JP2017507237A - 制御されたラジカル重合 - Google Patents

制御されたラジカル重合 Download PDF

Info

Publication number
JP2017507237A
JP2017507237A JP2016573674A JP2016573674A JP2017507237A JP 2017507237 A JP2017507237 A JP 2017507237A JP 2016573674 A JP2016573674 A JP 2016573674A JP 2016573674 A JP2016573674 A JP 2016573674A JP 2017507237 A JP2017507237 A JP 2017507237A
Authority
JP
Japan
Prior art keywords
alkyl
polymer
independently
phenyl
aryl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2016573674A
Other languages
English (en)
Japanese (ja)
Other versions
JP2017507237A5 (enExample
Inventor
デブリング ジョン
デブリング ジョン
ネスファドバ ペーター
ネスファドバ ペーター
フンゲンベルク クラウス−ディーター
フンゲンベルク クラウス−ディーター
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jon Debling
Klaus Dieter Hungenberg
Peter Nesvadba
BASF SE
Original Assignee
Jon Debling
Klaus Dieter Hungenberg
Peter Nesvadba
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jon Debling, Klaus Dieter Hungenberg, Peter Nesvadba, BASF SE filed Critical Jon Debling
Publication of JP2017507237A publication Critical patent/JP2017507237A/ja
Publication of JP2017507237A5 publication Critical patent/JP2017507237A5/ja
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/44—Iso-indoles; Hydrogenated iso-indoles
    • C07D209/46—Iso-indoles; Hydrogenated iso-indoles with an oxygen atom in position 1
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3415—Five-membered rings
    • C08K5/3417—Five-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
JP2016573674A 2014-03-07 2015-03-04 制御されたラジカル重合 Pending JP2017507237A (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201461949890P 2014-03-07 2014-03-07
US61/949,890 2014-03-07
US201562100364P 2015-01-06 2015-01-06
US62/100,364 2015-01-06
PCT/US2015/018710 WO2015134591A1 (en) 2014-03-07 2015-03-04 Controlled radical polymerization

Publications (2)

Publication Number Publication Date
JP2017507237A true JP2017507237A (ja) 2017-03-16
JP2017507237A5 JP2017507237A5 (enExample) 2018-04-12

Family

ID=54055835

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2016573674A Pending JP2017507237A (ja) 2014-03-07 2015-03-04 制御されたラジカル重合

Country Status (7)

Country Link
US (1) US20170015762A1 (enExample)
EP (1) EP3114150A4 (enExample)
JP (1) JP2017507237A (enExample)
KR (1) KR20170005403A (enExample)
CN (1) CN106604941A (enExample)
BR (1) BR112016020481A2 (enExample)
WO (1) WO2015134591A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019536853A (ja) * 2016-10-28 2019-12-19 フラウンホーファー−ゲゼルシャフト ツゥア フェアデルング デア アンゲヴァンドテン フォァシュング エー．ファウ． ニトロキシル精密重合によるポリマーの製造方法およびポリマー

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108368109B (zh) 2015-11-19 2021-11-23 巴斯夫欧洲公司 用于制备聚氨酯的催化剂
TWI887216B (zh) * 2018-11-12 2025-06-21 日商日東電工股份有限公司 偏光薄膜、積層偏光薄膜、影像顯示面板及影像顯示裝置
FR3101354A1 (fr) * 2019-10-01 2021-04-02 Arkema France Sous-couche neutre pour copolymère à blocs et empilement polymérique comprenant une telle sous-couche recouverte d’un film de copolymère à blocs
FR3101355A1 (fr) * 2019-10-01 2021-04-02 Arkema France Sous-couche neutre pour copolymère à blocs et empilement polymérique comprenant une telle sous-couche recouverte d’un film de copolymère à blocs

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001510208A (ja) * 1997-07-15 2001-07-31 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド ニトロソ化合物又はニトロン化合物から誘導されたアルコキシアミン化合物を含む重合可能な組成物
JP2002533548A (ja) * 1998-12-23 2002-10-08 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド 低い多分散性を有するポリマー状安定剤
JP2003534347A (ja) * 2000-05-19 2003-11-18 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド 重合開始剤としてのヒドロキシルアミンエステル
JP2003535080A (ja) * 2000-05-26 2003-11-25 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド 第二アミノオキシドからのアミンエーテルの合成方法
JP2005532442A (ja) * 2002-07-09 2005-10-27 ポリメーリ　エウローパ　ソシエタ　ペル　アチオニ ブロックコポリマーの製造方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4581429A (en) * 1983-07-11 1986-04-08 Commonwealth Scientific And Industrial Research Organization Polymerization process and polymers produced thereby

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001510208A (ja) * 1997-07-15 2001-07-31 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド ニトロソ化合物又はニトロン化合物から誘導されたアルコキシアミン化合物を含む重合可能な組成物
JP2002533548A (ja) * 1998-12-23 2002-10-08 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド 低い多分散性を有するポリマー状安定剤
JP2003534347A (ja) * 2000-05-19 2003-11-18 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド 重合開始剤としてのヒドロキシルアミンエステル
JP2003535080A (ja) * 2000-05-26 2003-11-25 チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド 第二アミノオキシドからのアミンエーテルの合成方法
JP2005532442A (ja) * 2002-07-09 2005-10-27 ポリメーリ　エウローパ　ソシエタ　ペル　アチオニ ブロックコポリマーの製造方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019536853A (ja) * 2016-10-28 2019-12-19 フラウンホーファー−ゲゼルシャフト ツゥア フェアデルング デア アンゲヴァンドテン フォァシュング エー．ファウ． ニトロキシル精密重合によるポリマーの製造方法およびポリマー
US11292859B2 (en) 2016-10-28 2022-04-05 Fraunhofer-Gesellschaft Zurförderung Der Angewandten Forschung E.V. Method for producing a polymer by nitroxyl-controlled polymerisation, and polymer
JP7177050B2 (ja) 2016-10-28 2022-11-22 フラウンホーファー－ゲゼルシャフト ツゥア フェアデルング デア アンゲヴァンドテン フォァシュング エー．ファウ． ニトロキシル精密重合によるポリマーの製造方法

Also Published As

Publication number Publication date
US20170015762A1 (en) 2017-01-19
CN106604941A (zh) 2017-04-26
KR20170005403A (ko) 2017-01-13
EP3114150A4 (en) 2017-11-22
EP3114150A1 (en) 2017-01-11
WO2015134591A1 (en) 2015-09-11
BR112016020481A2 (pt) 2018-06-05

Similar Documents

Publication Publication Date Title
JP2017507237A (ja) 制御されたラジカル重合
Eberhardt et al. RAFT polymerization of pentafluorophenyl methacrylate: preparation of reactive linear diblock copolymers
Dire et al. Nitroxide-mediated copolymerization of methacrylic acid and styrene to form amphiphilic diblock copolymers
De Brouwer et al. Controlled radical copolymerization of styrene and maleic anhydride and the synthesis of novel polyolefin‐based block copolymers by reversible addition–fragmentation chain‐transfer (RAFT) polymerization
NZ331313A (en) Branched polymer synthesis
Schumers et al. Are o‐nitrobenzyl (meth) acrylate monomers polymerizable by controlled‐radical polymerization?
Nilles et al. RAFT polymerization of activated 4‐vinylbenzoates
Lessard et al. Smart morpholine-functional statistical copolymers synthesized by nitroxide mediated polymerization
Lessard et al. Understanding the controlled polymerization of Methyl Methacrylate with low concentrations of 9-(4-Vinylbenzyl)-9 H-carbazole comonomer by nitroxide-mediated polymerization: The pivotal role of reactivity ratios
Liu et al. Living/controlled copolymerization of acrylates with nonactivated alkenes
Ponce‐Vargas et al. Preparation of poly (N‐vinylcaprolactam)(NVCL) and statistical copolymers of NVCL with variable cloud point temperature by using a trithiocarbonate RAFT agent
Hajiali et al. Nitroxide mediated polymerization of sustainably sourced isobornyl methacrylate and tridecyl methacrylate with acrylonitrile co‐monomer
Maksym et al. High pressure RAFT of sterically hindered ionic monomers. Studying relationship between rigidity of the polymer backbone and conductivity
Hui et al. Reverse iodine transfer polymerization (RITP) of chloroprene
Savelyeva et al. Pyrrolidone‐functional smart polymers via nitroxide‐mediated polymerization
Zhang et al. Synthesis and characterization of benzyl methacrylate/styrene random copolymers prepared by NMP
Hajiali et al. Incorporation of POSS to improve thermal stability of bio‐based polymethacrylates by nitroxide‐mediated polymerization: Polymerization kinetics and characterization
Zhao et al. Living/controlled radical copolymerization of N‐substituted maleimides with styrene in 1‐butyl‐3‐methylimidazolium hexafluorophosphate and anisole
Cheng et al. Polymerization and copolymerization of α‐alkylacrylic acids and characterization of their polymers
WO2023122807A1 (en) Degradable polymers for coatings, films, and adhesives
Vega-Rios et al. Controlled synthesis of block copolymers containing N-isopropylacrylamide by reversible addition-fragmentation chain-transfer (RAFT) polymerization
Maric et al. Versatility of a succinimidyl‐ester functional alkoxyamine for controlling acrylonitrile copolymerizations
Degirmenci et al. Synthesis of block copolymers by combined ultrasonic irradiation and reverse atom transfer radical polymerization processes
Yan et al. Kinetics of RAFT emulsion polymerization of styrene mediated by oligo (acrylic acid‐b‐styrene) trithiocarbonate
Mei et al. Nitroxide‐Mediated Polymerization of 2‐Hydroxyethyl Methacrylate (HEMA) Controlled with Low Concentrations of Acrylonitrile and Styrene

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20180302

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20180302

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20181213

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20190204

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20190930