JP2016504477A - 繊維強化複合材料の製造方法 - Google Patents
繊維強化複合材料の製造方法 Download PDFInfo
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- JP2016504477A JP2016504477A JP2015554163A JP2015554163A JP2016504477A JP 2016504477 A JP2016504477 A JP 2016504477A JP 2015554163 A JP2015554163 A JP 2015554163A JP 2015554163 A JP2015554163 A JP 2015554163A JP 2016504477 A JP2016504477 A JP 2016504477A
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- resin
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- peroxide
- transition metal
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/045—Reinforcing macromolecular compounds with loose or coherent fibrous material with vegetable or animal fibrous material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
- C08K5/24—Derivatives of hydrazine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L45/00—Compositions of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
- C08J2363/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/06—Unsaturated polyesters
Abstract
Description
シノライト(Synolite) 1967−X1 − 予備促進化されていないDCPDポリエステル樹脂(例 DSM社)
ブタノクス(Butanox)(登録商標)M50 − 活性酸素の含有量8.9重量%であるメチルエチルケトンペルオキシド(フタル酸ジメチル中の50重量%;例 アクゾノーベル社)
ヌーリーアクト(Nouryact)(商標)CF32 − 鉄ベースの促進剤溶液 例 アクゾノーベル社
アクセルレーター(Accelerator) NL49−P − コバルト(II)2−エチルヘキサノエート、溶媒混合液中にコバルトが1%(例 アクゾノーベル社)
反応抑制剤 NLD−20 − 2,6−ジ−t−ブチル−4−メチルフェノール系反応抑制剤(例 アクゾノーベル社)
「そのままの状態」の不織布の亜麻 − 温度13.9℃、相対湿度71%で保管した後、約9.3重量%の水を含有する「前処理していない」亜麻
乾燥させた不織布の亜麻−「そのままの状態」の亜麻と比較して9.3重量%の重量損失となるように105℃のハロゲン/熱風乾燥機中で1時間乾燥させた亜麻
濡れた不織布の亜麻−20℃で100%RH(相対湿度)の密閉容器にて96時間保管した後に約14重量%の水を含む水蒸気で飽和した亜麻
Claims (15)
- (i)ラジカル硬化性樹脂、(ii)繊維の総重量を基準として全含水量が0.5〜20重量%である繊維、(iii)マンガン化合物、鉄化合物、および銅化合物から選択される少なくとも1種の遷移金属化合物、および、(iv)過酸化物を接触させる工程を含む繊維強化複合材料の製造方法。
- 前記繊維が、亜麻、黄麻、洋麻、工業用大麻、亜麻、竹およびラミー麻から選択される天然繊維である、請求項1に記載の製造方法。
- 前記樹脂が、不飽和ポリエステル樹脂、ビニルエステル樹脂、(メタ)アクリレート樹脂である、請求項1または2に記載の製造方法。
- 前記遷移金属化合物が、銅化合物、鉄化合物またはこれらの組み合わせである、請求項1から3のいずれか一項に記載の製造方法。
- 前記過酸化物が、有機ヒドロペルオキシド、ケトンペルオキシド、ペルオキシカーボネート、および、ペルオキシエステルからなる群から選択される、請求項1から4のいずれか一項に記載の製造方法。
- 前記過酸化物が、ケトンペルオキシドである、請求項5に記載の製造方法。
- 前記ラジカル硬化性組成物が、前記遷移金属化合物を除いた、アルカリまたはアルカリ土類金属化合物、リン含有化合物および/または1,3−ジケトンを含有する溶液の形態の樹脂に、前記遷移金属化合物を添加することによって調製される、請求項1から6のいずれか一項に記載の製造方法。
- 1〜75mmol/kg樹脂の前記遷移金属化合物を前記樹脂に添加する、請求項1から7のいずれか一項に記載の製造方法。
- (i)ラジカル硬化性樹脂、(ii)繊維の総重量を基準として全含水量が0.5〜20重量%である繊維、および、(iii)マンガン化合物、鉄化合物および銅化合物から選択される少なくとも1種の遷移金属化合物を含むラジカル硬化性組成物。
- 前記樹脂が、不飽和ポリエステル樹脂、ビニルエステル樹脂、または、(メタ)アクリルレート樹脂である、請求項9に記載のラジカル硬化性組成物。
- 前記遷移金属化合物が、銅化合物、鉄化合物またはこれらの混合物である、請求項9または10に記載のラジカル硬化性組成物。
- アルカリまたはアルカリ土類金属化合物、リン含有化合物および/または1,3−ジケトンをさらに含む、請求項9から11のいずれか一項に記載のラジカル硬化性組成物。
- 成分Aおよび成分Bを含む2成分系組成物であって、成分Aは請求項9から12のいずれか一項に記載のラジカル硬化性組成物を含有し、成分Bは過酸化物を含有する、2成分系組成物。
- 前記過酸化物が、有機ヒドロペルオキシド、ケトンペルオキシド、ペルオキシカーボネートおよびペルオキシエステルからなる群から選択される、請求項13に記載の2成分系組成物。
- 前記過酸化物がケトンペルオキシドである、請求項14に記載の2成分系組成物。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13153074 | 2013-01-29 | ||
EP13153074.3 | 2013-01-29 | ||
US201361760818P | 2013-02-05 | 2013-02-05 | |
US61/760,818 | 2013-02-05 | ||
PCT/EP2014/051463 WO2014118101A1 (en) | 2013-01-29 | 2014-01-27 | Process for preparing a fiber-reinforced composite material |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2016504477A true JP2016504477A (ja) | 2016-02-12 |
JP6082823B2 JP6082823B2 (ja) | 2017-02-15 |
Family
ID=47628023
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015554163A Expired - Fee Related JP6082823B2 (ja) | 2013-01-29 | 2014-01-27 | 繊維強化複合材料の製造方法 |
Country Status (21)
Country | Link |
---|---|
US (1) | US9873795B2 (ja) |
EP (1) | EP2951233B1 (ja) |
JP (1) | JP6082823B2 (ja) |
KR (1) | KR20150114466A (ja) |
CN (1) | CN104955881B (ja) |
AR (1) | AR094669A1 (ja) |
AU (1) | AU2014211548B2 (ja) |
BR (1) | BR112015016781A2 (ja) |
CA (1) | CA2894825A1 (ja) |
DK (1) | DK2951233T3 (ja) |
ES (1) | ES2616904T3 (ja) |
IL (1) | IL239473A (ja) |
MX (1) | MX2015009462A (ja) |
MY (1) | MY173381A (ja) |
PH (1) | PH12015501553B1 (ja) |
PL (1) | PL2951233T3 (ja) |
RU (1) | RU2653695C2 (ja) |
SI (1) | SI2951233T1 (ja) |
TW (1) | TWI613235B (ja) |
WO (1) | WO2014118101A1 (ja) |
ZA (1) | ZA201504651B (ja) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3464428B1 (en) * | 2016-05-24 | 2020-10-14 | Green Composites B.V. | Natural fibre-reinforced composite material |
BR112020025244A2 (pt) * | 2018-06-12 | 2021-03-09 | Nouryon Chemicals International B.V. | Processo de produção de artigos compostos e formulação de peróxido orgânico |
NL2027367B1 (en) | 2021-01-22 | 2022-08-05 | Green Composites B V | Fibre-reinforced composite material |
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JP2003049001A (ja) * | 2001-08-02 | 2003-02-21 | Hitachi Chem Co Ltd | シートモールディングコンパウンド及びそれを用いた成形品 |
JP2007138361A (ja) * | 2005-11-22 | 2007-06-07 | Kurabo Ind Ltd | 繊維強化熱可塑性樹脂成形体 |
JP2011256218A (ja) * | 2010-06-04 | 2011-12-22 | Panasonic Electric Works Co Ltd | シートモールディングコンパウンドの製造方法とそれに用いる強化繊維 |
WO2012126918A1 (en) * | 2011-03-24 | 2012-09-27 | Akzo Nobel Chemicals International B.V. | Accelerator for curing resins |
WO2012126917A1 (en) * | 2011-03-24 | 2012-09-27 | Akzo Nobel Chemicals International B.V. | Accelerator for curing resins |
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FR2603521B1 (fr) * | 1986-09-04 | 1989-01-13 | Du Pin Cellulose | Materiaux composites a base d'une matrice de resine polyester renforcee par des fibres cellulosiques discontinues et procede de fabrication |
US5830395A (en) * | 1997-08-12 | 1998-11-03 | E. I. Du Pont De Nemours And Company | Process for making a uniform dispersion of aramid fibers and polymer |
CN1315471A (zh) * | 2000-03-31 | 2001-10-03 | 王友桐 | 植物纤维复合材料、其制品及其制造方法 |
DE10360808B4 (de) * | 2003-12-19 | 2005-10-27 | Airbus Deutschland Gmbh | Faserverstärkter metallischer Verbundwerkstoff |
US8039559B2 (en) * | 2006-07-06 | 2011-10-18 | Dsm Ip Assets B.V. | Unsaturated polyester resin or vinyl ester resin compositions |
WO2008003498A1 (en) | 2006-07-06 | 2008-01-10 | Dsm Ip Assets B.V. | Unsaturated polyester resin or vinyl ester resin compositions |
PL2125947T3 (pl) * | 2007-02-23 | 2019-06-28 | Basf Se | Materiały kompozytowe i sposób ich wytwarzania |
US20090321981A1 (en) * | 2008-01-15 | 2009-12-31 | RheTech, Inc. | Cellulosic inclusion thermoplastic composition and molding thereof |
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US8487052B2 (en) * | 2009-08-17 | 2013-07-16 | Dic Corporation | Resin composition for fiber-reinforced composite material, cured product thereof, fiber-reinforced composite material, molding of fiber-reinforced resin, and process for production thereof |
EP2343336A1 (en) | 2010-01-06 | 2011-07-13 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Curing liquids |
PT2652025T (pt) | 2010-12-15 | 2018-11-02 | Ppg Europe B V | Composição secante e a sua utilização |
CN102858879B (zh) * | 2011-04-12 | 2013-12-04 | 三菱瓦斯化学株式会社 | 聚酰胺树脂系复合材料及其制造方法 |
KR101967724B1 (ko) | 2012-08-29 | 2019-04-10 | 아크조 노벨 케미칼즈 인터내셔널 비.브이. | 수지 경화용 철계 가속화제 |
UY35191A (es) | 2012-12-18 | 2014-07-31 | Akzo Nobel Coatings Int Bv | Secante para composiciones de recubrimiento autooxidables |
-
2014
- 2014-01-27 RU RU2015135572A patent/RU2653695C2/ru active
- 2014-01-27 MY MYPI2015702368A patent/MY173381A/en unknown
- 2014-01-27 EP EP14701736.2A patent/EP2951233B1/en active Active
- 2014-01-27 JP JP2015554163A patent/JP6082823B2/ja not_active Expired - Fee Related
- 2014-01-27 SI SI201430165A patent/SI2951233T1/sl unknown
- 2014-01-27 US US14/761,137 patent/US9873795B2/en not_active Expired - Fee Related
- 2014-01-27 CN CN201480005591.XA patent/CN104955881B/zh not_active Expired - Fee Related
- 2014-01-27 KR KR1020157017879A patent/KR20150114466A/ko not_active Application Discontinuation
- 2014-01-27 DK DK14701736.2T patent/DK2951233T3/en active
- 2014-01-27 AU AU2014211548A patent/AU2014211548B2/en not_active Ceased
- 2014-01-27 MX MX2015009462A patent/MX2015009462A/es active IP Right Grant
- 2014-01-27 WO PCT/EP2014/051463 patent/WO2014118101A1/en active Application Filing
- 2014-01-27 ES ES14701736.2T patent/ES2616904T3/es active Active
- 2014-01-27 CA CA2894825A patent/CA2894825A1/en not_active Abandoned
- 2014-01-27 BR BR112015016781A patent/BR112015016781A2/pt active Search and Examination
- 2014-01-27 PL PL14701736T patent/PL2951233T3/pl unknown
- 2014-01-28 TW TW103103281A patent/TWI613235B/zh not_active IP Right Cessation
- 2014-01-29 AR ARP140100284A patent/AR094669A1/es active IP Right Grant
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2015
- 2015-06-17 IL IL239473A patent/IL239473A/en not_active IP Right Cessation
- 2015-06-26 ZA ZA2015/04651A patent/ZA201504651B/en unknown
- 2015-07-10 PH PH12015501553A patent/PH12015501553B1/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2003049001A (ja) * | 2001-08-02 | 2003-02-21 | Hitachi Chem Co Ltd | シートモールディングコンパウンド及びそれを用いた成形品 |
JP2007138361A (ja) * | 2005-11-22 | 2007-06-07 | Kurabo Ind Ltd | 繊維強化熱可塑性樹脂成形体 |
JP2011256218A (ja) * | 2010-06-04 | 2011-12-22 | Panasonic Electric Works Co Ltd | シートモールディングコンパウンドの製造方法とそれに用いる強化繊維 |
WO2012126918A1 (en) * | 2011-03-24 | 2012-09-27 | Akzo Nobel Chemicals International B.V. | Accelerator for curing resins |
WO2012126917A1 (en) * | 2011-03-24 | 2012-09-27 | Akzo Nobel Chemicals International B.V. | Accelerator for curing resins |
Also Published As
Publication number | Publication date |
---|---|
ZA201504651B (en) | 2016-07-27 |
PH12015501553A1 (en) | 2015-09-21 |
PH12015501553B1 (en) | 2015-09-21 |
CA2894825A1 (en) | 2014-08-07 |
MY173381A (en) | 2020-01-21 |
DK2951233T3 (en) | 2017-03-13 |
IL239473A (en) | 2017-05-29 |
AU2014211548B2 (en) | 2017-02-23 |
AU2014211548A1 (en) | 2015-07-02 |
RU2015135572A (ru) | 2017-03-07 |
PL2951233T3 (pl) | 2017-08-31 |
TW201434888A (zh) | 2014-09-16 |
TWI613235B (zh) | 2018-02-01 |
AR094669A1 (es) | 2015-08-19 |
US9873795B2 (en) | 2018-01-23 |
JP6082823B2 (ja) | 2017-02-15 |
MX2015009462A (es) | 2015-09-24 |
CN104955881B (zh) | 2018-04-06 |
SI2951233T1 (sl) | 2017-04-26 |
EP2951233B1 (en) | 2016-12-14 |
EP2951233A1 (en) | 2015-12-09 |
KR20150114466A (ko) | 2015-10-12 |
CN104955881A (zh) | 2015-09-30 |
US20150322264A1 (en) | 2015-11-12 |
ES2616904T3 (es) | 2017-06-14 |
BR112015016781A2 (pt) | 2017-07-11 |
WO2014118101A1 (en) | 2014-08-07 |
IL239473A0 (en) | 2015-07-30 |
RU2653695C2 (ru) | 2018-05-14 |
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