JP2015531795A - 亜鉛(ii)アミジン錯体を含む水性樹脂性分散体およびその製造方法 - Google Patents
亜鉛(ii)アミジン錯体を含む水性樹脂性分散体およびその製造方法 Download PDFInfo
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- JP2015531795A JP2015531795A JP2015520322A JP2015520322A JP2015531795A JP 2015531795 A JP2015531795 A JP 2015531795A JP 2015520322 A JP2015520322 A JP 2015520322A JP 2015520322 A JP2015520322 A JP 2015520322A JP 2015531795 A JP2015531795 A JP 2015531795A
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- dispersion
- aqueous resinous
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- active hydrogen
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
- C09D5/4465—Polyurethanes
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Abstract
Description
本発明は、水性樹脂性分散体、かかる分散体を作製する方法、関連する塗料組成物および被覆基材に関する。
塗料塗布法としての電着は、印加電位の影響下での伝導性基材上への膜形成組成物の堆積を伴う。電着は、非電気泳動型塗装法と比べてより高いペイント利用率、ずば抜けた耐食性、および低環境汚染がもたらされるため、塗装業界において普及してきている。カチオン電着およびアニオン電着の両方が商業的に使用されており、カチオン電着の方が、高い腐食防御レベルが所望される用途において、より広まっている。
特定の観点において、本発明は水性樹脂性分散体を作製する方法に関する。この方法は、第1の水性樹脂性分散体を第2の水性樹脂性分散体と合わせることを含む。第1の水性樹脂性分散体は(i)活性水素含有カチオン塩基含有ポリマー;および(ii)亜鉛(II)アミジン錯体を含むものである。第2の水性樹脂性分散体は:(i)活性水素含有カチオン塩基含有ポリマー;および(ii)少なくとも一部がブロックされたポリイソシアネートを含むものである。
以下の詳細説明の目的上、本発明では、そうでないことを明示している場合を除き、種々の択一的なバリエーションおよび工程シーケンスが想定され得ると理解されるべきである。さらに、任意の作業実施例以外、またはそうでないことを記載している場合以外、例えば、本明細書および特許請求の範囲で用いている成分の量を示す数値はすべて、すべての場合において用語「約」によって修飾されていると理解されるべきである。したがって、そうでないことを記載していない限り、以下の明細書および添付の特許請求の範囲に示された数値パラメータは、本発明により得られる所望の特性に応じて異なり得る近似値である。少なくとも、均等論の適用を特許請求の範囲の範囲に限定する試みとしてではなく、各数値パラメータは少なくとも、報告した有効数字の数値に鑑みて通常の丸め手法を適用することにより解釈されるべきである。
の部分を有するウレタン含有物質を含むものである。
の化合物と反応させることにより調製される。
を有する物質で少なくとも一部がブロックされたポリイソシアネート、これは米国特許第6,017,432号の第2欄、43〜64行目および第6欄、33行目〜第8欄、38行目(記載した箇所は引用により本明細書に組み込まれる)に記載されている;(ii)ケトオキシム−ブロックポリイソシアネート、これは米国特許第3,694,389号の第2欄、24行目〜第6欄、29行目(記載した箇所は引用により本明細書に組み込まれる)に記載されている;ならびに(iii)3,5−ジメチルピラゾールブロックポリイソシアネート、例えば、Baxenden Chemicals,Ltd.(Lancashire,England)から市販されているものが挙げられる。
この実施例では、実施例6の生成物およびスズ無含有顔料ペースト(顔料/バインダー比は0.1)を用いて作製した15%固形分のエレクトロコーティング浴組成物を記載する。
この実施例では、実施例7の生成物およびスズ無含有ペーストCP549(顔料/バインダー比は0.1)を用いて作製した15%固形分のエレクトロコーティング浴組成物を記載する。
この実施例では、36%固形分の対照樹脂ブレンドの調製を記載する。この樹脂ブレンドは単相物質であり、経時的に(60日間超)沈降は示されなかった。
この実施例では、実施例10の生成物およびDBTO含有ペーストCP 524(PPG industries製)(顔料/バインダー比は0.1)を用いて作製した15%固形分の対照エレクトロコーティング浴組成物を記載する。
実施例8、9および11の組成物を0.8ミルの所望のフィルムビルドで、それぞれ、被覆条件(90°F/120秒/225V)および(90°F/120秒/250V)で塗装し、一連の温度における硬化(ガスオーブン内でピーク金属温度にて20分間)について調べた。以下に結果を以下の表12に示す。
Claims (19)
- (a)活性水素含有カチオン塩基含有ポリマー;
(b)亜鉛(II)アミジン錯体;および
(c)320°Fまたは320°F未満の温度で硬化する水性樹脂性分散体が得られるように選択された少なくとも一部がブロックされたポリイソシアネート
を含むものであり、
安定な分散体である、
水性樹脂性分散体。 - 前記活性水素含有カチオン塩基含有ポリマーが非ゲル化ポリエポキシド−ポリオキシアルキレンポリアミン樹脂を含むものである、請求項1に記載の分散体。
- 前記活性水素含有カチオン塩基含有ポリマーが、さらにポリエポキシド−アミン付加物を含み、該ポリエポキシドと反応するアミンの一部分がポリアミンのケチミンである、請求項2に記載の分散体。
- 前記亜鉛(II)アミジン錯体がアミジン配位子およびカルボキシレート配位子を含むものである、請求項1に記載の分散体。
- 250°F〜320°Fの温度で硬化する、請求項1に記載の分散体。
- 275°F〜320°Fの温度で硬化する、請求項6に記載の分散体。
- 請求項1に記載の分散体を導電性アノードおよび導電性カソードと接触させて配置することを含み、塗装対象表面が該カソードである方法。
- 第1の水性樹脂性分散体を第2の水性樹脂性分散体と合わせることを含む、水性樹脂性分散体を作製する方法であって:
(a)該第1の水性樹脂性分散体が:
(i)活性水素含有カチオン塩基含有ポリマー;および
(ii)亜鉛(II)アミジン錯体
を含むものであり;
(b)該第2の水性樹脂性分散体が:
(i)活性水素含有カチオン塩基含有ポリマー;および
(ii)少なくとも一部がブロックされたポリイソシアネート
を含むものである、
方法。 - 前記第1の水性樹脂性分散体および前記第2の水性樹脂性分散体がともに安定な分散体である、請求項9に記載の方法。
- 前記第1の水性樹脂性分散体中に存在する前記活性水素含有カチオン塩基含有ポリマーが非ゲル化ポリエポキシド−ポリオキシアルキレンポリアミン樹脂を含むものである、請求項9に記載の方法。
- 前記第2の水性分散体中に存在する前記活性水素含有カチオン塩基含有ポリマーがポリエポキシド−アミン付加物を含むものであり、該ポリエポキシドと反応するアミンの一部分がポリアミンのケチミンである、請求項11に記載の方法。
- 前記亜鉛(II)アミジン錯体がアミジン配位子およびカルボキシレート配位子を含むものである、請求項9に記載の方法。
- 前記亜鉛(II)アミジン錯体が前記第1の水性樹脂性分散体中に、前記第1の水性樹脂性分散体の全固形分重量に対して10〜30重量パーセントの量で存在する、請求項9に記載の方法。
- 前記第1の水性樹脂性分散体が任意の少なくとも一部がブロックされたポリイソシアネートを実質的に含有していない、請求項9に記載の方法。
- 前記第1の水性樹脂性分散体がスズ含有金属触媒を実質的に含有していない、請求項9に記載の方法。
- 前記少なくとも一部がブロックされたポリイソシアネートが、前記第1の水性分散体と合わせると320°Fまたは320°F未満の温度で硬化する水性樹脂性分散体が得られるように選択される、請求項9に記載の方法。
- 請求項9に記載の方法によって作製される組成物を導電性アノードおよび導電性カソードと接触させて配置することを含み、塗装対象表面が該カソードである、基材を塗装する方法。
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US13/531,935 US9534074B2 (en) | 2012-06-25 | 2012-06-25 | Aqueous resinous dispersions that include a zinc (II) amidine complex and methods for the manufacture thereof |
PCT/US2013/046976 WO2014004273A1 (en) | 2012-06-25 | 2013-06-21 | Aqueous resinous dispersions that include a zinc (ii) amidine complex and methods for the manufacture thereof |
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EP2757123A3 (en) * | 2013-01-18 | 2017-11-01 | PPG Industries Ohio Inc. | Clear electrodepositable primers for radiator coatings |
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- 2013-06-21 CA CA2877870A patent/CA2877870C/en active Active
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2015
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JP2002503287A (ja) * | 1997-07-03 | 2002-01-29 | ピーピージー インダストリーズ オハイオ,インコーポレイテッド | 電着可能コーティング組成物およびカチオン性電着方法におけるこれらの使用 |
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SG11201408672RA (en) | 2015-02-27 |
HK1207872A1 (en) | 2016-02-12 |
BR112014032670B1 (pt) | 2021-11-03 |
MX2015000170A (es) | 2015-07-17 |
EP2864384B1 (en) | 2021-08-04 |
IN2014DN11054A (ja) | 2015-09-25 |
CN104520344B (zh) | 2016-11-09 |
AU2013280822A1 (en) | 2015-01-29 |
PL2864384T3 (pl) | 2021-11-29 |
KR20150023854A (ko) | 2015-03-05 |
AU2013280822B2 (en) | 2015-07-30 |
KR101674330B1 (ko) | 2016-11-08 |
CA2877870C (en) | 2017-02-28 |
BR112014032670A2 (pt) | 2017-06-27 |
RU2015102086A (ru) | 2016-08-10 |
EP2864384A1 (en) | 2015-04-29 |
CN104520344A (zh) | 2015-04-15 |
US9534074B2 (en) | 2017-01-03 |
CA2877870A1 (en) | 2014-01-03 |
ZA201602371B (en) | 2017-07-26 |
HUE055914T2 (hu) | 2022-01-28 |
RU2610278C2 (ru) | 2017-02-08 |
US20130344231A1 (en) | 2013-12-26 |
WO2014004273A1 (en) | 2014-01-03 |
ES2882809T3 (es) | 2021-12-02 |
JP5952965B2 (ja) | 2016-07-13 |
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