JP2015535530A - 炭化水素流からの有機アミンの除去および回収のための方法 - Google Patents
炭化水素流からの有機アミンの除去および回収のための方法 Download PDFInfo
- Publication number
- JP2015535530A JP2015535530A JP2015544385A JP2015544385A JP2015535530A JP 2015535530 A JP2015535530 A JP 2015535530A JP 2015544385 A JP2015544385 A JP 2015544385A JP 2015544385 A JP2015544385 A JP 2015544385A JP 2015535530 A JP2015535530 A JP 2015535530A
- Authority
- JP
- Japan
- Prior art keywords
- phase
- aqueous
- hydrocarbon
- amine
- iii
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 60
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 60
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 59
- 150000001412 amines Chemical class 0.000 title claims abstract description 51
- 238000000034 method Methods 0.000 title claims abstract description 42
- 238000011084 recovery Methods 0.000 title claims abstract description 9
- 239000008346 aqueous phase Substances 0.000 claims abstract description 26
- 238000002156 mixing Methods 0.000 claims abstract description 23
- 239000012071 phase Substances 0.000 claims abstract description 21
- 239000012074 organic phase Substances 0.000 claims abstract description 17
- 150000007522 mineralic acids Chemical class 0.000 claims abstract description 15
- 239000012670 alkaline solution Substances 0.000 claims abstract description 3
- 238000006384 oligomerization reaction Methods 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 9
- 239000005977 Ethylene Substances 0.000 claims description 9
- 238000000746 purification Methods 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 239000004711 α-olefin Substances 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 239000003463 adsorbent Substances 0.000 claims description 4
- 230000009849 deactivation Effects 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 150000002484 inorganic compounds Chemical class 0.000 claims description 2
- 229910010272 inorganic material Inorganic materials 0.000 claims description 2
- 239000002808 molecular sieve Substances 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims description 2
- 239000000741 silica gel Substances 0.000 claims description 2
- 229910002027 silica gel Inorganic materials 0.000 claims description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 2
- 238000010908 decantation Methods 0.000 claims 1
- 230000003134 recirculating effect Effects 0.000 abstract description 2
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000005191 phase separation Methods 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- -1 amine salt Chemical class 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000003518 caustics Substances 0.000 description 4
- 238000004821 distillation Methods 0.000 description 3
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003606 oligomerizing effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/82—Purification; Separation; Stabilisation; Use of additives
- C07C209/86—Separation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
- C07C7/17—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with acids or sulfur oxides
- C07C7/171—Sulfuric acid or oleum
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G17/00—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge
- C10G17/02—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge with acids or acid-containing liquids, e.g. acid sludge
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G57/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one cracking process or refining process and at least one other conversion process
- C10G57/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one cracking process or refining process and at least one other conversion process with polymerisation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
- C07C7/17—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with acids or sulfur oxides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G17/00—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge
- C10G17/02—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge with acids or acid-containing liquids, e.g. acid sludge
- C10G17/04—Liquid-liquid treatment forming two immiscible phases
- C10G17/06—Liquid-liquid treatment forming two immiscible phases using acids derived from sulfur or acid sludge thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G17/00—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge
- C10G17/02—Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge with acids or acid-containing liquids, e.g. acid sludge
- C10G17/04—Liquid-liquid treatment forming two immiscible phases
- C10G17/07—Liquid-liquid treatment forming two immiscible phases using halogen acids or oxyacids of halogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
a.オリゴマ化反応器中にエチレンを供給するステップと、
b.反応器中のエチレンをオリゴマ化するステップと、
c.直鎖アルファオレフィンを含む反応器の出口流を、反応器出口の配管系を通って反応器から除去するステップと、
d.任意選択で反応器の出口流を触媒の失活および除去ステップに移送するステップと、
e.任意選択で反応器の出口流から触媒を失活させ、かつ除去するステップと、
を含み、少なくとも1種の有機アミンがオリゴマ化反応器中および/または反応器出口の配管系に加えられる、方法に組み込まれている。反応器の出口流またはその画分は、次いで本発明の炭化水素流とすることができる。
アミン+HCl→アミン塩
に従って酸と反応させる。アミン塩は、水相に可溶であり、したがって結果として、炭化水素流から水相中に抽出することができる。
アミン塩+NaOH→アミン+H2O+NaCl
を実現することによって、アルカリ水溶液と混合することができる。この反応ステップでは、苛性アルカリ(NaOH)も、Ca(OH)2のような任意の他のアルカリ媒体と置き換えることができる。
Claims (10)
- アミンを含有する炭化水素流からの有機アミンの除去および回収のための方法であって、
(i)前記アミンを含有する炭化水素流を、水性無機酸と、炭化水素流:水性無機酸1:1超〜5:1、好ましくは1.5:1〜4:1、より好ましくは3:1の容量比で混合するステップと、
(ii)炭化水素相と水相を相分離するステップと、
(iii)前記炭化水素相を除去し、任意選択でさらにそれを精製するステップと、
(iv)任意選択で、ステップ(iii)で得られた前記炭化水素相の少なくとも一部を、混合するステップ(i)に再循環させるステップと、
(v)ステップ(iii)で得られた前記水相をアルカリ水溶液と混合するステップと、
(vi)形成された水相と有機相を相分離するステップと、
(vii)ステップ(vi)で得られた前記有機相を除去し、任意選択でさらにそれを精製するステップと、
を含むことを特徴とする方法。 - 請求項1に記載の方法であって、前記アミンを含有する炭化水素流が、エチレンのオリゴマ化によって直鎖アルファオレフィン(LAO)を調製するための反応器からの出口流またはその出口流の画分であることを特徴とする方法。
- 請求項2に記載の方法であって、前記画分が、C10〜C18の範囲の生成物の画分であることを特徴とする方法。
- 請求項1〜3のいずれか1項に記載の方法であって、前記水性無機酸が、10wt.%の濃度、好ましくは5wt.%の濃度の水性HCl、または水性硫酸であることを特徴とする方法。
- 請求項1〜4のいずれか1項に記載の方法であって、ステップ(iii)における前記炭化水素相の除去がデカントによることを特徴とする方法。
- 請求項1〜5のいずれか1項に記載の方法であって、ステップ(iii)におけるさらなる精製が、前記炭化水素相の水洗および得られた前記炭化水素相を吸着剤に通すことによって行われ、前記吸着剤が好ましくは、シリカゲル、アルミナおよびモレキュラーシーブを含む群から選択される無機化合物であることを特徴とする方法。
- 請求項1〜6のいずれか1項に記載の方法であって、ステップ(vii)における前記有機相の精製が、水洗、前記水相の除去および/または前記有機相からのあらゆる残留水の蒸留によることを特徴とする方法。
- 請求項1〜7のいずれか1項に記載の方法であって、ステップ(vii)で得られた前記有機相が、ステップ(i)より前の前記アミンを含有する炭化水素流に再循環されることを特徴とする方法。
- 請求項1〜8のいずれか1項に記載の方法であって、ステップ(vi)で得られた前記水相が、エチレンのオリゴマ化のためのプラントの触媒除去および失活セクションに移送されることを特徴とする方法。
- 請求項1〜9のいずれか1項に記載の方法であって、ステップ(v)におけるpHが塩基性であることを特徴とする方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12194658.6 | 2012-11-28 | ||
EP12194658.6A EP2738152B1 (en) | 2012-11-28 | 2012-11-28 | Method for removal and recovery of organic amines from a hydrocarbon stream |
PCT/EP2013/069932 WO2014082770A1 (en) | 2012-11-28 | 2013-09-25 | Method for removal and recovery of organic amines from a hydrocarbon stream |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2018018075A Division JP2018065883A (ja) | 2012-11-28 | 2018-02-05 | 炭化水素流からの有機アミンの除去および回収のための方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2015535530A true JP2015535530A (ja) | 2015-12-14 |
JP6513026B2 JP6513026B2 (ja) | 2019-05-15 |
Family
ID=47263163
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015544385A Expired - Fee Related JP6513026B2 (ja) | 2012-11-28 | 2013-09-25 | 炭化水素流からの有機アミンの除去および回収のための方法 |
JP2018018075A Withdrawn JP2018065883A (ja) | 2012-11-28 | 2018-02-05 | 炭化水素流からの有機アミンの除去および回収のための方法 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2018018075A Withdrawn JP2018065883A (ja) | 2012-11-28 | 2018-02-05 | 炭化水素流からの有機アミンの除去および回収のための方法 |
Country Status (13)
Country | Link |
---|---|
US (1) | US8809611B2 (ja) |
EP (1) | EP2738152B1 (ja) |
JP (2) | JP6513026B2 (ja) |
KR (1) | KR102109058B1 (ja) |
CN (1) | CN104955791B (ja) |
BR (1) | BR112015012002A2 (ja) |
CA (1) | CA2892959A1 (ja) |
MX (1) | MX365167B (ja) |
MY (1) | MY196937A (ja) |
RU (1) | RU2612967C2 (ja) |
SG (1) | SG11201504071SA (ja) |
TW (1) | TWI520931B (ja) |
WO (1) | WO2014082770A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018065883A (ja) * | 2012-11-28 | 2018-04-26 | サウディ ベーシック インダストリーズ コーポレイション | 炭化水素流からの有機アミンの除去および回収のための方法 |
KR20190060368A (ko) * | 2017-11-24 | 2019-06-03 | 한국에너지기술연구원 | 아민을 포함하는 기체의 고순도화 공정 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018503643A (ja) * | 2015-01-16 | 2018-02-08 | サビック グローバル テクノロジーズ ベスローテン フェンノートシャップ | アミン除去装置におけるエマルジョン除去方法 |
US10760008B2 (en) * | 2017-06-05 | 2020-09-01 | Baker Hughes, A Ge Company, Llc | Compositions and methods of removing contaminants in refinery desalting |
CN108727226B (zh) * | 2018-06-01 | 2021-02-09 | 黎明化工研究设计院有限责任公司 | 一种四丁基脲中二丁胺的去除方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4392948A (en) * | 1979-07-06 | 1983-07-12 | Labofina, S.A. | Process for removing the nitrogen impurities from a hydrocarbon mixture |
EP2258674A1 (en) * | 2009-05-06 | 2010-12-08 | Saudi Basic Industries Corporation | Method for removal of an organic amine from a hydrocarbon stream |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2263176A (en) * | 1938-06-20 | 1941-11-18 | Tide Water Associated Oil Comp | Process of recovering nitrogen bases |
LU85346A1 (fr) * | 1984-05-02 | 1986-01-29 | Labofina Sa | Procede de purification d'effluents acides |
US4973790A (en) * | 1989-11-16 | 1990-11-27 | Mobil Oil Corporation | Process for upgrading light olefinic streams |
DE69012295T2 (de) * | 1989-11-16 | 1995-01-05 | Mobil Oil Corp | Verfahren zur Qualitätserhöhung von Leichtolefinströmen. |
FR2715154B1 (fr) | 1994-01-14 | 1996-04-05 | Inst Francais Du Petrole | Procédé de production d'oléfines alpha légères de pureté améliorée par oligomérisation, de l'éthylène. |
PT1141043E (pt) * | 1999-09-23 | 2005-01-31 | Bp Corp North America Inc | Oleos oligomericos e sua producao |
WO2009095417A1 (en) | 2008-01-28 | 2009-08-06 | Specialites Pet Food | Method for enhancing pet food palatability |
CN105753622B (zh) * | 2008-01-30 | 2019-01-29 | 林德股份公司 | 制备线性α-烯烃的方法 |
EP2338865A1 (en) * | 2009-12-22 | 2011-06-29 | Total Petrochemicals Research Feluy | Process for removing oxygenated contaminants from an hydrocarbon stream |
EP2455359B1 (en) * | 2010-11-23 | 2013-03-27 | Linde AG | Method for purification of a hydrocarbon stream olefin and amine |
EP2738152B1 (en) * | 2012-11-28 | 2019-05-01 | Saudi Basic Industries Corporation | Method for removal and recovery of organic amines from a hydrocarbon stream |
-
2012
- 2012-11-28 EP EP12194658.6A patent/EP2738152B1/en not_active Not-in-force
-
2013
- 2013-09-25 MY MYPI2015001253A patent/MY196937A/en unknown
- 2013-09-25 SG SG11201504071SA patent/SG11201504071SA/en unknown
- 2013-09-25 WO PCT/EP2013/069932 patent/WO2014082770A1/en active Application Filing
- 2013-09-25 CA CA2892959A patent/CA2892959A1/en not_active Abandoned
- 2013-09-25 JP JP2015544385A patent/JP6513026B2/ja not_active Expired - Fee Related
- 2013-09-25 MX MX2015006557A patent/MX365167B/es active IP Right Grant
- 2013-09-25 RU RU2015124112A patent/RU2612967C2/ru active
- 2013-09-25 KR KR1020157014449A patent/KR102109058B1/ko active IP Right Grant
- 2013-09-25 CN CN201380060475.3A patent/CN104955791B/zh not_active Expired - Fee Related
- 2013-09-25 BR BR112015012002A patent/BR112015012002A2/pt not_active IP Right Cessation
- 2013-11-01 US US14/070,039 patent/US8809611B2/en not_active Expired - Fee Related
- 2013-11-26 TW TW102143019A patent/TWI520931B/zh not_active IP Right Cessation
-
2018
- 2018-02-05 JP JP2018018075A patent/JP2018065883A/ja not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4392948A (en) * | 1979-07-06 | 1983-07-12 | Labofina, S.A. | Process for removing the nitrogen impurities from a hydrocarbon mixture |
EP2258674A1 (en) * | 2009-05-06 | 2010-12-08 | Saudi Basic Industries Corporation | Method for removal of an organic amine from a hydrocarbon stream |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018065883A (ja) * | 2012-11-28 | 2018-04-26 | サウディ ベーシック インダストリーズ コーポレイション | 炭化水素流からの有機アミンの除去および回収のための方法 |
KR20190060368A (ko) * | 2017-11-24 | 2019-06-03 | 한국에너지기술연구원 | 아민을 포함하는 기체의 고순도화 공정 |
KR102034860B1 (ko) * | 2017-11-24 | 2019-10-21 | 한국에너지기술연구원 | 아민을 포함하는 기체의 고순도화 공정 |
Also Published As
Publication number | Publication date |
---|---|
CN104955791A (zh) | 2015-09-30 |
MX365167B (es) | 2019-05-14 |
EP2738152A1 (en) | 2014-06-04 |
KR102109058B1 (ko) | 2020-05-12 |
US20140148618A1 (en) | 2014-05-29 |
EP2738152B1 (en) | 2019-05-01 |
SG11201504071SA (en) | 2015-06-29 |
MX2015006557A (es) | 2015-09-10 |
WO2014082770A1 (en) | 2014-06-05 |
JP6513026B2 (ja) | 2019-05-15 |
CN104955791B (zh) | 2016-10-26 |
JP2018065883A (ja) | 2018-04-26 |
TWI520931B (zh) | 2016-02-11 |
TW201433562A (zh) | 2014-09-01 |
RU2015124112A (ru) | 2017-01-10 |
BR112015012002A2 (pt) | 2017-07-11 |
KR20150088264A (ko) | 2015-07-31 |
RU2612967C2 (ru) | 2017-03-14 |
US8809611B2 (en) | 2014-08-19 |
CA2892959A1 (en) | 2014-06-05 |
MY196937A (en) | 2023-05-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP2018065883A (ja) | 炭化水素流からの有機アミンの除去および回収のための方法 | |
RU2469014C2 (ru) | Способ получения линейных альфа-олефинов | |
EP2258674A1 (en) | Method for removal of an organic amine from a hydrocarbon stream | |
JP2007112799A (ja) | ニトロ化工程からの混酸混合物の回収方法 | |
KR20080037030A (ko) | 에틸렌의 올리고머화에서의 촉매 성분들의 비활성화 및제거 방법 | |
JP2017190351A (ja) | オレフィンおよびアミンを含有する炭化水素流の精製方法 | |
JP2016522803A (ja) | ニトロベンゼン製造からの廃水の後処理方法 | |
JP2014528504A (ja) | 炭化水素流から有機アミンを除去する方法 | |
KR101667418B1 (ko) | 아세트산-질산-인산계 혼산 폐액으로부터의 인산의 분리 회수 방법 | |
ATE529383T1 (de) | Verfahren und vorrichtung zur herstellung von calciumbromid durch flüssig-flüssig extraktion | |
RU2018127060A (ru) | Способ получения (мет)акриловой кислоты | |
RU2663621C1 (ru) | Способ удаления эмульсии в установке удаления аминов |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150821 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20150821 |
|
A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A711 Effective date: 20160426 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20160426 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20160927 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20161222 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20170131 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20171003 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20181227 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20190409 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6513026 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
LAPS | Cancellation because of no payment of annual fees |