JP2015515439A5 - - Google Patents
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- Publication number
- JP2015515439A5 JP2015515439A5 JP2015503725A JP2015503725A JP2015515439A5 JP 2015515439 A5 JP2015515439 A5 JP 2015515439A5 JP 2015503725 A JP2015503725 A JP 2015503725A JP 2015503725 A JP2015503725 A JP 2015503725A JP 2015515439 A5 JP2015515439 A5 JP 2015515439A5
- Authority
- JP
- Japan
- Prior art keywords
- hypophosphite
- hydroxide
- salt
- catalyst
- quaternary ammonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims description 18
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 11
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- NHGXDBSUJJNIRV-UHFFFAOYSA-M tetrabutylammonium chloride Chemical compound [Cl-].CCCC[N+](CCCC)(CCCC)CCCC NHGXDBSUJJNIRV-UHFFFAOYSA-M 0.000 claims description 4
- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 claims description 4
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 2
- OKIZCWYLBDKLSU-UHFFFAOYSA-M N,N,N-Trimethylmethanaminium chloride Chemical compound [Cl-].C[N+](C)(C)C OKIZCWYLBDKLSU-UHFFFAOYSA-M 0.000 claims description 2
- 229960000686 benzalkonium chloride Drugs 0.000 claims description 2
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 claims description 2
- KXHPPCXNWTUNSB-UHFFFAOYSA-M benzyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1=CC=CC=C1 KXHPPCXNWTUNSB-UHFFFAOYSA-M 0.000 claims description 2
- 229960000800 cetrimonium bromide Drugs 0.000 claims description 2
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 claims description 2
- MCZDHTKJGDCTAE-UHFFFAOYSA-M tetrabutylazanium;acetate Chemical compound CC([O-])=O.CCCC[N+](CCCC)(CCCC)CCCC MCZDHTKJGDCTAE-UHFFFAOYSA-M 0.000 claims description 2
- HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 claims description 2
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 claims description 2
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 claims description 2
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 16
- 239000003054 catalyst Substances 0.000 claims 5
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims 4
- 150000001768 cations Chemical class 0.000 claims 3
- 150000003839 salts Chemical class 0.000 claims 3
- 238000005406 washing Methods 0.000 claims 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims 2
- 150000001449 anionic compounds Chemical group 0.000 claims 2
- 229910001412 inorganic anion Chemical group 0.000 claims 2
- 150000002891 organic anions Chemical group 0.000 claims 2
- 150000004714 phosphonium salts Chemical class 0.000 claims 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 235000019270 ammonium chloride Nutrition 0.000 claims 1
- NLBGHBQQANSEEN-UHFFFAOYSA-N bromomethylbenzene N,N-dimethylmethanamine Chemical compound CN(C)C.BrCC1=CC=CC=C1 NLBGHBQQANSEEN-UHFFFAOYSA-N 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 150000004679 hydroxides Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- 239000002243 precursor Substances 0.000 claims 1
- 125000001453 quaternary ammonium group Chemical group 0.000 claims 1
- 230000000087 stabilizing effect Effects 0.000 claims 1
- 239000003039 volatile agent Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 16
- 238000005481 NMR spectroscopy Methods 0.000 description 12
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 8
- 229910052786 argon Inorganic materials 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- YOUGRGFIHBUKRS-UHFFFAOYSA-N benzyl(trimethyl)azanium Chemical compound C[N+](C)(C)CC1=CC=CC=C1 YOUGRGFIHBUKRS-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2012/073582 WO2013149396A1 (en) | 2012-04-06 | 2012-04-06 | Process for production of hypophosphite salts |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015515439A JP2015515439A (ja) | 2015-05-28 |
| JP2015515439A5 true JP2015515439A5 (https=) | 2016-03-31 |
| JP5992601B2 JP5992601B2 (ja) | 2016-09-14 |
Family
ID=49299933
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015503725A Expired - Fee Related JP5992601B2 (ja) | 2012-04-06 | 2012-04-06 | 次亜リン酸塩の製造方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9976010B2 (https=) |
| EP (1) | EP2834190A4 (https=) |
| JP (1) | JP5992601B2 (https=) |
| KR (1) | KR101979057B1 (https=) |
| CN (1) | CN104936891B (https=) |
| CA (1) | CA2868035A1 (https=) |
| WO (1) | WO2013149396A1 (https=) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106829898A (zh) * | 2017-01-09 | 2017-06-13 | 杨洋 | 一种利用四甲基氢氧化铵母液制备亚磷酸钙的方法 |
| CN107337187B (zh) * | 2017-07-21 | 2019-05-10 | 湖南工业大学 | 一种纳米次磷酸铝的制备方法 |
| CN111892217A (zh) * | 2020-06-24 | 2020-11-06 | 南昌航空大学 | 一种化学镀镍废液中含镍化合物转化再利用的方法 |
| CN114772568B (zh) * | 2021-09-30 | 2023-08-11 | 四川金核高分子材料有限公司 | 一种制备改性次磷酸铝的方法及其产品 |
| CN117550569B (zh) * | 2023-11-28 | 2025-09-19 | 云南云天化股份有限公司 | 一种生产次磷酸的方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2125587C3 (de) | 1971-05-24 | 1974-08-15 | Knapsack Ag, 5033 Huerth-Knapsack | Verfahren zur Herstellung von Hypophosphiten |
| US4265866A (en) | 1979-05-03 | 1981-05-05 | Stauffer Chemical Company | Process for producing hypophosphorous acid (H3 PO2) and non-transition metal hypophosphites |
| DE3207716A1 (de) * | 1982-03-04 | 1983-09-08 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von alkalihypophosphit-loesungen |
| JPS58185412A (ja) * | 1982-04-23 | 1983-10-29 | Nippon Chem Ind Co Ltd:The | 次亜りん酸ソ−ダの製造法 |
| JPH01313310A (ja) * | 1988-06-13 | 1989-12-18 | Nippon Chem Ind Co Ltd | 次亜リン酸ソーダの製造法 |
| SU1616037A1 (ru) * | 1989-01-16 | 1996-01-27 | Институт органической и физической химии им.А.Е.Арбузова Казанского филиала АН СССР | Способ получения гипофосфита натрия |
| JPH07110764B2 (ja) * | 1990-05-30 | 1995-11-29 | 燐化学工業株式会社 | アルカリ金属次亜リン酸塩の製造方法 |
| JP3205004B2 (ja) * | 1991-05-17 | 2001-09-04 | 日本化学工業株式会社 | 亜リン酸アルカリの製造方法 |
| US6238637B1 (en) * | 1998-02-26 | 2001-05-29 | Monsanto Company | Process and apparatus for preparation of phosphorus oxyacids from elemental phosphorus |
| ID27590A (id) * | 1998-02-26 | 2001-04-12 | Monsanto Co | Proses dan peralatan untuk pembuatan asam oksi fosforus dari unsur fosforus |
| ES2307988T3 (es) | 2003-11-07 | 2008-12-01 | Italmatch Chemicals S.P.A. | Composiciones de policarbonato retardadoras de llama libres de halogenos. |
| US7807755B2 (en) * | 2004-05-12 | 2010-10-05 | Commonwealth Scientific And Industrial Research Organisation | Method for removing sulfur-containing end groups |
| CN101332982B (zh) | 2008-07-30 | 2010-06-09 | 江苏康祥集团公司 | 次磷酸钙的生产方法 |
| JP5694933B2 (ja) * | 2008-08-06 | 2015-04-01 | スティロン ヨーロッパ ゲゼルシャフト ミット ベシュレンクテル ハフツング | 耐燃性カーボネート重合体組成物 |
| CN101654233A (zh) * | 2009-06-19 | 2010-02-24 | 昆明理工大学 | 一种综合利用泥磷制取次磷酸钠的方法 |
| AU2009354427B2 (en) | 2009-10-23 | 2014-11-13 | Rhodia (China) Co., Ltd. | Process for stabilizing hypophosphite |
| JP5992906B2 (ja) * | 2010-06-24 | 2016-09-14 | アイシーエル−アイピー アメリカ インコーポレイテッド | 金属ホスホネート難燃剤およびその製造方法 |
-
2012
- 2012-04-06 WO PCT/CN2012/073582 patent/WO2013149396A1/en not_active Ceased
- 2012-04-06 KR KR1020147030501A patent/KR101979057B1/ko not_active Expired - Fee Related
- 2012-04-06 CA CA2868035A patent/CA2868035A1/en not_active Abandoned
- 2012-04-06 CN CN201280072062.2A patent/CN104936891B/zh not_active Expired - Fee Related
- 2012-04-06 JP JP2015503725A patent/JP5992601B2/ja not_active Expired - Fee Related
- 2012-04-06 US US14/389,390 patent/US9976010B2/en not_active Expired - Fee Related
- 2012-04-06 EP EP12873851.5A patent/EP2834190A4/en not_active Withdrawn
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