JP2015535825A5 - - Google Patents
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- Publication number
- JP2015535825A5 JP2015535825A5 JP2015533059A JP2015533059A JP2015535825A5 JP 2015535825 A5 JP2015535825 A5 JP 2015535825A5 JP 2015533059 A JP2015533059 A JP 2015533059A JP 2015533059 A JP2015533059 A JP 2015533059A JP 2015535825 A5 JP2015535825 A5 JP 2015535825A5
- Authority
- JP
- Japan
- Prior art keywords
- alkali metal
- electrochemical
- anolyte
- feedstock
- oxalate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 28
- 239000000047 product Substances 0.000 description 19
- 229910052783 alkali metal Inorganic materials 0.000 description 18
- -1 alkali metal oxalate Chemical class 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 16
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 15
- 239000002253 acid Substances 0.000 description 15
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 14
- 238000000034 method Methods 0.000 description 14
- 238000006722 reduction reaction Methods 0.000 description 14
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 12
- 235000006408 oxalic acid Nutrition 0.000 description 9
- 229910002092 carbon dioxide Inorganic materials 0.000 description 7
- 239000001569 carbon dioxide Substances 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- WFIZEGIEIOHZCP-UHFFFAOYSA-M potassium formate Chemical compound [K+].[O-]C=O WFIZEGIEIOHZCP-UHFFFAOYSA-M 0.000 description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 4
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 description 4
- 229910000039 hydrogen halide Inorganic materials 0.000 description 4
- 239000012433 hydrogen halide Substances 0.000 description 4
- 238000005341 cation exchange Methods 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 229910000042 hydrogen bromide Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000003014 ion exchange membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
Applications Claiming Priority (23)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261703238P | 2012-09-19 | 2012-09-19 | |
| US201261703232P | 2012-09-19 | 2012-09-19 | |
| US201261703231P | 2012-09-19 | 2012-09-19 | |
| US201261703229P | 2012-09-19 | 2012-09-19 | |
| US201261703175P | 2012-09-19 | 2012-09-19 | |
| US201261703158P | 2012-09-19 | 2012-09-19 | |
| US201261703187P | 2012-09-19 | 2012-09-19 | |
| US201261703234P | 2012-09-19 | 2012-09-19 | |
| US61/703,231 | 2012-09-19 | ||
| US61/703,187 | 2012-09-19 | ||
| US61/703,232 | 2012-09-19 | ||
| US61/703,158 | 2012-09-19 | ||
| US61/703,229 | 2012-09-19 | ||
| US61/703,175 | 2012-09-19 | ||
| US61/703,238 | 2012-09-19 | ||
| US61/703,234 | 2012-09-19 | ||
| US201261715060P | 2012-10-17 | 2012-10-17 | |
| US61/715,060 | 2012-10-17 | ||
| US201261720670P | 2012-10-31 | 2012-10-31 | |
| US61/720,670 | 2012-10-31 | ||
| US13/724,339 | 2012-12-21 | ||
| US13/724,339 US9175407B2 (en) | 2012-07-26 | 2012-12-21 | Integrated process for producing carboxylic acids from carbon dioxide |
| PCT/US2013/053566 WO2014046791A1 (en) | 2012-09-19 | 2013-08-05 | Integrated process for producing carboxylic acids from carbon dioxide |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015535825A JP2015535825A (ja) | 2015-12-17 |
| JP2015535825A5 true JP2015535825A5 (enExample) | 2018-01-18 |
| JP6333263B2 JP6333263B2 (ja) | 2018-05-30 |
Family
ID=50341843
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015533059A Active JP6333263B2 (ja) | 2012-09-19 | 2013-08-05 | 二酸化炭素からカルボン酸を生成する統合的方法 |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP2898117B1 (enExample) |
| JP (1) | JP6333263B2 (enExample) |
| KR (1) | KR20150056627A (enExample) |
| CN (1) | CN104919088A (enExample) |
| AU (1) | AU2013318500B8 (enExample) |
| BR (1) | BR112015006193A2 (enExample) |
| CA (1) | CA2883437C (enExample) |
| DK (1) | DK2898117T3 (enExample) |
| ES (1) | ES2655423T3 (enExample) |
| SA (1) | SA515360158B1 (enExample) |
| WO (1) | WO2014046791A1 (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2950294C (en) * | 2014-05-29 | 2022-07-19 | Liquid Light, Inc. | Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode |
| KR101738590B1 (ko) | 2015-07-14 | 2017-06-09 | 한국에너지기술연구원 | 이산화탄소를 전기환원시켜 이산화탄소의 환원 생성물을 제조하는 방법 및 장치 |
| CA3011375A1 (en) * | 2016-01-13 | 2017-07-20 | Avantium Knowledge Centre B.V. | Process for producing formic acid and lactic acid |
| US10822709B2 (en) | 2016-05-03 | 2020-11-03 | Opus 12 Incorporated | Reactor with advanced architecture for the electrochemical reaction of CO2, CO and other chemical compounds |
| US12359325B2 (en) | 2016-05-03 | 2025-07-15 | Twelve Benefit Corporation | Membrane electrode assembly for COx reduction |
| JP6636885B2 (ja) | 2016-09-12 | 2020-01-29 | 株式会社東芝 | 還元触媒および還元反応装置 |
| CN110088360A (zh) * | 2016-11-24 | 2019-08-02 | 阿凡田知识中心有限公司 | 方法 |
| JP6845114B2 (ja) * | 2017-09-20 | 2021-03-17 | 株式会社東芝 | 二酸化炭素電解装置および二酸化炭素電解方法 |
| GB201811785D0 (en) * | 2018-07-19 | 2018-09-05 | Univ Surrey | A continuous process for sustainable production of hydrogen |
| US11578415B2 (en) * | 2018-11-28 | 2023-02-14 | Twelve Benefit Corporation | Electrolyzer and method of use |
| EP3899092A1 (en) | 2018-12-18 | 2021-10-27 | Opus 12 Incorporated | Electrolyzer and method of use |
| KR102331686B1 (ko) * | 2019-03-08 | 2021-11-30 | 서강대학교산학협력단 | 이산화탄소의 옥살산 전환 전기화학적 공정 |
| JP7204620B2 (ja) * | 2019-09-17 | 2023-01-16 | 株式会社東芝 | 電気化学反応装置 |
| KR20260100871A (ko) | 2019-11-25 | 2026-06-30 | 트웰브 베네핏 코포레이션 | COx 환원을 위한 막 전극 조립체 |
| EP4232197A4 (en) | 2020-10-20 | 2024-11-20 | Twelve Benefit Corporation | IONIC POLYMERS AND COPOLYMERS |
| KR102481048B1 (ko) * | 2021-01-21 | 2022-12-27 | 서강대학교산학협력단 | 알칼리-옥살산염 전환 전기화학적 공정 |
| EP4294964A4 (en) * | 2021-02-19 | 2025-11-12 | Prometheus Fuels Inc | INTEGRATED DIRECT AIR CAPTURE AND ELECTROCHEMICAL REDUCTION OF CARBON DIOXIDE |
| BR112023016931A2 (pt) | 2021-02-23 | 2023-11-07 | Twelve Benefit Corp | Procedimento de recuperação para eletrolisadores de óxido de carbono |
| US20230112608A1 (en) | 2021-10-13 | 2023-04-13 | Disruptive Oil And Gas Technologies Corp | Nanobubble dispersions generated in electrochemically activated solutions |
| US12305304B2 (en) | 2022-10-13 | 2025-05-20 | Twelve Benefit Corporation | Interface for carbon oxide electrolyzer bipolar membrane |
| CN115672020B (zh) * | 2022-12-12 | 2023-02-28 | 中国科学院西北生态环境资源研究院 | 烟道废气中二氧化碳捕集分离催化装置及其控制方法 |
| US12378685B2 (en) | 2022-12-22 | 2025-08-05 | Twelve Benefit Corporation | Surface modification of metal catalysts with hydrophobic ligands or ionomers |
| CN117138542A (zh) * | 2023-08-23 | 2023-12-01 | 中国华能集团清洁能源技术研究院有限公司 | 一种碳还原装置及方法 |
| CN119332256A (zh) * | 2024-09-18 | 2025-01-21 | 万华化学集团股份有限公司 | 一种草酸的制备方法 |
| WO2026128441A1 (en) * | 2024-12-10 | 2026-06-18 | Northwestern University | Integrated system for electrosynthesis of co and related methods |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1280622A (en) | 1915-05-08 | 1918-10-08 | Launcelot W Andrews | Process for manufacturing oxalates. |
| DE2301032A1 (de) | 1973-01-10 | 1974-07-25 | Dechema | Verfahren und vorrichtung zur herstellung von oxalsaeure durch elektrochemische reduktion von kohlendioxid |
| US4589963A (en) * | 1984-12-07 | 1986-05-20 | The Dow Chemical Company | Process for the conversion of salts of carboxylic acid to their corresponding free acids |
| US5290404A (en) | 1990-10-31 | 1994-03-01 | Reilly Industries, Inc. | Electro-synthesis of alcohols and carboxylic acids from corresponding metal salts |
| US5928806A (en) * | 1997-05-07 | 1999-07-27 | Olah; George A. | Recycling of carbon dioxide into methyl alcohol and related oxygenates for hydrocarbons |
| JP2009511740A (ja) * | 2005-10-13 | 2009-03-19 | マントラ エナジー オールターナティヴス リミテッド | 二酸化炭素の連続並流電気化学還元 |
| EP2132820A4 (en) | 2007-04-03 | 2014-12-24 | New Sky Energy Inc | ELECTROCHEMICAL SYSTEM, DEVICE AND METHOD FOR PRODUCING RENEWABLE HYDROGEN AND FOR SEQUESTRATING CARBON DIOXIDE |
| JP4992019B2 (ja) * | 2007-08-10 | 2012-08-08 | 公益財団法人地球環境産業技術研究機構 | 酸とアルカリの製造方法 |
| US8282810B2 (en) * | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
| US9099720B2 (en) * | 2009-05-29 | 2015-08-04 | Medtronic, Inc. | Elongate battery for implantable medical device |
| WO2011067873A1 (ja) | 2009-12-04 | 2011-06-09 | パナソニック株式会社 | 二酸化炭素還元方法、並びに、それに用いる二酸化炭素還元触媒および二酸化炭素還元装置 |
| US20110114502A1 (en) * | 2009-12-21 | 2011-05-19 | Emily Barton Cole | Reducing carbon dioxide to products |
| US8524066B2 (en) * | 2010-07-29 | 2013-09-03 | Liquid Light, Inc. | Electrochemical production of urea from NOx and carbon dioxide |
-
2013
- 2013-08-05 KR KR1020157009788A patent/KR20150056627A/ko not_active Withdrawn
- 2013-08-05 ES ES13839580.1T patent/ES2655423T3/es active Active
- 2013-08-05 CN CN201380048389.0A patent/CN104919088A/zh active Pending
- 2013-08-05 CA CA2883437A patent/CA2883437C/en active Active
- 2013-08-05 EP EP13839580.1A patent/EP2898117B1/en active Active
- 2013-08-05 JP JP2015533059A patent/JP6333263B2/ja active Active
- 2013-08-05 WO PCT/US2013/053566 patent/WO2014046791A1/en not_active Ceased
- 2013-08-05 BR BR112015006193A patent/BR112015006193A2/pt not_active IP Right Cessation
- 2013-08-05 DK DK13839580.1T patent/DK2898117T3/en active
- 2013-08-05 AU AU2013318500A patent/AU2013318500B8/en active Active
-
2015
- 2015-03-18 SA SA515360158A patent/SA515360158B1/ar unknown
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