CA2883437C - Integrated process for producing carboxylic acids from carbon dioxide - Google Patents

Integrated process for producing carboxylic acids from carbon dioxide Download PDF

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Publication number
CA2883437C
CA2883437C CA2883437A CA2883437A CA2883437C CA 2883437 C CA2883437 C CA 2883437C CA 2883437 A CA2883437 A CA 2883437A CA 2883437 A CA2883437 A CA 2883437A CA 2883437 C CA2883437 C CA 2883437C
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CA
Canada
Prior art keywords
alkali metal
electrochemical
region
anolyte
catholyte
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CA2883437A
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English (en)
French (fr)
Other versions
CA2883437A1 (en
Inventor
Jerry J. Kaczur
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Avantium Knowledge Centre BV
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Avantium Knowledge Centre BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/724,339 external-priority patent/US9175407B2/en
Application filed by Avantium Knowledge Centre BV filed Critical Avantium Knowledge Centre BV
Publication of CA2883437A1 publication Critical patent/CA2883437A1/en
Application granted granted Critical
Publication of CA2883437C publication Critical patent/CA2883437C/en
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Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/23—Carbon monoxide or syngas
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/07—Oxygen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • C25B9/73—Assemblies comprising two or more cells of the filter-press type
    • C25B9/77—Assemblies comprising two or more cells of the filter-press type having diaphragms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CA2883437A 2012-09-19 2013-08-05 Integrated process for producing carboxylic acids from carbon dioxide Active CA2883437C (en)

Applications Claiming Priority (23)

Application Number Priority Date Filing Date Title
US201261703238P 2012-09-19 2012-09-19
US201261703232P 2012-09-19 2012-09-19
US201261703231P 2012-09-19 2012-09-19
US201261703229P 2012-09-19 2012-09-19
US201261703175P 2012-09-19 2012-09-19
US201261703158P 2012-09-19 2012-09-19
US201261703187P 2012-09-19 2012-09-19
US201261703234P 2012-09-19 2012-09-19
US61/703,231 2012-09-19
US61/703,187 2012-09-19
US61/703,232 2012-09-19
US61/703,158 2012-09-19
US61/703,229 2012-09-19
US61/703,175 2012-09-19
US61/703,238 2012-09-19
US61/703,234 2012-09-19
US201261715060P 2012-10-17 2012-10-17
US61/715,060 2012-10-17
US201261720670P 2012-10-31 2012-10-31
US61/720,670 2012-10-31
US13/724,339 2012-12-21
US13/724,339 US9175407B2 (en) 2012-07-26 2012-12-21 Integrated process for producing carboxylic acids from carbon dioxide
PCT/US2013/053566 WO2014046791A1 (en) 2012-09-19 2013-08-05 Integrated process for producing carboxylic acids from carbon dioxide

Publications (2)

Publication Number Publication Date
CA2883437A1 CA2883437A1 (en) 2014-03-27
CA2883437C true CA2883437C (en) 2020-10-27

Family

ID=50341843

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2883437A Active CA2883437C (en) 2012-09-19 2013-08-05 Integrated process for producing carboxylic acids from carbon dioxide

Country Status (11)

Country Link
EP (1) EP2898117B1 (enExample)
JP (1) JP6333263B2 (enExample)
KR (1) KR20150056627A (enExample)
CN (1) CN104919088A (enExample)
AU (1) AU2013318500B8 (enExample)
BR (1) BR112015006193A2 (enExample)
CA (1) CA2883437C (enExample)
DK (1) DK2898117T3 (enExample)
ES (1) ES2655423T3 (enExample)
SA (1) SA515360158B1 (enExample)
WO (1) WO2014046791A1 (enExample)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2950294C (en) * 2014-05-29 2022-07-19 Liquid Light, Inc. Method and system for electrochemical reduction of carbon dioxide employing a gas diffusion electrode
KR101738590B1 (ko) 2015-07-14 2017-06-09 한국에너지기술연구원 이산화탄소를 전기환원시켜 이산화탄소의 환원 생성물을 제조하는 방법 및 장치
CA3011375A1 (en) * 2016-01-13 2017-07-20 Avantium Knowledge Centre B.V. Process for producing formic acid and lactic acid
US10822709B2 (en) 2016-05-03 2020-11-03 Opus 12 Incorporated Reactor with advanced architecture for the electrochemical reaction of CO2, CO and other chemical compounds
US12359325B2 (en) 2016-05-03 2025-07-15 Twelve Benefit Corporation Membrane electrode assembly for COx reduction
JP6636885B2 (ja) 2016-09-12 2020-01-29 株式会社東芝 還元触媒および還元反応装置
CN110088360A (zh) * 2016-11-24 2019-08-02 阿凡田知识中心有限公司 方法
JP6845114B2 (ja) * 2017-09-20 2021-03-17 株式会社東芝 二酸化炭素電解装置および二酸化炭素電解方法
GB201811785D0 (en) * 2018-07-19 2018-09-05 Univ Surrey A continuous process for sustainable production of hydrogen
US11578415B2 (en) * 2018-11-28 2023-02-14 Twelve Benefit Corporation Electrolyzer and method of use
EP3899092A1 (en) 2018-12-18 2021-10-27 Opus 12 Incorporated Electrolyzer and method of use
KR102331686B1 (ko) * 2019-03-08 2021-11-30 서강대학교산학협력단 이산화탄소의 옥살산 전환 전기화학적 공정
JP7204620B2 (ja) * 2019-09-17 2023-01-16 株式会社東芝 電気化学反応装置
KR20260100871A (ko) 2019-11-25 2026-06-30 트웰브 베네핏 코포레이션 COx 환원을 위한 막 전극 조립체
EP4232197A4 (en) 2020-10-20 2024-11-20 Twelve Benefit Corporation IONIC POLYMERS AND COPOLYMERS
KR102481048B1 (ko) * 2021-01-21 2022-12-27 서강대학교산학협력단 알칼리-옥살산염 전환 전기화학적 공정
EP4294964A4 (en) * 2021-02-19 2025-11-12 Prometheus Fuels Inc INTEGRATED DIRECT AIR CAPTURE AND ELECTROCHEMICAL REDUCTION OF CARBON DIOXIDE
BR112023016931A2 (pt) 2021-02-23 2023-11-07 Twelve Benefit Corp Procedimento de recuperação para eletrolisadores de óxido de carbono
US20230112608A1 (en) 2021-10-13 2023-04-13 Disruptive Oil And Gas Technologies Corp Nanobubble dispersions generated in electrochemically activated solutions
US12305304B2 (en) 2022-10-13 2025-05-20 Twelve Benefit Corporation Interface for carbon oxide electrolyzer bipolar membrane
CN115672020B (zh) * 2022-12-12 2023-02-28 中国科学院西北生态环境资源研究院 烟道废气中二氧化碳捕集分离催化装置及其控制方法
US12378685B2 (en) 2022-12-22 2025-08-05 Twelve Benefit Corporation Surface modification of metal catalysts with hydrophobic ligands or ionomers
CN117138542A (zh) * 2023-08-23 2023-12-01 中国华能集团清洁能源技术研究院有限公司 一种碳还原装置及方法
CN119332256A (zh) * 2024-09-18 2025-01-21 万华化学集团股份有限公司 一种草酸的制备方法
WO2026128441A1 (en) * 2024-12-10 2026-06-18 Northwestern University Integrated system for electrosynthesis of co and related methods

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1280622A (en) 1915-05-08 1918-10-08 Launcelot W Andrews Process for manufacturing oxalates.
DE2301032A1 (de) 1973-01-10 1974-07-25 Dechema Verfahren und vorrichtung zur herstellung von oxalsaeure durch elektrochemische reduktion von kohlendioxid
US4589963A (en) * 1984-12-07 1986-05-20 The Dow Chemical Company Process for the conversion of salts of carboxylic acid to their corresponding free acids
US5290404A (en) 1990-10-31 1994-03-01 Reilly Industries, Inc. Electro-synthesis of alcohols and carboxylic acids from corresponding metal salts
US5928806A (en) * 1997-05-07 1999-07-27 Olah; George A. Recycling of carbon dioxide into methyl alcohol and related oxygenates for hydrocarbons
JP2009511740A (ja) * 2005-10-13 2009-03-19 マントラ エナジー オールターナティヴス リミテッド 二酸化炭素の連続並流電気化学還元
EP2132820A4 (en) 2007-04-03 2014-12-24 New Sky Energy Inc ELECTROCHEMICAL SYSTEM, DEVICE AND METHOD FOR PRODUCING RENEWABLE HYDROGEN AND FOR SEQUESTRATING CARBON DIOXIDE
JP4992019B2 (ja) * 2007-08-10 2012-08-08 公益財団法人地球環境産業技術研究機構 酸とアルカリの製造方法
US8282810B2 (en) * 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
US9099720B2 (en) * 2009-05-29 2015-08-04 Medtronic, Inc. Elongate battery for implantable medical device
WO2011067873A1 (ja) 2009-12-04 2011-06-09 パナソニック株式会社 二酸化炭素還元方法、並びに、それに用いる二酸化炭素還元触媒および二酸化炭素還元装置
US20110114502A1 (en) * 2009-12-21 2011-05-19 Emily Barton Cole Reducing carbon dioxide to products
US8524066B2 (en) * 2010-07-29 2013-09-03 Liquid Light, Inc. Electrochemical production of urea from NOx and carbon dioxide

Also Published As

Publication number Publication date
EP2898117B1 (en) 2017-10-25
WO2014046791A1 (en) 2014-03-27
DK2898117T3 (en) 2018-01-22
CN104919088A (zh) 2015-09-16
CA2883437A1 (en) 2014-03-27
JP6333263B2 (ja) 2018-05-30
EP2898117A1 (en) 2015-07-29
KR20150056627A (ko) 2015-05-26
BR112015006193A2 (pt) 2017-07-04
AU2013318500B8 (en) 2017-08-10
ES2655423T3 (es) 2018-02-20
AU2013318500B2 (en) 2017-07-20
AU2013318500A1 (en) 2015-03-26
EP2898117A4 (en) 2015-10-21
JP2015535825A (ja) 2015-12-17
AU2013318500A8 (en) 2017-08-10
SA515360158B1 (ar) 2016-04-21

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