CN105679985B (zh) | 2019-02-01 |
WO2016078492A1 (zh) | 2016-05-26 |
EP3223354A1 (en) | 2017-09-27 |
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