JP2015526562A5 - - Google Patents
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- Publication number
- JP2015526562A5 JP2015526562A5 JP2015527997A JP2015527997A JP2015526562A5 JP 2015526562 A5 JP2015526562 A5 JP 2015526562A5 JP 2015527997 A JP2015527997 A JP 2015527997A JP 2015527997 A JP2015527997 A JP 2015527997A JP 2015526562 A5 JP2015526562 A5 JP 2015526562A5
- Authority
- JP
- Japan
- Prior art keywords
- additive composition
- derivative
- quinone
- group
- derivatives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 claims 21
- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims 19
- 239000000654 additive Substances 0.000 claims 16
- 230000000996 additive effect Effects 0.000 claims 16
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 12
- 238000000034 method Methods 0.000 claims 11
- -1 quinone methide derivatives Chemical class 0.000 claims 10
- 150000003512 tertiary amines Chemical class 0.000 claims 9
- 239000000178 monomer Substances 0.000 claims 8
- 238000006116 polymerization reaction Methods 0.000 claims 6
- 229920002554 vinyl polymer Polymers 0.000 claims 5
- 238000004519 manufacturing process Methods 0.000 claims 4
- 150000001412 amines Chemical class 0.000 claims 3
- BYACHAOCSIPLCM-UHFFFAOYSA-N 2-[2-[bis(2-hydroxyethyl)amino]ethyl-(2-hydroxyethyl)amino]ethanol Chemical compound OCCN(CCO)CCN(CCO)CCO BYACHAOCSIPLCM-UHFFFAOYSA-N 0.000 claims 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims 2
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims 2
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 230000002401 inhibitory effect Effects 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims 2
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 claims 2
- CSGAUKGQUCHWDP-UHFFFAOYSA-N 1-hydroxy-2,2,6,6-tetramethylpiperidin-4-ol Chemical compound CC1(C)CC(O)CC(C)(C)N1O CSGAUKGQUCHWDP-UHFFFAOYSA-N 0.000 claims 1
- UZFMOKQJFYMBGY-UHFFFAOYSA-N 4-hydroxy-TEMPO Chemical compound CC1(C)CC(O)CC(C)(C)N1[O] UZFMOKQJFYMBGY-UHFFFAOYSA-N 0.000 claims 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical class ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000004093 cyano group Chemical group *C#N 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- LGRLWUINFJPLSH-UHFFFAOYSA-N methanide Chemical compound [CH3-] LGRLWUINFJPLSH-UHFFFAOYSA-N 0.000 claims 1
- 125000005525 methide group Chemical group 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- ODUCDPQEXGNKDN-UHFFFAOYSA-N nitroxyl Chemical class O=N ODUCDPQEXGNKDN-UHFFFAOYSA-N 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 150000004053 quinones Chemical class 0.000 claims 1
- 238000000101 transmission high energy electron diffraction Methods 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IN2465MU2012 | 2012-08-24 | ||
| IN2465/MUM/2012 | 2012-08-24 | ||
| PCT/IB2013/056787 WO2014030131A1 (en) | 2012-08-24 | 2013-08-21 | Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015526562A JP2015526562A (ja) | 2015-09-10 |
| JP2015526562A5 true JP2015526562A5 (https=) | 2016-09-23 |
| JP6255405B2 JP6255405B2 (ja) | 2017-12-27 |
Family
ID=54187096
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015527997A Active JP6255405B2 (ja) | 2012-08-24 | 2013-08-21 | モノマーの重合の制御及び阻害用キノンメチド及びアミンの組成物、並びにその製造及び使用する方法 |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US9234057B2 (https=) |
| EP (1) | EP2888212B1 (https=) |
| JP (1) | JP6255405B2 (https=) |
| KR (1) | KR101803750B1 (https=) |
| CN (1) | CN104718181B (https=) |
| AU (1) | AU2013307242B2 (https=) |
| BR (1) | BR112015003564B1 (https=) |
| CA (1) | CA2880244C (https=) |
| ES (1) | ES2686127T3 (https=) |
| MX (1) | MX360426B (https=) |
| MY (1) | MY182112A (https=) |
| PL (1) | PL2888212T3 (https=) |
| RU (1) | RU2632879C2 (https=) |
| SG (1) | SG11201500774WA (https=) |
| TW (1) | TWI610915B (https=) |
| WO (1) | WO2014030131A1 (https=) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9234057B2 (en) * | 2012-08-24 | 2016-01-12 | Dorf Ketal Chemicals (India) Private Limited | Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof |
| IN2013MU01165A (https=) * | 2013-03-26 | 2015-04-24 | Dorf Ketal Chemicals India Private Ltd | |
| CN108884004B (zh) * | 2016-02-13 | 2020-02-25 | 多尔夫凯塔尔化学制品（I）私人有限公司 | 用于控制和抑制乙烯基芳族单体聚合的组合物，及其使用方法 |
| US11180578B2 (en) | 2018-07-13 | 2021-11-23 | Ecolab Usa Inc. | Polymerization inhibitor and retarder compositions with amine stabilizer |
| EP3820836A1 (en) | 2018-07-13 | 2021-05-19 | Ecolab USA, Inc. | Compositions of oxygenated amines and quinone methides as antifoulants for vinylic monomers |
| TWI880966B (zh) | 2019-10-11 | 2025-04-21 | 美商藝康美國公司 | 醌甲基化物及銨鹽抗聚合劑組合物及方法 |
| CN116553996A (zh) * | 2023-07-07 | 2023-08-08 | 吉林金海化工新材料有限公司 | 一种阻聚剂及其应用 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2039757C1 (ru) * | 1992-05-15 | 1995-07-20 | Нижнекамское производственное объединение "Нижнекамскнефтехим" | Способ ингибирования полимеризации винилароматических мономеров |
| US5583247A (en) * | 1995-04-14 | 1996-12-10 | Ciba-Geigy Corporation | 7-substituted quinone methides as inhibitors for unsaturated monomers |
| US6024894A (en) * | 1998-03-25 | 2000-02-15 | Betzdearborn Inc. | Compositions and methods for inhibiting vinyl aromatic monomer polymerization |
| US7045647B2 (en) * | 2000-10-16 | 2006-05-16 | Uniroyal Chemical Company, Inc. | Blends of quinone alkide and nitroxyl compounds and polymerization inhibitors |
| US20040034247A1 (en) * | 2002-08-16 | 2004-02-19 | Sherif Eldin | Compositions and methods for inhibiting vinyl aromatic monomer polymerization |
| CN101102984A (zh) * | 2004-12-03 | 2008-01-09 | 科聚亚公司 | 作为聚合抑制剂的与含氮氧自由基的化合物或c-亚硝基苯胺结合的芳族磺酸、胺和硝基酚 |
| US7651635B1 (en) * | 2009-02-05 | 2010-01-26 | Nalco Company | Polymer inhibition of vinyl aromatic monomers using a quinone methide/alkyl hydroxylamine combination |
| US8298440B2 (en) | 2010-06-03 | 2012-10-30 | General Electric Company | Methods and compositions for inhibiting vinyl aromatic monomer polymerization |
| KR101812624B1 (ko) * | 2011-08-26 | 2017-12-27 | 도르프 케탈 케미칼즈 (인디아) 프라이비트 리미티드 | 스타이렌의 중합화의 제어 및 억제를 위한 첨가제 조성물, 및 그의 제조와 사용 방법 |
| ES2547893T3 (es) * | 2011-12-26 | 2015-10-09 | Dorf Ketal Chemicals (India) Private Limited | Composición de aditivo mejorada a base de amina para el control y la inhibición de la polimerización de monómeros aromáticos de vinilo, y procedimiento para su uso |
| US9234057B2 (en) * | 2012-08-24 | 2016-01-12 | Dorf Ketal Chemicals (India) Private Limited | Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof |
-
2013
- 2013-08-21 US US14/423,218 patent/US9234057B2/en active Active
- 2013-08-21 BR BR112015003564-7A patent/BR112015003564B1/pt active IP Right Grant
- 2013-08-21 PL PL13765802T patent/PL2888212T3/pl unknown
- 2013-08-21 MY MYPI2015700524A patent/MY182112A/en unknown
- 2013-08-21 EP EP13765802.7A patent/EP2888212B1/en active Active
- 2013-08-21 JP JP2015527997A patent/JP6255405B2/ja active Active
- 2013-08-21 SG SG11201500774WA patent/SG11201500774WA/en unknown
- 2013-08-21 ES ES13765802.7T patent/ES2686127T3/es active Active
- 2013-08-21 RU RU2015109877A patent/RU2632879C2/ru active
- 2013-08-21 KR KR1020157007306A patent/KR101803750B1/ko active Active
- 2013-08-21 CA CA2880244A patent/CA2880244C/en active Active
- 2013-08-21 CN CN201380044001.XA patent/CN104718181B/zh active Active
- 2013-08-21 AU AU2013307242A patent/AU2013307242B2/en not_active Ceased
- 2013-08-21 MX MX2015002382A patent/MX360426B/es active IP Right Grant
- 2013-08-21 WO PCT/IB2013/056787 patent/WO2014030131A1/en not_active Ceased
- 2013-08-23 TW TW102130325A patent/TWI610915B/zh active
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