JP2015533697A5 - - Google Patents
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- Publication number
- JP2015533697A5 JP2015533697A5 JP2015535807A JP2015535807A JP2015533697A5 JP 2015533697 A5 JP2015533697 A5 JP 2015533697A5 JP 2015535807 A JP2015535807 A JP 2015535807A JP 2015535807 A JP2015535807 A JP 2015535807A JP 2015533697 A5 JP2015533697 A5 JP 2015533697A5
- Authority
- JP
- Japan
- Prior art keywords
- microspheres
- main surface
- binder layer
- article
- less
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004005 microsphere Substances 0.000 claims 7
- 239000011230 binding agent Substances 0.000 claims 6
- 239000011347 resin Substances 0.000 claims 4
- 229920005989 resin Polymers 0.000 claims 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims 1
- 235000015450 Tilia cordata Nutrition 0.000 claims 1
- 235000011941 Tilia x europaea Nutrition 0.000 claims 1
- 239000005388 borosilicate glass Substances 0.000 claims 1
- 239000004571 lime Substances 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N silicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
Claims (2)
- 少なくとも第１の表面を含む物品であって、前記第１の表面は、
（ａ）直鎖状樹脂及び低架橋密度樹脂のうちの少なくとも１種から選択される第１の結合剤層であって、第２の主表面とは反対側の第１の主表面を有する、第１の結合剤層と、
（ｂ）前記第１の結合剤層の前記第１の主表面内に少なくとも部分的に包埋された複数の微小球と、を有し、前記微小球は１．５７以下の屈折率を有するソーダ石灰ケイ酸塩微小球及び１．４９以下の屈折率を有するホウケイ酸塩ガラス微小球の少なくとも１つより選ばれる、物品。 - 第１の表面を含む物品であって、前記第１の表面は、
（ａ）直鎖状樹脂及び低架橋密度樹脂のうちの少なくとも１種から選択される第１の結合剤層であって、第２の主表面とは反対側の第１の主表面を有する、第１の結合剤層と、
（ｂ）前記第１の結合剤層の前記第１の主表面内に少なくとも部分的に包埋された複数の微小球であって、前記第１の主表面の少なくとも一部に対して、前記第１の主表面のその部分の３０％以上かつ前記第１の主表面のその部分の５０％以下を覆う、複数の微小球と、を有し、
更に、前記微小球は、略均一に離間配置されており、破損時の伸び率が２６％よりも大きい、物品。
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261709366P | 2012-10-04 | 2012-10-04 | |
| US61/709,366 | 2012-10-04 | ||
| US201361791918P | 2013-03-15 | 2013-03-15 | |
| US61/791,918 | 2013-03-15 | ||
| PCT/US2013/063392 WO2014055828A1 (en) | 2012-10-04 | 2013-10-04 | Thermoformable microsphere articles |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015533697A JP2015533697A (ja) | 2015-11-26 |
| JP2015533697A5 true JP2015533697A5 (ja) | 2016-11-24 |
| JP6388589B2 JP6388589B2 (ja) | 2018-09-12 |
Family
ID=49448302
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015535807A Active JP6388589B2 (ja) | 2012-10-04 | 2013-10-04 | 熱成形可能な微小球物品 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US9650499B2 (ja) |
| EP (1) | EP2903836B1 (ja) |
| JP (1) | JP6388589B2 (ja) |
| KR (1) | KR102132308B1 (ja) |
| CN (1) | CN104853931A (ja) |
| WO (1) | WO2014055828A1 (ja) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10513626B2 (en) | 2013-06-26 | 2019-12-24 | 3M Innovative Properties Company | Stain resistant microsphere articles |
| WO2015123526A1 (en) | 2014-02-13 | 2015-08-20 | 3M Innovative Properties Company | Flexible microsphere articles having high temperature stability |
| CN106029363B (zh) | 2014-02-13 | 2018-01-16 | 3M创新有限公司 | 双重固化耐污微球体制品 |
| WO2016130172A1 (en) * | 2015-02-13 | 2016-08-18 | 3M Innovative Properties Company | Flexible microsphere articles having high temperature stability |
| US10442967B2 (en) * | 2015-08-12 | 2019-10-15 | 3M Innovative Properties Company | Chemical resistant microsphere articles |
| DE102015011894A1 (de) | 2015-09-11 | 2017-03-16 | Konrad Hornschuch Ag | Folie |
| US11390059B2 (en) * | 2015-12-18 | 2022-07-19 | 3M Innovative Properties Company | Decorative article featuring a microscopic periodic pattern and methods of making the same |
| WO2017106098A1 (en) | 2015-12-18 | 2017-06-22 | 3M Innovative Properties Company | Process for depositing dry powder particles onto a substrate and attaching the particles to the substrate |
| WO2017106613A1 (en) | 2015-12-18 | 2017-06-22 | 3M Innovative Properties Company | Process for depositing dry powder particles onto a substrate and adhesively bonding the particles to the substrate |
| EP3436259A4 (en) | 2016-03-30 | 2020-02-05 | 3M Innovative Properties Company | ARTICLE HAVING A PREDETERMINED PATTERN OF RANDOM DISTRIBUTED MICROSPHERES AND METHODS OF MAKING SAME |
| US20200180353A1 (en) | 2017-08-31 | 2020-06-11 | 3M Innovative Properties Company | Shaped transfer article comprising partially embedded microspheres, shaped finished articles therefrom, and methods of making |
| CN111108138A (zh) * | 2017-09-21 | 2020-05-05 | 3M创新有限公司 | 挤出的聚氨酯表面膜 |
| WO2019197956A1 (en) | 2018-04-13 | 2019-10-17 | 3M Innovative Properties Company | Articles with textured surfaces having pseudorandom protrusions |
| EP3837297A1 (en) * | 2018-08-14 | 2021-06-23 | 3M Innovative Properties Company | Extruded polyurethane surface films |
| EP3969279B1 (en) * | 2019-05-17 | 2023-06-28 | 3M Innovative Properties Company | Microsphere-coated polyurethane articles and methods of making the same |
| CN110376182B (zh) * | 2019-08-15 | 2021-11-30 | 西南交通大学 | 具有内在拉曼光子导向能力的sers基底及其制备方法 |
| CN111897040B (zh) * | 2020-08-12 | 2022-04-15 | 常州市日月反光材料有限公司 | 一种高强度抗撕裂反光膜及其制备工艺 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2546853B2 (ja) | 1987-09-03 | 1996-10-23 | オーツタイヤ株式会社 | 装飾性ビーズコートシートおよびその製造方法 |
| US5055347A (en) * | 1988-12-09 | 1991-10-08 | Minnesota Mining And Manufacturing Company | Retroreflective sheeting adapted to be bonded to vulcanizable or curable substrate |
| JP2740943B2 (ja) | 1994-10-31 | 1998-04-15 | 大日本印刷株式会社 | 耐摩耗性を有する化粧材 |
| US5620775A (en) * | 1995-11-03 | 1997-04-15 | Minnesota Mining And Manufacturing Company | Low refractive index glass microsphere coated article having a smooth surface and a method for preparing same |
| US6365262B1 (en) | 1998-10-20 | 2002-04-02 | 3M Innovative Properties Company | Pavement marking articles having enhanced retroreflectivity under dry or wet conditions and method for making same |
| JP3453679B2 (ja) * | 2000-04-27 | 2003-10-06 | 大日本印刷株式会社 | 化粧材 |
| AU2003277661C1 (en) * | 2002-11-27 | 2005-12-08 | Kiwa Chemical Industry Co., Ltd. | Retroreflective Sheet |
| US7854984B2 (en) | 2005-05-03 | 2010-12-21 | The Diller Corporation | Wear-resistant decorative laminates |
| US7645355B2 (en) * | 2006-11-17 | 2010-01-12 | 3M Innovative Properties Company | Method of making a microsphere transfer adhesive |
| US7833611B2 (en) * | 2007-02-23 | 2010-11-16 | Mannington Mills, Inc. | Olefin based compositions and floor coverings containing the same |
| US20090246439A1 (en) * | 2008-03-31 | 2009-10-01 | 3M Innovative Properties Company | Decorative sheet |
-
2013
- 2013-10-04 US US14/433,054 patent/US9650499B2/en active Active
- 2013-10-04 EP EP13780006.6A patent/EP2903836B1/en active Active
- 2013-10-04 WO PCT/US2013/063392 patent/WO2014055828A1/en active Application Filing
- 2013-10-04 JP JP2015535807A patent/JP6388589B2/ja active Active
- 2013-10-04 KR KR1020157011472A patent/KR102132308B1/ko active IP Right Grant
- 2013-10-04 CN CN201380052321.XA patent/CN104853931A/zh active Pending
-
2017
- 2017-04-05 US US15/479,496 patent/US9868832B2/en active Active
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