JP2016522857A - 高濃度で錯化剤を含有する水溶液 - Google Patents
高濃度で錯化剤を含有する水溶液 Download PDFInfo
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- JP2016522857A JP2016522857A JP2016515703A JP2016515703A JP2016522857A JP 2016522857 A JP2016522857 A JP 2016522857A JP 2016515703 A JP2016515703 A JP 2016515703A JP 2016515703 A JP2016515703 A JP 2016515703A JP 2016522857 A JP2016522857 A JP 2016522857A
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- aqueous solution
- acid
- salt
- complexing agent
- alkali metal
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- 239000007864 aqueous solution Substances 0.000 title claims abstract description 73
- 239000008139 complexing agent Substances 0.000 title claims abstract description 45
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 26
- -1 alkali metal salt Chemical class 0.000 claims abstract description 25
- 150000003839 salts Chemical class 0.000 claims abstract description 25
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 claims abstract description 8
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims abstract description 8
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 235000013922 glutamic acid Nutrition 0.000 claims abstract description 8
- 239000004220 glutamic acid Substances 0.000 claims abstract description 8
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims abstract description 4
- 150000007524 organic acids Chemical class 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 12
- 239000004094 surface-active agent Substances 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 239000002202 Polyethylene glycol Substances 0.000 claims description 10
- 229920001223 polyethylene glycol Polymers 0.000 claims description 10
- 238000009472 formulation Methods 0.000 claims description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- 238000004851 dishwashing Methods 0.000 claims description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical class OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- 235000011054 acetic acid Nutrition 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 239000001630 malic acid Substances 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- PDIZYYQQWUOPPK-UHFFFAOYSA-N acetic acid;2-(methylamino)acetic acid Chemical compound CC(O)=O.CC(O)=O.CNCC(O)=O PDIZYYQQWUOPPK-UHFFFAOYSA-N 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000007787 solid Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 7
- 238000001556 precipitation Methods 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 150000007529 inorganic bases Chemical class 0.000 description 3
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 235000011056 potassium acetate Nutrition 0.000 description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 2
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3409—Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/264—Aldehydes; Ketones; Acetals or ketals
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3245—Aminoacids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/34—Organic compounds containing sulfur
Abstract
Description
(A)30から60質量%の範囲内の、メチルグリシン二酢酸のアルカリ金属塩およびグルタミン酸二酢酸のアルカリ金属塩から選択される錯化剤と、
(B)1から25質量%の範囲内の、スルホン酸または有機酸の少なくとも1種の塩と
を含む水溶液であって、百分率がそれぞれの水溶液の総質量に対し、前記水溶液が界面活性剤を含まない、水溶液を対象とする。
(A)30から60質量%の範囲内の錯化剤であって、以後、「錯化剤(A)」とも称される、メチルグリシン二酢酸のアルカリ金属塩およびグルタミン酸二酢酸のアルカリ金属塩から選択される錯化剤と、
(B)以後「塩(B)」とも称される、1から25質量%の範囲内の、スルホン酸または有機酸の少なくとも1種の塩とを含有し、前記水溶液が界面活性剤を含まず、百分率は本発明による水溶液の総質量に対する。
(B)1から25質量%の範囲内の、好ましくは3から15質量%の塩(B)
をさらに含む。
(C)400から10,000g/molの範囲内の、好ましくは600から6,000g/molの平均分子量Mnを有する少なくとも1種のポリエチレングリコールであって、以後「ポリエチレングリコール(C)」とも称される、ポリエチレングリコール
をさらに含む。
錯化剤(A.1):MGDAの三ナトリウム塩、40質量%水溶液、pH値:13として提供
塩(B.1):酢酸ナトリウム、固体
塩(B.2):酢酸カリウム、固体
プラスチック栓付きの25mlガラス瓶に、22.5gの上記(A.1)の40質量%水溶液を入れた。これを75℃に加温した。前記溶液に、繰り返し振とうしながら、2.5gの(B.1)を加えた。生じた水溶液の総固形分は、46質量%であった。これは澄明な溶液であり、23℃で30日後でも、MGDAの結晶化または沈殿の兆候を示さなかった。
プラスチック栓付きの25mlガラス瓶に、20gの上記(A.1)の40質量%水溶液を入れた。これを75℃に加温した。前記溶液に、繰り返し振とうしながら、5gの(B.1)を加えた。生じた水溶液の総固形分は、52質量%であった。これは澄明な溶液であり、23℃で30日後でも、MGDAの結晶化または沈殿の兆候を示さなかった。
プラスチック栓付きの25mlガラス瓶に、22.5gの上記(A.1)の40質量%水溶液を入れた。これを75℃に加温した。前記溶液に、繰り返し振とうしながら、2.5gの(B.2)を加えた。生じた水溶液の総固形分は、46質量%であった。これは澄明な溶液であり、23℃で30日後でも、MGDAの結晶化または沈殿の兆候を示さなかった。
プラスチック栓付きの25mlガラス瓶に、20gの上記(A.1)の40質量%水溶液を入れた。これを75℃に加温した。前記溶液に、繰り返し振とうしながら、5gの(B.2)を加えた。生じた水溶液の総固形分は、52質量%であった。これは澄明な溶液であり、23℃で30日後でも、MGDAの結晶化または沈殿の兆候を示さなかった。
Claims (8)
- (A)30から60質量%の範囲内の、メチルグリシン二酢酸のアルカリ金属塩およびグルタミン酸二酢酸のアルカリ金属塩から選択される錯化剤と、
(B)1から25質量%の範囲内の、スルホン酸または有機酸の少なくとも1種の塩と
を含む水溶液であって、百分率がそれぞれの水溶液の総質量に対し、前記水溶液が界面活性剤を含まない、水溶液。 - 9から13の範囲内のpH値を有する、請求項1に記載の水溶液。
- (B)が、酢酸、酒石酸、乳酸、マレイン酸、フマル酸、およびリンゴ酸のアルカリ金属塩から選択される、請求項1または2に記載の水溶液。
- 塩(B)がメチルスルホン酸のアルカリ金属塩から選択される、請求項1から3のいずれか一項に記載の水溶液。
- (C)400から10,000g/molの範囲内の平均分子量Mnを有する少なくとも1種のポリエチレングリコール
をさらに含む、請求項1から4のいずれか一項に記載の水溶液。 - 請求項1から5のいずれか一項に記載の水溶液を製造するための方法であって、錯化剤(A)の水溶液と塩(B)とを合わせる工程を含む方法。
- ランドリーケアまたは食器洗浄用配合物を製造するための、請求項1から5のいずれか一項に記載の水溶液を使用する方法。
- 管または容器中で輸送するための、請求項1から5のいずれか一項に記載の水溶液を使用する方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13169341.8 | 2013-05-27 | ||
EP13169341 | 2013-05-27 | ||
PCT/EP2014/059727 WO2014191199A1 (en) | 2013-05-27 | 2014-05-13 | Aqueous solutions containing a complexing agent in high concentration |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2016522857A true JP2016522857A (ja) | 2016-08-04 |
JP2016522857A5 JP2016522857A5 (ja) | 2017-06-29 |
Family
ID=48534208
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016515703A Pending JP2016522857A (ja) | 2013-05-27 | 2014-05-13 | 高濃度で錯化剤を含有する水溶液 |
Country Status (14)
Country | Link |
---|---|
US (1) | US9850453B2 (ja) |
EP (1) | EP3004316B1 (ja) |
JP (1) | JP2016522857A (ja) |
KR (1) | KR20160012209A (ja) |
CN (1) | CN105247034B (ja) |
BR (1) | BR112015029544A2 (ja) |
CA (1) | CA2912309A1 (ja) |
ES (1) | ES2628161T3 (ja) |
HK (1) | HK1219972A1 (ja) |
MX (1) | MX2015016424A (ja) |
MY (1) | MY169131A (ja) |
PL (1) | PL3004316T3 (ja) |
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EP3004311B1 (en) * | 2013-05-27 | 2017-04-05 | Basf Se | Aqueous solutions containing a complexing agent in high concentration |
JP7086604B6 (ja) | 2014-11-26 | 2022-07-04 | ビーエーエスエフ ソシエタス・ヨーロピア | 錯化剤の組み合わせを含有する水溶液 |
KR20170128398A (ko) | 2015-03-12 | 2017-11-22 | 바스프 에스이 | 거울상이성질체의 혼합물의 제조 방법, 및 거울상이성질체의 혼합물 |
WO2017097637A1 (en) * | 2015-12-08 | 2017-06-15 | Basf Se | Aqueous solution containing a complexing agent in high concentrations |
WO2018197249A1 (en) | 2017-04-27 | 2018-11-01 | Basf Se | Container comprising a detergent composition containing salts of mgda and glda |
US11713435B2 (en) | 2018-01-30 | 2023-08-01 | Eastman Chemical Company | Aminocarboxylate chelating agents and detergent compositions containing them |
WO2023004106A1 (en) | 2021-07-23 | 2023-01-26 | Ascend Performance Materials Operations Llc | Aqueous solutions containing amino carboxylic acid chelators |
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- 2014-05-13 CA CA2912309A patent/CA2912309A1/en not_active Abandoned
- 2014-05-13 EP EP14726333.9A patent/EP3004316B1/en not_active Revoked
- 2014-05-13 WO PCT/EP2014/059727 patent/WO2014191199A1/en active Application Filing
- 2014-05-13 JP JP2016515703A patent/JP2016522857A/ja active Pending
- 2014-05-13 MY MYPI2015002796A patent/MY169131A/en unknown
- 2014-05-13 US US14/893,859 patent/US9850453B2/en not_active Expired - Fee Related
- 2014-05-13 MX MX2015016424A patent/MX2015016424A/es unknown
- 2014-05-13 KR KR1020157036430A patent/KR20160012209A/ko not_active Application Discontinuation
- 2014-05-13 PL PL14726333T patent/PL3004316T3/pl unknown
- 2014-05-13 CN CN201480030285.1A patent/CN105247034B/zh not_active Expired - Fee Related
- 2014-05-13 BR BR112015029544A patent/BR112015029544A2/pt not_active Application Discontinuation
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2016
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Also Published As
Publication number | Publication date |
---|---|
CN105247034A (zh) | 2016-01-13 |
WO2014191199A1 (en) | 2014-12-04 |
MY169131A (en) | 2019-02-18 |
CA2912309A1 (en) | 2014-12-04 |
ES2628161T3 (es) | 2017-08-01 |
EP3004316B1 (en) | 2017-03-22 |
BR112015029544A2 (pt) | 2017-07-25 |
HK1219972A1 (zh) | 2017-04-21 |
KR20160012209A (ko) | 2016-02-02 |
US9850453B2 (en) | 2017-12-26 |
PL3004316T3 (pl) | 2017-09-29 |
RU2659787C2 (ru) | 2018-07-04 |
US20160130531A1 (en) | 2016-05-12 |
EP3004316A1 (en) | 2016-04-13 |
RU2015155965A (ru) | 2017-07-04 |
MX2015016424A (es) | 2016-03-03 |
CN105247034B (zh) | 2018-10-16 |
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