JP2015515641A5 - - Google Patents

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JP2015515641A5
JP2015515641A5 JP2014558744A JP2014558744A JP2015515641A5 JP 2015515641 A5 JP2015515641 A5 JP 2015515641A5 JP 2014558744 A JP2014558744 A JP 2014558744A JP 2014558744 A JP2014558744 A JP 2014558744A JP 2015515641 A5 JP2015515641 A5 JP 2015515641A5
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monoatomic layer
layer
region
monoatomic
gas mixture
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Claims (16)

デバイス内の化合物層上にフィーチャを形成するための方法であって、
(a)基板表面上に化合物層の第1単原子層を形成するために、処理チャンバ内に配置された基板の表面に第1反応ガス混合物をパルス供給する工程と、
(b)第1単原子層の第1領域を処理するために、エネルギー照射を向ける工程と、
(c)第1単原子層を第1領域から除去する工程と、
(d)第1単原子層の第2領域上に第2単原子層を選択的に形成するために、基板表面に第2反応ガス混合物をパルス供給する工程であって、第2単原子層は、第2領域上に化合物層を形成するために、第1単原子層と反応する工程を含む方法。
A method for forming a feature on a compound layer in a device comprising:
(A) pulsing a first reactant gas mixture to the surface of the substrate disposed in the processing chamber to form a first monoatomic layer of the compound layer on the substrate surface;
(B) directing energy irradiation to treat the first region of the first monoatomic layer;
(C) removing the first monoatomic layer from the first region;
(D) pulse supplying a second reactive gas mixture to the substrate surface to selectively form a second monoatomic layer on the second region of the first monoatomic layer , the second monoatomic layer The method comprising reacting with the first monoatomic layer to form a compound layer on the second region .
エネルギー照射によって処理された第1単原子層の第1領域に配置された第1単原子層を選択的に除去する工程を含む請求項1記載の方法。   The method of claim 1, comprising selectively removing a first monoatomic layer disposed in a first region of the first monoatomic layer that has been treated by energy irradiation. 基板表面上の処理された第1単原子層を除去した後、第1及び第2単原子層の構造又はフィーチャを形成する工程を含む請求項2記載の方法。   3. The method of claim 2 including the step of forming the first and second monoatomic layer structures or features after removing the treated first monoatomic layer on the substrate surface. 第1単原子層を除去する工程は、The step of removing the first monoatomic layer includes
基板表面から処理された第1単原子層を除去するためにエッチング処理を行う請求項2記載の方法。3. The method of claim 2, wherein an etching process is performed to remove the processed first monoatomic layer from the substrate surface.
光の放射は、約5nmと約400nmの間の波長を有するUV光源である請求項1記載の方法。   The method of claim 1, wherein the light radiation is a UV light source having a wavelength between about 5 nm and about 400 nm. エネルギー照射を向ける工程は、
エネルギー照射が通過する、マスクによって保護されていない第1単原子層の第1領域にエネルギー照射を向ける工程を含む請求項1記載の方法。
The process of directing energy irradiation is
The method of claim 1, comprising directing the energy irradiation to a first region of the first monoatomic layer that is not protected by a mask through which the energy irradiation passes.
第1反応ガス混合物又は第2反応ガス混合物のパルス供給の後に、処理チャンバにパージガス混合物をパルス供給する工程を含む請求項1記載の方法。   The method of claim 1 including the step of pulsing the purge gas mixture into the processing chamber after pulsing the first reaction gas mixture or the second reaction gas mixture. 第1及び第2単原子層の所定の全厚さが達成されるまで(a)から(c)を繰り返す請求項1記載の方法。   The method of claim 1, wherein (a) to (c) are repeated until a predetermined total thickness of the first and second monoatomic layers is achieved. エネルギー照射を向ける工程は、
第1領域内の第1単原子層の化学的性質を変化させる請求項1記載の方法。
The process of directing energy irradiation is
The method of claim 1, wherein the chemical properties of the first monoatomic layer in the first region are varied.
(a)から(c)は、単一の処理チャンバ内で実行される請求項1記載の方法。   The method of claim 1, wherein (a) to (c) are performed in a single processing chamber. 第1及び第2反応ガス混合物をパルス供給する(a)及び(c)は、処理チャンバ内で形成され、(b)は、別の処理チャンバ内で実行される請求項1記載の方法。   The method of claim 1, wherein (a) and (c) pulsing the first and second reaction gas mixtures are formed in a processing chamber and (b) is performed in another processing chamber. デバイス内の化合物層上にフィーチャを形成するための方法であって、
原子層堆積プロセス内で実行される第1反応ガス混合物のパルス供給によって堆積される材料層の第1単原子層の第1領域を処理するために、エネルギー照射を向ける工程と、
化合物層の第1単原子層上に第2単原子層を形成するために、原子層堆積プロセスを実行し続ける工程であって、第2単原子層は、第1単原子層の第1領域には付着せず、第2単原子層は、第2領域上に化合物層を形成するために、第1単原子層と反応する工程と、
光照射によって処理された第1領域内の第1単原子層を除去する工程を含む方法。
A method for forming a feature on a compound layer in a device comprising:
Directing energy irradiation to treat a first region of a first monoatomic layer of a material layer deposited by pulsing a first reactant gas mixture performed within an atomic layer deposition process;
Continuing to perform an atomic layer deposition process to form a second monoatomic layer on the first monoatomic layer of the compound layer , wherein the second monoatomic layer is a first region of the first monoatomic layer. The second monoatomic layer reacts with the first monoatomic layer to form a compound layer on the second region; and
Removing the first monoatomic layer in the first region treated by light irradiation.
原子層堆積プロセスを実行し続ける工程は、
エネルギー照射によって未処理の第1単原子層の第2領域上のみに第2単原子層を選択的に形成する工程を含む請求項12記載の方法。
The process of continuing to perform the atomic layer deposition process is:
The method according to claim 12 , further comprising the step of selectively forming the second monoatomic layer only on the second region of the untreated first monoatomic layer by energy irradiation.
第1単原子層を除去する工程は、
第2単原子層を除去することなく基板表面から処理された第1単原子層を選択的に除去する工程を含む請求項12記載の方法。
The step of removing the first monoatomic layer includes
13. The method of claim 12 , comprising selectively removing the treated first monoatomic layer from the substrate surface without removing the second monoatomic layer.
光照射は、約5nmと約400nmの間の波長を有するUV光源である請求項12記載の方法。 The method of claim 12 , wherein the light irradiation is a UV light source having a wavelength between about 5 nm and about 400 nm. 半導体デバイス内の化合物層上にフィーチャを形成するための方法であって、A method for forming a feature on a compound layer in a semiconductor device comprising:
(a)基板表面上に化合物層の第1単原子層を形成するために、処理チャンバ内に配置された基板の表面に第1反応ガス混合物をパルス供給する工程と、(A) pulsing a first reactant gas mixture to the surface of the substrate disposed in the processing chamber to form a first monoatomic layer of the compound layer on the substrate surface;
(b)第1単原子層の第1領域を処理するために、光照射を向ける工程と、(B) directing light irradiation to treat the first region of the first monoatomic layer;
(c)第1単原子層の第1領域上に第2単原子層を選択的に形成するために、第2反応ガス混合物をパルス供給する工程であって、第2単原子層は、第1領域上に化合物層を形成するために、第1単原子層と反応する工程と、(C) pulsing the second reactive gas mixture to selectively form the second monoatomic layer on the first region of the first monoatomic layer, the second monoatomic layer comprising: Reacting with the first monoatomic layer to form a compound layer on one region;
(d)光照射によって処理されなかった第1単原子層の第2領域を選択的に除去する工程を含む方法。(D) A method including a step of selectively removing the second region of the first monoatomic layer that has not been processed by light irradiation.
JP2014558744A 2012-02-21 2013-01-24 Atomic layer deposition lithography Expired - Fee Related JP5771339B2 (en)

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US201261601511P 2012-02-21 2012-02-21
US61/601,511 2012-02-21
PCT/US2013/022988 WO2013126175A1 (en) 2012-02-21 2013-01-24 Atomic layer deposition lithography

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