JP2017109431A - 粘着テープ用基材の製造方法及び粘着テープの製造方法 - Google Patents
粘着テープ用基材の製造方法及び粘着テープの製造方法 Download PDFInfo
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- JP2017109431A JP2017109431A JP2015247332A JP2015247332A JP2017109431A JP 2017109431 A JP2017109431 A JP 2017109431A JP 2015247332 A JP2015247332 A JP 2015247332A JP 2015247332 A JP2015247332 A JP 2015247332A JP 2017109431 A JP2017109431 A JP 2017109431A
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- QRWZCJXEAOZAAW-UHFFFAOYSA-N n,n,2-trimethylprop-2-enamide Chemical compound CN(C)C(=O)C(C)=C QRWZCJXEAOZAAW-UHFFFAOYSA-N 0.000 description 1
- DFENKTCEEGOWLB-UHFFFAOYSA-N n,n-bis(methylamino)-2-methylidenepentanamide Chemical compound CCCC(=C)C(=O)N(NC)NC DFENKTCEEGOWLB-UHFFFAOYSA-N 0.000 description 1
- JMCVCHBBHPFWBF-UHFFFAOYSA-N n,n-diethyl-2-methylprop-2-enamide Chemical compound CCN(CC)C(=O)C(C)=C JMCVCHBBHPFWBF-UHFFFAOYSA-N 0.000 description 1
- OVHHHVAVHBHXAK-UHFFFAOYSA-N n,n-diethylprop-2-enamide Chemical compound CCN(CC)C(=O)C=C OVHHHVAVHBHXAK-UHFFFAOYSA-N 0.000 description 1
- 229940088644 n,n-dimethylacrylamide Drugs 0.000 description 1
- YLGYACDQVQQZSW-UHFFFAOYSA-N n,n-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 description 1
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 229940080818 propionamide Drugs 0.000 description 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
- 229940007718 zinc hydroxide Drugs 0.000 description 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Moulding By Coating Moulds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesive Tapes (AREA)
Abstract
Description
を使用することが、後述する好適な引張破断伸度及び引張破断強度を備え、薄型であっても任意の細幅形状に加工しやすく、被着体に対する追従性に優れ、かつ、絶縁性に優れた粘着テープを得るうえでより好ましい。
引張破断伸度は、450%以上であることが好ましく、600%以上であることが、薄型であっても任意の細幅形状に加工しやすく、被着体に対する追従性に優れ、かつ、絶縁性に優れた粘着テープを得るうえでより好ましい。前記引張破断伸度の上限は、1000%であることが好ましい。
白色の着色剤としては、コスト、入手性、絶縁性、発泡性ポリオレフィン系樹脂組成物を押し出す工程や発泡工程における温度に耐える耐熱性を備えた酸化アルミニウムや酸化亜鉛を使用することが好ましい。
サンプル注入量:100μl
溶離液:THF
流速:1.0ml/分
測定温度:40℃
本カラム:TSKgel GMHHR−H(20)2本
ガードカラム:TSKgel HXL−H
検出器:示差屈折計
スタンダードポリスチレン分子量:1万〜2000万(東ソー株式会社製)
攪拌機、還流冷却管、窒素導入管、温度計を備えた反応容器に、n−ブチルアクリレート80.94質量部、2−エチルヘキシルアクリレート5質量部、シクロヘキシルアクリレート10質量部、アクリル酸4質量部、4−ヒドロキシブチルアクリレート0.06質量部、及び、酢酸エチル200質量部を仕込み、攪拌下、窒素を吹き込みながら72℃まで昇温させた。
GPC法による分子量の測定は、東ソー株式会社製GPC装置(HLC−8320GPC)を用いて測定される、スタンダードポリスチレン換算値である。
サンプル注入量:100μl
溶離液:THF(テトラヒドロフラン)
流速:1.0ml/分
測定温度:40℃
本カラム:TSKgel GMHHR−H(20)2本
ガードカラム:TSKgel HXL−H
検出器:示差屈折計
スタンダードポリスチレン分子量:1万〜2000万(東ソー株式会社製)
1,6−ヘキサンジオール及びネオペンチルグリコールとアジピン酸とを反応させて得られた数平均分子量1500のポリエステルポリオール42.0質量部、及び1,4−ブタンジオールとアジピン酸とを反応させて得られた数平均分子量600のポリブチレンアジペートポリオール18.0質量部、トリメチロールプロパン0.5質量部を、酢酸エチルで1.7倍に希釈した。
前記水酸基を有するポリウレタン溶液(t−1)と、バーノックD−40(DIC(株)製、トリレンジイソシアネートのトリメチロールプロパンアダクト体、イソシアネート基含有率7質量%、不揮発分40質量%)8.25質量部とを混合したものを、大気圧下に10分静置する代わりに、ゲージ圧−0.09MPaの減圧下に10分静置すること以外は、実施例1と同様の方法で、2液硬化型組成物(T−2)〔不揮発分54質量%〕を得た。
前記水酸基を有するポリウレタン溶液(t−1)〔不揮発分55質量%〕の代わりに、不揮発分を63質量%に変更した水酸基を有するポリウレタン溶液(t−2)を使用すること以外は、実施例1と同様の方法で、2液硬化型組成物(T−3)〔不揮発分61質量%〕を得た。
前記水酸基を有するポリウレタン溶液(t−1)〔不揮発分55質量%〕の代わりに、不揮発分を63質量%に変更した水酸基を有するポリウレタン溶液(t−2)を使用すること、及び、前記水酸基を有するポリウレタン溶液(t−2)と、バーノックD−40(DIC(株)製、トリレンジイソシアネートのトリメチロールプロパンアダクト体、イソシアネート基含有率7質量%、不揮発分40質量%)8.25質量部とを混合したものを、大気圧下に10分静置する代わりに、ゲージ圧−0.09MPaの減圧下に10分静置すること以外は、実施例1と同様の方法で、2液硬化型組成物(T−4)〔不揮発分61質量%〕を得た。
1,6−ヘキサンジオール及びネオペンチルグリコールとアジピン酸とを反応させて得られた数平均分子量1500のポリエステルポリオール42.0質量部、及び1,4−ブタンジオールとアジピン酸とを反応させて得られた数平均分子量600のポリブチレンアジペートポリオール18.0質量部、トリメチロールプロパン0.5質量部を、酢酸エチルで1.7倍に希釈した。
前記水酸基を有するポリウレタン溶液(t−3)〔不揮発分50質量%〕の代わりに、不揮発分を65質量%に変更した水酸基を有するポリウレタン溶液(t−4)を使用すること以外は、実施例1と同様の方法で、2液硬化型組成物(T’−2)〔不揮発分63質量%〕を得た。
前記水酸基を有するポリウレタン溶液(t−3)〔不揮発分50質量%〕の代わりに、不揮発分を65質量%に変更した水酸基を有するポリウレタン溶液(t−4)を使用すること、及び、前記水酸基を有するポリウレタン溶液(t−4)と、バーノックD−40(DIC(株)製、トリレンジイソシアネートのトリメチロールプロパンアダクト体、イソシアネート基含有率7質量%、不揮発分40質量%)8.25質量部とを混合したものを、大気圧下に10分静置する代わりに、ゲージ圧−0.09MPaの減圧下に10分静置すること以外は、比較例1と同様の方法で、2液硬化型組成物(T’−3)〔不揮発分63質量%〕を得た。
前記水酸基を有するポリウレタン溶液(t−3)〔不揮発分50質量%〕の代わりに、不揮発分を70質量%に変更した水酸基を有するポリウレタン溶液(t−5)を使用すること以外は、実施例1と同様の方法で、2液硬化型組成物(T’−4)〔不揮発分68質量%〕を得た。
前記水酸基を有するポリウレタン溶液(t−3)〔不揮発分50質量%〕の代わりに、不揮発分を70質量%に変更した水酸基を有するポリウレタン溶液(t−5)を使用すること、及び、前記水酸基を有するポリウレタン溶液(t−5)と、バーノックD−40(DIC(株)製、トリレンジイソシアネートのトリメチロールプロパンアダクト体、イソシアネート基含有率7質量%、不揮発分40質量%)8.25質量部とを混合したものを、大気圧下に10分静置する代わりに、ゲージ圧−0.09MPaの減圧下に10分静置すること以外は、比較例1と同様の方法で、2液硬化型組成物(T’−5)〔不揮発分68質量%〕を得た。
2液硬化型組成物をガラス瓶に100g入れた。前記2液硬化型組成物の粘度を、温度23℃及び50%の測定環境下で、B型粘度計(東機産業株式会社製)を用いNo.4のローターで測定した。
前記粘着テープ用基材を10cm×10cmの正方形に裁断して得た試験片を3枚用意した。前記試験片を目視で観察し、2液硬化型組成物のはじきによってできた穴の個数を数えて、その平均個数を算出した。
〇:いずれの試験片にも、はじきによる穴が形成されていなかった。
×:いずれかの試験片に、はじきによる穴が1個以上あった。
前記粘着テープ用基材を1.0cm×1.0cmの正方形に裁断して得た試験片を3枚用意した。前記試験片を目視で観察し、気泡の個数を数え、その平均個数を算出した。
◎:いずれの試験片にも、気泡が存在しなかった。
〇:いずれかの試験片に、1個以上50個未満の気泡が確認できた。
×:いずれかの試験片に、50個以上の気泡が確認できた。
Claims (7)
- 23℃における粘度が6000mPa・s〜20000mPa・sの範囲である樹脂組成物を剥離ライナーの表面に塗工し乾燥する工程を有することを特徴とする粘着テープ用基材の製造方法。
- 23℃における粘度が6000mPa・s〜20000mPa・sの範囲である樹脂組成物を減圧環境下に放置する工程を有する請求項1に記載の粘着テープ用基材の製造方法。
- 前記樹脂組成物がポリウレタンを含有するものである請求項1または2に記載の粘着テープ用基材の製造方法。
- 前記樹脂組成物が2液硬化型ポリウレタン組成物である請求項1または2に記載の粘着テープ用基材の製造方法。
- 前記樹脂組成物が溶媒を含有するものであり、前記溶媒の全量に対するアミド系有機溶剤及び芳香族炭化水素系溶剤の少なくとも1種の含有量が合計0質量%〜50質量%である請求項1〜4のいずれか1項に記載の粘着テープ用基材の製造方法。
- 粘着テープ用基材の厚さが10μm〜100μmの範囲である請求項1〜5のいずれか1項に記載の粘着テープ用基材の製造方法。
- 23℃における粘度が6000mPa・s〜20000mPa・sの範囲である樹脂組成物を剥離ライナーの表面に塗工し乾燥する工程を経ることによって粘着テープ用基材を製造した後、前記粘着テープ用基材の片面または両面に粘着剤層を設けることを特徴とする粘着テープの製造方法。
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JP2017226757A (ja) * | 2016-06-22 | 2017-12-28 | Dic株式会社 | 粘着テープ及びその製造方法、ならびに、物品及び携帯電子端末 |
JP2022508158A (ja) * | 2018-11-21 | 2022-01-19 | エントロテック・インコーポレーテッド | 物品の凹面状表面のトポグラフィーへの適用に有用な高分子シートとそれに関連する方法 |
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JP2014065813A (ja) * | 2012-09-26 | 2014-04-17 | Nitto Denko Corp | シート状伸長性有機基材 |
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Cited By (4)
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JP2017226757A (ja) * | 2016-06-22 | 2017-12-28 | Dic株式会社 | 粘着テープ及びその製造方法、ならびに、物品及び携帯電子端末 |
JP2022508158A (ja) * | 2018-11-21 | 2022-01-19 | エントロテック・インコーポレーテッド | 物品の凹面状表面のトポグラフィーへの適用に有用な高分子シートとそれに関連する方法 |
JP7419370B2 (ja) | 2018-11-21 | 2024-01-22 | ピーピージー・アドバンスト・サーフェス・テクノロジーズ・エルエルシー | 物品の凹面状表面のトポグラフィーへの適用に有用な高分子シートとそれに関連する方法 |
US12065549B2 (en) | 2018-11-21 | 2024-08-20 | Ppg Advanced Surface Technologies, Llc | Polymeric sheet useful for application to concave surface topographies of articles and related methods |
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